Vinylmagnesium Chloride Solution | AMERICAN ELEMENTS ®

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<div class="elements-header clearfix"> <div class="panel-pane pane-entity-field pane-node-field-cas3" id="header-cas"> <div class="pane-content"> <h3 class="field-label inline-sibling">CAS #:</h3> <div class="field-cas3"><a href="https://www-americanelements-com.translate.goog/cas/3536-96-7?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">3536-96-7</a> </div> </div> </div> <div class="panel-separator"></div> <div class="panel-pane pane-entity-field pane-node-field-chem-ids header-chem" id="header-float"> <div class="pane-content"> <div class="field-chem-ids"> <h3 class="field-label inline-sibling">Linear Formula:</h3> <div class="field-formula"> CH<sub>2</sub>=CHMgCl </div> </div> </div> </div> <div class="panel-separator"></div> <div class="panel-pane pane-entity-field pane-node-field-chem-ids header-chem" id="chemid2"> <div class="pane-content"> <div class="field-chem-ids"><span id="block-display"><h3 class="field-label inline-sibling">MDL Number:</h3> <div class="field-mdl"> MFCD00013594 </div></span> <h3 class="field-label inline-sibling">EC No.:</h3> <div class="field-einecs"> 222-575-9 </div> </div> </div> </div> </div> <div class="elements-container elements-main clearfix"> <div class="elements-content product-information"> <div id="block-webform-client-block-257629" class="block block-webform"> <div id="popup-element-0" class="popup-element popup-element-noscript activate-click effect-fade expand-top-left origin-bottom-left"><a class="popup-element-title">Email SDS</a> <div class="popup-element-body expand-top-left opacity origin-bottom-left width-500"> <div class="inner"><a class="popup-close popup-close-button"><span>[X]</span></a> <form class="webform-client-form webform-client-form-257629" action="/vinylmagnesium-chloride-solution-3536-96-7" method="post" id="webform-client-form-257629" accept-charset="UTF-8"> <div> <div class="form-item webform-component webform-component-email 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Your email address will not be stored! </div> </div><input type="hidden" name="details[sid]"><input type="hidden" name="details[page_num]" value="1"><input type="hidden" name="details[page_count]" value="1"><input type="hidden" name="details[finished]" value="0"><input type="hidden" name="form_build_id" value="form-rgUPfnuTK7rcGJ5TX_IwNkbgIdEauB-pYkGXKvhm9C4"><input type="hidden" name="form_id" value="webform_client_form_257629"><input type="hidden" name="honeypot_time" value="1734498362|Pg4hyXMXM1tZgi1MdNcTTxMW9E5lT17n0V76H2t8V3M"> <div class="url-textfield"> <div class="form-item form-type-textfield form-item-url"><label for="edit-url">Leave this field blank </label> <input autocomplete="off" type="text" id="edit-url" name="url" value="" size="20" maxlength="128" class="form-text"> </div> </div> <div class="form-actions"> <input class="webform-submit button-primary form-submit" type="submit" name="op" value="Submit"> </div> </div> </form> </div> </div> </div> </div> <div class="panel-separator"></div> <div id="seal-mobile"> <a href="https://translate.google.com/website?sl=en&tl=nl&hl=en&u=https://en.wikipedia.org/wiki/American_Elements"><span class="element-invisible">View the history of American Elements on Wikipedia</span></a> </div> <div class="panel-separator"></div> <div class="panel-pane pane-views pane-add-to-cart"> <div class="pane-content"> <div class="view view-add-to-cart view-id-add_to_cart view-display-id-block_5 order-box view-dom-id-f60161ecb24f3957f0e5a67dd470e47e"> <div class="view-header"> <h3 id="request_quote">ORDER</h3> </div> <div class="view-content"> <table class="views-table cols-5" data-view-name="add_to_cart" data-view-display="block_5"> <thead> <tr> <th class="product-name" scope="col">PRODUCT</th> <th class="mobile-center pn-col" scope="col">Product Code</th> <th class="mobile-center request-quote-col" scope="col">ORDER</th> <th class="mobile-center sds-button-col" scope="col">SAFETY DATA</th> <th class="mobile-center tds-col" scope="col">TECHNICAL DATA</th> </tr> </thead> <tbody> <tr class="item-56435"> <td class="prod-name">Vinylmagnesium Chloride Solution, 1.6 M in THF<br><em></em></td> <td class="mobile-center pn-hide"> <div class="field-product-code-rfq"> MX-OMX-01-SOL.16MTHF </div></td> <td class="mobile-center"><a class="rfq-button" href="https://www-americanelements-com.translate.goog/quote?product=Vinylmagnesium+Chloride+Solution&var=Vinylmagnesium+Chloride+Solution,+1.6+M+in+THF&code=MX-OMX-01-SOL.16MTHF&purity=01&cas=3536-96-7&src=https://www.americanelements.com/vinylmagnesium-chloride-solution-3536-96-7&_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en" itemprop="potentialAction" content="Request Pricing" rel="noindex">Pricing ></a></td> <td class="mobile-center"><span class="sds-button-desktop mobile-center"><a class="sds-button" href="https://www-americanelements-com.translate.goog/printpdf/product/56435/sds?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en" rel="nofollow">SDS ></a></span></td> <td class="mobile-center"><a class="datasheet-button" href="https://www-americanelements-com.translate.goog/printpdf/product/56435/datasheet?