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href="/wiki/Special:%E6%88%91%E7%9A%84%E8%B4%A1%E7%8C%AE" title="来自此IP地址的编辑列表[y]" accesskey="y"><span>贡献</span></a></li><li id="pt-anontalk" class="mw-list-item"><a href="/wiki/Special:%E6%88%91%E7%9A%84%E8%AE%A8%E8%AE%BA%E9%A1%B5" title="对于来自此IP地址编辑的讨论[n]" accesskey="n"><span>讨论</span></a></li> </ul> </div> </div> </div> </div> </nav> </div> </header> </div> <div class="mw-page-container"> <div class="mw-page-container-inner"> <div class="vector-sitenotice-container"> <div id="siteNotice"></div> </div> <div class="vector-column-start"> <div class="vector-main-menu-container"> <div id="mw-navigation"> <nav id="mw-panel" class="vector-main-menu-landmark" aria-label="站点"> <div id="vector-main-menu-pinned-container" class="vector-pinned-container"> </div> </nav> </div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="目录" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">目录</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">隐藏</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">序言</div> </a> </li> <li id="toc-分类" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#分类"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>分类</span> </div> </a> <button aria-controls="toc-分类-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>开关分类子章节</span> </button> <ul id="toc-分类-sublist" class="vector-toc-list"> <li id="toc-1.按照单体-聚合物变化" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#1.按照单体-聚合物变化"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.1</span> <span>1.按照单体-聚合物变化</span> </div> </a> <ul id="toc-1.按照单体-聚合物变化-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-2.按照聚合机理" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#2.按照聚合机理"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.2</span> <span>2.按照聚合机理</span> </div> </a> <ul id="toc-2.按照聚合机理-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-3.按照聚合单体" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#3.按照聚合单体"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.3</span> <span>3.按照聚合单体</span> </div> </a> <ul id="toc-3.按照聚合单体-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-4.按照聚合方式" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#4.按照聚合方式"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.4</span> <span>4.按照聚合方式</span> </div> </a> <ul id="toc-4.按照聚合方式-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-参见" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参见"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>参见</span> </div> </a> <ul id="toc-参见-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-参考文献" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考文献"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>参考文献</span> </div> </a> <ul id="toc-参考文献-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" title="目录" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">聚合</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。53种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-53" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">53种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%A8%D9%84%D9%85%D8%B1%D8%A9" title="بلمرة – 阿拉伯语" lang="ar" hreflang="ar" data-title="بلمرة" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-ast mw-list-item"><a href="https://ast.wikipedia.org/wiki/Polimerizaci%C3%B3n" title="Polimerización – 阿斯图里亚斯语" lang="ast" hreflang="ast" data-title="Polimerización" data-language-autonym="Asturianu" data-language-local-name="阿斯图里亚斯语" class="interlanguage-link-target"><span>Asturianu</span></a></li><li class="interlanguage-link interwiki-be mw-list-item"><a href="https://be.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D1%96%D0%BC%D0%B5%D1%80%D1%8B%D0%B7%D0%B0%D1%86%D1%8B%D1%8F" title="Полімерызацыя – 白俄罗斯语" lang="be" hreflang="be" data-title="Полімерызацыя" data-language-autonym="Беларуская" data-language-local-name="白俄罗斯语" class="interlanguage-link-target"><span>Беларуская</span></a></li><li class="interlanguage-link interwiki-bg mw-list-item"><a href="https://bg.