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자유팽창 - 위키백과, 우리 모두의 백과사전

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[o]" accesskey="o"><span class="vector-icon mw-ui-icon-logIn mw-ui-icon-wikimedia-logIn"></span> <span>로그인</span></a></li> </ul> </div> </div> <div id="p-user-menu-anon-editor" class="vector-menu mw-portlet mw-portlet-user-menu-anon-editor" > <div class="vector-menu-heading"> 로그아웃한 편집자를 위한 문서 <a href="/wiki/%EB%8F%84%EC%9B%80%EB%A7%90:%EC%86%8C%EA%B0%9C" aria-label="편집에 관해 더 알아보기"><span>더 알아보기</span></a> </div> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="pt-anoncontribs" class="mw-list-item"><a href="/wiki/%ED%8A%B9%EC%88%98:%EB%82%B4%EA%B8%B0%EC%97%AC" title="이 IP 주소의 편집 목록 [y]" accesskey="y"><span>기여</span></a></li><li id="pt-anontalk" class="mw-list-item"><a href="/wiki/%ED%8A%B9%EC%88%98:%EB%82%B4%EC%82%AC%EC%9A%A9%EC%9E%90%ED%86%A0%EB%A1%A0" title="현재 사용하는 IP 주소에 대한 토론 문서 [n]" accesskey="n"><span>토론</span></a></li> </ul> </div> </div> </div> </div> </nav> </div> </header> </div> <div class="mw-page-container"> <div class="mw-page-container-inner"> <div class="vector-sitenotice-container"> <div id="siteNotice"><!-- CentralNotice --></div> </div> <div class="vector-column-start"> <div class="vector-main-menu-container"> <div id="mw-navigation"> <nav id="mw-panel" class="vector-main-menu-landmark" aria-label="사이트"> <div id="vector-main-menu-pinned-container" class="vector-pinned-container"> </div> </nav> </div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="목차" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">목차</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">사이드바로 이동</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">숨기기</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">처음 위치</div> </a> </li> <li id="toc-각주" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#각주"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>각주</span> </div> </a> <ul id="toc-각주-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-외부_링크" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#외부_링크"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>외부 링크</span> </div> </a> <ul id="toc-외부_링크-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="목차" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="목차 토글" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">목차 토글</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">자유팽창</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="다른 언어로 문서를 방문합니다. 16개 언어로 읽을 수 있습니다" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-16" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">16개 언어</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%AA%D9%85%D8%AF%D8%AF_%D8%AC%D9%88%D9%84" title="تمدد جول – 아랍어" lang="ar" hreflang="ar" data-title="تمدد جول" data-language-autonym="العربية" data-language-local-name="아랍어" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Expansi%C3%B3_lliure" title="Expansió lliure – 카탈로니아어" lang="ca" hreflang="ca" data-title="Expansió lliure" data-language-autonym="Català" data-language-local-name="카탈로니아어" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-da mw-list-item"><a href="https://da.wikipedia.org/wiki/Joule-ekspansion" title="Joule-ekspansion – 덴마크어" lang="da" hreflang="da" data-title="Joule-ekspansion" data-language-autonym="Dansk" data-language-local-name="덴마크어" class="interlanguage-link-target"><span>Dansk</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Gay-Lussac-Versuch" title="Gay-Lussac-Versuch – 독일어" lang="de" hreflang="de" data-title="Gay-Lussac-Versuch" data-language-autonym="Deutsch" data-language-local-name="독일어" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Joule_expansion" title="Joule expansion – 영어" lang="en" hreflang="en" data-title="Joule expansion" data-language-autonym="English" data-language-local-name="영어" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Expansi%C3%B3n_libre" title="Expansión libre – 스페인어" lang="es" hreflang="es" data-title="Expansión libre" data-language-autonym="Español" data-language-local-name="스페인어" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/D%C3%A9tente_de_Joule-Gay-Lussac" title="Détente de Joule-Gay-Lussac – 프랑스어" lang="fr" hreflang="fr" data-title="Détente de Joule-Gay-Lussac" data-language-autonym="Français" data-language-local-name="프랑스어" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-he mw-list-item"><a href="https://he.wikipedia.org/wiki/%D7%94%D7%AA%D7%A4%D7%A9%D7%98%D7%95%D7%AA_%D7%92%27%D7%90%D7%95%D7%9C" title="התפשטות ג&#039;אול – 히브리어" lang="he" hreflang="he" data-title="התפשטות ג&#039;אול" data-language-autonym="עברית" data-language-local-name="히브리어" class="interlanguage-link-target"><span>עברית</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Espansione_di_Joule" title="Espansione di Joule – 이탈리아어" lang="it" hreflang="it" data-title="Espansione di Joule" data-language-autonym="Italiano" data-language-local-name="이탈리아어" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-no mw-list-item"><a href="https://no.wikipedia.org/wiki/Joule-ekspansjon" title="Joule-ekspansjon – 노르웨이어(보크말)" lang="nb" hreflang="nb" data-title="Joule-ekspansjon" data-language-autonym="Norsk bokmål" data-language-local-name="노르웨이어(보크말)" class="interlanguage-link-target"><span>Norsk bokmål</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Expans%C3%A3o_livre" title="Expansão livre – 포르투갈어" lang="pt" hreflang="pt" data-title="Expansão livre" data-language-autonym="Português" data-language-local-name="포르투갈어" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Destindere_Joule" title="Destindere Joule – 루마니아어" lang="ro" hreflang="ro" data-title="Destindere Joule" data-language-autonym="Română" data-language-local-name="루마니아어" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Joule_geni%C5%9Flemesi" title="Joule genişlemesi – 터키어" lang="tr" hreflang="tr" data-title="Joule genişlemesi" data-language-autonym="Türkçe" data-language-local-name="터키어" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Gi%C3%A3n_n%E1%BB%9F_t%E1%BB%B1_do" title="Giãn