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<div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">From Wikipedia, the free encyclopedia</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="en" dir="ltr"><figure typeof="mw:File/Thumb"><a href="/wiki/File:RuA5(SMeEt)%2B%2B_(KUFKIF).png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/4/4b/RuA5%28SMeEt%29%2B%2B_%28KUFKIF%29.png/120px-RuA5%28SMeEt%29%2B%2B_%28KUFKIF%29.png" decoding="async" width="120" height="168" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/4b/RuA5%28SMeEt%29%2B%2B_%28KUFKIF%29.png/180px-RuA5%28SMeEt%29%2B%2B_%28KUFKIF%29.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/4b/RuA5%28SMeEt%29%2B%2B_%28KUFKIF%29.png/240px-RuA5%28SMeEt%29%2B%2B_%28KUFKIF%29.png 2x" data-file-width="977" data-file-height="1371" /></a><figcaption>Structure of [Ru(NH<sub>3</sub>)<sub>5</sub>(SMeEt)]<sup>2+</sup>.<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup></figcaption></figure> <p><b>Transition metal thioether complexes</b> comprise <a href="/wiki/Coordination_complex" title="Coordination complex">coordination complexes</a> of thioether (R<sub>2</sub>S) ligands. The inventory is extensive. </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Dimethylsulfide_complexes">Dimethylsulfide complexes</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Transition_metal_thioether_complex&action=edit&section=1" title="Edit section: Dimethylsulfide complexes"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>As the simplest thioether, <a href="/wiki/Dimethyl_sulfide" title="Dimethyl sulfide">dimethyl sulfide</a> forms complexes that are illustrative of the class.<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> Well characterized derivatives include <i>cis</i>-[TiCl<sub>4</sub>L<sub>2</sub>], VCl<sub>3</sub>L<sub>2</sub>, NbCl<sub>5</sub>L, NbCl<sub>4</sub>L<sub>2</sub>, Cr(CO)<sub>5</sub>L, CrCl<sub>3</sub>L<sub>3</sub>, RuCl<sub>2</sub>L<sub>4</sub>, RuCl<sub>3</sub>L<sub>3</sub>, RhCl<sub>3</sub>L<sub>3</sub>, <i>cis</i>- and <i>trans</i>-[IrCl<sub>4</sub>L<sub>3</sub>]<sup>-</sup>, <i>cis</i>-MCl<sub>2</sub>L<sub>2</sub> (M = Pd, Pt), [PtCl<sub>3</sub>L]<sup>−</sup>, <i>cis</i>- and <i>trans</i>-[PtCl<sub>4</sub>L<sub>2</sub>] (L = SMe<sub>2</sub>). With respect to donor properties, dimethyl sulfide is a soft ligand with donor properties weaker than <a href="/wiki/Metal-phosphine_complex" title="Metal-phosphine complex">phosphine ligands</a>.<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> Such complexes are generally prepared by treating the metal halide with the thioether. <a href="/wiki/Chloro(dimethyl_sulfide)gold(I)" title="Chloro(dimethyl sulfide)gold(I)">Chloro(dimethyl sulfide)gold(I)</a> can however be prepared by redox reaction of elemental gold and <a href="/wiki/Dimethyl_sulfoxide" title="Dimethyl sulfoxide">DMSO</a> in the presence of <a href="/wiki/Hydrochloric_acid" title="Hydrochloric acid">hydrochloric acid</a>.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Stereochemistry">Stereochemistry</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Transition_metal_thioether_complex&action=edit&section=2" title="Edit section: Stereochemistry"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-halign-left" typeof="mw:File/Thumb"><a href="/wiki/File:L3MSEt3.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/5/51/L3MSEt3.svg/122px-L3MSEt3.svg.png" decoding="async" width="122" height="112" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/51/L3MSEt3.svg/183px-L3MSEt3.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/5/51/L3MSEt3.svg/244px-L3MSEt3.svg.png 2x" data-file-width="128" data-file-height="118" /></a><figcaption>Diastereotopic methylene protons in complexes of diethyl sulfide.</figcaption></figure> <p>Thioether complexes feature <a href="/wiki/Trigonal_pyramidal_molecular_geometry" title="Trigonal pyramidal molecular geometry">pyramidal</a> sulfur centers. Typical C-S-C angles are near 99° in both free thioethers and their complexes. The C-S distance in dimethylsulfide is 1.81 Å, which is also unaffected in its complexes.