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D0%B8%D0%BC%D0%B5%D1%80%D0%B8%D0%B7%D0%B0%D1%86%D0%B8%D1%8F" title="Полимеризация – 保加利亚语" lang="bg" hreflang="bg" data-title="Полимеризация" data-language-autonym="Български" data-language-local-name="保加利亚语" class="interlanguage-link-target"><span>Български</span></a></li><li class="interlanguage-link interwiki-bn mw-list-item"><a href="https://bn.wikipedia.org/wiki/%E0%A6%AA%E0%A6%B2%E0%A6%BF%E0%A6%AE%E0%A6%BE%E0%A6%B0%E0%A6%95%E0%A6%B0%E0%A6%A3_%E0%A6%AC%E0%A6%BF%E0%A6%95%E0%A7%8D%E0%A6%B0%E0%A6%BF%E0%A6%AF%E0%A6%BC%E0%A6%BE" title="পলিমারকরণ বিক্রিয়া – 孟加拉语" lang="bn" hreflang="bn" data-title="পলিমারকরণ বিক্রিয়া" data-language-autonym="বাংলা" data-language-local-name="孟加拉语" class="interlanguage-link-target"><span>বাংলা</span></a></li><li class="interlanguage-link interwiki-bs mw-list-item"><a href="https://bs.wikipedia.org/wiki/Polimerizacija" title="Polimerizacija – 波斯尼亚语" lang="bs" hreflang="bs" data-title="Polimerizacija" data-language-autonym="Bosanski" data-language-local-name="波斯尼亚语" class="interlanguage-link-target"><span>Bosanski</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Polimeritzaci%C3%B3" title="Polimerització – 加泰罗尼亚语" lang="ca" hreflang="ca" data-title="Polimerització" data-language-autonym="Català" data-language-local-name="加泰罗尼亚语" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Polymerizace" title="Polymerizace – 捷克语" lang="cs" hreflang="cs" data-title="Polymerizace" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Polymerisation" title="Polymerisation – 德语" lang="de" hreflang="de" data-title="Polymerisation" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%A0%CE%BF%CE%BB%CF%85%CE%BC%CE%B5%CF%81%CE%B9%CF%83%CE%BC%CF%8C%CF%82" title="Πολυμερισμός – 希腊语" lang="el" hreflang="el" data-title="Πολυμερισμός" data-language-autonym="Ελληνικά" data-language-local-name="希腊语" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Polymerization" title="Polymerization – 英语" lang="en" hreflang="en" data-title="Polymerization" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Polimerizaci%C3%B3n" title="Polimerización – 西班牙语" lang="es" hreflang="es" data-title="Polimerización" data-language-autonym="Español" data-language-local-name="西班牙语" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-et mw-list-item"><a href="https://et.wikipedia.org/wiki/Pol%C3%BCmerisatsioon" title="Polümerisatsioon – 爱沙尼亚语" lang="et" hreflang="et" data-title="Polümerisatsioon" data-language-autonym="Eesti" data-language-local-name="爱沙尼亚语" class="interlanguage-link-target"><span>Eesti</span></a></li><li class="interlanguage-link interwiki-eu mw-list-item"><a href="https://eu.wikipedia.org/wiki/Polimerizazio" title="Polimerizazio – 巴斯克语" lang="eu" hreflang="eu" data-title="Polimerizazio" data-language-autonym="Euskara" data-language-local-name="巴斯克语" class="interlanguage-link-target"><span>Euskara</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D9%BE%D9%84%DB%8C%D9%85%D8%B1%DB%8C%D8%B2%D8%A7%D8%B3%DB%8C%D9%88%D9%86" title="پلیمریزاسیون – 波斯语" lang="fa" hreflang="fa" data-title="پلیمریزاسیون" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Polymerointi" title="Polymerointi – 芬兰语" lang="fi" hreflang="fi" data-title="Polymerointi" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Polym%C3%A9risation" title="Polymérisation – 法语" lang="fr" hreflang="fr" data-title="Polymérisation" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-ga mw-list-item"><a href="https://ga.wikipedia.org/wiki/Polaim%C3%A9iri%C3%BAch%C3%A1n" title="Polaiméiriúchán – 爱尔兰语" lang="ga" hreflang="ga" data-title="Polaiméiriúchán" data-language-autonym="Gaeilge" data-language-local-name="爱尔兰语" class="interlanguage-link-target"><span>Gaeilge</span></a></li><li class="interlanguage-link interwiki-gl mw-list-item"><a href="https://gl.wikipedia.org/wiki/Polimerizaci%C3%B3n" title="Polimerización – 