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Kompleksühend – Vikipeedia
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class="mw-list-item"><a href="/wiki/Eri:Viimased_muudatused" title="Vikis tehtud viimaste muudatuste loend [r]" accesskey="r"><span>Viimased muudatused</span></a></li><li id="n-randompage" class="mw-list-item"><a href="/wiki/Eri:Juhuslik_artikkel" title="Mine juhuslikule leheküljele [x]" accesskey="x"><span>Juhuslik lehekülg</span></a></li><li id="n-help" class="mw-list-item"><a href="/wiki/Juhend:Sisukord" title="Kuidas redigeerida"><span>Juhend</span></a></li><li id="n-contact" class="mw-list-item"><a href="/wiki/Vikipeedia:Kontakteeru_meiega"><span>Kontakt</span></a></li> </ul> </div> </div> <div id="p-coll-print_export" class="vector-menu mw-portlet mw-portlet-coll-print_export" > <div class="vector-menu-heading"> Trüki või ekspordi </div> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="coll-create_a_book" class="mw-list-item"><a href="/w/index.php?title=Eri:Raamat&bookcmd=book_creator&referer=Kompleks%C3%BChend"><span>Koosta 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[o]" accesskey="o" class=""><span>Logi sisse</span></a> </li> </ul> </div> </div> </div> <div id="vector-user-links-dropdown" class="vector-dropdown vector-user-menu vector-button-flush-right vector-user-menu-logged-out" title="Veel valikuid" > <input type="checkbox" id="vector-user-links-dropdown-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-user-links-dropdown" class="vector-dropdown-checkbox " aria-label="Isiklikud lehed" > <label id="vector-user-links-dropdown-label" for="vector-user-links-dropdown-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-ellipsis mw-ui-icon-wikimedia-ellipsis"></span> <span class="vector-dropdown-label-text">Isiklikud lehed</span> </label> <div class="vector-dropdown-content"> <div id="p-personal" class="vector-menu mw-portlet mw-portlet-personal user-links-collapsible-item" title="Kasutajamenüü" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="pt-sitesupport" class="user-links-collapsible-item mw-list-item"><a href="//donate.wikimedia.org/wiki/Special:FundraiserRedirector?utm_source=donate&utm_medium=sidebar&utm_campaign=C13_et.wikipedia.org&uselang=et"><span>Annetused</span></a></li><li id="pt-createaccount" class="user-links-collapsible-item mw-list-item"><a href="/w/index.php?title=Eri:Konto_loomine&returnto=Kompleks%C3%BChend" title="See pole küll kohustuslik, aga sul tasub konto luua ja sisse logida."><span class="vector-icon mw-ui-icon-userAdd mw-ui-icon-wikimedia-userAdd"></span> <span>Loo konto</span></a></li><li id="pt-login" class="user-links-collapsible-item mw-list-item"><a href="/w/index.php?title=Eri:Sisselogimine&returnto=Kompleks%C3%BChend" title="See pole küll kohustuslik, aga sul tasub sisse logida. [o]" accesskey="o"><span class="vector-icon mw-ui-icon-logIn mw-ui-icon-wikimedia-logIn"></span> <span>Logi sisse</span></a></li> </ul> </div> </div> <div id="p-user-menu-anon-editor" class="vector-menu mw-portlet mw-portlet-user-menu-anon-editor" > <div class="vector-menu-heading"> Sisselogimata kasutaja leheküljed <a href="/wiki/Juhend:Sissejuhatus" aria-label="Lisateave redigeerimise kohta"><span>lisateave</span></a> </div> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="pt-anoncontribs" class="mw-list-item"><a href="/wiki/Eri:Minu_kaast%C3%B6%C3%B6" title="Sellelt IP-aadressilt tehtud muudatuste loend [y]" accesskey="y"><span>Kaastöö</span></a></li><li id="pt-anontalk" class="mw-list-item"><a href="/wiki/Eri:Minu_aruteluleht" title="Arutelu sellelt IP-aadressilt tehtud muudatuste kohta [n]" accesskey="n"><span>Arutelu</span></a></li> </ul> </div> </div> </div> </div> </nav> </div> </header> </div> <div class="mw-page-container"> <div 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class="vector-pinnable-header-label">Sisukord</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">vii külgpaanile</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">peida</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">Algus</div> </a> </li> <li id="toc-Nomenklatuur" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Nomenklatuur"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>Nomenklatuur</span> </div> </a> <ul