<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> The stereochemistry of thioether complexes have been extensively studied.<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> Unsymmetrical thioethers, e.g., SMeEt, are <a href="/wiki/Prochiral" class="mw-redirect" title="Prochiral">prochiral</a> ligands, and their complexes are chiral. One example is [Ru(NH<sub>3</sub>)<sub>5</sub>(SMeEt)]<sup>2+</sup>. The complex <i>cis</i>-VOCl<sub>2</sub>(SMeEt)<sub>2</sub> exists as meso- and a pair of enantiomers.<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> In complexes of thioethers of the type S(CH<sub>2</sub>R)<sub>2</sub> (R ≠ H), the methylene protons are <a href="/wiki/Diastereotopic" class="mw-redirect" title="Diastereotopic">diastereotopic</a>. Examination of the NMR spectra of such complexes reveal that they undergo <a href="/wiki/Pyramidal_inversion" title="Pyramidal inversion">inversion</a> at sulfur, without dissociation of the M-S bond.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Thioether_as_a_bridging_ligand">Thioether as a bridging ligand</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Transition_metal_thioether_complex&action=edit&section=3" title="Edit section: Thioether as a bridging ligand"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Nb2Cl6(SMe2)3.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/91/Nb2Cl6%28SMe2%293.svg/220px-Nb2Cl6%28SMe2%293.svg.png" decoding="async" width="220" height="115" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/91/Nb2Cl6%28SMe2%293.svg/330px-Nb2Cl6%28SMe2%293.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/91/Nb2Cl6%28SMe2%293.svg/440px-Nb2Cl6%28SMe2%293.svg.png 2x" data-file-width="199" data-file-height="104" /></a><figcaption>Structure of Nb<sub>2</sub>Cl<sub>6</sub>(SMe<sub>2</sub>)<sub>3</sub>, illustrating a bridging thioether.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup></figcaption></figure> <p>Unlike ethers, thioethers occasionally serve as <a href="/wiki/Bridging_ligand" title="Bridging ligand">bridging ligands</a>. The complexes Nb<sub>2</sub>Cl<sub>6</sub>(SMe<sub>2</sub>)<sub>3</sub> is one such example. It adopts a face-sharing <a href="/wiki/Bioctahedral" class="mw-redirect" title="Bioctahedral">bioctahedral</a> structure with a Nb(III)=Nb(III) bond, spanned by two chloride and one dimethylsulfide ligands. The complex Pt<sub>2</sub>Me<sub>4</sub>(μ-SMe<sub>2</sub>)<sub>2</sub> is a source of "PtMe<sub>2</sub>".<sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Complexes_chelating_thioether_ligands">Complexes chelating thioether ligands</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Transition_metal_thioether_complex&action=edit&section=4" title="Edit section: Complexes chelating thioether ligands"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul class="gallery mw-gallery-traditional"> <li class="gallerybox" style="width: 155px"> <div class="thumb" style="width: 150px; height: 150px;"><span typeof="mw:File"><a href="/wiki/File:Ag(18-ane-S6)_dication.png" class="mw-file-description" title="Structure of [Ag(18-ane-S6)]2+. The Ag-S distances are 2.62 Å."><img alt="Structure of [Ag(18-ane-S6)]2+. The Ag-S distances are 2.62 Å." src="//upload.wikimedia.org/wikipedia/commons/thumb/7/78/Ag%2818-ane-S6%29_dication.png/120px-Ag%2818-ane-S6%29_dication.png" decoding="async" width="120" height="114" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/7/78/Ag%2818-ane-S6%29_dication.png/180px-Ag%2818-ane-S6%29_dication.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/7/78/Ag%2818-ane-S6%29_dication.png/240px-Ag%2818-ane-S6%29_dication.png 2x" data-file-width="1200" data-file-height="1138" /></a></span></div> <div class="gallerytext">Structure of [Ag(18-ane-S6)]<sup>2+</sup>. The Ag-S distances are 2.62 Å.