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[Note: A solid below 42°F.] " /> <meta name="robots" content="index, archive" /> <meta property="cdc:template_version" content="4.0"/> <meta property="cdc:last_updated" content="October 30, 2019"/> <meta property="cdc:last_reviewed" content="October 30, 2019"/> <meta property="cdc:content_source" content="EDUCATION AND INFORMATION DIVISION"/> <meta property="cdc:maintained_by" content="EDUCATION AND INFORMATION DIVISION"/> <title>CDC - NIOSH Pocket Guide to Chemical Hazards - Benzene </title> <link rel="stylesheet" type="text/css" href="/niosh/npg/wcms-inc/npg.css" /> </head> <body class="no-js"> <div id="skipmenu"> <a class="skippy sr-only-focusable" href="#content">Skip directly to site content</a> <a class="skippy sr-only-focusable" href="#share-nav">Skip directly to page options</a> <a class="skippy d-none d-lg-block sr-only-focusable" href="#az-large">Skip directly to A-Z link</a> </div>  <div class="container-fluid header-wrapper"> <div class="container"> <header role="banner" aria-label="Header" class="pt-2 pb-2"> <div class="row"> <div class="col cdc-logo"> <a href="https://www.cdc.gov"> <span class="sr-only">Centers for Disease Control and Prevention. 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</div> <div class="row"> <div class="col content"> <h1 id="content">Benzene</h1> <div class="mb-3 card tp-related-pages fourth-level-nav d-none"> <div class="card-header collapse-icon"> <a class="collapse-link float-right nav-minus fs0875" data-toggle="collapse" href="#collapse_819535bae1ca30b564" aria-expanded="false" aria-controls="_collapse"> <svg viewBox="0 0 24 24" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"> <title>Minus</title> <path d="M19,13H5V11H19V13Z"> </path> </svg> </a> <div class="h4">Related Pages</div> </div> <div class="card-body collapse show" id="collapse_819535bae1ca30b564"> </div> </div> <div class="syndicate"> <div class="row"> <div class="col-md-12"> <div class="card mb-2 bg-tertiary"> <div class="card-title h6"> Synonyms & Trade Names </div> <div class="card-body"> <div class="card-text"> Benzol, Phenyl hydride </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-4"> <div class="card mb-2"> <div class="card-title h6">CAS No.</div> <div class="card-body"> <div class="card-text"> 71-43-2 </div> </div> </div> </div> <div class="col-md-4"> <div class="card mb-2"> <div class="card-title h6">RTECS No.</div> <div class="card-body"> <div class="card-text"> <a href='/niosh-rtecs/CY155CC0.html'>CY1400000</a> </div> </div> </div> </div> <div class="col-md-4"> <div class="card mb-2"> <div class="card-title h6">DOT ID & Guide</div> <div class="card-body"> <div class="card-text"> 1114 <a href='//wwwapps.tc.gc.ca/saf-sec-sur/3/erg-gmu/erg/guidepage.aspx/guide130/'>130</a> </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-4"> <div class="card mb-2 bg-tertiary"> <div class='card-title h6'>Formula</div><div class='card-body'><div class='card-text'>C₆H₆</div></div> </div> </div> <div class="col-md-4"> <div class="card mb-2 bg-tertiary"> <div class="card-title h6">Conversion</div> <div class="card-body"> <div class="card-text"> 1 ppm = 3.19 mg/m³ </div> </div> </div> </div> <div class="col-md-4"> <div class="card mb-2 bg-tertiary"> <div class="card-title h6">IDLH</div> <div class="card-body"> <div class="card-text"> Ca [500 ppm]<br />See: <a href = '/niosh/idlh/71432.html'>71432</a> </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-6"> <div class="card mb-2"> <div class="card-title h6">Exposure Limits</div> <div class="card-body"> <div class="card-text"> <h6>NIOSH REL</h6>Ca TWA 0.1 ppm ST 1 ppm <a href = 'nengapdxa.html'>See Appendix A</a> <br /> <h6>OSHA PEL</h6> [1910.1028] TWA 1 ppm ST 5 ppm <a href = 'nengapdxf.html'>See Appendix F</a> </div> </div> </div> </div> <div class="col-md-6"> <div class="card mb-2"> <div class="card-title h6">Measurement Methods</div> <div class="card-body"> <div class="card-text"> <strong>NIOSH</strong> <a href='/niosh/docs/2003-154/pdfs/1500.pdf' >1500</a> , <a href='/niosh/docs/2003-154/pdfs/1501.pdf' >1501</a> , <a href='/niosh/docs/2003-154/pdfs/3700.pdf' >3700</a> , <a href='/niosh/docs/2003-154/pdfs/3800.pdf' >3800</a>;<br /> <strong>OSHA</strong> <a href='//www.osha.gov/sites/default/files/methods/1005-v2-1.pdf' >1005</a> , <a href='//www.osha.gov/sites/default/files/methods/5000.pdf' >5000</a> <br /> See: <a href="/niosh/docs/2003-154/">NMAM</a> or <a href="//www.osha.gov/dts/sltc/methods/index.html">OSHA Methods</a> </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2 bg-tertiary"> <div class="card-title h6">Physical Description</div> <div class="card-body"> <div class="card-text"> Colorless to light-yellow liquid with an aromatic odor. [Note: A solid below 42°F.] </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-2"> <div