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en" rel="nofollow">Data Sheet ></a></td> </tr> </tbody> </table> </div> <div class="view-footer"> WHOLESALE/SKU 0000-742-240835 </div> </div> </div> </div> <div class="panel-separator"></div> <div class="panel-pane pane-custom pane-2"> <div class="pane-content"> <h5 class="ask-question"><a href="https://www-americanelements-com.translate.goog/question-ask-an-american-elements-engineer?src=240835&_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Question? Ask an American Elements Materials Science Engineer</a></h5> </div> </div> <div class="panel-separator"></div> <div id="section-properties" class="ctools-collapsible-container product-material"> <h2 class="pane-title ctools-collapsible-handle">Vinylmagnesium Chloride Solution Properties (Theoretical)</h2> <div class="ctools-collapsible-content"> <div class="view view-data-tables view-id-data_tables view-display-id-block_2 product-data-table view-dom-id-23c9d0bcd5a57ef114ce5e14214efa33"> <div class="view-content"> <table class="views-table cols-9"> <tbody> <tr class=""> <th class="">Compound Formula</th> <td class="">C<sub>2</sub>H<sub>3</sub>ClMg</td> </tr> <tr class=""> <th class="">Molecular Weight</th> <td class="">88.8</td> </tr> <tr class=""> <th class="">Appearance</th> <td class="">Brown liquid</td> </tr> <tr class=""> <th class="">Melting Point</th> <td class="">N/A</td> </tr> <tr class=""> <th class="">Boiling Point</th> <td class="">N/A</td> </tr> <tr class=""> <th class="">Density</th> <td class="">0.980 g/mL</td> </tr> <tr class=""> <th class="">Solubility in H2O</th> <td class="">Reacts violently</td> </tr> <tr class=""> <th class="">Exact Mass</th> <td class="">85.977369 g/mol</td> </tr> <tr class=""> <th class="">Monoisotopic Mass</th> <td class="">85.977369 g/mol</td> </tr> </tbody> </table> </div> </div> </div> </div> <div class="panel-separator"></div> <div id="section-safety" class="ctools-collapsible-container paneled safety-data sds"> <h2 class="pane-title ctools-collapsible-handle">Vinylmagnesium Chloride Solution Health & Safety Information</h2> <div class="ctools-collapsible-content"> <div class="view view-data-tables view-id-data_tables view-display-id-block_4 view-dom-id-9bd8e2dc444e3275ba8b1d75cf643397"> <div class="view-content"> <table class="views-table cols-11"> <tbody> <tr class="views-row views-row-1 views-row-odd views-row-first"> <th class="">Signal Word</th> <td class=" views-column-odd views-column-first views-column-last">Danger</td> </tr> <tr class="views-row views-row-2 views-row-even"> <th class="">Hazard Statements</th> <td class=" views-column-odd views-column-first views-column-last">H225-H260-H302-H314-H335-H351</td> </tr> <tr class="views-row views-row-3 views-row-odd"> <th class="">Hazard Codes</th> <td class=" views-column-odd views-column-first views-column-last">F, C, T</td> </tr> <tr class="views-row views-row-4 views-row-even"> <th class="">Precautionary Statements</th> <td class=" views-column-odd views-column-first views-column-last">P210-P231 + P232-P280-P370 + P378-P402 + P404-P403 + P235</td> </tr> <tr class="views-row views-row-5 views-row-odd"> <th class="">Flash Point</th> <td class=" views-column-odd views-column-first views-column-last">1.4 °F -17 °C</td> </tr> <tr class="views-row views-row-6 views-row-even"> <th class="">Risk Codes</th> <td class=" views-column-odd views-column-first views-column-last">N/A</td> </tr> <tr class="views-row views-row-7 views-row-odd"> <th class="">Safety Statements</th> <td class=" views-column-odd views-column-first views-column-last">N/A</td> </tr> <tr class="views-row views-row-8 views-row-even"> <th class="">RTECS Number</th> <td class=" views-column-odd views-column-first views-column-last">N/A</td> </tr> <tr class="views-row views-row-9 views-row-odd"> <th class="">Transport Information</th> <td class=" views-column-odd views-column-first views-column-last">UN 3399A 4.3(3) / PGI</td> </tr> <tr class="views-row views-row-10 views-row-even"> <th class="">WGK Germany</th> <td class=" views-column-odd views-column-first views-column-last">1</td> </tr> <tr class="views-row views-row-11 views-row-odd views-row-last"> <th class="">GHS Pictograms</th> <td class="inline-div views-column-odd views-column-first views-column-last"> <div id="file-2655" class="file file-image file-image-png"> <h2 class="element-invisible"><a href="https://www-americanelements-com.translate.goog/file/2655?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">GHS05 Corrosive</a></h2> <div class="content"><img typeof="foaf:Image" src="https://www.americanelements.com/sites/public/files/images/ghs_images/corrosion.png" width="42" height="43" alt="Corrosive - GHS05" title="GHS05 - Corrosive"> </div> </div> <div id="file-2657" class="file file-image file-image-png"> <h2 class="element-invisible"><a href="https://www-americanelements-com.translate.goog/file/2657?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">GHS07 Exclamation Point</a></h2> <div class="content"><img typeof="foaf:Image" src="https://www.americanelements.com/sites/public/files/images/ghs_images/exclamation-mark.png" width="44" height="45" alt="Exclamation Point - GHS07" title="GHS07 - Exclamation Point"> </div> </div> <div id="file-2659" class="file file-image file-image-png"> <h2 class="element-invisible"><a href="https://www-americanelements-com.translate.goog/file/2659?