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charset="UTF-8" src="https://cdn.bibblio.org/rcm/4.23/bib-related-content.min.js" data-auto-ingestion="true" data-recommendation-key="45dcfb80-3ce8-4f5c-87b9-e5c35d842c2f"></script> </div> </div> </div> </div> </div><div class="et_pb_section et_pb_section_1_tb_body et_pb_with_background et_section_regular" > <div class="et_pb_row et_pb_row_1_tb_body"> <div class="et_pb_column et_pb_column_3_4 et_pb_column_1_tb_body et_pb_css_mix_blend_mode_passthrough"> <div class="et_pb_module et_pb_post_title et_pb_post_title_0_tb_body et_pb_bg_layout_light et_pb_text_align_left" > <div class="et_pb_title_container"> <h1 class="entry-title">Monitoring Flare Gas Net Heating Value with Gas Chromatographs</h1><p class="et_pb_title_meta_container"> by <span class="author vcard"><a href="https://www.emersonautomationexperts.com/author/jim-cahill/" title="Posts by Jim Cahill" rel="author">Jim Cahill</a>, <a href="https://www.emersonautomationexperts.com/author/jamie-marsden/" title="Posts by Jamie Marsden" rel="author">Jamie Marsden</a></span> | <span class="published">Aug 24, 2021</span> | <a href="https://www.emersonautomationexperts.com/measurement-instrumentation/analytical/" rel="category tag">Analytical</a>, <a href="https://www.emersonautomationexperts.com/production/" rel="category tag">Production</a> | <span class="comments-number"><a href="https://www.emersonautomationexperts.com/2021/measurement-instrumentation/analytical/monitoring-flare-gas-net-heating-value-gas-chromatographs/#respond"><span class="dsq-postid" data-dsqidentifier="51017 https://www.emersonautomationexperts.com/?p=51017">0 comments</span></a></span></p> </div> </div><div class="et_pb_module et_pb_divider et_pb_divider_0_tb_body et_pb_divider_position_ et_pb_space"><div class="et_pb_divider_internal"></div></div><div class="et_pb_module et_pb_post_content et_pb_post_content_0_tb_body"> <p>Emerson’s <a href="https://www.linkedin.com/in/jamie-marsden-ab0aa34b/">Jamie Marsden</a> presented on the subject of gas chromatographs (GCs) for flare regulations 40 CFR Part 63 at the 4C Heath, Safety & Environmental conference. Here is his presentation abstract:</p> <blockquote><p>Gas Chromatograph Fast BTU Flare measurement and control – Application spotlight to discuss EPA ruling 40-CFR-63 BTU measurement in Flares, and CEMS VOC Measurement. – Discussion on VOC measurement for Vinyl Chloride (VCM) in ambient air.</p></blockquote> <p>Jamie opened describing the <a href="https://www.law.cornell.edu/cfr/text/40/63.670">U.S. 40 CFR 63 regulations</a> which set flare operating limits, require a flare management plan (FMP), and require a continuous parameter monitoring system (CPMS) plant. They also cover pilot flame monitoring, visible emissions and flare tip velocity.</p> <div id="attachment_51018" style="width: 864px" class="wp-caption aligncenter"><a href="https://www.emersonautomationexperts.com/wp-content/uploads/2021/08/flare-gas-system-40-CFR-63.670-controls.png"><img fetchpriority="high" decoding="async" aria-describedby="caption-attachment-51018" class="wp-image-51018" src="https://www.emersonautomationexperts.com/wp-content/uploads/2021/08/flare-gas-system-40-CFR-63.670-controls.png" alt="" width="854" height="479" /></a><p id="caption-attachment-51018" class="wp-caption-text"><a href="https://www.emersonautomationexperts.com/wp-content/uploads/2021/08/flare-gas-system-40-CFR-63.670-controls.png">Click to enlarge</a></p></div> <p><a href="https://www.emerson.com/en-us/catalog/rosemount-1500xa-process-gas-chromatograph"><img decoding="async" class="alignright size-full wp-image-51019" src="https://www.emersonautomationexperts.com/wp-content/uploads/2021/08/Rosemount-1500XA-gas-chromatograph.png" alt="Rosemount 1500XA gas chromatograph" width="194" height="386" srcset="https://www.emersonautomationexperts.com/wp-content/uploads/2021/08/Rosemount-1500XA-gas-chromatograph.png 194w, https://www.emersonautomationexperts.com/wp-content/uploads/2021/08/Rosemount-1500XA-gas-chromatograph-108x214.png 108w" sizes="(max-width: 194px) 100vw, 194px" /></a>The <a href="https://www3.epa.gov/airtoxics/flare/2012flaretechreport.pdf">regulation states</a> that within a 15-minute time block, the owner/operator must measure the net heating value of flare combustion zone gas (NHVcz) to make sure it’s above 270 BTUs per standard cubic foot (BTU/SCF).</p> <p>Technologies that measure net heating value include calorimeter, mass spectroscopy, and gas chromatographs. Calorimeters do BTU measurements only. Mass specs do BTU and composition but require a shelter. GCs do BTU, gas composition, work on multiple streams, but don’t necessarily require a shelter in warmer regions.</p> <p>He described Emerson’s <a href="https://www.emerson.com/en-us/catalog/rosemount-1500xa-process-gas-chromatograph">Rosemount 1500XA gas chromatograph</a> with Intercolumn (ITC) detectors, 2 clocks, 4 detectors and a redesigned detector housing. Parallel chromatography allows for breaking down a complex train into the simpler trains that can be run simultaneously. The ITC can be used to show components as they elute from one column to another.</p> <p>GC technology requires the hydrocarbon to be unpacked into its components which takes time to complete. Sample conditioning is important to make sure the gas being analyzed gets a good, clean sample.</p> <p>Fast GC measurements combine some larger components such as carbon chains 3 atoms and longer into a single measurement (C3+). Longer may consider something like C5+.</p> <p>Visit the <a href="https://www.emerson.com/en-us/automation/measurement-instrumentation/gas-analysis/about-process-gas-chromatographs">Gas Chromatographs section on Emerson.com</a> for more on the technologies and solutions to meet stringent flare regulatory reporting.</p> <div style="margin:30px 0 0 0;"> <h3 style="padding:0 0 30px 0;">Popular Posts</h1> <div class="bib--rcm-init" data-recommendation-key="45dcfb80-3ce8-4f5c-87b9-e5c35d842c2f" data-recommendation-type="popular" data-subtitle-field="description" data-offset="3" data-date-format="DMY" data-style-classes="bib--hover bib--recency-show bib--row-3 bib--wide bib--split bib--shine" data-query-string-params="utm_source=bibblio"> </div> </div><div class="ssba-classic-2 ssba ssbp-wrap alignleft ssbp--theme-1"><div style="text-align:left"><span class="ssba-share-text">Share this...</span><br/><a data-site="linkedin" class="ssba_linkedin_share ssba_share_link" 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