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Měrná magnetická susceptibilita – Wikipedie

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data-event-name="pinnable-header.vector-appearance.unpin">skrýt</button> </div> </div> </div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">Z Wikipedie, otevřené encyklopedie</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="cs" dir="ltr"><p><b>Měrná magnetická susceptibilita</b> dříve specifická magnetická susceptibilita je <a href="/wiki/Magnetick%C3%A1_susceptibilita" title="Magnetická susceptibilita">magnetická susceptibilita</a> vztažená na jednotkovou hustotu dané látky (nikoli na jednotkovou hmotnost, jak by naznačoval název). Obvyklá značka veličiny <i><a href="/wiki/Ch%C3%AD" title="Chí">χ</a></i><sub>mass</sub>, jednotka v <a href="/wiki/Soustava_SI" title="Soustava SI">SI</a> m<sup>3</sup>·kg<sup>−1</sup> (v <a href="/wiki/Soustava_CGS" title="Soustava CGS">CGS</a> cm<sup>3</sup>·g<sup>−1</sup>). Jde o kvantitativní vyjádření schopnosti částic látky se zmagnetizovat. U izotropních látek jde o <a href="/wiki/Skal%C3%A1r" title="Skalár">skalár</a>, jinak o <a href="/wiki/Tenzor" title="Tenzor">tenzor</a>. </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \chi _{\text{mass}}=\chi /\rho }"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <msub> <mi>&#x03C7;<!-- χ --></mi> <mrow class="MJX-TeXAtom-ORD"> <mtext>mass</mtext> </mrow> </msub> <mo>=</mo> <mi>&#x03C7;<!-- χ --></mi> <mrow class="MJX-TeXAtom-ORD"> <mo>/</mo> </mrow> <mi>&#x03C1;<!-- ρ --></mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \chi _{\text{mass}}=\chi /\rho }</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/bac96962464d1734b3fef0cc9686fa3278b9ae5c" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:12.092ex; height:2.843ex;" alt="{\displaystyle \chi _{\text{mass}}=\chi /\rho }"></span>, kde <span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \chi \,}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>&#x03C7;<!-- χ --></mi> <mspace width="thinmathspace" /> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \chi \,}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/20ccded05dc5366a538db649e7cb6648c02896f9" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:1.842ex; height:2.009ex;" alt="{\displaystyle \chi \,}"></span> je magnetická susceptibilita, <span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \rho \,}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>&#x03C1;<!-- ρ --></mi> <mspace width="thinmathspace" /> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \rho \,}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/a1d651c28959a0f15127c097ff4488b123d9e708" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:1.589ex; height:2.176ex;" alt="{\displaystyle \rho \,}"></span> hustota.</dd></dl> <p>Jedná se o zastaralou veličinu z pohledu SI (normy řady ČSN ISO/IEC 800000) i IUPAC; jako obdobnou charakteristiku schopnosti částic látky se zmagnetizovat aktuální Zelená kniha IUPAC doporučuje veličinu <b>molární magnetická susceptibilita</b> (doporučená značka veličiny χ<sub>m</sub>, jednotka v <a href="/wiki/Soustava_SI" title="Soustava SI">SI</a> m<sup>3</sup>·mol<sup>−1</sup>,<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> definovanou vztahem: </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \chi _{\text{m}}=\chi /V_{\text{m}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <msub> <mi>&#x03C7;<!-- χ --></mi> <mrow class="MJX-TeXAtom-ORD"> <mtext>m</mtext> </mrow> </msub> <mo>=</mo> <mi>&#x03C7;<!