加利西亚语" lang="gl" hreflang="gl" data-title="Polimerización" data-language-autonym="Galego" data-language-local-name="加利西亚语" class="interlanguage-link-target"><span>Galego</span></a></li><li class="interlanguage-link interwiki-he mw-list-item"><a href="https://he.wikipedia.org/wiki/%D7%A4%D7%99%D7%9C%D7%9E%D7%95%D7%A8" title="פילמור – 希伯来语" lang="he" hreflang="he" data-title="פילמור" data-language-autonym="עברית" data-language-local-name="希伯来语" class="interlanguage-link-target"><span>עברית</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%AC%E0%A4%B9%E0%A5%81%E0%A4%B2%E0%A4%95%E0%A5%80%E0%A4%95%E0%A4%B0%E0%A4%A3" title="बहुलकीकरण – 印地语" lang="hi" hreflang="hi" data-title="बहुलकीकरण" data-language-autonym="हिन्दी" data-language-local-name="印地语" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-hr mw-list-item"><a href="https://hr.wikipedia.org/wiki/Polimerizacija" title="Polimerizacija – 克罗地亚语" lang="hr" hreflang="hr" data-title="Polimerizacija" data-language-autonym="Hrvatski" data-language-local-name="克罗地亚语" class="interlanguage-link-target"><span>Hrvatski</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Polimeriz%C3%A1ci%C3%B3" title="Polimerizáció – 匈牙利语" lang="hu" hreflang="hu" data-title="Polimerizáció" data-language-autonym="Magyar" data-language-local-name="匈牙利语" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Polimerisasi" title="Polimerisasi – 印度尼西亚语" lang="id" hreflang="id" data-title="Polimerisasi" data-language-autonym="Bahasa Indonesia" data-language-local-name="印度尼西亚语" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Polimerizzazione" title="Polimerizzazione – 意大利语" lang="it" hreflang="it" data-title="Polimerizzazione" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E9%87%8D%E5%90%88%E5%8F%8D%E5%BF%9C" title="重合反応 – 日语" lang="ja" hreflang="ja" data-title="重合反応" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-kk mw-list-item"><a href="https://kk.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D0%B8%D0%BC%D0%B5%D1%80%D0%BB%D0%B5%D1%83" title="Полимерлеу – 哈萨克语" lang="kk" hreflang="kk" data-title="Полимерлеу" data-language-autonym="Қазақша" data-language-local-name="哈萨克语" class="interlanguage-link-target"><span>Қазақша</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%EC%A4%91%ED%95%A9" title="중합 – 韩语" lang="ko" hreflang="ko" data-title="중합" data-language-autonym="한국어" data-language-local-name="韩语" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-ky mw-list-item"><a href="https://ky.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D0%B8%D0%BC%D0%B5%D1%80%D0%BB%D3%A9%D3%A9" title="Полимерлөө – 柯尔克孜语" lang="ky" hreflang="ky" data-title="Полимерлөө" data-language-autonym="Кыргызча" data-language-local-name="柯尔克孜语" class="interlanguage-link-target"><span>Кыргызча</span></a></li><li class="interlanguage-link interwiki-lt mw-list-item"><a href="https://lt.wikipedia.org/wiki/Polimerizacija" title="Polimerizacija – 立陶宛语" lang="lt" hreflang="lt" data-title="Polimerizacija" data-language-autonym="Lietuvių" data-language-local-name="立陶宛语" class="interlanguage-link-target"><span>Lietuvių</span></a></li><li class="interlanguage-link interwiki-mk mw-list-item"><a href="https://mk.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D0%B8%D0%BC%D0%B5%D1%80%D0%B8%D0%B7%D0%B0%D1%86%D0%B8%D1%98%D0%B0" title="Полимеризација – 马其顿语" lang="mk" hreflang="mk" data-title="Полимеризација" data-language-autonym="Македонски" data-language-local-name="马其顿语" class="interlanguage-link-target"><span>Македонски</span></a></li><li class="interlanguage-link interwiki-ms mw-list-item"><a href="https://ms.wikipedia.org/wiki/Pempolimeran" title="Pempolimeran – 马来语" lang="ms" hreflang="ms" data-title="Pempolimeran" data-language-autonym="Bahasa Melayu" data-language-local-name="马来语" class="interlanguage-link-target"><span>Bahasa Melayu</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Polymerisatie" title="Polymerisatie – 荷兰语" lang="nl" hreflang="nl" data-title="Polymerisatie" data-language-autonym="Nederlands" data-language-local-name="荷兰语" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-nn