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Can Flow Batteries Finally Beat Lithium? - IEEE Spectrum
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tag-evs tag-flow-batteries tag-grid-storage tag-lithium-ion-batteries tag-type-cover tag-batteries tag-nanoelectrofuel-batteries post-section--topic/energy" data-category="Energy"><article elid="2666672335" data-frozen-sections="[]" class="clearfix image-article sm-mb-1 quality-HD post-2666672335" data-category="Energy"><div class="row px10"><div class="rm-col-center col sm-mb-1" style="width:100.0%;"><div class="widget__body clearfix sm-mt-1"><div class="all-related-sections"><a href="https://spectrum.ieee.org/topic/energy/">Energy</a><a href="https://spectrum.ieee.org/magazine/">Magazine</a><a href="https://spectrum.ieee.org/type/feature/">Feature</a><a href="https://spectrum.ieee.org/topic/climate-tech/">Climate Tech</a><a href="https://spectrum.ieee.org/magazine/2024/february/">February 2024</a><a href="https://spectrum.ieee.org/collections/climate-change/">Climate Change</a></div><h1 class="widget__headline h1"><span class="widget__headline-text custom-post-headline" data-type="text"> Can Flow Batteries Finally Beat Lithium? </span></h1><div class="widget__subheadline"><h2 class="widget__subheadline-text h2" data-type="text"><p>Nanoparticles may boost energy density enough for EVs</p></h2></div><div class="social-author clearfix"><div class="social-author__avatar image"><div class="cover-all image" style="background-image: url("https://spectrum.ieee.org/media-library/eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJpbWFnZSI6Imh0dHBzOi8vYXNzZXRzLnJibC5tcy8yNjY0NTkxNC9vcmlnaW4ucG5nIiwiZXhwaXJlc19hdCI6MTc1NDM4NzE3M30.MTQySQ4SkKwqBh31wur--gqjA9a52wpqPBFrbbae81E/image.png?width=210")"></div></div><a class="social-author__name" href="https://spectrum.ieee.org/u/robert-n-charette" data-type="text">Robert N. Charette</a></div><div class="social-date"><span class="social-date__text">24 Dec 2023</span></div><div class="time-to-read">10 min read</div><div class="like-button" data-post-likes="17"></div><div class="widget__shares share-panel"><!-- EMAIL --><a href="mailto:?subject=Can%20Flow%20Batteries%20Finally%20Beat%20Lithium%3F&body=https://spectrum.ieee.org/flow-battery-2666672335" target="_blank" data-track-share="Email" class="share share-popup share-email" rel="noopener noreferrer" aria-label="Share via Email"><i aria-hidden="true" class="icons-share em fa fa-envelope"></i></a><!-- COPY LINK --><a href="https://spectrum.ieee.org/flow-battery-2666672335" data-clipboard-text="https://spectrum.ieee.org/flow-battery-2666672335" class="share share-copy-link" title="Copy this link to clipboard"><i class="icons-share" style="width: 60%"><svg aria-hidden="true" data-prefix="far" data-icon="copy" class="svg-inline--fa fa-copy fa-w-14" role="img" xmlns="http://www.w3.org/2000/svg" viewbox="0 0 448 512"><path fill="currentColor" d="M433.941 65.941l-51.882-51.882A48 48 0 0 0 348.118 0H176c-26.51 0-48 21.49-48 48v48H48c-26.51 0-48 21.49-48 48v320c0 26.51 21.49 48 48 48h224c26.51 0 48-21.49 48-48v-48h80c26.51 0 48-21.49 48-48V99.882a48 48 0 0 0-14.059-33.941zM266 464H54a6 6 0 0 1-6-6V150a6 6 0 0 1 6-6h74v224c0 26.51 21.49 48 48 48h96v42a6 6 0 0 1-6 6zm128-96H182a6 6 0 0 1-6-6V54a6 6 0 0 1 6-6h106v88c0 13.255 10.745 24 24 24h88v202a6 6 0 0 1-6 6zm6-256h-64V48h9.632c1.591 0 3.117.632 4.243 1.757l48.368 48.368a6 6 0 0 1 1.757 4.243V112z"></path></svg></i></a><!-- TWITTER --><a href="https://twitter.com/intent/tweet?url=https://spectrum.ieee.org/flow-battery-2666672335&text=Can%20Flow%20Batteries%20Finally%20Beat%20Lithium%3F&" target="_blank" data-track-share="Twitter" class="share share-popup share-tw" rel="noopener noreferrer" aria-label="Share on Twitter"><i aria-hidden="true" class="icons-share tw fa fa-twitter"></i></a><!-- FACEBOOK --><a href="https://www.facebook.com/sharer/sharer.php?u=https%3A%2F%2Fspectrum.ieee.org%2Fflow-battery-2666672335%3Fxrs%3DRebelMouse_fb%26ts%3D1706104249" target="_blank" data-track-share="Facebook" class="share share-popup share-fb" rel="noopener noreferrer" aria-label="Share on Facebook"><i aria-hidden="true" class="icons-share fb fa fa-facebook"></i></a><!-- LINKEDIN --><a href="https://www.linkedin.com/shareArticle?mini=false&url=https://spectrum.ieee.org/flow-battery-2666672335&" target="_blank" class="share share-popup share-linkedin" data-track-share="Linkedin" rel="noopener noreferrer" aria-label="Share on Linkedin"><i aria-hidden="true" class="icons-share fa fa-linkedin"></i></a></div><div class="custom-field-FeaturePostImgPosition">Vertical</div></div><div class="widget__head"><picture><source srcset="https://spectrum.ieee.org/media-library/an-image-of-a-gas-nozzle-in-front-of-a-forest-with-lightning-coming-out.jpg?id=50902453&width=3600&height=4728 3x, https://spectrum.ieee.org/media-library/an-image-of-a-gas-nozzle-in-front-of-a-forest-with-lightning-coming-out.jpg?id=50902453&width=2400&height=3152 2x, https://spectrum.ieee.org/media-library/an-image-of-a-gas-nozzle-in-front-of-a-forest-with-lightning-coming-out.jpg?id=50902453&width=1200&height=1576 1x"/><img fetchpriority="high" role="img" alt="An image of a gas nozzle in front of a forest with lightning coming out. " aria-label="An image of a gas nozzle in front of a forest with lightning coming out. " src="https://spectrum.ieee.org/media-library/an-image-of-a-gas-nozzle-in-front-of-a-forest-with-lightning-coming-out.jpg?id=50902453&width=1200&height=1576" style="object-fit: cover;" class="rm-lazyloadable-image rm-hero-media" width="1800" height="2364"/></picture></div><div class="widget__body clearfix sm-mt-1"><div class="photo-credit"> Edmon De Haro </div><span class="js-scroll-trigger" data-target="body" data-triggers="render-rebelbar" data-toggle-class="with-floating-shares"></span><div id="utm_campaign"></div><div class="body js-expandable clearfix js-listicle-body css-listicle-body-2666672335" data-headline="Can Flow Batteries Finally Beat Lithium?"