class="card mb-2"> <div Class='card-title h6'>Molecular Weight</div><div class='card-body'><div class='card-text'>78.1</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2"> <div Class='card-title h6'>Boiling Point</div><div class='card-body'><div class='card-text'>176°F</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2"> <div Class='card-title h6'>Freezing Point</div><div class='card-body'><div class='card-text'>42°F</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2"> <div Class='card-title h6'>Solubility</div><div class='card-body'><div class='card-text'>0.07%</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2"> <div Class='card-title h6'>Vapor Pressure</div><div class='card-body'><div class='card-text'>75 mmHg</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2"> <div Class='card-title h6'>Ionization Potential</div><div class='card-body'><div class='card-text'>9.24 eV</div></div> </div> </div> </div> <div class="row"> <div class="col-md-2"> <div class="card mb-2 bg-tertiary"> <div Class='card-title h6'>Specific Gravity</div><div class='card-body'><div class='card-text'>0.88</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2 bg-tertiary"> <div Class='card-title h6'>Flash Point</div><div class='card-body'><div class='card-text'>12°F</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2 bg-tertiary"> <div Class='card-title h6'>Upper Explosive Limit</div><div class='card-body'><div class='card-text'>7.8%</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2 bg-tertiary"> <div Class='card-title h6'>Lower Explosive Limit</div><div class='card-body'><div class='card-text'>1.2%</div></div> </div> </div> <div class="col-md-2"> <div class="card mb-2 bg-tertiary"> </div> </div> <div class="col-md-2"> <div class="card mb-2 bg-tertiary"> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2"> <div class="card-body"> <div class="card-text"> Class IB Flammable Liquid: Fl.P. below 73°F and BP at or above 100°F. </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2 bg-tertiary"> <div class="card-title h6"> Incompatibilities & Reactivities </div> <div class="card-body"> <div class="card-text"> Strong oxidizers, many fluorides & perchlorates, nitric acid </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2"> <div class="card-title h6"> Exposure Routes </div> <div class="card-body"> <div class="card-text"> inhalation, skin absorption, ingestion, skin and/or eye contact </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2 bg-tertiary"> <div class="card-title h6"> Symptoms </div> <div class="card-body"> <div class="card-text"> irritation eyes, skin, nose, respiratory system; dizziness; headache, nausea, staggered gait; anorexia, lassitude (weakness, exhaustion); dermatitis; bone marrow depression; [potential occupational carcinogen] </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2"> <div class="card-title h6"> Target Organs </div> <div class="card-body"> <div class="card-text"> Eyes, skin, respiratory system, blood, central nervous system, bone marrow </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2 bg-tertiary"> <div class='card-title h6'>Cancer Site</div><div class='card-body'><div class='card-text'>[leukemia]</div></div> </div> </div> </div> <div class="row"> <div class="col-md-6"> <div class="card mb-2"> <div class="card-title h6">Personal Protection/Sanitation</div> <div class="card-body"> (<a href="protect.html">See protection codes</a>) <br /> <strong>Skin:</strong>Prevent skin contact <br /> <strong>Eyes:</strong>Prevent eye contact <br /> <strong>Wash skin:</strong>When contaminated <br /> <strong>Remove:</strong>When wet (flammable) <br /> <strong>Change:</strong>No recommendation <br /> <strong>Provide:</strong>Eyewash, Quick drench </div> </div> </div> <div class="col-md-6"> <div class="card mb-2"> <div class="card-title h6">First Aid</div> <div class="card-body"> (<a href="firstaid.html">See procedures</a>)<br /> <strong>Eye:</strong>Irrigate immediately <br /> <strong>Skin:</strong>Soap wash immediately <br /> <strong>Breathing:</strong>Respiratory support <br /> <strong>Swallow:</strong>Medical attention immediately </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2 bg-tertiary"> <div class="card-title h6"> Respirator Recommendations </div> <div class="card-body"> <p> <a href='nengapdxe.html'>(See Appendix E)</a><br /></p><p><strong>NIOSH</strong><p><strong>At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration:</strong></p> <br />(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode<br />(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus</p><p><strong>Escape:</strong> <br />(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister<br />Any appropriate escape-type, self-contained breathing apparatus <br /> </p> <p> <a