nở tự do – 베트남어" lang="vi" hreflang="vi" data-title="Giãn nở tự do" data-language-autonym="Tiếng Việt" data-language-local-name="베트남어" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E8%87%AA%E7%94%B1%E8%86%A8%E8%84%B9" title="自由膨脹 – 중국어" lang="zh" hreflang="zh" data-title="自由膨脹" data-language-autonym="中文" data-language-local-name="중국어" class="interlanguage-link-target"><span>中文</span></a></li><li class="interlanguage-link interwiki-zh-yue mw-list-item"><a href="https://zh-yue.wikipedia.org/wiki/%E8%87%AA%E7%94%B1%E6%93%B4%E6%95%A3" title="自由擴散 – 광둥어" lang="yue" hreflang="yue" data-title="自由擴散" data-language-autonym="粵語" data-language-local-name="광둥어" class="interlanguage-link-target"><span>粵語</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q1109469#sitelinks-wikipedia" title="언어 간 링크 편집" class="wbc-editpage">링크 편집</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav aria-label="이름공간"> <div id="p-associated-pages" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-associated-pages" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-nstab-main" class="selected vector-tab-noicon mw-list-item"><a href="/wiki/%EC%9E%90%EC%9C%A0%ED%8C%BD%EC%B0%BD" title="본문 보기 [c]" accesskey="c"><span>문서</span></a></li><li id="ca-talk" class="vector-tab-noicon mw-list-item"><a href="/wiki/%ED%86%A0%EB%A1%A0:%EC%9E%90%EC%9C%A0%ED%8C%BD%EC%B0%BD" rel="discussion" title="문서의 내용에 대한 토론 문서 [t]" accesskey="t"><span>토론</span></a></li> </ul> </div> </div> <div id="vector-variants-dropdown" class="vector-dropdown emptyPortlet" > <input type="checkbox" id="vector-variants-dropdown-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-variants-dropdown" class="vector-dropdown-checkbox " aria-label="언어 변종 바꾸기" > <label id="vector-variants-dropdown-label" for="vector-variants-dropdown-checkbox" 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href="mw-data:TemplateStyles:r36480595"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r34311371"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r34311371"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r36480595"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r34311371"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r34311371"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r36480591"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r34311371"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r36480591"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r34311371"><table class="sidebar sidebar-collapse nomobile nowraplinks plainlist"><tbody><tr><th class="sidebar-title"><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99" title="열역학">열역학</a></th></tr><tr><td class="sidebar-image"><span typeof="mw:File"><a href="/wiki/%EC%B9%B4%EB%A5%B4%EB%85%B8_%EA%B8%B0%EA%B4%80" title="카르노 기관"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/2/22/Carnot_heat_engine_2.svg/220px-Carnot_heat_engine_2.svg.png" decoding="async" width="220" height="97" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/2/22/Carnot_heat_engine_2.svg/330px-Carnot_heat_engine_2.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/2/22/Carnot_heat_engine_2.svg/440px-Carnot_heat_engine_2.svg.png 2x" data-file-width="840" data-file-height="370" /></a></span><div class="sidebar-caption" style="padding:0.5em 0.2em 0.6em;border-bottom:1px solid #aaa; display:block;margin-bottom:0.1em;">고전적 <a href="/wiki/%EC%B9%B4%EB%A5%B4%EB%85%B8_%EA%B8%B0%EA%B4%80" title="카르노 기관">카르노 기관</a></div></td></tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;">분과</div><div class="sidebar-list-content mw-collapsible-content hlist"> <ul><li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99" title="열역학">고전열역학</a></li> <li><a href="/wiki/%ED%86%B5%EA%B3%84%EC%97%AD%ED%95%99" title="통계역학">통계역학</a></li> <li><a href="/wiki/%ED%99%94%ED%95%99%EC%97%B4%EC%97%AD%ED%95%99" title="화학열역학">화학열역학</a></li> <li><a href="/wiki/%ED%8F%89%ED%98%95%EC%97%B4%EC%97%AD%ED%95%99" title="평형열역학">평형열역학</a>/<a href="/wiki/%EB%B9%84%ED%8F%89%ED%98%95%EC%97%B4%EC%97%AD%ED%95%99" title="비평형열역학">비평형열역학</a></li></ul></div></div></td> </tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;">법칙</div><div class="sidebar-list-content mw-collapsible-content hlist"> <ul><li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99_%EC%A0%9C0%EB%B2%95%EC%B9%99" title="열역학 제0법칙">열역학 제0법칙</a></li> <li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99_%EC%A0%9C1%EB%B2%95%EC%B9%99" title="열역학 제1법칙">열역학 제1법칙</a></li> <li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99_%EC%A0%9C2%EB%B2%95%EC%B9%99" title="열역학 제2법칙">열역학 제2법칙</a></li> <li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99_%EC%A0%9C3%EB%B2%95%EC%B9%99" title="열역학 제3법칙">열역학 제3법칙</a></li></ul></div></div></td> </tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;"><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99_%EA%B3%84" class="mw-redirect" title="열역학 계">계</a></div><div class="sidebar-list-content mw-collapsible-content hlist"><table class="sidebar nomobile nowraplinks" style="border-collapse:collapse; border-spacing:0px; border:none; width:100%; margin:0px; font-size:100%; clear:none; float:none"><tbody><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> <a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%EC%83%81%ED%83%9C" title="열역학적 상태">상태</a></th></tr><tr><td class="sidebar-content hlist"> <ul><li><a href="/wiki/%EC%83%81%ED%83%9C%EB%B0%A9%EC%A0%95%EC%8B%9D" class="mw-redirect" title="상태방정식">상태방정식</a></li> <li><a href="/wiki/%EC%9D%B4%EC%83%81%EA%B8%B0%EC%B2%B4" title="이상기체">이상기체</a></li> <li><a href="/wiki/%EC%8B%A4%EC%A0%9C_%EA%B8%B0%EC%B2%B4" title="실제 기체">실제 기체</a></li> <li><a href="/wiki/%EB%AC%BC%EC%A7%88%EC%9D%98_%EC%83%81%ED%83%9C" title="물질의 상태">물질의 상태</a></li> <li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%ED%8F%89%ED%98%95" title="열역학적 평형">열역학적 평형</a></li> <li><a