><div class="body-description"><p><strong>As she drives her </strong>electric vehicle to her mother’s house, Monique’s battery gauge indicates that it’s time to reenergize. She stops at a charging station, taps her credit card at the pump, inserts a nozzle into the car, and in 5 minutes exchanges 400 liters of spent nanofluid for fresher stuff. As she waits, a tanker pulls up to refill the station itself by exchanging tens of thousands of liters of charged for spent fuel. Monique closes her EV’s fueling port and heads onto the highway with enough stored energy to drive 640 kilometers (400 miles). </p><p> The battery in her EV is a variation on the <a href="https://spectrum.ieee.org/its-big-and-longlived-and-it-wont-catch-fire-the-vanadium-redoxflow-battery" target="_self">flow battery</a>, a design in which spent electrolyte can be replaced, the fastest option, or the battery could be directly recharged, though that takes longer. Flow batteries are safe, stable, long-lasting, and easily refilled, qualities that suit them well for balancing the grid, providing uninterrupted power, and backing up sources of electricity.</p><p> This battery, though, uses a completely new kind of fluid, called a nanoelectrofuel. Compared to a traditional flow battery of comparable size, it can store 15 to 25 times as much energy, allowing for a battery system small enough for use in an electric vehicle and energy-dense enough to provide the range and the speedy refill of a gasoline-powered vehicle. It’s the hoped-for civilian spin-off of a <a href="https://www.youtube.com/watch?v=8333g246i3o" rel="noopener noreferrer" target="_blank">project</a> that the <a href="https://www.darpa.mil/about-us/offices/STO" rel="noopener noreferrer" target="_blank">Strategic Technology Office</a> of the U.S. <a href="https://www.darpa.mil/about-us/offices/STO" rel="noopener noreferrer" target="_blank">Defense Advanced Research Projects Agency</a> (<a href="https://spectrum.ieee.org/tag/darpa">DARPA</a>) is pursuing as part of a drive to ease the military’s deployment of all-electric supply vehicles by <a href="https://www.politico.com/news/2021/03/31/electric-vehicles-biofuel-pentagon-biden-478764" rel="noopener noreferrer" target="_blank">2030</a> and of EV tactical vehicles by <a href="https://www.defensenews.com/smr/energy-and-environment/2023/10/09/us-army-ready-to-pursue-electric-light-recon-vehicle/#:~:text=As%20part%20of%20the%20Army's,2050%20to%20include%20a%20charging" rel="noopener noreferrer" target="_blank">2050</a>. </p><p><div class="rblad-ieee_in_content"></div></p><p class="shortcode-media shortcode-media-rebelmouse-image"><img alt="A symmetrical diagram with two cylindrical tanks, one atop the other, on either side of a rectangular reaction vessel in which positive ions flow to the right and electrons flow counterclockwise " class="rm-shortcode rm-lazyloadable-image" data-rm-shortcode-id="5c0b14a77f8c24987623b8fdd861b33c" data-rm-shortcode-name="rebelmouse-image" data-runner-src="https://spectrum.ieee.org/media-library/a-symmetrical-diagram-with-two-cylindrical-tanks-one-atop-the-other-on-either-side-of-a-rectangular-reaction-vessel-in-which-p.png?id=50902560&width=980" height="900" id="51bed" lazy-loadable="true" src="data:image/svg+xml,%3Csvg%20xmlns='http://www.w3.org/2000/svg'%20viewBox='0%200%201500%20900'%3E%3C/svg%3E" width="1500"/><small class="image-media media-caption" placeholder="Add Photo Caption...">Nanoparticles add greatly to the energy density of the fuel of the flow battery, making it suitable for use in <a href="https://spectrum.ieee.org/tag/evs">EVs</a>.</small><small class="image-media media-photo-credit" placeholder="Add Photo Credit...">Chris Philpot</small></p><p> Using lithium-based batteries would create its own <a href="https://www.americansecurityproject.org/battery-technology-and-the-military-ev-transition/" rel="noopener noreferrer" target="_blank">set of problems</a>. You’d need a charging infrastructure, which for the U.S. military would mean deploying one, often in inhospitable places. Then there’s the long charging time; the danger of thermal runaway—that is, fires; the relatively short working life of lithium batteries; and the difficulties of acquiring battery materials and recycling them when the old batteries are no longer any good. A battery that mitigates these problems is DARPA’s objective. The new flow battery seems to hit every mark. If it works, the benefits to the electrification of transportation would be huge. </p><h2>Flow batteries are safe and long-lived</h2><p> Nanoelectrofuel batteries are a <a href="https://iopscience.iop.org/article/10.1149/2.F06103if" rel="noopener noreferrer" target="_blank">new take</a> on the reduction-oxidation (redox) flow battery, which was <a href="https://en.wikipedia.org/wiki/Flow_battery" rel="noopener noreferrer" target="_blank">first proposed</a> nearly a century and a half ago. The design <a href="https://blog.upsbatterycenter.com/flow-batteries-history/" rel="noopener noreferrer" target="_blank">returned to life</a> in the mid-20th century, was developed for possible use on a moon base, and was further improved for use in grid storage. </p><p> The cell of a flow battery uses two chemical solutions containing ions, one acting as the anolyte (adjacent to the anode), the other as the catholyte (near the cathode). An electrochemical reaction between the two solutions pushes electrons through a circuit. Typical redox flow batteries use ions based on iron chromium or vanadium chemistries; the latter takes advantage of vanadium’s four distinct ionic states. </p><p> On the chemical side of the reaction, each solution is continuously pumped into separate sides of a battery