mw-list-item"><a href="https://nn.wikipedia.org/wiki/Polymerisasjon" title="Polymerisasjon – 挪威尼诺斯克语" lang="nn" hreflang="nn" data-title="Polymerisasjon" data-language-autonym="Norsk nynorsk" data-language-local-name="挪威尼诺斯克语" class="interlanguage-link-target"><span>Norsk nynorsk</span></a></li><li class="interlanguage-link interwiki-no mw-list-item"><a href="https://no.wikipedia.org/wiki/Polymerisering" title="Polymerisering – 书面挪威语" lang="nb" hreflang="nb" data-title="Polymerisering" data-language-autonym="Norsk bokmål" data-language-local-name="书面挪威语" class="interlanguage-link-target"><span>Norsk bokmål</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Polimeryzacja" title="Polimeryzacja – 波兰语" lang="pl" hreflang="pl" data-title="Polimeryzacja" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Polimeriza%C3%A7%C3%A3o" title="Polimerização – 葡萄牙语" lang="pt" hreflang="pt" data-title="Polimerização" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Polimerizare" title="Polimerizare – 罗马尼亚语" lang="ro" hreflang="ro" data-title="Polimerizare" data-language-autonym="Română" data-language-local-name="罗马尼亚语" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D0%B8%D0%BC%D0%B5%D1%80%D0%B8%D0%B7%D0%B0%D1%86%D0%B8%D1%8F" title="Полимеризация – 俄语" lang="ru" hreflang="ru" data-title="Полимеризация" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Polimerizacija" title="Polimerizacija – 塞尔维亚-克罗地亚语" lang="sh" hreflang="sh" data-title="Polimerizacija" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="塞尔维亚-克罗地亚语" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-simple mw-list-item"><a href="https://simple.wikipedia.org/wiki/Polymerization" title="Polymerization – Simple English" lang="en-simple" hreflang="en-simple" data-title="Polymerization" data-language-autonym="Simple English" data-language-local-name="Simple English" class="interlanguage-link-target"><span>Simple English</span></a></li><li class="interlanguage-link interwiki-sk mw-list-item"><a href="https://sk.wikipedia.org/wiki/Polymeriz%C3%A1cia" title="Polymerizácia – 斯洛伐克语" lang="sk" hreflang="sk" data-title="Polymerizácia" data-language-autonym="Slovenčina" data-language-local-name="斯洛伐克语" class="interlanguage-link-target"><span>Slovenčina</span></a></li><li class="interlanguage-link interwiki-sl mw-list-item"><a href="https://sl.wikipedia.org/wiki/Polimerizacija" title="Polimerizacija – 斯洛文尼亚语" lang="sl" hreflang="sl" data-title="Polimerizacija" data-language-autonym="Slovenščina" data-language-local-name="斯洛文尼亚语" class="interlanguage-link-target"><span>Slovenščina</span></a></li><li class="interlanguage-link interwiki-sq mw-list-item"><a href="https://sq.wikipedia.org/wiki/Polimerizimi" title="Polimerizimi – 阿尔巴尼亚语" lang="sq" hreflang="sq" data-title="Polimerizimi" data-language-autonym="Shqip" data-language-local-name="阿尔巴尼亚语" class="interlanguage-link-target"><span>Shqip</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D0%B8%D0%BC%D0%B5%D1%80%D0%B8%D0%B7%D0%B0%D1%86%D0%B8%D1%98%D0%B0" title="Полимеризација – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Полимеризација" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-su mw-list-item"><a href="https://su.wikipedia.org/wiki/Polim%C3%A9risasi" title="Polimérisasi – 巽他语" lang="su" hreflang="su" data-title="Polimérisasi" data-language-autonym="Sunda" data-language-local-name="巽他语" class="interlanguage-link-target"><span>Sunda</span></a></li><li class="interlanguage-link interwiki-sv mw-list-item"><a href="https://sv.wikipedia.org/wiki/Polymerisation" title="Polymerisation – 瑞典语" lang="sv" hreflang="sv" data-title="Polymerisation" data-language-autonym="Svenska" data-language-local-name="瑞典语" class="interlanguage-link-target"><span>Svenska</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%AA%E0%AE%B2%E0%AF%8D%E0%AE%B2%E0%AF%81%E0%AE%B1%E0%AF%81%E0%AE%AA%E0%AF%8D%E0%AE%AA%E0%AE%BE%E0%AE%95%E0%AF%8D%E0%AE%95%E0%AE%B2%E0%AF%8D" title="பல்லுறுப்பாக்கல் – 