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electrochemical performance</title> <meta name="description" content="Search results for: electrochemical performance"> <meta name="keywords" content="electrochemical performance"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="electrochemical performance"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 13333</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: electrochemical performance</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13333</span> Electrochemical Performance of Al-Mn2O3 Based Electrode Materials</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Noor%20Ul%20Ain%20Bhatti">Noor Ul Ain Bhatti</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Junaid%20Khan"> M. Junaid Khan</a>, <a href="https://publications.waset.org/abstracts/search?q=Javed%20Ahmad"> Javed Ahmad</a>, <a href="https://publications.waset.org/abstracts/search?q=Murtaza%20Saleem"> Murtaza Saleem</a>, <a href="https://publications.waset.org/abstracts/search?q=Shahid%20M.%20Ramay"> Shahid M. Ramay</a>, <a href="https://publications.waset.org/abstracts/search?q=Saadat%20A.%20Siddiqi"> Saadat A. Siddiqi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Manganese oxide is being recently used as electrode material for rechargeable batteries. In this study, Al incorporated Mn<sub>2</sub>O<sub>3</sub> compositions were synthesized to study the effect of Al doping on electrochemical performance of host material. Structural studies were carried out using X-ray diffraction analysis to confirm the phase stability and explore the lattice parameters, crystallite size, lattice strain, density and cell volume. Morphology and composition were analyzed using field emission scanning electron microscope and energy dispersive X-ray spectroscopy, respectively. Dynamic light scattering analysis was performed to observe the average particle size of the compositions. FTIR measurements exhibit the O-Al-O and O-Mn-O and Al-O bonding and with increasing the concentration of Al, the vibrational peaks of Mn-O become sharper. An enhanced electrochemical performance was observed in compositions with higher Al content. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mn2O3" title="Mn2O3">Mn2O3</a>, <a href="https://publications.waset.org/abstracts/search?q=electrode%20materials" title=" electrode materials"> electrode materials</a>, <a href="https://publications.waset.org/abstracts/search?q=energy%20storage%20and%20conversion" title=" energy storage and conversion"> energy storage and conversion</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20performance" title=" electrochemical performance"> electrochemical performance</a> </p> <a href="https://publications.waset.org/abstracts/63281/electrochemical-performance-of-al-mn2o3-based-electrode-materials" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/63281.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">367</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13332</span> Hydrothermal Synthesis of Mesoporous Carbon Nanospheres and Their Electrochemical Properties for Glucose Detection</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ali%20Akbar%20Kazemi%20Asl">Ali Akbar Kazemi Asl</a>, <a href="https://publications.waset.org/abstracts/search?q=Mansour%20Rahsepar"> Mansour Rahsepar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Mesoporous carbon nanospheres (MCNs) with uniform particle size distribution having an average of 290 nm and large specific surface area (274.4 m²/g) were synthesized by a one-step hydrothermal method followed by the calcination process and then utilized as an enzyme-free glucose biosensor. Morphology, crystal structure, and porous nature of the synthesized nanospheres were characterized by scanning electron microscopy (SEM), X-Ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) analysis, respectively. Also, the electrochemical performance of the MCNs@GCE electrode for the measurement of glucose concentration in alkaline media was investigated by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and chronoamperometry (CA). MCNs@GCE electrode shows good sensing performance, including a rapid glucose oxidation response within 3.1 s, a wide linear range of 0.026-12 mM, a sensitivity of 212.34 μA.mM⁻¹.cm⁻², and a detection limit of 25.7 μM with excellent selectivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biosensor" title="biosensor">biosensor</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical" title=" electrochemical"> electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=glucose" title=" glucose"> glucose</a>, <a href="https://publications.waset.org/abstracts/search?q=mesoporous%20carbon" title=" mesoporous carbon"> mesoporous carbon</a>, <a href="https://publications.waset.org/abstracts/search?q=non-enzymatic" title=" non-enzymatic"> non-enzymatic</a> </p> <a href="https://publications.waset.org/abstracts/142299/hydrothermal-synthesis-of-mesoporous-carbon-nanospheres-and-their-electrochemical-properties-for-glucose-detection" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/142299.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">190</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13331</span> Electrochemical Regeneration of GIC Adsorbent in a Continuous Electrochemical Reactor</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20N.%20Hussain">S. N. Hussain</a>, <a href="https://publications.waset.org/abstracts/search?q=H.%20M.%20A.%20Asghar"> H. M. A. Asghar</a>, <a href="https://publications.waset.org/abstracts/search?q=H.%20Sattar"> H. Sattar</a>, <a href="https://publications.waset.org/abstracts/search?q=E.%20P.%20L.%20Roberts"> E. P. L. Roberts</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Arvia™ introduced a novel technology consisting of adsorption followed by electrochemical regeneration with a graphite intercalation compound adsorbent that takes place in a single unit. The adsorbed species may lead to the formation of intermediate by-products products due to incomplete mineralization during electrochemical regeneration. Therefore, the investigation of breakdown products due to incomplete oxidation is of great concern regarding the commercial applications of this process. In the present paper, the formation of the chlorinated breakdown products during continuous process of adsorption and electrochemical regeneration based on a graphite intercalation compound adsorbent has been investigated. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=GIC" title="GIC">GIC</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20regeneration" title=" electrochemical regeneration"> electrochemical regeneration</a>, <a href="https://publications.waset.org/abstracts/search?q=chlorphenols" title=" chlorphenols"> chlorphenols</a> </p> <a href="https://publications.waset.org/abstracts/13387/electrochemical-regeneration-of-gic-adsorbent-in-a-continuous-electrochemical-reactor" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/13387.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">306</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13330</span> Analysis of Some Produced Inhibitors for Corrosion of J55 Steel in NaCl Solution Saturated with CO₂</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ambrish%20Singh">Ambrish Singh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The corrosion inhibition performance of pyran (AP) and benzimidazole (BI) derivatives on J55 steel in 3.5% NaCl solution saturated with CO₂ was investigated by electrochemical, weight loss, surface characterization, and theoretical studies. The electrochemical studies included electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), electrochemical frequency modulation (EFM), and electrochemical frequency modulation trend (EFMT). Surface characterization was done using contact angle, scanning electron microscopy (SEM), and atomic force microscopy (AFM) techniques. DFT and molecular dynamics (MD) studies were done using Gaussian and Materials Studio softwares. All the studies suggested the good inhibition by the synthesized inhibitors on J55 steel in 3.5% NaCl solution saturated with CO₂ due to the formation of a protective film on the surface. Molecular dynamic simulation was applied to search for the most stable configuration and adsorption energies for the interaction of the inhibitors with Fe (110) surface. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=corrosion" title="corrosion">corrosion</a>, <a href="https://publications.waset.org/abstracts/search?q=inhibitor" title=" inhibitor"> inhibitor</a>, <a href="https://publications.waset.org/abstracts/search?q=EFM" title=" EFM"> EFM</a>, <a href="https://publications.waset.org/abstracts/search?q=AFM" title=" AFM"> AFM</a>, <a href="https://publications.waset.org/abstracts/search?q=DFT" title=" DFT"> DFT</a>, <a href="https://publications.waset.org/abstracts/search?q=MD" title=" MD"> MD</a> </p> <a href="https://publications.waset.org/abstracts/115086/analysis-of-some-produced-inhibitors-for-corrosion-of-j55-steel-in-nacl-solution-saturated-with-co2" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/115086.