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Search results for: sono-chemistry

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text-center" style="font-size:1.6rem;">Search results for: sono-chemistry</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3</span> High Frequency Sonochemistry: A New Field of Cavitation鈥怓ree Acoustic Materials Synthesis and Manipulation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Amgad%20Rezk">Amgad Rezk</a>, <a href="https://publications.waset.org/abstracts/search?q=Heba%20Ahmed"> Heba Ahmed</a>, <a href="https://publications.waset.org/abstracts/search?q=Leslie%20Yeo"> Leslie Yeo</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Ultrasound presents a powerful means for material synthesis. In this talk, we showcase a new field demonstrating the possibility for harnessing sound energy sources at considerably higher frequencies (10 MHz to 1 GHz) compared to conventional ultrasound (kHz and up to ~2 MHz) for crystalising and manipulating a variety of nanoscale materials. At these frequencies, cavitation鈥攚hich underpins most sonochemical processes鈥攊s largely absent, suggesting that altogether fundamentally different mechanisms are at dominant. Examples include the crystallization of highly oriented structures, quasi-2D metal-organic frameworks and nanocomposites. These fascinating examples reveal how the highly nonlinear electromechanical coupling associated with high-frequency surface vibration gives rise to molecular ordering and assembly on the nano and microscale. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=high-frequency%20acoustics" title="high-frequency acoustics">high-frequency acoustics</a>, <a href="https://publications.waset.org/abstracts/search?q=microfluidics" title=" microfluidics"> microfluidics</a>, <a href="https://publications.waset.org/abstracts/search?q=crystallisation" title=" crystallisation"> crystallisation</a>, <a href="https://publications.waset.org/abstracts/search?q=composite%20nanomaterials" title=" composite nanomaterials"> composite nanomaterials</a> </p> <a href="https://publications.waset.org/abstracts/147372/high-frequency-sonochemistry-a-new-field-of-cavitationfree-acoustic-materials-synthesis-and-manipulation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/147372.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">121</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">2</span> Sonochemically Prepared Non-Noble Metal Oxide Catalysts for Methane Catalytic Combustion</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Przemyslaw%20J.%20Jodlowski">Przemyslaw J. Jodlowski</a>, <a href="https://publications.waset.org/abstracts/search?q=Roman%20J.%20Jedrzejczyk"> Roman J. Jedrzejczyk</a>, <a href="https://publications.waset.org/abstracts/search?q=Damian%20K.%20Chlebda"> Damian K. Chlebda</a>, <a href="https://publications.waset.org/abstracts/search?q=Anna%20Dziedzicka"> Anna Dziedzicka</a>, <a href="https://publications.waset.org/abstracts/search?q=Lukasz%20Kuterasinski"> Lukasz Kuterasinski</a>, <a href="https://publications.waset.org/abstracts/search?q=Anna%20Gancarczyk"> Anna Gancarczyk</a>, <a href="https://publications.waset.org/abstracts/search?q=Maciej%20Sitarz"> Maciej Sitarz</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The aim of this study was to obtain highly active catalysts based on non-noble metal oxides supported on zirconia prepared via a sonochemical method. In this study, the influence of the stabilizers addition during the preparation step was checked. The final catalysts were characterized by using such characterization methods as X-ray Diffraction (XRD), nitrogen adsorption, X-ray fluorescence (XRF), scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectrometer (EDS), transmission electron microscopy (TEM) and 碌Raman. The proposed preparation method allowed to obtain uniformly dispersed metal-oxide nanoparticles at the support鈥檚 surface. The catalytic activity of prepared catalyst samples was measured in a methane combustion reaction. The activity of the catalysts prepared by the sonochemical method was considerably higher than their counterparts prepared by the incipient wetness method. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=methane%20catalytic%20combustion" title="methane catalytic combustion">methane catalytic combustion</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title=" nanoparticles"> nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=non-noble%20metals" title=" non-noble metals"> non-noble metals</a>, <a href="https://publications.waset.org/abstracts/search?q=sonochemistry" title=" sonochemistry"> sonochemistry</a> </p> <a href="https://publications.waset.org/abstracts/83478/sonochemically-prepared-non-noble-metal-oxide-catalysts-for-methane-catalytic-combustion" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/83478.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">217</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">1</span> Biodegradation of Chlorophenol Derivatives Using Macroporous Material</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dmitriy%20Berillo">Dmitriy Berillo</a>, <a href="https://publications.waset.org/abstracts/search?q=Areej%20K.%20A.%20Al-Jwaid"> Areej K. A. Al-Jwaid</a>, <a href="https://publications.waset.org/abstracts/search?q=Jonathan%20L.