cell. Ions pass from one solution to the other by crossing a membrane, which keeps the solutions apart. On the electrical side, current moves from one electrode into an external circuit, circling around before returning to the opposite electrode. The battery can be recharged in two ways: The two solutions can be charged in place by a current moving in the opposite direction, the way conventional batteries are charged, or the spent solutions can be replaced with charged ones. </p><p> Besides beating lithium batteries in performance and safety, flow batteries also scale up more easily: If you want to store more energy, just increase the size of the solution storage tanks or the concentration of the solutions. If you want to provide more power, just stack more cells on top of one another or add new stacks. </p><p> This scalability makes flow batteries suitable for applications that require as much as 100 megawatts, says <a href="https://volta.vc/about-us/" rel="noopener noreferrer" target="_blank">Kara Rodby</a>, a technical principal at <a href="https://volta.vc" rel="noopener noreferrer" target="_blank">Volta Energy Technologies</a>, in Naperville, Ill., and an expert in flow batteries. An example, she says, is the task of balancing energy flows in the <a href="https://spectrum.ieee.org/tag/power-grid">power grid. </a></p><p><div class="rblad-ieee_in_content"></div></p><p> However, conventional flow batteries pack very little energy into a given volume and mass. Their energy density is as little as 10 percent that of lithium-ion batteries. It has to do with the amount of material an aqueous solution can hold, Rodby explains. There is only so much salt you can dissolve in a glass of water. </p><p> Therefore, flow batteries have so far been too bulky for most applications. To shrink them enough to fit in <a href="https://spectrum.ieee.org/tag/electric-vehicles">electric vehicles</a>, you need to raise their energy density to that of lithium-ion batteries. </p><p class="shortcode-media shortcode-media-rebelmouse-image"><img alt="A number of vessels linked by tubes and held up by a tubular metal framework are shown. The one in the middle is orange; the others are white or transparent." class="rm-shortcode rm-lazyloadable-image" data-rm-shortcode-id="5f77ae87f41dccec2047528e37bac39d" data-rm-shortcode-name="rebelmouse-image" data-runner-src="https://spectrum.ieee.org/media-library/a-number-of-vessels-linked-by-tubes-and-held-up-by-a-tubular-metal-framework-are-shown-the-one-in-the-middle-is-orange-the-oth.png?id=50902569&width=980" height="2063" id="4d10f" lazy-loadable="true" src="data:image/svg+xml,%3Csvg%20xmlns='http://www.w3.org/2000/svg'%20viewBox='0%200%203000%202063'%3E%3C/svg%3E" width="3000"/><small class="image-media media-caption" placeholder="Add Photo Caption...">This 100-liter reaction vessel [orange] is used to make the anodes for the nanoelectrofuel flow battery. </small><small class="image-media media-photo-credit" placeholder="Add Photo Credit...">Influit Energy</small></p><h2>Nanoparticles boost flow battery’s energy density</h2><p> One good way to add capacity to a flow battery is with nanofluids, which hold nanoparticles in suspension. These particles undergo redox reactions at the electrode surface similar to how the dissolved ions react in conventional flow batteries, but the nanofluids are more energy dense. Importantly, the nanofluids are engineered to remain suspended indefinitely, unlike other suspensions—for instance, sand in water. That indefinite suspension helps the particles move through the system and make contact with the electrodes. The particles can compose up to 80 percent of the liquid’s weight while leaving it no more viscous than motor oil. </p><p> Nanofluids suspended in water-based electrolytes were first <a href="http://www.phys.iit.edu/~segre/nanoelectrofuels.pdf" rel="noopener noreferrer" target="_blank">investigated</a> for this application in 2009 by researchers at <a href="https://www.anl.gov/" rel="noopener noreferrer" target="_blank">Argonne National Laboratory</a> and the <a href="https://www.iit.edu/" rel="noopener noreferrer" target="_blank">Illinois Institute of Technology</a>. The scientists found the nanofluids could be used in a system with an energy-storing potential approaching that of a lithium-ion battery and with the pumpable recharging of a flow battery. What’s more, the nanoscale particles could be made from readily available, inexpensive minerals, such as ferric oxide and gamma manganese dioxide for the anode and cathode materials, respectively. </p><p> Additionally, because the nanoelectrofuel is an aqueous suspension, it did not catch fire or explode, nor would the material be hazardous if the battery were to leak. The battery possessed a wide operational range of between -40 °C and 80 °C. </p><p> In 2013, the team <a href="https://www.anl.gov/article/arpae-awards-iitargonne-team-34-million-for-breakthrough-battery-technology" rel="noopener noreferrer" target="_blank">received</a> a three-year, US $3.44 million grant from the <a href="https://www.energy.gov" rel="noopener noreferrer" target="_blank">U.S. Department of Energy’s</a> <a href="https://arpa-e.energy.gov/" rel="noopener noreferrer" target="_blank">Advanced Research Projects Agency–Energy</a> (ARPA-E) to build a prototype 1 kilowatt-hour nanoelectrofuel battery. The prototype’s success encouraged several of the principal investigators to spin off a company, called <a href="https://www.influitenergy.com/" rel="noopener noreferrer" target="_blank">Influit Energy</a>, to commercialize the technology. Through additional government contracts, the startup has continued to improve the components of the technology—the nanoelectrofuel itself, the battery architecture, and the recharging and delivery system. </p><p><a href="https://www.influitenergy.com/team/john-katsoudas" rel="noopener noreferrer" target="_blank">John Katsoudas</a>, a founder and chief executive of Influit, emphasizes the distinction between his company’s design and a conventional flow battery. “Our novelty is in doing what others have already done [with flow batteries] but doing it with nanofluids,” he says. </p><p> With the basic science problem resolved, Katsoudas adds, Influit is now developing a battery with an energy density rated at 550 to 850 watt-hours per kilogram or higher, as compared to 200 to 350 Wh/kg for a <a href="https://thundersaidenergy.com/downloads/lithium-ion-batteries-energy-density/#:~:text=(in%20mols).