Study of Buried Interfaces in Fe/Si Multilayer by Hard X-Ray Emission Spectroscopy

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Fe/Si Multilayer by Hard X-Ray Emission Spectroscopy</title> <meta name="description" content="Study of Buried Interfaces in Fe/Si Multilayer by Hard X-Ray Emission Spectroscopy"> <meta name="keywords" content="buried interfaces, hard X-ray emission spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img 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publication-listing mt-3 mb-3"> <h5 class="card-header" style="font-size:.9rem">Study of Buried Interfaces in Fe/Si Multilayer by Hard X-Ray Emission Spectroscopy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hina%20Verma">Hina Verma</a>, <a href="https://publications.waset.org/abstracts/search?q=Karine%20Le%20Guen"> Karine Le Guen</a>, <a href="https://publications.waset.org/abstracts/search?q=Renaud%20Dalaunay"> Renaud Dalaunay</a>, <a href="https://publications.waset.org/abstracts/search?q=Iyas%20Ismail"> Iyas Ismail</a>, <a href="https://publications.waset.org/abstracts/search?q=Vita%20Ilakovac"> Vita Ilakovac</a>, <a href="https://publications.waset.org/abstracts/search?q=Jean%20Pascal%20Rueff"> Jean Pascal Rueff</a>, <a href="https://publications.waset.org/abstracts/search?q=Yunlin%20Jacques%20Zheng"> Yunlin Jacques Zheng</a>, <a href="https://publications.waset.org/abstracts/search?q=Philippe%20Jonnard"> Philippe Jonnard</a> </p> <p class="card-text"><strong>Abstract:</strong></p> To the extent of our knowledge, X-ray emission spectroscopy (XES) has been applied in the soft x-ray region (photon energy ≤ 2 keV) to study the buried layers and interfaces of stacks of nanometer-thin films. Now we extend the methodology to study the buried interfaces in the hard X-ray region (i.e., ≥ five keV). The emission spectra allow us to study the interactions between elements in the buried layers from the analysis of their valence states, thereby providing sensitive information about the physical-chemical environment of the emitting element in multilayers. We exploit the chemical sensitivity of XES to study the interfaces between Fe and Si layers in the Fe/Si multilayer from the Fe Kβ₂,₅ emission spectra (7108 eV). The Fe Kβ₅ emission line results from the electronic transition from occupied 3d to 1s levels (i.e., valence to core transition) and is hence sensitive to the chemical state of emitting Fe atoms. The comparison of emission spectra recorded for Fe/Si multilayer with Fe and FeSi₂ references reveal the formation of FeSi₂ at the Fe-Si interfaces inside the multilayer stack. The interfacial thickness was calculated to be 1.4 ± 0.2 nm by taking into consideration the intensity of Fe atoms emitted from the interface and the Fe layer. The formation of FeSi₂ at the interface was further confirmed by the X-ray diffraction and X-ray photoelectron spectroscopy done on the Fe/Si multilayer. Hence, we can conclude that the XES in the hard X-ray range could be used to study multilayers and their interfaces and obtain information both qualitatively and quantitatively. <iframe src="https://publications.waset.org/abstracts/136026.pdf" style="width:100%; height:400px;" frameborder="0"></iframe> <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=buried%20interfaces" title="buried interfaces">buried interfaces</a>, <a href="https://publications.waset.org/abstracts/search?q=hard%20X-ray%20emission%20spectroscopy" title=" hard X-ray emission spectroscopy"> hard X-ray emission spectroscopy</a>, <a href="https://publications.waset.org/abstracts/search?q=X-ray%20diffraction" title=" X-ray diffraction"> X-ray diffraction</a>, <a href="https://publications.waset.org/abstracts/search?q=X-ray%20photoelectron%20spectroscopy" title=" X-ray photoelectron spectroscopy"> X-ray photoelectron spectroscopy</a> </p> <a 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Study of Buried Interfaces in Fe/Si Multilayer by Hard X-Ray Emission Spectroscopy