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overflow: hidden; text-overflow: ellipsis; -webkit-line-clamp: 3; -webkit-box-orient: vertical; }</style><div class="col-xs-12 clearfix"><div class="u-floatLeft"><h1 class="PageHeader-title u-m0x u-fs30">Thermal Decomposition</h1><div class="u-tcGrayDark">1,940 Followers</div><div class="u-tcGrayDark u-mt2x">Recent papers in <b>Thermal Decomposition</b></div></div></div></div></div></div><div class="TabbedNavigation"><div class="container"><div class="row"><div class="col-xs-12 clearfix"><ul class="nav u-m0x u-p0x list-inline u-displayFlex"><li class="active"><a href="https://www.academia.edu/Documents/in/Thermal_Decomposition">Top Papers</a></li><li><a href="https://www.academia.edu/Documents/in/Thermal_Decomposition/MostCited">Most Cited Papers</a></li><li><a href="https://www.academia.edu/Documents/in/Thermal_Decomposition/MostDownloaded">Most Downloaded Papers</a></li><li><a href="https://www.academia.edu/Documents/in/Thermal_Decomposition/MostRecent">Newest Papers</a></li><li><a class="" href="https://www.academia.edu/People/Thermal_Decomposition">People</a></li></ul></div><style type="text/css">ul.nav{flex-direction:row}@media(max-width: 567px){ul.nav{flex-direction:column}.TabbedNavigation li{max-width:100%}.TabbedNavigation li.active{background-color:var(--background-grey, #dddde2)}.TabbedNavigation li.active:before,.TabbedNavigation li.active:after{display:none}}</style></div></div></div><div class="container"><div class="row"><div class="col-xs-12"><div class="u-displayFlex"><div class="u-flexGrow1"><div class="works"><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_77048818" data-work_id="77048818" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/77048818/Thermal_decomposition_kinetics_of_potassium_iodate">Thermal decomposition kinetics of potassium iodate</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The rate and kinetics of the thermal decomposition of potassium iodate (KIO 3) has been studied as a function of particle size, in the range 63-150 lm, by isothermal thermogravimetry at different temperatures, 790, 795, 800 and 805 K in... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_77048818" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The rate and kinetics of the thermal decomposition of potassium iodate (KIO 3) has been studied as a function of particle size, in the range 63-150 lm, by isothermal thermogravimetry at different temperatures, 790, 795, 800 and 805 K in nitrogen atmosphere. The theoretical and experimental mass loss data are in good agreement for the thermal decomposition of all samples of KIO 3 at all temperatures studied. The isothermal decomposition of all samples of KIO 3 was subjected to both model-fitting and model-free (isoconversional) kinetic methods of analysis. It has been observed that the activation energy values are independent of the particle size. Isothermal model-fitting analysis shows that the thermal decomposition kinetics of all the samples of KIO 3 studied can be best described by the contracting cube equation.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/77048818" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="5778a9985cdab048c945463c5aaae24e" rel="nofollow" data-download="{"attachment_id":84553579,"asset_id":77048818,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/84553579/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="331684" href="https://calicutuniversity.academia.edu/MPKannan">MP Kannan</a><script data-card-contents-for-user="331684" type="text/json">{"id":331684,"first_name":"MP","last_name":"Kannan","domain_name":"calicutuniversity","page_name":"MPKannan","display_name":"MP Kannan","profile_url":"https://calicutuniversity.academia.edu/MPKannan?f_ri=483677","photo":"https://0.academia-photos.com/331684/149680753/139252901/s65_mp.kannan.jpeg"}</script></span></span></li><li class="js-paper-rank-work_77048818 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="77048818"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 77048818, container: ".js-paper-rank-work_77048818", }); 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$(".js-view-count[data-work-id=77048818]").text(description); $(".js-view-count-work_77048818").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_77048818").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="77048818"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">13</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="523" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemistry">Chemistry</a>, <script data-card-contents-for-ri="523" type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4987" rel="nofollow" href="https://www.academia.edu/Documents/in/Kinetics">Kinetics</a>, <script data-card-contents-for-ri="4987" type="text/json">{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="147640" rel="nofollow" href="https://www.academia.edu/Documents/in/Activation_Energy">Activation Energy</a>, <script data-card-contents-for-ri="147640" type="text/json">{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="151091" rel="nofollow" href="https://www.academia.edu/Documents/in/Nitrogen">Nitrogen</a><script data-card-contents-for-ri="151091" type="text/json">{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=77048818]'), work: {"id":77048818,"title":"Thermal decomposition kinetics of potassium iodate","created_at":"2022-04-20T02:41:33.363-07:00","url":"https://www.academia.edu/77048818/Thermal_decomposition_kinetics_of_potassium_iodate?f_ri=483677","dom_id":"work_77048818","summary":"The rate and kinetics of the thermal decomposition of potassium iodate (KIO 3) has been studied as a function of particle size, in the range 63-150 lm, by isothermal thermogravimetry at different temperatures, 790, 795, 800 and 805 K in nitrogen atmosphere. The theoretical and experimental mass loss data are in good agreement for the thermal decomposition of all samples of KIO 3 at all temperatures studied. The isothermal decomposition of all samples of KIO 3 was subjected to both model-fitting and model-free (isoconversional) kinetic methods of analysis. It has been observed that the activation energy values are independent of the particle size. Isothermal model-fitting analysis shows that the thermal decomposition kinetics of all the samples of KIO 3 studied can be best described by the contracting cube equation.","downloadable_attachments":[{"id":84553579,"asset_id":77048818,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":331684,"first_name":"MP","last_name":"Kannan","domain_name":"calicutuniversity","page_name":"MPKannan","display_name":"MP Kannan","profile_url":"https://calicutuniversity.academia.edu/MPKannan?f_ri=483677","photo":"https://0.academia-photos.com/331684/149680753/139252901/s65_mp.kannan.jpeg"}],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=483677","nofollow":true},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677","nofollow":true},{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=483677","nofollow":true},{"id":160656,"name":"Potassium","url":"https://www.academia.edu/Documents/in/Potassium?f_ri=483677"},{"id":174347,"name":"Thermal","url":"https://www.academia.edu/Documents/in/Thermal?f_ri=483677"},{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677"},{"id":396853,"name":"Differential Thermal Analysis","url":"https://www.academia.edu/Documents/in/Differential_Thermal_Analysis?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":963709,"name":"Mass Loss","url":"https://www.academia.edu/Documents/in/Mass_Loss?f_ri=483677"},{"id":1523571,"name":"Iodate","url":"https://www.academia.edu/Documents/in/Iodate?f_ri=483677"},{"id":2726782,"name":"Thermal Analysis and Calorimetry","url":"https://www.academia.edu/Documents/in/Thermal_Analysis_and_Calorimetry?f_ri=483677"},{"id":3505420,"name":"Model fitting","url":"https://www.academia.edu/Documents/in/Model_fitting?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_22961418" data-work_id="22961418" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/22961418/Thermal_decomposition_and_kinetic_analysis_of_sodium_propoxides">Thermal decomposition and kinetic analysis of sodium propoxides</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Sodium n-propoxide and sodium iso-propoxides were synthesized and characterized. Thermal decomposition of these compounds was studied using thermogravimetric technique (TGA) coupled with mass spectrometry (MS) under non-isothermal and... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_22961418" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Sodium n-propoxide and sodium iso-propoxides were synthesized and characterized. Thermal decomposition of these compounds was studied using thermogravimetric technique (TGA) coupled with mass spectrometry (MS) under non-isothermal and isothermal conditions. Various analytical techniques namely atomic emission spectroscopy (AES), infrared spectroscopy (IR), powder X-ray diffraction (XRD), elemental and volumetric analyses were employed to characterize these compounds and their decomposition residues. Kinetic parameters, namely, the activation energy and pre-exponential factor were deduced from the dynamic TGA and MS data. The activation energies derived from isothermal runs for the thermal decomposition of sodium n-propoxide and sodium iso-propoxide were 151.45 ± 2.16 and 128.07 ± 3.44 kJ mol À1 , respectively. Decomposition of sodium n-propoxide and sodium iso-propoxide results in the formation of gaseous products of saturated and unsaturated hydrocarbons leaving behind residue consisting of sodium carbonate, sodium hydroxide and free carbon.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/22961418" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="59dd84bec2ba214b30f1787428e2e832" rel="nofollow" data-download="{"attachment_id":43482868,"asset_id":22961418,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/43482868/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="44665398" href="https://independent.academia.edu/KChandran1">K. 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Thermal decomposition of these compounds was studied using thermogravimetric technique (TGA) coupled with mass spectrometry (MS) under non-isothermal and isothermal conditions. Various analytical techniques namely atomic emission spectroscopy (AES), infrared spectroscopy (IR), powder X-ray diffraction (XRD), elemental and volumetric analyses were employed to characterize these compounds and their decomposition residues. Kinetic parameters, namely, the activation energy and pre-exponential factor were deduced from the dynamic TGA and MS data. The activation energies derived from isothermal runs for the thermal decomposition of sodium n-propoxide and sodium iso-propoxide were 151.45 ± 2.16 and 128.07 ± 3.44 kJ mol À1 , respectively. Decomposition of sodium n-propoxide and sodium iso-propoxide results in the formation of gaseous products of saturated and unsaturated hydrocarbons leaving behind residue consisting of sodium carbonate, sodium hydroxide and free carbon.","downloadable_attachments":[{"id":43482868,"asset_id":22961418,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":44665398,"first_name":"K.","last_name":"Chandran","domain_name":"independent","page_name":"KChandran1","display_name":"K. Chandran","profile_url":"https://independent.academia.edu/KChandran1?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true},{"id":5769,"name":"Mass Spectrometry","url":"https://www.academia.edu/Documents/in/Mass_Spectrometry?f_ri=483677","nofollow":true},{"id":21423,"name":"Nuclear Materials","url":"https://www.academia.edu/Documents/in/Nuclear_Materials?f_ri=483677","nofollow":true},{"id":44507,"name":"Nuclear","url":"https://www.academia.edu/Documents/in/Nuclear?f_ri=483677","nofollow":true},{"id":78842,"name":"Infrared spectroscopy","url":"https://www.academia.edu/Documents/in/Infrared_spectroscopy?f_ri=483677"},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677"},{"id":198733,"name":"Powder X-Ray Diffraction","url":"https://www.academia.edu/Documents/in/Powder_X-Ray_Diffraction?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":845690,"name":"Sodium Hydroxide","url":"https://www.academia.edu/Documents/in/Sodium_Hydroxide?f_ri=483677"},{"id":1167882,"name":"Kinetic Parameter","url":"https://www.academia.edu/Documents/in/Kinetic_Parameter?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_19811081" data-work_id="19811081" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/19811081/Analysis_of_different_kinetic_models_in_the_dynamic_pyrolysis_of_cellulose">Analysis of different kinetic models in the dynamic pyrolysis of cellulose</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The kinetics of the thermal decomposition of cellulose in nitrogen were studied using dynamic TG at heating rates between 5 and 50 K min-]. The most widely used models found in the literature which are usually applied in isothermal... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_19811081" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The kinetics of the thermal decomposition of cellulose in nitrogen were studied using dynamic TG at heating rates between 5 and 50 K min-]. The most widely used models found in the literature which are usually applied in isothermal conditions were tested. Important differences were found between models that take into account the formation of an activated cellulose and those that assume the direct decomposition of cellulose to char, tar and gases. The best agreement between experimental and calculated values was found with models which consider the formation of activated cellulose and take into account the different behaviour at low and high temperatures.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/19811081" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="6d3c63525e8277a47fa5e1b771dae125" rel="nofollow" data-download="{"attachment_id":40858501,"asset_id":19811081,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40858501/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="40562392" href="https://alicante.academia.edu/JuanConesa">Juan Conesa</a><script data-card-contents-for-user="40562392" type="text/json">{"id":40562392,"first_name":"Juan","last_name":"Conesa","domain_name":"alicante","page_name":"JuanConesa","display_name":"Juan Conesa","profile_url":"https://alicante.academia.edu/JuanConesa?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_19811081 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="19811081"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 19811081, container: ".js-paper-rank-work_19811081", }); 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$(".js-view-count[data-work-id=19811081]").text(description); $(".js-view-count-work_19811081").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_19811081").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="19811081"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">8</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4987" rel="nofollow" href="https://www.academia.edu/Documents/in/Kinetics">Kinetics</a>, <script data-card-contents-for-ri="4987" type="text/json">{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="147640" rel="nofollow" href="https://www.academia.edu/Documents/in/Activation_Energy">Activation Energy</a>, <script data-card-contents-for-ri="147640" type="text/json">{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="151091" rel="nofollow" href="https://www.academia.edu/Documents/in/Nitrogen">Nitrogen</a><script data-card-contents-for-ri="151091" type="text/json">{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=19811081]'), work: {"id":19811081,"title":"Analysis of different kinetic models in the dynamic pyrolysis of cellulose","created_at":"2015-12-23T23:07:00.573-08:00","url":"https://www.academia.edu/19811081/Analysis_of_different_kinetic_models_in_the_dynamic_pyrolysis_of_cellulose?f_ri=483677","dom_id":"work_19811081","summary":"The kinetics of the thermal decomposition of cellulose in nitrogen were studied using dynamic TG at heating rates between 5 and 50 K min-]. The most widely used models found in the literature which are usually applied in isothermal conditions were tested. Important differences were found between models that take into account the formation of an activated cellulose and those that assume the direct decomposition of cellulose to char, tar and gases. The best agreement between experimental and calculated values was found with models which consider the formation of activated cellulose and take into account the different behaviour at low and high temperatures.","downloadable_attachments":[{"id":40858501,"asset_id":19811081,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":40562392,"first_name":"Juan","last_name":"Conesa","domain_name":"alicante","page_name":"JuanConesa","display_name":"Juan Conesa","profile_url":"https://alicante.academia.edu/JuanConesa?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677","nofollow":true},{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=483677","nofollow":true},{"id":191117,"name":"High Temperature","url":"https://www.academia.edu/Documents/in/High_Temperature?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":835697,"name":"Lumping Kinetic Model","url":"https://www.academia.edu/Documents/in/Lumping_Kinetic_Model?f_ri=483677"},{"id":1120502,"name":"Experimental Data","url":"https://www.academia.edu/Documents/in/Experimental_Data?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_69347693" data-work_id="69347693" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/69347693/Thermogravimetric_and_calorimetric_evaluation_of_babassu_biodiesel_obtained_by_the_methanol_route">Thermogravimetric and calorimetric evaluation of babassu biodiesel obtained by the methanol route</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The growing petroleum deficit requires the development of alternative fuel sources. Biodiesel is a good alternative, as it is a biodegradable and renewable product, which obeys the carbon cycle. In this work, the biodiesel from babassu... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_69347693" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The growing petroleum deficit requires the development of alternative fuel sources. Biodiesel is a good alternative, as it is a biodegradable and renewable product, which obeys the carbon cycle. In this work, the biodiesel from babassu was synthesized using the methanol route, and characterized by physico-chemical analyses in order to make able the investigated biodiesel to fulfill with its properties the requirements of Brazilian National Agency for Petroleum, Natural Gas and Biofuel (ANP). Besides gas chromatography, IR spectroscopy experiments and thermoanalytical measurements in air and in nitrogen were done to determine the main thermal decomposition processes and calorimetric events. The evaporation temperature of babassu biodiesel was similar in both atmospheres, started around 52 in air and around 60°C in nitrogen.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/69347693" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="25628befcd1e3ac4a3917a4a6f364c24" rel="nofollow" data-download="{"attachment_id":79479286,"asset_id":69347693,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/79479286/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="123237098" href="https://ufpb.academia.edu/IedadosSantos">Ieda dos Santos</a><script data-card-contents-for-user="123237098" type="text/json">{"id":123237098,"first_name":"Ieda","last_name":"dos Santos","domain_name":"ufpb","page_name":"IedadosSantos","display_name":"Ieda dos Santos","profile_url":"https://ufpb.academia.edu/IedadosSantos?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_69347693 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="69347693"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 69347693, container: ".js-paper-rank-work_69347693", }); 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$(".js-view-count[data-work-id=69347693]").text(description); $(".js-view-count-work_69347693").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_69347693").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="69347693"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">17</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="7892" rel="nofollow" href="https://www.academia.edu/Documents/in/Biodiesel">Biodiesel</a>, <script data-card-contents-for-ri="7892" type="text/json">{"id":7892,"name":"Biodiesel","url":"https://www.academia.edu/Documents/in/Biodiesel?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="14719" rel="nofollow" href="https://www.academia.edu/Documents/in/Carbon_Cycle">Carbon Cycle</a>, <script data-card-contents-for-ri="14719" type="text/json">{"id":14719,"name":"Carbon Cycle","url":"https://www.academia.edu/Documents/in/Carbon_Cycle?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="59128" rel="nofollow" href="https://www.academia.edu/Documents/in/Natural_Gas">Natural Gas</a>, <script data-card-contents-for-ri="59128" type="text/json">{"id":59128,"name":"Natural Gas","url":"https://www.academia.edu/Documents/in/Natural_Gas?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="86176" rel="nofollow" href="https://www.academia.edu/Documents/in/Alcohol">Alcohol</a><script data-card-contents-for-ri="86176" type="text/json">{"id":86176,"name":"Alcohol","url":"https://www.academia.edu/Documents/in/Alcohol?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=69347693]'), work: {"id":69347693,"title":"Thermogravimetric and calorimetric evaluation of babassu biodiesel obtained by the methanol route","created_at":"2022-01-24T04:53:36.704-08:00","url":"https://www.academia.edu/69347693/Thermogravimetric_and_calorimetric_evaluation_of_babassu_biodiesel_obtained_by_the_methanol_route?f_ri=483677","dom_id":"work_69347693","summary":"The growing petroleum deficit requires the development of alternative fuel sources. Biodiesel is a good alternative, as it is a biodegradable and renewable product, which obeys the carbon cycle. In this work, the biodiesel from babassu was synthesized using the methanol route, and characterized by physico-chemical analyses in order to make able the investigated biodiesel to fulfill with its properties the requirements of Brazilian National Agency for Petroleum, Natural Gas and Biofuel (ANP). Besides gas chromatography, IR spectroscopy experiments and thermoanalytical measurements in air and in nitrogen were done to determine the main thermal decomposition processes and calorimetric events. The evaporation temperature of babassu biodiesel was similar in both atmospheres, started around 52 in air and around 60°C in nitrogen.","downloadable_attachments":[{"id":79479286,"asset_id":69347693,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":123237098,"first_name":"Ieda","last_name":"dos Santos","domain_name":"ufpb","page_name":"IedadosSantos","display_name":"Ieda dos Santos","profile_url":"https://ufpb.academia.edu/IedadosSantos?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":7892,"name":"Biodiesel","url":"https://www.academia.edu/Documents/in/Biodiesel?f_ri=483677","nofollow":true},{"id":14719,"name":"Carbon Cycle","url":"https://www.academia.edu/Documents/in/Carbon_Cycle?f_ri=483677","nofollow":true},{"id":59128,"name":"Natural Gas","url":"https://www.academia.edu/Documents/in/Natural_Gas?f_ri=483677","nofollow":true},{"id":86176,"name":"Alcohol","url":"https://www.academia.edu/Documents/in/Alcohol?f_ri=483677","nofollow":true},{"id":93647,"name":"Biofuel","url":"https://www.academia.edu/Documents/in/Biofuel?f_ri=483677"},{"id":112334,"name":"Methanol","url":"https://www.academia.edu/Documents/in/Methanol?f_ri=483677"},{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=483677"},{"id":166448,"name":"Gas Chromatography","url":"https://www.academia.edu/Documents/in/Gas_Chromatography?f_ri=483677"},{"id":174347,"name":"Thermal","url":"https://www.academia.edu/Documents/in/Thermal?f_ri=483677"},{"id":187424,"name":"Alternative Fuel","url":"https://www.academia.edu/Documents/in/Alternative_Fuel?f_ri=483677"},{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677"},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677"},{"id":448421,"name":"IR Spectroscopy","url":"https://www.academia.edu/Documents/in/IR_Spectroscopy?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":677739,"name":"Calorimetry","url":"https://www.academia.edu/Documents/in/Calorimetry?f_ri=483677"},{"id":907359,"name":"Infrared Spectrometry","url":"https://www.academia.edu/Documents/in/Infrared_Spectrometry?f_ri=483677"},{"id":2726782,"name":"Thermal Analysis and Calorimetry","url":"https://www.academia.edu/Documents/in/Thermal_Analysis_and_Calorimetry?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_22975037" data-work_id="22975037" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/22975037/An_ablation_model_for_the_thermal_decomposition_of_porous_zinc_oxide_layer_heated_by_concentrated_solar_radiation">An ablation model for the thermal decomposition of porous zinc oxide layer heated by concentrated solar radiation</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Thermal decomposition of porous ZnO under high-flux solar irradiation is considered. The process is well described by a transient ablation model that couples radiation, conduction, and convection heat transfer to an Arrhenius-type kinetic... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_22975037" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Thermal decomposition of porous ZnO under high-flux solar irradiation is considered. The process is well described by a transient ablation model that couples radiation, conduction, and convection heat transfer to an Arrhenius-type kinetic rate law with a pre-exponential factor dependent on the porosity, grain/pore size, and convective removal of the reaction products Zn(g) and O 2 . Main model parameters are determined by comparing numerical and experimental results.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/22975037" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="530317d288997b6bc7338efd2e405d9c" rel="nofollow" data-download="{"attachment_id":43495712,"asset_id":22975037,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/43495712/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="44430224" href="https://independent.academia.edu/LDombrovsky">Leonid Dombrovsky</a><script data-card-contents-for-user="44430224" type="text/json">{"id":44430224,"first_name":"Leonid","last_name":"Dombrovsky","domain_name":"independent","page_name":"LDombrovsky","display_name":"Leonid Dombrovsky","profile_url":"https://independent.academia.edu/LDombrovsky?f_ri=483677","photo":"https://0.academia-photos.com/44430224/11877057/13236041/s65_leonid.dombrovsky.jpg"}</script></span></span></li><li class="js-paper-rank-work_22975037 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="22975037"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 22975037, container: ".js-paper-rank-work_22975037", }); 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The process is well described by a transient ablation model that couples radiation, conduction, and convection heat transfer to an Arrhenius-type kinetic rate law with a pre-exponential factor dependent on the porosity, grain/pore size, and convective removal of the reaction products Zn(g) and O 2 . Main model parameters are determined by comparing numerical and experimental results.","downloadable_attachments":[{"id":43495712,"asset_id":22975037,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":44430224,"first_name":"Leonid","last_name":"Dombrovsky","domain_name":"independent","page_name":"LDombrovsky","display_name":"Leonid Dombrovsky","profile_url":"https://independent.academia.edu/LDombrovsky?f_ri=483677","photo":"https://0.academia-photos.com/44430224/11877057/13236041/s65_leonid.dombrovsky.jpg"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":8067,"name":"Heat Transfer","url":"https://www.academia.edu/Documents/in/Heat_Transfer?f_ri=483677","nofollow":true},{"id":33661,"name":"Heat and Mass Transfer","url":"https://www.academia.edu/Documents/in/Heat_and_Mass_Transfer?f_ri=483677","nofollow":true},{"id":58032,"name":"Zinc Oxide","url":"https://www.academia.edu/Documents/in/Zinc_Oxide?f_ri=483677"},{"id":63431,"name":"Solar Energy","url":"https://www.academia.edu/Documents/in/Solar_Energy?f_ri=483677"},{"id":80414,"name":"Mathematical Sciences","url":"https://www.academia.edu/Documents/in/Mathematical_Sciences?f_ri=483677"},{"id":118582,"name":"Physical sciences","url":"https://www.academia.edu/Documents/in/Physical_sciences?f_ri=483677"},{"id":139273,"name":"Pore Size","url":"https://www.academia.edu/Documents/in/Pore_Size?f_ri=483677"},{"id":284947,"name":"Solar radiation","url":"https://www.academia.edu/Documents/in/Solar_radiation?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":661889,"name":"Convective Heat Transfer","url":"https://www.academia.edu/Documents/in/Convective_Heat_Transfer?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_22525173" data-work_id="22525173" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/22525173/Electrochromism_in_nickel_oxide_films_obtained_by_thermal_decomposition">Electrochromism in nickel oxide films obtained by thermal decomposition</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Nickel hydroxide is a well-studied material due to its use as the positive electrode in batteries . More recently, interest has been ruled out to the electrochromic properties of coatings of this material . Electrochromism is a reversible... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_22525173" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Nickel hydroxide is a well-studied material due to its use as the positive electrode in batteries . More recently, interest has been ruled out to the electrochromic properties of coatings of this material . Electrochromism is a reversible colour change that is promoted in a thin film by the injection or ejection of mobile ion (see, for example ). Nickel oxide bleaches cathodically, i.e. the bleached states are obtained from reduction reactions in which the intercalation of positive ions (H--, Li ÷ and Na ÷) is promoted by the application of an electric field . The coloured states are obtained in the oxidation process, during the deintercalation of the positive ions. Potential technological applications of electrochromic materials are in energy-efficient "smart windows" with controllable throughput of radiant energy, mirrors with variable reflectance and high-contrast non-emissive information displays [6-81.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/22525173" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="e8b62718f958cd04079cc13f807f48a3" rel="nofollow" data-download="{"attachment_id":43140071,"asset_id":22525173,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/43140071/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="44044564" href="https://independent.academia.edu/UrbanoAlexandre">Alexandre Urbano</a><script data-card-contents-for-user="44044564" type="text/json">{"id":44044564,"first_name":"Alexandre","last_name":"Urbano","domain_name":"independent","page_name":"UrbanoAlexandre","display_name":"Alexandre Urbano","profile_url":"https://independent.academia.edu/UrbanoAlexandre?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_22525173 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="22525173"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 22525173, container: ".js-paper-rank-work_22525173", }); 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More recently, interest has been ruled out to the electrochromic properties of coatings of this material . Electrochromism is a reversible colour change that is promoted in a thin film by the injection or ejection of mobile ion (see, for example ). Nickel oxide bleaches cathodically, i.e. the bleached states are obtained from reduction reactions in which the intercalation of positive ions (H--, Li ÷ and Na ÷) is promoted by the application of an electric field . The coloured states are obtained in the oxidation process, during the deintercalation of the positive ions. Potential technological applications of electrochromic materials are in energy-efficient \"smart windows\" with controllable throughput of radiant energy, mirrors with variable reflectance and high-contrast non-emissive information displays [6-81.","downloadable_attachments":[{"id":43140071,"asset_id":22525173,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":44044564,"first_name":"Alexandre","last_name":"Urbano","domain_name":"independent","page_name":"UrbanoAlexandre","display_name":"Alexandre Urbano","profile_url":"https://independent.academia.edu/UrbanoAlexandre?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true},{"id":792383,"name":"Nickel Oxide","url":"https://www.academia.edu/Documents/in/Nickel_Oxide?f_ri=483677","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_7584366" data-work_id="7584366" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/7584366/Hydrogen_release_from_solid_state_NaBH_4">Hydrogen release from solid state NaBH 4</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest">Ab initio calculations Calphad Thermal decomposition a b s t r a c t</div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item 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href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="104345" rel="nofollow" href="https://www.academia.edu/Documents/in/Hydrogen_Energy">Hydrogen Energy</a>, <script data-card-contents-for-ri="104345" type="text/json">{"id":104345,"name":"Hydrogen Energy","url":"https://www.academia.edu/Documents/in/Hydrogen_Energy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="260118" rel="nofollow" href="https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES">CHEMICAL SCIENCES</a>, <script data-card-contents-for-ri="260118" type="text/json">{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677","nofollow":true}</script><a 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t","downloadable_attachments":[{"id":48412019,"asset_id":7584366,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":13663898,"first_name":"Marcello","last_name":"Baricco","domain_name":"unito","page_name":"MarcelloBaricco","display_name":"Marcello Baricco","profile_url":"https://unito.academia.edu/MarcelloBaricco?f_ri=483677","photo":"https://0.academia-photos.com/13663898/4286823/4984607/s65_marcello.baricco.jpg"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":104345,"name":"Hydrogen Energy","url":"https://www.academia.edu/Documents/in/Hydrogen_Energy?f_ri=483677","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677","nofollow":true},{"id":308420,"name":"Phase Transformation","url":"https://www.academia.edu/Documents/in/Phase_Transformation?f_ri=483677","nofollow":true},{"id":386527,"name":"X ray diffraction","url":"https://www.academia.edu/Documents/in/X_ray_diffraction?f_ri=483677"},{"id":391252,"name":"Room Temperature","url":"https://www.academia.edu/Documents/in/Room_Temperature?f_ri=483677"},{"id":394503,"name":"Thermal Treatment","url":"https://www.academia.edu/Documents/in/Thermal_Treatment?