-,Today's%20lithium%20ion%20batteries%20have%20an%20energy%20density%20of%20200,0.1%20kg%20in%20the%20balance." rel="noopener noreferrer" target="_blank">standard</a> EV lithium-ion battery. The company expects larger versions would also beat old-style flow batteries at backing up the grid because the nanoelectrofuel can be reused at least as many times as a flow battery—10,000 or more cycles—and it will probably be cheaper. </p><p class="shortcode-media shortcode-media-rebelmouse-image"><img alt="Front view of a toy jeep with black grill, orange body, open top and a mass of wires in the back. Behind the jeep stands a man in a lab coat. Various lab equipment brackets the view, and on the right side there is another man bent over a laboratory bench." class="rm-shortcode rm-lazyloadable-image" data-rm-shortcode-id="2faba27e368cad34a4570c09fae7b140" data-rm-shortcode-name="rebelmouse-image" data-runner-src="https://spectrum.ieee.org/media-library/front-view-of-a-toy-jeep-with-black-grill-orange-body-open-top-and-a-mass-of-wires-in-the-back-behind-the-jeep-stands-a-man-i.png?id=50902651&width=980" height="2000" id="60f6d" lazy-loadable="true" src="data:image/svg+xml,%3Csvg%20xmlns='http://www.w3.org/2000/svg'%20viewBox='0%200%203000%202000'%3E%3C/svg%3E" width="3000"/><small class="image-media media-caption" placeholder="Add Photo Caption...">This remote-controlled toy Jeep is powered by a nanoelectrofuel flow battery. </small><small class="image-media media-photo-credit" placeholder="Add Photo Credit...">Influit Energy </small></p><p class="shortcode-media shortcode-media-rebelmouse-image"><img alt="Photo of the back part of an orange toy Jeep that is filled with apparatus, including cubical sections containing red wires and a small tank to which two tubes are attached" class="rm-shortcode rm-lazyloadable-image" data-rm-shortcode-id="a2b86c047f4b44b9e7205e995333cc62" data-rm-shortcode-name="rebelmouse-image" data-runner-src="https://spectrum.ieee.org/media-library/photo-of-the-back-part-of-an-orange-toy-jeep-that-is-filled-with-apparatus-including-cubical-sections-containing-red-wires-and.png?id=50902661&width=980" height="2000" id="6eeae" lazy-loadable="true" src="data:image/svg+xml,%3Csvg%20xmlns='http://www.w3.org/2000/svg'%20viewBox='0%200%203000%202000'%3E%3C/svg%3E" width="3000"/><small class="image-media media-caption" placeholder="Add Photo Caption...">This closeup shows the toy Jeep’s onboard nanoelectrofuel battery. </small><small class="image-media media-photo-credit" placeholder="Add Photo Credit...">Influit Energy </small></p><p class="shortcode-media shortcode-media-rebelmouse-image"><img alt="A white tray on a wooden table bears an assemblage of objects, including two transparent vessels. The objects are connected by a system of tubes and wires, some of which lead leftward to a square gray panel studded, on its perimeter, with a dozen metal screws threaded through bolts. Behind the tray with a digital display." class="rm-shortcode rm-lazyloadable-image" data-rm-shortcode-id="a39f81e390a04f38c09df8f71a9842e9" data-rm-shortcode-name="rebelmouse-image" data-runner-src="https://spectrum.ieee.org/media-library/a-white-tray-on-a-wooden-table-bears-an-assemblage-of-objects-including-two-transparent-vessels-the-objects-are-connected-by-a.png?id=50902658&width=980" height="2000" id="a42f3" lazy-loadable="true" src="data:image/svg+xml,%3Csvg%20xmlns='http://www.w3.org/2000/svg'%20viewBox='0%200%203000%202000'%3E%3C/svg%3E" width="3000"/><small class="image-media media-caption" placeholder="Add Photo Caption...">Here’s a clear view of a cell of the nanoelectrofuel battery, unobscured by any packaging other than its front panel, to the left. </small><small class="image-media media-photo-credit" placeholder="Add Photo Credit...">Influit Energy </small></p><p> The fuel would be created as needed, he says, eventually at such a scale as to replace fossil fuels. The fuel could be transported to depots much as gasoline is today, either by tanker trucks or via existing upgraded pipelines. At the depot, the spent fuel could be recharged with electricity from any source—solar, wind, hydroelectric, nuclear, or fossil fuels. The recharging could also be done at a service station or in the EV itself. In the latter case, the recharging would work just as it does for today’s battery electric vehicles. </p><p> What if there were a tanker crash or a pipeline rupture? </p><p> “The NEF turns into a pastelike substance, which you then sweep up,” Katsoudas explains. If you don’t want to wait for it to dry, he adds, you can add more water to reduce the acidity, “then you just shop-vac it up.” </p><p> What you do not want to do is throw that stuff away. “What is collected is the most valuable part of the battery,” he says. “There are processes to easily reconstitute the active material into a new nanofluid that can be reused.” </p><p>And what of the risks of the charged liquids intermingling? Katsoudas says they have demonstrated that directly mixing the different existing anolyte and catholyte liquids poses minimal safety hazards, and that since the next generation NEF materials will use identical liquids, the risks are minimized altogether.</p><h2>Designing a flow battery for electric vehicles</h2><p> On every count, nanoelectrofuel flow batteries appear to beat lithium-ion batteries for use in EVs and larger systems. Influit expects that its current generation of nanoelectrofuel, together with the entire ecosystem needed to produce, distribute, and recycle the fuel that the company is building around it, should cost $130/kWh when used in an EV. In comparison, <a href="https://about.bnef.com/blog/lithium-ion-battery-pack-prices-rise-for-first-time-to-an-average-of-151-kwh/" rel="noopener noreferrer" target="_blank">lithium-ion batteries cost</a> around $138/kWh. True, lithium-ion’s costs should drop below $100/kWh in a few years, but Influit expects its next-generation nanoelectrofuel to fall even further, to around $50 to $80/kWh. That next-gen system should have 5 times the energy density of present Li-ion systems. </p><p> Here’s what that means for an EV. </p><p> A <a href="https://motorandwheels.com/electric-cars-battery-sizes/" rel="noopener noreferrer" target="_blank">typical EV battery</a> today occupies about the same volume as would a flow battery with 400 liters of nanelectrofuel. If nanoparticles made up 30 percent of the weight of that fuel, the EV would have a range of only 105 km. Raise that to 40 percent, and the range would climb to 274 km. At 50 percent, it hits 362 km. And at 80 percent, it’s 724 km (450 miles). And that’s all assuming the flow battery’s tank remains the same size. </p><p> Influit has already achieved the 50 percent mark and has demonstrated an 80 percent nanoelectrofuel, says <a href="https://www.darpa.mil/staff/mr-aaron-kofford" rel="noopener noreferrer" target="_blank">Aaron Kofford</a>, a program manager in DARPA’s Strategic Technology Office. </p><p> For the military, nanoelectrofuel batteries have obvious advantages over lithium-ion batteries as well as internal combustion engines, Kofford says. In military fighting vehicles, protecting a vehicle’s fossil-fuel tank is critical, but that added protection weighs a lot and requires that the vehicle have a heavier suspension. That weight, in turn, reduces range and payload. Lithium-ion batteries, which are heavy in themselves and prone to fires, would also need to be heavily shielded against a shell hit. </p><p> By contrast, nanoelectrofuel batteries are fireproof, so the weight and safety issues are reduced tremendously. This video shows flammability tests with nanoelectrofuel samples: </p><p class="shortcode-media shortcode-media-youtube"><span class="rm-shortcode" data-rm-shortcode-id="3252d2e8b85ad1a07da7f96a4dc0325b" style="display:block;position:relative;padding-top:56.25%;"><iframe frameborder="0" height="auto" type="lazy-iframe" scrolling="no" data-runner-src="https://www.youtube.com/embed/DsbqNSUklNE?rel=0" style="position:absolute;top:0;left:0;width:100%;height:100%;" width="100%"></iframe></span><small class="image-media media-photo-credit" placeholder="Add Photo Credit...">Influit Energy</small></p><p> “At the <a href="https://www.youtube.com/watch?v=8333g246i3o" rel="noopener noreferrer" target="_blank">system level</a>, if we can take a chemistry that is inherently safe, we don’t need as much inner packaging in the battery itself,” Kofford says. They also don’t give off as much heat, so the vehicles are harder to spot from a distance, he adds. Civilian applications for nanoelectrofuel flow batteries beckon, notably in aviation. The reduced need for fire-safety systems in electric aircraft is a draw, observes<a href="https://www.aiaa.org/detail/person/starr-ginn" rel="noopener noreferrer" target="_blank"> Starr Ginn</a>, NASA’s advanced air-mobility lead strategist. </p><p> With nanoelectrofuels, Ginn says, “You don’t [need] high-powered cables, you don’t have electromagnetic interference problems.” Nanoelectrofuel “just keeps checking these boxes off of all the things that are making it hard to build electric airplanes.” </p><p> Similarly, the <a href="https://www.afrl.af.mil/" rel="noopener noreferrer" target="_blank">U.S. Air Force Research Laboratory</a>’s <a href="https://www.wpafb.af.mil/News/Article-Display/Article/2344474/afrls-transformational-capabilities-office-reaches-initial-operating-capability/" rel="noopener noreferrer" target="_blank">Transformational Capabilities Office</a> is assessing how nanoelectrofuels <a href="https://www.wpafb.af.mil/News/Article-Display/Article/2832192/afrls-expeditionary-energy-campaign-commences/" rel="noopener noreferrer" target="_blank">could</a> help in combat operations. Influit is also working with a commercial partner to pilot nanoelectrofuel flow batteries in their line of electric utility vehicles. </p><h2>Lithium-ion batteries have a considerable head start</h2><p> Considerably more work must be done to fulfill the potential of nanoelectrofuel technology. Influit and its government sponsors expect it will take two more years to put together all the pieces of a closed-loop system and to prove its value and scalability in a variety of applications. Katsoudas says that by 2025 or 2026, the world will be ready to give a serious look to nanoelectrofuel flow batteries for powering zero-emission vehicles, grid backup, electric utility vehicles, and the like. </p><p> Two possible barriers block the technology’s ascent: market forces and competing technologies. </p><p> Lithium-ion batteries are a mature technology and have a developed market. Hundreds of billions of dollars are being <a href="https://spectrum.ieee.org/the-ev-transition-explained-2658463682" target="_self">poured</a> into the development and improvement of <a href="https://dragonflyenergy.com/types-of-lithium-batteries-guide/" rel="noopener noreferrer" target="_blank">lithium batteries of all types</a>, with governments underwriting much of the investment. For instance, <a