Recovery of Acetonitrile from Aqueous Solutions by Extractive Distillation

<!DOCTYPE html> <html lang="en" dir="ltr"> <head>  <script async src="https://www.googletagmanager.com/gtag/js?id=G-P63WKM1TM1"></script> <script> window.dataLayer = window.dataLayer || []; function gtag(){dataLayer.push(arguments);} gtag('js', new Date()); gtag('config', 'G-P63WKM1TM1'); </script>  <script type="text/javascript" > (function(m,e,t,r,i,k,a){m[i]=m[i]||function(){(m[i].a=m[i].a||[]).push(arguments)}; m[i].l=1*new Date(); for (var j = 0; j < document.scripts.length; j++) {if (document.scripts[j].src === r) { return; }} k=e.createElement(t),a=e.getElementsByTagName(t)[0],k.async=1,k.src=r,a.parentNode.insertBefore(k,a)}) (window, document, "script", "https://mc.yandex.ru/metrika/tag.js", "ym"); ym(55165297, "init", { clickmap:false, trackLinks:true, accurateTrackBounce:true, webvisor:false }); </script> <noscript><div><img src="https://mc.yandex.ru/watch/55165297" style="position:absolute; left:-9999px;" alt="" /></div></noscript>    <title>Recovery of Acetonitrile from Aqueous Solutions by Extractive Distillation–Effect of Entrainer</title> <meta name="description" content="Recovery of Acetonitrile from Aqueous Solutions by Extractive Distillation–Effect of Entrainer"> <meta name="keywords" content="Acetonitrile, entrainer, extractive distillation, water."> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <meta name="citation_title" content="Recovery of Acetonitrile from Aqueous Solutions by Extractive Distillation–Effect of Entrainer"> <meta name="citation_author" content="Aleksandra Yu. Sazonova"> <meta name="citation_author" content="Valentina M. Raeva"> <meta name="citation_publication_date" content="2015/01/03"> <meta name="citation_journal_title" content="International Journal of Chemical and Molecular Engineering"> <meta name="citation_volume" content="9"> <meta name="citation_issue" content="2"> <meta name="citation_firstpage" content="288"> <meta name="citation_lastpage" content="291"> <meta name="citation_pdf_url" content="https://publications.waset.org/10000430/pdf"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none navbar-toggler ml-auto" type="button" data-toggle="collapse" data-target="#navbarMenu" aria-controls="navbarMenu" aria-expanded="false" aria-label="Toggle navigation"> <span class="navbar-toggler-icon"></span> </button> <div class="w-100"> <div class="d-none d-lg-flex flex-row-reverse"> <form method="get" action="https://waset.org/search" class="form-inline my-2 my-lg-0"> <input class="form-control mr-sm-2" type="search" placeholder="Search Conferences" value="" name="q" aria-label="Search"> <button class="btn btn-light my-2 my-sm-0" type="submit"><i class="fas fa-search"></i></button> </form> </div> <div class="collapse navbar-collapse mt-1" id="navbarMenu"> <ul class="navbar-nav ml-auto align-items-center" id="mainNavMenu"> <li class="nav-item"> <a class="nav-link" href="https://waset.org/conferences" title="Conferences in 2024/2025/2026">Conferences</a> </li> <li class="nav-item"> <a class="nav-link" href="https://waset.org/disciplines" title="Disciplines">Disciplines</a> </li> <li class="nav-item"> <a class="nav-link" href="https://waset.org/committees" rel="nofollow">Committees</a> </li> <li class="nav-item dropdown"> <a class="nav-link dropdown-toggle" href="#" id="navbarDropdownPublications" role="button" data-toggle="dropdown" aria-haspopup="true" aria-expanded="false"> Publications </a> <div class="dropdown-menu" aria-labelledby="navbarDropdownPublications"> <a class="dropdown-item" href="https://publications.waset.org/abstracts">Abstracts</a> <a class="dropdown-item" href="https://publications.waset.org">Periodicals</a> <a class="dropdown-item" href="https://publications.waset.org/archive">Archive</a> </div> </li> <li class="nav-item"> <a class="nav-link" href="https://waset.org/page/support" title="Support">Support</a> </li> </ul> </div> </div> </nav> </div> </header> <main> <div class="container mt-4"> <div class="row"> <div class="col-md-9 mx-auto"> <form method="get" action="https://publications.waset.org/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value=""> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 33093</div> </div> </div> </div> <div class="card publication-listing mt-3 mb-3"> <h5 class="card-header" style="font-size:.9rem">Recovery of Acetonitrile from Aqueous Solutions by Extractive Distillation–Effect of Entrainer</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/search?q=Aleksandra%20Yu.%20Sazonova">Aleksandra Yu. Sazonova</a>, <a href="https://publications.waset.org/search?q=Valentina%20M.