</div> </li> <li class="gallerybox" style="width: 155px"> <div class="thumb" style="width: 150px; height: 150px;"><span typeof="mw:File"><a href="/wiki/File:Ru(15-ane-5)Cl%2B_(ORIZIZ).png" class="mw-file-description" title="Structure of [Ru(15-ane-S5)Cl]+.[11]"><img alt="Structure of [Ru(15-ane-S5)Cl]+.[11]" src="//upload.wikimedia.org/wikipedia/commons/thumb/4/45/Ru%2815-ane-5%29Cl%2B_%28ORIZIZ%29.png/120px-Ru%2815-ane-5%29Cl%2B_%28ORIZIZ%29.png" decoding="async" width="120" height="111" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/45/Ru%2815-ane-5%29Cl%2B_%28ORIZIZ%29.png/180px-Ru%2815-ane-5%29Cl%2B_%28ORIZIZ%29.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/45/Ru%2815-ane-5%29Cl%2B_%28ORIZIZ%29.png/240px-Ru%2815-ane-5%29Cl%2B_%28ORIZIZ%29.png 2x" data-file-width="1200" data-file-height="1105" /></a></span></div> <div class="gallerytext">Structure of [Ru(15-ane-S5)Cl]<sup>+</sup>.<sup id="cite_ref-Janz_11-0" class="reference"><a href="#cite_note-Janz-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup></div> </li> <li class="gallerybox" style="width: 155px"> <div class="thumb" style="width: 150px; height: 150px;"><span typeof="mw:File"><a href="/wiki/File:(DTCO)PdCl2_(VIVXUT).png" class="mw-file-description" title="Structure of (DTCO)PdCl2.[12]"><img alt="Structure of (DTCO)PdCl2.[12]" src="//upload.wikimedia.org/wikipedia/commons/thumb/1/1b/%28DTCO%29PdCl2_%28VIVXUT%29.png/120px-%28DTCO%29PdCl2_%28VIVXUT%29.png" decoding="async" width="120" height="107" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/1b/%28DTCO%29PdCl2_%28VIVXUT%29.png/180px-%28DTCO%29PdCl2_%28VIVXUT%29.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/1b/%28DTCO%29PdCl2_%28VIVXUT%29.png/240px-%28DTCO%29PdCl2_%28VIVXUT%29.png 2x" data-file-width="1200" data-file-height="1074" /></a></span></div> <div class="gallerytext">Structure of (<a href="/wiki/DTCO" class="mw-redirect" title="DTCO">DTCO</a>)PdCl<sub>2</sub>.<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup></div> </li> </ul> <p>Thiacrown ligands are analogous to <a href="/wiki/Crown_ether" title="Crown ether">crown ethers</a>. The best studied thiacrown ligands have the formula (SCH<sub>2</sub>CH<sub>2</sub>)<sub>n</sub> (n = 3,4,5,6). The tridentate tri-thioether <a href="/wiki/9-ane-S3" class="mw-redirect" title="9-ane-S3">9-ane-S3</a> forms extensive families of complexes of the type M(9-ane-S3)L<sub>3</sub> and [M(9-ane-S3)<sub>2</sub>]<sup>2+</sup>. Examples of Cu(II)-thioether complexes were prepared from 14-ane-S4<sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup> and 15-ane-S5.<sup id="cite_ref-Janz_11-1" class="reference"><a href="#cite_note-Janz-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> The hexadentate ligand 18-ane-6 also forms extensive family of complexes, including unusual examples of Pd(III) and Ag(II).<sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup> Examples of homoleptic complexes [M(SR<sub>2</sub>)<sub>6</sub>]<sup>n+</sup> are otherwise rare. </p> <div class="mw-heading mw-heading2"><h2 id="Occurrence">Occurrence</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Transition_metal_thioether_complex&action=edit&section=5" title="Edit section: Occurrence"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Thioether complexes in nature arise from coordination of the sulfur substituent found in the amino acid <a href="/wiki/Methionine" title="Methionine">methionine</a>. One of the axial ligands in <a href="/wiki/Cytochrome_c" title="Cytochrome c">cytochrome c</a> is illustrative. Methionine sulfur weakly binds to copper in <a href="/wiki/Azurin" title="Azurin">azurin</a>. </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Transition_metal_thioether_complex&action=edit&section=6" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-references-wrap mw-references-columns"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFKrogh-JespersenZhangDingWestbrook1992" class="citation journal cs1">Krogh-Jespersen, Karsten; Zhang, Xiaohua; Ding, Yanbo; Westbrook, John D.; Potenza, Joseph A.; Schugar, Harvey J. 