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":1114938,"name":"Ab Initio Calculation","url":"https://www.academia.edu/Documents/in/Ab_Initio_Calculation?f_ri=483677"},{"id":1247851,"name":"Experimental Method","url":"https://www.academia.edu/Documents/in/Experimental_Method?f_ri=483677"},{"id":1256879,"name":"Thermodynamic Properties","url":"https://www.academia.edu/Documents/in/Thermodynamic_Properties?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_22257410" data-work_id="22257410" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/22257410/TG_MS_TG_DTG_AND_DTA_METHODS_IN_STUDY_OF_THERMAL_DECOMPOSITION_OF_SOME_d_METAL_COMPLEXES_WITH_4_4_BPY_AND_PROPIONATES">TG-MS, TG, DTG AND DTA METHODS IN STUDY OF THERMAL DECOMPOSITION OF SOME d-METAL COMPLEXES WITH 4,4-BPY AND PROPIONATES</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The new mixed ligand complexes with formulae M(4-bpy)(C 2 H 5 COO) 2 ·2H 2 O (where M(II)=Mn, Co, Ni; and Cu(4-bpy) 0.5 (C 2 H 5 COO) 2 ·H 2 O were prepared and characterized by VIS (for solid compounds of Co(II), Ni(II), Cu(II) in... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_22257410" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The new mixed ligand complexes with formulae M(4-bpy)(C 2 H 5 COO) 2 ·2H 2 O (where M(II)=Mn, Co, Ni; and Cu(4-bpy) 0.5 (C 2 H 5 COO) 2 ·H 2 O were prepared and characterized by VIS (for solid compounds of Co(II), Ni(II), Cu(II) in Nujol), IR spectroscopy, X-ray powder diffraction and molar conductance in MeOH, DMF or DMSO. Thermal behaviour of complexes was studied under static conditions in air atmosphere. Corresponding metal oxides were identified as final products of pyrolysis. A coupled TG-MS system was used to analysis of principal volatile thermal decomposition and fragmentation products of isolated complexes under dynamic air and argon atmosphere. The principal species correspond to: C + , OH + , H 2 O + , NO + , CO 2 + and other; additionally CO + in argon atmosphere.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/22257410" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="abb63839e5984c3306c4577c01244644" rel="nofollow" data-download="{"attachment_id":42907267,"asset_id":22257410,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/42907267/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="43638480" href="https://independent.academia.edu/AgnieszkaCzylkowska">Agnieszka Czylkowska</a><script data-card-contents-for-user="43638480" type="text/json">{"id":43638480,"first_name":"Agnieszka","last_name":"Czylkowska","domain_name":"independent","page_name":"AgnieszkaCzylkowska","display_name":"Agnieszka Czylkowska","profile_url":"https://independent.academia.edu/AgnieszkaCzylkowska?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_22257410 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="22257410"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 22257410, container: ".js-paper-rank-work_22257410", }); 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$(".js-view-count[data-work-id=22257410]").text(description); $(".js-view-count-work_22257410").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_22257410").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="22257410"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">5</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="94870" rel="nofollow" href="https://www.academia.edu/Documents/in/Metal_Complexes">Metal Complexes</a>, <script data-card-contents-for-ri="94870" type="text/json">{"id":94870,"name":"Metal Complexes","url":"https://www.academia.edu/Documents/in/Metal_Complexes?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="406753" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_behaviour_of_buildings">Thermal behaviour of buildings</a>, <script data-card-contents-for-ri="406753" type="text/json">{"id":406753,"name":"Thermal behaviour of buildings","url":"https://www.academia.edu/Documents/in/Thermal_behaviour_of_buildings?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="448421" rel="nofollow" href="https://www.academia.edu/Documents/in/IR_Spectroscopy">IR Spectroscopy</a>, <script data-card-contents-for-ri="448421" type="text/json">{"id":448421,"name":"IR Spectroscopy","url":"https://www.academia.edu/Documents/in/IR_Spectroscopy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="483677" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_Decomposition">Thermal Decomposition</a><script data-card-contents-for-ri="483677" type="text/json">{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=22257410]'), work: {"id":22257410,"title":"TG-MS, TG, DTG AND DTA METHODS IN STUDY OF THERMAL DECOMPOSITION OF SOME d-METAL COMPLEXES WITH 4,4-BPY AND PROPIONATES","created_at":"2016-02-21T10:33:16.102-08:00","url":"https://www.academia.edu/22257410/TG_MS_TG_DTG_AND_DTA_METHODS_IN_STUDY_OF_THERMAL_DECOMPOSITION_OF_SOME_d_METAL_COMPLEXES_WITH_4_4_BPY_AND_PROPIONATES?f_ri=483677","dom_id":"work_22257410","summary":"The new mixed ligand complexes with formulae M(4-bpy)(C 2 H 5 COO) 2 ·2H 2 O (where M(II)=Mn, Co, Ni; and Cu(4-bpy) 0.5 (C 2 H 5 COO) 2 ·H 2 O were prepared and characterized by VIS (for solid compounds of Co(II), Ni(II), Cu(II) in Nujol), IR spectroscopy, X-ray powder diffraction and molar conductance in MeOH, DMF or DMSO. Thermal behaviour of complexes was studied under static conditions in air atmosphere. Corresponding metal oxides were identified as final products of pyrolysis. A coupled TG-MS system was used to analysis of principal volatile thermal decomposition and fragmentation products of isolated complexes under dynamic air and argon atmosphere. The principal species correspond to: C + , OH + , H 2 O + , NO + , CO 2 + and other; additionally CO + in argon atmosphere.","downloadable_attachments":[{"id":42907267,"asset_id":22257410,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":43638480,"first_name":"Agnieszka","last_name":"Czylkowska","domain_name":"independent","page_name":"AgnieszkaCzylkowska","display_name":"Agnieszka Czylkowska","profile_url":"https://independent.academia.edu/AgnieszkaCzylkowska?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":94870,"name":"Metal Complexes","url":"https://www.academia.edu/Documents/in/Metal_Complexes?f_ri=483677","nofollow":true},{"id":406753,"name":"Thermal behaviour of buildings","url":"https://www.academia.edu/Documents/in/Thermal_behaviour_of_buildings?f_ri=483677","nofollow":true},{"id":448421,"name":"IR Spectroscopy","url":"https://www.academia.edu/Documents/in/IR_Spectroscopy?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true},{"id":2240987,"name":"X ray powder diffraction","url":"https://www.academia.edu/Documents/in/X_ray_powder_diffraction?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_48511301" data-work_id="48511301" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/48511301/Simple_method_for_prediction_of_activation_energies_of_the_thermal_decomposition_of_nitramines">Simple method for prediction of activation energies of the thermal decomposition of nitramines</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A novel general method has been introduced to predict activation energies of thermal decomposition of nitramines as an important class of energetic compounds. It is shown that the activation energies of acyclic nitramines can be expressed... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_48511301" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A novel general method has been introduced to predict activation energies of thermal decomposition of nitramines as an important class of energetic compounds. It is shown that the activation energies of acyclic nitramines can be expressed as a function of optimized elemental composition. The resultant relationship as a core correlation can be corrected for cyclic nitramines that contain more than five member ring. R 2 value or the coefficient of determination of the new correlation is 0.94. The new correlation has the root mean square (rms) and the average deviations of 5.67 and 3.98 kJ/mol, respectively, for 14 nitramines with different molecular structures. The new method is also tested for some cyclic and acyclic nitramines with complex molecular structures, e.g. two new nitramines 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW) and 4,10-dinitro-2,4,6-tetroxa-4,10diaazaisowurtzitane (TEX), so that it can predict relatively good results as compared to the experimental values.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/48511301" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="6236afd3ec37305742a5163c6b51eccb" rel="nofollow" data-download="{"attachment_id":67085423,"asset_id":48511301,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/67085423/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="50444254" href="https://independent.academia.edu/MohammadHosseinKeshavarz">Mohammad Hossein Keshavarz</a><script data-card-contents-for-user="50444254" type="text/json">{"id":50444254,"first_name":"Mohammad Hossein","last_name":"Keshavarz","domain_name":"independent","page_name":"MohammadHosseinKeshavarz","display_name":"Mohammad Hossein Keshavarz","profile_url":"https://independent.academia.edu/MohammadHosseinKeshavarz?f_ri=483677","photo":"https://0.academia-photos.com/50444254/26759655/25245514/s65_mohammad_hossein.keshavarz.jpg"}</script></span></span></li><li class="js-paper-rank-work_48511301 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="48511301"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 48511301, container: ".js-paper-rank-work_48511301", }); 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It is shown that the activation energies of acyclic nitramines can be expressed as a function of optimized elemental composition. The resultant relationship as a core correlation can be corrected for cyclic nitramines that contain more than five member ring. R 2 value or the coefficient of determination of the new correlation is 0.94. The new correlation has the root mean square (rms) and the average deviations of 5.67 and 3.98 kJ/mol, respectively, for 14 nitramines with different molecular structures. The new method is also tested for some cyclic and acyclic nitramines with complex molecular structures, e.g. two new nitramines 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW) and 4,10-dinitro-2,4,6-tetroxa-4,10diaazaisowurtzitane (TEX), so that it can predict relatively good results as compared to the experimental values.","downloadable_attachments":[{"id":67085423,"asset_id":48511301,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":50444254,"first_name":"Mohammad Hossein","last_name":"Keshavarz","domain_name":"independent","page_name":"MohammadHosseinKeshavarz","display_name":"Mohammad Hossein Keshavarz","profile_url":"https://independent.academia.edu/MohammadHosseinKeshavarz?f_ri=483677","photo":"https://0.academia-photos.com/50444254/26759655/25245514/s65_mohammad_hossein.keshavarz.jpg"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":7968,"name":"Prediction","url":"https://www.academia.edu/Documents/in/Prediction?f_ri=483677","nofollow":true},{"id":49161,"name":"Safety","url":"https://www.academia.edu/Documents/in/Safety?f_ri=483677","nofollow":true},{"id":81504,"name":"Correlation","url":"https://www.academia.edu/Documents/in/Correlation?f_ri=483677","nofollow":true},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677"},{"id":149625,"name":"Hazardous Materials","url":"https://www.academia.edu/Documents/in/Hazardous_Materials?f_ri=483677"},{"id":168891,"name":"Chemical Analysis","url":"https://www.academia.edu/Documents/in/Chemical_Analysis?f_ri=483677"},{"id":181597,"name":"Root-Mean Square Error","url":"https://www.academia.edu/Documents/in/Root-Mean_Square_Error?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":611815,"name":"Coefficient of Determination","url":"https://www.academia.edu/Documents/in/Coefficient_of_Determination?f_ri=483677"},{"id":1724844,"name":"Molecular Structure","url":"https://www.academia.edu/Documents/in/Molecular_Structure?f_ri=483677"},{"id":1782947,"name":"aniline Compounds","url":"https://www.academia.edu/Documents/in/aniline_Compounds?f_ri=483677"},{"id":3794076,"name":"Elemental composition","url":"https://www.academia.edu/Documents/in/Elemental_composition?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_5856303" data-work_id="5856303" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/5856303/Poly_vinyl_alcohol_and_poly_vinyl_pyrrolidone_blended_films_for_local_nitric_oxide_release">Poly(vinyl alcohol) and poly(vinyl pyrrolidone) blended films for local nitric oxide release</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The nitric oxide (NO) donor S-nitrosoglutathione (GSNO) was incorporated in solid polymeric films of poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP) and blended PVA/PVP. These matrices were found to provide a great stabilization... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_5856303" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The nitric oxide (NO) donor S-nitrosoglutathione (GSNO) was incorporated in solid polymeric films of poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP) and blended PVA/PVP. These matrices were found to provide a great stabilization effect on the thermal decomposition of GSNO, leading to 8-16-fold reduction in the first-order rate constants of NO release, compared to aqueous GSNO solutions. PVA/PVP-GSNO released 90% of the NO supply, over a time period of 24 h at 37 C. Differential scanning calorimetry has confirmed the miscibility between the two polymeric components. Stress-strain analysis has shown an improvement of the mechanical property of PVA films in the PVA/PVP blend, which leads to an increase of 25% in the stress at break. Scanning electron microscopy has shown that the PVA/PVP-GSNO blend leads to a smooth coating of metallic surfaces. These properties, allied to the already known good biocompatibility of PVA and PVP, makes GSNO-containing PVA and PVA/ PVP blend films good candidates for the local and controlled release of NO in target areas. r</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/5856303" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="a730a4d30cfe136762ebeac61ffb655b" rel="nofollow" data-download="{"attachment_id":49109874,"asset_id":5856303,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49109874/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="8632244" href="https://independent.academia.edu/MarceloOliveira10">Marcelo Oliveira</a><script data-card-contents-for-user="8632244" type="text/json">{"id":8632244,"first_name":"Marcelo","last_name":"Oliveira","domain_name":"independent","page_name":"MarceloOliveira10","display_name":"Marcelo Oliveira","profile_url":"https://independent.academia.edu/MarceloOliveira10?f_ri=483677","photo":"https://0.academia-photos.com/8632244/9321083/10388928/s65_marcelo.oliveira.jpg_oh_54f5bc709e80661c967ce32a5a92bae1_oe_5608658a___gda___1442805558_f4b68f3641c55e22a1ece0fdd27f7c84"}</script></span></span></li><li class="js-paper-rank-work_5856303 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="5856303"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 5856303, container: ".js-paper-rank-work_5856303", }); 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These matrices were found to provide a great stabilization effect on the thermal decomposition of GSNO, leading to 8-16-fold reduction in the first-order rate constants of NO release, compared to aqueous GSNO solutions. PVA/PVP-GSNO released 90% of the NO supply, over a time period of 24 h at 37 C. Differential scanning calorimetry has confirmed the miscibility between the two polymeric components. Stress-strain analysis has shown an improvement of the mechanical property of PVA films in the PVA/PVP blend, which leads to an increase of 25% in the stress at break. Scanning electron microscopy has shown that the PVA/PVP-GSNO blend leads to a smooth coating of metallic surfaces. These properties, allied to the already known good biocompatibility of PVA and PVP, makes GSNO-containing PVA and PVA/ PVP blend films good candidates for the local and controlled release of NO in target areas. r","downloadable_attachments":[{"id":49109874,"asset_id":5856303,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":8632244,"first_name":"Marcelo","last_name":"Oliveira","domain_name":"independent","page_name":"MarceloOliveira10","display_name":"Marcelo 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itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/6345614/Thermal_decomposition_of_RDX_BAMO_pseudo_propellants">Thermal decomposition of RDX/BAMO pseudo-propellants</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Measurements of gaseous species and temperature profiles for RDX/BAMO pseudo-propellants were performed to study their decomposition and the chemical and physical effects of their binder ingredient, 3,3Ј-bis-azidomethyl-oxetane (BAMO), on... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_6345614" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Measurements of gaseous species and temperature profiles for RDX/BAMO pseudo-propellants were performed to study their decomposition and the chemical and physical effects of their binder ingredient, 3,3Ј-bis-azidomethyl-oxetane (BAMO), on the base ingredient, 1,3,5-trimethylene trinitramine (RDX). The propellants were made from a physical mixture of RDX and BAMO in weight ratio of 80:20. Experiments were conducted at atmospheric pressure in argon with heat fluxes of 100 and 400 W/cm 2 delivered by a CO 2 laser. Gaseous samples were extracted through the use of quartz microprobes and analyzed by a triple quadrupole mass spectrometer (TQMS). Temperature profiles were measured using micro-thermocouple techniques to investigate surface and gas-phase reaction zones identified by the species measurement. Results of species and temperature measurements showed chemical and physical interactions between the two ingredients. From the species measurements, products of each ingredient, RDX and BAMO, were found to exist simultaneously throughout the gas phase; however, primary reaction chemistry in the gas phase was dominated by RDX. Three different categories of gaseous products were identified in the species measurements: species common to both BAMO and RDX; from RDX or BAMO only; and those which can not be attributed to RDX or BAMO alone. Surface temperatures were ϳ640 and ϳ670 K at 100 and 400 W/cm 2 , respectively, while that of RDX was ϳ610 K for both heat fluxes. The temperature profiles showed the existence of an isothermal region in the gas phase, with the temperature of ϳ1200 K at 100 W/cm 2 and ϳ1500 K at 400 W/cm 2 . The effect of BAMO in RDX/BAMO was clearly evident in the change of surface mole fractions and profiles of major species, expansion of reaction zones, and the constant temperature profile in the gas phase.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/6345614" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="e2b4df4e5478b8287908ce9de4db30d4" rel="nofollow" data-download="{"attachment_id":48907847,"asset_id":6345614,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/48907847/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="9896808" href="https://independent.academia.edu/ChingJenTang">Ching-Jen Tang</a><script data-card-contents-for-user="9896808" type="text/json">{"id":9896808,"first_name":"Ching-Jen","last_name":"Tang","domain_name":"independent","page_name":"ChingJenTang","display_name":"Ching-Jen Tang","profile_url":"https://independent.academia.edu/ChingJenTang?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_6345614 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="6345614"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 6345614, container: ".js-paper-rank-work_6345614", }); 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The propellants were made from a physical mixture of RDX and BAMO in weight ratio of 80:20. Experiments were conducted at atmospheric pressure in argon with heat fluxes of 100 and 400 W/cm 2 delivered by a CO 2 laser. Gaseous samples were extracted through the use of quartz microprobes and analyzed by a triple quadrupole mass spectrometer (TQMS). Temperature profiles were measured using micro-thermocouple techniques to investigate surface and gas-phase reaction zones identified by the species measurement. Results of species and temperature measurements showed chemical and physical interactions between the two ingredients. From the species measurements, products of each ingredient, RDX and BAMO, were found to exist simultaneously throughout the gas phase; however, primary reaction chemistry in the gas phase was dominated by RDX. Three different categories of gaseous products were identified in the species measurements: species common to both BAMO and RDX; from RDX or BAMO only; and those which can not be attributed to RDX or BAMO alone. Surface temperatures were ϳ640 and ϳ670 K at 100 and 400 W/cm 2 , respectively, while that of RDX was ϳ610 K for both heat fluxes. The temperature profiles showed the existence of an isothermal region in the gas phase, with the temperature of ϳ1200 K at 100 W/cm 2 and ϳ1500 K at 400 W/cm 2 . The effect of BAMO in RDX/BAMO was clearly evident in the change of surface mole fractions and profiles of major species, expansion of reaction zones, and the constant temperature profile in the gas phase.","downloadable_attachments":[{"id":48907847,"asset_id":6345614,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":9896808,"first_name":"Ching-Jen","last_name":"Tang","domain_name":"independent","page_name":"ChingJenTang","display_name":"Ching-Jen Tang","profile_url":"https://independent.academia.edu/ChingJenTang?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":60,"name":"Mechanical Engineering","url":"https://www.academia.edu/Documents/in/Mechanical_Engineering?f_ri=483677","nofollow":true},{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true},{"id":47297,"name":"Automotive Engineering","url":"https://www.academia.edu/Documents/in/Automotive_Engineering?f_ri=483677","nofollow":true},{"id":133294,"name":"Land Surface Temperature","url":"https://www.academia.edu/Documents/in/Land_Surface_Temperature?f_ri=483677","nofollow":true},{"id":148176,"name":"Atmospheric Pressure","url":"https://www.academia.edu/Documents/in/Atmospheric_Pressure?f_ri=483677"},{"id":201306,"name":"Heat Flux","url":"https://www.academia.edu/Documents/in/Heat_Flux?f_ri=483677"},{"id":243384,"name":"Physical Interaction","url":"https://www.academia.edu/Documents/in/Physical_Interaction?f_ri=483677"},{"id":266485,"name":"Temperature measurement","url":"https://www.academia.edu/Documents/in/Temperature_measurement?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17193638" data-work_id="17193638" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17193638/Electrocatalytic_properties_of_new_spinel_type_MMoO4_M_Fe_Co_and_Ni_electrodes_for_oxygen_evolution_in_alkaline_solutions">Electrocatalytic properties of new spinel-type MMoO4 (M=Fe, Co and Ni) electrodes for oxygen evolution in alkaline solutions</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">New spinel-type oxides with molecular formulae MMoO 4 (M ¼ Fe, Co and Ni) have been prepared by a thermal decomposition method at 650 C and investigated as electrocatalysts for the O 2 evolution reaction (OER) in KOH solutions. The... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17193638" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">New spinel-type oxides with molecular formulae MMoO 4 (M ¼ Fe, Co and Ni) have been prepared by a thermal decomposition method at 650 C and investigated as electrocatalysts for the O 2 evolution reaction (OER) in KOH solutions. The results show that the new oxide electrocatalysts are highly active for the OER, but they have very low electrochemically active areas, the relative oxide roughness factor being <2. The Tafel slope values for the OER on each oxide in 1 M KOH are found to be w40 and w60 mV at low and higher potentials, respectively. The reaction order with respect to OH À concentration has been observed to be 1.18, 1.51 and 1.94 on CoMoO 4 , FeMoO 4 and NiMoO 4 electrodes, respectively. Both in 1 M KOH and practical cell solution (30 wt% KOH) at 25 C, the performance of the FeMoO 4 electrode is observed to be better than the other two electrodes. ª</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17193638" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="12d8a42787ac0f616e7d243db78a1e4c" rel="nofollow" data-download="{"attachment_id":39383456,"asset_id":17193638,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39383456/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36653961" href="https://independent.academia.edu/rajsingh218">raj singh</a><script data-card-contents-for-user="36653961" type="text/json">{"id":36653961,"first_name":"raj","last_name":"singh","domain_name":"independent","page_name":"rajsingh218","display_name":"raj singh","profile_url":"https://independent.academia.edu/rajsingh218?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_17193638 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17193638"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17193638, container: ".js-paper-rank-work_17193638", }); 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The results show that the new oxide electrocatalysts are highly active for the OER, but they have very low electrochemically active areas, the relative oxide roughness factor being \u003c2. The Tafel slope values for the OER on each oxide in 1 M KOH are found to be w40 and w60 mV at low and higher potentials, respectively. The reaction order with respect to OH À concentration has been observed to be 1.18, 1.51 and 1.94 on CoMoO 4 , FeMoO 4 and NiMoO 4 electrodes, respectively. Both in 1 M KOH and practical cell solution (30 wt% KOH) at 25 C, the performance of the FeMoO 4 electrode is observed to be better than the other two electrodes. ª","downloadable_attachments":[{"id":39383456,"asset_id":17193638,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":36653961,"first_name":"raj","last_name":"singh","domain_name":"independent","page_name":"rajsingh218","display_name":"raj singh","profile_url":"https://independent.academia.edu/rajsingh218?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":104345,"name":"Hydrogen Energy","url":"https://www.academia.edu/Documents/in/Hydrogen_Energy?f_ri=483677","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal 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Metal","url":"https://www.academia.edu/Documents/in/Heavy_Metal?f_ri=483677"},{"id":158165,"name":"Zinc","url":"https://www.academia.edu/Documents/in/Zinc?f_ri=483677"},{"id":191117,"name":"High Temperature","url":"https://www.academia.edu/Documents/in/High_Temperature?f_ri=483677"},{"id":394503,"name":"Thermal Treatment","url":"https://www.academia.edu/Documents/in/Thermal_Treatment?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":574053,"name":"Pyrometallurgy","url":"https://www.academia.edu/Documents/in/Pyrometallurgy?f_ri=483677"},{"id":976404,"name":"Reaction Kinetics","url":"https://www.academia.edu/Documents/in/Reaction_Kinetics?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_48601591" data-work_id="48601591" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/48601591/Thermal_Decomposition_of_Silicon_rich_Oxides_Deposited_by_the_LPCVD_Method">Thermal Decomposition of Silicon-rich Oxides Deposited by the LPCVD Method</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Silicon-rich oxide (SiO x , 0 < x < 2) thin films were deposited using the Low Pressure Chemical Vapor Deposition (LPCVD) method at temperature of 570 °C using silane (SiH 4) and oxygen as the reactant gasses. The films were annealed at... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_48601591" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Silicon-rich oxide (SiO x , 0 < x < 2) thin films were deposited using the Low Pressure Chemical Vapor Deposition (LPCVD) method at temperature of 570 °C using silane (SiH 4) and oxygen as the reactant gasses. The films were annealed at temperatures of 800, 900, 1000, and 1100 °C to induce the separation of excess silicon in the SiO x films into nanosized crystalline silicon particles inside an amorphous SiO x matrix. The size of the silicon particles was determined using Raman spectroscopy.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/48601591" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="6b4ef962cb18ce05a5fa4ad915ac4e87" rel="nofollow" data-download="{"attachment_id":67128730,"asset_id":48601591,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/67128730/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="76155679" href="https://independent.academia.edu/KresimirFuric">Kresimir Furic</a><script data-card-contents-for-user="76155679" type="text/json">{"id":76155679,"first_name":"Kresimir","last_name":"Furic","domain_name":"independent","page_name":"KresimirFuric","display_name":"Kresimir Furic","profile_url":"https://independent.academia.edu/KresimirFuric?f_ri=483677","photo":"https://0.academia-photos.com/76155679/19754101/19600896/s65_kresimir.furic.jpg"}</script></span></span></li><li class="js-paper-rank-work_48601591 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="48601591"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 48601591, container: ".js-paper-rank-work_48601591", }); 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$(".js-view-count[data-work-id=48601591]").text(description); $(".js-view-count-work_48601591").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_48601591").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="48601591"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">14</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="9339" rel="nofollow" href="https://www.academia.edu/Documents/in/Raman_Spectroscopy">Raman Spectroscopy</a>, <script data-card-contents-for-ri="9339" type="text/json">{"id":9339,"name":"Raman Spectroscopy","url":"https://www.academia.edu/Documents/in/Raman_Spectroscopy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="11406" rel="nofollow" href="https://www.academia.edu/Documents/in/Silicon">Silicon</a>, <script data-card-contents-for-ri="11406" type="text/json">{"id":11406,"name":"Silicon","url":"https://www.academia.edu/Documents/in/Silicon?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="14136" rel="nofollow" href="https://www.academia.edu/Documents/in/Pyrolysis">Pyrolysis</a>, <script data-card-contents-for-ri="14136" type="text/json">{"id":14136,"name":"Pyrolysis","url":"https://www.academia.edu/Documents/in/Pyrolysis?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="49427" rel="nofollow" href="https://www.academia.edu/Documents/in/Thin_Films">Thin Films</a><script data-card-contents-for-ri="49427" type="text/json">{"id":49427,"name":"Thin Films","url":"https://www.academia.edu/Documents/in/Thin_Films?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=48601591]'), work: {"id":48601591,"title":"Thermal Decomposition of Silicon-rich Oxides Deposited by the LPCVD Method","created_at":"2021-05-05T00:17:43.970-07:00","url":"https://www.academia.edu/48601591/Thermal_Decomposition_of_Silicon_rich_Oxides_Deposited_by_the_LPCVD_Method?f_ri=483677","dom_id":"work_48601591","summary":"Silicon-rich oxide (SiO x , 0 \u003c x \u003c 2) thin films were deposited using the Low Pressure Chemical Vapor Deposition (LPCVD) method at temperature of 570 °C using silane (SiH 4) and oxygen as the reactant gasses. The films were annealed at temperatures of 800, 900, 1000, and 1100 °C to induce the separation of excess silicon in the SiO x films into nanosized crystalline silicon particles inside an amorphous SiO x matrix. The size of the silicon particles was determined using Raman spectroscopy.","downloadable_attachments":[{"id":67128730,"asset_id":48601591,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":76155679,"first_name":"Kresimir","last_name":"Furic","domain_name":"independent","page_name":"KresimirFuric","display_name":"Kresimir Furic","profile_url":"https://independent.academia.edu/KresimirFuric?f_ri=483677","photo":"https://0.academia-photos.com/76155679/19754101/19600896/s65_kresimir.furic.jpg"}],"research_interests":[{"id":9339,"name":"Raman Spectroscopy","url":"https://www.academia.edu/Documents/in/Raman_Spectroscopy?f_ri=483677","nofollow":true},{"id":11406,"name":"Silicon","url":"https://www.academia.edu/Documents/in/Silicon?f_ri=483677","nofollow":true},{"id":14136,"name":"Pyrolysis","url":"https://www.academia.edu/Documents/in/Pyrolysis?f_ri=483677","nofollow":true},{"id":49427,"name":"Thin Films","url":"https://www.academia.edu/Documents/in/Thin_Films?f_ri=483677","nofollow":true},{"id":99667,"name":"Annealing","url":"https://www.academia.edu/Documents/in/Annealing?f_ri=483677"},{"id":101573,"name":"Thin Film","url":"https://www.academia.edu/Documents/in/Thin_Film?f_ri=483677"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677"},{"id":296824,"name":"Phonons","url":"https://www.academia.edu/Documents/in/Phonons?