泰米尔语" lang="ta" hreflang="ta" data-title="பல்லுறுப்பாக்கல்" data-language-autonym="தமிழ்" data-language-local-name="泰米尔语" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-th mw-list-item"><a href="https://th.wikipedia.org/wiki/%E0%B8%9E%E0%B8%AD%E0%B8%A5%E0%B8%B4%E0%B9%80%E0%B8%A1%E0%B8%AD%E0%B9%84%E0%B8%A3%E0%B9%80%E0%B8%8B%E0%B8%8A%E0%B8%B1%E0%B8%99" title="พอลิเมอไรเซชัน – 泰语" lang="th" hreflang="th" data-title="พอลิเมอไรเซชัน" data-language-autonym="ไทย" data-language-local-name="泰语" class="interlanguage-link-target"><span>ไทย</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Polimerizasyon" title="Polimerizasyon – 土耳其语" lang="tr" hreflang="tr" data-title="Polimerizasyon" data-language-autonym="Türkçe" data-language-local-name="土耳其语" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%9F%D0%BE%D0%BB%D1%96%D0%BC%D0%B5%D1%80%D0%B8%D0%B7%D0%B0%D1%86%D1%96%D1%8F" title="Полімеризація – 乌克兰语" lang="uk" hreflang="uk" data-title="Полімеризація" data-language-autonym="Українська" 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.ambox+link+link+.ambox,.mw-parser-output .ambox+.mw-empty-elt+link+.ambox,.mw-parser-output .ambox+.mw-empty-elt+link+style+.ambox,.mw-parser-output .ambox+.mw-empty-elt+link+link+.ambox{margin-top:-1px}html body.mediawiki .mw-parser-output .ambox.mbox-small-left{margin:4px 1em 4px 0;overflow:hidden;width:238px;border-collapse:collapse;font-size:88%;line-height:1.25em}.mw-parser-output .ambox-speedy{border-left:10px solid #b32424;background-color:#fee7e6}.mw-parser-output .ambox-delete{border-left:10px solid #b32424}.mw-parser-output .ambox-content{border-left:10px solid #f28500}.mw-parser-output .ambox-style{border-left:10px solid #fc3}.mw-parser-output .ambox-move{border-left:10px solid #9932cc}.mw-parser-output .ambox-protection{border-left:10px solid #a2a9b1}.mw-parser-output .ambox .mbox-text{border:none;padding:0.25em 0.5em;width:100%}.mw-parser-output .ambox .mbox-image{border:none;padding:2px 0 2px 0.5em;text-align:center}.mw-parser-output .ambox 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.ambox-move{border-left-color:#9932cc!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-protection{border-left-color:#a2a9b1!important}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ambox{border-left-color:#36c!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-speedy,html.skin-theme-clientpref-os .mw-parser-output .ambox-delete{border-left-color:#b32424!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-speedy{background-color:#300!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-content{border-left-color:#f28500!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-style{border-left-color:#fc3!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-move{border-left-color:#9932cc!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-protection{border-left-color:#a2a9b1!important}}</style><table class="box-Unreferenced plainlinks metadata ambox ambox-content" role="presentation"><tbody><tr><td class="mbox-image"><div style="width:52px"><span typeof="mw:File"><a href="/wiki/File:Tango-nosources.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/4/4e/Tango-nosources.svg/45px-Tango-nosources.svg.png" decoding="async" width="45" height="45" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/4e/Tango-nosources.svg/68px-Tango-nosources.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/4e/Tango-nosources.svg/90px-Tango-nosources.svg.png 2x" data-file-width="48" data-file-height="48" /></a></span></div></td><td class="mbox-text"><div class="mbox-text-span">此條目<b>没有列出任何<a href="/wiki/Wikipedia:%E5%88%97%E6%98%8E%E6%9D%A5%E6%BA%90" title="Wikipedia:列明来源">参考或来源</a></b>。<span class="hide-when-compact"></span> <small class="date-container"><i>(<span class="date">2022年12月8日</span>)</i></small><span class="hide-when-compact"><br /><small>維基百科所有的內容都應該<a href="/wiki/Wikipedia:%E5%8F%AF%E4%BE%9B%E6%9F%A5%E8%AD%89" title="Wikipedia:可供查證">可供查證</a>。