href="/w/index.php?title=%EA%B3%B5%EC%A0%9C%EB%B6%80%ED%94%BC&amp;action=edit&amp;redlink=1" class="new" title="공제부피 (없는 문서)">공제부피</a></li></ul></td> </tr><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> <a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99_%EA%B3%BC%EC%A0%95" title="열역학 과정">과정</a></th></tr><tr><td class="sidebar-content hlist"> <ul><li><a href="/wiki/%EB%93%B1%EC%95%95%EA%B3%BC%EC%A0%95" title="등압과정">등압과정</a></li> <li><a href="/wiki/%EB%93%B1%EC%A0%81%EA%B3%BC%EC%A0%95" title="등적과정">등적과정</a></li> <li><a href="/wiki/%EB%93%B1%EC%98%A8%EA%B3%BC%EC%A0%95" title="등온과정">등온과정</a></li> <li><a href="/wiki/%EB%8B%A8%EC%97%B4%EA%B3%BC%EC%A0%95" title="단열과정">단열과정</a></li> <li><a href="/wiki/%EB%93%B1%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC_%EA%B3%BC%EC%A0%95" title="등엔트로피 과정">등엔트로피 과정</a></li> <li><a href="/wiki/%EB%93%B1%EC%97%94%ED%83%88%ED%94%BC_%EA%B3%BC%EC%A0%95" title="등엔탈피 과정">등엔탈피 과정</a></li> <li><a href="/w/index.php?title=%EC%A4%80%EC%A0%95%EC%A0%81%EA%B3%BC%EC%A0%95&amp;action=edit&amp;redlink=1" class="new" title="준정적과정 (없는 문서)">준정적과정</a></li> <li><a href="/wiki/%EB%8B%A4%EB%B0%A9%EA%B3%BC%EC%A0%95" title="다방과정">다방과정</a></li> <li><a class="mw-selflink selflink">자유팽창</a></li> <li><a href="/wiki/%EA%B0%80%EC%97%AD%EA%B3%BC%EC%A0%95" title="가역과정">가역과정</a></li> <li><a href="/wiki/%EB%B9%84%EA%B0%80%EC%97%AD%EA%B3%BC%EC%A0%95" title="비가역과정">비가역과정</a></li> <li><a href="/w/index.php?title=%EB%82%B4%EC%A0%81%EA%B0%80%EC%97%AD_%EC%97%B4%EC%97%AD%ED%95%99&amp;action=edit&amp;redlink=1" class="new" title="내적가역 열역학 (없는 문서)">내적가역성</a></li></ul></td> </tr><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> <a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99_%EC%82%AC%EC%9D%B4%ED%81%B4" title="열역학 사이클">순환</a></th></tr><tr><td class="sidebar-content hlist"> <ul><li><a href="/wiki/%EC%97%B4%EA%B8%B0%EA%B4%80" title="열기관">열기관</a></li> <li><a href="/w/index.php?title=%EB%83%89%EB%82%9C%EB%B0%A9_%EC%88%9C%ED%99%98&amp;action=edit&amp;redlink=1" class="new" title="냉난방 순환 (없는 문서)">냉난방 순환</a></li> <li><a href="/wiki/%EC%97%B4%ED%9A%A8%EC%9C%A8" title="열효율">열효율</a></li></ul></td> </tr></tbody></table></div></div></td> </tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;"><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%EC%84%B1%EC%A7%88" title="열역학적 성질">계의 성질</a></div><div class="sidebar-list-content mw-collapsible-content hlist"><div style="font-size:90%;padding-bottom:0.2em;border-bottom:1px solid #aaa;">비고: <i>기울임꼴</i>로 된 것들은 <a href="/w/index.php?title=%EA%B3%B5%EC%95%A1%EB%B3%80%EC%88%98&amp;action=edit&amp;redlink=1" class="new" title="공액변수 (없는 문서)">공액변수</a>이다.</div> <table class="sidebar nomobile nowraplinks" style="border-collapse:collapse; border-spacing:0px; border:none; width:100%; margin:0px; font-size:100%; clear:none; float:none;margin-top:0.4em;"><tbody><tr><td class="sidebar-content" style="padding-bottom:0.7em;"> <ul><li><a href="/w/index.php?title=%EC%97%B4%EC%97%AD%ED%95%99%EB%8F%84&amp;action=edit&amp;redlink=1" class="new" title="열역학도 (없는 문서)">열역학도</a></li> <li><a href="/wiki/%EC%84%B8%EA%B8%B0_%EC%84%B1%EC%A7%88%EA%B3%BC_%ED%81%AC%EA%B8%B0_%EC%84%B1%EC%A7%88" title="세기 성질과 크기 성질">세기 성질과 크기 성질</a></li></ul></td> </tr><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> <a href="/wiki/%EC%83%81%ED%83%9C%ED%95%A8%EC%88%98" class="mw-redirect" title="상태함수">상태함수</a></th></tr><tr><td class="sidebar-content" style="padding-bottom:0.7em;"> <ul><li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%EC%98%A8%EB%8F%84" class="mw-redirect" title="열역학적 온도">온도</a> &#160;/ <i><a href="/wiki/%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC" title="엔트로피">엔트로피</a></i>&#160;(<a href="/w/index.php?title=%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC_%EA%B0%9C%EB%A1%A0&amp;action=edit&amp;redlink=1" class="new" title="엔트로피 개론 (없는 문서)">개론</a>)</li> <li><a href="/wiki/%EC%95%95%EB%A0%A5" title="압력">압력</a>&#160;/ <i><a href="/w/index.php?title=%EB%B6%80%ED%94%BC_(%EC%97%B4%EC%97%AD%ED%95%99)&amp;action=edit&amp;redlink=1" class="new" title="부피 (열역학) (없는 문서)">부피</a></i></li> <li><a href="/w/index.php?title=%ED%99%94%ED%95%99%EC%A0%81_%ED%8D%BC%ED%85%90%EC%85%9C&amp;action=edit&amp;redlink=1" class="new" title="화학적 퍼텐셜 (없는 문서)">화학적 퍼텐셜</a>&#160;/ <i><a href="/wiki/%EC%9E%85%EC%9E%90%EC%88%98" class="mw-redirect" title="입자수">입자수</a></i></li> <li><a href="/w/index.php?title=%EC%A6%9D%EA%B8%B0%EB%9F%89&amp;action=edit&amp;redlink=1" class="new" title="증기량 (없는 문서)">증기량</a></li> <li><a href="/w/index.php?title=%EB%8C%80%EB%B9%84%EC%84%B1%EC%A7%88&amp;action=edit&amp;redlink=1" class="new" title="대비성질 (없는 문서)">대비성질</a></li></ul></td> </tr><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> <a href="/wiki/%EA%B2%BD%EB%A1%9C_%ED%95%A8%EC%88%98" title="경로 함수">과정함수</a></th></tr><tr><td class="sidebar-content" style="padding-bottom:0.7em;;padding-bottom:0.4em;"> <ul><li><a href="/wiki/%EC%9D%BC_(%EB%AC%BC%EB%A6%AC%ED%95%99)" title="일 (물리학)">일</a></li> <li><a href="/wiki/%EC%97%B4" title="열">열</a></li></ul></td> </tr></tbody></table></div></div></td> </tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;"><a href="/w/index.php?title=%EB%AC%BC%EC%84%B1_(%EC%97%B4%EC%97%AD%ED%95%99)&amp;action=edit&amp;redlink=1" class="new" title="물성 (열역학) (없는 문서)">물성</a></div><div class="sidebar-list-content mw-collapsible-content hlist"> <ul><li><a href="/w/index.php?title=%EC%88%9C%EC%88%98_%EB%AC%BC%EC%A7%88%EC%9D%98_%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%EB%8D%B0%EC%9D%B4%ED%84%B0%EB%B2%A0%EC%9D%B4%EC%8A%A4&amp;action=edit&amp;redlink=1" class="new" title="순수 물질의 열역학적 데이터베이스 (없는 문서)">순수 물질의 열역학적 데이터베이스</a></li></ul> <div style="font-size:90%;margin-top:0.4em;border-top:1px solid #aaa;text-align:center;"><table> <tbody><tr><td style="vertical-align:middle; text-align:right"><a href="/wiki/%EC%97%B4%EC%9A%A9%EB%9F%89" title="열용량">비열용량</a>&#160;</td> <td style="vertical-align:middle; text-align:left"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle c=}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>c</mi> <mo>=</mo> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle c=}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/891d40a9b18752b04065caee655d008b3ec11428" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:3.46ex; height:1.676ex;" alt="{\displaystyle c=}"></span></td> <td><table><tbody><tr><td><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle T}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>T</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle T}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/ec7200acd984a1d3a3d7dc455e262fbe54f7f6e0" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:1.636ex; height:2.176ex;" alt="{\displaystyle T}"></span></td><td><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \partial S}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x2202;<!