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">GHS02 Flame</a></h2> <div class="content"><img typeof="foaf:Image" src="https://www.americanelements.com/sites/public/files/images/ghs_images/flame.png" width="42" height="42" alt="Flammable - GHS02" title="GHS02 - Flammable"> </div> </div> <div id="file-2660" class="file file-image file-image-png"> <h2 class="element-invisible"><a href="https://www-americanelements-com.translate.goog/file/2660?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">GHS08 Health Hazard</a></h2> <div class="content"><img typeof="foaf:Image" src="https://www.americanelements.com/sites/public/files/images/ghs_images/health-hazard.png" width="45" height="45" alt="Health Hazard - GHS08" title="GHS08 Health Hazard"> </div> </div></td> </tr> </tbody> </table> </div> </div> </div> </div> <div class="panel-separator"></div> <div id="sds" class="ctools-collapsible-container ctools-collapsed paneled paneled-padded paneled-sds"> <h2 class="pane-title ctools-collapsible-handle">View and Print SDS</h2> <div class="ctools-collapsible-content"> <div class="view view-sds-pane view-id-sds_pane view-display-id-block sds-content view-dom-id-046749484d799f66ccb072132c057db2"> <div class="view-header"> <div class="link-container"> <span class="print_pdf"><a href="https://www-americanelements-com.translate.goog/printpdf/vinylmagnesium-chloride-solution-3536-96-7/sds?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en" title="Display a printable version of this page." class="print-pdf" rel="nofollow">Print to PDF</a></span> </div> <h2 class="centered">SAFETY DATA SHEET</h2> <div id="sds-date"> <div> <strong>Date Accessed:</strong> 12/17/2024 </div> <div> <strong>Date Revised:</strong>01/15/2022 </div> </div> </div> <div class="view-content"> <div class="view-grouping"> <div> <hr> <h3>SECTION 1. IDENTIFICATION</h3> <p><strong>Product Name:</strong> Vinylmagnesium Chloride Solution</p> <p><strong>Product Number:</strong> All applicable American Elements product codes, e.g. MX-OMX-01-SOL.16MTHF</p> <p><strong>CAS #:</strong> 3536-96-7</p> <p><strong>Relevant identified uses of the substance: </strong> Scientific research and development</p> <p><strong>Supplier details:</strong><br> American Elements<br> 10884 Weyburn Ave.<br> Los Angeles, CA 90024<br> Tel: +1 310-208-0551<br> Fax: +1 310-208-0351</p> <p><strong>Emergency telephone number:</strong><br> Domestic, North America: +1 800-424-9300<br> International: +1 703-527-3887</p> <hr> <h3>SECTION 2. HAZARDS IDENTIFICATION</h3> <p>2.1 Classification of the substance or mixture<br> GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)<br> Flammable liquids (Category 2), H225<br> Substances and mixtures, which in contact with water, emit flammable gases (Category 1), H260<br> Acute toxicity, Oral (Category 4), H302<br> Skin corrosion (Category 1B), H314<br> Serious eye damage (Category 1), H318<br> Carcinogenicity (Category 2), H351<br> Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335</p> <p>2.2 GHS Label elements, including precautionary statements</p> <div class="ghs-images"> <img src="https://www.americanelements.com/flame.png" alt="Flame - GHS02" width="42" height="42"><img src="https://www.americanelements.com/health-hazard.png" alt="Health Hazard - GHS08" width="45" height="45"><img src="https://www.americanelements.com/corrosion.png" alt="Corrosion - GHS05" width="42" height="43"><img src="https://www.americanelements.com/exclamation-mark.png" alt="Exclamation Mark - GHS07" width="44" height="45"> </div> <p>Pictogram<br> Signal word Danger<br> Hazard statement(s)<br> H225 Highly flammable liquid and Vapor.<br> H260 In contact with water releases flammable gases which may ignite<br> spontaneously.<br> H302 Harmful if swallowed.<br> H314 Causes severe skin burns and eye damage.<br> H335 May cause respiratory irritation.<br> H351 Suspected of causing cancer.<br> Precautionary statement(s)<br> P201 Obtain special instructions before use.<br> P202 Do not handle until all safety precautions have been read and<br> understood.<br> P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.<br> P223 Do not allow contact with water.<br> P231 + P232 Handle under inert gas. Protect from moisture.<br> P233 Keep container tightly closed.<br> P240 Ground/bond container and receiving equipment.<br> P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.<br> P242 Use only non-sparking tools.<br> P243 Take precautionary measures against static discharge.<br> P261 Avoid breathing dust/ fume/ gas/ mist/ Vapors/ spray.<br> P264 Wash skin thoroughly after handling.<br> P270 Do not eat, drink or smoke when using this product.<br> P271 Use only outdoors or in a well-ventilated area.<br> P280 Wear protective gloves/ protective clothing/ eye protection/ face<br> protection.<br> P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you<br> feel unwell. Rinse mouth.<br> P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.<br> P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.<br> Rinse skin with water/shower.<br> P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for<br> breathing. Immediately call a POISON CENTER or doctor/ physician.<br> P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove<br> contact lenses, if present and easy to do. Continue rinsing. Immediately<br> call a POISON CENTER or doctor/ physician.<br> P308 + P313 IF exposed or concerned: Get medical advice/ attention.<br> P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet<br> bandages.<br> P363 Wash contaminated clothing before reuse.