请协助補充<a href="/wiki/Wikipedia:%E5%8F%AF%E9%9D%A0%E6%9D%A5%E6%BA%90" title="Wikipedia:可靠来源">可靠来源</a>以<a class="external text" href="https://zh.wikipedia.org/w/index.php?title=%E8%81%9A%E5%90%88&action=edit">改善这篇条目</a>。无法查证的內容可能會因為異議提出而被移除。</small></span><span class="hide-when-compact"></span></div></td></tr></tbody></table> <p><b>聚合</b>(<b>Polymerization</b>)，或者<b>聚合反应</b>是指由低分子单机合成<a href="/wiki/%E8%81%9A%E5%90%88%E7%89%A9" title="聚合物">聚合物</a>的反应。 </p><p>大分子量的物质一般叫作<a href="/wiki/%E8%81%9A%E5%90%88%E7%89%A9" title="聚合物">聚合物</a>或<a href="/wiki/%E9%AB%98%E5%88%86%E5%AD%90" title="高分子">高分子化合物</a>，<a href="/wiki/%E5%88%86%E5%AD%90%E9%87%8F" title="分子量">分子量</a>都高达几千甚至几百万。<a href="/wiki/%E6%B7%80%E7%B2%89" title="淀粉">淀粉</a>、<a href="/wiki/%E7%BA%A4%E7%BB%B4%E7%B4%A0" title="纤维素">纤维素</a>都是天然的高聚物，是由<a href="/wiki/%E5%8D%95%E7%B3%96" class="mw-redirect" title="单糖">单糖</a>聚合而成的。<a href="/wiki/%E5%A1%91%E6%96%99" title="塑料">塑料</a>是人工合成的高聚物。能够聚合成高聚物的小分子物质叫做<a href="/wiki/%E5%8D%95%E4%BD%93" title="单体">单体</a>，单体一般有三类：一种是含有不饱和键，大部分是碳碳双键，也可能是碳碳三键或者是碳氮三键；另一种单体是含有两个或多个有特殊功能的原子团；第三种单体是不同原子组成的环状分子，比如碳氧环、氧硫环、碳氮环等。这些单体可以互相连接形成高聚物。 </p><p>任何小分子合并的过程都可以叫做聚合，不仅仅是必须形成高聚物。例如三个<a href="/wiki/%E7%94%B2%E9%86%9B" title="甲醛">甲醛</a>分子合成一个三聚甲醛分子的过程也叫做聚合过程，此时叫寡聚反应（Oligomerization）。 </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="分类"><span id=".E5.88.86.E7.B1.BB"></span>分类</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%81%9A%E5%90%88&action=edit&section=1" title="编辑章节：分类"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>20世纪30年代，<a href="/wiki/%E5%8D%8E%E8%8E%B1%E5%A3%AB%C2%B7%E5%8D%A1%E7%BD%97%E7%91%9F%E6%96%AF" title="华莱士·卡罗瑟斯">华莱士·卡罗瑟斯</a>曾将聚合反应分成两类：缩聚反应和加聚反应。50年代，<a href="/wiki/%E4%BF%9D%E7%BD%97%C2%B7%E5%BC%97%E6%B4%9B%E9%87%8C" title="保罗·弗洛里">保罗·弗洛里</a>根据反应机理和动力学分成逐步聚合和连锁聚合两类。随着高分子化学发展，又引入了开环聚合，与缩聚和加聚反应并列。<sup id="cite_ref-教材_1-0" class="reference"><a href="#cite_note-教材-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="1.按照单体-聚合物变化"><span id="1..E6.8C.89.E7.85.A7.E5.8D.95.E4.BD.93-.E8.81.9A.E5.90.88.E7.89.A9.E5.8F.98.E5.8C.96"></span>1.按照单体-聚合物变化</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%81%9A%E5%90%88&action=edit&section=2" title="编辑章节：1.按照单体-聚合物变化"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>按聚合过程中单体与聚合物的变化，可划分为缩聚反应、加聚反应、开环聚合三类。 </p> <ul><li><b>缩合聚合</b></li></ul> <style data-mw-deduplicate="TemplateStyles:r85100532">.mw-parser-output .hatnote{font-size:small}.mw-parser-output div.hatnote{padding-left:2em;margin-bottom:0.8em;margin-top:0.8em}.mw-parser-output .hatnote-notice-img::after{content:"\202f \202f \202f \202f "}.mw-parser-output .hatnote-notice-img-small::after{content:"\202f \202f "}.mw-parser-output .hatnote+link+.hatnote{margin-top:-0.5em}body.skin-minerva .mw-parser-output .hatnote-notice-img,body.skin-minerva .mw-parser-output .hatnote-notice-img-small{display:none}@media print{body.ns-0 .mw-parser-output .hatnote{display:none!important}}</style><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/wiki/%E7%BC%A9%E8%81%9A" class="mw-redirect" title="缩聚">缩聚</a></div> <p>缩合聚合(condensation polymerization)，简称<b>缩聚</b>,是指官能团单体多次缩合成聚合物的反应，除了产生缩聚物，同时还有小分子副产物产生。缩聚物的结构单元比单体少若干原子。 </p><p>常见的缩聚产物有<a href="/wiki/%E8%81%9A%E9%85%AF" title="聚酯">聚酯</a>、<a href="/wiki/%E9%85%9A%E9%86%9B%E6%A0%91%E8%84%82" title="酚醛树脂">酚醛树脂</a>、<a href="/wiki/%E5%B0%BC%E9%BE%99" title="尼龙">尼龙</a>等。 </p> <ul><li><b>加成聚合</b></li></ul> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r85100532" /><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/w/index.php?title=%E5%8A%A0%E8%81%9A&action=edit&redlink=1" class="new" title="加聚（页面不存在）">加聚</a></div> <p>加成聚合(Addition Polymerization)，简称<b>加聚</b>,是指含有不饱和键单体π键断裂后加成聚合起来的反应。产物为加聚物。加聚物结构单元与单子原子组成相同，仅仅电子结构产生变化。 </p><p>常见的缩聚产物有<a href="/wiki/%E8%81%9A%E4%B9%99%E7%83%AF" title="聚乙烯">聚乙烯</a>、<a href="/wiki/%E8%81%9A%E8%8B%AF%E4%B9%99%E7%83%AF" title="聚苯乙烯">聚苯乙烯</a>、<a href="/wiki/%E8%81%9A%E4%B8%99%E7%83%AF" title="聚丙烯">聚丙烯</a>等。 </p> <ul><li><b>开环聚合</b></li></ul> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r85100532" /><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/w/index.php?title=%E5%BC%80%E7%8E%AF%E8%81%9A%E5%90%88&action=edit&redlink=1" class="new" title="开环聚合（页面不存在）">开环聚合</a></div> <p>开环聚合(Ring opening polymerization)是指环状单体σ键断裂而后聚合形成的聚合物的反应。 </p><p>常见的开环产物有<a href="/wiki/%E8%81%9A%E7%8E%AF%E6%B0%A7%E4%B9%99%E7%83%B7" class="mw-redirect" title="聚环氧乙烷">聚环氧乙烷</a>、<a href="/wiki/%E8%81%9A%E5%B7%B1%E5%86%85%E9%85%B0%E8%83%BA" class="mw-redirect" title="聚己内酰胺">聚己内酰胺</a>等。 </p> <ul><li><b>其他聚合：</b></li></ul> <p>除了上述三种聚合反应外，还有新发现的聚合反应难以划分到上述类型中。 <b>消去聚合</b>(Elimination polymerization)：指聚合过程发生<a href="/wiki/%E6%B6%88%E9%99%A4%E5%8F%8D%E5%BA%94" title="消除反应">消去反应</a>，是一种不典型的缩合聚合。如<a href="/wiki/%E6%B0%A8%E5%9F%BA%E6%B0%B0" title="氨基氰">氨基氰</a>与<a href="/wiki/%E4%B8%89%E6%B0%9F%E5%8C%96%E7%A1%BC" title="三氟化硼">BF<sub>3</sub></a>加热形成聚甲烯和氮气<sup id="cite_ref-教材_1-1" class="reference"><a href="#cite_note-教材-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>；2,6-二甲苯酚氧化生成<a href="/wiki/%E8%81%9A%E6%B0%A7%E4%BA%8C%E7%94%B2%E8%8B%AF" title="聚氧二甲苯">聚二甲基苯醚</a>等<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>。 </p><p><b>异构化聚合</b>（Isomerization polymerization）：指在聚合过程中发生原子或原子团的<a href="/wiki/%E9%87%8D%E6%8E%92%E5%8F%8D%E5%BA%94" title="重排反应">重排</a>过程的反应。如丙烯酰胺聚合时发生分子内转移产生聚酰胺-3。 </p> <div class="mw-heading mw-heading3"><h3 id="2.按照聚合机理"><span id="2..E6.8C.89.E7.85.A7.E8.81.9A.E5.90.88.E6.9C.BA.E7.90.86"></span>2.按照聚合机理</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%81%9A%E5%90%88&action=edit&section=3" title="编辑章节：2.按照聚合机理"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>按照聚合反应机理常分成逐步聚合、连锁聚合、配位聚合三大类<sup id="cite_ref-教材_1-2" class="reference"><a href="#cite_note-教材-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <ul><li><b>逐步聚合</b></li></ul> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r85100532" /><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/wiki/%E9%80%90%E6%AD%A5%E8%81%9A%E5%90%88" title="逐步聚合">逐步聚合</a></div> <p><b>逐步聚合</b>（Step-growth polymerization）指低分子单体逐步增长转变成高分子的聚合反应。每步<a href="/wiki/%E5%8F%8D%E5%BA%94%E9%80%9F%E7%8E%87" class="mw-redirect" title="反应速率">反应速率</a>和<a href="/wiki/%E6%B4%BB%E5%8C%96%E8%83%BD" title="活化能">活化能</a>大致相同，无<a href="/wiki/%E6%B4%BB%E6%80%A7%E4%B8%AD%E9%97%B4%E4%BD%93" title="活性中间体">活性中心</a>产生。多数缩聚反应属逐步聚合。 </p> <ul><li><b>连锁聚合</b></li></ul> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r85100532" /><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/wiki/%E8%BF%9E%E9%94%81%E8%81%9A%E5%90%88" class="mw-redirect" title="连锁聚合">连锁聚合</a></div> <p>连锁聚合（Chain-growth polymerization，Chain polymerization）：指在聚合反应过程中有<a href="/wiki/%E6%B4%BB%E6%80%A7%E4%B8%AD%E9%97%B4%E4%BD%93" title="活性中间体">活性中心</a>形成，而且可以在很短的时间形成分子量很大的聚合物的反应。多数烯类单体加聚反应属连锁聚合。 </p><p>根据形成活性中心性质，可又分为<a href="/wiki/%E8%87%AA%E7%94%B1%E5%9F%BA%E8%81%9A%E5%90%88" class="mw-redirect" title="自由基聚合">自由基聚合</a>(Free radical polymerization)，离子聚合(Ionic polymerization)（包括<a href="/wiki/%E9%99%B0%E9%9B%A2%E5%AD%90%E5%8A%A0%E6%88%90%E8%81%9A%E5%90%88%E5%8F%8D%E6%87%89" title="陰離子加成聚合反應">阴离子聚合</a>和<a href="/wiki/%E9%99%BD%E9%9B%A2%E5%AD%90%E8%81%9A%E5%90%88%E5%8F%8D%E6%87%89" title="陽離子聚合反應">阳离子聚合</a>）。 </p> <ul><li><b>配位聚合</b></li></ul> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r85100532" /><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/w/index.php?title=%E9%85%8D%E4%BD%8D%E8%81%9A%E5%90%88&action=edit&redlink=1" class="new" title="配位聚合（页面不存在）">配位聚合</a></div> <p>配位聚合（complexing polymerization），又称<b>齐格勒-纳塔聚合</b>（Ziegler–Natta polymerization），指利用<a href="/wiki/%E9%BD%90%E6%A0%BC%E5%8B%92-%E7%BA%B3%E5%A1%94%E5%82%AC%E5%8C%96%E5%89%82" title="齐格勒-纳塔催化剂">配合物</a>作为催化剂与单体络合形成活性中心进行链增长的聚合反应。 </p> <div class="mw-heading mw-heading3"><h3 id="3.按照聚合单体"><span id="3..E6.8C.89.E7.85.A7.E8.81.9A.E5.90.88.E5.8D.95.E4.BD.93"></span>3.按照聚合单体</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%81%9A%E5%90%88&action=edit&section=4" title="编辑章节：3.