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"Redox Non-innocence of Thioether Macrocycles: Elucidation of the Electronic Structures of Mononuclear Complexes of Gold(II) and Silver(II)". <i>Journal of the American Chemical Society</i>. <b>128</b> (42): 13827–13839. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fja0636439">10.1021/ja0636439</a>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/17044711">17044711</a>.</cite><span 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.navbar{display:none!important}}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Coordination_complexes" title="Template:Coordination complexes"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Coordination_complexes" title="Template talk:Coordination complexes"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Coordination_complexes" title="Special:EditPage/Template:Coordination complexes"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Coordination_complexes" style="font-size:114%;margin:0 4em"><a href="/wiki/Coordination_complex" title="Coordination complex">Coordination complexes</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">H donors:</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Transition_metal_hydride" title="Transition metal hydride">H<sup>−</sup></a></li> <li><a href="/wiki/Dihydrogen_complex" title="Dihydrogen complex">H<sub>2</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">B donors:</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Transition_metal_boryl_complex" title="Transition metal boryl complex">BR<sub>2</sub><sup>−</sup></a></li> <li><a href="/wiki/Metallaborane" title="Metallaborane">B<sub>m</sub>H<sub>n</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">C donors:</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Transition_metal_alkyl_complexes" title="Transition metal alkyl complexes">R<sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_acyl_complexes" title="Transition metal acyl complexes">RC(O)<sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_formyl_complex" title="Transition metal formyl complex">HC(O)<sup>−</sup></a></li> <li><a href="/wiki/Transition-metal_allyl_complex" title="Transition-metal allyl complex">CH<sub>2</sub>＝CH-CH<sub>2</sub><sup>−</sup></a></li> <li><a href="/wiki/Trimethylenemethane_complexes" title="Trimethylenemethane complexes">C(CH<sub>2</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Transition_metal_alkene_complex" title="Transition metal alkene complex">CH<sub>2</sub>＝CH<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_alkyne_complex" title="Transition metal alkyne complex">RC<sub>2</sub>R</a></li> <li><a href="/wiki/Transition_metal_benzyne_complex" title="Transition metal benzyne complex">C<sub>6</sub>H<sub>4</sub></a></li> <li><a href="/wiki/Cyanometalate" title="Cyanometalate">CN<sup>−</sup></a></li> <li><a href="/wiki/Metal_carbonyl" title="Metal carbonyl">CO</a></li> <li><a href="/wiki/Metal_carbon_dioxide_complex" title="Metal carbon dioxide complex">CO<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_carbide" class="mw-redirect" title="Transition metal carbide">C<sup>4-</sup></a></li> <li><a href="/wiki/Transition_metal_arene_complex" title="Transition metal arene complex">C<sub>6</sub>R<sub>6</sub></a></li> <li><a href="/wiki/Transition_metal_fullerene_complex" title="Transition metal fullerene complex">C<sub>60</sub> & C<sub>70</sub></a></li> <li><a href="/wiki/Transition_metal_isocyanide_complexes" title="Transition metal isocyanide complexes">RNC</a></li> <li><a href="/wiki/Transition_metal_carbene_complex" title="Transition metal carbene complex">=CR<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_carbyne_complex" title="Transition metal carbyne complex">≡CR</a></li> <li><a