href="https://www.darpa.mil/program/morphogenic-interfaces" rel="noopener noreferrer" target="_blank">DARPA</a>, the <a href="https://www.energy.gov/eere/vehicles/batteries" rel="noopener noreferrer" target="_blank">Department of Energy</a>, and the <a href="https://www.nsf.gov/awardsearch/showAward?AWD_ID=2101129" rel="noopener noreferrer" target="_blank">National Science Foundation</a> are working with a host of companies to overcome the limitations of lithium batteries. Government research organizations in the <a href="https://rechargebatteries.org/battery-research-innovation/#:~:text=Research%20&%20Innovation%20for%20Sustainable%20Battery%20Power.,leadership%20potential%20of%20the%20European%20battery%20industry." rel="noopener noreferrer" target="_blank">EU</a>, <a href="https://www.reuters.com/article/southkorea-battery/s-korea-launches-government-backed-battery-alliance-to-source-key-metals-idUSL4N31X27P" rel="noopener noreferrer" target="_blank">South Korea</a>, and elsewhere are funding similar research. To overtake lithium technology, Influit will have to convince someone with extremely deep pockets to help it scale up—perhaps from its own logistics supply chain or from EV manufacturers. </p><p class="shortcode-media shortcode-media-rebelmouse-image"><img alt="A man in a striped shirt stands behind a wooden table bearing three rectangular prisms with a metallic shine." class="rm-shortcode rm-lazyloadable-image" data-rm-shortcode-id="08652d34794527ebe15d71b5eedf07fd" data-rm-shortcode-name="rebelmouse-image" data-runner-src="https://spectrum.ieee.org/media-library/a-man-in-a-striped-shirt-stands-behind-a-wooden-table-bearing-three-rectangular-prisms-with-a-metallic-shine.png?id=50902785&width=980" height="1778" id="b51c1" lazy-loadable="true" src="data:image/svg+xml,%3Csvg%20xmlns='http://www.w3.org/2000/svg'%20viewBox='0%200%202200%201778'%3E%3C/svg%3E" width="2200"/><small class="image-media media-caption" placeholder="Add Photo Caption...">An Influit Energy technician assembles stacks of battery cells. </small><small class="image-media media-photo-credit" placeholder="Add Photo Credit...">Influit Energy </small></p><p> Then there is the technological competition. News arrives nearly daily of yet another lithium-ion advance. One report from researchers at the Chinese Academy of Sciences boasts of a <a href="https://iopscience.iop.org/article/10.1088/0256-307X/40/4/048201" rel="noopener noreferrer" target="_blank">711 Wh/kg lithium-ion battery</a>. A Chinese manufacturer <a href="https://thedriven.io/2023/05/24/breakthrough-ev-battery-pack-could-last-2-million-kms-or-130-years-of-average-driving/" rel="noopener noreferrer" target="_blank">claims</a> that a new lithium manganese iron phosphate battery chemistry will power an EV for 1,000 km on a single charge and last 130 years. Other announcements involve <a href="https://www.eurekalert.org/news-releases/993042" rel="noopener noreferrer" target="_blank">significant improvements</a> in rapidly charging lithium-based batteries and making them <a href="https://www.haaretz.com/haaretz-labels/chariotindustries/2023-03-19/ty-article-labels/.premium/power-to-defend-producing-the-next-generation-of-military-batteries/00000186-f913-dd8e-a7d7-ff7fdab90000" rel="noopener noreferrer" target="_blank">safer for use in military vehicles</a>. </p><p> Then there are the new battery chemistries that are not lithium based—for instance, <a href="https://cleantechnica.com/2023/04/22/the-sodium-ion-battery-is-coming-to-production-cars-this-year/" rel="noopener noreferrer" target="_blank">sodium-ion</a> and<a href="https://www.gac-motor.com/en/media/newsdetail/id/166.html" rel="noopener noreferrer" target="_blank"> graphene-based</a> batteries. And there have been advances in grid-scale batteries involving <a href="https://spectrum.ieee.org/liquid-metal-battery" target="_self">liquid metal technology</a>, and <a href="https://www.pv-magazine.com/2023/01/13/lithium-sulfur-flow-battery-with-250-wh-l-energy-density/" rel="noopener noreferrer" target="_blank">improved</a> traditional flow-battery technology using lithium sulfur. </p><p> Other direct competitors to Influit include <a href="https://www.efuel-alliance.eu/efuels" rel="noopener noreferrer" target="_blank">e-fuels</a> (synthetic carbon-based and carbon-neutral fuels produced from captured carbon dioxide and water using renewable electricity sources), as well as liquid organic hydrogen. Both fuels aim <a href="https://www.whitehouse.gov/briefing-room/statements-releases/2023/10/13/biden-harris-administration-announces-regional-clean-hydrogen-hubs-to-drive-clean-manufacturing-and-jobs/" rel="noopener noreferrer" target="_blank">to directly displace fossil fuels</a>. For Influit to gain market adoption, Volta’s Rodby says, the company will need to articulate what the “market differentiator” for nanoelectrofuels is. Right now it seems the technology is a particularly good fit for the Department of Defense, which would likely be willing to pay a premium for it. As the largest user of fossil fuels in government, the DOD alone may enable Influit Energy to get to scale. </p><p> Of course, it may turn out that nanoelectrofuels find a home in other applications, such as boats, trains, or planes. For example, the largest cargo container ship carries some 15 million liters of fuel. If some portion of that were nanoelectrofuel that could be continually recharged, it might be possible to reduce the ship’s carbon footprint. </p><p> There is a rich history of apparently superior technologies that came too late <a href="https://spectrum.ieee.org/xerox-alto" target="_self">or too early</a> to displace the incumbents. Nanoelectrofuel flow batteries appear to be superior to what we have today. Perhaps they will also be lucky. <span class="ieee-end-mark"></span></p><p><em>This article appears in the February 2024 print issue.