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":856179,"name":"Raman Scattering","url":"https://www.academia.edu/Documents/in/Raman_Scattering?f_ri=483677"},{"id":958812,"name":"Raman Spectra","url":"https://www.academia.edu/Documents/in/Raman_Spectra?f_ri=483677"},{"id":1178191,"name":"LPCVD","url":"https://www.academia.edu/Documents/in/LPCVD?f_ri=483677"},{"id":1271926,"name":"Solids","url":"https://www.academia.edu/Documents/in/Solids?f_ri=483677"},{"id":1886528,"name":"Chemical vapour deposition","url":"https://www.academia.edu/Documents/in/Chemical_vapour_deposition?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_4834878" data-work_id="4834878" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/4834878/Thermoanalyticalstudies_of_titanium_IV_acetylacetonate_xerogels_with_emphasis_on_evolvedgas_analysis">Thermoanalyticalstudies of titanium(IV) acetylacetonate xerogels with emphasis on evolvedgas analysis</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Thermal decomposition of precursor xerogels for TiO2, obtained by gelling of acetylacetonate-modified titanium(IV) tetraisopropoxide (prepared at Ti-alkoxide:acetylacetone molar ratios of 1:1 (Ti-1) and 1:2 (Ti-2)) in boiling... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_4834878" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Thermal decomposition of precursor xerogels for TiO2, obtained by gelling of acetylacetonate-modified titanium(IV) tetraisopropoxide (prepared at Ti-alkoxide:acetylacetone molar ratios of 1:1 (Ti-1) and 1:2 (Ti-2)) in boiling 2-methoxyethanol, was monitored by simultaneous TG/DTA/EGA-MS and EGA-FTIR measurements. Thermal degradation processes of Ti-1 and Ti-2 in the temperature range of 30–700°C consist of six mass loss steps, the total mass loss being 46.3% and 54.4%, respectively. EGA by FTIR and MS revealed release of H2O below 120°C; followed by evolution of acetone and acetic acid between approximately 100 and 320°C, and that of CO2 up to 560°C. Acetylacetone is evolved to a significant extent from sample Ti-2 at 120–200°C.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4834878" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="40ca0007f3e6cb17495ced13b6ccf973" rel="nofollow" data-download="{"attachment_id":49609471,"asset_id":4834878,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49609471/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="6262361" href="https://ttu-ee.academia.edu/KaiaTonsuaadu">Kaia Tonsuaadu</a><script data-card-contents-for-user="6262361" type="text/json">{"id":6262361,"first_name":"Kaia","last_name":"Tonsuaadu","domain_name":"ttu-ee","page_name":"KaiaTonsuaadu","display_name":"Kaia Tonsuaadu","profile_url":"https://ttu-ee.academia.edu/KaiaTonsuaadu?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_4834878 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4834878"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4834878, container: ".js-paper-rank-work_4834878", }); 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$(".js-view-count[data-work-id=4834878]").text(description); $(".js-view-count-work_4834878").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_4834878").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="4834878"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">4</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="11404" rel="nofollow" href="https://www.academia.edu/Documents/in/Titanium">Titanium</a>, <script data-card-contents-for-ri="11404" type="text/json">{"id":11404,"name":"Titanium","url":"https://www.academia.edu/Documents/in/Titanium?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="483677" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_Decomposition">Thermal Decomposition</a>, <script data-card-contents-for-ri="483677" type="text/json">{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="723149" rel="nofollow" href="https://www.academia.edu/Documents/in/Acetic_Acid">Acetic Acid</a>, <script data-card-contents-for-ri="723149" type="text/json">{"id":723149,"name":"Acetic Acid","url":"https://www.academia.edu/Documents/in/Acetic_Acid?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="963709" rel="nofollow" href="https://www.academia.edu/Documents/in/Mass_Loss">Mass Loss</a><script data-card-contents-for-ri="963709" type="text/json">{"id":963709,"name":"Mass Loss","url":"https://www.academia.edu/Documents/in/Mass_Loss?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=4834878]'), work: {"id":4834878,"title":"Thermoanalyticalstudies of titanium(IV) acetylacetonate xerogels with emphasis on evolvedgas analysis","created_at":"2013-10-20T18:03:08.598-07:00","url":"https://www.academia.edu/4834878/Thermoanalyticalstudies_of_titanium_IV_acetylacetonate_xerogels_with_emphasis_on_evolvedgas_analysis?f_ri=483677","dom_id":"work_4834878","summary":"Thermal decomposition of precursor xerogels for TiO2, obtained by gelling of acetylacetonate-modified titanium(IV) tetraisopropoxide (prepared at Ti-alkoxide:acetylacetone molar ratios of 1:1 (Ti-1) and 1:2 (Ti-2)) in boiling 2-methoxyethanol, was monitored by simultaneous TG/DTA/EGA-MS and EGA-FTIR measurements. Thermal degradation processes of Ti-1 and Ti-2 in the temperature range of 30–700°C consist of six mass loss steps, the total mass loss being 46.3% and 54.4%, respectively. EGA by FTIR and MS revealed release of H2O below 120°C; followed by evolution of acetone and acetic acid between approximately 100 and 320°C, and that of CO2 up to 560°C. Acetylacetone is evolved to a significant extent from sample Ti-2 at 120–200°C.","downloadable_attachments":[{"id":49609471,"asset_id":4834878,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":6262361,"first_name":"Kaia","last_name":"Tonsuaadu","domain_name":"ttu-ee","page_name":"KaiaTonsuaadu","display_name":"Kaia Tonsuaadu","profile_url":"https://ttu-ee.academia.edu/KaiaTonsuaadu?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":11404,"name":"Titanium","url":"https://www.academia.edu/Documents/in/Titanium?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true},{"id":723149,"name":"Acetic Acid","url":"https://www.academia.edu/Documents/in/Acetic_Acid?f_ri=483677","nofollow":true},{"id":963709,"name":"Mass Loss","url":"https://www.academia.edu/Documents/in/Mass_Loss?f_ri=483677","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_28720480" data-work_id="28720480" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/28720480/Thermal_decomposition_reactions_of_carboxybenzenediazonium_salts_I_1_4_Dehydroaromatic_compounds_from_o_carboxybenzenediazonium_salts">Thermal decomposition reactions of carboxybenzenediazonium salts. I. 1,4-Dehydroaromatic compounds from o-carboxybenzenediazonium salts</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The thermal decomposition reaction of p-carboxybenzenediazonium chloride ( 5 ) and 4-carboxy-3-nitrobenzenediazonium chloride (6) was studied and the mixture of gases evolved (HCI, Nz, and COZ) and the solid products obtained were... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_28720480" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The thermal decomposition reaction of p-carboxybenzenediazonium chloride ( 5 ) and 4-carboxy-3-nitrobenzenediazonium chloride (6) was studied and the mixture of gases evolved (HCI, Nz, and COZ) and the solid products obtained were identified and determinated for each experiment. The solid products were separated into substances with one phenyl ring and polymeric products. A heterolytic mechanism is proposed for this decomposition reaction. Evolution of nitrogen is postulated to lead t o a carbonium ion followed by loss of carbon dioxide which produces a 1,Pdehydro aromatic compound. This latter intermediate yields a chloro derivative (HC1 trapping) and polymeric products (autocondensation).</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/28720480" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ba66e6038f520b0bca28cbd645710567" rel="nofollow" data-download="{"attachment_id":49127020,"asset_id":28720480,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49127020/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="53534924" href="https://independent.academia.edu/robertorossi49">roberto rossi</a><script data-card-contents-for-user="53534924" type="text/json">{"id":53534924,"first_name":"roberto","last_name":"rossi","domain_name":"independent","page_name":"robertorossi49","display_name":"roberto rossi","profile_url":"https://independent.academia.edu/robertorossi49?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_28720480 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="28720480"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 28720480, container: ".js-paper-rank-work_28720480", }); 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$(".js-view-count[data-work-id=28720480]").text(description); $(".js-view-count-work_28720480").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_28720480").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="28720480"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">3</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="530" rel="nofollow" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a>, <script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="531" rel="nofollow" href="https://www.academia.edu/Documents/in/Organic_Chemistry">Organic Chemistry</a>, <script data-card-contents-for-ri="531" type="text/json">{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="483677" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_Decomposition">Thermal Decomposition</a><script data-card-contents-for-ri="483677" type="text/json">{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=28720480]'), work: {"id":28720480,"title":"Thermal decomposition reactions of carboxybenzenediazonium salts. I. 1,4-Dehydroaromatic compounds from o-carboxybenzenediazonium salts","created_at":"2016-09-26T04:11:03.240-07:00","url":"https://www.academia.edu/28720480/Thermal_decomposition_reactions_of_carboxybenzenediazonium_salts_I_1_4_Dehydroaromatic_compounds_from_o_carboxybenzenediazonium_salts?f_ri=483677","dom_id":"work_28720480","summary":"The thermal decomposition reaction of p-carboxybenzenediazonium chloride ( 5 ) and 4-carboxy-3-nitrobenzenediazonium chloride (6) was studied and the mixture of gases evolved (HCI, Nz, and COZ) and the solid products obtained were identified and determinated for each experiment. The solid products were separated into substances with one phenyl ring and polymeric products. A heterolytic mechanism is proposed for this decomposition reaction. Evolution of nitrogen is postulated to lead t o a carbonium ion followed by loss of carbon dioxide which produces a 1,Pdehydro aromatic compound. This latter intermediate yields a chloro derivative (HC1 trapping) and polymeric products (autocondensation).","downloadable_attachments":[{"id":49127020,"asset_id":28720480,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":53534924,"first_name":"roberto","last_name":"rossi","domain_name":"independent","page_name":"robertorossi49","display_name":"roberto rossi","profile_url":"https://independent.academia.edu/robertorossi49?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=483677","nofollow":true},{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_26046777" data-work_id="26046777" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/26046777/Thermal_degradation_of_Fenitrothion_Identification_and_eco_toxicity_of_decomposition_products">Thermal degradation of Fenitrothion: Identification and eco-toxicity of decomposition products</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The thermal decomposition of Fenitrothion [phosphorothioic acid O,O-diethyl O-(3-methyl-4nitrophenyl) ester] was investigated. Results obtained by different scale calorimetric techniques show that the thermal decomposition of Fenitrothion... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_26046777" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The thermal decomposition of Fenitrothion [phosphorothioic acid O,O-diethyl O-(3-methyl-4nitrophenyl) ester] was investigated. Results obtained by different scale calorimetric techniques show that the thermal decomposition of Fenitrothion involves two main steps. Intermediate and final thermal degradation products formed during isothermal and adiabatic thermal decomposition experiments were identified. The eco-toxicological profile of the decomposition products was assessed experimentally and compared to results obtained with a predictive software (ECOSAR). A specific index was defined to assess the change in ecotoxicity profile of decomposition products with respect to the original compound.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/26046777" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ee53af05a32a4759fb122803579f9fec" rel="nofollow" data-download="{"attachment_id":46385305,"asset_id":26046777,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/46385305/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="33206096" href="https://unina.academia.edu/AntoninoPollio">Antonino Pollio</a><script data-card-contents-for-user="33206096" type="text/json">{"id":33206096,"first_name":"Antonino","last_name":"Pollio","domain_name":"unina","page_name":"AntoninoPollio","display_name":"Antonino Pollio","profile_url":"https://unina.academia.edu/AntoninoPollio?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_26046777 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="26046777"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 26046777, container: ".js-paper-rank-work_26046777", }); 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$(".js-view-count[data-work-id=26046777]").text(description); $(".js-view-count-work_26046777").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_26046777").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="26046777"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">7</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="78753" rel="nofollow" href="https://www.academia.edu/Documents/in/Differential_scanning_calorimetry">Differential scanning calorimetry</a>, <script data-card-contents-for-ri="78753" type="text/json">{"id":78753,"name":"Differential scanning calorimetry","url":"https://www.academia.edu/Documents/in/Differential_scanning_calorimetry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="85437" rel="nofollow" href="https://www.academia.edu/Documents/in/Pesticides">Pesticides</a>, <script data-card-contents-for-ri="85437" type="text/json">{"id":85437,"name":"Pesticides","url":"https://www.academia.edu/Documents/in/Pesticides?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="149625" rel="nofollow" href="https://www.academia.edu/Documents/in/Hazardous_Materials">Hazardous Materials</a><script data-card-contents-for-ri="149625" type="text/json">{"id":149625,"name":"Hazardous Materials","url":"https://www.academia.edu/Documents/in/Hazardous_Materials?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=26046777]'), work: {"id":26046777,"title":"Thermal degradation of Fenitrothion: Identification and eco-toxicity of decomposition products","created_at":"2016-06-10T13:22:42.021-07:00","url":"https://www.academia.edu/26046777/Thermal_degradation_of_Fenitrothion_Identification_and_eco_toxicity_of_decomposition_products?f_ri=483677","dom_id":"work_26046777","summary":"The thermal decomposition of Fenitrothion [phosphorothioic acid O,O-diethyl O-(3-methyl-4nitrophenyl) ester] was investigated. Results obtained by different scale calorimetric techniques show that the thermal decomposition of Fenitrothion involves two main steps. Intermediate and final thermal degradation products formed during isothermal and adiabatic thermal decomposition experiments were identified. The eco-toxicological profile of the decomposition products was assessed experimentally and compared to results obtained with a predictive software (ECOSAR). A specific index was defined to assess the change in ecotoxicity profile of decomposition products with respect to the original compound.","downloadable_attachments":[{"id":46385305,"asset_id":26046777,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":33206096,"first_name":"Antonino","last_name":"Pollio","domain_name":"unina","page_name":"AntoninoPollio","display_name":"Antonino Pollio","profile_url":"https://unina.academia.edu/AntoninoPollio?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":78753,"name":"Differential scanning calorimetry","url":"https://www.academia.edu/Documents/in/Differential_scanning_calorimetry?f_ri=483677","nofollow":true},{"id":85437,"name":"Pesticides","url":"https://www.academia.edu/Documents/in/Pesticides?f_ri=483677","nofollow":true},{"id":149625,"name":"Hazardous Materials","url":"https://www.academia.edu/Documents/in/Hazardous_Materials?f_ri=483677","nofollow":true},{"id":394388,"name":"Hazardous","url":"https://www.academia.edu/Documents/in/Hazardous?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":677739,"name":"Calorimetry","url":"https://www.academia.edu/Documents/in/Calorimetry?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_12470008" data-work_id="12470008" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/12470008/High_Temperature_Thermal_Decomposition_of_Isobutane_and_n_Butane_Behind_Shock_Waves">High-Temperature Thermal Decomposition of Isobutane and n -Butane Behind Shock Waves</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/12470008" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="cd62585e2a98116e234d226387039656" rel="nofollow" data-download="{"attachment_id":46160373,"asset_id":12470008,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/46160373/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="31306603" href="https://independent.academia.edu/MatthewOehlschlaeger">Matthew Oehlschlaeger</a><script data-card-contents-for-user="31306603" type="text/json">{"id":31306603,"first_name":"Matthew","last_name":"Oehlschlaeger","domain_name":"independent","page_name":"MatthewOehlschlaeger","display_name":"Matthew Oehlschlaeger","profile_url":"https://independent.academia.edu/MatthewOehlschlaeger?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_12470008 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="12470008"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 12470008, container: ".js-paper-rank-work_12470008", }); 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$(".js-view-count[data-work-id=12470008]").text(description); $(".js-view-count-work_12470008").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_12470008").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="12470008"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">4</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="191117" rel="nofollow" href="https://www.academia.edu/Documents/in/High_Temperature">High Temperature</a>, <script data-card-contents-for-ri="191117" type="text/json">{"id":191117,"name":"High Temperature","url":"https://www.academia.edu/Documents/in/High_Temperature?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="483677" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_Decomposition">Thermal Decomposition</a>, <script data-card-contents-for-ri="483677" type="text/json">{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="645605" rel="nofollow" href="https://www.academia.edu/Documents/in/THEORETICAL_AND_COMPUTATIONAL_CHEMISTRY">THEORETICAL AND COMPUTATIONAL CHEMISTRY</a>, <script data-card-contents-for-ri="645605" type="text/json">{"id":645605,"name":"THEORETICAL AND COMPUTATIONAL CHEMISTRY","url":"https://www.academia.edu/Documents/in/THEORETICAL_AND_COMPUTATIONAL_CHEMISTRY?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="837148" rel="nofollow" href="https://www.academia.edu/Documents/in/Shock_Wave">Shock Wave</a><script data-card-contents-for-ri="837148" type="text/json">{"id":837148,"name":"Shock Wave","url":"https://www.academia.edu/Documents/in/Shock_Wave?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=12470008]'), work: {"id":12470008,"title":"High-Temperature Thermal Decomposition of Isobutane and n -Butane Behind Shock Waves","created_at":"2015-05-19T12:02:36.348-07:00","url":"https://www.academia.edu/12470008/High_Temperature_Thermal_Decomposition_of_Isobutane_and_n_Butane_Behind_Shock_Waves?f_ri=483677","dom_id":"work_12470008","summary":null,"downloadable_attachments":[{"id":46160373,"asset_id":12470008,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":31306603,"first_name":"Matthew","last_name":"Oehlschlaeger","domain_name":"independent","page_name":"MatthewOehlschlaeger","display_name":"Matthew Oehlschlaeger","profile_url":"https://independent.academia.edu/MatthewOehlschlaeger?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":191117,"name":"High Temperature","url":"https://www.academia.edu/Documents/in/High_Temperature?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true},{"id":645605,"name":"THEORETICAL AND COMPUTATIONAL CHEMISTRY","url":"https://www.academia.edu/Documents/in/THEORETICAL_AND_COMPUTATIONAL_CHEMISTRY?f_ri=483677","nofollow":true},{"id":837148,"name":"Shock Wave","url":"https://www.academia.edu/Documents/in/Shock_Wave?f_ri=483677","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_63071235" data-work_id="63071235" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/63071235/Synthesis_structural_properties_and_thermal_stability_of_Mn_doped_hydroxyapatite">Synthesis, structural properties and thermal stability of Mn-doped hydroxyapatite</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Hydroxyapatite (HA) - Ca(10)(PO(4))(6)(OH)(2) is a basic inorganic model component of hard biological tissues, such as bones and teeth. The significant property of HA is its ability to exchange Ca(2+) ions, which influences crystallinity,... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_63071235" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Hydroxyapatite (HA) - Ca(10)(PO(4))(6)(OH)(2) is a basic inorganic model component of hard biological tissues, such as bones and teeth. The significant property of HA is its ability to exchange Ca(2+) ions, which influences crystallinity, physico-chemical and biological properties of modified hydroxyapatite materials. In this work, FTIR, Raman spectroscopy, XRD. SEM and EDS techniques were used to determine thermal stability, chemical and phase composition of Mn containing hydroxyapatite (MnHA). Described methods confirmed thermal decomposition and phase transformation of MnHA to alpha TCP, beta TCP and formation of Mn(3)O(4) depending on sintering temperature and manganese content. In vitro biological evaluation of Mn-modified HA ceramics was also performed using human osteoblast cells. (C) 2010 Elsevier B.V. All rights reserved.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/63071235" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="109247998af614f502764ff2d1358734" rel="nofollow" data-download="{"attachment_id":75619566,"asset_id":63071235,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/75619566/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="39980572" href="https://independent.academia.edu/Czes%C5%82awaPaluszkiewicz">Czesława Paluszkiewicz</a><script data-card-contents-for-user="39980572" type="text/json">{"id":39980572,"first_name":"Czesława","last_name":"Paluszkiewicz","domain_name":"independent","page_name":"CzesławaPaluszkiewicz","display_name":"Czesława Paluszkiewicz","profile_url":"https://independent.academia.edu/Czes%C5%82awaPaluszkiewicz?f_ri=483677","photo":"https://0.academia-photos.com/39980572/30616992/28354044/s65_czes_awa.paluszkiewicz.jpg"}</script></span></span></li><li class="js-paper-rank-work_63071235 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="63071235"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 63071235, container: ".js-paper-rank-work_63071235", }); 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$(".js-view-count[data-work-id=63071235]").text(description); $(".js-view-count-work_63071235").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_63071235").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="63071235"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">9</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="6216" rel="nofollow" href="https://www.academia.edu/Documents/in/Hydroxyapatite">Hydroxyapatite</a>, <script data-card-contents-for-ri="6216" type="text/json">{"id":6216,"name":"Hydroxyapatite","url":"https://www.academia.edu/Documents/in/Hydroxyapatite?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="9339" rel="nofollow" href="https://www.academia.edu/Documents/in/Raman_Spectroscopy">Raman Spectroscopy</a>, <script data-card-contents-for-ri="9339" type="text/json">{"id":9339,"name":"Raman Spectroscopy","url":"https://www.academia.edu/Documents/in/Raman_Spectroscopy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="78842" rel="nofollow" href="https://www.academia.edu/Documents/in/Infrared_spectroscopy">Infrared spectroscopy</a>, <script data-card-contents-for-ri="78842" type="text/json">{"id":78842,"name":"Infrared spectroscopy","url":"https://www.academia.edu/Documents/in/Infrared_spectroscopy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="308420" rel="nofollow" href="https://www.academia.edu/Documents/in/Phase_Transformation">Phase Transformation</a><script data-card-contents-for-ri="308420" type="text/json">{"id":308420,"name":"Phase Transformation","url":"https://www.academia.edu/Documents/in/Phase_Transformation?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=63071235]'), work: {"id":63071235,"title":"Synthesis, structural properties and thermal stability of Mn-doped hydroxyapatite","created_at":"2021-12-03T00:44:35.734-08:00","url":"https://www.academia.edu/63071235/Synthesis_structural_properties_and_thermal_stability_of_Mn_doped_hydroxyapatite?f_ri=483677","dom_id":"work_63071235","summary":"Hydroxyapatite (HA) - Ca(10)(PO(4))(6)(OH)(2) is a basic inorganic model component of hard biological tissues, such as bones and teeth. The significant property of HA is its ability to exchange Ca(2+) ions, which influences crystallinity, physico-chemical and biological properties of modified hydroxyapatite materials. In this work, FTIR, Raman spectroscopy, XRD. SEM and EDS techniques were used to determine thermal stability, chemical and phase composition of Mn containing hydroxyapatite (MnHA). Described methods confirmed thermal decomposition and phase transformation of MnHA to alpha TCP, beta TCP and formation of Mn(3)O(4) depending on sintering temperature and manganese content. In vitro biological evaluation of Mn-modified HA ceramics was also performed using human osteoblast cells. (C) 2010 Elsevier B.V. All rights reserved.","downloadable_attachments":[{"id":75619566,"asset_id":63071235,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":39980572,"first_name":"Czesława","last_name":"Paluszkiewicz","domain_name":"independent","page_name":"CzesławaPaluszkiewicz","display_name":"Czesława Paluszkiewicz","profile_url":"https://independent.academia.edu/Czes%C5%82awaPaluszkiewicz?f_ri=483677","photo":"https://0.academia-photos.com/39980572/30616992/28354044/s65_czes_awa.paluszkiewicz.jpg"}],"research_interests":[{"id":6216,"name":"Hydroxyapatite","url":"https://www.academia.edu/Documents/in/Hydroxyapatite?f_ri=483677","nofollow":true},{"id":9339,"name":"Raman Spectroscopy","url":"https://www.academia.edu/Documents/in/Raman_Spectroscopy?f_ri=483677","nofollow":true},{"id":78842,"name":"Infrared spectroscopy","url":"https://www.academia.edu/Documents/in/Infrared_spectroscopy?f_ri=483677","nofollow":true},{"id":308420,"name":"Phase Transformation","url":"https://www.academia.edu/Documents/in/Phase_Transformation?f_ri=483677","nofollow":true},{"id":389180,"name":"Thermal Stability","url":"https://www.academia.edu/Documents/in/Thermal_Stability?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":494642,"name":"Structural Properties","url":"https://www.academia.edu/Documents/in/Structural_Properties?f_ri=483677"},{"id":645605,"name":"THEORETICAL AND COMPUTATIONAL CHEMISTRY","url":"https://www.academia.edu/Documents/in/THEORETICAL_AND_COMPUTATIONAL_CHEMISTRY?f_ri=483677"},{"id":1724844,"name":"Molecular Structure","url":"https://www.academia.edu/Documents/in/Molecular_Structure?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_3138259" data-work_id="3138259" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/3138259/Iron_filled_carbon_nanotubes_grown_on_substrates_with_thin_metal_layers_and_their_magnetic_properties">Iron filled carbon nanotubes grown on substrates with thin metal layers and their magnetic properties</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The thermal decomposition of ferrocene combined with a catalyst-assisted structuring of a Si-substrate surface is a favourable way to produce Fe-filled carbon nanotubes in good quality and in high yields. In this work we have studied the... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_3138259" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The thermal decomposition of ferrocene combined with a catalyst-assisted structuring of a Si-substrate surface is a favourable way to produce Fe-filled carbon nanotubes in good quality and in high yields. In this work we have studied the growth of such aligned filled nanotubes on iron and cobalt pre-coated Si-substrates and their dependence on the deposition time. The nanotube diameter depends on the used catalyst metal on the substrate surface. Magnetization measurements were carried out perpendicular (along tube axis) and parallel to the substrate and show excellent coercivities, a strong uniaxial anisotropy (ratios of H c,per /H c,par up to 6) and high saturation magnetization moments per substrate square. The magnetic behavior has been also interpreted as a function of deposition time and of the catalyst metal on the substrate. These investigations were complemented by X-ray diffraction, which revealed a majority fraction of a-Fe and a small amount of Fe 3 C.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/3138259" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="933d5126a488882b0fe503d6f2929e76" rel="nofollow" data-download="{"attachment_id":50441970,"asset_id":3138259,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50441970/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="3597287" href="https://independent.academia.edu/VishalUdmale">Vishal Udmale</a><script data-card-contents-for-user="3597287" type="text/json">{"id":3597287,"first_name":"Vishal","last_name":"Udmale","domain_name":"independent","page_name":"VishalUdmale","display_name":"Vishal Udmale","profile_url":"https://independent.academia.edu/VishalUdmale?f_ri=483677","photo":"https://0.academia-photos.com/3597287/1253769/1563722/s65_vishal.udmale.jpg"}</script></span></span></li><li class="js-paper-rank-work_3138259 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="3138259"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 3138259, container: ".js-paper-rank-work_3138259", }); });</script></li><li class="js-percentile-work_3138259 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 3138259; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_3138259"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_3138259 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="3138259"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 3138259; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=3138259]").text(description); $(".js-view-count-work_3138259").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_3138259").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="3138259"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">21</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="5303" rel="nofollow" href="https://www.academia.edu/Documents/in/Carbon">Carbon</a>, <script data-card-contents-for-ri="5303" type="text/json">{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="6399" rel="nofollow" href="https://www.academia.edu/Documents/in/Catalysts">Catalysts</a>, <script data-card-contents-for-ri="6399" type="text/json">{"id":6399,"name":"Catalysts","url":"https://www.academia.edu/Documents/in/Catalysts?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="10655" rel="nofollow" href="https://www.academia.edu/Documents/in/Scanning_Electron_Microscopy">Scanning Electron Microscopy</a><script data-card-contents-for-ri="10655" type="text/json">{"id":10655,"name":"Scanning Electron Microscopy","url":"https://www.academia.edu/Documents/in/Scanning_Electron_Microscopy?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=3138259]'), work: {"id":3138259,"title":"Iron filled carbon nanotubes grown on substrates with thin metal layers and their magnetic properties","created_at":"2013-03-28T03:03:55.386-07:00","url":"https://www.academia.edu/3138259/Iron_filled_carbon_nanotubes_grown_on_substrates_with_thin_metal_layers_and_their_magnetic_properties?f_ri=483677","dom_id":"work_3138259","summary":"The thermal decomposition of ferrocene combined with a catalyst-assisted structuring of a Si-substrate surface is a favourable way to produce Fe-filled carbon nanotubes in good quality and in high yields. In this work we have studied the growth of such aligned filled nanotubes on iron and cobalt pre-coated Si-substrates and their dependence on the deposition time. The nanotube diameter depends on the used catalyst metal on the substrate surface. Magnetization measurements were carried out perpendicular (along tube axis) and parallel to the substrate and show excellent coercivities, a strong uniaxial anisotropy (ratios of H c,per /H c,par up to 6) and high saturation magnetization moments per substrate square. The magnetic behavior has been also interpreted as a function of deposition time and of the catalyst metal on the substrate. These investigations were complemented by X-ray diffraction, which revealed a majority fraction of a-Fe and a small amount of Fe 3 C.","downloadable_attachments":[{"id":50441970,"asset_id":3138259,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":3597287,"first_name":"Vishal","last_name":"Udmale","domain_name":"independent","page_name":"VishalUdmale","display_name":"Vishal Udmale","profile_url":"https://independent.academia.edu/VishalUdmale?f_ri=483677","photo":"https://0.academia-photos.com/3597287/1253769/1563722/s65_vishal.udmale.jpg"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=483677","nofollow":true},{"id":6399,"name":"Catalysts","url":"https://www.academia.edu/Documents/in/Catalysts?f_ri=483677","nofollow":true},{"id":10655,"name":"Scanning Electron Microscopy","url":"https://www.academia.edu/Documents/in/Scanning_Electron_Microscopy?f_ri=483677","nofollow":true},{"id":10909,"name":"Carbon Nanotubes","url":"https://www.academia.edu/Documents/in/Carbon_Nanotubes?f_ri=483677"},{"id":12842,"name":"Carbon Nanotube","url":"https://www.academia.edu/Documents/in/Carbon_Nanotube?f_ri=483677"},{"id":37333,"name":"Anisotropy","url":"https://www.academia.edu/Documents/in/Anisotropy?f_ri=483677"},{"id":44752,"name":"Chemical Vapor Deposition","url":"https://www.academia.edu/Documents/in/Chemical_Vapor_Deposition?f_ri=483677"},{"id":54961,"name":"Growth","url":"https://www.academia.edu/Documents/in/Growth?f_ri=483677"},{"id":118582,"name":"Physical sciences","url":"https://www.academia.edu/Documents/in/Physical_sciences?f_ri=483677"},{"id":133975,"name":"Magnetic Properties","url":"https://www.academia.edu/Documents/in/Magnetic_Properties?f_ri=483677"},{"id":134201,"name":"Deposition","url":"https://www.academia.edu/Documents/in/Deposition?f_ri=483677"},{"id":158597,"name":"Iron","url":"https://www.academia.edu/Documents/in/Iron?f_ri=483677"},{"id":186080,"name":"XRD","url":"https://www.academia.edu/Documents/in/XRD?f_ri=483677"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677"},{"id":386527,"name":"X ray diffraction","url":"https://www.academia.edu/Documents/in/X_ray_diffraction?