%20Raeva"> Valentina M. Raeva</a> </p> <p class="card-text"><strong>Abstract:</strong></p> <p>The aim of this work was to apply extractive distillation for acetonitrile removal from water solutions, to validate thermodynamic criterion based on excess Gibbs energy to entrainer selection process for acetonitrile – water mixture separation and show its potential efficiency at isothermal conditions as well as at isobaric (conditions of real distillation process), to simulate and analyze an extractive distillation process with chosen entrainers: optimize amount of trays and feeds, entrainer/original mixture and reflux ratios. Equimolar composition of the feed stream was chosen for the process, comparison of the energy consumptions was carried out. Glycerol was suggested as the most energetically and ecologically suitable entrainer.</p> <iframe src="https://publications.waset.org/10000430.pdf" style="width:100%; height:400px;" frameborder="0"></iframe> <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/search?q=Acetonitrile" title="Acetonitrile">Acetonitrile</a>, <a href="https://publications.waset.org/search?q=entrainer" title=" entrainer"> entrainer</a>, <a href="https://publications.waset.org/search?q=extractive%20distillation" title=" extractive distillation"> extractive distillation</a>, <a href="https://publications.waset.org/search?q=water." title=" water."> water.</a> </p> <p class="card-text"><strong>Digital Object Identifier (DOI):</strong> <a href="https://doi.org/10.5281/zenodo.1099084" target="_blank">doi.org/10.5281/zenodo.1099084</a> </p> <a href="https://publications.waset.org/10000430/recovery-of-acetonitrile-from-aqueous-solutions-by-extractive-distillation-effect-of-entrainer" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/10000430/apa" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">APA</a> <a href="https://publications.waset.org/10000430/bibtex" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">BibTeX</a> <a href="https://publications.waset.org/10000430/chicago" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">Chicago</a> <a href="https://publications.waset.org/10000430/endnote" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">EndNote</a> <a href="https://publications.waset.org/10000430/harvard" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">Harvard</a> <a href="https://publications.waset.org/10000430/json" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">JSON</a> <a href="https://publications.waset.org/10000430/mla" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">MLA</a> <a href="https://publications.waset.org/10000430/ris" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">RIS</a> <a href="https://publications.waset.org/10000430/xml" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">XML</a> <a href="https://publications.waset.org/10000430/iso690" target="_blank" rel="nofollow" class="btn btn-primary btn-sm">ISO 690</a> <a href="https://publications.waset.org/10000430.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">7194</span> </span> <p class="card-text"><strong>References:</strong></p> <br>[1] K.X. Xu, Handbook of fine organic chemical raw materials and intermediates, 2nd ed.; Chemical Industry Press: Beijing, 2002. <br>[2] Tingyue Gu, Yesong Gu, and Yizhou Zheng, Paul E. Wiehl and John J. Kopchick, “Phase separation of acetonitrile-water mixture in protein purification,” Sep. Technol., vol. 4, pp. 258-260, 1994. <br>[3] J. Rosen, K.-E. Hellenas, “Analysis of acrylamide in cooked foods by liquid chromatography tandem mass spectrometry”, Analyst, vol. 127, pp. 880−882, 2002. <br>[4] M.K. Srinivasu, A.N. Raju, G.O. Reddy, “Determination of lovastatin and simvastatin in pharmaceutical dosage forms by MEKC”, J. Pharm. Biomed. Anal., vol. 29, pp. 715-721, 2002. <br>[5] J. Gmehling, J. Menke, J. Krafczyk, K. Fischer, Azeotropic Data, VCH Editor, Weinheim, 1994. <br>[6] J. Acosta-Esquijarosa, I. Rodrıguez-Donis, U. J´auregui-Haza, L. Nuevas-Paz, E. Pardillo-Fontdevila, “Recovery of acetonitrile from aqueous waste by a combined process: Solvent extraction and batch distillation”, Separation and Purification Technology, vol. 52, pp. 95- 101, 2006. <br>[7] J.-U. Repke, A. Klein, D. Bogle and G. Wozny, “Pressure swing batch distillation for homogeneous azeotropic separation”, Trans IChemE, Part A, vol. 85, pp. 492–501. <br>[8] Zhigang Zhang, Ming Lv, Donghao Huang, Peng Jia, Dezhang Sun, and Wenxiu Li, “Isobaric Vapor−Liquid Equilibrium for the Extractive Distillation of Acetonitrile + Water Mixtures Using Dimethyl Sulfoxide at 101.3 kPa”, J. Chem. Eng. Data, vol. 58, pp. 3364−3369, 2013. <br>[9] J.B. Zhou, X. B. Cui, B.L. Dong, Y.F. Wang, Z.K. Chen, “Separation of acetonitrile and water mixture by batch extractive distillation”, Chem. Ind. Eng., vol. 26, pp. 482−486, 2009. <br>[10] M. Khayet , C. Cojocaru, G. Zakrzewska-Trznadel, “Studies on pervaporation separation of acetone, acetonitrile and ethanol from aqueous solutions,” Separation and Purification Technology, vol. 63, pp. 303–310, 