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">105</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13329</span> Synthesis and Electrochemical Characterization of a Copolymer (PANI/PEDOT:PSS) for Application in Supercapacitors</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Naima%20Boudieb">Naima Boudieb</a>, <a href="https://publications.waset.org/abstracts/search?q=Mohamed%20Loucif%20Seaid"> Mohamed Loucif Seaid</a>, <a href="https://publications.waset.org/abstracts/search?q=Imad%20Rati"> Imad Rati</a>, <a href="https://publications.waset.org/abstracts/search?q=Imane%20Benammane"> Imane Benammane</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The aim of this study is to synthesis of a copolymer PANI/PEDOT:PSS by electrochemical means to apply in supercapacitors. Polyaniline (PANI) is a conductive polymer; it was synthesized by electrochemical polymerization. It exhibits very stable properties in different environments, whereas PEDOT:PSS is a conductive polymer based on poly(3,4-ethylenedioxythiophene) (PEDOT) and poly(styrene sulfonate)(PSS). It is commonly used with polyaniline to improve its electrical conductivity. Several physicochemical and electrochemical techniques were used for the characterization of PANI/PEDOT:PSS: cyclic voltammetry (VC), electrochemical impedance spectroscopy (EIS), open circuit potential, SEM, X-ray diffraction, etc. The results showed that the PANI/PEDOT:PSS composite is a promising material for supercapacitors due to its high electrical conductivity and high porosity. Electrochemical and physicochemical characterization tests have shown that the composite has high electrical and structural performances, making it a material of choice for high-performance energy storage applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=energy%20storage" title="energy storage">energy storage</a>, <a href="https://publications.waset.org/abstracts/search?q=supercapacitors" title=" supercapacitors"> supercapacitors</a>, <a href="https://publications.waset.org/abstracts/search?q=SIE" title=" SIE"> SIE</a>, <a href="https://publications.waset.org/abstracts/search?q=VC" title=" VC"> VC</a>, <a href="https://publications.waset.org/abstracts/search?q=PANI" title=" PANI"> PANI</a>, <a href="https://publications.waset.org/abstracts/search?q=poly%283" title=" poly(3"> poly(3</a>, <a href="https://publications.waset.org/abstracts/search?q=4-ethylenedioxythiophene" title="4-ethylenedioxythiophene">4-ethylenedioxythiophene</a>, <a href="https://publications.waset.org/abstracts/search?q=PEDOT" title=" PEDOT"> PEDOT</a>, <a href="https://publications.waset.org/abstracts/search?q=polystyrene%20sulfonate" title=" polystyrene sulfonate"> polystyrene sulfonate</a> </p> <a href="https://publications.waset.org/abstracts/182320/synthesis-and-electrochemical-characterization-of-a-copolymer-panipedotpss-for-application-in-supercapacitors" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/182320.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">63</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13328</span> Effect of Li-excess on Electrochemical Performance of Ni-rich LiNi₀.₉Co₀.₀₉Mn₀.₀₉O₂ Cathode Materials for Li-ion Batteries</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Eyob%20Belew%20Abebe">Eyob Belew Abebe</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Nickel-rich layered oxide cathode materials having a Ni content of ≥ 90% have great potential for use in next-generation lithium-ion batteries (LIBs), due to their high energy densities and relatively low cost. They suffer, however, from poor cycling performance and rate capability, significantly hampering their widespread applicability. In this study we synthesized a Ni-rich precursor through a co-precipitation method and added different amounts of Li-excess on the precursors using a solid-state method to obtain sintered Li1+x(Ni0.9Co0.05Mn0.05)1–xO2 (denoted as L1+x-NCM; x = 0.00, 0.02, 0.04, 0.06, and 0.08) transition metal (TM) oxide cathode materials. The L1+x-NCM cathode having a Li-excess of 4% exhibited a discharge capacity of ca. 216.17 mAh g–1 at 2.7–4.3 V, 0.1C and retained 95.7% of its initial discharge capacity (ca. 181.39 mAh g–1) after 100 cycles of 1C charge/discharge which is the best performance as compared with stoichiometric Li1+x(Ni0.9Co0.05Mn0.05)1-xO2 (i.e. x=0, Li:TM = 1:1). Furthermore, a high-rate capability of ca. 162.92 mAh g–1 at a rate of 10C, led to the 4% Li-excess optimizing the electrochemical performance, relative to the other Li-excess samples. Ex/in-situ X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy revealed that the 4% Li-excess in the Ni-rich NCM90 cathode material: (i). decreased the Li+/Ni2+ disorder by increasing the content of Ni3+ in the TM slab, (ii). increased the crystallinity, and (iii). accelerated Li+ ion transport by widening the Li-slab. Furthermore, electrochemical impedance spectroscopy and cyclic voltammetry confirmed that the appropriate Li-excess lowered the electrochemical impedance and improved the reversibility of the electrochemical reaction. Therefore, our results revealed that NCM90 cathode materials featuring an optimal Li-excess are potential candidates for use in next-generation Li-ion batteries. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=LiNi%E2%82%80.%E2%82%89Co%E2%82%80.%E2%82%80%E2%82%89Mn%E2%82%80.%E2%82%80%E2%82%89O%E2%82%82" title="LiNi₀.₉Co₀.₀₉Mn₀.₀₉O₂">LiNi₀.₉Co₀.₀₉Mn₀.₀₉O₂</a>, <a href="https://publications.waset.org/abstracts/search?q=li-excess" title=" li-excess"> li-excess</a>, <a href="https://publications.waset.org/abstracts/search?q=cation%20mixing" title=" cation mixing"> cation mixing</a>, <a href="https://publications.waset.org/abstracts/search?q=structure%20change" title=" structure change"> structure change</a>, <a href="https://publications.waset.org/abstracts/search?q=cycle%20stability" title=" cycle stability"> cycle stability</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20properties" title=" electrochemical properties"> electrochemical properties</a> </p> <a href="https://publications.waset.org/abstracts/151888/effect-of-li-excess-on-electrochemical-performance-of-ni-rich-lini09co009mn009o2-cathode-materials-for-li-ion-batteries" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/151888.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">175</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13327</span> Development of an Aptamer-Molecularly Imprinted Polymer Based Electrochemical Sensor to Detect Pathogenic Bacteria</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Meltem%20Agar">Meltem Agar</a>, <a href="https://publications.waset.org/abstracts/search?q=Maisem%20Laabei"> Maisem Laabei</a>, <a href="https://publications.waset.org/abstracts/search?q=Hannah%20Leese"> Hannah Leese</a>, <a href="https://publications.waset.org/abstracts/search?q=Pedro%20Estrela"> Pedro Estrela</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Pathogenic bacteria and the diseases they cause have become a global problem. Their early detection is vital and can only be possible by detecting the bacteria causing the disease accurately and rapidly. Great progress has been made in this field with the use of biosensors. Molecularly imprinted polymers have gain broad interest because of their excellent properties over natural receptors, such as being stable in a variety of conditions, inexpensive, biocompatible and having long shelf life. These properties make molecularly imprinted polymers an attractive candidate to be used in biosensors. In this study it is aimed to produce an aptamer-molecularly imprinted polymer based electrochemical sensor by utilizing the properties of molecularly imprinted polymers coupled with the enhanced specificity offered by DNA aptamers. These ‘apta-MIP’ sensors were used for the detection of Staphylococcus aureus and Escherichia coli. The experimental parameters for the fabrication of sensor were optimized, and detection of the bacteria was evaluated via Electrochemical Impedance Spectroscopy. Sensitivity and selectivity experiments were conducted. Furthermore, molecularly imprinted polymer only and aptamer only electrochemical sensors were produced separately, and their performance were compared with the electrochemical sensor produced in this study. Aptamer-molecularly imprinted polymer based electrochemical sensor showed good sensitivity and selectivity in terms of detection of Staphylococcus aureus and Escherichia coli. The performance of the sensor was assessed in buffer solution and tap water. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=aptamer" title="aptamer">aptamer</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20sensor" title=" electrochemical sensor"> electrochemical sensor</a>, <a href="https://publications.waset.org/abstracts/search?q=staphylococcus%20aureus" title=" staphylococcus aureus"> staphylococcus aureus</a>, <a href="https://publications.waset.org/abstracts/search?q=molecularly%20imprinted%20polymer" title=" molecularly imprinted polymer"> molecularly imprinted polymer</a> </p> <a href="https://publications.waset.org/abstracts/171368/development-of-an-aptamer-molecularly-imprinted-polymer-based-electrochemical-sensor-to-detect-pathogenic-bacteria" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/171368.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">118</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13326</span> Effects of Phase and Morphology on the Electrochemical and Electrochromic Performances of Tungsten Oxide and Tungsten-Molybdenum Oxide Nanostructures</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jinjoo%20Jung">Jinjoo Jung</a>, <a href="https://publications.waset.org/abstracts/search?q=Hayeon%20Won"> Hayeon Won</a>, <a href="https://publications.waset.org/abstracts/search?q=Doyeong%20Jeong"> Doyeong Jeong</a>, <a href="https://publications.waset.org/abstracts/search?q=Do%20Hyung%20Kim"> Do Hyung Kim</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We present the electrochemical and electrochromic performance of the novel crystalline tungsten oxide and tungsten-molybdenum oxide nanostructures synthesized by utilizing solvo-thermal method with hexacarbonyl tungsten, hexacarbonyl molybdenum, and ethyl alcohol. The morphology and phase of the prepared products were highly dependent on the synthesis conditions such as synthesis and annealing temperature, synthesis time, and precursor ratio. The tungsten oxide nanostructures (TCNs) have urchin-like or spherical nanostructure with different phase of W18O49 and WO3. The morphology of tungsten-molybdenum oxide nanostructures (TMONs) is basically similar to that of TCNs. However, the morphology and phase of TMONs are more diverse and are strongly dependent on the composition ratios of W/Mo in the precursor. The electrochemical properties depending on their morphologies and phases of TCNs and TMONs are compared using cyclic voltammetry and galvanostatic charge/discharge tests. The relationship between the electrochromic performance and phase structures/morphologies of nanostructured TCNs and TMONs are systematically investigated. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=electrochemical" title="electrochemical">electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochromic" title=" electrochromic"> electrochromic</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten%20oxide" title=" tungsten oxide"> tungsten oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten-molybdenum%20oxide" title=" tungsten-molybdenum oxide"> tungsten-molybdenum oxide</a> </p> <a href="https://publications.waset.org/abstracts/21623/effects-of-phase-and-morphology-on-the-electrochemical-and-electrochromic-performances-of-tungsten-oxide-and-tungsten-molybdenum-oxide-nanostructures" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/21623.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">590</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13325</span> Treatment of Leather Industry Wastewater with Advance Treatment Methods</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Seval%20Yilmaz">Seval Yilmaz</a>, <a href="https://publications.waset.org/abstracts/search?q=Filiz%20Bayrakci%20Karel"> Filiz Bayrakci Karel</a>, <a href="https://publications.waset.org/abstracts/search?q=Ali%20Savas%20Koparal"> Ali Savas Koparal</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Textile products produced by leather have been indispensable for human consumption. Various chemicals are used to enhance the durability of end-products in the processing of leather products. The wastewaters from the leather industry which contain these chemicals exhibit toxic effects on the receiving environment and threaten the natural ecosystem. In this study, leather industry wastewater (LIW), which has high loads of contaminants, was treated using advanced treatment techniques instead of conventional methods. During the experiments, the performance of electrochemical methods was investigated. During the electrochemical experiments, the performance of batch electrooxidation (EO) using boron-doped diamond (BDD) electrodes with monopolar configuration for removal of chemical oxygen demand (COD) from LIW were investigated. The influences of electrolysis time, current density (which varies as 5 mA/cm², 10 mA/cm², 20 mA/cm², 30 mA/cm², 50 mA/cm²) and initial pH (which varies as 3,80 (natural pH of LIW), 7, 9) on removal efficiency were investigated in a batch stirred cell to determine the best treatment conditions. The current density applied to the electrochemical reactors is directly proportional to the consumption of electric energy, so electrical energy consumption was monitored during the experiment. The best experimental conditions obtained in electrochemical studies were as follows: electrolysis time = 60 min, current density = 30.0 mA/cm², pH 7. Using these parameters, 53.59% COD removal rates for LIW was achieved and total energy consumption was obtained as 13.03 kWh/m³. It is concluded that electrooxidation process constitutes a plausible and developable method for the treatment of LIW. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=BDD%20electrodes" title="BDD electrodes">BDD electrodes</a>, <a href="https://publications.waset.org/abstracts/search?q=COD%20removal" title=" COD removal"> COD removal</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20treatment" title=" electrochemical treatment"> electrochemical treatment</a>, <a href="https://publications.waset.org/abstracts/search?q=leather%20industry%20wastewater" title=" leather industry wastewater"> leather industry wastewater</a> </p> <a href="https://publications.waset.org/abstracts/96331/treatment-of-leather-industry-wastewater-with-advance-treatment-methods" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/96331.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">159</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13324</span> Controlling the Oxygen Vacancies in the Structure of Anode Materials for Improved Electrochemical Performance in Lithium-Ion Batteries</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Moustafa%20M.%20S.%20Sanad">Moustafa M. S. Sanad</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The worsening of energy supply crisis and the exacerbation of climate change by environmental pollution problems have become the greatest threat to human life. One of the ways to confront these problems is to rely on renewable energy and its storage systems. Nowadays, huge attention has been directed to the development of lithium-ion batteries (LIBs) as efficient tools for storing the clean energy produced by green sources like solar and wind energies. Accordingly, the demand for powerful electrode materials with excellent electrochemical characteristics has been progressively increased to meet fast and continuous growth in the market of energy storage systems. Therefore, the electronic and electrical properties of conversion anode materials for rechargeable lithium-ion batteries (LIBs) can be enhanced by introducing lattice defects and oxygen vacancies in the crystal structure. In this regard, the intended presentation will demonstrate new insights and effective ways for enhancing the electrical conductivity and improving the electrochemical performance of different anode materials such as MgFe₂O₄, CdFe₂O₄, Fe₃O₄, LiNbO₃ and Nb₂O₅. The changes in the physicochemical and morphological properties have been deeply investigated via structural and spectroscopic analyses (e.g., XRD, FESEM, HRTEM, and XPS). Moreover, the enhancement in the electrochemical properties of these anode materials will be discussed through Galvanostatic Cycling (GC), Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) techniques. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=structure%20modification" title="structure modification">structure modification</a>, <a href="https://publications.waset.org/abstracts/search?q=cationic%20substitution" title=" cationic substitution"> cationic substitution</a>, <a href="https://publications.waset.org/abstracts/search?q=non-stoichiometric%20synthesis" title=" non-stoichiometric synthesis"> non-stoichiometric synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=plasma%20treatment" title=" plasma treatment"> plasma treatment</a>, <a href="https://publications.waset.org/abstracts/search?q=lithium-ion%20batteries" title=" lithium-ion batteries"> lithium-ion batteries</a> </p> <a href="https://publications.waset.org/abstracts/186386/controlling-the-oxygen-vacancies-in-the-structure-of-anode-materials-for-improved-electrochemical-performance-in-lithium-ion-batteries" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/186386.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">59</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13323</span> Nitrogen Doping Effect on Enhancement of Electrochemical Performance of a Carbon Nanotube Based Microsupercapacitor</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Behnoush%20Dousti">Behnoush Dousti</a>, <a href="https://publications.waset.org/abstracts/search?q=Ye%20Choi"> Ye Choi</a>, <a href="https://publications.waset.org/abstracts/search?q=Gil%20S.%20Lee"> Gil S. Lee</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Microsupercapacitors (MScs) are known as the future of miniaturized energy sources that can be coupled to a battery to deliver stable and constant energy to microelectronics. Among all their counterparts, electrochemical microsupercapacitor have drawn the most research attention due to their higher power density and long cycle life. Designing the microstructure and choosing the electroactive materials are two significant factors that greatly affect the performance of the device. Here, we report successful fabrication and characterization of a microsupercapacitor with interdigitated structure based on Carbon nanotube sheets (CNT sheet). Novel structure of highly aligned CNT sheet as the electrode materials which also offers excellent conductivity and large surface area along with doping with nitrogen, enabled us to develop a device with serval order of magnitude higher electrochemical performance than the pristine CNT in aqueous electrolyte including high specific capacitance and rate capabilities and excellent cycle life over 10000 cycles. Geometric parameters such as finger width and gap size were also studied and it was shown the device performance is much depended on them. Results of this study confirms the potential of CNT sheet for future energy storage devices. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbon%20nanotube" title="carbon nanotube">carbon nanotube</a>, <a href="https://publications.waset.org/abstracts/search?q=energy%20storage%20systems" title=" energy storage systems"> energy storage systems</a>, <a href="https://publications.waset.org/abstracts/search?q=microsupercapacitor" title=" microsupercapacitor"> microsupercapacitor</a>, <a href="https://publications.waset.org/abstracts/search?q=nitrogen%20doping" title=" nitrogen doping"> nitrogen doping</a> </p> <a href="https://publications.waset.org/abstracts/93498/nitrogen-doping-effect-on-enhancement-of-electrochemical-performance-of-a-carbon-nanotube-based-microsupercapacitor" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/93498.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">132</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13322</span> Unique NiO Based 1 D Core/Shell Nano-Heterostructure Electrodes for High-Performance Supercapacitor</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Gobinda%20Gopal%20Khan">Gobinda Gopal Khan</a>, <a href="https://publications.waset.org/abstracts/search?q=Ashutosh%20K.