-- ∂ --></mi> <mi>S</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \partial S}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/c609f4d3c5692ea4495479ef47594dc67f9fa464" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:2.817ex; height:2.176ex;" alt="{\displaystyle \partial S}"></span></td></tr><tr><td style="border-top:solid 1px black;"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle N}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>N</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle N}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/f5e3890c981ae85503089652feb48b191b57aae3" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:2.064ex; height:2.176ex;" alt="{\displaystyle N}"></span></td><td style="border-top:solid 1px black;"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \partial T}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x2202;<!-- ∂ --></mi> <mi>T</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \partial T}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/504aa558fff3d00d10b03cadb1085cb0b7bdc631" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:2.954ex; height:2.176ex;" alt="{\displaystyle \partial T}"></span></td></tr></tbody></table></td></tr> <tr><td style="vertical-align:middle; text-align:right"><a href="/wiki/%EC%95%95%EC%B6%95%EB%A5%A0" title="압축률">압축률</a>&#160;</td> <td style="vertical-align:middle; text-align:left"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \beta =-}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>&#x03B2;<!-- β --></mi> <mo>=</mo> <mo>&#x2212;<!-- − --></mo> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \beta =-}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/b01c042bf1456bd4d2a8caed1f4912820a7ecbb3" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:6.239ex; height:2.509ex;" alt="{\displaystyle \beta =-}"></span></td> <td><table><tbody><tr><td><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle 1}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mn>1</mn> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle 1}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/92d98b82a3778f043108d4e20960a9193df57cbf" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:1.162ex; height:2.176ex;" alt="{\displaystyle 1}"></span></td><td><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \partial V}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x2202;<!-- ∂ --></mi> <mi>V</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \partial V}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/0cecdd9d069fa84159940068fc11a91b6b3b9ee4" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:3.105ex; height:2.176ex;" alt="{\displaystyle \partial V}"></span></td></tr><tr><td style="border-top:solid 1px black;"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle V}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>V</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle V}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/af0f6064540e84211d0ffe4dac72098adfa52845" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:1.787ex; height:2.176ex;" alt="{\displaystyle V}"></span></td><td style="border-top:solid 1px black;"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \partial p}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x2202;<!-- ∂ --></mi> <mi>p</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \partial p}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/ebc4a48eb2412f08b54fe438b5139c88f9cfa372" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:2.487ex; height:2.509ex;" alt="{\displaystyle \partial p}"></span></td></tr></tbody></table></td></tr> <tr><td style="vertical-align:middle; text-align:right"><a href="/wiki/%EC%97%B4%ED%8C%BD%EC%B0%BD" title="열팽창">열팽창</a>&#160;</td> <td style="vertical-align:middle; text-align:left"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \alpha =}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>&#x03B1;<!-- α --></mi> <mo>=</mo> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \alpha =}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/a92d4583d351f08c1c70985f0c843b2fff1b01e7" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:3.941ex; height:1.676ex;" alt="{\displaystyle \alpha =}"></span></td> <td><table><tbody><tr><td><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle 1}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mn>1</mn> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle 1}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/92d98b82a3778f043108d4e20960a9193df57cbf" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:1.162ex; height:2.176ex;" alt="{\displaystyle 1}"></span></td><td><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \partial V}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x2202;<!