</em></p><div class="around-the-web"><div class="from-your-site__headline">From Your Site Articles</div><ul class="around-the-web__list"><li class="from-your-site__item"><a href="https://spectrum.ieee.org/new-flow-battery-can-store-ten-times-more-energy" class="from-your-site__link" target="_blank" rel="noopener noreferrer">New Flow Battery Ups Storage Capacity by Factor of Ten ›</a></li><li class="from-your-site__item"><a href="https://spectrum.ieee.org/its-big-and-longlived-and-it-wont-catch-fire-the-vanadium-redoxflow-battery" class="from-your-site__link" target="_blank" rel="noopener noreferrer">It’s Big and Long-Lived, and It Won’t Catch Fire: The Vanadium Redox-Flow Battery ›</a></li></ul><div class="around-the-web__headline">Related Articles Around the Web</div><ul class="around-the-web__list"><li class="around-the-web__item"><a href="https://www.sciencedirect.com/topics/engineering/flow-battery" class="around-the-web__link" target="_blank" rel="noopener noreferrer">Flow Battery - an overview | ScienceDirect Topics ›</a></li><li class="around-the-web__item"><a href="https://en.wikipedia.org/wiki/Flow_battery" class="around-the-web__link" target="_blank" rel="noopener noreferrer">Flow battery - Wikipedia ›</a></li></ul></div></div></div><span class="" data-elid="2666672335" data-post-url="https://spectrum.ieee.org/flow-battery-2666672335" data-authors="Robert N. Charette" data-headline="Can Flow Batteries Finally Beat Lithium?" data-page-title="Can Flow Batteries Finally Beat Lithium? - IEEE Spectrum"></span><div class="tags"><a class="tags__item" href="https://spectrum.ieee.org/tag/climate-change">climate change</a><a class="tags__item" href="https://spectrum.ieee.org/tag/climate-tech">climate tech</a><a class="tags__item" href="https://spectrum.ieee.org/tag/evs">evs</a><a class="tags__item" href="https://spectrum.ieee.org/tag/flow-batteries">flow batteries</a><a class="tags__item" href="https://spectrum.ieee.org/tag/grid-storage">grid storage</a><a class="tags__item" href="https://spectrum.ieee.org/tag/lithium-ion-batteries">lithium-ion batteries</a><a class="tags__item" href="https://spectrum.ieee.org/tag/type-cover">type:cover</a><a class="tags__item" href="https://spectrum.ieee.org/tag/batteries">batteries</a><a class="tags__item" href="https://spectrum.ieee.org/tag/nanoelectrofuel-batteries">nanoelectrofuel batteries</a></div></div></div></div><script type="application/json" id="post-context-2666672335" class="post-context post-context-2666672335"> {"customDimensions": {"5":"Robert N. 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Charette</a><div class="social-author__bio"><p><a href="https://www.linkedin.com/in/robert-charette-500309/" target="_blank">Robert N. Charette</a> is a Contributing Editor to <em>IEEE Spectrum</em> and an acknowledged international authority on information technology and systems risk management. A self-described “risk ecologist,” he is interested in the intersections of business, political, technological, and societal risks. Charette is an award-winning author of multiple books and numerous articles on the subjects of risk management, project and program management, innovation, and entrepreneurship. A Life Senior Member of the IEEE, Charette was a recipient of the IEEE Computer Society’s Golden Core Award in 2008.</p></div></div></div><div class="widget__head"></div></div></div><script type="application/json" id="post-context-2666672335" class="post-context post-context-2666672335"> {"customDimensions": {"5":"Robert N. 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Paying at the pump. Now what? TA-HW WON now I’m a gonner in a Ron Serling episode of “Dreams For Sale” - twilight Zone</p></div><div class="comment--item--action"><div><a href="javascript: void(0);" title="reply" class="comment--item__reply disabled" data-message_id="65c3d91d042aef7817a98518" aria-label="reply"><svg class="comment-action-icon" xmlns="http://www.w3.org/2000/svg" width="17" height="17" viewbox="0 0 24 24" aria-hidden="true"><path d="M10 9V5l-7 7 7 7v-4.1c5 0 8.5 1.6 11 5.1-1-5-4-10-11-11z"></path><path d="M0 0h24v24H0z" fill="none"></path></svg></a><a href="javascript: void(0);" title="share" class="comment--item__share disabled" data-message_id="65c3d91d042aef7817a98518" aria-label="share"><svg class="comment-action-icon" xmlns="http://www.w3.org/2000/svg" width="17" height="17" viewbox="0 0 24 24" aria-hidden="true"><path d="M0 0h24v24H0z" fill="none"></path><path d="M18 16.08c-.76 0-1.44.3-1.96.77L8.91 12.7c.05-.23.09-.46.09-.7s-.04-.47-.09-.7l7.05-4.11c.54.5 1.25.81 2.04.81 1.66 0 3-1.34 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aria-label="hide replies"><svg xmlns="http://www.w3.org/2000/svg" width="16" height="16" viewbox="0 0 24 24" aria-hidden="true"><path d="M12 8l-6 6 1.41 1.41L12 10.83l4.59 4.58L18 14z"></path><path d="M0 0h24v24H0z" fill="none"></path></svg> Hide replies </a><div class="reply-items hidden"></div><div class="talk--load_more__replies hidden" data-message_id="65c3d91d042aef7817a98518">Show More Replies</div></div></div><div id="comment-658c135153102b5acc4ea060" class="comment--item approved-comment" data-talk_id="post:2666672335:comments" data-message_id="658c135153102b5acc4ea060" data-parents=""><div class="comment--item-avatar"><img src="https://spectrum.ieee.org/res/avatars/default" title="Joseph Kerr" alt="Joseph Kerr" loading="lazy" width="38" height="38"/></div><div class="comment--item-text"><span class="comment--item-username">Joseph Kerr</span><span class="comment--item-date" title="December 27 2023, 12:06:41">27 Dec, 2023</span><div class="comment--custom-field-grade" data-value="INDV"> INDV </div><div class="comment--item-message"><p>I didn't see mention of use in cars?