%20Singh"> Ashutosh K. Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=Debasish%20Sarkar"> Debasish Sarkar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Unique one-dimensional (1D) Ni-NiO and Co-Ni/Co3O4-NiO core/shell nano-heterostructures are fabricated by combining the electrochemical deposition and annealing. The high-performance pseudo-capacitor electrode based on the Ni-NiO and Co-Ni/Co3O4-NiO core/shell nano-heterostructures is designed and demonstrated. The Co-Ni/Co3O4-NiO core/shell nano-heterostructures exhibit high specific capacitance (2013 Fg-1 at 2.5 Ag-1), high energy and power density (23 Wh kg-1 and 5.5 kW kg-1, at the discharge current density of 20.8 A g-1.), good capacitance retention, and long cyclicality. The remarkable electrochemical property of the large surface area nano-heterostructures is demonstrated based on the novel nano-architectural design of the electrode with the coexistence of the two highly redox active materials at the surface supported by highly conducting metal alloy channel at the core for faster charge transport. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nano-heterostructures" title="nano-heterostructures">nano-heterostructures</a>, <a href="https://publications.waset.org/abstracts/search?q=energy%20storage" title=" energy storage"> energy storage</a>, <a href="https://publications.waset.org/abstracts/search?q=supercapacitors" title=" supercapacitors"> supercapacitors</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20deposition" title=" electrochemical deposition"> electrochemical deposition</a> </p> <a href="https://publications.waset.org/abstracts/15453/unique-nio-based-1-d-coreshell-nano-heterostructure-electrodes-for-high-performance-supercapacitor" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/15453.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">326</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13321</span> Construction and Performance of Nanocomposite-Based Electrochemical Biosensor</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jianfang%20Wang">Jianfang Wang</a>, <a href="https://publications.waset.org/abstracts/search?q=Xianzhe%20Chen"> Xianzhe Chen</a>, <a href="https://publications.waset.org/abstracts/search?q=Zhuoliang%20Liu"> Zhuoliang Liu</a>, <a href="https://publications.waset.org/abstracts/search?q=Cheng-An%20Tao"> Cheng-An Tao</a>, <a href="https://publications.waset.org/abstracts/search?q=Yujiao%20Li"> Yujiao Li</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Organophosphorus (OPs) pesticide used as insecticides are widely used in agricultural pest control, household and storage deworming. The detection of pesticides needs more simple and efficient methods. One of the best ways is to make electrochemical biosensors. In this paper, an electrochemical enzyme biosensor based on acetylcholine esterase (AChE) was constructed, and its sensing properties and sensing mechanisms were studied. Reduced graphene oxide-polydopamine complexes (RGO-PDA), gold nanoparticles (AuNPs) and silver nanoparticles (AgNPs) were prepared firstly and composited with AChE and chitosan (CS), then fixed on the glassy carbon electrode (GCE) surface to construct the biosensor GCE/RGO-PDA-AuNPs-AgNPs-AChE-CS by one-pot method. The results show that graphene oxide (GO) can be reduced by dopamine (DA) and dispersed well in RGO-PDA complexes. And the composites have a synergistic catalysis effect and can improve the surface resistance of GCE. The biosensor selectively can detect acetylcholine (ACh) and OPs pesticide with good linear range and high sensitivity. The performance of the biosensor is affected by the ratio and adding ways of AChE and the adding of AuNPs and AChE. And the biosensor can achieve a detection limit of 2.4 ng/L for methyl parathion and a wide linear detection range of 0.02 ng/L ~ 80 ng/L, and has excellent stability, good anti-interference ability, and excellent preservation performance, indicating that the sensor has practical value. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=acetylcholine%20esterase" title="acetylcholine esterase">acetylcholine esterase</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20biosensor" title=" electrochemical biosensor"> electrochemical biosensor</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title=" nanoparticles"> nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=organophosphates" title=" organophosphates"> organophosphates</a>, <a href="https://publications.waset.org/abstracts/search?q=reduced%20graphene%20oxide" title=" reduced graphene oxide"> reduced graphene oxide</a> </p> <a href="https://publications.waset.org/abstracts/116820/construction-and-performance-of-nanocomposite-based-electrochemical-biosensor" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/116820.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">112</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13320</span> Mesoporous RGO@(Co,Mn)3O4 Nanocomposite Prepared by Microwave Method and Its Electrochemical Performance</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Charmaine%20Lamiel">Charmaine Lamiel</a>, <a href="https://publications.waset.org/abstracts/search?q=Van%20Hoa%20Nguyen"> Van Hoa Nguyen</a>, <a href="https://publications.waset.org/abstracts/search?q=Jae-Jin%20Shim"> Jae-Jin Shim</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Supercapacitors are energy storage devices capable of storing more energy than conventional capacitors and have higher power density than batteries. The advantages of this method include the non-use of reducing agents and acidic medium, and no further use of a post-heat treatment unlike the conventional processes, in which calcination is generally employed after obtaining the initial product. Furthermore, it also offers a shorter reaction time at low temperatures and low power requirements, which allows low fabrication and energy cost. In this study, microwave irradiation was used for the facile and rapid synthesis of mesoporous RGO@(Co,Mn)3O4 nanosheets as an electrode material. The as-prepared electrode exhibited a high capacitance of 953 F•g^−1 at 1 A•g^−1 in a 6 M KOH electrolyte solution. Moreover, the electrode exhibited a high energy density of 76.2 Wh•kg^−1 at a power density of 720 W•kg^−1, and a high power density of 7200 W•kg^−1 at an energy density of 38 Wh•kg^−1. The successful methodology was considered to be efficient and cost-effective, thereby providing an active electrode material with very promising electrochemical performance. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=cobalt-manganese%20oxide" title="cobalt-manganese oxide">cobalt-manganese oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical" title=" electrochemical"> electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene" title=" graphene"> graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=microwave%20synthesis" title=" microwave synthesis"> microwave synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=supercapacitor" title=" supercapacitor"> supercapacitor</a> </p> <a href="https://publications.waset.org/abstracts/42664/mesoporous-rgo-at-comn3o4-nanocomposite-prepared-by-microwave-method-and-its-electrochemical-performance" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/42664.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">213</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13319</span> Enhancing the Structural and Electrochemical Performance of Li-Rich Layered Metal Oxides Cathodes for Li-Ion Battery by Coating with the Active Material</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Cyril%20O.%20Ehi-Eromosele">Cyril O. Ehi-Eromosele</a>, <a href="https://publications.waset.org/abstracts/search?q=Ajayi%20Kayode"> Ajayi Kayode</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The Li-rich layered metal oxides (LLO) are the most promising candidates for promising electrodes of high energy Li-ion battery (LIB). In literature, these electrode system has either been designed as a hetero-structure of the primary components (composite) or as a core-shell structure with improved electrochemistry reported for both configurations when compared with its primary components. With the on-going efforts to improve on the electrochemical performance of the LIB, it is important to investigate comparatively the structural and electrochemical characteristics of the core-shell like and ‘composite’ forms of these materials with the same compositions and synthesis conditions which could influence future engineering of these materials. Therefore, this study concerns the structural and electrochemical properties of the ‘composite’ and core-shell like LLO cathode materials with the same nominal composition of 0.5Li₂MnO₃-0.5LiNi₀.₅Mn₀.₃Co₀.₂O₂ (LiNi₀.₅Mn₀.₃Co₀.₂O₂ as core and Li₂MnO₃ as the shell). The results show that the core-shell sample (–CS) gave better electrochemical performance than the ‘composite’ sample (–C). Both samples gave the same initial charge capacity of ~300 mAh/g when cycled at 10 mA/g and comparable charge capacity (246 mAh/g for the –CS sample and 240 mAh/g for the –C sample) when cycled at 200 mA/g. However, the –CS sample gave a higher initial discharge capacity at both current densities. The discharge capacity of the –CS sample was 232 mAh/g and 164 mAh/g while the –C sample is 208 mAh/g and 143 mAh/g at the current densities of 10 mA/g and 200 mA/g, respectively. Electrochemical impedance spectroscopy (EIS) results show that the –CS sample generally exhibited a smaller resistance than the –C sample both for the uncycled and after 50th cycle. Detailed structural analysis is on-going, but preliminary results show that the –CS sample had bigger unit cell volume and a higher degree of cation mixing. The thermal stability of the –CS sample was higher than the –C sample. XPS investigation also showed that the pristine –C sample gave a more reactive surface (showing formation of carbonate species to a greater degree) which could result in the greater resistance seen in the EIS result. To reinforce the results obtained for the 0.5Li₂MnO₃-0.5LiNi₀.