<br> P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to<br> extinguish.<br> P402 + P404 Store in a dry place. Store in a closed container.<br> P403 + P233 Store in a well-ventilated place. Keep container tightly closed.<br> P403 + P235 Store in a well-ventilated place. Keep cool.<br> P405 Store locked up.<br> P501 Dispose of contents/ container to an approved waste disposal plant.<br> 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS<br> Reacts violently with water., May form explosive peroxides.</p> <hr> <h3>SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS</h3> <p>3.2 Mixtures<br> Formula : C2H3ClMg<br> Molecular weight : 86.80 g/mol<br> Hazardous components<br> Component Classification Concentration<br> Tetrahydrofuran<br> CAS-No.<br> EC-No.<br> Index-No.<br> Registration number<br> 109-99-9<br> 203-726-8<br> 603-025-00-0<br> 01-2119444314-46-XXXX<br> Flam. Liq. 2; Acute Tox. 4; Eye<br> Irrit. 2A; Carc. 2; STOT SE 3;<br> H225, H302, H319, H335,<br> H351<br> >= 70 - < 90 %<br> Chlorovinylmagnesium<br> CAS-No.<br> EC-No.<br> 3536-96-7<br> 222-575-9<br> Water-react. 1; Skin Corr. 1B;<br> Eye Dam. 1; H260, H314,<br> H318<br> >= 10 - < 20 %</p> <hr> <h3>SECTION 4. FIRST AID MEASURES</h3> <p>4.1 Description of first aid measures<br> General advice<br> Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.<br> If inhaled<br> If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.<br> In case of skin contact<br> Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.<br> In case of eye contact<br> Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Continue rinsing eyes during<br> transport to hospital.<br> If swallowed<br> Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a<br> physician.<br> 4.2 Most important symptoms and effects, both acute and delayed<br> The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11<br> 4.3 Indication of any immediate medical attention and special treatment needed<br> No data available</p> <hr> <h3>SECTION 5. FIREFIGHTING MEASURES</h3> <p>5.1 Extinguishing media<br> Suitable extinguishing media<br> Dry powder<br> 5.2 Special hazards arising from the substance or mixture<br> Carbon oxides, Hydrogen chloride gas, Magnesium oxide<br> 5.3 Advice for firefighters<br> Wear self-contained breathing apparatus for firefighting if necessary.<br> 5.4 Further information<br> No data available</p> <hr> <h3>SECTION 6. ACCIDENTAL RELEASE MEASURES</h3> <p>6.1 Personal precautions, protective equipment and emergency procedures<br> Use personal protective equipment. Avoid breathing Vapors, mist or gas. Ensure adequate ventilation. Remove all<br> sources of ignition. Evacuate personnel to safe areas. Beware of Vapors accumulating to form explosive<br> concentrations. Vapors can accumulate in low areas.<br> For personal protection see section 8.<br> 6.2 Environmental precautions<br> Prevent further leakage or spillage if safe to do so. Do not let product enter drains.<br> 6.3 Methods and materials for containment and cleaning up<br> Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in<br> container for disposal according to local regulations (see section 13). Do not flush with water.<br> 6.4 Reference to other sections<br> For disposal see section 13.</p> <hr> <h3>SECTION 7. HANDLING AND STORAGE</h3> <p>7.1 Precautions for safe handling<br> Avoid contact with skin and eyes. Avoid inhalation of Vapor or mist.<br> Use explosion-proof equipment.Keep away from sources of ignition - No smoking.Take measures to prevent the build<br> up of electrostatic charge.<br> For precautions see section 2.2.<br> 7.2 Conditions for safe storage, including any incompatibilities<br> Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully<br> resealed and kept upright to prevent leakage.<br> Never allow product to get in contact with water during storage.<br> Store under inert gas. Dry residue is explosive. Test for peroxide formation periodically and before distillation. Dry<br> residue is explosive. Store under inert gas. Test for peroxide formation periodically and before distillation.<br> Storage class (TRGS 510): Hazardous materials, which set free flammable gases upon contact with water<br> 7.3 Specific end use(s)<br> Apart from the uses mentioned in section 1.2 no other specific uses are stipulated</p> <hr> <h3>SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION</h3> <p>8.1 Control parameters<br> Components with workplace control parameters<br> Component CAS-No. Value Control<br> parameters<br> Basis<br> Tetrahydrofuran 109-99-9 TWA 50.000000 ppm<br> USA. ACGIH Threshold Limit Values<br> (TLV)<br> Remarks Central Nervous System impairment<br> Upper Respiratory Tract irritation<br> Kidney damage<br> Confirmed animal carcinogen with unknown relevance to humans<br> Danger of cutaneous absorption<br> STEL 100.000000<br> ppm<br> USA. ACGIH Threshold Limit Values<br> (TLV)<br> Central Nervous System impairment<br> Upper Respiratory Tract irritation<br> Kidney damage<br> Confirmed animal carcinogen with unknown relevance to humans<br> Danger of cutaneous absorption<br> TWA 200.000000<br> ppm<br> 590.000000<br> mg/m3<br> USA. NIOSH Recommended<br> Exposure Limits<br> ST 250.000000<br> ppm<br> 735.000000<br> mg/m3<br> USA. NIOSH Recommended<br> Exposure Limits<br> TWA 200.000000<br> ppm<br> 590.000000<br> mg/m3<br> USA. Occupational Exposure Limits<br> (OSHA) - Table Z-1 Limits for Air<br> Contaminants<br> The value in mg/m3 is approximate.