-- ∂ --></mi> <mi>V</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \partial V}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/0cecdd9d069fa84159940068fc11a91b6b3b9ee4" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:3.105ex; height:2.176ex;" alt="{\displaystyle \partial V}"></span></td></tr><tr><td style="border-top:solid 1px black;"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle V}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>V</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle V}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/af0f6064540e84211d0ffe4dac72098adfa52845" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:1.787ex; height:2.176ex;" alt="{\displaystyle V}"></span></td><td style="border-top:solid 1px black;"><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \partial T}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x2202;<!-- ∂ --></mi> <mi>T</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \partial T}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/504aa558fff3d00d10b03cadb1085cb0b7bdc631" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:2.954ex; height:2.176ex;" alt="{\displaystyle \partial T}"></span></td></tr></tbody></table></td></tr> </tbody></table></div></div></div></td> </tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;"><a href="/w/index.php?title=%EC%97%B4%EC%97%AD%ED%95%99_%EB%B0%A9%EC%A0%95%EC%8B%9D&amp;action=edit&amp;redlink=1" class="new" title="열역학 방정식 (없는 문서)">방정식</a></div><div class="sidebar-list-content mw-collapsible-content hlist"> <ul><li><a href="/w/index.php?title=%EC%B9%B4%EB%A5%B4%EB%85%B8_%EC%A0%95%EB%A6%AC_(%EC%97%B4%EC%97%AD%ED%95%99)&amp;action=edit&amp;redlink=1" class="new" title="카르노 정리 (열역학) (없는 문서)">카르노 정리</a></li> <li><a href="/w/index.php?title=%ED%81%B4%EB%9D%BC%EC%9A%B0%EC%A7%80%EC%9A%B0%EC%8A%A4_%EC%A0%95%EB%A6%AC&amp;action=edit&amp;redlink=1" class="new" title="클라우지우스 정리 (없는 문서)">클라우지우스 정리</a></li> <li><a href="/w/index.php?title=%EC%97%B4%EC%97%AD%ED%95%99_%EA%B8%B0%EB%B3%B8%EA%B4%80%EA%B3%84&amp;action=edit&amp;redlink=1" class="new" title="열역학 기본관계 (없는 문서)">열역학 기본관계</a></li> <li><a href="/wiki/%EC%9D%B4%EC%83%81%EA%B8%B0%EC%B2%B4_%EB%B2%95%EC%B9%99" title="이상기체 법칙">이상기체 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href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%ED%8D%BC%ED%85%90%EC%85%9C" class="mw-redirect" title="열역학적 퍼텐셜">퍼텐셜</a></div><div class="sidebar-list-content mw-collapsible-content hlist"> <ul><li><a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%EC%9E%90%EC%9C%A0_%EC%97%90%EB%84%88%EC%A7%80" title="열역학적 자유 에너지">자유 에너지</a></li> <li><a href="/w/index.php?title=%EC%9E%90%EC%9C%A0_%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC&amp;action=edit&amp;redlink=1" class="new" title="자유 엔트로피 (없는 문서)">자유 엔트로피</a></li></ul> <hr /> <div class="plainlist"><ul><li style="font-size:105%;line-height:1.6em;padding-bottom:0.5em;"><a href="/wiki/%EB%82%B4%EB%B6%80_%EC%97%90%EB%84%88%EC%A7%80" title="내부 에너지">내부 에너지</a><br /><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle U(S,V)}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>U</mi> <mo stretchy="false">(</mo> <mi>S</mi> <mo>,</mo> <mi>V</mi> <mo stretchy="false">)</mo> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle U(S,V)}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/921f33f9c6551562ec836007b035c2de6323d2d6" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:7.912ex; height:2.843ex;" alt="{\displaystyle U(S,V)}"></span><br /></li><li style="font-size:105%;line-height:1.6em;padding-bottom:0.5em;"><a href="/wiki/%EC%97%94%ED%83%88%ED%94%BC" title="엔탈피">엔탈피</a><br /><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle H(S,p)=U+pV}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>H</mi> <mo stretchy="false">(</mo> <mi>S</mi> <mo>,</mo> <mi>p</mi> <mo stretchy="false">)</mo> <mo>=</mo> <mi>U</mi> <mo>+</mo> <mi>p</mi> <mi>V</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle H(S,p)=U+pV}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/6407d78e5f39d07f70e2414a92e08e2e068519f3" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:18.254ex; height:2.843ex;" alt="{\displaystyle H(S,p)=U+pV}"></span><br /></li><li style="font-size:105%;line-height:1.6em;padding-bottom:0.5em;"><a href="/wiki/%ED%97%AC%EB%A6%84%ED%99%80%EC%B8%A0_%EC%9E%90%EC%9C%A0_%EC%97%90%EB%84%88%EC%A7%80" title="헬름홀츠 자유 에너지">헬름홀츠 자유 에너지</a><br /><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle A(T,V)=U-TS}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>A</mi> <mo stretchy="false">(</mo> <mi>T</mi> <mo>,</mo> <mi>V</mi> <mo stretchy="false">)</mo> <mo>=</mo> <mi>U</mi> <mo>&#x2212;<!-- − --></mo> <mi>T</mi> <mi>S</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle A(T,V)=U-TS}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/5e93692f031ba6484d82731c54db83a69daed3f0" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:18.867ex; height:2.843ex;" alt="{\displaystyle A(T,V)=U-TS}"></span><br /></li><li style="font-size:105%;line-height:1.6em;padding-bottom:0.5em;"><a href="/wiki/%EA%B9%81%EC%8A%A4_%EC%9E%90%EC%9C%A0_%EC%97%90%EB%84%88%EC%A7%80" title="깁스 자유 에너지">깁스 자유 에너지</a><br /><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle G(T,p)=H-TS}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>G</mi> <mo stretchy="false">(</mo> <mi>T</mi> <mo>,</mo> <mi>p</mi> <mo stretchy="false">)</mo> <mo>=</mo> <mi>H</mi> <mo>&#x2212;<!