id="toc-Nomenklatuur-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Liigitamine" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Liigitamine"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>Liigitamine</span> </div> </a> <ul id="toc-Liigitamine-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Tüüpilised_koordinatsiooniarvud" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Tüüpilised_koordinatsiooniarvud"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>Tüüpilised koordinatsiooniarvud</span> </div> </a> <ul id="toc-Tüüpilised_koordinatsiooniarvud-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Isomeeria" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Isomeeria"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>Isomeeria</span> </div> </a> <ul id="toc-Isomeeria-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Vaata_ka" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Vaata_ka"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>Vaata ka</span> </div> </a> <ul id="toc-Vaata_ka-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Viited" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Viited"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>Viited</span> </div> </a> <ul id="toc-Viited-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Sisukord" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="Lülita sisukord ümber" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">Lülita sisukord ümber</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Kompleksühend</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="Mine teises keeles artiklisse. Saadaval 43 keeles" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-43" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">43 keelt</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%85%D8%B9%D9%82%D8%AF_%D8%AA%D9%86%D8%A7%D8%B3%D9%82%D9%8A" title="معقد تناسقي – araabia" lang="ar" hreflang="ar" data-title="معقد تناسقي" data-language-autonym="العربية" data-language-local-name="araabia" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-az mw-list-item"><a href="https://az.wikipedia.org/wiki/Kompleks_birl%C9%99%C5%9Fm%C9%99l%C9%99r" title="Kompleks birləşmələr – aserbaidžaani" lang="az" hreflang="az" data-title="Kompleks birləşmələr" data-language-autonym="Azərbaycanca" data-language-local-name="aserbaidžaani" class="interlanguage-link-target"><span>Azərbaycanca</span></a></li><li class="interlanguage-link interwiki-bs mw-list-item"><a href="https://bs.wikipedia.org/wiki/Koordinacijski_kompleks" title="Koordinacijski kompleks – bosnia" lang="bs" hreflang="bs" data-title="Koordinacijski kompleks" data-language-autonym="Bosanski" data-language-local-name="bosnia" class="interlanguage-link-target"><span>Bosanski</span></a></li><li class="interlanguage-link interwiki-bg mw-list-item"><a href="https://bg.wikipedia.org/wiki/%D0%9A%D0%BE%D0%BC%D0%BF%D0%BB%D0%B5%D0%BA%D1%81%D0%BD%D0%BE_%D1%81%D1%8A%D0%B5%D0%B4%D0%B8%D0%BD%D0%B5%D0%BD%D0%B8%D0%B5" title="Комплексно съединение – bulgaaria" lang="bg" hreflang="bg" data-title="Комплексно съединение" data-language-autonym="Български" data-language-local-name="bulgaaria" class="interlanguage-link-target"><span>Български</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Complex_de_coordinaci%C3%B3" title="Complex de coordinació – katalaani" lang="ca" hreflang="ca" data-title="Complex de coordinació" data-language-autonym="Català" data-language-local-name="katalaani" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cv mw-list-item"><a href="https://cv.wikipedia.org/wiki/%D0%9A%D0%BE%D0%BC%D0%BF%D0%BB%D0%B5%D0%BA%D1%81%D0%BB%C4%83_%D1%8F%D0%BF%D0%B0%D0%BB%D0%B0%D0%BB%C4%83%D1%85" title="Комплекслă япалалăх – tšuvaši" lang="cv" hreflang="cv" data-title="Комплекслă япалалăх" data-language-autonym="Чӑвашла" data-language-local-name="tšuvaši" class="interlanguage-link-target"><span>Чӑвашла</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Komplexn%C3%AD_slou%C4%8Denina" title="Komplexní sloučenina – tšehhi" lang="cs" hreflang="cs" data-title="Komplexní sloučenina" data-language-autonym="Čeština" data-language-local-name="tšehhi" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%A3%CF%8D%CE%BC%CF%80%CE%BB%CE%BF%CE%BA%CE%BF_(%CF%87%CE%B7%CE%BC%CE%B5%CE%AF%CE%B1)" title="Σύμπλοκο (χημεία) – kreeka" lang="el" hreflang="el" data-title="Σύμπλοκο (χημεία)" data-language-autonym="Ελληνικά" data-language-local-name="kreeka" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Coordination_complex" title="Coordination