<br> Biological occupational exposure limits<br> Component CAS-No. Parameters Value Biological<br> specimen<br> Basis<br> Tetrahydrofuran 109-99-9 Tetrahydrofur<br> an<br> 2.0000<br> mg/l<br> Urine ACGIH - Biological<br> Exposure Indices<br> (BEI)<br> Remarks End of shift (As soon as possible after exposure ceases)<br> 8.2 Exposure controls<br> Appropriate engineering controls<br> Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of<br> workday.<br> Personal protective equipment<br> Eye/face protection<br> Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and<br> approved under appropriate government standards such as NIOSH (US) or EN 166(EU).<br> Skin protection<br> Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without<br> touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after<br> use in accordance with applicable laws and good laboratory practices. Wash and dry hands.<br> Splash contact<br> Material: butyl-rubber<br> Minimum layer thickness: 0.3 mm<br> Break through time: 10 min<br> Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M)<br> data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:<br> EN374<br> If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the<br> supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an<br> industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It<br> should not be construed as offering an approval for any specific use scenario.<br> Body Protection<br> Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of<br> protective equipment must be selected according to the concentration and amount of the dangerous substance<br> at the specific workplace.<br> Respiratory protection<br> Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose<br> combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.<br> If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and<br> components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).<br> Control of environmental exposure<br> Prevent further leakage or spillage if safe to do so. Do not let product enter drains.</p> <hr> <h3>SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES</h3> <p>9.1 Information on basic physical and chemical properties<br> a) Appearance Form: liquid<br> Colour: dark brown<br> b) Odor No data available<br> c) Odor Threshold No data available<br> d) pH No data available<br> e) Melting point/freezing<br> point<br> No data available<br> f) Initial boiling point and<br> boiling range<br> No data available<br> g) Flash point -17 °C (1 °F) - closed cup<br> h) Evaporation rate No data available<br> i) Flammability (solid, gas) No data available<br> j) Upper/lower<br> flammability or<br> explosive limits<br> No data available<br> k) Vapor pressure No data available<br> l) Vapor density No data available<br> m) Relative density 0.980 g/cm3<br> n) Water solubility No data available<br> o) Partition coefficient: noctanol/<br> water<br> No data available<br> p) Auto-ignition<br> temperature<br> No data available<br> q) Decomposition<br> temperature<br> No data available<br> r) Viscosity No data available<br> s) Explosive properties No data available<br> t) Oxidizing properties No data available<br> 9.2 Other safety information<br> No data available</p> <hr> <h3>SECTION 10. STABILITY AND REACTIVITY</h3> <p>10.1 Reactivity<br> No data available<br> 10.2 Chemical stability<br> Stable under recommended storage conditions.<br> 10.3 Possibility of hazardous reactions<br> Vapors may form explosive mixture with air.Reacts violently with water.<br> 10.4 Conditions to avoid<br> Heat, flames and sparks. Exposure to moisture<br> 10.5 Incompatible materials<br> Oxidizing agents, Oxygen, Reacts violently with water.<br> 10.6 Hazardous decomposition products<br> Other decomposition products - No data available<br> In the event of fire: see section 5</p> <hr> <h3>SECTION 11. TOXICOLOGICAL INFORMATION</h3> <p>11.1 Information on toxicological effects<br> Acute toxicity<br> No data available<br> Inhalation: No data available<br> Dermal: No data available<br> No data available<br> Skin corrosion/irritation<br> No data available<br> Serious eye damage/eye irritation<br> No data available<br> Respiratory or skin sensitisation<br> No data available<br> Germ cell mutagenicity<br> No data available<br> Carcinogenicity<br> IARC: No component of this product present at levels greater than or equal to 0.1% is identified as<br> probable, possible or confirmed human carcinogen by IARC.<br> NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a<br> known or anticipated carcinogen by NTP.<br> OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a<br> carcinogen or potential carcinogen by OSHA.<br> Reproductive toxicity<br> No data available<br> No data available<br> Specific target organ toxicity - single exposure<br> No data available<br> Specific target organ toxicity - repeated exposure<br> No data available<br> Aspiration hazard<br> No data available<br> Additional Information<br> RTECS: Not available<br> Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.,<br> spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary<br> edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea<br> Stomach - Irregularities - Based on Human Evidence<br> Stomach - Irregularities - Based on Human Evidence (Tetrahydrofuran)</p> <hr> <h3>SECTION 12. ECOLOGICAL INFORMATION</h3> <p>12.1 Toxicity<br> No data available<br> 12.2 Persistence and degradability<br> No data available<br> 12.3 Bioaccumulative potential<br> No data available<br> 12.4 Mobility in soil<br> No data available<br> 12.5 Results of PBT and vPvB assessment<br> PBT/vPvB assessment not available as chemical safety assessment not required/not conducted<br> 12.6 Other adverse effects<br> No data available</p> <hr> <h3>SECTION 13. DISPOSAL CONSIDERATIONS</h3> <p>13.1 Waste treatment methods<br> Product<br> Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this<br> material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a<br> licensed professional waste disposal service to dispose of this material.