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":519549,"name":"Magnetization","url":"https://www.academia.edu/Documents/in/Magnetization?f_ri=483677"},{"id":729430,"name":"Saturation","url":"https://www.academia.edu/Documents/in/Saturation?f_ri=483677"},{"id":882535,"name":"Substrates","url":"https://www.academia.edu/Documents/in/Substrates?f_ri=483677"},{"id":1029319,"name":"Diameter","url":"https://www.academia.edu/Documents/in/Diameter?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_19899553" data-work_id="19899553" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/19899553/Thermal_Decomposition_of_Diammonium_Tetrachloroplatinate_to_form_Platinum_Nanoparticles_and_its_Application_as_Electrodes">Thermal Decomposition of Diammonium Tetrachloroplatinate to form Platinum Nanoparticles and its Application as Electrodes</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Pt nanoparticles were obtained via the thermal decomposition of (NH 4 ) 2 [PtCl 4 ] (diammonium tetrachloroplatinate) by heating from room temperature to 760°C. The thermal decomposition process was analyzed using thermogravimetric... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_19899553" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Pt nanoparticles were obtained via the thermal decomposition of (NH 4 ) 2 [PtCl 4 ] (diammonium tetrachloroplatinate) by heating from room temperature to 760°C. The thermal decomposition process was analyzed using thermogravimetric analysis (TGA) and differential thermal analysis (DTA), X-ray thermodiffraction and infrared spectroscopy. The size and structure of the platinum particles were analyzed using transmission electron microscopy (TEM). The electrochemical activity of Pt particles was assessed by cyclic voltammetry in 0.5 M H 2 SO 4 . The TGA and DTA results suggested that the thermal decomposition of the precursor proceeded in two stages: loss of NH 4 Cl at *300°C, followed by loss of NH 4 Cl and Cl 2 at *372°C. Metallic Pt particles were then produced at temperatures of 372°C and above. At 760°C, the mean ± SD size of the Pt particles was (4.1 ± 1.6) nm, as determined from TEM measurements. In cyclic voltammetry (CV) measurements, an electrode comprised of glassy carbon and Pt particles in 0.5 M H 2 SO 4 exhibited behavior similar to that observed using a polycrystalline Pt electrode.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/19899553" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ccfb4dd55a5bd33caddb87ce70b4f416" rel="nofollow" data-download="{"attachment_id":40906971,"asset_id":19899553,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40906971/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="40740777" href="https://independent.academia.edu/UlisesMorales6">Ulises Morales</a><script data-card-contents-for-user="40740777" type="text/json">{"id":40740777,"first_name":"Ulises","last_name":"Morales","domain_name":"independent","page_name":"UlisesMorales6","display_name":"Ulises Morales","profile_url":"https://independent.academia.edu/UlisesMorales6?f_ri=483677","photo":"https://0.academia-photos.com/40740777/67957203/56331590/s65_ulises.morales.jpeg"}</script></span></span></li><li class="js-paper-rank-work_19899553 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="19899553"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 19899553, container: ".js-paper-rank-work_19899553", }); 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$(".js-view-count[data-work-id=19899553]").text(description); $(".js-view-count-work_19899553").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_19899553").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="19899553"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">10</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="72" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemical_Engineering">Chemical Engineering</a>, <script data-card-contents-for-ri="72" type="text/json">{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="14076" rel="nofollow" href="https://www.academia.edu/Documents/in/Transmission_Electron_Microscopy">Transmission Electron Microscopy</a>, <script data-card-contents-for-ri="14076" type="text/json">{"id":14076,"name":"Transmission Electron Microscopy","url":"https://www.academia.edu/Documents/in/Transmission_Electron_Microscopy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="20902" rel="nofollow" href="https://www.academia.edu/Documents/in/Cyclic_Voltammetry">Cyclic Voltammetry</a>, <script data-card-contents-for-ri="20902" type="text/json">{"id":20902,"name":"Cyclic Voltammetry","url":"https://www.academia.edu/Documents/in/Cyclic_Voltammetry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="56001" rel="nofollow" href="https://www.academia.edu/Documents/in/X_Rays">X Rays</a><script data-card-contents-for-ri="56001" type="text/json">{"id":56001,"name":"X Rays","url":"https://www.academia.edu/Documents/in/X_Rays?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=19899553]'), work: {"id":19899553,"title":"Thermal Decomposition of Diammonium Tetrachloroplatinate to form Platinum Nanoparticles and its Application as Electrodes","created_at":"2015-12-30T00:21:22.303-08:00","url":"https://www.academia.edu/19899553/Thermal_Decomposition_of_Diammonium_Tetrachloroplatinate_to_form_Platinum_Nanoparticles_and_its_Application_as_Electrodes?f_ri=483677","dom_id":"work_19899553","summary":"Pt nanoparticles were obtained via the thermal decomposition of (NH 4 ) 2 [PtCl 4 ] (diammonium tetrachloroplatinate) by heating from room temperature to 760°C. The thermal decomposition process was analyzed using thermogravimetric analysis (TGA) and differential thermal analysis (DTA), X-ray thermodiffraction and infrared spectroscopy. The size and structure of the platinum particles were analyzed using transmission electron microscopy (TEM). The electrochemical activity of Pt particles was assessed by cyclic voltammetry in 0.5 M H 2 SO 4 . The TGA and DTA results suggested that the thermal decomposition of the precursor proceeded in two stages: loss of NH 4 Cl at *300°C, followed by loss of NH 4 Cl and Cl 2 at *372°C. Metallic Pt particles were then produced at temperatures of 372°C and above. At 760°C, the mean ± SD size of the Pt particles was (4.1 ± 1.6) nm, as determined from TEM measurements. In cyclic voltammetry (CV) measurements, an electrode comprised of glassy carbon and Pt particles in 0.5 M H 2 SO 4 exhibited behavior similar to that observed using a polycrystalline Pt electrode.","downloadable_attachments":[{"id":40906971,"asset_id":19899553,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":40740777,"first_name":"Ulises","last_name":"Morales","domain_name":"independent","page_name":"UlisesMorales6","display_name":"Ulises Morales","profile_url":"https://independent.academia.edu/UlisesMorales6?f_ri=483677","photo":"https://0.academia-photos.com/40740777/67957203/56331590/s65_ulises.morales.jpeg"}],"research_interests":[{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true},{"id":14076,"name":"Transmission Electron Microscopy","url":"https://www.academia.edu/Documents/in/Transmission_Electron_Microscopy?f_ri=483677","nofollow":true},{"id":20902,"name":"Cyclic Voltammetry","url":"https://www.academia.edu/Documents/in/Cyclic_Voltammetry?f_ri=483677","nofollow":true},{"id":56001,"name":"X Rays","url":"https://www.academia.edu/Documents/in/X_Rays?f_ri=483677","nofollow":true},{"id":78842,"name":"Infrared spectroscopy","url":"https://www.academia.edu/Documents/in/Infrared_spectroscopy?f_ri=483677"},{"id":352783,"name":"Glassy Carbon","url":"https://www.academia.edu/Documents/in/Glassy_Carbon?f_ri=483677"},{"id":391252,"name":"Room Temperature","url":"https://www.academia.edu/Documents/in/Room_Temperature?f_ri=483677"},{"id":396853,"name":"Differential Thermal Analysis","url":"https://www.academia.edu/Documents/in/Differential_Thermal_Analysis?f_ri=483677"},{"id":398652,"name":"Thermogravimetric Analysis","url":"https://www.academia.edu/Documents/in/Thermogravimetric_Analysis?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_62356824" data-work_id="62356824" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/62356824/Photodecomposition_of_anthracene_on_dry_surfaces_products_and_mechanism">Photodecomposition of anthracene on dry surfaces: products and mechanism</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The photochemistry of anthracene (1) was studied on dry surfaces of silica, Cab-O-Sil (fumed silica) and alumina (neutral) at low coverages (less than 11% of a monolayer). The adsorption of 1 onto these surfaces from cyclohexane obeys a... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_62356824" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The photochemistry of anthracene (1) was studied on dry surfaces of silica, Cab-O-Sil (fumed silica) and alumina (neutral) at low coverages (less than 11% of a monolayer). The adsorption of 1 onto these surfaces from cyclohexane obeys a Freundlich adsorption isotherm, demonstrating a distribution of adsorption sites for interactions between 1 and the surface. Photolysis of 1 (A~x = 350 nm) adsorbed on silica, Cab-O-Sil or alumina, under deaerated conditions, proceeds slowly to give the anthracene-9,10-photodimer (2) as the only product. Diffuse reflectance and fluorescence spectroscopy show that a novel process, involving the formation of a stable ground state pair between two molecules of 1 takes place on all three surfaces at coverages of more than 1% of a monolayer. We propose a dimerization mechanism involving a singlet excimer formed from the stable ground state pairs. Photolysis at the solid-air interface, on the other hand, is considerably faster and proceeds to give 2 and photo-oxidation products of 1. The primary oxidation product is anthracene-9,10-endoperoxide (3) which undergoes thermal decomposition on the surface to give 9,10-anthraquinone (4), 9,10-dihydro-9,10-dihydroxyanthracene (5), bianthronyl (6), 9hydroxyanthrone (7) and 10,10'-dihydroxy-9,9',10,10'-tetrahydro-9,9'-bianthryl (8) as the secondary products. Photo-oxidation is mediated by the addition of singlet molecular oxygen to ground state 1.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/62356824" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ff72f118cabfbc96e5f1e33c150a5888" rel="nofollow" data-download="{"attachment_id":75150642,"asset_id":62356824,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/75150642/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="47595812" href="https://independent.academia.edu/SigmanMichael">Michael Sigman</a><script data-card-contents-for-user="47595812" type="text/json">{"id":47595812,"first_name":"Michael","last_name":"Sigman","domain_name":"independent","page_name":"SigmanMichael","display_name":"Michael Sigman","profile_url":"https://independent.academia.edu/SigmanMichael?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_62356824 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="62356824"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 62356824, container: ".js-paper-rank-work_62356824", }); 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$(".js-view-count[data-work-id=62356824]").text(description); $(".js-view-count-work_62356824").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_62356824").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="62356824"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">13</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="1525" rel="nofollow" href="https://www.academia.edu/Documents/in/Fluorescence_Spectroscopy">Fluorescence Spectroscopy</a>, <script data-card-contents-for-ri="1525" type="text/json">{"id":1525,"name":"Fluorescence Spectroscopy","url":"https://www.academia.edu/Documents/in/Fluorescence_Spectroscopy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="5104" rel="nofollow" href="https://www.academia.edu/Documents/in/Photochemistry">Photochemistry</a>, <script data-card-contents-for-ri="5104" type="text/json">{"id":5104,"name":"Photochemistry","url":"https://www.academia.edu/Documents/in/Photochemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="7698" rel="nofollow" href="https://www.academia.edu/Documents/in/Fluorescence">Fluorescence</a><script data-card-contents-for-ri="7698" type="text/json">{"id":7698,"name":"Fluorescence","url":"https://www.academia.edu/Documents/in/Fluorescence?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=62356824]'), work: {"id":62356824,"title":"Photodecomposition of anthracene on dry surfaces: products and mechanism","created_at":"2021-11-25T06:00:56.529-08:00","url":"https://www.academia.edu/62356824/Photodecomposition_of_anthracene_on_dry_surfaces_products_and_mechanism?f_ri=483677","dom_id":"work_62356824","summary":"The photochemistry of anthracene (1) was studied on dry surfaces of silica, Cab-O-Sil (fumed silica) and alumina (neutral) at low coverages (less than 11% of a monolayer). The adsorption of 1 onto these surfaces from cyclohexane obeys a Freundlich adsorption isotherm, demonstrating a distribution of adsorption sites for interactions between 1 and the surface. Photolysis of 1 (A~x = 350 nm) adsorbed on silica, Cab-O-Sil or alumina, under deaerated conditions, proceeds slowly to give the anthracene-9,10-photodimer (2) as the only product. Diffuse reflectance and fluorescence spectroscopy show that a novel process, involving the formation of a stable ground state pair between two molecules of 1 takes place on all three surfaces at coverages of more than 1% of a monolayer. We propose a dimerization mechanism involving a singlet excimer formed from the stable ground state pairs. Photolysis at the solid-air interface, on the other hand, is considerably faster and proceeds to give 2 and photo-oxidation products of 1. The primary oxidation product is anthracene-9,10-endoperoxide (3) which undergoes thermal decomposition on the surface to give 9,10-anthraquinone (4), 9,10-dihydro-9,10-dihydroxyanthracene (5), bianthronyl (6), 9hydroxyanthrone (7) and 10,10'-dihydroxy-9,9',10,10'-tetrahydro-9,9'-bianthryl (8) as the secondary products. Photo-oxidation is mediated by the addition of singlet molecular oxygen to ground state 1.","downloadable_attachments":[{"id":75150642,"asset_id":62356824,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":47595812,"first_name":"Michael","last_name":"Sigman","domain_name":"independent","page_name":"SigmanMichael","display_name":"Michael Sigman","profile_url":"https://independent.academia.edu/SigmanMichael?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":1525,"name":"Fluorescence Spectroscopy","url":"https://www.academia.edu/Documents/in/Fluorescence_Spectroscopy?f_ri=483677","nofollow":true},{"id":5104,"name":"Photochemistry","url":"https://www.academia.edu/Documents/in/Photochemistry?f_ri=483677","nofollow":true},{"id":7698,"name":"Fluorescence","url":"https://www.academia.edu/Documents/in/Fluorescence?f_ri=483677","nofollow":true},{"id":47884,"name":"Biological Sciences","url":"https://www.academia.edu/Documents/in/Biological_Sciences?f_ri=483677"},{"id":98440,"name":"Silica","url":"https://www.academia.edu/Documents/in/Silica?f_ri=483677"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677"},{"id":350232,"name":"Diffuse reflectance","url":"https://www.academia.edu/Documents/in/Diffuse_reflectance?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":623612,"name":"Photolysis","url":"https://www.academia.edu/Documents/in/Photolysis?f_ri=483677"},{"id":1269940,"name":"Excimer","url":"https://www.academia.edu/Documents/in/Excimer?f_ri=483677"},{"id":1903296,"name":"Secondary production","url":"https://www.academia.edu/Documents/in/Secondary_production?f_ri=483677"},{"id":2631484,"name":"Adsorption isotherm","url":"https://www.academia.edu/Documents/in/Adsorption_isotherm?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_15419309 coauthored" data-work_id="15419309" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/15419309/Electrosynthesised_thin_polymer_films_the_role_of_XPS_in_the_design_of_application_oriented_innovative_materials">Electrosynthesised thin polymer films: the role of XPS in the design of application oriented innovative materials</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The paper reviews some significant pieces of work carried out in the authors' laboratory in the course of about three decades and concerned with the development of market oriented devices, which exploit the singular characteristics of... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_15419309" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The paper reviews some significant pieces of work carried out in the authors' laboratory in the course of about three decades and concerned with the development of market oriented devices, which exploit the singular characteristics of electrosynthesised polymers. The strategic role of X-Ray Photoelectron Spectroscopy is underlined not only as a powerful technique for the characterization of these thin films, but mainly as an unvaluable tool to feedback optimization procedures both in film synthesis and modification. Case studies relevant to the development of permselective membranes for biosensors, of biocompatible coatings and active layers for gas sensors have been selected and reviewed. Future trends and prospects of the work in progress are also described.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/15419309" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="dff88f8ffcfe9d049f1f3297d59a7478" rel="nofollow" data-download="{"attachment_id":43216227,"asset_id":15419309,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/43216227/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="34564331" href="https://independent.academia.edu/IlarioLosito">Ilario Losito</a><script data-card-contents-for-user="34564331" type="text/json">{"id":34564331,"first_name":"Ilario","last_name":"Losito","domain_name":"independent","page_name":"IlarioLosito","display_name":"Ilario Losito","profile_url":"https://independent.academia.edu/IlarioLosito?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-15419309">+1</span><div class="hidden js-additional-users-15419309"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/LSabbatini">L. 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The strategic role of X-Ray Photoelectron Spectroscopy is underlined not only as a powerful technique for the characterization of these thin films, but mainly as an unvaluable tool to feedback optimization procedures both in film synthesis and modification. Case studies relevant to the development of permselective membranes for biosensors, of biocompatible coatings and active layers for gas sensors have been selected and reviewed. Future trends and prospects of the work in progress are also described.","downloadable_attachments":[{"id":43216227,"asset_id":15419309,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":34564331,"first_name":"Ilario","last_name":"Losito","domain_name":"independent","page_name":"IlarioLosito","display_name":"Ilario Losito","profile_url":"https://independent.academia.edu/IlarioLosito?f_ri=483677","photo":"/images/s65_no_pic.png"},{"id":34611253,"first_name":"L.","last_name":"Sabbatini","domain_name":"independent","page_name":"LSabbatini","display_name":"L. Sabbatini","profile_url":"https://independent.academia.edu/LSabbatini?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":505,"name":"Condensed Matter Physics","url":"https://www.academia.edu/Documents/in/Condensed_Matter_Physics?f_ri=483677","nofollow":true},{"id":4331,"name":"Biosensors","url":"https://www.academia.edu/Documents/in/Biosensors?f_ri=483677","nofollow":true},{"id":4594,"name":"Carbon Dioxide","url":"https://www.academia.edu/Documents/in/Carbon_Dioxide?f_ri=483677","nofollow":true},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":13585,"name":"Market Orientation","url":"https://www.academia.edu/Documents/in/Market_Orientation?f_ri=483677"},{"id":27303,"name":"Fuel Cell","url":"https://www.academia.edu/Documents/in/Fuel_Cell?f_ri=483677"},{"id":96047,"name":"Case Study","url":"https://www.academia.edu/Documents/in/Case_Study?f_ri=483677"},{"id":101573,"name":"Thin Film","url":"https://www.academia.edu/Documents/in/Thin_Film?f_ri=483677"},{"id":128014,"name":"Work in Progress","url":"https://www.academia.edu/Documents/in/Work_in_Progress?f_ri=483677"},{"id":130044,"name":"Gas Sensor","url":"https://www.academia.edu/Documents/in/Gas_Sensor?f_ri=483677"},{"id":191117,"name":"High Temperature","url":"https://www.academia.edu/Documents/in/High_Temperature?f_ri=483677"},{"id":194828,"name":"Nickel","url":"https://www.academia.edu/Documents/in/Nickel?f_ri=483677"},{"id":223470,"name":"Parallel Mechanism","url":"https://www.academia.edu/Documents/in/Parallel_Mechanism?f_ri=483677"},{"id":234569,"name":"Chemically Modified Electrode","url":"https://www.academia.edu/Documents/in/Chemically_Modified_Electrode?f_ri=483677"},{"id":319121,"name":"XPS","url":"https://www.academia.edu/Documents/in/XPS?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":616972,"name":"Low Temperature","url":"https://www.academia.edu/Documents/in/Low_Temperature?f_ri=483677"},{"id":627110,"name":"BioSensors","url":"https://www.academia.edu/Documents/in/BioSensors-1?f_ri=483677"},{"id":772972,"name":"Chemical Composition","url":"https://www.academia.edu/Documents/in/Chemical_Composition?f_ri=483677"},{"id":815888,"name":"Surface Analysis","url":"https://www.academia.edu/Documents/in/Surface_Analysis?f_ri=483677"},{"id":902639,"name":"X Ray Photoelectron Spectroscopy","url":"https://www.academia.edu/Documents/in/X_Ray_Photoelectron_Spectroscopy?f_ri=483677"},{"id":1015410,"name":"Modified Electrode","url":"https://www.academia.edu/Documents/in/Modified_Electrode?f_ri=483677"},{"id":1337673,"name":"Active Layer","url":"https://www.academia.edu/Documents/in/Active_Layer?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_75851380" data-work_id="75851380" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" rel="nofollow" href="https://www.academia.edu/75851380/Photochromism_of_Liquid_Crystalline_Polymers_with_Spiropyran_Derivatives">Photochromism of Liquid Crystalline Polymers with Spiropyran Derivatives</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Depnrtnienf of&#x27; Polynio. Science and Eriginerring. Hannnm Univevsit~~, Toeion 306-791 Korea ... Abstract New liquid crystalline polymers with spiropyran derivative for optical recording applications were prepared by radical... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_75851380" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Depnrtnienf of&#x27; Polynio. Science and Eriginerring. Hannnm Univevsit~~, Toeion 306-791 Korea ... Abstract New liquid crystalline polymers with spiropyran derivative for optical recording applications were prepared by radical polymerization from two different monomers composed of ...</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/75851380" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="83142831" href="https://tracuuxaydung.academia.edu/ChuongKim">Chuong Kim</a><script data-card-contents-for-user="83142831" type="text/json">{"id":83142831,"first_name":"Chuong","last_name":"Kim","domain_name":"tracuuxaydung","page_name":"ChuongKim","display_name":"Chuong Kim","profile_url":"https://tracuuxaydung.academia.edu/ChuongKim?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_75851380 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="75851380"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 75851380, container: ".js-paper-rank-work_75851380", }); 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$(".js-view-count[data-work-id=75851380]").text(description); $(".js-view-count-work_75851380").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_75851380").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="75851380"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">9</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="5104" rel="nofollow" href="https://www.academia.edu/Documents/in/Photochemistry">Photochemistry</a>, <script data-card-contents-for-ri="5104" type="text/json">{"id":5104,"name":"Photochemistry","url":"https://www.academia.edu/Documents/in/Photochemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="30766" rel="nofollow" href="https://www.academia.edu/Documents/in/Photochromism">Photochromism</a>, <script data-card-contents-for-ri="30766" type="text/json">{"id":30766,"name":"Photochromism","url":"https://www.academia.edu/Documents/in/Photochromism?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="30773" rel="nofollow" href="https://www.academia.edu/Documents/in/Spiropyran">Spiropyran</a>, <script data-card-contents-for-ri="30773" type="text/json">{"id":30773,"name":"Spiropyran","url":"https://www.academia.edu/Documents/in/Spiropyran?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="168481" rel="nofollow" href="https://www.academia.edu/Documents/in/UV_Vis_spectroscopy">UV/Vis spectroscopy</a><script data-card-contents-for-ri="168481" type="text/json">{"id":168481,"name":"UV/Vis spectroscopy","url":"https://www.academia.edu/Documents/in/UV_Vis_spectroscopy?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=75851380]'), work: {"id":75851380,"title":"Photochromism of Liquid Crystalline Polymers with Spiropyran Derivatives","created_at":"2022-04-08T14:04:15.160-07:00","url":"https://www.academia.edu/75851380/Photochromism_of_Liquid_Crystalline_Polymers_with_Spiropyran_Derivatives?f_ri=483677","dom_id":"work_75851380","summary":"Depnrtnienf of\u0026#x27; Polynio. Science and Eriginerring. Hannnm Univevsit~~, Toeion 306-791 Korea ... Abstract New liquid crystalline polymers with spiropyran derivative for optical recording applications were prepared by radical polymerization from two different monomers composed of ...","downloadable_attachments":[],"ordered_authors":[{"id":83142831,"first_name":"Chuong","last_name":"Kim","domain_name":"tracuuxaydung","page_name":"ChuongKim","display_name":"Chuong Kim","profile_url":"https://tracuuxaydung.academia.edu/ChuongKim?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":5104,"name":"Photochemistry","url":"https://www.academia.edu/Documents/in/Photochemistry?f_ri=483677","nofollow":true},{"id":30766,"name":"Photochromism","url":"https://www.academia.edu/Documents/in/Photochromism?f_ri=483677","nofollow":true},{"id":30773,"name":"Spiropyran","url":"https://www.academia.edu/Documents/in/Spiropyran?f_ri=483677","nofollow":true},{"id":168481,"name":"UV/Vis spectroscopy","url":"https://www.academia.edu/Documents/in/UV_Vis_spectroscopy?f_ri=483677","nofollow":true},{"id":389180,"name":"Thermal Stability","url":"https://www.academia.edu/Documents/in/Thermal_Stability?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":695018,"name":"Molecular weight","url":"https://www.academia.edu/Documents/in/Molecular_weight?f_ri=483677"},{"id":1398401,"name":"Indium tin oxide","url":"https://www.academia.edu/Documents/in/Indium_tin_oxide?f_ri=483677"},{"id":2545097,"name":"Radical Polymerization","url":"https://www.academia.edu/Documents/in/Radical_Polymerization?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_71298224" data-work_id="71298224" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/71298224/Synthesis_spectral_thermal_and_theoretical_studies_of_Cu_II_complexes_with_3_4_dimethylaminophenyl_1_2_pyridyl_prop_2_en_1_one_DMAPP_">Synthesis, spectral, thermal and theoretical studies of Cu(II) complexes with 3-[4′-dimethylaminophenyl]-1-(2-pyridyl)prop-2-en-1-one (DMAPP)</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Cu(II) complexes of 3-[4′-dimethylaminophenyl]-1-(2-pyridyl) prop-2-en-1-one (DMAPP) are prepared and characterized by elemental analysis as well as spectral studies (IR and UV–vis), ESR, magnetic susceptibilities and thermal studies. The... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_71298224" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Cu(II) complexes of 3-[4′-dimethylaminophenyl]-1-(2-pyridyl) prop-2-en-1-one (DMAPP) are prepared and characterized by elemental analysis as well as spectral studies (IR and UV–vis), ESR, magnetic susceptibilities and thermal studies. The effect of different alcoholic solvents as well as the temperature on the complex formation is studied. The effect of Cu(II) ion on the emission spectrum of the free chalcone is also assigned.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/71298224" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="fc5f41b0fac0be42a23950440535b2bc" rel="nofollow" data-download="{"attachment_id":80703143,"asset_id":71298224,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/80703143/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="71945963" href="https://independent.academia.edu/YusufAlNajjar">Yusuf Al-Najjar</a><script data-card-contents-for-user="71945963" type="text/json">{"id":71945963,"first_name":"Yusuf","last_name":"Al-Najjar","domain_name":"independent","page_name":"YusufAlNajjar","display_name":"Yusuf Al-Najjar","profile_url":"https://independent.academia.edu/YusufAlNajjar?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_71298224 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="71298224"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 71298224, container: ".js-paper-rank-work_71298224", }); 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The effect of different alcoholic solvents as well as the temperature on the complex formation is studied. The effect of Cu(II) ion on the emission spectrum of the free chalcone is also assigned.","downloadable_attachments":[{"id":80703143,"asset_id":71298224,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":71945963,"first_name":"Yusuf","last_name":"Al-Najjar","domain_name":"independent","page_name":"YusufAlNajjar","display_name":"Yusuf Al-Najjar","profile_url":"https://independent.academia.edu/YusufAlNajjar?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=483677","nofollow":true},{"id":35637,"name":"Molecular Mechanics","url":"https://www.academia.edu/Documents/in/Molecular_Mechanics?f_ri=483677","nofollow":true},{"id":94870,"name":"Metal Complexes","url":"https://www.academia.edu/Documents/in/Metal_Complexes?f_ri=483677","nofollow":true},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677","nofollow":true},{"id":149117,"name":"Magnetic Susceptibility","url":"https://www.academia.edu/Documents/in/Magnetic_Susceptibility?f_ri=483677"},{"id":321836,"name":"Spectrum","url":"https://www.academia.edu/Documents/in/Spectrum?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":645605,"name":"THEORETICAL AND COMPUTATIONAL CHEMISTRY","url":"https://www.academia.edu/Documents/in/THEORETICAL_AND_COMPUTATIONAL_CHEMISTRY?f_ri=483677"},{"id":1136570,"name":"Force Field Analysis","url":"https://www.academia.edu/Documents/in/Force_Field_Analysis?f_ri=483677"},{"id":1167882,"name":"Kinetic Parameter","url":"https://www.academia.edu/Documents/in/Kinetic_Parameter?f_ri=483677"},{"id":1242504,"name":"Molecular Dynamic Simulation","url":"https://www.academia.edu/Documents/in/Molecular_Dynamic_Simulation?f_ri=483677"},{"id":1724844,"name":"Molecular Structure","url":"https://www.academia.edu/Documents/in/Molecular_Structure?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_61267902" data-work_id="61267902" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/61267902/Properties_of_spray_deposited_tin_oxide_thin_films_derived_from_tri_n_butyltin_acetate">Properties of spray deposited tin oxide thin films derived from tri-n-butyltin acetate</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The thin films of undoped tin oxide were deposited using organotin compound tri-n-butyltin acetate onto the amorphous glass substrates at 673 K by spray pyrolysis technique. The spraying solution concentration of tri-n-butyltin acetate... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_61267902" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The thin films of undoped tin oxide were deposited using organotin compound tri-n-butyltin acetate onto the amorphous glass substrates at 673 K by spray pyrolysis technique. The spraying solution concentration of tri-n-butyltin acetate was varied from 12.5 to 100 mM to deposit thin films of tin oxide and their structural, electrical and optical properties have been studied, which were found to be solution concentration dependent. The thermal decomposition behaviour of the tri-n-butyltin acetate salt was studied using differential thermal analysis and thermal gravimetric analysis techniques. The preferred orientation of the film along (110) plane prevails upto 50 mM concentration, which shifts to (200) plane for higher concentrations. The values of room temperature electrical resistivity, carrier concentration and mobility of charge carrier were improved with rise in solution concentration. The samples deposited at 100 mM concentration exhibit better results than any other studied sample. The possible explanation for this is given in the present investigation.