-- χ --></mi> <mrow class="MJX-TeXAtom-ORD"> <mo>/</mo> </mrow> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mtext>m</mtext> </mrow> </msub> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \chi _{\text{m}}=\chi /V_{\text{m}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/0ff6e4831b04ea30e1fc460c82a7dfcd2a02711e" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:11.729ex; height:2.843ex;" alt="{\displaystyle \chi _{\text{m}}=\chi /V_{\text{m}}}"></span>, kde <span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle V_{\text{m}}\,}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mtext>m</mtext> </mrow> </msub> <mspace width="thinmathspace" /> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle V_{\text{m}}\,}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/424bed0dc7f724e38838b30473fcf08d64ada160" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:3.343ex; height:2.509ex;" alt="{\displaystyle V_{\text{m}}\,}"></span> je <a href="/wiki/Mol%C3%A1rn%C3%AD_objem" title="Molární objem">molární objem</a> (pozor, nejedná se o magnetickou susceptibilitu vztaženou na jednotkové <a href="/wiki/L%C3%A1tkov%C3%A9_mno%C5%BEstv%C3%AD" title="Látkové množství">látkové množství</a>, jak by naznačoval název).</dd></dl> <div class="mw-heading mw-heading2"><h2 id="Diamagnetika_a_paramagnetika">Diamagnetika a paramagnetika</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=M%C4%9Brn%C3%A1_magnetick%C3%A1_susceptibilita&amp;veaction=edit&amp;section=1" title="Editace sekce: Diamagnetika a paramagnetika" class="mw-editsection-visualeditor"><span>editovat</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=M%C4%9Brn%C3%A1_magnetick%C3%A1_susceptibilita&amp;action=edit&amp;section=1" title="Editovat zdrojový kód sekce Diamagnetika a paramagnetika"><span>editovat zdroj</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>V případě diamagnetik závisí měrná magnetická susceptibilita pouze na poloměrech drah elektronů a nikoliv na teplotě, což je dáno tím, že tepelné oscilace atomů nemají vliv na uspořádání elektronů v orbitalech. Naproti tomu u paramagnetik je teplotě nepřímo úměrná (<a href="/w/index.php?title=Curieho_z%C3%A1kon&amp;action=edit&amp;redlink=1" class="new" title="Curieho zákon (stránka neexistuje)">Curieho zákon</a>). </p> <div class="mw-heading mw-heading2"><h2 id="Experimentální_stanovení_měrné_magnetické_susceptibility"><span id="Experiment.C3.A1ln.C3.AD_stanoven.C3.AD_m.C4.9Brn.C3.A9_magnetick.C3.A9_susceptibility"></span>Experimentální stanovení měrné magnetické susceptibility</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=M%C4%9Brn%C3%A1_magnetick%C3%A1_susceptibilita&amp;veaction=edit&amp;section=2" title="Editace sekce: Experimentální stanovení měrné magnetické susceptibility" class="mw-editsection-visualeditor"><span>editovat</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=M%C4%9Brn%C3%A1_magnetick%C3%A1_susceptibilita&amp;action=edit&amp;section=2" title="Editovat zdrojový kód sekce Experimentální stanovení měrné magnetické susceptibility"><span>editovat zdroj</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Principem je měření síly, kterým je magnetikum vtahováno nebo vypuzováno z vnějšího magnetického pole (<a href="/w/index.php?title=Gouyovy_v%C3%A1hy&amp;action=edit&amp;redlink=1" class="new" title="Gouyovy váhy (stránka neexistuje)">Gouyovy váhy</a>). </p> <div class="mw-heading mw-heading2"><h2 id="Reference">Reference</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=M%C4%9Brn%C3%A1_magnetick%C3%A1_susceptibilita&amp;veaction=edit&amp;section=3" title="Editace sekce: Reference" class="mw-editsection-visualeditor"><span>editovat</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=M%C4%9Brn%C3%A1_magnetick%C3%A1_susceptibilita&amp;action=edit&amp;section=3" title="Editovat zdrojový kód sekce Reference"><span>editovat zdroj</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><a href="#cite_ref-1">↑</a></span> <span class="reference-text">Zelená kniha IUPAC (Quantities, Units and Symbols in Physical Chemistry), 3. vydání (2nd Printing), str. 17. <a rel="nofollow" class="external text" href="http://www.iupac.org/fileadmin/user_upload/publications/e-resources/ONLINE-IUPAC-GB3-2ndPrinting-Online-Sep2012.pdf">Dostupné online</a> <a rel="nofollow" class="external text" href="https://web.archive.org/web/20140211093111/http://www.iupac.org/fileadmin/user_upload/publications/e-resources/ONLINE-IUPAC-GB3-2ndPrinting-Online-Sep2012.pdf">Archivováno</a> 11. 2. 2014 na <a href="/wiki/Internet_Archive" title="Internet Archive">Wayback Machine</a>. 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