<br> Contaminated packaging<br> Dispose of as unused product.</p> <hr> <h3>SECTION 14. TRANSPORT INFORMATION</h3> <p>DOT (US)<br> UN number: 3399 Class: 4.3 (3) Packing group: I<br> Proper shipping name: Organometallic substance, liquid, water-reactive, flammable (Tetrahydrofuran,<br> Chlorovinylmagnesium)<br> Reportable Quantity (RQ): 1165 lbs<br> Poison Inhalation Hazard: No<br> IMDG<br> UN number: 3399 Class: 4.3 (3) Packing group: I EMS-No: F-G, S-N<br> Proper shipping name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE<br> (Chlorovinylmagnesium, Tetrahydrofuran)<br> IATA<br> UN number: 3399 Class: 4.3 (3) Packing group: I<br> Proper shipping name: Organometallic substance, liquid, water-reactive, flammable (Chlorovinylmagnesium,<br> Tetrahydrofuran)<br> IATA Passenger: Not permitted for transport</p> <hr> <h3>SECTION 15. REGULATORY INFORMATION</h3> <p>SARA 302 Components<br> No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.<br> SARA 313 Components<br> This material does not contain any chemical components with known CAS numbers that exceed the threshold (De<br> Minimis) reporting levels established by SARA Title III, Section 313.<br> SARA 311/312 Hazards<br> Fire Hazard, Reactivity Hazard, Acute Health Hazard, Chronic Health Hazard<br> Massachusetts Right To Know Components<br> Tetrahydrofuran<br> CAS-No.<br> 109-99-9<br> Revision Date<br> 1993-04-24<br> Pennsylvania Right To Know Components<br> Tetrahydrofuran<br> CAS-No.<br> 109-99-9<br> Revision Date<br> 1993-04-24<br> Chlorovinylmagnesium 3536-96-7<br> New Jersey Right To Know Components<br> Tetrahydrofuran<br> CAS-No.<br> 109-99-9<br> Revision Date<br> 1993-04-24<br> Chlorovinylmagnesium 3536-96-7<br> California Prop. 65 Components<br> This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other<br> reproductive harm.</p> <hr> <h3>SECTION 16. OTHER INFORMATION</h3> <p>Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.</p> </div> </div> </div> <div class="more-link"><a href="https://www-americanelements-com.translate.goog/vinylmagnesium-chloride-solution-3536-96-7/sds2?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en"> Print this page </a> </div> </div> </div> </div> <div class="panel-separator"></div> <div id="section-about" class="ctools-collapsible-container paneled paneled-padded"> <h2 class="pane-title ctools-collapsible-handle">About Vinylmagnesium Chloride Solution</h2> <div class="ctools-collapsible-content"> <div class="field-prod-para"><strong>Vinylmagnesium Chloride Solution</strong> is one of numerous organometallic compounds sold by American Elements under the trade name <a href="https://www-americanelements-com.translate.goog/organometallics.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en"> AE Organometallics™</a>. Organometallics are useful reagent, catalyst, and precursor materials with applications in <a href="https://www-americanelements-com.translate.goog/thin-film-evaporation-materials.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">thin film deposition</a>, <a href="https://www-americanelements-com.translate.goog/chemical-manufacturing.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">industrial chemistry</a>, <a href="https://www-americanelements-com.translate.goog/pharmaceuticals-cosmetics.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">pharmaceuticals</a>, <a href="https://www-americanelements-com.translate.goog/lighting?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">LED manufacturing</a>, and others. American Elements supplies Vinylmagnesium Chloride Solution in most volumes including bulk quantities and also can produce materials to customer specifications. Please request a quote above for more information on pricing and lead time. </div> </div> </div> <div class="panel-separator"></div> <div id="section-synonyms" class="ctools-collapsible-container paneled-padded"> <h2 class="pane-title ctools-collapsible-handle">Vinylmagnesium Chloride Solution Synonyms</h2> <div class="ctools-collapsible-content"> <div class="field-synonyms"> Chloro(ethenyl)magnesium, Vinylmagnesium chloride, 1.6M solution in Tetrahydrofuran, Magnesium, cloroethenyl- </div> </div> </div> <div class="panel-separator"></div> <div id="section-chemical-identifiers" class="ctools-collapsible-container"> <h2 class="pane-title ctools-collapsible-handle">Chemical Identifiers</h2> <div class="ctools-collapsible-content"> <div class="view view-data-tables view-id-data_tables view-display-id-block_7 product-data-table view-dom-id-ea34b6bd6e1987b1a683ae71ead7d05c"> <div class="view-content"> <table class="views-table cols-9"> <tbody> <tr class=""> <th class="">Linear Formula</th> <td class="">CH<sub>2</sub>=CHMgCl</td> </tr> <tr class=""> <th class="">MDL Number</th> <td class="">MFCD00013594</td> </tr> <tr class=""> <th class="">EC No.