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/61267902" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="dfdbae886aea86b8aa29d51d811378bd" rel="nofollow" data-download="{"attachment_id":74354583,"asset_id":61267902,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/74354583/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="32827114" href="https://unishivaji.academia.edu/ShivajiSadale">Shivaji Sadale</a><script data-card-contents-for-user="32827114" type="text/json">{"id":32827114,"first_name":"Shivaji","last_name":"Sadale","domain_name":"unishivaji","page_name":"ShivajiSadale","display_name":"Shivaji Sadale","profile_url":"https://unishivaji.academia.edu/ShivajiSadale?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_61267902 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="61267902"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 61267902, container: ".js-paper-rank-work_61267902", }); 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The spraying solution concentration of tri-n-butyltin acetate was varied from 12.5 to 100 mM to deposit thin films of tin oxide and their structural, electrical and optical properties have been studied, which were found to be solution concentration dependent. The thermal decomposition behaviour of the tri-n-butyltin acetate salt was studied using differential thermal analysis and thermal gravimetric analysis techniques. The preferred orientation of the film along (110) plane prevails upto 50 mM concentration, which shifts to (200) plane for higher concentrations. The values of room temperature electrical resistivity, carrier concentration and mobility of charge carrier were improved with rise in solution concentration. The samples deposited at 100 mM concentration exhibit better results than any other studied sample. The possible explanation for this is given in the present investigation.","downloadable_attachments":[{"id":74354583,"asset_id":61267902,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":32827114,"first_name":"Shivaji","last_name":"Sadale","domain_name":"unishivaji","page_name":"ShivajiSadale","display_name":"Shivaji Sadale","profile_url":"https://unishivaji.academia.edu/ShivajiSadale?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":923,"name":"Technology","url":"https://www.academia.edu/Documents/in/Technology?f_ri=483677","nofollow":true},{"id":101573,"name":"Thin Film","url":"https://www.academia.edu/Documents/in/Thin_Film?f_ri=483677","nofollow":true},{"id":118582,"name":"Physical sciences","url":"https://www.academia.edu/Documents/in/Physical_sciences?f_ri=483677","nofollow":true},{"id":149116,"name":"Electrical Resistance","url":"https://www.academia.edu/Documents/in/Electrical_Resistance?f_ri=483677"},{"id":185380,"name":"Optical Properties","url":"https://www.academia.edu/Documents/in/Optical_Properties?f_ri=483677"},{"id":386527,"name":"X ray diffraction","url":"https://www.academia.edu/Documents/in/X_ray_diffraction?f_ri=483677"},{"id":391252,"name":"Room Temperature","url":"https://www.academia.edu/Documents/in/Room_Temperature?f_ri=483677"},{"id":396853,"name":"Differential Thermal Analysis","url":"https://www.academia.edu/Documents/in/Differential_Thermal_Analysis?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":494642,"name":"Structural Properties","url":"https://www.academia.edu/Documents/in/Structural_Properties?f_ri=483677"},{"id":537242,"name":"Thin Solid Films","url":"https://www.academia.edu/Documents/in/Thin_Solid_Films?f_ri=483677"},{"id":1004903,"name":"Spray Pyrolysis","url":"https://www.academia.edu/Documents/in/Spray_Pyrolysis?f_ri=483677"},{"id":1499550,"name":"Thermal gravimetric analysis","url":"https://www.academia.edu/Documents/in/Thermal_gravimetric_analysis?f_ri=483677"},{"id":1804663,"name":"Tin Oxide","url":"https://www.academia.edu/Documents/in/Tin_Oxide?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_48630866" data-work_id="48630866" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/48630866/Flame_Retardant_Textile_Back_Coatings_Part_1_Antimony_Halogen_System_Interactions_and_the_Effect_of_Replacement_by_Phosphorus_Containing_Agents">Flame Retardant Textile Back-Coatings. Part 1: Antimony-Halogen System Interactions and the Effect of Replacement by Phosphorus-Containing Agents</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A series of back-coated cotton fabrics comprising varying molar ratios of chlorine, bromine and antimony has been studied using a simulated match ignition test, LOI and thermal analysis (TGA and DTA). Results show that the presence of... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_48630866" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A series of back-coated cotton fabrics comprising varying molar ratios of chlorine, bromine and antimony has been studied using a simulated match ignition test, LOI and thermal analysis (TGA and DTA). Results show that the presence of chlorine alone and in combination with bromine increases LOI and carbonaceous char values at optimum halogen :anti- mony molar ratios of 2.5-3.6:1 and bromine:chlorine molar ratios within the range 0.31-0.42. Only back-coated samples containing bromine pass the simu- lated match test although at Br:Sb molar ratios above 4:1, LOI and char residual values decrease. It is evident that condensed and vapour phase flame retardant *Author to whom correspondence should be addressed.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/48630866" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="302a34c39c69f467b4c73d4b75661df3" rel="nofollow" data-download="{"attachment_id":67142964,"asset_id":48630866,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/67142964/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="72191709" href="https://independent.academia.edu/HorrocksRichard">Richard Horrocks</a><script data-card-contents-for-user="72191709" type="text/json">{"id":72191709,"first_name":"Richard","last_name":"Horrocks","domain_name":"independent","page_name":"HorrocksRichard","display_name":"Richard Horrocks","profile_url":"https://independent.academia.edu/HorrocksRichard?f_ri=483677","photo":"https://0.academia-photos.com/72191709/53862351/41996288/s65_richard.horrocks.png"}</script></span></span></li><li class="js-paper-rank-work_48630866 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="48630866"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 48630866, container: ".js-paper-rank-work_48630866", }); 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$(".js-view-count[data-work-id=48630866]").text(description); $(".js-view-count-work_48630866").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_48630866").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="48630866"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">16</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="56" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials_Engineering">Materials Engineering</a>, <script data-card-contents-for-ri="56" type="text/json">{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="1649" rel="nofollow" href="https://www.academia.edu/Documents/in/Ergonomics">Ergonomics</a>, <script data-card-contents-for-ri="1649" type="text/json">{"id":1649,"name":"Ergonomics","url":"https://www.academia.edu/Documents/in/Ergonomics?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="3762" rel="nofollow" href="https://www.academia.edu/Documents/in/Human_Factors">Human Factors</a>, <script data-card-contents-for-ri="3762" type="text/json">{"id":3762,"name":"Human Factors","url":"https://www.academia.edu/Documents/in/Human_Factors?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="10867" rel="nofollow" href="https://www.academia.edu/Documents/in/Fire">Fire</a><script data-card-contents-for-ri="10867" type="text/json">{"id":10867,"name":"Fire","url":"https://www.academia.edu/Documents/in/Fire?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=48630866]'), work: {"id":48630866,"title":"Flame Retardant Textile Back-Coatings. Part 1: Antimony-Halogen System Interactions and the Effect of Replacement by Phosphorus-Containing Agents","created_at":"2021-05-05T01:12:59.506-07:00","url":"https://www.academia.edu/48630866/Flame_Retardant_Textile_Back_Coatings_Part_1_Antimony_Halogen_System_Interactions_and_the_Effect_of_Replacement_by_Phosphorus_Containing_Agents?f_ri=483677","dom_id":"work_48630866","summary":"A series of back-coated cotton fabrics comprising varying molar ratios of chlorine, bromine and antimony has been studied using a simulated match ignition test, LOI and thermal analysis (TGA and DTA). Results show that the presence of chlorine alone and in combination with bromine increases LOI and carbonaceous char values at optimum halogen :anti- mony molar ratios of 2.5-3.6:1 and bromine:chlorine molar ratios within the range 0.31-0.42. Only back-coated samples containing bromine pass the simu- lated match test although at Br:Sb molar ratios above 4:1, LOI and char residual values decrease. It is evident that condensed and vapour phase flame retardant *Author to whom correspondence should be addressed.","downloadable_attachments":[{"id":67142964,"asset_id":48630866,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":72191709,"first_name":"Richard","last_name":"Horrocks","domain_name":"independent","page_name":"HorrocksRichard","display_name":"Richard Horrocks","profile_url":"https://independent.academia.edu/HorrocksRichard?f_ri=483677","photo":"https://0.academia-photos.com/72191709/53862351/41996288/s65_richard.horrocks.png"}],"research_interests":[{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true},{"id":1649,"name":"Ergonomics","url":"https://www.academia.edu/Documents/in/Ergonomics?f_ri=483677","nofollow":true},{"id":3762,"name":"Human Factors","url":"https://www.academia.edu/Documents/in/Human_Factors?f_ri=483677","nofollow":true},{"id":10867,"name":"Fire","url":"https://www.academia.edu/Documents/in/Fire?f_ri=483677","nofollow":true},{"id":12159,"name":"Injury Prevention","url":"https://www.academia.edu/Documents/in/Injury_Prevention?f_ri=483677"},{"id":49161,"name":"Safety","url":"https://www.academia.edu/Documents/in/Safety?f_ri=483677"},{"id":53108,"name":"Phosphorus","url":"https://www.academia.edu/Documents/in/Phosphorus?f_ri=483677"},{"id":80668,"name":"Cotton","url":"https://www.academia.edu/Documents/in/Cotton?f_ri=483677"},{"id":111180,"name":"Textile","url":"https://www.academia.edu/Documents/in/Textile?f_ri=483677"},{"id":176756,"name":"FORMULATION","url":"https://www.academia.edu/Documents/in/FORMULATION?f_ri=483677"},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677"},{"id":396851,"name":"Flame Retardant","url":"https://www.academia.edu/Documents/in/Flame_Retardant?f_ri=483677"},{"id":398652,"name":"Thermogravimetric Analysis","url":"https://www.academia.edu/Documents/in/Thermogravimetric_Analysis?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":488611,"name":"Occupational Safety","url":"https://www.academia.edu/Documents/in/Occupational_Safety?f_ri=483677"},{"id":1671783,"name":"Ignition","url":"https://www.academia.edu/Documents/in/Ignition?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_13516034" data-work_id="13516034" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/13516034/Atomistic_scale_simulations_of_chemical_reactions_Bridging_from_quantum_chemistry_to_engineering">Atomistic-scale simulations of chemical reactions: Bridging from quantum chemistry to engineering</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">We provide an overview of the ReaxFF reactive force field method and discuss each calculation performed to determine the energy of a system at each iteration step. The concept of bond order is examined as well as how it is used to... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_13516034" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">We provide an overview of the ReaxFF reactive force field method and discuss each calculation performed to determine the energy of a system at each iteration step. The concept of bond order is examined as well as how it is used to determine bonding, angle, and torsion energies. The calculation of the Coulomb and van der Waals non-bonded interactions is also discussed. In addition to a description of the ReaxFF method, we also investigate the thermal decomposition dynamics of a zinc-oxide nanowire with and without the presence of water. Our results indicate that the presence of water significantly weakens the ZnO surface bonding and leads to an acceleration of the failure of the material.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/13516034" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="0c2215b18c24858ca3b844219fdd5890" rel="nofollow" data-download="{"attachment_id":45249344,"asset_id":13516034,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/45249344/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="32713752" href="https://psu-us.academia.edu/AdriVanDuin">Adri van Duin</a><script data-card-contents-for-user="32713752" type="text/json">{"id":32713752,"first_name":"Adri","last_name":"van Duin","domain_name":"psu-us","page_name":"AdriVanDuin","display_name":"Adri van Duin","profile_url":"https://psu-us.academia.edu/AdriVanDuin?f_ri=483677","photo":"https://0.academia-photos.com/32713752/12699342/14125438/s65_adri.van_duin.jpg"}</script></span></span></li><li class="js-paper-rank-work_13516034 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="13516034"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 13516034, container: ".js-paper-rank-work_13516034", }); });</script></li><li class="js-percentile-work_13516034 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13516034; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_13516034"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_13516034 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="13516034"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13516034; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13516034]").text(description); $(".js-view-count-work_13516034").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_13516034").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="13516034"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">10</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="407" rel="nofollow" href="https://www.academia.edu/Documents/in/Geochemistry">Geochemistry</a>, <script data-card-contents-for-ri="407" type="text/json">{"id":407,"name":"Geochemistry","url":"https://www.academia.edu/Documents/in/Geochemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="529" rel="nofollow" href="https://www.academia.edu/Documents/in/Quantum_Chemistry">Quantum Chemistry</a>, <script data-card-contents-for-ri="529" type="text/json">{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="50628" rel="nofollow" href="https://www.academia.edu/Documents/in/Nanowires">Nanowires</a>, <script data-card-contents-for-ri="50628" type="text/json">{"id":50628,"name":"Nanowires","url":"https://www.academia.edu/Documents/in/Nanowires?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="58032" rel="nofollow" href="https://www.academia.edu/Documents/in/Zinc_Oxide">Zinc Oxide</a><script data-card-contents-for-ri="58032" type="text/json">{"id":58032,"name":"Zinc Oxide","url":"https://www.academia.edu/Documents/in/Zinc_Oxide?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=13516034]'), work: {"id":13516034,"title":"Atomistic-scale simulations of chemical reactions: Bridging from quantum chemistry to engineering","created_at":"2015-07-01T14:57:49.411-07:00","url":"https://www.academia.edu/13516034/Atomistic_scale_simulations_of_chemical_reactions_Bridging_from_quantum_chemistry_to_engineering?f_ri=483677","dom_id":"work_13516034","summary":"We provide an overview of the ReaxFF reactive force field method and discuss each calculation performed to determine the energy of a system at each iteration step. The concept of bond order is examined as well as how it is used to determine bonding, angle, and torsion energies. The calculation of the Coulomb and van der Waals non-bonded interactions is also discussed. In addition to a description of the ReaxFF method, we also investigate the thermal decomposition dynamics of a zinc-oxide nanowire with and without the presence of water. Our results indicate that the presence of water significantly weakens the ZnO surface bonding and leads to an acceleration of the failure of the material.","downloadable_attachments":[{"id":45249344,"asset_id":13516034,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":32713752,"first_name":"Adri","last_name":"van Duin","domain_name":"psu-us","page_name":"AdriVanDuin","display_name":"Adri van Duin","profile_url":"https://psu-us.academia.edu/AdriVanDuin?f_ri=483677","photo":"https://0.academia-photos.com/32713752/12699342/14125438/s65_adri.van_duin.jpg"}],"research_interests":[{"id":407,"name":"Geochemistry","url":"https://www.academia.edu/Documents/in/Geochemistry?f_ri=483677","nofollow":true},{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=483677","nofollow":true},{"id":50628,"name":"Nanowires","url":"https://www.academia.edu/Documents/in/Nanowires?f_ri=483677","nofollow":true},{"id":58032,"name":"Zinc Oxide","url":"https://www.academia.edu/Documents/in/Zinc_Oxide?f_ri=483677","nofollow":true},{"id":212517,"name":"Van Der Waals","url":"https://www.academia.edu/Documents/in/Van_Der_Waals?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":539878,"name":"Chemical Reaction","url":"https://www.academia.edu/Documents/in/Chemical_Reaction?f_ri=483677"},{"id":554780,"name":"Interdisciplinary Engineering","url":"https://www.academia.edu/Documents/in/Interdisciplinary_Engineering?f_ri=483677"},{"id":1136570,"name":"Force Field Analysis","url":"https://www.academia.edu/Documents/in/Force_Field_Analysis?f_ri=483677"},{"id":1242504,"name":"Molecular Dynamic Simulation","url":"https://www.academia.edu/Documents/in/Molecular_Dynamic_Simulation?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_14095609" data-work_id="14095609" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/14095609/Preparation_and_characterization_of_CuO_CeO_2_catalysts_and_their_applications_in_low_temperature_CO_oxidation">Preparation and characterization of CuO/CeO 2 catalysts and their applications in low-temperature CO oxidation</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">CeO2 nanoparticles were prepared by thermal decomposition of cerous nitrate and then used as supports for CuO/CeO2 catalysts prepared via the impregnation method. The samples were characterized by HRTEM, XRD, H2-TPR, and XPS. The... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_14095609" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">CeO2 nanoparticles were prepared by thermal decomposition of cerous nitrate and then used as supports for CuO/CeO2 catalysts prepared via the impregnation method. The samples were characterized by HRTEM, XRD, H2-TPR, and XPS. The catalytic properties of the prepared catalysts for low-temperature CO oxidation were studied by using a microreactor–GC system. The results showed that the thermal decomposition temperature affected</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/14095609" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="cd40de84609ec4ff30c23958e7c8e2eb" rel="nofollow" data-download="{"attachment_id":44608181,"asset_id":14095609,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/44608181/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="33101911" href="https://zju.academia.edu/ShihuaWu">Shihua Wu</a><script data-card-contents-for-user="33101911" type="text/json">{"id":33101911,"first_name":"Shihua","last_name":"Wu","domain_name":"zju","page_name":"ShihuaWu","display_name":"Shihua Wu","profile_url":"https://zju.academia.edu/ShihuaWu?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_14095609 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="14095609"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 14095609, container: ".js-paper-rank-work_14095609", }); 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$(".js-view-count[data-work-id=14095609]").text(description); $(".js-view-count-work_14095609").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_14095609").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="14095609"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">8</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="72" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemical_Engineering">Chemical Engineering</a>, <script data-card-contents-for-ri="72" type="text/json">{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="209107" rel="nofollow" href="https://www.academia.edu/Documents/in/CO_oxidation">CO oxidation</a>, <script data-card-contents-for-ri="209107" type="text/json">{"id":209107,"name":"CO oxidation","url":"https://www.academia.edu/Documents/in/CO_oxidation?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="368560" rel="nofollow" href="https://www.academia.edu/Documents/in/Crystallite_Size">Crystallite Size</a>, <script data-card-contents-for-ri="368560" type="text/json">{"id":368560,"name":"Crystallite Size","url":"https://www.academia.edu/Documents/in/Crystallite_Size?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="390245" rel="nofollow" href="https://www.academia.edu/Documents/in/Particle_Size">Particle Size</a><script data-card-contents-for-ri="390245" type="text/json">{"id":390245,"name":"Particle Size","url":"https://www.academia.edu/Documents/in/Particle_Size?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=14095609]'), work: {"id":14095609,"title":"Preparation and characterization of CuO/CeO 2 catalysts and their applications in low-temperature CO oxidation","created_at":"2015-07-15T18:53:47.815-07:00","url":"https://www.academia.edu/14095609/Preparation_and_characterization_of_CuO_CeO_2_catalysts_and_their_applications_in_low_temperature_CO_oxidation?f_ri=483677","dom_id":"work_14095609","summary":"CeO2 nanoparticles were prepared by thermal decomposition of cerous nitrate and then used as supports for CuO/CeO2 catalysts prepared via the impregnation method. The samples were characterized by HRTEM, XRD, H2-TPR, and XPS. The catalytic properties of the prepared catalysts for low-temperature CO oxidation were studied by using a microreactor–GC system. The results showed that the thermal decomposition temperature affected","downloadable_attachments":[{"id":44608181,"asset_id":14095609,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":33101911,"first_name":"Shihua","last_name":"Wu","domain_name":"zju","page_name":"ShihuaWu","display_name":"Shihua Wu","profile_url":"https://zju.academia.edu/ShihuaWu?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true},{"id":209107,"name":"CO oxidation","url":"https://www.academia.edu/Documents/in/CO_oxidation?f_ri=483677","nofollow":true},{"id":368560,"name":"Crystallite Size","url":"https://www.academia.edu/Documents/in/Crystallite_Size?f_ri=483677","nofollow":true},{"id":390245,"name":"Particle Size","url":"https://www.academia.edu/Documents/in/Particle_Size?f_ri=483677","nofollow":true},{"id":415784,"name":"Phase Separation","url":"https://www.academia.edu/Documents/in/Phase_Separation?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":1228946,"name":"Physical Properties","url":"https://www.academia.edu/Documents/in/Physical_Properties?f_ri=483677"},{"id":1277798,"name":"Catalytic Activity","url":"https://www.academia.edu/Documents/in/Catalytic_Activity?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_37678947" data-work_id="37678947" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/37678947/Thermal_decomposition_of_bauxite_minerals_infrared_emission_spectroscopy_of_gibbsite_boehmite_and_diaspore">Thermal decomposition of bauxite minerals: infrared emission spectroscopy of gibbsite, boehmite and diaspore</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Infrared emission spectroscopy has been used to study the dehydroxylation behavior over the temperature range from 200 to 750 degrees Celsius of three major Al-minerals in bauxite: gibbsite (synthetic and natural), boehmite (synthetic and... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_37678947" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Infrared emission spectroscopy has been used to study the dehydroxylation behavior over the temperature range from 200 to 750 degrees Celsius of three major Al-minerals in bauxite: gibbsite (synthetic and natural), boehmite (synthetic and natural) and diaspore. A good agreement is found with the thermal analysis and differential thermal analysis curves of these minerals. Loss in intensity of especially the hydroxyl-stretching modes of gibbsite, boehmite and diaspore as function of temperature correspond well with the observed changes in the TGA/DTA patterns. The DTA pattern of gibbsite clearly indicates the formation of boehmite as an intermediate shown by a endotherm around 500 degrees Celsius. Dehydroxylation of gibbsite is followed by a loss of intensity of the 3620 and 3351 cm-1 OH-stretching bands and the corresponding deformation band around 1024 cm-1. Dehydroxylation starts around 220 degrees Celsius and is complete around 350 degrees Celsius. Similar observations were made for boehmite and diaspore. For boehmite dehydroxylation was observed to commence around 250 degrees Celsius and could be followed by especially the loss in intensity of the bands around 3319 and 3129 cm-1. The DTA pattern of diaspore is more complex with overlapping endotherms around 622 and 650 degrees Celsius. The dehydroxylation can be followed by the decrease in intensity of the OH-stretching bands around 3667, 3215 and 2972 cm-1. Above 550 degrees Celsius only a single band is observed that disappears after heating above 600 degrees Celsius corresponding to the two endotherms around 622 and 650 degrees Celsius in the DTA</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/37678947" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="16cee2d045479f170a116657b212a8ca" rel="nofollow" data-download="{"attachment_id":57668593,"asset_id":37678947,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/57668593/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="94226986" href="https://upvisayas.academia.edu/JTHEOKLOPROGGE">J. THEO KLOPROGGE</a><script data-card-contents-for-user="94226986" type="text/json">{"id":94226986,"first_name":"J. THEO","last_name":"KLOPROGGE","domain_name":"upvisayas","page_name":"JTHEOKLOPROGGE","display_name":"J. THEO KLOPROGGE","profile_url":"https://upvisayas.academia.edu/JTHEOKLOPROGGE?f_ri=483677","photo":"https://0.academia-photos.com/94226986/21035226/20527458/s65_j._theo.kloprogge.jpg"}</script></span></span></li><li class="js-paper-rank-work_37678947 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="37678947"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 37678947, container: ".js-paper-rank-work_37678947", }); });</script></li><li class="js-percentile-work_37678947 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 37678947; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_37678947"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_37678947 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="37678947"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 37678947; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=37678947]").text(description); $(".js-view-count-work_37678947").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_37678947").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="37678947"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">19</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="511" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials_Science">Materials Science</a>, <script data-card-contents-for-ri="511" type="text/json">{"id":511,"name":"Materials Science","url":"https://www.academia.edu/Documents/in/Materials_Science?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="6414" rel="nofollow" href="https://www.academia.edu/Documents/in/Decomposition">Decomposition</a>, <script data-card-contents-for-ri="6414" type="text/json">{"id":6414,"name":"Decomposition","url":"https://www.academia.edu/Documents/in/Decomposition?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="9533" rel="nofollow" href="https://www.academia.edu/Documents/in/Minerals">Minerals</a><script data-card-contents-for-ri="9533" type="text/json">{"id":9533,"name":"Minerals","url":"https://www.academia.edu/Documents/in/Minerals?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=37678947]'), work: {"id":37678947,"title":"Thermal decomposition of bauxite minerals: infrared emission spectroscopy of gibbsite, boehmite and diaspore","created_at":"2018-10-31T03:13:22.640-07:00","url":"https://www.academia.edu/37678947/Thermal_decomposition_of_bauxite_minerals_infrared_emission_spectroscopy_of_gibbsite_boehmite_and_diaspore?f_ri=483677","dom_id":"work_37678947","summary":"Infrared emission spectroscopy has been used to study the dehydroxylation behavior over the temperature range from 200 to 750 degrees Celsius of three major Al-minerals in bauxite: gibbsite (synthetic and natural), boehmite (synthetic and natural) and diaspore. A good agreement is found with the thermal analysis and differential thermal analysis curves of these minerals. Loss in intensity of especially the hydroxyl-stretching modes of gibbsite, boehmite and diaspore as function of temperature correspond well with the observed changes in the TGA/DTA patterns. The DTA pattern of gibbsite clearly indicates the formation of boehmite as an intermediate shown by a endotherm around 500 degrees Celsius. Dehydroxylation of gibbsite is followed by a loss of intensity of the 3620 and 3351 cm-1 OH-stretching bands and the corresponding deformation band around 1024 cm-1. Dehydroxylation starts around 220 degrees Celsius and is complete around 350 degrees Celsius. Similar observations were made for boehmite and diaspore. For boehmite dehydroxylation was observed to commence around 250 degrees Celsius and could be followed by especially the loss in intensity of the bands around 3319 and 3129 cm-1. The DTA pattern of diaspore is more complex with overlapping endotherms around 622 and 650 degrees Celsius. The dehydroxylation can be followed by the decrease in intensity of the OH-stretching bands around 3667, 3215 and 2972 cm-1. Above 550 degrees Celsius only a single band is observed that disappears after heating above 600 degrees Celsius corresponding to the two endotherms around 622 and 650 degrees Celsius in the DTA","downloadable_attachments":[{"id":57668593,"asset_id":37678947,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":94226986,"first_name":"J. THEO","last_name":"KLOPROGGE","domain_name":"upvisayas","page_name":"JTHEOKLOPROGGE","display_name":"J. THEO KLOPROGGE","profile_url":"https://upvisayas.academia.edu/JTHEOKLOPROGGE?f_ri=483677","photo":"https://0.academia-photos.com/94226986/21035226/20527458/s65_j._theo.kloprogge.jpg"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":511,"name":"Materials Science","url":"https://www.academia.edu/Documents/in/Materials_Science?f_ri=483677","nofollow":true},{"id":6414,"name":"Decomposition","url":"https://www.academia.edu/Documents/in/Decomposition?f_ri=483677","nofollow":true},{"id":9533,"name":"Minerals","url":"https://www.academia.edu/Documents/in/Minerals?f_ri=483677","nofollow":true},{"id":14925,"name":"Heat Treatment","url":"https://www.academia.edu/Documents/in/Heat_Treatment?f_ri=483677"},{"id":78842,"name":"Infrared spectroscopy","url":"https://www.academia.edu/Documents/in/Infrared_spectroscopy?f_ri=483677"},{"id":244898,"name":"Bauxite","url":"https://www.academia.edu/Documents/in/Bauxite?f_ri=483677"},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677"},{"id":335361,"name":"Infrared","url":"https://www.academia.edu/Documents/in/Infrared?f_ri=483677"},{"id":396853,"name":"Differential Thermal Analysis","url":"https://www.academia.edu/Documents/in/Differential_Thermal_Analysis?f_ri=483677"},{"id":398652,"name":"Thermogravimetric Analysis","url":"https://www.academia.edu/Documents/in/Thermogravimetric_Analysis?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":976620,"name":"Sedimentary Rocks","url":"https://www.academia.edu/Documents/in/Sedimentary_Rocks?f_ri=483677"},{"id":1019577,"name":"Absorption Spectra","url":"https://www.academia.edu/Documents/in/Absorption_Spectra?f_ri=483677"},{"id":1265916,"name":"Diaspore","url":"https://www.academia.edu/Documents/in/Diaspore?f_ri=483677"},{"id":1485664,"name":"Boehmite","url":"https://www.academia.edu/Documents/in/Boehmite?f_ri=483677"},{"id":3052553,"name":"Infrared Emission Spectroscopy","url":"https://www.academia.edu/Documents/in/Infrared_Emission_Spectroscopy?f_ri=483677"},{"id":3053699,"name":"hydroxide minerals","url":"https://www.academia.edu/Documents/in/hydroxide_minerals?f_ri=483677"},{"id":3053701,"name":"gibbsite","url":"https://www.academia.edu/Documents/in/gibbsite?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_5334538" data-work_id="5334538" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/5334538/Structure_and_Surface_and_Catalytic_Properties_of_Mg_Al_Basic_Oxides">Structure and Surface and Catalytic Properties of Mg-Al Basic Oxides</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Mg-Al mixed oxides with Mg/Al molar ratios of 0.5-9.0 were obtained by thermal decomposition of precipitated hydrotalcite precursors. The effect of composition on structure and surface and catalytic properties was studied by combining... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_5334538" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Mg-Al mixed oxides with Mg/Al molar ratios of 0.5-9.0 were obtained by thermal decomposition of precipitated hydrotalcite precursors. The effect of composition on structure and surface and catalytic properties was studied by combining several characterization methods with ethanol conversion reactions. The nature, density, and strength of surface basic sites depended on the Al content. On pure MgO, strong basic sites consisted predominantly of O 2− anions. Calcined hydrotalcites contained surface sites of low (OH − groups), medium (Mg-O pairs), and strong (O 2− anions) basicity. The relative abundance of low and medium strength basic sites increased with the Al content. The addition of small amounts of Al to MgO diminished drastically the density of surface basic sites because of a significant Al surface enrichment. Formation of surface amorphous AlO y structures in samples with low Al content (Mg/Al > 5) partially covered the Mg-O pairs and decreased the concentration of surface O 2− anions. At higher Al contents (5 > Mg/Al > 1), the basic site density increased because the Al 3+ cations within the MgO lattice created a defect in order to compensate the positive charge generated, and the adjacent oxygen anions became coordinatively unsaturated. In samples with Mg/Al < 1, segregation of bulk MgAl 2 O 4 spinels occurred and caused the basic site density to diminish. The catalyst activity and selectivity of Mg-Al mixed oxides in ethanol conversion reactions depended on composition. The dehydrogenation of ethanol to acetaldehyde and the aldol condensation to n-butanol both involved the initial surface ethoxide formation on a Lewis acid-strong base pair. Pure MgO exhibited poor activity because the predominant presence of isolated O 2− basic centers hindered formation of the ethoxide intermediate by ethanol dissociative adsorption.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/5334538" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="8c1dc083907fec1ead60a89e49635cad" rel="nofollow" data-download="{"attachment_id":49336764,"asset_id":5334538,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49336764/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="7379454" href="https://independent.academia.edu/IglesiasEnrique">Enrique Iglesias</a><script data-card-contents-for-user="7379454" type="text/json">{"id":7379454,"first_name":"Enrique","last_name":"Iglesias","domain_name":"independent","page_name":"IglesiasEnrique","display_name":"Enrique Iglesias","profile_url":"https://independent.academia.edu/IglesiasEnrique?f_ri=483677","photo":"https://0.academia-photos.com/7379454/2714897/3161345/s65_enrique.iglesias.jpg"}</script></span></span></li><li class="js-paper-rank-work_5334538 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="5334538"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 5334538, container: ".js-paper-rank-work_5334538", }); 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The effect of composition on structure and surface and catalytic properties was studied by combining several characterization methods with ethanol conversion reactions. The nature, density, and strength of surface basic sites depended on the Al content. On pure MgO, strong basic sites consisted predominantly of O 2− anions. Calcined hydrotalcites contained surface sites of low (OH − groups), medium (Mg-O pairs), and strong (O 2− anions) basicity. The relative abundance of low and medium strength basic sites increased with the Al content. The addition of small amounts of Al to MgO diminished drastically the density of surface basic sites because of a significant Al surface enrichment. Formation of surface amorphous AlO y structures in samples with low Al content (Mg/Al \u003e 5) partially covered the Mg-O pairs and decreased the concentration of surface O 2− anions. At higher Al contents (5 \u003e Mg/Al \u003e 1), the basic site density increased because the Al 3+ cations within the MgO lattice created a defect in order to compensate the positive charge generated, and the adjacent oxygen anions became coordinatively unsaturated. In samples with Mg/Al \u003c 1, segregation of bulk MgAl 2 O 4 spinels occurred and caused the basic site density to diminish. The catalyst activity and selectivity of Mg-Al mixed oxides in ethanol conversion reactions depended on composition. The dehydrogenation of ethanol to acetaldehyde and the aldol condensation to n-butanol both involved the initial surface ethoxide formation on a Lewis acid-strong base pair. Pure MgO exhibited poor activity because the predominant presence of isolated O 2− basic centers hindered formation of the ethoxide intermediate by ethanol dissociative adsorption.","downloadable_attachments":[{"id":49336764,"asset_id":5334538,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":7379454,"first_name":"Enrique","last_name":"Iglesias","domain_name":"independent","page_name":"IglesiasEnrique","display_name":"Enrique Iglesias","profile_url":"https://independent.academia.edu/IglesiasEnrique?f_ri=483677","photo":"https://0.academia-photos.com/7379454/2714897/3161345/s65_enrique.iglesias.jpg"}],"research_interests":[{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true},{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true},{"id":745347,"name":"Relative Abundance","url":"https://www.academia.edu/Documents/in/Relative_Abundance?f_ri=483677","nofollow":true},{"id":1342517,"name":"Magnesium Oxide","url":"https://www.academia.edu/Documents/in/Magnesium_Oxide?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_6501689" data-work_id="6501689" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/6501689/Study_on_the_obtaining_of_cobalt_oxides_by_thermal_decomposition_of_some_complex_combinations_undispersed_and_dispersed_in_SiO_2_matrix">Study on the obtaining of cobalt oxides by thermal decomposition of some complex combinations, undispersed and dispersed in SiO 2 matrix</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In order to obtain cobalt oxides nanoparticles we have used the thermal decomposition of some carboxylate type precursors. These precursors were obtained by the redox reaction between cobalt nitrate and ethylene glycol, either bulk or... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_6501689" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In order to obtain cobalt oxides nanoparticles we have used the thermal decomposition of some carboxylate type precursors. These precursors were obtained by the redox reaction between cobalt nitrate and ethylene glycol, either bulk or dispersed in silica matrix. The redox reaction takes place by heating the Co(NO3)2·6H2O-C2H6O2 solution or the Si(OC2H5)4-Co(NO3)2·6H2O-C2H6O2 gels. Thermal analysis of the Co(NO3)2·6H2O-C2H6O2 solution and Si(OC2H5)-Co(NO3)2·6H2O-C2H6O2 gels allowed us to establish the optimal value for the synthesis temperature of the carboxylate precursors. By fast heating of the solution Co(NO3)2·6H2O-C2H6O2, the redox reaction is immediately followed by the decomposition of the precursor, which represents an autocombustion process. The product of this combustion contains CoO as unique phase. We have obtained a mixture of CoO and Co3O4 by annealing the synthesized carboxylate compounds for 2 h at 400°C. With longer annealing time (6 h), we have obtained Co3O4 as unique phase. The XRD study of the crystalline phases resulted by thermal decomposition of the precursors embedded in silica matrix, showed that the formation of Co2SiO4 and Co3O4, as unique phases, depends on the thermal treatment.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/6501689" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="f6484047f64d1e6a0ecbc6d1a49af63a" rel="nofollow" data-download="{"attachment_id":48840148,"asset_id":6501689,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/48840148/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="10361123" href="https://independent.academia.edu/marcelastoia">marcela stoia</a><script data-card-contents-for-user="10361123" type="text/json">{"id":10361123,"first_name":"marcela","last_name":"stoia","domain_name":"independent","page_name":"marcelastoia","display_name":"marcela stoia","profile_url":"https://independent.academia.edu/marcelastoia?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_6501689 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="6501689"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 6501689, container: ".js-paper-rank-work_6501689", }); 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These precursors were obtained by the redox reaction between cobalt nitrate and ethylene glycol, either bulk or dispersed in silica matrix. The redox reaction takes place by heating the Co(NO3)2·6H2O-C2H6O2 solution or the Si(OC2H5)4-Co(NO3)2·6H2O-C2H6O2 gels. Thermal analysis of the Co(NO3)2·6H2O-C2H6O2 solution and Si(OC2H5)-Co(NO3)2·6H2O-C2H6O2 gels allowed us to establish the optimal value for the synthesis temperature of the carboxylate precursors. By fast heating of the solution Co(NO3)2·6H2O-C2H6O2, the redox reaction is immediately followed by the decomposition of the precursor, which represents an autocombustion process. The product of this combustion contains CoO as unique phase. We have obtained a mixture of CoO and Co3O4 by annealing the synthesized carboxylate compounds for 2 h at 400°C. With longer annealing time (6 h), we have obtained Co3O4 as unique phase. The XRD study of the crystalline phases resulted by thermal decomposition of the precursors embedded in silica matrix, showed that the formation of Co2SiO4 and Co3O4, as unique phases, depends on the thermal treatment.","downloadable_attachments":[{"id":48840148,"asset_id":6501689,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":10361123,"first_name":"marcela","last_name":"stoia","domain_name":"independent","page_name":"marcelastoia","display_name":"marcela stoia","profile_url":"https://independent.academia.edu/marcelastoia?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":98440,"name":"Silica","url":"https://www.academia.edu/Documents/in/Silica?f_ri=483677","nofollow":true},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677","nofollow":true},{"id":394503,"name":"Thermal Treatment","url":"https://www.academia.edu/Documents/in/Thermal_Treatment?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true},{"id":1650162,"name":"Ethylene Glycol","url":"https://www.academia.edu/Documents/in/Ethylene_Glycol?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_27924337" data-work_id="27924337" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/27924337/Thermal_decomposition_of_allantoin_as_probed_by_matrix_isolation_FTIR_spectroscopy">Thermal decomposition of allantoin as probed by matrix isolation FTIR spectroscopy</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest">Low temperature matrix isolation and room temperature crystalline state IR spectra Thermal decomposition a b s t r a c t</div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/27924337" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="626de53098b3dd02fb8e7bfaa1ebd8f4" rel="nofollow" data-download="{"attachment_id":48220060,"asset_id":27924337,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/48220060/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="52211894" href="https://uc-pt.academia.edu/RFausto">R. 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Fausto","profile_url":"https://uc-pt.academia.edu/RFausto?f_ri=483677","photo":"https://0.academia-photos.com/52211894/13810776/14906075/s65_r..fausto.jpg"}],"research_interests":[{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=483677","nofollow":true},{"id":435190,"name":"Tetrahedron","url":"https://www.academia.edu/Documents/in/Tetrahedron?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_9672480" data-work_id="9672480" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/9672480/Preparation_of_La0_3Sr0_7CoO3_perovskite_by_thermal_decomposition_of_metal_EDTA_complexes">Preparation of La0.3Sr0.7CoO3– perovskite by thermal decomposition of metal-EDTA complexes</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Perovskite powders of La 0.3 Sr 0.7 CoO 3−d were prepared by the thermal decomposition of precursor complexes derived from nitrate solutions using ethylenediaminetetraacetic acid (EDTA) as a complexing agent. The calcination temperature... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_9672480" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Perovskite powders of La 0.3 Sr 0.7 CoO 3−d were prepared by the thermal decomposition of precursor complexes derived from nitrate solutions using ethylenediaminetetraacetic acid (EDTA) as a complexing agent. The calcination temperature is 920°C. Powders thus obtained have a low carbon contamination. Dense ceramics with a relative density of about 96% have been prepared after sintering at 1150°C.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/9672480" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="968800028ca55173dfb0831d8c08d888" rel="nofollow" data-download="{"attachment_id":39242817,"asset_id":9672480,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39242817/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="1013835" href="https://utwente.academia.edu/LouisWinnubst">Louis Winnubst</a><script data-card-contents-for-user="1013835" type="text/json">{"id":1013835,"first_name":"Louis","last_name":"Winnubst","domain_name":"utwente","page_name":"LouisWinnubst","display_name":"Louis Winnubst","profile_url":"https://utwente.academia.edu/LouisWinnubst?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_9672480 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="9672480"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 9672480, container: ".js-paper-rank-work_9672480", }); 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$(".js-view-count[data-work-id=9672480]").text(description); $(".js-view-count-work_9672480").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_9672480").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="9672480"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">6</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="2305" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials_Chemistry">Materials Chemistry</a>, <script data-card-contents-for-ri="2305" type="text/json">{"id":2305,"name":"Materials Chemistry","url":"https://www.academia.edu/Documents/in/Materials_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="10650" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials">Materials</a>, <script data-card-contents-for-ri="10650" type="text/json">{"id":10650,"name":"Materials","url":"https://www.academia.edu/Documents/in/Materials?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="260118" rel="nofollow" href="https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES">CHEMICAL SCIENCES</a><script data-card-contents-for-ri="260118" type="text/json">{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=9672480]'), work: {"id":9672480,"title":"Preparation of La0.3Sr0.7CoO3– perovskite by thermal decomposition of metal-EDTA complexes","created_at":"2014-12-08T05:05:33.871-08:00","url":"https://www.academia.edu/9672480/Preparation_of_La0_3Sr0_7CoO3_perovskite_by_thermal_decomposition_of_metal_EDTA_complexes?f_ri=483677","dom_id":"work_9672480","summary":"Perovskite powders of La 0.3 Sr 0.7 CoO 3−d were prepared by the thermal decomposition of precursor complexes derived from nitrate solutions using ethylenediaminetetraacetic acid (EDTA) as a complexing agent. The calcination temperature is 920°C. Powders thus obtained have a low carbon contamination. Dense ceramics with a relative density of about 96% have been prepared after sintering at 1150°C.","downloadable_attachments":[{"id":39242817,"asset_id":9672480,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":1013835,"first_name":"Louis","last_name":"Winnubst","domain_name":"utwente","page_name":"LouisWinnubst","display_name":"Louis Winnubst","profile_url":"https://utwente.academia.edu/LouisWinnubst?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":2305,"name":"Materials Chemistry","url":"https://www.academia.edu/Documents/in/Materials_Chemistry?f_ri=483677","nofollow":true},{"id":10650,"name":"Materials","url":"https://www.academia.edu/Documents/in/Materials?f_ri=483677","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677","nofollow":true},{"id":336524,"name":"Relative Density","url":"https://www.academia.edu/Documents/in/Relative_Density?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_11824706" data-work_id="11824706" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/11824706/The_thermal_decomposition_of_huntite_and_hydromagnesite_A_review">The thermal decomposition of huntite and hydromagnesite—A review</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Naturally occurring mixtures of hydromagnesite and huntite are important industrial minerals. Their endothermic decomposition over a specific temperature range, releasing water and carbon dioxide, has lead to such mixtures being... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_11824706" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Naturally occurring mixtures of hydromagnesite and huntite are important industrial minerals. Their endothermic decomposition over a specific temperature range, releasing water and carbon dioxide, has lead to such mixtures being successfully used as fire retardants, often replacing aluminium hydroxide or magnesium hydroxide. The current understanding of the structure and thermal decomposition mechanism of both minerals and their combination in natural mixtures is reviewed. The crystalline structure of both minerals has been fully characterised. The thermal decomposition of huntite has been characterised and is relatively simple. However, the thermal decomposition mechanism of hydromagnesite is sensitive to many factors including rate of heating and the composition of the atmosphere. The partial pressure of carbon dioxide significantly affects the decomposition mechanism of hydromagnesite causing magnesium carbonate to crystallise and decompose at a higher temperature instead of decomposing directly to magnesium oxide.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/11824706" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="5291cda612630f43b1e10672db7b2f1b" rel="nofollow" data-download="{"attachment_id":46502812,"asset_id":11824706,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/46502812/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="29167001" href="https://lboro.academia.edu/LukeHollingbery">Luke Hollingbery</a><script data-card-contents-for-user="29167001" type="text/json">{"id":29167001,"first_name":"Luke","last_name":"Hollingbery","domain_name":"lboro","page_name":"LukeHollingbery","display_name":"Luke Hollingbery","profile_url":"https://lboro.academia.edu/LukeHollingbery?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_11824706 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="11824706"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 11824706, container: ".js-paper-rank-work_11824706", }); 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$(".js-view-count[data-work-id=11824706]").text(description); $(".js-view-count-work_11824706").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_11824706").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="11824706"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">4</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4594" rel="nofollow" href="https://www.academia.edu/Documents/in/Carbon_Dioxide">Carbon Dioxide</a>, <script data-card-contents-for-ri="4594" type="text/json">{"id":4594,"name":"Carbon Dioxide","url":"https://www.academia.edu/Documents/in/Carbon_Dioxide?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="70902" rel="nofollow" href="https://www.academia.edu/Documents/in/Magnesium">Magnesium</a>, <script data-card-contents-for-ri="70902" type="text/json">{"id":70902,"name":"Magnesium","url":"https://www.academia.edu/Documents/in/Magnesium?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="483677" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_Decomposition">Thermal Decomposition</a><script data-card-contents-for-ri="483677" type="text/json">{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=11824706]'), work: {"id":11824706,"title":"The thermal decomposition of huntite and hydromagnesite—A review","created_at":"2015-04-07T02:22:28.706-07:00","url":"https://www.academia.edu/11824706/The_thermal_decomposition_of_huntite_and_hydromagnesite_A_review?f_ri=483677","dom_id":"work_11824706","summary":"Naturally occurring mixtures of hydromagnesite and huntite are important industrial minerals. Their endothermic decomposition over a specific temperature range, releasing water and carbon dioxide, has lead to such mixtures being successfully used as fire retardants, often replacing aluminium hydroxide or magnesium hydroxide. The current understanding of the structure and thermal decomposition mechanism of both minerals and their combination in natural mixtures is reviewed. The crystalline structure of both minerals has been fully characterised. The thermal decomposition of huntite has been characterised and is relatively simple. However, the thermal decomposition mechanism of hydromagnesite is sensitive to many factors including rate of heating and the composition of the atmosphere. The partial pressure of carbon dioxide significantly affects the decomposition mechanism of hydromagnesite causing magnesium carbonate to crystallise and decompose at a higher temperature instead of decomposing directly to magnesium oxide.","downloadable_attachments":[{"id":46502812,"asset_id":11824706,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":29167001,"first_name":"Luke","last_name":"Hollingbery","domain_name":"lboro","page_name":"LukeHollingbery","display_name":"Luke Hollingbery","profile_url":"https://lboro.academia.edu/LukeHollingbery?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true},{"id":4594,"name":"Carbon Dioxide","url":"https://www.academia.edu/Documents/in/Carbon_Dioxide?f_ri=483677","nofollow":true},{"id":70902,"name":"Magnesium","url":"https://www.academia.edu/Documents/in/Magnesium?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_19359545" data-work_id="19359545" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/19359545/Production_of_olefins_via_steam_cracking_of_vegetable_oils">Production of olefins via steam cracking of vegetable oils</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Vegetable oils (in Europe particularly rapeseed) are the favoured raw material for production of methyl esters to be used as biodiesel. This paper discloses a possibility of their alternative utilization as crude oil substitute via... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_19359545" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Vegetable oils (in Europe particularly rapeseed) are the favoured raw material for production of methyl esters to be used as biodiesel. This paper discloses a possibility of their alternative utilization as crude oil substitute via vegetable oil steam cracking to produce short alkenes to be used in polyolefins production industry. During thermal decomposition under conditions matching those of gas-oil steam cracking (short residence time, temperature over 800 • C) vegetable oils form similar products as traditional crude-oilbased feedstocks. The yields of major pyrolysis products of various vegetable oils were determined using the apparatus employed previously to laboratory research of hydrocarbon pyrolysis and they were compared to yields obtained by cracking traditional feedstocks. Also the effects of hydrocarbon chain length and saturation of acyls forming the oils were analyzed in detail. The possibilities of processing vegetable oils by co-cracking in mixture with crude oil feedstocks are discussed and supported by experimental data.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/19359545" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="31588307dcbf42c1d94a9ce125e1fbd1" rel="nofollow" data-download="{"attachment_id":40577190,"asset_id":19359545,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40577190/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="39625641" href="https://vscht.academia.edu/PetrZ%C3%A1mostn%C3%BD">Petr Zámostný</a><script data-card-contents-for-user="39625641" type="text/json">{"id":39625641,"first_name":"Petr","last_name":"Zámostný","domain_name":"vscht","page_name":"PetrZámostný","display_name":"Petr Zámostný","profile_url":"https://vscht.academia.edu/PetrZ%C3%A1mostn%C3%BD?f_ri=483677","photo":"https://0.academia-photos.com/39625641/11238727/12539770/s65_petr.z_mostn_.jpg"}</script></span></span></li><li class="js-paper-rank-work_19359545 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="19359545"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 19359545, container: ".js-paper-rank-work_19359545", }); });</script></li><li class="js-percentile-work_19359545 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 19359545; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_19359545"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_19359545 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="19359545"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 19359545; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=19359545]").text(description); $(".js-view-count-work_19359545").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_19359545").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="19359545"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">9</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="58054" rel="nofollow" href="https://www.academia.edu/Documents/in/Environmental_Sciences">Environmental Sciences</a>, <script data-card-contents-for-ri="58054" type="text/json">{"id":58054,"name":"Environmental Sciences","url":"https://www.academia.edu/Documents/in/Environmental_Sciences?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="80691" rel="nofollow" href="https://www.academia.edu/Documents/in/Raw_materials">Raw materials</a>, <script data-card-contents-for-ri="80691" type="text/json">{"id":80691,"name":"Raw materials","url":"https://www.academia.edu/Documents/in/Raw_materials?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="283329" rel="nofollow" href="https://www.academia.edu/Documents/in/Vegetable_oil">Vegetable oil</a><script data-card-contents-for-ri="283329" type="text/json">{"id":283329,"name":"Vegetable oil","url":"https://www.academia.edu/Documents/in/Vegetable_oil?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=19359545]'), work: {"id":19359545,"title":"Production of olefins via steam cracking of vegetable oils","created_at":"2015-12-02T08:09:52.582-08:00","url":"https://www.academia.edu/19359545/Production_of_olefins_via_steam_cracking_of_vegetable_oils?f_ri=483677","dom_id":"work_19359545","summary":"Vegetable oils (in Europe particularly rapeseed) are the favoured raw material for production of methyl esters to be used as biodiesel. This paper discloses a possibility of their alternative utilization as crude oil substitute via vegetable oil steam cracking to produce short alkenes to be used in polyolefins production industry. During thermal decomposition under conditions matching those of gas-oil steam cracking (short residence time, temperature over 800 • C) vegetable oils form similar products as traditional crude-oilbased feedstocks. The yields of major pyrolysis products of various vegetable oils were determined using the apparatus employed previously to laboratory research of hydrocarbon pyrolysis and they were compared to yields obtained by cracking traditional feedstocks. Also the effects of hydrocarbon chain length and saturation of acyls forming the oils were analyzed in detail. The possibilities of processing vegetable oils by co-cracking in mixture with crude oil feedstocks are discussed and supported by experimental data.","downloadable_attachments":[{"id":40577190,"asset_id":19359545,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":39625641,"first_name":"Petr","last_name":"Zámostný","domain_name":"vscht","page_name":"PetrZámostný","display_name":"Petr Zámostný","profile_url":"https://vscht.academia.edu/PetrZ%C3%A1mostn%C3%BD?f_ri=483677","photo":"https://0.academia-photos.com/39625641/11238727/12539770/s65_petr.z_mostn_.jpg"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":58054,"name":"Environmental Sciences","url":"https://www.academia.edu/Documents/in/Environmental_Sciences?f_ri=483677","nofollow":true},{"id":80691,"name":"Raw materials","url":"https://www.academia.edu/Documents/in/Raw_materials?f_ri=483677","nofollow":true},{"id":283329,"name":"Vegetable oil","url":"https://www.academia.edu/Documents/in/Vegetable_oil?f_ri=483677","nofollow":true},{"id":316233,"name":"Crude Oil","url":"https://www.academia.edu/Documents/in/Crude_Oil?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":984993,"name":"Residence Time","url":"https://www.academia.edu/Documents/in/Residence_Time?f_ri=483677"},{"id":1120502,"name":"Experimental Data","url":"https://www.academia.edu/Documents/in/Experimental_Data?f_ri=483677"},{"id":1358142,"name":"Methyl Ester","url":"https://www.academia.edu/Documents/in/Methyl_Ester?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_19118802" data-work_id="19118802" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/19118802/Comparison_of_the_kinetics_of_thermal_decomposition_of_biological_substances_between_thermogravimetry_and_a_fielded_pyrolysis_bioaerosol_detector">Comparison of the kinetics of thermal decomposition of biological substances between thermogravimetry and a fielded pyrolysis bioaerosol detector</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Thermal decomposition processes were investigated for Bacillus Gram-positive spores. Thermogravimetry analysis (TGA) experiments at 200 K min −1 produced a temporal evolution of biochemicals from the spores. Qualitative and quantitative... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_19118802" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Thermal decomposition processes were investigated for Bacillus Gram-positive spores. Thermogravimetry analysis (TGA) experiments at 200 K min −1 produced a temporal evolution of biochemicals from the spores. Qualitative and quantitative aspects such as peak resolution, peak ratios, peak positions, and temperature maxima are compared and contrasted in the thermal weight loss and differential thermogravimetry (DTG) curves for different Bacillus bacterial spores. The TGA experimental data were used to generate the activation energy and frequency factor Arrhenius equation parameters. These parameters were used to produce TGA and the negative of the first derivative of the TGA (−DTG) decomposition model curves, and the latter are compared to their respective bacterial experimental TGA and −DTG profiles for validation and modeling purposes. The thermal decomposition model is also shown to have application in the prediction of weight loss profiles at significantly higher heating rates than that from the laboratory TGA system. The model thermal decomposition profiles are applied in comparisons to the total ion chromatograms of Bacillus atrophaeus bacterial spores generated by an outdoors fielded pyrolysis-gas chromatography-ion mobility spectrometry (Py-GC-IMS) bioaerosol detection system. Pyrolysis at a high heating rate of 3300 K min −1 was used. The bioaerosol detection system provides very similar qualitative information to the TGA and −DTG experimental and model profiles.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/19118802" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="4349ae8af2a76d1c0031075bef51cff8" rel="nofollow" data-download="{"attachment_id":40441792,"asset_id":19118802,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40441792/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="39303604" href="https://independent.academia.edu/JacekDworzanski">Jacek Dworzanski</a><script data-card-contents-for-user="39303604" type="text/json">{"id":39303604,"first_name":"Jacek","last_name":"Dworzanski","domain_name":"independent","page_name":"JacekDworzanski","display_name":"Jacek Dworzanski","profile_url":"https://independent.academia.edu/JacekDworzanski?f_ri=483677","photo":"https://0.academia-photos.com/39303604/136300130/125751942/s65_jacek.dworzanski.png"}</script></span></span></li><li class="js-paper-rank-work_19118802 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="19118802"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 19118802, container: ".js-paper-rank-work_19118802", }); });</script></li><li class="js-percentile-work_19118802 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 19118802; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_19118802"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_19118802 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="19118802"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 19118802; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=19118802]").text(description); $(".js-view-count-work_19118802").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_19118802").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="19118802"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">10</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4987" rel="nofollow" href="https://www.academia.edu/Documents/in/Kinetics">Kinetics</a>, <script data-card-contents-for-ri="4987" type="text/json">{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="55113" rel="nofollow" href="https://www.academia.edu/Documents/in/Ion_mobility_spectrometry">Ion mobility spectrometry</a>, <script data-card-contents-for-ri="55113" type="text/json">{"id":55113,"name":"Ion mobility spectrometry","url":"https://www.academia.edu/Documents/in/Ion_mobility_spectrometry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="83825" rel="nofollow" href="https://www.academia.edu/Documents/in/Gram_Positive">Gram Positive</a><script data-card-contents-for-ri="83825" type="text/json">{"id":83825,"name":"Gram Positive","url":"https://www.academia.edu/Documents/in/Gram_Positive?