-- − --></mo> <mi>T</mi> <mi>S</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle G(T,p)=H-TS}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/8dd7a8f0b8ae04963da133e3b202432e1b6caed4" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:18.614ex; height:2.843ex;" alt="{\displaystyle G(T,p)=H-TS}"></span></li></ul></div></div></div></td> </tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;">역사</div><div class="sidebar-list-content mw-collapsible-content hlist"><table class="sidebar nomobile nowraplinks" style="border-collapse:collapse; border-spacing:0px; border:none; width:100%; margin:0px; font-size:100%; clear:none; float:none"><tbody><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> 열역학사</th></tr><tr><td class="sidebar-content"> <ul><li><a href="/w/index.php?title=%EC%97%B4%EC%97%AD%ED%95%99%EC%82%AC&amp;action=edit&amp;redlink=1" class="new" title="열역학사 (없는 문서)">개괄</a></li> <li><a href="/w/index.php?title=%EC%97%B4_%EA%B0%9C%EB%85%90%EC%9D%98_%EC%97%AD%EC%82%AC&amp;action=edit&amp;redlink=1" class="new" title="열 개념의 역사 (없는 문서)">열 개념의 역사</a></li> <li><a href="/w/index.php?title=%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC%EC%9D%98_%EC%97%AD%EC%82%AC&amp;action=edit&amp;redlink=1" class="new" title="엔트로피의 역사 (없는 문서)">엔트로피의 역사</a></li> <li><a href="/wiki/%EA%B8%B0%EC%B2%B4_%EB%B2%95%EC%B9%99" title="기체 법칙">기체 법칙</a></li> <li><a href="/w/index.php?title=%EC%98%81%EA%B5%AC%EA%B8%B0%EA%B4%80%EC%9D%98_%EC%97%AD%EC%82%AC&amp;action=edit&amp;redlink=1" class="new" title="영구기관의 역사 (없는 문서)">영구기관의 역사</a></li></ul></td> </tr><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> <a href="/w/index.php?title=%ED%86%B5%EA%B3%84%EC%97%B4%EC%97%AD%ED%95%99%EC%B2%A0%ED%95%99&amp;action=edit&amp;redlink=1" class="new" title="통계열역학철학 (없는 문서)">과학철학</a></th></tr><tr><td class="sidebar-content"> <ul><li><a href="/w/index.php?title=%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC_(%EC%8B%9C%EA%B0%84%EC%9D%98_%ED%99%94%EC%82%B4)&amp;action=edit&amp;redlink=1" class="new" title="엔트로피 (시간의 화살) (없는 문서)">엔트로피와 시간</a></li> <li><a href="/w/index.php?title=%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC%EC%99%80_%EC%83%9D%EB%AA%85&amp;action=edit&amp;redlink=1" class="new" title="엔트로피와 생명 (없는 문서)">엔트로피와 생명</a></li> <li><a href="/w/index.php?title=%EB%B8%8C%EB%9D%BC%EC%9A%B4_%EB%9E%98%EC%B9%AB&amp;action=edit&amp;redlink=1" class="new" 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href="/w/index.php?title=%EB%B6%88%EA%B7%A0%EC%9D%BC_%EB%AC%BC%EC%A7%88%EC%9D%98_%ED%8F%89%ED%98%95%EC%97%90_%EB%8C%80%ED%95%98%EC%97%AC&amp;action=edit&amp;redlink=1" class="new" title="불균일 물질의 평형에 대하여 (없는 문서)">불균일 물질의<br />평형에 대하여</a></li> <li><a href="/w/index.php?title=%EB%B6%88%EC%9D%98_%EC%9B%90%EB%8F%99%EB%A0%A5%EC%97%90_%EA%B4%80%ED%95%9C_%EA%B3%A0%EC%B0%B0&amp;action=edit&amp;redlink=1" class="new" title="불의 원동력에 관한 고찰 (없는 문서)">불의 원동력에 <br /> 관한 고찰</a></li></ul></td> </tr><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> 연표</th></tr><tr><td class="sidebar-content"> <ul><li><a href="/w/index.php?title=%EC%97%B4%EC%97%AD%ED%95%99%EC%82%AC_%EC%97%B0%ED%91%9C&amp;action=edit&amp;redlink=1" class="new" title="열역학사 연표 (없는 문서)">열역학사 연표</a></li> <li><a href="/w/index.php?title=%EC%97%B4%EA%B8%B0%EA%B4%80_%EA%B0%9C%EB%B0%9C%EC%82%AC_%EC%97%B0%ED%91%9C&amp;action=edit&amp;redlink=1" class="new" title="열기관 개발사 연표 (없는 문서)">열기관 개발사 연표</a></li></ul></td> </tr><tr><th class="sidebar-heading" style="background:#eaeaff;font-style:italic;"> 교육</th></tr><tr><td class="sidebar-content"> <ul><li><a href="/w/index.php?title=%EB%A7%A5%EC%8A%A4%EC%9B%B0%EC%9D%98_%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%ED%91%9C%EB%A9%B4&amp;action=edit&amp;redlink=1" class="new" title="맥스웰의 열역학적 표면 (없는 문서)">맥스웰의 열역학적 표면</a></li> <li><a href="/w/index.php?title=%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC_(%EC%97%90%EB%84%88%EC%A7%80_%EB%B6%84%EC%82%B0)&amp;action=edit&amp;redlink=1" class="new" title="엔트로피 (에너지 분산) (없는 문서)">에너지 분산으로서의 엔트로피</a></li></ul></td> </tr></tbody></table></div></div></td> </tr><tr><td class="sidebar-content"> <div class="sidebar-list mw-collapsible mw-collapsed"><div class="sidebar-list-title" style="background:#ddf;text-align:center;">과학자</div><div class="sidebar-list-content mw-collapsible-content hlist"> <ul><li><a href="/wiki/%EB%8B%A4%EB%8B%88%EC%97%98_%EB%B2%A0%EB%A5%B4%EB%88%84%EC%9D%B4" title="다니엘 베르누이">베르누이</a></li> <li><a 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title="윌리엄 존 맥쿼른 랭킨 (없는 문서)">랭킨</a></li> <li><a href="/w/index.php?title=%EC%A1%B4_%EC%8A%A4%EB%AF%B8%ED%8A%BC&amp;action=edit&amp;redlink=1" class="new" title="존 스미튼 (없는 문서)">스미튼</a></li> <li><a href="/wiki/%EA%B2%8C%EC%98%A4%EB%A5%B4%ED%81%AC_%EC%97%90%EB%A5%B8%EC%8A%A4%ED%8A%B8_%EC%8A%88%ED%83%88" title="게오르크 에른스트 슈탈">슈탈</a></li> <li><a href="/wiki/%EB%B2%A4%EC%A0%80%EB%AF%BC_%ED%86%B0%EC%8A%A8" class="mw-redirect" title="벤저민 톰슨">톰슨</a></li> <li><a href="/wiki/%EC%A0%9C1%EB%8C%80_%EC%BC%88%EB%B9%88_%EB%82%A8%EC%9E%91_%EC%9C%8C%EB%A6%AC%EC%97%84_%ED%86%B0%EC%8A%A8" title="제1대 켈빈 남작 윌리엄 톰슨">켈빈 남작</a></li> <li><a href="/w/index.php?title=%EC%A1%B4_%EC%A0%9C%EC%9E%84%EC%8A%A4_%EC%9B%8C%ED%84%B0%EC%8A%A8&amp;action=edit&amp;redlink=1" class="new" title="존 제임스 워터슨 (없는 문서)">워터슨</a></li></ul></div></div></td> </tr><tr><td class="sidebar-below" style="display:block;margin-top:0.4em; line-height:1.6em;padding-bottom:0.5em;"> <span typeof="mw:File"><span title="분류"><img alt="분류" src="//upload.wikimedia.org/wikipedia/commons/thumb/4/48/Folder_Hexagonal_Icon.svg/16px-Folder_Hexagonal_Icon.svg.png" decoding="async" width="16" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/48/Folder_Hexagonal_Icon.svg/24px-Folder_Hexagonal_Icon.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/48/Folder_Hexagonal_Icon.svg/32px-Folder_Hexagonal_Icon.svg.png 2x" data-file-width="36" data-file-height="31" /></span></span>&#160;<a href="/wiki/%EB%B6%84%EB%A5%98:%EC%97%B4%EC%97%AD%ED%95%99" title="분류:열역학">분류: 열역학</a></td></tr><tr><td class="sidebar-navbar"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r36480591"><style data-mw-deduplicate="TemplateStyles:r34311309">.mw-parser-output .navbar{display:inline;font-size:88%;font-weight:normal}.mw-parser-output .navbar-collapse{float:left;text-align:left}.mw-parser-output .navbar-boxtext{word-spacing:0}.mw-parser-output .navbar ul{display:inline-block;white-space:nowrap;line-height:inherit}.mw-parser-output .navbar-brackets::before{margin-right:-0.125em;content:"[ "}.mw-parser-output .navbar-brackets::after{margin-left:-0.125em;content:" ]"}.mw-parser-output .navbar li{word-spacing:-0.125em}.mw-parser-output .navbar a>span,.mw-parser-output .navbar a>abbr{text-decoration:inherit}.mw-parser-output .navbar-mini