</th> <td class="">222-575-9</td> </tr> <tr class=""> <th class="">Beilstein/Reaxys No.</th> <td class="">3535268</td> </tr> <tr class=""> <th class="">Pubchem CID</th> <td class="">77075</td> </tr> <tr class=""> <th class="">IUPAC Name</th> <td class="">magnesium; ethene; chloride</td> </tr> <tr class=""> <th class="">SMILES</th> <td class="">InChI=1S/C2H3.ClH.Mg/c1-2;;/h1H,2H2;1H;/q-1;;+2/p-1</td> </tr> <tr class=""> <th class="">InchI Identifier</th> <td class="">InChI=1S/C2H3.ClH.Mg/c1-2;;/h1H,2H2;1H;/q-1;;+2/p-1</td> </tr> <tr class=""> <th class="">InchI Key</th> <td class="">IJMWREDHKRHWQI-UHFFFAOYSA-M</td> </tr> </tbody> </table> </div> </div> </div> </div> <div class="panel-separator"></div> <div id="section-also-viewed" class="ctools-collapsible-container paneled recommended-products"> <h2 class="pane-title 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Solution</h2> <div class="ctools-collapsible-content"> <div class="view view-taxonomy-link view-id-taxonomy_link view-display-id-panel_pane_5 view-dom-id-fd7b2d4ff7d4b8164329d84efbbe6206"> <div class="view-content"> <table class="views-view-grid cols-3"> <tbody> <tr> <td><a href="https://www-americanelements-com.translate.goog/chemical-manufacturing.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Chemical Manufacturing</a></td> <td><a href="https://www-americanelements-com.translate.goog/Chlorides.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Chlorides</a></td> <td><a href="https://www-americanelements-com.translate.goog/organometallics.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Grignard Reagents</a></td> </tr> <tr> <td><a href="https://www-americanelements-com.translate.goog/organometallics.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Organometallics</a></td> <td><a href="https://www-americanelements-com.translate.goog/research-laboratory.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Research & Laboratory</a></td> <td><a href="https://www-americanelements-com.translate.goog/solutions?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Solutions</a></td> </tr> </tbody> </table> </div> </div> </div> </div> <div class="panel-separator"></div> <div id="section-packaging-specs" class="ctools-collapsible-container ctools-collapsed paneled paneled-padded"> <h2 class="pane-title ctools-collapsible-handle">Packaging Specifications</h2> <div class="ctools-collapsible-content"> Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks. </div> </div> <div class="panel-separator"></div> <div id="section-element-content" class="ctools-collapsible-container paneled-padded boxton"> <h2 class="pane-title ctools-collapsible-handle">Related Elements</h2> <div class="ctools-collapsible-content"> <div class="field-element"> <div id="taxonomy-term-14" class="taxonomy-term vocabulary-elements"> <h2><a href="https://www-americanelements-com.translate.goog/chlorine-0?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Chlorine</a></h2> <div class="content"> <div class="taxonomy-term-description"> <div class="panel-display symbol clearfix element-symbol pink"> <a class="symbol-container panel-panel pageurl" href="https://www-americanelements-com.translate.goog/chlorine.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en"> <span class="atomicnumber"> 17 </span> <span class="elementsymbol"> Cl </span> <span class="nameweight"> 35.453000000 </span> <span class="nameweight elementname"> Chlorine </span></a> </div> <p class="field-paragraph-content"><a href="https://www-americanelements-com.translate.goog/chlorine.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en"><strong>Chlorine</strong></a> is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s<sup>2</sup>3p<sup>5</sup>. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. <img src="https://www.americanelements.com/chlorine-bohr.jpg" alt="Chlorine Model" class="image-right" height="95" width="95" sizes="100px" layout="responsive">In its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.</p> </div> </div> </div> </div> <div class="field-element"> <div id="taxonomy-term-35" class="taxonomy-term vocabulary-elements"> <h2><a href="https://www-americanelements-com.translate.goog/magnesium?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Magnesium</a></h2> <div class="content"> <div class="taxonomy-term-description"> <div class="panel-display symbol clearfix element-symbol orange"> <a class="symbol-container panel-panel pageurl" href="https://www-americanelements-com.translate.goog/mg.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en"> <span class="atomicnumber"> 12 </span> <span class="elementsymbol"> Mg </span> <span class="nameweight"> 24.305000000 </span> <span class="nameweight elementname"> Magnesium </span></a> </div> <p class="field-paragraph-content"><a href="https://www-americanelements-com.translate.goog/mg.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en"><img src="https://www.americanelements.com/magnesium-bohr.jpg" alt="Magnesium Bohr Model" class="image-right" height="88" width="83" sizes="100px" layout="responsive"><strong>See more Magnesium products.