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=19118802]'), work: {"id":19118802,"title":"Comparison of the kinetics of thermal decomposition of biological substances between thermogravimetry and a fielded pyrolysis bioaerosol detector","created_at":"2015-11-27T16:45:53.512-08:00","url":"https://www.academia.edu/19118802/Comparison_of_the_kinetics_of_thermal_decomposition_of_biological_substances_between_thermogravimetry_and_a_fielded_pyrolysis_bioaerosol_detector?f_ri=483677","dom_id":"work_19118802","summary":"Thermal decomposition processes were investigated for Bacillus Gram-positive spores. Thermogravimetry analysis (TGA) experiments at 200 K min −1 produced a temporal evolution of biochemicals from the spores. Qualitative and quantitative aspects such as peak resolution, peak ratios, peak positions, and temperature maxima are compared and contrasted in the thermal weight loss and differential thermogravimetry (DTG) curves for different Bacillus bacterial spores. The TGA experimental data were used to generate the activation energy and frequency factor Arrhenius equation parameters. These parameters were used to produce TGA and the negative of the first derivative of the TGA (−DTG) decomposition model curves, and the latter are compared to their respective bacterial experimental TGA and −DTG profiles for validation and modeling purposes. The thermal decomposition model is also shown to have application in the prediction of weight loss profiles at significantly higher heating rates than that from the laboratory TGA system. The model thermal decomposition profiles are applied in comparisons to the total ion chromatograms of Bacillus atrophaeus bacterial spores generated by an outdoors fielded pyrolysis-gas chromatography-ion mobility spectrometry (Py-GC-IMS) bioaerosol detection system. Pyrolysis at a high heating rate of 3300 K min −1 was used. The bioaerosol detection system provides very similar qualitative information to the TGA and −DTG experimental and model profiles.","downloadable_attachments":[{"id":40441792,"asset_id":19118802,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":39303604,"first_name":"Jacek","last_name":"Dworzanski","domain_name":"independent","page_name":"JacekDworzanski","display_name":"Jacek Dworzanski","profile_url":"https://independent.academia.edu/JacekDworzanski?f_ri=483677","photo":"https://0.academia-photos.com/39303604/136300130/125751942/s65_jacek.dworzanski.png"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":55113,"name":"Ion mobility spectrometry","url":"https://www.academia.edu/Documents/in/Ion_mobility_spectrometry?f_ri=483677","nofollow":true},{"id":83825,"name":"Gram Positive","url":"https://www.academia.edu/Documents/in/Gram_Positive?f_ri=483677","nofollow":true},{"id":89805,"name":"Weight Loss","url":"https://www.academia.edu/Documents/in/Weight_Loss?f_ri=483677"},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677"},{"id":166448,"name":"Gas Chromatography","url":"https://www.academia.edu/Documents/in/Gas_Chromatography?f_ri=483677"},{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":1120502,"name":"Experimental Data","url":"https://www.academia.edu/Documents/in/Experimental_Data?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_18352675" data-work_id="18352675" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/18352675/Rapid_nickel_oxalate_thermal_decomposition_for_producing_fine_porous_nickel_metal_powders">Rapid nickel oxalate thermal decomposition for producing fine porous nickel metal powders</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Precursor nickel oxalate powder was entrained in pure argon and a 5% hydrogen-in-argon carrier gas flow and carried through a heated transport tube reactor. The reactor wall temperature was maintained at 748-1018 K for residence times... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_18352675" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Precursor nickel oxalate powder was entrained in pure argon and a 5% hydrogen-in-argon carrier gas flow and carried through a heated transport tube reactor. The reactor wall temperature was maintained at 748-1018 K for residence times less than 4 s. Rapid reaction was possible because of high particle heating rates. A 5% addition of hydrogen to the carrier allowed for the synthesis of a high-purity elemental nickel powder with low residual oxygen content. Product particles consisted of nano-sized primary particles contained within an overall microcontainer matrix. Primary nickel particles nucleated within the precursor microcontainer matrix, followed by a coalescence period. The product powder was characterized as 2-40 m diameter microcontainer particles comprised of nano-sized nickel primary particles with diameters of 20-70 nm. The production of porous elemental nickel powder via the aerosol flow thermal decomposition of nickel oxalate results in powder with acceptable electrical properties and is more benign and potentially cheaper than the current commercial process for nickel powder production.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/18352675" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="3e29c88787cf48805a46879c847f064f" rel="nofollow" data-download="{"attachment_id":40009333,"asset_id":18352675,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40009333/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="38338451" href="https://independent.academia.edu/AlanWeimer">Alan Weimer</a><script data-card-contents-for-user="38338451" type="text/json">{"id":38338451,"first_name":"Alan","last_name":"Weimer","domain_name":"independent","page_name":"AlanWeimer","display_name":"Alan Weimer","profile_url":"https://independent.academia.edu/AlanWeimer?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_18352675 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="18352675"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 18352675, container: ".js-paper-rank-work_18352675", }); });</script></li><li class="js-percentile-work_18352675 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 18352675; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_18352675"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_18352675 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="18352675"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 18352675; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=18352675]").text(description); $(".js-view-count-work_18352675").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_18352675").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="18352675"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">6</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="56" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials_Engineering">Materials Engineering</a>, <script data-card-contents-for-ri="56" type="text/json">{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="60" rel="nofollow" href="https://www.academia.edu/Documents/in/Mechanical_Engineering">Mechanical Engineering</a>, <script data-card-contents-for-ri="60" type="text/json">{"id":60,"name":"Mechanical Engineering","url":"https://www.academia.edu/Documents/in/Mechanical_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="194828" rel="nofollow" href="https://www.academia.edu/Documents/in/Nickel">Nickel</a>, <script data-card-contents-for-ri="194828" type="text/json">{"id":194828,"name":"Nickel","url":"https://www.academia.edu/Documents/in/Nickel?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="398654" rel="nofollow" href="https://www.academia.edu/Documents/in/Electrical_Properties">Electrical Properties</a><script data-card-contents-for-ri="398654" type="text/json">{"id":398654,"name":"Electrical Properties","url":"https://www.academia.edu/Documents/in/Electrical_Properties?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=18352675]'), work: {"id":18352675,"title":"Rapid nickel oxalate thermal decomposition for producing fine porous nickel metal powders","created_at":"2015-11-14T15:24:14.621-08:00","url":"https://www.academia.edu/18352675/Rapid_nickel_oxalate_thermal_decomposition_for_producing_fine_porous_nickel_metal_powders?f_ri=483677","dom_id":"work_18352675","summary":"Precursor nickel oxalate powder was entrained in pure argon and a 5% hydrogen-in-argon carrier gas flow and carried through a heated transport tube reactor. The reactor wall temperature was maintained at 748-1018 K for residence times less than 4 s. Rapid reaction was possible because of high particle heating rates. A 5% addition of hydrogen to the carrier allowed for the synthesis of a high-purity elemental nickel powder with low residual oxygen content. Product particles consisted of nano-sized primary particles contained within an overall microcontainer matrix. Primary nickel particles nucleated within the precursor microcontainer matrix, followed by a coalescence period. The product powder was characterized as 2-40 m diameter microcontainer particles comprised of nano-sized nickel primary particles with diameters of 20-70 nm. The production of porous elemental nickel powder via the aerosol flow thermal decomposition of nickel oxalate results in powder with acceptable electrical properties and is more benign and potentially cheaper than the current commercial process for nickel powder production.","downloadable_attachments":[{"id":40009333,"asset_id":18352675,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":38338451,"first_name":"Alan","last_name":"Weimer","domain_name":"independent","page_name":"AlanWeimer","display_name":"Alan Weimer","profile_url":"https://independent.academia.edu/AlanWeimer?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true},{"id":60,"name":"Mechanical Engineering","url":"https://www.academia.edu/Documents/in/Mechanical_Engineering?f_ri=483677","nofollow":true},{"id":194828,"name":"Nickel","url":"https://www.academia.edu/Documents/in/Nickel?f_ri=483677","nofollow":true},{"id":398654,"name":"Electrical Properties","url":"https://www.academia.edu/Documents/in/Electrical_Properties?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":897122,"name":"Gas Flow","url":"https://www.academia.edu/Documents/in/Gas_Flow?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_5856314" data-work_id="5856314" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/5856314/Poly_vinyl_alcohol_and_poly_vinyl_pyrrolidone_blended_films_for_local_nitric_oxide_release">Poly(vinyl alcohol) and poly(vinyl pyrrolidone) blended films for local nitric oxide release</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The nitric oxide (NO) donor S-nitrosoglutathione (GSNO) was incorporated in solid polymeric films of poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP) and blended PVA/PVP. These matrices were found to provide a great stabilization... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_5856314" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The nitric oxide (NO) donor S-nitrosoglutathione (GSNO) was incorporated in solid polymeric films of poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP) and blended PVA/PVP. These matrices were found to provide a great stabilization effect on the thermal decomposition of GSNO, leading to 8-16-fold reduction in the first-order rate constants of NO release, compared to aqueous GSNO solutions. PVA/PVP-GSNO released 90% of the NO supply, over a time period of 24 h at 37 C. Differential scanning calorimetry has confirmed the miscibility between the two polymeric components. Stress-strain analysis has shown an improvement of the mechanical property of PVA films in the PVA/PVP blend, which leads to an increase of 25% in the stress at break. Scanning electron microscopy has shown that the PVA/PVP-GSNO blend leads to a smooth coating of metallic surfaces. These properties, allied to the already known good biocompatibility of PVA and PVP, makes GSNO-containing PVA and PVA/ PVP blend films good candidates for the local and controlled release of NO in target areas. r</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/5856314" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="81b6ae7808153b1303e87f63a827e5d4" rel="nofollow" data-download="{"attachment_id":49109875,"asset_id":5856314,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49109875/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="8632244" href="https://independent.academia.edu/MarceloOliveira10">Marcelo Oliveira</a><script data-card-contents-for-user="8632244" type="text/json">{"id":8632244,"first_name":"Marcelo","last_name":"Oliveira","domain_name":"independent","page_name":"MarceloOliveira10","display_name":"Marcelo Oliveira","profile_url":"https://independent.academia.edu/MarceloOliveira10?f_ri=483677","photo":"https://0.academia-photos.com/8632244/9321083/10388928/s65_marcelo.oliveira.jpg_oh_54f5bc709e80661c967ce32a5a92bae1_oe_5608658a___gda___1442805558_f4b68f3641c55e22a1ece0fdd27f7c84"}</script></span></span></li><li class="js-paper-rank-work_5856314 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="5856314"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 5856314, container: ".js-paper-rank-work_5856314", }); 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$(".js-view-count[data-work-id=5856314]").text(description); $(".js-view-count-work_5856314").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_5856314").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="5856314"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">33</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="2698" rel="nofollow" href="https://www.academia.edu/Documents/in/Biomaterials">Biomaterials</a>, <script data-card-contents-for-ri="2698" type="text/json">{"id":2698,"name":"Biomaterials","url":"https://www.academia.edu/Documents/in/Biomaterials?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4987" rel="nofollow" href="https://www.academia.edu/Documents/in/Kinetics">Kinetics</a>, <script data-card-contents-for-ri="4987" type="text/json">{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="10655" rel="nofollow" href="https://www.academia.edu/Documents/in/Scanning_Electron_Microscopy">Scanning Electron Microscopy</a><script data-card-contents-for-ri="10655" type="text/json">{"id":10655,"name":"Scanning Electron Microscopy","url":"https://www.academia.edu/Documents/in/Scanning_Electron_Microscopy?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=5856314]'), work: {"id":5856314,"title":"Poly(vinyl alcohol) and poly(vinyl pyrrolidone) blended films for local nitric oxide release","created_at":"2014-01-27T03:06:12.161-08:00","url":"https://www.academia.edu/5856314/Poly_vinyl_alcohol_and_poly_vinyl_pyrrolidone_blended_films_for_local_nitric_oxide_release?f_ri=483677","dom_id":"work_5856314","summary":"The nitric oxide (NO) donor S-nitrosoglutathione (GSNO) was incorporated in solid polymeric films of poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP) and blended PVA/PVP. These matrices were found to provide a great stabilization effect on the thermal decomposition of GSNO, leading to 8-16-fold reduction in the first-order rate constants of NO release, compared to aqueous GSNO solutions. PVA/PVP-GSNO released 90% of the NO supply, over a time period of 24 h at 37 C. Differential scanning calorimetry has confirmed the miscibility between the two polymeric components. Stress-strain analysis has shown an improvement of the mechanical property of PVA films in the PVA/PVP blend, which leads to an increase of 25% in the stress at break. Scanning electron microscopy has shown that the PVA/PVP-GSNO blend leads to a smooth coating of metallic surfaces. These properties, allied to the already known good biocompatibility of PVA and PVP, makes GSNO-containing PVA and PVA/ PVP blend films good candidates for the local and controlled release of NO in target areas. r","downloadable_attachments":[{"id":49109875,"asset_id":5856314,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":8632244,"first_name":"Marcelo","last_name":"Oliveira","domain_name":"independent","page_name":"MarceloOliveira10","display_name":"Marcelo Oliveira","profile_url":"https://independent.academia.edu/MarceloOliveira10?f_ri=483677","photo":"https://0.academia-photos.com/8632244/9321083/10388928/s65_marcelo.oliveira.jpg_oh_54f5bc709e80661c967ce32a5a92bae1_oe_5608658a___gda___1442805558_f4b68f3641c55e22a1ece0fdd27f7c84"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":2698,"name":"Biomaterials","url":"https://www.academia.edu/Documents/in/Biomaterials?f_ri=483677","nofollow":true},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":10655,"name":"Scanning Electron Microscopy","url":"https://www.academia.edu/Documents/in/Scanning_Electron_Microscopy?f_ri=483677","nofollow":true},{"id":28235,"name":"Multidisciplinary","url":"https://www.academia.edu/Documents/in/Multidisciplinary?f_ri=483677"},{"id":48904,"name":"Elasticity","url":"https://www.academia.edu/Documents/in/Elasticity?f_ri=483677"},{"id":58527,"name":"Polymer","url":"https://www.academia.edu/Documents/in/Polymer?f_ri=483677"},{"id":64660,"name":"Controlled release","url":"https://www.academia.edu/Documents/in/Controlled_release?f_ri=483677"},{"id":78753,"name":"Differential scanning calorimetry","url":"https://www.academia.edu/Documents/in/Differential_scanning_calorimetry?f_ri=483677"},{"id":83315,"name":"Diffusion","url":"https://www.academia.edu/Documents/in/Diffusion?f_ri=483677"},{"id":93922,"name":"Nitric 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weight","url":"https://www.academia.edu/Documents/in/Molecular_weight?f_ri=483677"},{"id":892969,"name":"Materials Testing","url":"https://www.academia.edu/Documents/in/Materials_Testing?f_ri=483677"},{"id":973999,"name":"Tensile Strength","url":"https://www.academia.edu/Documents/in/Tensile_Strength?f_ri=483677"},{"id":1031068,"name":"Drug Carriers","url":"https://www.academia.edu/Documents/in/Drug_Carriers?f_ri=483677"},{"id":1137107,"name":"Delayed-Action Preparations","url":"https://www.academia.edu/Documents/in/Delayed-Action_Preparations?f_ri=483677"},{"id":1160034,"name":"Miscibility","url":"https://www.academia.edu/Documents/in/Miscibility?f_ri=483677"},{"id":1431635,"name":"Dynamic Mechanical Analysis","url":"https://www.academia.edu/Documents/in/Dynamic_Mechanical_Analysis?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_14830245" data-work_id="14830245" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/14830245/Studies_on_the_thermal_properties_of_sisal_fiber_and_its_constituents">Studies on the thermal properties of sisal fiber and its constituents</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In this work the thermal analysis of raw and defatted sisal fiber and its chemical constituents (cellulose, hemicellulose and lignin) was performed by thermogravimetric analysis, and differential scanning calorimetry under air and... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_14830245" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In this work the thermal analysis of raw and defatted sisal fiber and its chemical constituents (cellulose, hemicellulose and lignin) was performed by thermogravimetric analysis, and differential scanning calorimetry under air and nitrogen atmospheres. The DSC studies showed that the degradation process depends on the atmosphere involved. In inert atmosphere, the DSC curves exhibited distinct peaks for sisal fiber and its constituents, whereas in air atmosphere the thermal curves presented two exothermic peaks for all the constituents. The degradation of cellulose in inert atmosphere occurred by endothermic processes whereas, in air atmosphere, it occurred by exothermic processes. TGA measurements corroborated the results obtained by DSC. It is shown that cellulose and hemicellulose degraded at lower temperatures than that of the raw sisal fiber, which can be attributed to the removal of lignin. The thermal decomposition of sisal fiber and its constituents was discussed and compared to jute and hemp fibers.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/14830245" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="f8a035aba13a29ce7ef8af074fef1f27" rel="nofollow" data-download="{"attachment_id":43867862,"asset_id":14830245,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/43867862/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="33789464" href="https://embrapa.academia.edu/LuizMattoso">Luiz H C Mattoso</a><script data-card-contents-for-user="33789464" type="text/json">{"id":33789464,"first_name":"Luiz","last_name":"Mattoso","domain_name":"embrapa","page_name":"LuizMattoso","display_name":"Luiz H C Mattoso","profile_url":"https://embrapa.academia.edu/LuizMattoso?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_14830245 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="14830245"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 14830245, container: ".js-paper-rank-work_14830245", }); 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$(".js-view-count[data-work-id=14830245]").text(description); $(".js-view-count-work_14830245").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_14830245").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="14830245"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">8</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="78753" rel="nofollow" href="https://www.academia.edu/Documents/in/Differential_scanning_calorimetry">Differential scanning calorimetry</a>, <script data-card-contents-for-ri="78753" type="text/json">{"id":78753,"name":"Differential scanning calorimetry","url":"https://www.academia.edu/Documents/in/Differential_scanning_calorimetry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="151091" rel="nofollow" href="https://www.academia.edu/Documents/in/Nitrogen">Nitrogen</a>, <script data-card-contents-for-ri="151091" type="text/json">{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="317239" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_Analysis">Thermal Analysis</a><script data-card-contents-for-ri="317239" type="text/json">{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=14830245]'), work: {"id":14830245,"title":"Studies on the thermal properties of sisal fiber and its constituents","created_at":"2015-08-10T11:36:53.136-07:00","url":"https://www.academia.edu/14830245/Studies_on_the_thermal_properties_of_sisal_fiber_and_its_constituents?f_ri=483677","dom_id":"work_14830245","summary":"In this work the thermal analysis of raw and defatted sisal fiber and its chemical constituents (cellulose, hemicellulose and lignin) was performed by thermogravimetric analysis, and differential scanning calorimetry under air and nitrogen atmospheres. The DSC studies showed that the degradation process depends on the atmosphere involved. In inert atmosphere, the DSC curves exhibited distinct peaks for sisal fiber and its constituents, whereas in air atmosphere the thermal curves presented two exothermic peaks for all the constituents. The degradation of cellulose in inert atmosphere occurred by endothermic processes whereas, in air atmosphere, it occurred by exothermic processes. TGA measurements corroborated the results obtained by DSC. It is shown that cellulose and hemicellulose degraded at lower temperatures than that of the raw sisal fiber, which can be attributed to the removal of lignin. The thermal decomposition of sisal fiber and its constituents was discussed and compared to jute and hemp fibers.","downloadable_attachments":[{"id":43867862,"asset_id":14830245,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":33789464,"first_name":"Luiz","last_name":"Mattoso","domain_name":"embrapa","page_name":"LuizMattoso","display_name":"Luiz H C Mattoso","profile_url":"https://embrapa.academia.edu/LuizMattoso?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=483677","nofollow":true},{"id":78753,"name":"Differential scanning calorimetry","url":"https://www.academia.edu/Documents/in/Differential_scanning_calorimetry?f_ri=483677","nofollow":true},{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=483677","nofollow":true},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677","nofollow":true},{"id":389180,"name":"Thermal Stability","url":"https://www.academia.edu/Documents/in/Thermal_Stability?f_ri=483677"},{"id":398652,"name":"Thermogravimetric Analysis","url":"https://www.academia.edu/Documents/in/Thermogravimetric_Analysis?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":854553,"name":"Thermal Properties","url":"https://www.academia.edu/Documents/in/Thermal_Properties?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_22611360" data-work_id="22611360" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/22611360/Synthesis_and_thermal_study_of_the_barium_complexes_with_8_hydroxyquinolinate_derivatives">Synthesis and thermal study of the barium complexes with 8-hydroxyquinolinate derivatives</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In this present work, barium ion was reacted with different ligands which are 5,7-dibromo, 5,7-dichloro, 7-iodo and 5-chloro-7-iodo-8-hydroxyquinoline, in acetone/ammonium hydroxide medium under constant stirring and the obtained... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_22611360" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In this present work, barium ion was reacted with different ligands which are 5,7-dibromo, 5,7-dichloro, 7-iodo and 5-chloro-7-iodo-8-hydroxyquinoline, in acetone/ammonium hydroxide medium under constant stirring and the obtained compounds were as follows: (I) Ba[(C 9 H 4 ONBr 2 ) 2 ]·1.5H 2 O; (II) Ba[(C 9 H 4 ONCl 2 )(OH)]·1H 2 O; (III) Ba[(C 9 H 5 ONI) 2 ]·1H 2 O and (IV) Ba[(C 9 H 4 ONICl) 2 ]·5H 2 O, respectively. The compounds were characterized by elemental analysis, infrared absorption spectrum (IR), inductively coupled plasma spectrometry (ICP), simultaneous thermogravimetry-differential thermal analysis (TG-DTA) and differential scanning calorimeter (DSC).</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/22611360" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="d5a4da20b8f8b569433fb001ac30dee4" rel="nofollow" data-download="{"attachment_id":43210555,"asset_id":22611360,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/43210555/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="44173256" href="https://unesp.academia.edu/MarisaCrespi">Marisa Crespi</a><script data-card-contents-for-user="44173256" type="text/json">{"id":44173256,"first_name":"Marisa","last_name":"Crespi","domain_name":"unesp","page_name":"MarisaCrespi","display_name":"Marisa Crespi","profile_url":"https://unesp.academia.edu/MarisaCrespi?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_22611360 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="22611360"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 22611360, container: ".js-paper-rank-work_22611360", }); });</script></li><li class="js-percentile-work_22611360 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 22611360; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_22611360"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_22611360 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="22611360"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 22611360; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=22611360]").text(description); $(".js-view-count-work_22611360").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_22611360").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="22611360"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">5</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="246949" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermogravimetry">Thermogravimetry</a>, <script data-card-contents-for-ri="246949" type="text/json">{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="321836" rel="nofollow" href="https://www.academia.edu/Documents/in/Spectrum">Spectrum</a>, <script data-card-contents-for-ri="321836" type="text/json">{"id":321836,"name":"Spectrum","url":"https://www.academia.edu/Documents/in/Spectrum?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="396373" rel="nofollow" href="https://www.academia.edu/Documents/in/Differential_Scanning_Calorimeter">Differential Scanning Calorimeter</a>, <script data-card-contents-for-ri="396373" type="text/json">{"id":396373,"name":"Differential Scanning Calorimeter","url":"https://www.academia.edu/Documents/in/Differential_Scanning_Calorimeter?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="396853" rel="nofollow" href="https://www.academia.edu/Documents/in/Differential_Thermal_Analysis">Differential Thermal Analysis</a><script data-card-contents-for-ri="396853" type="text/json">{"id":396853,"name":"Differential Thermal Analysis","url":"https://www.academia.edu/Documents/in/Differential_Thermal_Analysis?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=22611360]'), work: {"id":22611360,"title":"Synthesis and thermal study of the barium complexes with 8-hydroxyquinolinate derivatives","created_at":"2016-02-29T11:49:12.979-08:00","url":"https://www.academia.edu/22611360/Synthesis_and_thermal_study_of_the_barium_complexes_with_8_hydroxyquinolinate_derivatives?f_ri=483677","dom_id":"work_22611360","summary":"In this present work, barium ion was reacted with different ligands which are 5,7-dibromo, 5,7-dichloro, 7-iodo and 5-chloro-7-iodo-8-hydroxyquinoline, in acetone/ammonium hydroxide medium under constant stirring and the obtained compounds were as follows: (I) Ba[(C 9 H 4 ONBr 2 ) 2 ]·1.5H 2 O; (II) Ba[(C 9 H 4 ONCl 2 )(OH)]·1H 2 O; (III) Ba[(C 9 H 5 ONI) 2 ]·1H 2 O and (IV) Ba[(C 9 H 4 ONICl) 2 ]·5H 2 O, respectively. The compounds were characterized by elemental analysis, infrared absorption spectrum (IR), inductively coupled plasma spectrometry (ICP), simultaneous thermogravimetry-differential thermal analysis (TG-DTA) and differential scanning calorimeter (DSC).","downloadable_attachments":[{"id":43210555,"asset_id":22611360,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":44173256,"first_name":"Marisa","last_name":"Crespi","domain_name":"unesp","page_name":"MarisaCrespi","display_name":"Marisa Crespi","profile_url":"https://unesp.academia.edu/MarisaCrespi?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677","nofollow":true},{"id":321836,"name":"Spectrum","url":"https://www.academia.edu/Documents/in/Spectrum?f_ri=483677","nofollow":true},{"id":396373,"name":"Differential Scanning Calorimeter","url":"https://www.academia.edu/Documents/in/Differential_Scanning_Calorimeter?f_ri=483677","nofollow":true},{"id":396853,"name":"Differential Thermal Analysis","url":"https://www.academia.edu/Documents/in/Differential_Thermal_Analysis?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_21933613" data-work_id="21933613" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/21933613/Foaming_and_chain_extension_of_completely_biodegradable_poly_propylene_carbonate_using_DPT_as_blowing_agent">Foaming and chain extension of completely biodegradable poly(propylene carbonate) using DPT as blowing agent</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Completely biodegradable foams of poly(propylene carbonate) (PPC) derived from carbon dioxide and propylene oxide were fabricated using N, N′-dinitroso pentamethylene tetramine (DPT) as chemical blowing agent, and urea as the activator to... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_21933613" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Completely biodegradable foams of poly(propylene carbonate) (PPC) derived from carbon dioxide and propylene oxide were fabricated using N, N′-dinitroso pentamethylene tetramine (DPT) as chemical blowing agent, and urea as the activator to lower the decomposition temperature of DPT. Thermal decomposition behavior and gas evolution behavior of the DPT composite with various urea to DPT ratios were investigated to optimize the composition of the blowing agent. The formulation of blowing agent mixture and foaming condition, the foam morphologies, the molecular weight change, as well as the mechanical properties of produced PPC foams were studied extensively. The experimental results demonstrated that the greatest blowing ratio of 14.8 can be afforded in case 12 phr blowing agent was used at 170°C for 30 min. Gel permeation chromatography (GPC) and thermal analysis revealed that DPT acted as both chain-extension agent and blowing agent for PPC matrix. The molecular weight of PPC subjected to foaming increased by 76%. The foamed PPC exhibited superior mechanical properties and can be used as packaging material for many practical applications.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/21933613" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="71e1f5f46ce46315e995cccd09a68ef2" rel="nofollow" data-download="{"attachment_id":42658398,"asset_id":21933613,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/42658398/download_file?st=MTczOTkxODI3MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="43174058" href="https://independent.academia.edu/ShuanjinWang">Shuanjin Wang</a><script data-card-contents-for-user="43174058" type="text/json">{"id":43174058,"first_name":"Shuanjin","last_name":"Wang","domain_name":"independent","page_name":"ShuanjinWang","display_name":"Shuanjin Wang","profile_url":"https://independent.academia.edu/ShuanjinWang?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_21933613 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="21933613"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 21933613, container: ".js-paper-rank-work_21933613", }); });</script></li><li class="js-percentile-work_21933613 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21933613; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_21933613"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_21933613 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="21933613"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21933613; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21933613]").text(description); $(".js-view-count-work_21933613").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_21933613").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="21933613"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">7</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="56" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials_Engineering">Materials Engineering</a>, <script data-card-contents-for-ri="56" type="text/json">{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4594" rel="nofollow" href="https://www.academia.edu/Documents/in/Carbon_Dioxide">Carbon Dioxide</a>, <script data-card-contents-for-ri="4594" type="text/json">{"id":4594,"name":"Carbon Dioxide","url":"https://www.academia.edu/Documents/in/Carbon_Dioxide?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="58527" rel="nofollow" href="https://www.academia.edu/Documents/in/Polymer">Polymer</a>, <script data-card-contents-for-ri="58527" type="text/json">{"id":58527,"name":"Polymer","url":"https://www.academia.edu/Documents/in/Polymer?