%20Caplin"> Jonathan L. Caplin</a>, <a href="https://publications.waset.org/abstracts/search?q=Andrew%20Cundy"> Andrew Cundy</a>, <a href="https://publications.waset.org/abstracts/search?q=Irina%20Savina"> Irina Savina</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chlorophenols (CPs) are used as a precursor in the production of higher CPs and dyestuffs, and as a preservative. Contamination by CPs of the ground water is located in the range from 0.15-100mg/L. The EU has set maximum concentration limits for pesticides and their degradation products of 0.1渭g/L and 0.5渭g/L, respectively. People working in industries which produce textiles, leather products, domestic preservatives, and petrochemicals are most heavily exposed to CPs. The International Agency for Research on Cancers categorized CPs as potential human carcinogens. Existing multistep water purification processes for CPs such as hydrogenation, ion exchange, liquid-liquid extraction, adsorption by activated carbon, forward and inverse osmosis, electrolysis, sonochemistry, UV irradiation, and chemical oxidation are not always cost effective and can cause the formation of even more toxic or mutagenic derivatives. Bioremediation of CPs derivatives utilizing microorganisms results in 60 to 100% decontamination efficiency and the process is more environmentally-friendly compared with existing physico-chemical methods. Microorganisms immobilized onto a substrate show many advantages over free bacteria systems, such as higher biomass density, higher metabolic activity, and resistance to toxic chemicals. They also enable continuous operation, avoiding the requirement for biomass-liquid separation. The immobilized bacteria can be reused several times, which opens the opportunity for developing cost-effective processes for wastewater treatment. In this study, we develop a bioremediation system for CPs based on macroporous materials, which can be efficiently used for wastewater treatment. Conditions for the preparation of the macroporous material from specific bacterial strains (Pseudomonas mendocina and Rhodococus koreensis) were optimized. The concentration of bacterial cells was kept constant; the difference was only the type of cross-linking agents used e.g. glutaraldehyde, novel polymers, which were utilized at concentrations of 0.5 to 1.5%. SEM images and rheology analysis of the material indicated a monolithic macroporous structure. Phenol was chosen as a model system to optimize the function of the cryogel material and to estimate its enzymatic activity, since it is relatively less toxic and harmful compared to CPs. Several types of macroporous systems comprising live bacteria were prepared. The viability of the cross-linked bacteria was checked using Live/Dead BacLight kit and Laser Scanning Confocal Microscopy, which revealed the presence of viable bacteria with the novel cross-linkers, whereas the control material cross-linked with glutaraldehyde(GA), contained mostly dead cells. The bioreactors based on bacteria were used for phenol degradation in batch mode at an initial concentration of 50mg/L, pH 7.5 and a temperature of 30掳C. Bacterial strains cross-linked with GA showed insignificant ability to degrade phenol and for one week only, but a combination of cross-linking agents illustrated higher stability, viability and the possibility to be reused for at least five weeks. Furthermore, conditions for CPs degradation will be optimized, and the chlorophenol degradation rates will be compared to those for phenol. This is a cutting-edge bioremediation approach, which allows the purification of waste water from sustainable compounds without a separation step to remove free planktonic bacteria. Acknowledgments: Dr. Berillo D. A. is very grateful to Individual Fellowship Marie Curie Program for funding of the research. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bioremediation" title="bioremediation">bioremediation</a>, <a href="https://publications.waset.org/abstracts/search?q=cross-linking%20agents" title=" cross-linking agents"> cross-linking agents</a>, <a href="https://publications.waset.org/abstracts/search?q=cross-linked%20microbial%20cell" title=" cross-linked microbial cell"> cross-linked microbial cell</a>, <a href="https://publications.waset.org/abstracts/search?q=chlorophenol%20degradation" title=" chlorophenol degradation"> chlorophenol degradation</a> </p> <a href="https://publications.waset.org/abstracts/58858/biodegradation-of-chlorophenol-derivatives-using-macroporous-material" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/58858.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">213</span> </span> </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/WASET-16th-foundational-anniversary.pdf">WASET celebrates its 16th foundational anniversary</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Account <li><a href="https://waset.org/profile">My Account</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Explore <li><a href="https://waset.org/disciplines">Disciplines</a></li> <li><a href="https://waset.org/conferences">Conferences</a></li> <li><a href="https://waset.org/conference-programs">Conference Program</a></li> <li><a href="https://waset.org/committees">Committees</a></li> <li><a href="https://publications.waset.org">Publications</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Research <li><a href="https://publications.waset.org/abstracts">Abstracts</a></li> <li><a href="https://publications.waset.org">Periodicals</a></li> <li><a href="https://publications.waset.org/archive">Archive</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Open Science <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Open-Science-Philosophy.pdf">Open Science Philosophy</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Open-Science-Award.pdf">Open Science Award</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Open-Society-Open-Science-and-Open-Innovation.pdf">Open Innovation</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Postdoctoral-Fellowship-Award.pdf">Postdoctoral Fellowship Award</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Scholarly-Research-Review.pdf">Scholarly Research Review</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Support <li><a href="https://waset.org/page/support">Support</a></li> <li><a href="https://waset.org/profile/messages/create">Contact Us</a></li> <li><a href="https://waset.org/profile/messages/create">Report Abuse</a></li> </ul> </div> </div> </div> </div> </div> <div class="container text-center"> <hr style="margin-top:0;margin-bottom:.3rem;"> <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank" class="text-muted small">Creative Commons Attribution 4.0 International License</a> <div id="copy" class="mt-2">&copy; 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