₅Mn₀.₃Co₀.₃O₂ composition, the same investigations were extended to another ‘composite’ and core-shell like LLO cathode materials also with the same nominal composition of 0.5Li₂MnO₃-0.5LiNi₀.₃Mn₀.₃Co₀.₃O₂. In this case, the aim was to determine the electrochemical performance of the material using a low Ni content (LiNi₀.₃Mn₀.₃Co₀.₃O₂) as the core to clarify the contributions of the core-shell configuration to the electrochemical performance of these materials. Ni-rich layered oxides show active catalytic surface leading to electrolyte oxidation resulting in poor thermal stability and cycle life. Here, the core-shell sample also gave better electrochemical performance than the ‘composite’ sample with 0.5Li₂MnO₃-0.5LiNi₀.₃Mn₀.₃Co₀.₃O₂ composition. Furthermore, superior electrochemical performance was also recorded for the core-shell like spinel modified LLO (0.5Li₂MnO₃-0.45LiNi₀.₅Mn₀.₃Co₀.₂O₂-0.05LiNi₀.₅Mn₁.₅O₄) when compared to the composite system. These results show that the core-shell configuration can generally be used to improve the structural and electrochemical properties of the LLO and spinel modified LLO materials. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=lithium-ion%20battery" title="lithium-ion battery">lithium-ion battery</a>, <a href="https://publications.waset.org/abstracts/search?q=lithium%20rich%20oxide%20cathode" title=" lithium rich oxide cathode"> lithium rich oxide cathode</a>, <a href="https://publications.waset.org/abstracts/search?q=core-shell%20structure" title=" core-shell structure"> core-shell structure</a>, <a href="https://publications.waset.org/abstracts/search?q=composite%20structure" title=" composite structure"> composite structure</a> </p> <a href="https://publications.waset.org/abstracts/111608/enhancing-the-structural-and-electrochemical-performance-of-li-rich-layered-metal-oxides-cathodes-for-li-ion-battery-by-coating-with-the-active-material" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/111608.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">122</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13318</span> Electrodeposited Silver Nanostructures: A Non-Enzymatic Sensor for Hydrogen Peroxide </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mandana%20Amiri">Mandana Amiri</a>, <a href="https://publications.waset.org/abstracts/search?q=Sima%20Nouhi"> Sima Nouhi</a>, <a href="https://publications.waset.org/abstracts/search?q=Yashar%20Azizan-Kalandaragh"> Yashar Azizan-Kalandaragh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Silver nanostructures have been successfully fabricated by using electrodeposition method onto indium-tin-oxide (ITO) substrate. Scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and ultraviolet-visible spectroscopy (UV-Vis) techniques were employed for characterization of silver nanostructures. The results show nanostructures with different morphology and electrochemical properties can be obtained by various the deposition potentials and times. Electrochemical behavior of the nanostructures has been studied by using cyclic voltammetry. Silver nanostructures exhibits good electrocatalytic activity towards the reduction of H<sub>2</sub>O<sub>2</sub>. The presented electrode can be employed as sensing element for hydrogen peroxide. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20sensor" title="electrochemical sensor">electrochemical sensor</a>, <a href="https://publications.waset.org/abstracts/search?q=electrodeposition" title=" electrodeposition"> electrodeposition</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogen%20peroxide" title=" hydrogen peroxide"> hydrogen peroxide</a>, <a href="https://publications.waset.org/abstracts/search?q=silver%20nanostructures" title=" silver nanostructures "> silver nanostructures </a> </p> <a href="https://publications.waset.org/abstracts/21938/electrodeposited-silver-nanostructures-a-non-enzymatic-sensor-for-hydrogen-peroxide" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/21938.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">512</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13317</span> The Viscosity of Xanthan Gum Grout with Different pH and Ionic Strength</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=H.%20Ahmad%20Raji">H. Ahmad Raji</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Ziaie%20Moayed"> R. Ziaie Moayed</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20A.%20Nozari"> M. A. Nozari</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Xanthan gum (XG) an eco-friendly biopolymer has been recently explicitly investigated for ground improvement approaches. Rheological behavior of this additive strongly depends on electrochemical condition such as pH, ionic strength and also its content in aqueous solution. So, the effects of these factors have been studied in this paper considering various XG contents as 0.25, 0.5, 1, and 2% of water. Moreover, adjusting pH values such as 3, 5, 7 and 9 in addition to increasing ionic strength to 0.1 and 0.2 in the molar scale has covered a practical range of electrochemical condition. The viscosity of grouts shows an apparent upward trend with an increase in ionic strength and XG content. Also, pH affects the polymerization as much as other parameters. As a result, XG behavior is severely influenced by electrochemical settings <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20condition" title="electrochemical condition">electrochemical condition</a>, <a href="https://publications.waset.org/abstracts/search?q=ionic%20strength" title=" ionic strength"> ionic strength</a>, <a href="https://publications.waset.org/abstracts/search?q=viscosity" title=" viscosity"> viscosity</a>, <a href="https://publications.waset.org/abstracts/search?q=xhanthan%20gum" title=" xhanthan gum "> xhanthan gum </a> </p> <a href="https://publications.waset.org/abstracts/116666/the-viscosity-of-xanthan-gum-grout-with-different-ph-and-ionic-strength" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/116666.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">190</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13316</span> Corrosion Inhibition of Brass in Phosphoric Acid Solution by 2-(5-Methyl-2-Nitro-1H-Imidazol-1-Yl) Ethyl Benzoate</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=R.%20Khrifou">R. Khrifou</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Galai"> M. Galai</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Touir"> R. Touir</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Ebn%20Touhami"> M. Ebn Touhami</a>, <a href="https://publications.waset.org/abstracts/search?q=Y.%20Ramli"> Y. Ramli</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A 2-(5-methyl-2-Nitro-1H-imidazol-1-yl)ethyl benzoate (IMDZ-B) was synthesized and characterized using elemental analyses, NMR, and Fourier transform infrared (FTIR) techniques. Its effect on brass corrosion in 1.0 M H₃PO₄ solution was investigated by using electrochemical measurements coupled with X-ray diffraction analysis (XRD), Scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDX). The polarization measurements showed that the IMDZ-B acts as a mixed-type inhibitor. Indeed, it is found that the IMDZ-B compound is a very good inhibitor, and its inhibition efficiency increases with concentration to reach a maximum of 99.5 % at 10-³ M. In addition, the obtained electrochemical parameters from impedance indicated that the IMDZ-B molecules act by adsorption on metallic surfaces. This adsorption was found to obey Langmuir’s adsorption isotherm. However, the temperature effect on the performance of IMDZ-B was also studied. It is found that the IMDZ-B takes its performance at high temperatures. In addition, the obtained kinetic and thermodynamic parameters showed that the IMDZ-B molecules act via two adsorption modes, physisorption and chemisorptions, and its process is endothermic and spontaneous. Finally, the XRD and SEM/EDX analyses confirmed the electrochemical obtained results. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=low%20concentration" title="low concentration">low concentration</a>, <a href="https://publications.waset.org/abstracts/search?q=anti-corrosion%20brass" title=" anti-corrosion brass"> anti-corrosion brass</a>, <a href="https://publications.waset.org/abstracts/search?q=IMDZ-B%20product" title=" IMDZ-B product"> IMDZ-B product</a>, <a href="https://publications.waset.org/abstracts/search?q=phosphoric%20acid%20solution" title=" phosphoric acid solution"> phosphoric acid solution</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical" title=" electrochemical"> electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=SEM%5CEDAX%20analysis" title=" SEM\EDAX analysis"> SEM\EDAX analysis</a> </p> <a href="https://publications.waset.org/abstracts/182044/corrosion-inhibition-of-brass-in-phosphoric-acid-solution-by-2-5-methyl-2-nitro-1h-imidazol-1-yl-ethyl-benzoate" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/182044.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">65</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13315</span> Influence of Surface Preparation Effects on the Electrochemical Behavior of 2098-T351 Al–Cu–Li Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Rejane%20Maria%20P.%20da%20Silva">Rejane Maria P. da Silva</a>, <a href="https://publications.waset.org/abstracts/search?q=Mariana%20X.%20Milagre"> Mariana X. Milagre</a>, <a href="https://publications.waset.org/abstracts/search?q=Jo%C3%A3o%20Victor%20de%20S.%20Araujo"> João Victor de S. Araujo</a>, <a href="https://publications.waset.org/abstracts/search?q=Leandro%20A.%20de%20Oliveira"> Leandro A. de Oliveira</a>, <a href="https://publications.waset.org/abstracts/search?q=Renato%20A.