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="203966" rel="nofollow" href="https://www.academia.edu/Documents/in/Gel_Permeation_Chromatography">Gel Permeation Chromatography</a><script data-card-contents-for-ri="203966" type="text/json">{"id":203966,"name":"Gel Permeation Chromatography","url":"https://www.academia.edu/Documents/in/Gel_Permeation_Chromatography?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=21933613]'), work: {"id":21933613,"title":"Foaming and chain extension of completely biodegradable poly(propylene carbonate) using DPT as blowing agent","created_at":"2016-02-13T16:05:58.620-08:00","url":"https://www.academia.edu/21933613/Foaming_and_chain_extension_of_completely_biodegradable_poly_propylene_carbonate_using_DPT_as_blowing_agent?f_ri=483677","dom_id":"work_21933613","summary":"Completely biodegradable foams of poly(propylene carbonate) (PPC) derived from carbon dioxide and propylene oxide were fabricated using N, N′-dinitroso pentamethylene tetramine (DPT) as chemical blowing agent, and urea as the activator to lower the decomposition temperature of DPT. Thermal decomposition behavior and gas evolution behavior of the DPT composite with various urea to DPT ratios were investigated to optimize the composition of the blowing agent. The formulation of blowing agent mixture and foaming condition, the foam morphologies, the molecular weight change, as well as the mechanical properties of produced PPC foams were studied extensively. The experimental results demonstrated that the greatest blowing ratio of 14.8 can be afforded in case 12 phr blowing agent was used at 170°C for 30 min. Gel permeation chromatography (GPC) and thermal analysis revealed that DPT acted as both chain-extension agent and blowing agent for PPC matrix. The molecular weight of PPC subjected to foaming increased by 76%. The foamed PPC exhibited superior mechanical properties and can be used as packaging material for many practical applications.","downloadable_attachments":[{"id":42658398,"asset_id":21933613,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":43174058,"first_name":"Shuanjin","last_name":"Wang","domain_name":"independent","page_name":"ShuanjinWang","display_name":"Shuanjin Wang","profile_url":"https://independent.academia.edu/ShuanjinWang?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true},{"id":4594,"name":"Carbon Dioxide","url":"https://www.academia.edu/Documents/in/Carbon_Dioxide?f_ri=483677","nofollow":true},{"id":58527,"name":"Polymer","url":"https://www.academia.edu/Documents/in/Polymer?f_ri=483677","nofollow":true},{"id":203966,"name":"Gel Permeation Chromatography","url":"https://www.academia.edu/Documents/in/Gel_Permeation_Chromatography?f_ri=483677","nofollow":true},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":695018,"name":"Molecular weight","url":"https://www.academia.edu/Documents/in/Molecular_weight?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_19355139" data-work_id="19355139" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/19355139/Effect_of_hydroxides_and_hydroxycarbonate_structure_on_fire_retardant_effectiveness_and_mechanical_properties_in_ethylene_vinyl_acetate_copolymer">Effect of hydroxides and hydroxycarbonate structure on fire retardant effectiveness and mechanical properties in ethylene-vinyl acetate copolymer</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The flame retardant effect of inorganic hydroxides, like aluminum hydroxide and magnesium hydroxide in ethylene vinyl acetate copolymer, was evaluated and compared with that of other inorganic fillers such as boehmite and hydrotalcite.... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_19355139" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The flame retardant effect of inorganic hydroxides, like aluminum hydroxide and magnesium hydroxide in ethylene vinyl acetate copolymer, was evaluated and compared with that of other inorganic fillers such as boehmite and hydrotalcite. The thermal decomposition of the fillers and the mixtures with EVA polymer were analysed by differential scanning calorimetry (DSC), Thermogravimetry (TG) and X-ray diffraction (XRD). The most significant flame retardant effects, observed using a mass loss calorimeter, indicated that the EVA polymer filled with 50 wt.% of hydrotalcite has the slowest heat release rate and the lowest evolved gas temperature. XRD data, combined with thermal analysis results, indicated that the layered structure of hydrotalcite may play a role in the degradation mechanism. The improved fire resistance of EVA filled with hydrotalcite also results from its intumescent behaviour. # (M. Braglia).</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/19355139" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="07038e62e7b1089e55e1b6ca0f6ac136" rel="nofollow" data-download="{"attachment_id":40574630,"asset_id":19355139,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40574630/download_file?st=MTczOTkxODI3MSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="39620186" href="https://unile.academia.edu/AlfonsoMaffezzoli">Alfonso Maffezzoli</a><script data-card-contents-for-user="39620186" type="text/json">{"id":39620186,"first_name":"Alfonso","last_name":"Maffezzoli","domain_name":"unile","page_name":"AlfonsoMaffezzoli","display_name":"Alfonso Maffezzoli","profile_url":"https://unile.academia.edu/AlfonsoMaffezzoli?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_19355139 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="19355139"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 19355139, container: ".js-paper-rank-work_19355139", }); 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$(".js-view-count[data-work-id=19355139]").text(description); $(".js-view-count-work_19355139").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_19355139").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="19355139"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">13</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="56" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials_Engineering">Materials Engineering</a>, <script data-card-contents-for-ri="56" type="text/json">{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="72" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemical_Engineering">Chemical Engineering</a>, <script data-card-contents-for-ri="72" type="text/json">{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="35816" rel="nofollow" href="https://www.academia.edu/Documents/in/POlymer_degradation_and_stability">POlymer degradation and stability</a>, <script data-card-contents-for-ri="35816" type="text/json">{"id":35816,"name":"POlymer degradation and stability","url":"https://www.academia.edu/Documents/in/POlymer_degradation_and_stability?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="70902" rel="nofollow" href="https://www.academia.edu/Documents/in/Magnesium">Magnesium</a><script data-card-contents-for-ri="70902" type="text/json">{"id":70902,"name":"Magnesium","url":"https://www.academia.edu/Documents/in/Magnesium?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=19355139]'), work: {"id":19355139,"title":"Effect of hydroxides and hydroxycarbonate structure on fire retardant effectiveness and mechanical properties in ethylene-vinyl acetate copolymer","created_at":"2015-12-02T06:42:21.335-08:00","url":"https://www.academia.edu/19355139/Effect_of_hydroxides_and_hydroxycarbonate_structure_on_fire_retardant_effectiveness_and_mechanical_properties_in_ethylene_vinyl_acetate_copolymer?f_ri=483677","dom_id":"work_19355139","summary":"The flame retardant effect of inorganic hydroxides, like aluminum hydroxide and magnesium hydroxide in ethylene vinyl acetate copolymer, was evaluated and compared with that of other inorganic fillers such as boehmite and hydrotalcite. The thermal decomposition of the fillers and the mixtures with EVA polymer were analysed by differential scanning calorimetry (DSC), Thermogravimetry (TG) and X-ray diffraction (XRD). The most significant flame retardant effects, observed using a mass loss calorimeter, indicated that the EVA polymer filled with 50 wt.% of hydrotalcite has the slowest heat release rate and the lowest evolved gas temperature. XRD data, combined with thermal analysis results, indicated that the layered structure of hydrotalcite may play a role in the degradation mechanism. The improved fire resistance of EVA filled with hydrotalcite also results from its intumescent behaviour. # (M. Braglia).","downloadable_attachments":[{"id":40574630,"asset_id":19355139,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":39620186,"first_name":"Alfonso","last_name":"Maffezzoli","domain_name":"unile","page_name":"AlfonsoMaffezzoli","display_name":"Alfonso Maffezzoli","profile_url":"https://unile.academia.edu/AlfonsoMaffezzoli?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":56,"name":"Materials Engineering","url":"https://www.academia.edu/Documents/in/Materials_Engineering?f_ri=483677","nofollow":true},{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=483677","nofollow":true},{"id":35816,"name":"POlymer degradation and stability","url":"https://www.academia.edu/Documents/in/POlymer_degradation_and_stability?f_ri=483677","nofollow":true},{"id":70902,"name":"Magnesium","url":"https://www.academia.edu/Documents/in/Magnesium?f_ri=483677","nofollow":true},{"id":78753,"name":"Differential scanning calorimetry","url":"https://www.academia.edu/Documents/in/Differential_scanning_calorimetry?f_ri=483677"},{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677"},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677"},{"id":386527,"name":"X ray diffraction","url":"https://www.academia.edu/Documents/in/X_ray_diffraction?f_ri=483677"},{"id":390999,"name":"Layered Structure","url":"https://www.academia.edu/Documents/in/Layered_Structure?f_ri=483677"},{"id":396851,"name":"Flame Retardant","url":"https://www.academia.edu/Documents/in/Flame_Retardant?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":963709,"name":"Mass Loss","url":"https://www.academia.edu/Documents/in/Mass_Loss?f_ri=483677"},{"id":994779,"name":"Fire Resistance","url":"https://www.academia.edu/Documents/in/Fire_Resistance?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_1070915" data-work_id="1070915" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/1070915/The_effect_of_particle_size_on_the_thermal_decomposition_kinetics_of_potassium_bromate">The effect of particle size on the thermal decomposition kinetics of potassium bromate</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The thermal decomposition of potassium bromate (KBrO 3 ) has been studied as a function of particle size, in the range 53-150 lm, by isothermal thermogravimetry at different temperatures, viz. 668, 673, 678, and 683 K in static air... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_1070915" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The thermal decomposition of potassium bromate (KBrO 3 ) has been studied as a function of particle size, in the range 53-150 lm, by isothermal thermogravimetry at different temperatures, viz. 668, 673, 678, and 683 K in static air atmosphere. The theoretical and experimental mass loss data are in good agreement for the thermal decomposition of all samples of KBrO 3 at all temperatures studied. The isothermal decomposition of all samples of KBrO 3 was subjected to both model fitting and model-free (isoconversional) kinetic methods of analysis. Isothermal model fitting analysis shows that the thermal decomposition kinetics of all the samples of KBrO 3 studied can be best described by the contracting square equation. Contrary to the expected increase in rate followed by a decrease with decrease in particle size, KBrO 3 shows a regular increase in rate with reduction in particle size, which, we suggest, is an impact of melting of this solid during decomposition.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/1070915" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="a8074860025ae4fc4addcc540b4ea9ca" rel="nofollow" data-download="{"attachment_id":51115055,"asset_id":1070915,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/51115055/download_file?st=MTczOTkxODI3MSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="918105" href="https://iitkgp.academia.edu/AnishMMuraleedharan">Anish M Muraleedharan</a><script data-card-contents-for-user="918105" type="text/json">{"id":918105,"first_name":"Anish M","last_name":"Muraleedharan","domain_name":"iitkgp","page_name":"AnishMMuraleedharan","display_name":"Anish M Muraleedharan","profile_url":"https://iitkgp.academia.edu/AnishMMuraleedharan?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_1070915 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="1070915"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 1070915, container: ".js-paper-rank-work_1070915", }); });</script></li><li class="js-percentile-work_1070915 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 1070915; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_1070915"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_1070915 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="1070915"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 1070915; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=1070915]").text(description); $(".js-view-count-work_1070915").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_1070915").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="1070915"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">7</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4987" rel="nofollow" href="https://www.academia.edu/Documents/in/Kinetics">Kinetics</a>, <script data-card-contents-for-ri="4987" type="text/json">{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="160656" rel="nofollow" href="https://www.academia.edu/Documents/in/Potassium">Potassium</a>, <script data-card-contents-for-ri="160656" type="text/json">{"id":160656,"name":"Potassium","url":"https://www.academia.edu/Documents/in/Potassium?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="174347" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal">Thermal</a>, <script data-card-contents-for-ri="174347" type="text/json">{"id":174347,"name":"Thermal","url":"https://www.academia.edu/Documents/in/Thermal?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="246949" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermogravimetry">Thermogravimetry</a><script data-card-contents-for-ri="246949" type="text/json">{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=1070915]'), work: {"id":1070915,"title":"The effect of particle size on the thermal decomposition kinetics of potassium bromate","created_at":"2011-11-06T21:43:42.958-08:00","url":"https://www.academia.edu/1070915/The_effect_of_particle_size_on_the_thermal_decomposition_kinetics_of_potassium_bromate?f_ri=483677","dom_id":"work_1070915","summary":"The thermal decomposition of potassium bromate (KBrO 3 ) has been studied as a function of particle size, in the range 53-150 lm, by isothermal thermogravimetry at different temperatures, viz. 668, 673, 678, and 683 K in static air atmosphere. The theoretical and experimental mass loss data are in good agreement for the thermal decomposition of all samples of KBrO 3 at all temperatures studied. The isothermal decomposition of all samples of KBrO 3 was subjected to both model fitting and model-free (isoconversional) kinetic methods of analysis. Isothermal model fitting analysis shows that the thermal decomposition kinetics of all the samples of KBrO 3 studied can be best described by the contracting square equation. Contrary to the expected increase in rate followed by a decrease with decrease in particle size, KBrO 3 shows a regular increase in rate with reduction in particle size, which, we suggest, is an impact of melting of this solid during decomposition.","downloadable_attachments":[{"id":51115055,"asset_id":1070915,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":918105,"first_name":"Anish M","last_name":"Muraleedharan","domain_name":"iitkgp","page_name":"AnishMMuraleedharan","display_name":"Anish M Muraleedharan","profile_url":"https://iitkgp.academia.edu/AnishMMuraleedharan?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":160656,"name":"Potassium","url":"https://www.academia.edu/Documents/in/Potassium?f_ri=483677","nofollow":true},{"id":174347,"name":"Thermal","url":"https://www.academia.edu/Documents/in/Thermal?f_ri=483677","nofollow":true},{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677","nofollow":true},{"id":390245,"name":"Particle Size","url":"https://www.academia.edu/Documents/in/Particle_Size?f_ri=483677"},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":963709,"name":"Mass Loss","url":"https://www.academia.edu/Documents/in/Mass_Loss?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_30450965" data-work_id="30450965" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/30450965/Synthesis_characterization_and_X_ray_diffraction_of_Cu_malonate_phen_2_2_17H2O_complex">Synthesis, characterization and X-ray diffraction of [Cu(malonate)(phen)2]2·17H2O complex</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Mixed ligand complex, [Cu(malonate)(phen) 2 ] 2 Á17H 2 O (phen = 1,10-phenanthroline), was synthesized and characterized by elemental analyses, infrared spectrum, thermo-gravimetric analyses and single Xray crystallography. In the... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_30450965" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Mixed ligand complex, [Cu(malonate)(phen) 2 ] 2 Á17H 2 O (phen = 1,10-phenanthroline), was synthesized and characterized by elemental analyses, infrared spectrum, thermo-gravimetric analyses and single Xray crystallography. In the complex, copper atom displayed a five coordinated environment. It bonded with four nitrogen atoms of 1,10-phenanthroline and one oxygen atom of malonate group in a distorted square pyramidal arrangement. The crystal structure of the complex was determined by X-ray single crystallography using X-ray diffraction technique 100 K with a AXS SMART APEX (Bruker) diffractometer, Mo Ka radiations (k = 0.71073 Å), R = 0.0642 and 0.0989. Orthorhombic unit cell parameters are: a = 13.1888(11) Å, b = 14.8458(12) Å, c = 16.7159(14) Å, V = 2975.8(4) Å, Dx = 2, 1.516 Mg/m 3 and Mr = 1358.26. Thermal decomposition of the complex was studied under inert atmosphere.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/30450965" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="fbbd2fc0df088c3e08262429711952e9" rel="nofollow" data-download="{"attachment_id":50892379,"asset_id":30450965,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50892379/download_file?st=MTczOTkxODI3MSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="2485435" href="https://punjablahorepakistan.academia.edu/TariqMahmud">Tariq Mahmud</a><script data-card-contents-for-user="2485435" type="text/json">{"id":2485435,"first_name":"Tariq","last_name":"Mahmud","domain_name":"punjablahorepakistan","page_name":"TariqMahmud","display_name":"Tariq Mahmud","profile_url":"https://punjablahorepakistan.academia.edu/TariqMahmud?f_ri=483677","photo":"https://0.academia-photos.com/2485435/776938/965432/s65_tariq.mahmud.jpg"}</script></span></span></li><li class="js-paper-rank-work_30450965 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="30450965"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 30450965, container: ".js-paper-rank-work_30450965", }); 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$(".js-view-count[data-work-id=30450965]").text(description); $(".js-view-count-work_30450965").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_30450965").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="30450965"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">8</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="50630" rel="nofollow" href="https://www.academia.edu/Documents/in/Crystal_structure">Crystal structure</a>, <script data-card-contents-for-ri="50630" type="text/json">{"id":50630,"name":"Crystal structure","url":"https://www.academia.edu/Documents/in/Crystal_structure?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="321836" rel="nofollow" href="https://www.academia.edu/Documents/in/Spectrum">Spectrum</a>, <script data-card-contents-for-ri="321836" type="text/json">{"id":321836,"name":"Spectrum","url":"https://www.academia.edu/Documents/in/Spectrum?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="335361" rel="nofollow" href="https://www.academia.edu/Documents/in/Infrared">Infrared</a>, <script data-card-contents-for-ri="335361" type="text/json">{"id":335361,"name":"Infrared","url":"https://www.academia.edu/Documents/in/Infrared?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="386527" rel="nofollow" href="https://www.academia.edu/Documents/in/X_ray_diffraction">X ray diffraction</a><script data-card-contents-for-ri="386527" type="text/json">{"id":386527,"name":"X ray diffraction","url":"https://www.academia.edu/Documents/in/X_ray_diffraction?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=30450965]'), work: {"id":30450965,"title":"Synthesis, characterization and X-ray diffraction of [Cu(malonate)(phen)2]2·17H2O complex","created_at":"2016-12-14T18:35:15.444-08:00","url":"https://www.academia.edu/30450965/Synthesis_characterization_and_X_ray_diffraction_of_Cu_malonate_phen_2_2_17H2O_complex?f_ri=483677","dom_id":"work_30450965","summary":"Mixed ligand complex, [Cu(malonate)(phen) 2 ] 2 Á17H 2 O (phen = 1,10-phenanthroline), was synthesized and characterized by elemental analyses, infrared spectrum, thermo-gravimetric analyses and single Xray crystallography. In the complex, copper atom displayed a five coordinated environment. It bonded with four nitrogen atoms of 1,10-phenanthroline and one oxygen atom of malonate group in a distorted square pyramidal arrangement. The crystal structure of the complex was determined by X-ray single crystallography using X-ray diffraction technique 100 K with a AXS SMART APEX (Bruker) diffractometer, Mo Ka radiations (k = 0.71073 Å), R = 0.0642 and 0.0989. Orthorhombic unit cell parameters are: a = 13.1888(11) Å, b = 14.8458(12) Å, c = 16.7159(14) Å, V = 2975.8(4) Å, Dx = 2, 1.516 Mg/m 3 and Mr = 1358.26. Thermal decomposition of the complex was studied under inert atmosphere.","downloadable_attachments":[{"id":50892379,"asset_id":30450965,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":2485435,"first_name":"Tariq","last_name":"Mahmud","domain_name":"punjablahorepakistan","page_name":"TariqMahmud","display_name":"Tariq Mahmud","profile_url":"https://punjablahorepakistan.academia.edu/TariqMahmud?f_ri=483677","photo":"https://0.academia-photos.com/2485435/776938/965432/s65_tariq.mahmud.jpg"}],"research_interests":[{"id":50630,"name":"Crystal structure","url":"https://www.academia.edu/Documents/in/Crystal_structure?f_ri=483677","nofollow":true},{"id":321836,"name":"Spectrum","url":"https://www.academia.edu/Documents/in/Spectrum?f_ri=483677","nofollow":true},{"id":335361,"name":"Infrared","url":"https://www.academia.edu/Documents/in/Infrared?f_ri=483677","nofollow":true},{"id":386527,"name":"X ray diffraction","url":"https://www.academia.edu/Documents/in/X_ray_diffraction?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":645605,"name":"THEORETICAL AND COMPUTATIONAL CHEMISTRY","url":"https://www.academia.edu/Documents/in/THEORETICAL_AND_COMPUTATIONAL_CHEMISTRY?f_ri=483677"},{"id":1146655,"name":"X Ray Crystallography","url":"https://www.academia.edu/Documents/in/X_Ray_Crystallography?f_ri=483677"},{"id":1724844,"name":"Molecular Structure","url":"https://www.academia.edu/Documents/in/Molecular_Structure?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_29350938" data-work_id="29350938" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/29350938/Thermal_behaviour_of_some_industrial_and_food_dyes">Thermal behaviour of some industrial and food dyes</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Thermal behavior of four food dyes, i.e. tartrazine, crysoine, azorubine and amarant was studied under non-isothermal conditions, in dynamic air atmosphere and at heating rates of 5, 10, 15 and 20°C min -1 . The TG data were correlated to... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_29350938" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Thermal behavior of four food dyes, i.e. tartrazine, crysoine, azorubine and amarant was studied under non-isothermal conditions, in dynamic air atmosphere and at heating rates of 5, 10, 15 and 20°C min -1 . The TG data were correlated to the FTIR spectra of each sample, before and after the thermal decomposition. Kinetic study by processing the TG data was performed. The main conclusion of this study is that the non-parametric kinetic method allows a separation of the steps of a complex process and that the values of the activation energy obtained by this method agree satisfactory with that of Flynn-Wall-Ozawa estimation.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/29350938" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="a65bca6a0755ad6778cced4b774a8a49" rel="nofollow" data-download="{"attachment_id":49792231,"asset_id":29350938,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49792231/download_file?st=MTczOTkxODI3MSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="55438328" href="https://independent.academia.edu/GabrielaVlase">Gabriela Vlase</a><script data-card-contents-for-user="55438328" type="text/json">{"id":55438328,"first_name":"Gabriela","last_name":"Vlase","domain_name":"independent","page_name":"GabrielaVlase","display_name":"Gabriela Vlase","profile_url":"https://independent.academia.edu/GabrielaVlase?f_ri=483677","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_29350938 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="29350938"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 29350938, container: ".js-paper-rank-work_29350938", }); 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$(".js-view-count[data-work-id=29350938]").text(description); $(".js-view-count-work_29350938").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_29350938").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="29350938"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">9</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4987" rel="nofollow" href="https://www.academia.edu/Documents/in/Kinetics">Kinetics</a>, <script data-card-contents-for-ri="4987" type="text/json">{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="147640" rel="nofollow" href="https://www.academia.edu/Documents/in/Activation_Energy">Activation Energy</a>, <script data-card-contents-for-ri="147640" type="text/json">{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="246949" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermogravimetry">Thermogravimetry</a>, <script data-card-contents-for-ri="246949" type="text/json">{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="317239" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermal_Analysis">Thermal Analysis</a><script data-card-contents-for-ri="317239" type="text/json">{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=29350938]'), work: {"id":29350938,"title":"Thermal behaviour of some industrial and food dyes","created_at":"2016-10-22T12:07:02.055-07:00","url":"https://www.academia.edu/29350938/Thermal_behaviour_of_some_industrial_and_food_dyes?f_ri=483677","dom_id":"work_29350938","summary":"Thermal behavior of four food dyes, i.e. tartrazine, crysoine, azorubine and amarant was studied under non-isothermal conditions, in dynamic air atmosphere and at heating rates of 5, 10, 15 and 20°C min -1 . The TG data were correlated to the FTIR spectra of each sample, before and after the thermal decomposition. Kinetic study by processing the TG data was performed. The main conclusion of this study is that the non-parametric kinetic method allows a separation of the steps of a complex process and that the values of the activation energy obtained by this method agree satisfactory with that of Flynn-Wall-Ozawa estimation.","downloadable_attachments":[{"id":49792231,"asset_id":29350938,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":55438328,"first_name":"Gabriela","last_name":"Vlase","domain_name":"independent","page_name":"GabrielaVlase","display_name":"Gabriela Vlase","profile_url":"https://independent.academia.edu/GabrielaVlase?f_ri=483677","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=483677","nofollow":true},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy?f_ri=483677","nofollow":true},{"id":246949,"name":"Thermogravimetry","url":"https://www.academia.edu/Documents/in/Thermogravimetry?f_ri=483677","nofollow":true},{"id":317239,"name":"Thermal Analysis","url":"https://www.academia.edu/Documents/in/Thermal_Analysis?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal Decomposition","url":"https://www.academia.edu/Documents/in/Thermal_Decomposition?f_ri=483677"},{"id":907359,"name":"Infrared Spectrometry","url":"https://www.academia.edu/Documents/in/Infrared_Spectrometry?f_ri=483677"},{"id":963367,"name":"FT IR","url":"https://www.academia.edu/Documents/in/FT_IR?f_ri=483677"},{"id":1288273,"name":"Fourier Transformation","url":"https://www.academia.edu/Documents/in/Fourier_Transformation?f_ri=483677"},{"id":2512175,"name":"thermal behaviour","url":"https://www.academia.edu/Documents/in/thermal_behaviour?f_ri=483677"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_61190584" data-work_id="61190584" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/61190584/Mechanistic_study_on_the_thermal_decomposition_of_polybenzoxazines_Effects_of_aliphatic_amines">Mechanistic study on the thermal decomposition of polybenzoxazines: Effects of aliphatic amines</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The thermal degradation of a series of polybenzoxazines based on bisphenol A and various aliphatic amines has been studied. Using the hyphenated techniques of thermogravimetric analysis-Fourier transform infrared spectroscopy (TGA-FTIR),... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_61190584" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The thermal degradation of a series of polybenzoxazines based on bisphenol A and various aliphatic amines has been studied. Using the hyphenated techniques of thermogravimetric analysis-Fourier transform infrared spectroscopy (TGA-FTIR), and gas chromatography-mass spectrometry (GC-MS), the mechanisms of thermal decomposition have been proposed. It is also proposed that the Mannich base in polybenzoxazines plays a significant role in the thermal degradation of polybenzoxazines. The contribution of hydrogen bonding to the degradation mechanism of the Mannich base has been examined. The proposed mechanisms have also been supported through the thermal degradation study of benzoxazine model dimers.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/61190584" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="89c9be6f4e517af2dd0db41d0207c41b" rel="nofollow" data-download="{"attachment_id":74310958,"asset_id":61190584,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/74310958/download_file?st=MTczOTkxODI3MSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="39701870" href="https://independent.academia.edu/HatsuoIshida">Hatsuo Ishida</a><script data-card-contents-for-user="39701870" type="text/json">{"id":39701870,"first_name":"Hatsuo","last_name":"Ishida","domain_name":"independent","page_name":"HatsuoIshida","display_name":"Hatsuo Ishida","profile_url":"https://independent.academia.edu/HatsuoIshida?f_ri=483677","photo":"https://0.academia-photos.com/39701870/33093140/29634677/s65_hatsuo.ishida.png"}</script></span></span></li><li class="js-paper-rank-work_61190584 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="61190584"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 61190584, container: ".js-paper-rank-work_61190584", }); 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Using the hyphenated techniques of thermogravimetric analysis-Fourier transform infrared spectroscopy (TGA-FTIR), and gas chromatography-mass spectrometry (GC-MS), the mechanisms of thermal decomposition have been proposed. It is also proposed that the Mannich base in polybenzoxazines plays a significant role in the thermal degradation of polybenzoxazines. The contribution of hydrogen bonding to the degradation mechanism of the Mannich base has been examined. The proposed mechanisms have also been supported through the thermal degradation study of benzoxazine model dimers.","downloadable_attachments":[{"id":74310958,"asset_id":61190584,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":39701870,"first_name":"Hatsuo","last_name":"Ishida","domain_name":"independent","page_name":"HatsuoIshida","display_name":"Hatsuo Ishida","profile_url":"https://independent.academia.edu/HatsuoIshida?f_ri=483677","photo":"https://0.academia-photos.com/39701870/33093140/29634677/s65_hatsuo.ishida.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=483677","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=483677","nofollow":true},{"id":483677,"name":"Thermal 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})();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_29571310" data-work_id="29571310" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/29571310/Theoretical_analysis_of_the_direct_decomposition_of_methane_gas_in_a_laminar_stagnation_point_flow_CO2_free_production_of_hydrogen">Theoretical analysis of the direct decomposition of methane gas in a laminar stagnation-point flow: CO2-free production of hydrogen</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Hydrogen production Endothermic reaction Surface coverage a b s t r a c t In this work, a theoretical analysis is developed to predict the decomposition temperature of methane gas, CH 4 , in a planar stagnation-point flow over a catalytic... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_29571310" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Hydrogen production Endothermic reaction Surface coverage a b s t r a c t In this work, a theoretical analysis is developed to predict the decomposition temperature of methane gas, CH 4 , in a planar stagnation-point flow over a catalytic carbon surface.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/29571310" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li 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