href="/wiki/Metallocene" title="Metallocene">C<sub>5</sub>H<sub>5</sub><sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_indenyl_complex" title="Transition metal indenyl complex">C<sub>9</sub>H<sub>7</sub><sup>−</sup></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Si donors:</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Transition_metal_silane_complexes" class="mw-redirect" title="Transition metal silane complexes">H<sub>n</sub>SiR<sub>4−n</sub></a></li> <li><a href="/wiki/Transition_metal_silyl_complexes" title="Transition metal silyl complexes">R<sub>3</sub>Si<sup>−</sup></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">N donors:</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Metal_ammine_complex" title="Metal ammine complex">NH<sub>3</sub></a></li> <li><a href="/wiki/Transition_metal_azide_complex" title="Transition metal azide complex">N<sub>3</sub><sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_imidazole_complex" title="Transition metal imidazole complex">imidazole</a></li> <li><a href="/wiki/Metal_nitrosyl_complex" title="Metal nitrosyl complex">NO</a></li> <li><a href="/wiki/Transition_metal_nitroso_complexes" title="Transition metal nitroso complexes">RNO</a></li> <li><a href="/wiki/Transition_metal_nitrite_complex#Bonding_modes" title="Transition metal nitrite complex">NO<sub>2</sub><sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_pyridine_complexes" title="Transition metal pyridine complexes">py</a></li> <li><a href="/wiki/Transition_metal_amino_acid_complexes" title="Transition metal amino acid complexes">amino acid</a></li> <li><a href="/wiki/Metal_nitrido_complex" title="Metal nitrido complex">N<sup>3-</sup></a></li> <li><a href="/wiki/Transition_metal_imido_complex" title="Transition metal imido complex">RN<sup>2-</sup></a></li> <li><a href="/wiki/Transition_metal_nitrile_complexes" title="Transition metal nitrile complexes">RCN</a></li> <li><a href="/wiki/Transition_metal_complexes_of_2,2%27-bipyridine" title="Transition metal complexes of 2,2'-bipyridine">bipy</a></li> <li><a href="/wiki/Transition_metal_complexes_of_1,10-phenanthroline" title="Transition metal complexes of 1,10-phenanthroline">phen</a></li> <li><a href="/wiki/Transition_metal_porphyrin_complexes" title="Transition metal porphyrin complexes">porphyrin</a></li> <li><a href="/wiki/Metal_bis(trimethylsilyl)amides" title="Metal bis(trimethylsilyl)amides">(Me<sub>3</sub>Si)<sub>2</sub>N<sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_dinitrogen_complex" title="Transition metal dinitrogen complex">N<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_complexes_of_thiocyanate" title="Transition metal complexes of thiocyanate"><i>N</i>CS<sup>-</sup></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">P donors:</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Metal_phosphine_complex" class="mw-redirect" title="Metal phosphine complex">PR<sub>3</sub></a></li> <li><a href="/wiki/Transition_metal_phosphido_complexes" title="Transition metal phosphido complexes">PR<sub>2</sub><sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_complexes_of_phosphine_oxides#Secondary_phosphine_oxides_as_ligands" title="Transition metal complexes of phosphine oxides">PR<sub>2</sub>OH</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">O donors:</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Metal_aquo_complex" title="Metal aquo complex">H<sub>2</sub>O</a></li> <li><a href="/wiki/Transition_metal_ether_complex" title="Transition metal ether complex">R<sub>2</sub>O</a></li> <li><a href="/wiki/Metal_alkoxide" class="mw-redirect" title="Metal alkoxide">RO<sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_oxo_complex" title="Transition metal oxo complex">O<sup>2-</sup></a></li> <li><a href="/wiki/Transition_metal_dioxygen_complex" title="Transition metal dioxygen complex">O<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_carbonate_and_bicarbonate_complexes" title="Transition metal carbonate