%20Antunes"> Renato A. Antunes</a>, <a href="https://publications.waset.org/abstracts/search?q=Isolda%20Costa"> Isolda Costa</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The Al-Cu-Li alloys are advanced materials for aerospace application because of their interesting mechanical properties and low density when compared with conventional Al-alloys. However, Al-Cu-Li alloys are susceptible to localized corrosion. The near-surface deformed layer (NSDL) induced by the rolling process during the production of the alloy and its removal by polishing can influence on the corrosion susceptibility of these alloys. In this work, the influence of surface preparation effects on the electrochemical activity of AA2098-T351 (Al–Cu–Li alloy) was investigated using a correlation between surface chemistry, microstructure, and electrochemical activity. Two conditions were investigated, polished and as-received surfaces of the alloy. The morphology of the two types of surfaces was investigated using confocal laser scanning microscopy (CLSM) and optical microscopy. The surface chemistry was analyzed by X-ray Photoelectron Spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDS). Global electrochemical techniques (potentiodynamic polarization and EIS technique) and a local electrochemical technique (Localized Electrochemical Impedance Spectroscopy-LEIS) were used to examine the electrochemical activity of the surfaces. The results obtained in this study showed that in the as-received surface, the near-surface deformed layer (NSDL), which is composed of Mg-rich bands, influenced the electrochemical behavior of the alloy. The results showed higher electrochemical activity to the polished surface condition compared to the as-received one. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Al-Cu-Li%20alloys" title="Al-Cu-Li alloys">Al-Cu-Li alloys</a>, <a href="https://publications.waset.org/abstracts/search?q=surface%20preparation%20effects" title=" surface preparation effects"> surface preparation effects</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20techniques" title=" electrochemical techniques"> electrochemical techniques</a>, <a href="https://publications.waset.org/abstracts/search?q=localized%20corrosion" title=" localized corrosion"> localized corrosion</a> </p> <a href="https://publications.waset.org/abstracts/110369/influence-of-surface-preparation-effects-on-the-electrochemical-behavior-of-2098-t351-al-cu-li-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/110369.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">159</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13314</span> Electrochemical Corrosion of Steels in Distillery Effluent</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=A.%20K.%20Singh">A. K. Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=Chhotu%20Ram"> Chhotu Ram</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The present work relates to the corrosivity of distillery effluent and corrosion performance of mild steel and stainless steels SS304L, SS316L, and 2205. The report presents the results and conclusions drawn on the basis of (i) electrochemical polarization tests performed in distillery effluent and laboratory prepared solutions having composition similar to that of the effluent (ii) the surface examination by scanning electron microscope (SEM) of the corroded steel samples. It is observed that pH and presence of chloride, phosphate, calcium, nitrite and nitrate in distillery effluent enhance corrosion, whereas presence of sulphate and potassium inhibits corrosion. Among the materials tested, mild steel is observed to experience maximum corrosion followed by stainless steels SS304L, SS316L, and 2205. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=corrosion" title="corrosion">corrosion</a>, <a href="https://publications.waset.org/abstracts/search?q=distillery%20effluent" title=" distillery effluent"> distillery effluent</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20polarization" title=" electrochemical polarization"> electrochemical polarization</a>, <a href="https://publications.waset.org/abstracts/search?q=steel" title=" steel"> steel</a> </p> <a href="https://publications.waset.org/abstracts/61278/electrochemical-corrosion-of-steels-in-distillery-effluent" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/61278.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">409</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13313</span> High Electrochemical Performance of Electrode Material Based On Mesoporous RGO@(Co,Mn)3O4 Nanocomposites</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Charmaine%20Lamiel">Charmaine Lamiel</a>, <a href="https://publications.waset.org/abstracts/search?q=Van%20Hoa%20Nguyen"> Van Hoa Nguyen</a>, <a href="https://publications.waset.org/abstracts/search?q=Deivasigamani%20Ranjith%20Kumar"> Deivasigamani Ranjith Kumar</a>, <a href="https://publications.waset.org/abstracts/search?q=Jae-Jin%20Shim"> Jae-Jin Shim</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The quest for alternative sources of energy storage had led to the exploration on supercapacitors. Hybrid supercapacitors, a combination of carbon-based material and transition metals, had yielded long and improved cycle life as well as high energy and power densities. In this study, microwave irradiation was used for the facile and rapid synthesis of mesoporous RGO@(Co,Mn)3O4 nanosheets as an active electrode material. The advantages of this method include the non-use of reducing agents and acidic medium, and no further post-heat treatment. Additionally, it offers shorter reaction time at low temperature and low power requirement, which allows low fabrication and energy cost. The as-prepared electrode material demonstrated a high capacitance of 953 F•g−1 at 1 A•g−1 in a 6 M KOH electrolyte. Furthermore, the electrode exhibited a high energy density of 76.2 Wh•kg−1 (power density of 720 W•kg−1) and a high power density of 7200 W•kg−1 (energy density of 38 Wh•kg−1). The successful synthesis was considered to be efficient and cost-effective, with very promising electrochemical performance that can be used as an active material in supercapacitors. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=cobalt%20manganese%20oxide" title="cobalt manganese oxide">cobalt manganese oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical" title=" electrochemical"> electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene" title=" graphene"> graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=microwave%20synthesis" title=" microwave synthesis"> microwave synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=supercapacitor" title=" supercapacitor"> supercapacitor</a> </p> <a href="https://publications.waset.org/abstracts/42939/high-electrochemical-performance-of-electrode-material-based-on-mesoporous-rgo-at-comn3o4-nanocomposites" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/42939.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">358</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13312</span> Electrochemical Layer by Layer Assembly</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mao%20Li">Mao Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Yuguang%20Ma"> Yuguang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Katsuhiko%20Ariga"> Katsuhiko Ariga</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The performance of functional materials is governed by their ability to interact with surrounding environments in a well-defined and controlled manner. Layer-by-Layer (LbL) assembly is one of the most widely used technologies for coating both planar and particulate substrates in a diverse range of fields, including optics, energy, catalysis, separations, and biomedicine. Herein, we introduce electrochemical-coupling layer-by-layer assembly as a novel fabrication methodology for preparing layered thin films. This assembly method not only determines the process properties (such as the time, scalability, and manual intervention) but also directly control the physicochemical properties of the films (such as the thickness, homogeneity, and inter- and intra-layer film organization), with both sets of properties linked to application-specific performance. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=layer%20by%20layer%20assembly" title="layer by layer assembly">layer by layer assembly</a>, <a href="https://publications.waset.org/abstracts/search?q=electropolymerization" title=" electropolymerization"> electropolymerization</a>, <a href="https://publications.waset.org/abstracts/search?q=carbazole" title=" carbazole"> carbazole</a>, <a href="https://publications.waset.org/abstracts/search?q=optical%20thin%20film" title=" optical thin film"> optical thin film</a>, <a href="https://publications.waset.org/abstracts/search?q=electronics" title=" electronics"> electronics</a> </p> <a href="https://publications.waset.org/abstracts/42525/electrochemical-layer-by-layer-assembly" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/42525.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">382</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13311</span> Synthesis and Performance Study of Co3O4 as a Bi-Functional Next Generation Material</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Shrikaant%20Kulkarni">Shrikaant Kulkarni</a>, <a href="https://publications.waset.org/abstracts/search?q=Akshata%20Naik%20Nimbalkar"> Akshata Naik Nimbalkar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this worki a method protocol has been developed for the synthesis of innovative Co3O4 material by using a method of chemical synthesis followed by calcination. The effect of calcination temperature on the morphology, structure and catalytic performance on material in question is investigated by using characterization tools like scanning electron microscopy (SEM), X-ray diffraction (XRD) spectroscopy and electrochemical techniques. The SEM images reveal that the morphology of the Co3O4 material undergoes a change from the rod to a beadlike shape on calcination at temperature of 700 °C. The XRD image shows that although the morphology of synthesized Co3O4 material exhibits a cubic phase but it differs in crystallinity depending upon morphology. Similarly spherical beadlike Co3O4 material has exhibited better activity than its rodlike counterpart which is reflected from electrochemical findings. Further, its performance in terms of bifunctional nature and hlods a lot much of promise as a excellent electrode material in the next generation batteries and fuel cells. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bifunctional" title="bifunctional">bifunctional</a>, <a href="https://publications.waset.org/abstracts/search?q=next%20generation%20material" title=" next generation material"> next generation material</a>, <a href="https://publications.waset.org/abstracts/search?q=Co3O4" title=" Co3O4"> Co3O4</a>, <a href="https://publications.waset.org/abstracts/search?q=XRD" title=" XRD"> XRD</a> </p> <a href="https://publications.waset.org/abstracts/16208/synthesis-and-performance-study-of-co3o4-as-a-bi-functional-next-generation-material" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/16208.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">379</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13310</span> A Comparative Analysis of Traditional and Advanced Methods in Evaluating Anti-corrosion Performance of Sacrificial and Barrier Coatings</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kazem%20Sabet-Bokati">Kazem Sabet-Bokati</a>, <a href="https://publications.waset.org/abstracts/search?q=Ilia%20Rodionov"> Ilia Rodionov</a>, <a href="https://publications.waset.org/abstracts/search?q=Marciel%20Gaier"> Marciel Gaier</a>, <a href="https://publications.waset.org/abstracts/search?q=Kevin%20Plucknett"> Kevin Plucknett</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Protective coatings play a pivotal role in mitigating corrosion and preserving the integrity of metallic structures exposed to harsh environmental conditions. The diversity of corrosive environments necessitates the development of protective coatings suitable for various conditions. Accurately selecting and interpreting analysis methods is crucial in identifying the most suitable protective coatings for the various corrosive environments. This study conducted a comprehensive comparative analysis of traditional and advanced methods to assess the anti-corrosion performance of sacrificial and barrier coatings. The protective performance of pure epoxy, zinc-rich epoxy, and cold galvanizing coatings was evaluated using salt spray tests, together with electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization methods. The performance of each coating was thoroughly differentiated under both atmospheric and immersion conditions. The distinct protective performance of each coating against atmospheric corrosion was assessed using traditional standard methods. Additionally, the electrochemical responses of these coatings in immersion conditions were systematically studied, and a detailed discussion on interpreting the electrochemical responses is provided. Zinc-rich epoxy and cold galvanizing coatings offer superior anti-corrosion performance against atmospheric corrosion, while the pure epoxy coating excels in immersion conditions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=corrosion" title="corrosion">corrosion</a>, <a href="https://publications.waset.org/abstracts/search?q=barrier%20coatings" title=" barrier coatings"> barrier coatings</a>, <a href="https://publications.waset.org/abstracts/search?q=sacrificial%20coatings" title=" sacrificial coatings"> sacrificial coatings</a>, <a href="https://publications.waset.org/abstracts/search?q=salt-spray" title=" salt-spray"> salt-spray</a>, <a href="https://publications.waset.org/abstracts/search?q=EIS" title=" EIS"> EIS</a>, <a href="https://publications.waset.org/abstracts/search?q=polarization" title=" polarization"> polarization</a> </p> <a href="https://publications.waset.org/abstracts/181638/a-comparative-analysis-of-traditional-and-advanced-methods-in-evaluating-anti-corrosion-performance-of-sacrificial-and-barrier-coatings" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/181638.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">66</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13309</span> Bio-Electrochemical Process Coupled with MnO2 Nanowires for Wastewater Treatment</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=A.%20Giwa">A. Giwa</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20M.%20Jung"> S. M. Jung</a>, <a href="https://publications.waset.org/abstracts/search?q=W.%20Fang"> W. Fang</a>, <a href="https://publications.waset.org/abstracts/search?q=J.%20Kong"> J. Kong</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20W.%20Hasan"> S. W. Hasan </a> </p> <p class="card-text"><strong>Abstract:</strong></p> MnO<sub>2</sub> nanowires were developed as filtration media for wastewater treatment that uniquely combines several advantages. The resulting material demonstrated strong capability to remove the pollution of heavy metal ions and organic contents in water. In addition, the manufacture process of such material is practical and economical. In this work, MnO<sub>2</sub> nanowires were integrated with the state-of-art bio-electrochemical system for wastewater treatment, to overcome problems currently encountered with organic, inorganic, heavy metal, and microbe removal, and to minimize the unit footprint (land/space occupation) at low cost. Results showed that coupling the bio-electrochemical with MnO<sub>2</sub> resulted in very encouraging results with higher removal efficiencies of such pollutants. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bio-electrochemical" title="bio-electrochemical">bio-electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=nanowires" title=" nanowires"> nanowires</a>, <a href="https://publications.waset.org/abstracts/search?q=novel" title=" novel"> novel</a>, <a href="https://publications.waset.org/abstracts/search?q=wastewater" title=" wastewater"> wastewater</a> </p> <a href="https://publications.waset.org/abstracts/42431/bio-electrochemical-process-coupled-with-mno2-nanowires-for-wastewater-treatment" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/42431.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">387</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13308</span> 1-Butyl-2,3-Dimethylimidazolium Bis (Trifluoromethanesulfonyl) Imide and Titanium Oxide Based Voltammetric Sensor for the Quantification of Flunarizine Dihydrochloride in Solubilized Media</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Rajeev%20Jain">Rajeev Jain</a>, <a href="https://publications.waset.org/abstracts/search?q=Nimisha%20Jadon"> Nimisha Jadon</a>, <a href="https://publications.waset.org/abstracts/search?q=Kshiti%20Singh"> Kshiti Singh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Titanium oxide nanoparticles and 1-butyl-2,3-dimethylimidazolium bis (trifluoromethane- sulfonyl) imide modified glassy carbon electrode (TiO2/IL/GCE) has been fabricated for electrochemical sensing of flunarizine dihydrochloride (FRH). The electrochemical properties and morphology of the prepared nanocomposite were studied by electrochemical impedance spectroscopy (EIS) and transmission electron microscopy (TEM). The response of the electrochemical sensor was found to be proportional to the concentrations of FRH in the range from 0.5 µg mL-1 to 16 µg mL-1. The detection limit obtained was 0.03 µg mL-1. The proposed method was also applied to the determination of FRH in pharmaceutical formulation and human serum with good recoveries. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=flunarizine%20dihydrochloride" title="flunarizine dihydrochloride">flunarizine dihydrochloride</a>, <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquid" title=" ionic liquid"> ionic liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title=" nanoparticles"> nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=voltammetry" title=" voltammetry"> voltammetry</a>, <a href="https://publications.waset.org/abstracts/search?q=human%20serum" title=" human serum"> human serum</a> </p> <a href="https://publications.waset.org/abstracts/80599/1-butyl-23-dimethylimidazolium-bis-trifluoromethanesulfonyl-imide-and-titanium-oxide-based-voltammetric-sensor-for-the-quantification-of-flunarizine-dihydrochloride-in-solubilized-media" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/80599.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">329</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13307</span> Nanohybrids for Energy Storage Devices</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=O.%20Guellati">O. Guellati</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Harat"> A. Harat</a>, <a href="https://publications.waset.org/abstracts/search?q=F.%20Djefaflia"> F. Djefaflia</a>, <a href="https://publications.waset.org/abstracts/search?q=N.%20Habib"> N. Habib</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Nait-Merzoug"> A. Nait-Merzoug</a>, <a href="https://publications.waset.org/abstracts/search?q=J.%20El%20Haskouri"> J. El Haskouri</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Momodu"> D. Momodu</a>, <a href="https://publications.waset.org/abstracts/search?q=N.