</p></div><div class="comment--item--action"><div><a href="javascript: void(0);" title="reply" class="comment--item__reply disabled" data-message_id="658c135153102b5acc4ea060" aria-label="reply"><svg class="comment-action-icon" xmlns="http://www.w3.org/2000/svg" width="17" height="17" viewbox="0 0 24 24" aria-hidden="true"><path d="M10 9V5l-7 7 7 7v-4.1c5 0 8.5 1.6 11 5.1-1-5-4-10-11-11z"></path><path d="M0 0h24v24H0z" fill="none"></path></svg></a><a href="javascript: void(0);" title="share" class="comment--item__share disabled" data-message_id="658c135153102b5acc4ea060" aria-label="share"><svg class="comment-action-icon" xmlns="http://www.w3.org/2000/svg" width="17" height="17" viewbox="0 0 24 24" aria-hidden="true"><path d="M0 0h24v24H0z" fill="none"></path><path d="M18 16.08c-.76 0-1.44.3-1.96.77L8.91 12.7c.05-.23.09-.46.09-.7s-.04-.47-.09-.7l7.05-4.11c.54.5 1.25.81 2.04.81 1.66 0 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aria-label="hide replies"><svg xmlns="http://www.w3.org/2000/svg" width="16" height="16" viewbox="0 0 24 24" aria-hidden="true"><path d="M12 8l-6 6 1.41 1.41L12 10.83l4.59 4.58L18 14z"></path><path d="M0 0h24v24H0z" fill="none"></path></svg> Hide replies </a><div class="reply-items hidden"></div><div class="talk--load_more__replies hidden" data-message_id="658c135153102b5acc4ea060">Show More Replies</div></div></div><div id="comment-658c2e4fb8fd66964927d311" class="comment--item approved-comment" data-talk_id="post:2666672335:comments" data-message_id="658c2e4fb8fd66964927d311" data-parents=""><div class="comment--item-avatar"><img src="https://spectrum.ieee.org/res/avatars/default" title="Daniel Smith" alt="Daniel Smith" loading="lazy" width="38" height="38"/></div><div class="comment--item-text"><span class="comment--item-username">Daniel Smith</span><span class="comment--item-date" title="December 27 2023, 14:01:51">27 Dec, 2023</span><div class="comment--custom-field-grade" data-value="M"> M </div><div class="comment--item-message"><p>Again the EV folks flunk geochemistry. Vanadium, like lithium, is relatively scarce in the Earth's crust. There are only thirteen elements we can use effectively without limit (H, C, N, O, Na, Mg, Al, Si, Cl, Ar, K, Ca, Fe) due to their abundance in Earth's atmosphere, oceans, or crust. Bulk use of any other elements will always prove uneconomical at scale. There's only enough lithium to service at most 10% of the current vehicle fleet. The technology may be neat, but it simply isn't commercially viable.</p></div><div class="comment--item--action"><div><a href="javascript: void(0);" title="reply" class="comment--item__reply disabled" data-message_id="658c2e4fb8fd66964927d311" aria-label="reply"><svg class="comment-action-icon" xmlns="http://www.w3.org/2000/svg" width="17" height="17" viewbox="0 0 24 24" aria-hidden="true"><path d="M10 9V5l-7 7 7 7v-4.1c5 0 8.5 1.6 11 5.1-1-5-4-10-11-11z"></path><path d="M0 0h24v24H0z" fill="none"></path></svg></a><a href="javascript: void(0);" title="share" class="comment--item__share disabled" data-message_id="658c2e4fb8fd66964927d311" aria-label="share"><svg class="comment-action-icon" xmlns="http://www.w3.org/2000/svg" width="17" height="17" viewbox="0 0 24 24" aria-hidden="true"><path d="M0 0h24v24H0z" fill="none"></path><path d="M18 16.08c-.76 0-1.44.3-1.96.77L8.91 12.7c.05-.23.09-.46.09-.7s-.04-.47-.09-.7l7.05-4.11c.54.5 1.25.81 2.04.81 1.66 0 3-1.34 3-3s-1.34-3-3-3-3 1.34-3 3c0 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it\u2019s schmuck....I just spilled some of that nanoelectrofuel on my paper cut. Paying at the pump. Now what? TA-HW WON now I\u2019m a gonner in a Ron Serling episode of \u201cDreams For Sale\u201d - twilight Zone\u003c/p\u003e", "data": null, "payload": {"review_score": 5}, "status": "approved", "rating": 10, "author_id": 24547848, "created_ts": 1707333917, "updated_ts": 1707333917, "parents": "", "counts": {"replies": {"total": 0, "direct": 0, "public": {"total": 0, "direct": 0, "total_eq_1": false}}, "reports": 0}}, {"id": "658c135153102b5acc4ea060", "html": "\u003cp\u003eI didn't see mention of use in cars?\u003c/p\u003e", "data": null, "payload": {"review_score": 5}, "status": "approved", "rating": 10, "author_id": 24145345, "created_ts": 1703678801, "updated_ts": 1703678801, "parents": "", "counts": {"replies": {"total": 0, "direct": 0, "public": {"total": 0, "direct": 0, "total_eq_1": false}}, "reports": 0}}, {"id": "658c2e4fb8fd66964927d311", "html": "\u003cp\u003eAgain the EV folks flunk geochemistry. Vanadium, like lithium, is relatively scarce in the Earth's crust. There are only thirteen elements we can use effectively without limit (H, C, N, O, Na, Mg, Al, Si, Cl, Ar, K, Ca, Fe) due to their abundance in Earth's atmosphere, oceans, or crust. Bulk use of any other elements will always prove uneconomical at scale. There's only enough lithium to service at most 10% of the current vehicle fleet. The technology may be neat, but it simply isn't commercially viable.\u003c/p\u003e", "data": null, "payload": {"review_score": 5}, "status": "approved", "rating": 9, "author_id": 24515027, "created_ts": 1703685711, "updated_ts": 1703685711, "parents": "", "counts": {"replies": {"total": 3, "direct": 3, "public": {"total": 3, "direct": 3, "total_eq_1": false}}, "reports": 0}}], "featuredComments": []} </script><div class="talk--load_more-wrp has_load_more"></div></div></div></div></div><!-- User Code --><script> var clickeableItems = [ ".talk-comments-wrp .add-comment", ".talk-comments-wrp .comment-item--publish", ".talk-comments-wrp .comment--item__reply", ".talk-comments-wrp .comment--item__like", ".talk-comments-wrp .comment--item__dislike", ".talk-comments-wrp .replies"]; var talkItems = document.querySelectorAll(clickeableItems.join(",")) || []; talkItems.forEach(function(item) { item.addEventListener("click", function(event){ event.preventDefault(); event.stopPropagation(); 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