</strong></a> Magnesium (atomic symbol: Mg, atomic number: 12) is a Block S, Group 2, Period 3 element with an atomic mass of 24.3050. The number of electrons in each of Magnesium's shells is [2, 8, 2] and its electron configuration is [Ne] 3s<sup>2</sup>. The magnesium atom has a radius of 160 pm and a Van der Waals radius of 173 pm. Magnesium was discovered by Joseph Black in 1775 and first isolated by Sir Humphrey Davy in 1808. Magnesium is the eighth most abundant element in the earth's crust and the fourth most common element in the earth as a whole. <img src="https://www.americanelements.com/elemental-magnesium.png" alt="Elemental Magnesium" class="image-left" height="85" width="79" sizes="100px" layout="responsive">In its elemental form, magnesium has a shiny grey metallic appearance and is an extremely reactive. It is can be found in minerals such as brucite, carnallite, dolomite, magnesite, olivine and talc. Commercially, magnesium is primarily used in the creation of strong and lightweight <a href="https://www-americanelements-com.translate.goog/al.html?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">aluminum</a>-magnesium alloys, which have numerous advantages in industrial applications. The name "Magnesium" originates from a Greek district in Thessaly called Magnesia.</p> </div> </div> </div> </div> </div> </div> <div class="panel-separator"></div> <div id="section-research-content" class="ctools-collapsible-container paneled paneled-padded"> <h2 class="pane-title ctools-collapsible-handle">Recent Research</h2> <div class="ctools-collapsible-content"> <div class="view view-research-views-new view-id-research_views_new view-display-id-block_2 view-dom-id-802b09fff4fa3ecf66bedfc11eebd2fe"> <div class="view-header"> <div class="research-float"> <a href="https://www-americanelements-com.translate.goog/research-submission?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Publish your research on the American Elements website</a> </div> </div> <div class="view-content"> <div class="view-grouping"> <div> <p><a href="https://www-americanelements-com.translate.goog/bismuth-oxychloride-biocl-copper-phthalocyanine-cutnpc-heterostructures-immobilized-on-electrospun?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Bismuth oxychloride (BiOCl)/copper phthalocyanine (CuTNPc) heterostructures immobilized on electrospun polyacrylonitrile nanofibers with enhanced activity for floating photocatalysis.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/spray-chilling-encapsulation-of-2-acetyl-1-pyrroline-zinc-chloride-complex-using-hydrophobic?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Spray-chilling encapsulation of 2-acetyl-1-pyrroline zinc chloride complex using hydrophobic materials: Feasibility and characterization of microcapsules.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/simple-and-selective-hplc-uv-vis-bioanalytical-method-to-determine-aluminum-phthalocyanine-chloride?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Simple and Selective HPLC-UV/Vis Bioanalytical Method to Determine Aluminum Phthalocyanine Chloride in Skin Permeation Studies.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/optical-parameters-and-dispersion-behavior-of-potassium-magnesium-chloride-sulfate-single-crystals?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Optical parameters and dispersion behavior of potassium magnesium chloride sulfate single crystals doped with Co ions.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/reaction-of-tin-iv-phthalocyanine-dichloride-with-decamethylmetallocenes-m-crii-and-coii-strong?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Reaction of tin(iv) phthalocyanine dichloride with decamethylmetallocenes (M = CrII and CoII). Strong magnetic coupling of spins in (Cp*2Co+){SnIVCl2(Pc?3-)}?-·2C6H4Cl2.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/anionic-water-cluster-polymers-ho-18-oh-n2n-is-stabilized-by-bis-2-2-bipyridine-cupric-chloride-cu?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Anionic Water Cluster Polymers [(H?O)18(OH)?]n2n- Is Stabilized by Bis(2,2'-bipyridine) Cupric Chloride [Cu(bipy)?Cl].</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/uhplc-ms-and-maldi-ms-study-of-aluminum-phthalocyanine-chloride-and-development-of-a-bioanalytical?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">UHPLC-MS and MALDI-MS study of aluminum phthalocyanine chloride and development of a bioanalytical method for its quantification in nanoemulsions and biological matrices.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/a-new-study-of-iodine-complexes-of-oxidized-gum-arabic-an-interaction-between-iodine-monochloride?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">A new study of iodine complexes of oxidized gum arabic: An interaction between iodine monochloride and aldehyde groups.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/palladium-catalyzed-2-2-2-trifluoroethoxylation-of-aromatic-and-heteroaromatic-chlorides-utilizing?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">Palladium-Catalyzed 2,2,2-Trifluoroethoxylation of Aromatic and Heteroaromatic Chlorides Utilizing Borate Salt and the Synthesis of a Trifluoro Analogue of Sildenafil.</a></p> </div> <div> <p><a href="https://www-americanelements-com.translate.goog/a-comparative-study-of-magnetization-dynamics-in-dinuclear-dysprosium-complexes-featuring-bridging?_x_tr_sl=en&_x_tr_tl=nl&_x_tr_hl=en">A comparative study of magnetization dynamics in dinuclear dysprosium complexes featuring 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