Search results for: 6"-terpyridine

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6"-terpyridine</title> <meta name="description" content="Search results for: 6"-terpyridine"> <meta name="keywords" content="6"-terpyridine"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="6"-terpyridine"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 3</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: 6"-terpyridine</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3</span> Study of Self-Assembled Photocatalyst by Metal-Terpyridine Interactions in Polymer Network</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dong-Cheol%20Jeong">Dong-Cheol Jeong</a>, <a href="https://publications.waset.org/abstracts/search?q=Jookyung%20Lee"> Jookyung Lee</a>, <a href="https://publications.waset.org/abstracts/search?q=Yu%20Hyeon%20Ro"> Yu Hyeon Ro</a>, <a href="https://publications.waset.org/abstracts/search?q=Changsik%20Song"> Changsik Song</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The design and synthesis of photo-active polymeric systems are important in regard to solar energy harvesting and utilization. In this study, we synthesized photo-active polymer, thin films, and polymer gel via iterative self-assembly using reversible metal-terpyridine (M-tpy) interactions. The photocurrent generated in the polymeric thin films with Zn(II) was much higher than those of other films. Apparent diffusion rate constant (kapp) was measured for the electron hopping process via potential-step chronoamperometry. As a result, the kapp for the polymeric thin films with Zn(II) was almost two times larger than those with other metal ions. We found that the anodic photocurrents increased with the inclusion of the multi-walled carbon nanotube (MWNT) layer. Inclusion of MWNTs can provide efficient electron transfer pathways. In addition, polymer gel based on interactions between terpyridine and metal ions was shown the photocatalytic activity. Interestingly, in the Mg-terpyridine gel, the reaction rate of benzylamine to imine photo-oxidative coupling was faster than Fe-terpyridine gel because the Mg-terpyridine gel has two steps electron transfer pathway but Fe-terpyridine gel has three steps electron transfer pathway. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=terpyridine" title="terpyridine">terpyridine</a>, <a href="https://publications.waset.org/abstracts/search?q=photocatalyst" title=" photocatalyst"> photocatalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=self-assebly" title=" self-assebly"> self-assebly</a>, <a href="https://publications.waset.org/abstracts/search?q=metal-ligand" title=" metal-ligand"> metal-ligand</a> </p> <a href="https://publications.waset.org/abstracts/50618/study-of-self-assembled-photocatalyst-by-metal-terpyridine-interactions-in-polymer-network" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/50618.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">308</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">2</span> Homoleptic Complexes of a Tetraphenylporphyrinatozinc(II)-conjugated 2,2':6',6"-Terpyridine</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Angelo%20Lanzilotto">Angelo Lanzilotto</a>, <a href="https://publications.waset.org/abstracts/search?q=Martin%20Kuss-Petermann"> Martin Kuss-Petermann</a>, <a href="https://publications.waset.org/abstracts/search?q=Catherine%20E.%20Housecroft"> Catherine E. Housecroft</a>, <a href="https://publications.waset.org/abstracts/search?q=Edwin%20C.%20Constable"> Edwin C. Constable</a>, <a href="https://publications.waset.org/abstracts/search?q=Oliver%20S.%20Wenger"> Oliver S. Wenger</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We recently described the synthesis of a new tetraphenylporphyrinatozinc(II)-conjugated 2,2':6',6"-terpyridine (1) in which the tpy domain enables the molecule to act as a metalloligand. The synthetic route to 1 has been optimized, the importance of selecting a particular sequence of synthetic steps will be discussed. Three homoleptic complexes have been prepared, [Zn(1)₂]²⁺, [Fe(1)₂]²⁺ and [Ru(1)₂]²⁺, and have been isolated as the hexafluoridophosphate salts. Spectroelectrochemical measurements have been performed and the spectral changes ascribed to redox processes are partitioned on either the porphyrin or the terpyridine units. Compound 1 undergoes a reversible one-electron oxidation/reduction. The removal/gain of a second electron leads to a further irreversible chemical transformation. For the homoleptic [M(1)₂]²⁺ complexes, a suitable potential can be chosen at which both the oxidation and the reduction of the {ZnTPP} core are reversible. When the homoleptic complex contains a redox active metal such as Fe or Ru, spectroelectrochemistry has been used to investigate the metal to ligand charge transfer (MLCT) transition. The latter is sensitive to the oxidation state of the metal, and electrochemical oxidation of the metal center suppresses it. Detailed spectroelectrochemical studies will be presented. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=homoleptic%20complexes" title="homoleptic complexes">homoleptic complexes</a>, <a href="https://publications.waset.org/abstracts/search?q=spectroelectrochemistry" title=" spectroelectrochemistry"> spectroelectrochemistry</a>, <a href="https://publications.waset.org/abstracts/search?q=tetraphenylporphyrinatozinc%28II%29" title=" tetraphenylporphyrinatozinc(II)"> tetraphenylporphyrinatozinc(II)</a>, <a href="https://publications.waset.org/abstracts/search?q=2" title=" 2"> 2</a>, <a href="https://publications.waset.org/abstracts/search?q=2%27%3A6%27" title="2':6'">2':6'</a>, <a href="https://publications.waset.org/abstracts/search?q=6%22-terpyridine" title="6"-terpyridine">6"-terpyridine</a> </p> <a href="https://publications.waset.org/abstracts/59759/homoleptic-complexes-of-a-tetraphenylporphyrinatozincii-conjugated-2266-terpyridine" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/59759.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">219</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">1</span> Supramolecular Approach towards Novel Applications: Battery, Band Gap and Gas Separation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sudhakara%20Naidu%20Neppalli">Sudhakara Naidu Neppalli</a>, <a href="https://publications.waset.org/abstracts/search?q=Tejas%20S.%20Bhosale"> Tejas S. Bhosale</a> </p> <p class="card-text"><strong>Abstract:</strong></p> It is well known that the block copolymer (BCP) can form a complex molecule, through non-covalent bonds such as hydrogen bond, ionic bond and co-ordination bond, with low molecular weight compound as well as with macromolecules, which provide vast applications, includes the alteration of morphology and properties of polymers. Hence we covered the research that, the importance of non-covalent bonds in increasing the non-favourable segmental interactions of the blocks was well examined by attaching and detaching the bonds between the BCP and additive. We also monitored the phase transition of block copolymer and effective interaction parameter (χeff) for Li-doped polymers using small angle x-ray scattering and transmission electron microscopy. The effective interaction parameter (χeff) between two block components was evaluated using Leibler theory based on the incompressible random phase approximation (RPA) for ionized BCP in a disordered state. Furthermore, conductivity experiments demonstrate that the ionic conductivity in the samples quenched from the different structures is morphology-independent, while it increases with increasing ion salt concentration. Morphological transitions, interaction parameter, and thermal stability also examined in quarternized block copolymer. D-spacing was used to estimate effective interaction parameter (χeff) of block components in weak and strong segregation regimes of ordered phase. Metal-containing polymer has been the topic of great attention in recent years due to their wide range of potential application. Similarly, metal- ligand complex is used as a supramolecular linker between the polymers giving rise to a ‘Metallo-Supramolecule assembly. More precisely, functionalized polymer end capped with 2, 2’:6’, 2”- terpyridine ligand can be selectively complexed with wide range of transition metal ions and then subsequently attached to other terpyridine terminated polymer block. In compare to other supramolecular assembly, BCP involved metallo-supramolecule assembly offers vast applications such as optical activity, electrical conductivity, luminescence and photo refractivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=band%20gap" title="band gap">band gap</a>, <a href="https://publications.waset.org/abstracts/search?q=block%20copolymer" title=" block copolymer"> block copolymer</a>, <a href="https://publications.waset.org/abstracts/search?q=conductivity" title=" conductivity"> conductivity</a>, <a href="https://publications.waset.org/abstracts/search?q=interaction%20parameter" title=" interaction parameter"> interaction parameter</a>, <a href="https://publications.waset.org/abstracts/search?q=phase%20transition" title=" phase transition"> phase transition</a> </p> <a href="https://publications.waset.org/abstracts/72662/supramolecular-approach-towards-novel-applications-battery-band-gap-and-gas-separation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/72662.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">169</span> </span> </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/WASET-16th-foundational-anniversary.pdf">WASET celebrates its 16th foundational anniversary</a></li> </ul> </div> <div 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Search results for: 6"-terpyridine