2008. <br>[11] J. Rarey, J. Gmehling, “Factual data banks and their application to the synthesis and design of chemical processes and the development and testing of thermophysical property estimation methods,” Pure Appl. Chem., vol. 81, p. 1745, 2009. <br>[12] A.Yu. Sazonova,V.M. Raeva, A.K. Frolkova, “Comparison of extractive agents efficiency at mixture separation of acrylonitrile and water,” Izvestia Vish. Uch. Zaved.: Khimia I Khim. Tekhnologia, vol. 56, pp. 50-57, 2013. <br>[13] V.M. Raeva, A. Yu. Sebyakin, A.Yu. Sazonova, and A.K. Frolkova, “Selecting potential separating agents for extractive distillation of the cyclohexane–benzol mixture”, Vestn. Mosk. Inst. Tonkoi Khim. Tekhnol., vol. 6, no. 1, p. 43, 2011. <br>[14] A. Yu. Sazonova, V. M. Raeva, T. V. Chelyuskina, and A. K. Frolkova, “Choice of Extractive Agents for Separating Benzene–Perfluorobenzene Biazeotropic Mixture Based on Thermodynamic Criterion,” Theoretical Foundations of Chemical Engineering, vol. 48, no. 2, pp. 148–157, 2014. <br>[15] I. Rodriguez-Donis, V. Gerbaud, X. Joulia, “Entrainer selection rules for the separation of azeotropic and close-boiling-temperature mixtures by homogeneous batch distillation process”, Ind. Eng. Chem. Res., vol. 40, no. 12, pp. 2729–2741, 2001. <br>[16] I. Rodriguez-Donis, J. Acosta-Esquijarosa, V. Gerbaud, X. Joulia, “Heterogeneous Batch Extractive Distillation of Minimum Boiling Azeotropic Mixtures,” AIChE Journal, vol. 49, no. 12, pp. 3074-3083, 2003. </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/WASET-16th-foundational-anniversary.pdf">WASET celebrates its 16th foundational anniversary</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Account <li><a href="https://waset.org/profile">My Account</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Explore <li><a href="https://waset.org/disciplines">Disciplines</a></li> <li><a href="https://waset.org/conferences">Conferences</a></li> <li><a href="https://waset.org/conference-programs">Conference Program</a></li> <li><a href="https://waset.org/committees">Committees</a></li> <li><a href="https://publications.waset.org">Publications</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Research <li><a href="https://publications.waset.org/abstracts">Abstracts</a></li> <li><a href="https://publications.waset.org">Periodicals</a></li> <li><a href="https://publications.waset.org/archive">Archive</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Open Science <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Open-Science-Philosophy.pdf">Open Science Philosophy</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Open-Science-Award.pdf">Open Science Award</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Open-Society-Open-Science-and-Open-Innovation.pdf">Open Innovation</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Postdoctoral-Fellowship-Award.pdf">Postdoctoral Fellowship Award</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/Scholarly-Research-Review.pdf">Scholarly Research Review</a></li> </ul> </div> <div class="col-md-2"> <ul class="list-unstyled"> Support <li><a href="https://waset.org/page/support">Support</a></li> <li><a href="https://waset.org/profile/messages/create">Contact Us</a></li> <li><a href="https://waset.org/profile/messages/create">Report Abuse</a></li> </ul> </div> </div> </div> </div> </div> <div class="container text-center"> <hr style="margin-top:0;margin-bottom:.3rem;"> <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank" class="text-muted small">Creative Commons Attribution 4.0 International License</a> <div id="copy" class="mt-2">© 2024 World Academy of Science, Engineering and Technology</div> </div> </footer> <a href="javascript:" id="return-to-top"><i class="fas fa-arrow-up"></i></a> <div class="modal" id="modal-template"> <div class="modal-dialog"> <div class="modal-content"> <div class="row m-0 mt-1"> <div class="col-md-12"> <button type="button" class="close" data-dismiss="modal" aria-label="Close"><span aria-hidden="true">×</span></button> </div> </div> <div class="modal-body"></div> </div> </div> </div> <script src="https://cdn.waset.org/static/plugins/jquery-3.3.1.min.js"></script> <script src="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/js/bootstrap.bundle.min.js"></script> <script src="https://cdn.waset.org/static/js/site.js?v=150220211556"></script> <script> jQuery(document).ready(function() { /*jQuery.get("https://publications.waset.org/xhr/user-menu", function (response) { jQuery('#mainNavMenu').append(response); });*/ jQuery.get({ url: "https://publications.waset.org/xhr/user-menu", cache: false }).then(function(response){ jQuery('#mainNavMenu').append(response); }); }); </script> </body> </html>

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Recovery of Acetonitrile from Aqueous Solutions by Extractive Distillation–Effect of Entrainer