按照聚合单体"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r85100532" /><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/wiki/%E5%9D%87%E8%81%9A%E7%89%A9" title="均聚物">均聚物</a>和<a href="/wiki/%E5%85%B1%E8%81%9A%E7%89%A9" title="共聚物">共聚物</a></div> <p>根据聚合单体种类数量，分为均聚合反应和共聚合反应。 </p> <ul><li><b>均聚合反应</b></li></ul> <p>均聚合反应，简称<b>均聚</b>(Homopolymerization), </p><p>如由<a href="/wiki/%E4%B9%99%E7%83%AF" title="乙烯">乙烯</a>分子作为单体聚合形成<a href="/wiki/%E8%81%9A%E4%B9%99%E7%83%AF" title="聚乙烯">聚乙烯</a>反应；此外还有<a href="/wiki/%E4%B8%99%E7%83%AF" title="丙烯">丙烯</a>均聚形成<a href="/wiki/%E8%81%9A%E4%B8%99%E7%83%AF" title="聚丙烯">聚丙烯</a>塑料，<a href="/wiki/%E6%B0%AF%E4%B9%99%E7%83%AF" title="氯乙烯">氯乙烯</a>形成<a href="/wiki/%E8%81%9A%E6%B0%AF%E4%B9%99%E7%83%AF" title="聚氯乙烯">聚氯乙烯</a>等。 </p> <ul><li><b>共聚合反应</b></li></ul> <p>共聚合反应，简称<b>共聚</b>(Copolymerization),指由几种不同的单体聚合形成高聚物的反应。 </p><p>如由乙烯和丙烯进行共聚，可以形成合成<a href="/wiki/%E6%A9%A1%E8%83%B6" class="mw-redirect" title="橡胶">橡胶</a>，叫做<a href="/wiki/%E4%B9%99%E4%B8%99%E6%A9%A1%E8%83%B6" title="乙丙橡胶">乙丙橡胶</a>。 </p> <div class="mw-heading mw-heading3"><h3 id="4.按照聚合方式"><span id="4..E6.8C.89.E7.85.A7.E8.81.9A.E5.90.88.E6.96.B9.E5.BC.8F"></span>4.按照聚合方式</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%81%9A%E5%90%88&action=edit&section=5" title="编辑章节：4.按照聚合方式"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>按照聚合实施方式优可分为本体聚合与溶液聚合、均相聚合与非均相聚合等多种划分方式。 </p> <ul><li>均相聚合：聚合体系为<a href="/wiki/%E5%9D%87%E7%9B%B8%E7%B3%BB" class="mw-redirect" title="均相系">均相</a>。包括本体聚合(熔体聚合)、溶液聚合等。</li> <li>非均相聚合：聚合体系为非均相。包括悬浮聚合、界面聚合、乳液聚合、沉淀聚合等。</li></ul> <div class="mw-heading mw-heading2"><h2 id="参见"><span id=".E5.8F.82.E8.A7.81"></span>参见</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%81%9A%E5%90%88&action=edit&section=6" title="编辑章节：参见"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/w/index.php?title=%E5%8A%A0%E8%81%9A&action=edit&redlink=1" class="new" title="加聚（页面不存在）">加聚</a></li> <li><a href="/wiki/%E7%BC%A9%E8%81%9A" class="mw-redirect" title="缩聚">缩聚</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="参考文献"><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span>参考文献</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%81%9A%E5%90%88&action=edit&section=7" title="编辑章节：参考文献"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-教材-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-教材_1-0"><sup><b>1.0</b></sup></a> <a href="#cite_ref-教材_1-1"><sup><b>1.1</b></sup></a> <a href="#cite_ref-教材_1-2"><sup><b>1.2</b></sup></a></span> <span class="reference-text"><cite class="citation book">潘祖仁. 高分子化学第五版. 北京: 化学工业出版社. 2011: 6–9. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/978-7-122-10798-5" title="Special:网络书源/978-7-122-10798-5"><span title="国际标准书号">ISBN</span> 978-7-122-10798-5</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%81%9A%E5%90%88&rft.au=%E6%BD%98%E7%A5%96%E4%BB%81&rft.btitle=%E9%AB%98%E5%88%86%E5%AD%90%E5%8C%96%E5%AD%A6&rft.date=2011&rft.edition=%E7%AC%AC%E4%BA%94%E7%89%88&rft.genre=book&rft.isbn=978-7-122-10798-5&rft.pages=6-9&rft.place=%E5%8C%97%E4%BA%AC&rft.pub=%E5%8C%96%E5%AD%A6%E5%B7%A5%E4%B8%9A%E5%87%BA%E7%89%88%E7%A4%BE&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text"><cite class="citation book">林茵; 李想. 高分子化学辞典. 呼和浩特: 远方出版社. 2006. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/7-80595-982-X" title="Special:网络书源/7-80595-982-X"><span title="国际标准书号">ISBN</span> 7-80595-982-X</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%81%9A%E5%90%88&rft.au=%E6%9D%8E%E6%83%B3&rft.au=%E6%9E%97%E8%8C%B5&rft.btitle=%E9%AB%98%E5%88%86%E5%AD%90%E5%8C%96%E5%AD%A6%E8%BE%9E%E5%85%B8&rft.date=2006&rft.genre=book&rft.isbn=7-80595-982-X&rft.place=%E5%91%BC%E5%92%8C%E6%B5%A9%E7%89%B9&rft.pub=%E8%BF%9C%E6%96%B9%E5%87%BA%E7%89%88%E7%A4%BE&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> </ol></div> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r84265675">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist dt,.mw-parser-output .hlist li{margin:0;display:inline}.mw-parser-output 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