and bicarbonate complexes">CO<sub>3</sub><sup>2-</sup>/HCO<sub>3</sub><sup>-</sup></a></li> <li><a href="/wiki/Transition_metal_oxalate_complex" title="Transition metal oxalate complex">C<sub>2</sub>O<sub>4</sub><sup>2-</sup></a></li> <li><a href="/wiki/Transition_metal_carboxylate_complex" title="Transition metal carboxylate complex">RCO<sub>2</sub><sup>−</sup></a></li> <li><a href="/wiki/Metal_acetylacetonates" title="Metal acetylacetonates">acac</a></li> <li><a href="/wiki/Transition_metal_complexes_of_aldehydes_and_ketones" title="Transition metal complexes of aldehydes and ketones">R<sub>2</sub>CO</a></li> <li><a href="/wiki/Transition_metal_nitrite_complex" title="Transition metal nitrite complex">ONO<sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_nitrate_complex" title="Transition metal nitrate complex">NO<sub>3</sub><sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_perchlorate_complexes" title="Transition metal perchlorate complexes">ClO<sub>4</sub><sup>-</sup></a></li> <li><a href="/wiki/Transition_metal_complexes_of_pyridine-N-oxides" title="Transition metal complexes of pyridine-N-oxides">C<sub>5</sub>H<sub>5</sub>NO</a></li> <li><a href="/wiki/Transition_metal_sulfoxide_complex" title="Transition metal sulfoxide complex">OSR<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_sulfate_complex" title="Transition metal sulfate complex">SO<sub>4</sub><sup>2-</sup></a></li> <li><a href="/wiki/Transition_metal_phosphate_complex" title="Transition metal phosphate complex">PO<sub>4</sub><sup>3-</sup></a></li> <li><a href="/wiki/Transition_metal_complexes_of_phosphine_oxides" title="Transition metal complexes of phosphine oxides">OPR<sub>3</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">S donors:</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Transition_metal_dithiocarbamate_complexes" title="Transition metal dithiocarbamate complexes">R<sub>2</sub>NCS<sub>2</sub><sup>−</sup></a></li> <li><a href="/wiki/Transition_metal_thiolate_complex" title="Transition metal thiolate complex">RS<sup>−</sup></a></li> <li><a class="mw-selflink selflink">R<sub>2</sub>S</a></li> <li><a href="/wiki/Metal_dithiolene_complex" title="Metal dithiolene complex">R<sub>2</sub>C<sub>2</sub>S<sub>2</sub><sup>2-</sup></a></li> <li><a href="/wiki/Metal_sulfur_dioxide_complex" title="Metal sulfur dioxide complex">SO<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_thiosulfate_complex" title="Transition metal thiosulfate complex">S<sub>2</sub>O<sub>3</sub><sup>2-</sup></a></li> <li><a href="/wiki/Transition_metal_sulfoxide_complex" title="Transition metal sulfoxide complex">SR<sub>2</sub>O</a></li> <li><a href="/wiki/Transition_metal_complexes_of_thiocyanate" title="Transition metal complexes of thiocyanate">NC<i>S</i><sup>-</sup></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Halide donors:</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/w/index.php?title=Fluoro_complex&action=edit&redlink=1" class="new" title="Fluoro complex (page does not exist)">F<sup>−</sup></a></li> <li><a href="/wiki/Difluorine_complex" title="Difluorine complex">F<sub>2</sub></a></li> <li><a href="/wiki/Transition_metal_chloride_complex" title="Transition metal chloride complex">Cl<sup>−</sup></a></li> <li><a href="/w/index.php?title=Bromo_complex&action=edit&redlink=1" class="new" title="Bromo complex (page does not exist)">Br<sup>−</sup></a></li> <li><a href="/w/index.php?title=Iodo_complex&action=edit&redlink=1" class="new" title="Iodo complex (page does not exist)">I<sup>−</sup></a></li></ul> </div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">Retrieved from "<a dir="ltr" href="https://en.wikipedia.org/w/index.php?title=Transition_metal_thioether_complex&oldid=1202267167">https://en.wikipedia.org/w/index.php?title=Transition_metal_thioether_complex&oldid=1202267167</a>"</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div 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