href="pgintrod.html#mustread">Important additional information about respirator selection</a> </p> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> <div class="card mb-2"> <div class="card-title h6"> See also </div> <div class="card-body"> <a href="/niosh/npg/pgintrod.html">INTRODUCTION </a>   ICSC CARD: <a href='https://www.ilo.org/dyn/icsc/showcard.display?p_lang=en&p_card_id=0015&p_version=2'>0015</a>   MEDICAL TESTS: <a href='/niosh/docs/2005-110/'>0022</a> </div> </div> </div> </div> </div> </div> </div> <div class="row d-none d-lg-block"> <div class="col pca">  </div> </div> <div class="row"> <div class="col last-reviewed"> Page last reviewed: <span id="last-reviewed-date">October 30, 2019</span> <div class="d-none d-lg-block content-source">Content source: <a href="/niosh/" class="td-none">National Institute for Occupational Safety and Health</a> </div> </div> </div> </main>  <div class="col-lg-3 order-lg-1 leftnav-wrapper"> <nav role="navigation" aria-label="Left Navigation Menu"> <div class="nav-section-home d-sm-block"> <svg xmlns="http://www.w3.org/2000/svg" version="1.1" viewBox="0 0 24 24"><title>home</title> <path d="M9.984 20.016h-4.969v-8.016h-3l9.984-9 9.984 9h-3v8.016h-4.969v-6h-4.031v6z"></path></svg><a href="/niosh/npg/default.html">NIOSH Pocket Guide to Chemical Hazards</a> </div> <ul id="nav-primary" class="list-group tp-nav-main"> <li class="list-group-item nav-lvl1"><a href="/niosh/npg/pgintrod.html">Introduction</a></li> <li class="list-group-item nav-lvl1"><a href="/niosh/npg/search.html">Search the Pocket Guide</a></li> <li class="list-group-item nav-lvl1"> <a href="/niosh/npg/npgsyn-a.html#">Chemical Names, Synonyms and Trade Names</a> <a href="#nav-group-chemical-names-synonyms-and-trade-names" class="nav-plus nav-expandcollapse" data-toggle="collapse" aria-controls="nav-group-chemical-names-synonyms-and-trade-names"><svg viewBox="0 0 24 24"><title>expand</title> <path d="M19,13H13V19H11V13H5V11H11V5H13V11H19V13Z"></path></svg></a><ul class="collapse" id="nav-group-chemical-names-synonyms-and-trade-names"> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-a.html">A</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-b.html">B</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-c.html">C</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-d.html">D</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-e.html">E</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-f.html">F</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-g.html">G</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-h.html">H</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-i.html">I</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-j.html">J</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-k.html">K</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-l.html">L</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-m.html">M</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-n.html">N</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-o.html">O</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-p.html">P</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-q.html">Q</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-r.html">R</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-s.html">S</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-t.html">T</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-u.html">U</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-v.html">V</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-w.html">W</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-x.html">X</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-y.html">Y</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/npgsyn-z.html">Z</a></li> </ul> </li> <li class="list-group-item nav-lvl1"><a href="/niosh/npg/npgdcas.html">CAS Numbers</a></li> <li class="list-group-item nav-lvl1"><a href="/niosh/npg/npgdrtec.html">RTECS Numbers</a></li> <li class="list-group-item nav-lvl1"> <a href="/niosh/npg/nengapdx.html">Appendices</a> <a href="#nav-group-appendices" class="nav-plus nav-expandcollapse" data-toggle="collapse" aria-controls="nav-group-appendices"><svg viewBox="0 0 24 24"><title>expand</title> <path d="M19,13H13V19H11V13H5V11H11V5H13V11H19V13Z"></path></svg></a><ul class="collapse" id="nav-group-appendices"> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/nengapdxa.html">A – NIOSH Potential Occupational Carcinogens</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/nengapdxb.html">B – Thirteen OSHA-Regulated Carcinogens</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/nengapdxc.html">C – Supplementary Exposure Limits</a></li> <li class="list-group-item nav-lvl2"><a href="/niosh/npg/nengapdxd.html">D – Substances with No 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