abbr{font-variant:small-caps;border-bottom:none;text-decoration:none;cursor:inherit}.mw-parser-output .navbar-ct-full{font-size:114%;margin:0 7em}.mw-parser-output .navbar-ct-mini{font-size:114%;margin:0 4em}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-보기"><a href="/wiki/%ED%8B%80:%EC%97%B4%EC%97%AD%ED%95%99" title="틀:열역학"><abbr title="이 틀을 보기">v</abbr></a></li><li class="nv-토론"><a href="/w/index.php?title=%ED%8B%80%ED%86%A0%EB%A1%A0:%EC%97%B4%EC%97%AD%ED%95%99&amp;action=edit&amp;redlink=1" class="new" title="틀토론:열역학 (없는 문서)"><abbr title="이 틀에 관해 토론하기">t</abbr></a></li><li class="nv-편집"><a href="/wiki/%ED%8A%B9%EC%88%98:%EB%AC%B8%EC%84%9C%ED%8E%B8%EC%A7%91/%ED%8B%80:%EC%97%B4%EC%97%AD%ED%95%99" title="특수:문서편집/틀:열역학"><abbr title="이 틀을 편집하기">e</abbr></a></li></ul></div></td></tr></tbody></table> <p><b>자유팽창</b>(自由膨脹, free expansion)은 단열된 진공 공간으로 저절로 팽창하는 <a href="/wiki/%EB%B9%84%EA%B0%80%EC%97%AD%EA%B3%BC%EC%A0%95" title="비가역과정">비가역과정</a>이다. <a href="/w/index.php?title=%EC%A4%84_%ED%8C%BD%EC%B0%BD&amp;action=edit&amp;redlink=1" class="new" title="줄 팽창 (없는 문서)">줄 팽창</a>이라고도 한다. </p><p>실제 기체는 자유팽창을 하는 도중에도 온도 변화가 생긴다. <a href="/wiki/%EC%9D%B4%EC%83%81%EA%B8%B0%EC%B2%B4" title="이상기체">이상기체</a>에서는 온도가 변하지 않는다고 가정하며, 단열자유팽창은 </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle P_{i}V_{i}=P_{f}V_{f}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <msub> <mi>P</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> </msub> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> </msub> <mo>=</mo> <msub> <mi>P</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msub> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msub> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle P_{i}V_{i}=P_{f}V_{f}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/33852088656c5a9c1bade6f1efe74f3577bc677d" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.005ex; width:12.666ex; height:2.843ex;" alt="{\displaystyle P_{i}V_{i}=P_{f}V_{f}}"></span></dd></dl> <p>를 만족한다. 이때 <span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle P}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>P</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle P}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/b4dc73bf40314945ff376bd363916a738548d40a" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:1.745ex; height:2.176ex;" alt="{\displaystyle P}"></span>는 압력, <span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle V}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>V</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle V}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/af0f6064540e84211d0ffe4dac72098adfa52845" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:1.787ex; height:2.176ex;" alt="{\displaystyle V}"></span>는 부피이고 <span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle i}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>i</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle i}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/add78d8608ad86e54951b8c8bd6c8d8416533d20" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.338ex; width:0.802ex; height:2.176ex;" alt="{\displaystyle i}"></span>와 <span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle f}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi>f</mi> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle f}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/132e57acb643253e7810ee9702d9581f159a1c61" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:1.279ex; height:2.509ex;" alt="{\displaystyle f}"></span>는 각각 이전과 이후를 나타낸다. 즉 기체가 팽창해서 부피가 늘어나면(<span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle V_{i}&lt;V_{f}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> </msub> <mo>&lt;</mo> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msub> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle V_{i}&lt;V_{f}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/0f4699677babb6b4eb484936b44f025c7bc97cb3" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.005ex; width:7.745ex; height:2.843ex;" alt="{\displaystyle V_{i}&lt;V_{f}}"></span>) 압력은 감소한다(<span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle P_{i}&gt;P_{f}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <msub> <mi>P</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> </msub> <mo>&gt;</mo> <msub> <mi>P</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msub> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle P_{i}&gt;P_{f}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/9a859aeee7f5b63af24cd138f92083e7b82fd4e0" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.005ex; width:8.019ex; height:2.843ex;" alt="{\displaystyle P_{i}&gt;P_{f}}"></span>). </p><p>자유팽창을 하는 기체는 일을 하지 않는다. 기체는 최종 상태가 될 때까지 <a href="/wiki/%EC%97%B4%EC%97%AD%ED%95%99%EC%A0%81_%ED%8F%89%ED%98%95" title="열역학적 평형">열역학적 평형</a>이 아닌 상태를 거치며, 이 상태에서는 기체의 열역학적 변수를 모두 결정할 수 없다. 예컨대 기체의 압력은 점에서 점마다 국소적으로 변하기 때문에 입자의 총체로서의 기체의 부피는 쉽게 정의할 수 있는 양이 아니다. </p><p>코크를 열어서 기체가 진공으로 퍼져나가는 것이 자유팽창의 대표적인 사례이다. 계 안으로 들어오거나 나가는 열에너지가 없으므로, 이루어진 일은 없다. <a href="/wiki/%EC%97%94%ED%8A%B8%EB%A1%9C%ED%94%BC" title="엔트로피">엔트로피</a> 변화는 있지만 잘 알려진 엔트로피 변화공식 </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \Delta S=\int {\frac {dQ_{rev}}{T}}\,,}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x0394;<!-- Δ --></mi> <mi>S</mi> <mo>=</mo> <mo>&#x222B;<!-- ∫ --></mo> <mrow class="MJX-TeXAtom-ORD"> <mfrac> <mrow> <mi>d</mi> <msub> <mi>Q</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>r</mi> <mi>e</mi> <mi>v</mi> </mrow> </msub> </mrow> <mi>T</mi> </mfrac> </mrow> <mspace width="thinmathspace" /> <mo>,</mo> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \Delta S=\int {\frac {dQ_{rev}}{T}}\,,}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/d92e2d5582ffd448e9a64734d1f9010a6b5ddb26" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -2.338ex; width:16.576ex; height:5.843ex;" alt="{\displaystyle \Delta S=\int {\frac {dQ_{rev}}{T}}\,,}"></span></dd></dl> <p>은 적용되지 않는다. 