%20Manyala"> N. Manyala</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20B%C3%A9gin"> D. Bégin</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Guerioune"> M. Guerioune</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We report a facile and low-cost free-template synthesis method was used to synthesize mesoporous smart multifunctional nanohybrids based on Graphene/PANI nanofibers micro/nanostructures with very interesting physic-chemical properties and faradic electrochemical behavior of these products was investigated. These nanohybrid products have been characterized quantitatively and qualitatively using different techniques, such as XRD / FTIR, Raman, XPS spectroscopy, Field Emission SEM and High-Resolution TEM microscopy, BET textural analysis, electrochemical measurements (CV, CD, EIS). Moreover, the electrochemical measurements performed in a 6 M KOH aqueous electrolyte depicted excellent electrochemical performance ascribed to the optimized composition of hydroxides et PANI nanofibers. An exceptionally notable specific capacitance between 800 and 2000 F. g-1 was obtained at 5 mV. s-1 scan rate for these synthesized products depends on the optimized growth conditions. We found much better nanohybrids by reinforcing hydroxides or conduction polymer nanofibers with carbonaceous nanomaterials depicting their potential as suitable materials for energy storage devices. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nanohybrid%20materials" title="nanohybrid materials">nanohybrid materials</a>, <a href="https://publications.waset.org/abstracts/search?q=conducting%20polymers" title=" conducting polymers"> conducting polymers</a>, <a href="https://publications.waset.org/abstracts/search?q=carbonaceous%20nanomaterials" title=" carbonaceous nanomaterials"> carbonaceous nanomaterials</a>, <a href="https://publications.waset.org/abstracts/search?q=supercapacitors" title=" supercapacitors"> supercapacitors</a>, <a href="https://publications.waset.org/abstracts/search?q=energy%20storage" title=" energy storage"> energy storage</a> </p> <a href="https://publications.waset.org/abstracts/169195/nanohybrids-for-energy-storage-devices" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/169195.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">71</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13306</span> Testing of Protective Coatings on Automotive Steel, a Correlation Between Salt Spray, Electrochemical Impedance Spectroscopy, and Linear Polarization Resistance Test</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dhanashree%20Aole">Dhanashree Aole</a>, <a href="https://publications.waset.org/abstracts/search?q=V.%20Hariharan"> V. Hariharan</a>, <a href="https://publications.waset.org/abstracts/search?q=Swati%20Surushe"> Swati Surushe</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Corrosion can cause serious and expensive damage to the automobile components. Various proven techniques for controlling and preventing corrosion depend on the specific material to be protected. Electrochemical Impedance Spectroscopy (EIS) and salt spray tests are commonly used to assess the corrosion degradation mechanism of coatings on metallic surfaces. While, the only test which monitors the corrosion rate in real time is known as Linear Polarisation Resistance (LPR). In this study, electrochemical tests (EIS & LPR) and spray test are reviewed to assess the corrosion resistance and durability of different coatings. The main objective of this study is to correlate the test results obtained using linear polarization resistance (LPR) and Electrochemical Impedance Spectroscopy (EIS) with the results obtained using standard salt spray test. Another objective of this work is to evaluate the performance of various coating systems- CED, Epoxy, Powder coating, Autophoretic, and Zn-trivalent coating for vehicle underbody application. The corrosion resistance coating are assessed. From this study, a promising correlation between different corrosion testing techniques is noted. The most profound observation is that electrochemical tests gives quick estimation of corrosion resistance and can detect the degradation of coatings well before visible signs of damage appear. Furthermore, the corrosion resistances and salt spray life of the coatings investigated were found to be according to the order as follows- CED> powder coating > Autophoretic > epoxy coating > Zn- Trivalent plating. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Linear%20Polarization%20Resistance%20%28LPR%29" title="Linear Polarization Resistance (LPR)">Linear Polarization Resistance (LPR)</a>, <a href="https://publications.waset.org/abstracts/search?q=Electrochemical%20Impedance%20Spectroscopy%20%28EIS%29" title=" Electrochemical Impedance Spectroscopy (EIS)"> Electrochemical Impedance Spectroscopy (EIS)</a>, <a href="https://publications.waset.org/abstracts/search?q=salt%20spray%20test" title=" salt spray test"> salt spray test</a>, <a href="https://publications.waset.org/abstracts/search?q=sacrificial%20and%20barrier%20coatings" title=" sacrificial and barrier coatings"> sacrificial and barrier coatings</a> </p> <a href="https://publications.waset.org/abstracts/27040/testing-of-protective-coatings-on-automotive-steel-a-correlation-between-salt-spray-electrochemical-impedance-spectroscopy-and-linear-polarization-resistance-test" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/27040.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">526</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13305</span> Modified Fe₃O₄ Nanoparticles for Electrochemical Sensing of Heavy Metal Ions Pb²⁺, Hg²⁺, and Cd²⁺ in Water</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Megha">Megha</a>, <a href="https://publications.waset.org/abstracts/search?q=Diksha"> Diksha</a>, <a href="https://publications.waset.org/abstracts/search?q=Seema%20Rani"> Seema Rani</a>, <a href="https://publications.waset.org/abstracts/search?q=Balwinder%20Kaur"> Balwinder Kaur</a>, <a href="https://publications.waset.org/abstracts/search?q=Harminder%20Kaur"> Harminder Kaur</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Fe₃O₄@SiO₂@SB functionalized magnetic nanoparticles were synthesized and used to detect heavy metal ions such as Pb²⁺, Hg²⁺, and Cd²⁺ in water. The formation of Fe₃O₄@SiO₂@SB nanocatalyst was confirmed by XRD, SEM, TEM, and IR. The simultaneous determination of analyte cations was carried out using square wave anodic stripping voltammetry (SWASV). Investigation and optimisation were done to study how experimental variables affected the performance of the modified magnetic electrode. Pb²⁺, Hg²⁺, and Cd²⁺ were successfully detected using the designed sensor in the presence of various possibly interfering ions. The recovery rate was found to be 97.5% for Pb²⁺, 96.2% for Hg²⁺, 103.5% for Cd²⁺. The electrochemical sensor was also employed to determine the presence of heavy metal ions in drinking water samples, which are well below the World Health Organization (WHO) guidelines. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=magnetic%20nanoparticles" title="magnetic nanoparticles">magnetic nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=heavy%20metal%20ions" title=" heavy metal ions"> heavy metal ions</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20sensor" title=" electrochemical sensor"> electrochemical sensor</a>, <a href="https://publications.waset.org/abstracts/search?q=environmental%20water%20samples" title=" environmental water samples"> environmental water samples</a> </p> <a href="https://publications.waset.org/abstracts/172188/modified-fe3o4-nanoparticles-for-electrochemical-sensing-of-heavy-metal-ions-pb2-hg2-and-cd2-in-water" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/172188.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">79</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13304</span> Investigation of Zinc Corrosion in Tropical Soil Solution</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Lebrini">M. Lebrini</a>, <a href="https://publications.waset.org/abstracts/search?q=L.%20Salhi"> L. Salhi</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20Deyrat"> C. Deyrat</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20Roos"> C. Roos</a>, <a href="https://publications.waset.org/abstracts/search?q=O.%20Nait-Rabah"> O. Nait-Rabah</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The paper presents a large experimental study on the corrosion of zinc in tropical soil and in the ground water at the various depths. Through this study, the corrosion rate prediction was done on the basis of two methods the electrochemical method and the gravimetric. The electrochemical results showed that the corrosion rate is more important at the depth levels 0 m to 0.5 m and 0.5 m to 1 m and beyond these depth levels, the corrosion rate is less important. The electrochemical results indicated also that a passive layer is formed on the zinc surface. The found SEM and EDX micrographs displayed that the surface is extremely attacked and confirmed that a zinc oxide layer is present on the surface whose thickness and relief increase as the contact with soil increases. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=soil%20corrosion" title="soil corrosion">soil corrosion</a>, <a href="https://publications.waset.org/abstracts/search?q=galvanized%20steel" title=" galvanized steel"> galvanized steel</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20technique" title=" electrochemical technique"> electrochemical technique</a>, <a href="https://publications.waset.org/abstracts/search?q=SEM%20and%20EDX" title=" SEM and EDX"> SEM and EDX</a> </p> <a href="https://publications.waset.org/abstracts/153148/investigation-of-zinc-corrosion-in-tropical-soil-solution" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/153148.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">128</span> </span> </div> </div> <ul class="pagination"> <li class="page-item disabled"><span class="page-link">&lsaquo;</span></li> <li class="page-item active"><span class="page-link">1</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=electrochemical%20performance&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=electrochemical%20performance&page=3">3</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=electrochemical%20performance&page=4">4</a></li> <li class="page-item"><a class="page-link" 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