이는 자유팽창이 <a href="/wiki/%EA%B0%80%EC%97%AD%EA%B3%BC%EC%A0%95" title="가역과정">가역과정</a>이 아니기 때문이다. 이상기체의 경우 자유팽창의 엔트로피는 <a href="/wiki/%EC%A4%84-%ED%86%B0%EC%8A%A8_%ED%9A%A8%EA%B3%BC" title="줄-톰슨 효과">줄-톰슨 효과</a>와 같이 구한다.<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \Delta S=\int _{i}^{f}\mathrm {d} S=\int _{V_{i}}^{V_{f}}{\frac {P\,\mathrm {d} V}{T}}=\int _{V_{i}}^{V_{f}}{\frac {nR\,\mathrm {d} V}{V}}=nR\ln {\frac {V_{f}}{V_{i}}}.}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mi mathvariant="normal">&#x0394;<!-- Δ --></mi> <mi>S</mi> <mo>=</mo> <msubsup> <mo>&#x222B;<!-- ∫ --></mo> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> <mi mathvariant="normal">d</mi> </mrow> <mi>S</mi> <mo>=</mo> <msubsup> <mo>&#x222B;<!-- ∫ --></mo> <mrow class="MJX-TeXAtom-ORD"> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> </msub> </mrow> <mrow class="MJX-TeXAtom-ORD"> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msub> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> <mfrac> <mrow> <mi>P</mi> <mspace width="thinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mi mathvariant="normal">d</mi> </mrow> <mi>V</mi> </mrow> <mi>T</mi> </mfrac> </mrow> <mo>=</mo> <msubsup> <mo>&#x222B;<!-- ∫ --></mo> <mrow class="MJX-TeXAtom-ORD"> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> </msub> </mrow> <mrow class="MJX-TeXAtom-ORD"> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msub> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> <mfrac> <mrow> <mi>n</mi> <mi>R</mi> <mspace width="thinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mi mathvariant="normal">d</mi> </mrow> <mi>V</mi> </mrow> <mi>V</mi> </mfrac> </mrow> <mo>=</mo> <mi>n</mi> <mi>R</mi> <mi>ln</mi> <mo>&#x2061;<!-- ⁡ --></mo> <mrow class="MJX-TeXAtom-ORD"> <mfrac> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>f</mi> </mrow> </msub> <msub> <mi>V</mi> <mrow class="MJX-TeXAtom-ORD"> <mi>i</mi> </mrow> </msub> </mfrac> </mrow> <mo>.</mo> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle \Delta S=\int _{i}^{f}\mathrm {d} S=\int _{V_{i}}^{V_{f}}{\frac {P\,\mathrm {d} V}{T}}=\int _{V_{i}}^{V_{f}}{\frac {nR\,\mathrm {d} V}{V}}=nR\ln {\frac {V_{f}}{V_{i}}}.}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/3d82a140ebb76802e224d5b839fd7235ba736387" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -2.671ex; width:55.845ex; height:6.676ex;" alt="{\displaystyle \Delta S=\int _{i}^{f}\mathrm {d} S=\int _{V_{i}}^{V_{f}}{\frac {P\,\mathrm {d} V}{T}}=\int _{V_{i}}^{V_{f}}{\frac {nR\,\mathrm {d} V}{V}}=nR\ln {\frac {V_{f}}{V_{i}}}.}"></span></dd></dl> <div class="mw-heading mw-heading2"><h2 id="각주"><span id=".EA.B0.81.EC.A3.BC"></span>각주</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%EC%9E%90%EC%9C%A0%ED%8C%BD%EC%B0%BD&amp;action=edit&amp;section=1" title="부분 편집: 각주"><span>편집</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><a href="#cite_ref-1">↑</a></span> <span class="reference-text">Tipler, P., and Mosca, G. <i>Physics for Scientists and Engineers (with modern physics), 6th edition, 2008. pages 602 and 647</i></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="외부_링크"><span id=".EC.99.B8.EB.B6.80_.EB.A7.81.ED.81.AC"></span>외부 링크</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%EC%9E%90%EC%9C%A0%ED%8C%BD%EC%B0%BD&amp;action=edit&amp;section=2" title="부분 편집: 외부 링크"><span>편집</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><span typeof="mw:File"><span><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/4/4a/Commons-logo.svg/12px-Commons-logo.svg.png" decoding="async" width="12" height="16" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/4a/Commons-logo.svg/18px-Commons-logo.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/4a/Commons-logo.svg/24px-Commons-logo.svg.png 2x" data-file-width="1024" data-file-height="1376" /></span></span> 위키미디어 공용에 <span class="plainlinks"><a class="external text" href="https://commons.wikimedia.org/wiki/Category:Joule/Gay-Lussac_expansions?uselang=ko">자유팽창</a></span> 관련 미디어 분류가 있습니다.</li></ul> <table class="notice metadata plainlinks stub" style="clear: both; font-size: smaller;"> <tbody><tr> <td style="width: 40px;"><span typeof="mw:File"><a href="/wiki/%EB%B6%84%EB%A5%98:%EB%AC%BC%EB%A6%AC%ED%95%99%EC%97%90_%EA%B4%80%ED%95%9C_%ED%86%A0%EB%A7%89%EA%B8%80" title="분류:물리학에 관한 토막글"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/3/3b/Emojione_269B.svg/40px-Emojione_269B.svg.png" decoding="async" width="40" height="40" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/3/3b/Emojione_269B.svg/60px-Emojione_269B.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/3/3b/Emojione_269B.svg/80px-Emojione_269B.svg.png 2x" data-file-width="512" data-file-height="512" /></a></span> </td> <td>이 글은 물리학에 관한 <a href="/wiki/%EC%9C%84%ED%82%A4%EB%B0%B1%EA%B3%BC:%ED%86%A0%EB%A7%89%EA%B8%80" title="위키백과:토막글">토막글</a>입니다. 여러분의 지식으로 알차게 <a class="external text" href="https://ko.wikipedia.org/w/index.php?title=%EC%9E%90%EC%9C%A0%ED%8C%BD%EC%B0%BD&amp;action=edit">문서를 완성해</a> 갑시다. </td></tr> </tbody></table> <!-- NewPP limit report Parsed by mw‐api‐ext.codfw.main‐7cb5748566‐s7z2f Cached time: 20241107001833 Cache expiry: 2592000 Reduced expiry: false Complications: [] CPU time usage: 0.283 seconds Real time usage: 0.444 seconds Preprocessor visited node count: 1352/1000000 Post‐expand include size: 57456/2097152 bytes Template argument size: 851/2097152 bytes Highest expansion depth: 21/100 Expensive parser function count: 0/500 Unstrip recursion depth: 0/20 Unstrip post‐expand size: 32379/5000000 bytes Lua time usage: 0.120/10.000 seconds Lua memory usage: 1652658/52428800 bytes Number of Wikibase entities loaded: 1/400 --> <!-- Transclusion expansion time report (%,ms,calls,template) 100.00% 245.683 1 -total 50.16% 123.231 1 틀:열역학 49.05% 120.507 1 틀:접이식_사이드바 28.47% 69.941 3 틀:Sidebar 24.47% 60.117 1 틀:출처_필요 19.24% 47.263 1 틀:Ambox 11.52% 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