complex – inglise" lang="en" hreflang="en" data-title="Coordination complex" data-language-autonym="English" data-language-local-name="inglise" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-eo mw-list-item"><a href="https://eo.wikipedia.org/wiki/Kunordiga_komplekso" title="Kunordiga komplekso – esperanto" lang="eo" hreflang="eo" data-title="Kunordiga komplekso" data-language-autonym="Esperanto" data-language-local-name="esperanto" class="interlanguage-link-target"><span>Esperanto</span></a></li><li class="interlanguage-link interwiki-eu mw-list-item"><a href="https://eu.wikipedia.org/wiki/Koordinazio_konposatu" title="Koordinazio konposatu – baski" lang="eu" hreflang="eu" data-title="Koordinazio konposatu" data-language-autonym="Euskara" data-language-local-name="baski" class="interlanguage-link-target"><span>Euskara</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%DA%A9%D9%85%D9%BE%D9%84%DA%A9%D8%B3_%D8%B4%DB%8C%D9%85%DB%8C%D8%A7%DB%8C%DB%8C" title="کمپلکس شیمیایی – pärsia" lang="fa" hreflang="fa" data-title="کمپلکس شیمیایی" data-language-autonym="فارسی" data-language-local-name="pärsia" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Complexe_de_coordination" title="Complexe de coordination – prantsuse" lang="fr" hreflang="fr" data-title="Complexe de coordination" data-language-autonym="Français" data-language-local-name="prantsuse" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-ga mw-list-item"><a href="https://ga.wikipedia.org/wiki/Coimpl%C3%A9asc_comhordan%C3%A1idithe" title="Coimpléasc comhordanáidithe – iiri" lang="ga" hreflang="ga" data-title="Coimpléasc comhordanáidithe" data-language-autonym="Gaeilge" data-language-local-name="iiri" class="interlanguage-link-target"><span>Gaeilge</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%EB%B0%B0%EC%9C%84_%ED%99%94%ED%95%A9%EB%AC%BC" title="배위 화합물 – korea" lang="ko" hreflang="ko" data-title="배위 화합물" data-language-autonym="한국어" data-language-local-name="korea" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-hy mw-list-item"><a href="https://hy.wikipedia.org/wiki/%D4%BF%D5%B8%D5%B4%D5%BA%D5%AC%D5%A5%D6%84%D5%BD_%D5%B4%D5%AB%D5%A1%D6%81%D5%B8%D6%82%D5%A9%D5%B5%D5%B8%D6%82%D5%B6%D5%B6%D5%A5%D6%80" title="Կոմպլեքս միացություններ – armeenia" lang="hy" hreflang="hy" data-title="Կոմպլեքս միացություններ" data-language-autonym="Հայերեն" data-language-local-name="armeenia" class="interlanguage-link-target"><span>Հայերեն</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%89%E0%A4%AA%E0%A4%B8%E0%A4%B9%E0%A4%B8%E0%A4%82%E0%A4%AF%E0%A5%8B%E0%A4%9C%E0%A4%95_%E0%A4%AF%E0%A5%8C%E0%A4%97%E0%A4%BF%E0%A4%95" title="उपसहसंयोजक यौगिक – hindi" lang="hi" hreflang="hi" data-title="उपसहसंयोजक यौगिक" data-language-autonym="हिन्दी" data-language-local-name="hindi" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Complesso_(chimica)" title="Complesso (chimica) – itaalia" lang="it" hreflang="it" data-title="Complesso (chimica)" data-language-autonym="Italiano" data-language-local-name="itaalia" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-he mw-list-item"><a href="https://he.wikipedia.org/wiki/%D7%A7%D7%95%D7%9E%D7%A4%D7%9C%D7%A7%D7%A1_(%D7%9B%D7%99%D7%9E%D7%99%D7%94)" title="קומפלקס (כימיה) – heebrea" lang="he" hreflang="he" data-title="קומפלקס (כימיה)" data-language-autonym="עברית" data-language-local-name="heebrea" class="interlanguage-link-target"><span>עברית</span></a></li><li class="interlanguage-link interwiki-kk mw-list-item"><a href="https://kk.wikipedia.org/wiki/%D0%9A%D0%B5%D1%88%D0%B5%D0%BD%D0%B4%D1%96_%D2%9B%D0%BE%D1%81%D1%8B%D0%BB%D1%8B%D1%81%D1%82%D0%B0%D1%80" title="Кешенді қосылыстар – kasahhi" lang="kk" hreflang="kk" data-title="Кешенді қосылыстар" data-language-autonym="Қазақша" data-language-local-name="kasahhi" class="interlanguage-link-target"><span>Қазақша</span></a></li><li class="interlanguage-link interwiki-lv mw-list-item"><a href="https://lv.wikipedia.org/wiki/Kompleksie_savienojumi" title="Kompleksie savienojumi – läti" lang="lv" hreflang="lv" data-title="Kompleksie savienojumi" data-language-autonym="Latviešu" data-language-local-name="läti" class="interlanguage-link-target"><span>Latviešu</span></a></li><li class="interlanguage-link interwiki-ml mw-list-item"><a href="https://ml.wikipedia.org/wiki/%E0%B4%95%E0%B5%8B%E0%B5%BC%E0%B4%A1%E0%B4%BF%E0%B4%A8%E0%B5%87%E0%B4%B7%E0%B5%BB_%E0%B4%95%E0%B5%8B%E0%B4%82%E0%B4%AA%E0%B5%8D%E0%B4%B2%E0%B4%95%E0%B5%8D%E0%B4%B8%E0%B5%8D" title="കോർഡിനേഷൻ കോംപ്ലക്സ് – malajalami" lang="ml" hreflang="ml" data-title="കോർഡിനേഷൻ കോംപ്ലക്സ്" data-language-autonym="മലയാളം" data-language-local-name="malajalami" class="interlanguage-link-target"><span>മലയാളം</span></a></li><li class="interlanguage-link interwiki-mn mw-list-item"><a href="https://mn.wikipedia.org/wiki/%D0%9A%D0%BE%D0%BC%D0%BF%D0%BB%D0%B5%D0%BA%D1%81_%D0%BD%D1%8D%D0%B3%D0%B4%D1%8D%D0%BB" title="Комплекс нэгдэл – mongoli" lang="mn" hreflang="mn" data-title="Комплекс нэгдэл" data-language-autonym="Монгол" data-language-local-name="mongoli" class="interlanguage-link-target"><span>Монгол</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Co%C3%B6rdinatieverbinding" title="Coördinatieverbinding – hollandi" lang="nl" hreflang="nl" data-title="Coördinatieverbinding" data-language-autonym="Nederlands" data-language-local-name="hollandi" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E9%8C%AF%E4%BD%93" title="錯体 – jaapani" lang="ja" hreflang="ja" data-title="錯体" data-language-autonym="日本語" data-language-local-name="jaapani" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-uz mw-list-item"><a href="https://uz.wikipedia.org/wiki/Koordinatsion_birikmalar" title="Koordinatsion birikmalar – usbeki" lang="uz" hreflang="uz" data-title="Koordinatsion birikmalar" data-language-autonym="Oʻzbekcha / ўзбекча" data-language-local-name="usbeki" class="interlanguage-link-target"><span>Oʻzbekcha / ўзбекча</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Zwi%C4%85zki_kompleksowe" title="Związki kompleksowe – poola" lang="pl" hreflang="pl" data-title="Związki kompleksowe" data-language-autonym="Polski" data-language-local-name="poola" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Composto_de_coordena%C3%A7%C3%A3o" title="Composto de coordenação – portugali" lang="pt" hreflang="pt" data-title="Composto de coordenação" data-language-autonym="Português" data-language-local-name="portugali" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Complex_coordinativ" title="Complex coordinativ – rumeenia" lang="ro" hreflang="ro" data-title="Complex coordinativ" data-language-autonym="Română" data-language-local-name="rumeenia" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%9A%D0%BE%D0%BC%D0%BF%D0%BB%D0%B5%D0%BA%D1%81%D0%BD%D1%8B%D0%B5_%D1%81%D0%BE%D0%B5%D0%B4%D0%B8%D0%BD%D0%B5%D0%BD%D0%B8%D1%8F" title="Комплексные соединения – vene" lang="ru" hreflang="ru" data-title="Комплексные соединения" data-language-autonym="Русский" data-language-local-name="vene" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-simple mw-list-item"><a href="https://simple.wikipedia.org/wiki/Coordination_complex" title="Coordination complex – lihtsustatud inglise" lang="en-simple" hreflang="en-simple" data-title="Coordination complex" data-language-autonym="Simple English" data-language-local-name="lihtsustatud inglise" class="interlanguage-link-target"><span>Simple English</span></a></li><li class="interlanguage-link interwiki-sk mw-list-item"><a href="https://sk.wikipedia.org/wiki/Koordina%C4%8Dn%C3%A1_zl%C3%BA%C4%8Denina" title="Koordinačná zlúčenina – slovaki" lang="sk" hreflang="sk" data-title="Koordinačná zlúčenina" data-language-autonym="Slovenčina" data-language-local-name="slovaki" class="interlanguage-link-target"><span>Slovenčina</span></a></li><li class="interlanguage-link interwiki-sl mw-list-item"><a href="https://sl.wikipedia.org/wiki/Kompleksna_spojina" title="Kompleksna spojina – sloveeni" lang="sl" hreflang="sl" data-title="Kompleksna spojina" data-language-autonym="Slovenščina" data-language-local-name="sloveeni" class="interlanguage-link-target"><span>Slovenščina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/%D0%9A%D0%BE%D0%BC%D0%BF%D0%BB%D0%B5%D0%BA%D1%81%D0%BD%D0%BE_%D1%98%D0%B5%D0%B4%D0%B8%D1%9A%D0%B5%D1%9A%D0%B5" title="Комплексно једињење – serbia" lang="sr" hreflang="sr" data-title="Комплексно једињење" data-language-autonym="Српски / srpski" data-language-local-name="serbia" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Kompleksno_jedinjenje" title="Kompleksno jedinjenje – serbia-horvaadi" lang="sh" hreflang="sh" data-title="Kompleksno jedinjenje" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="serbia-horvaadi" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%85%E0%AE%A3%E0%AF%88%E0%AE%B5%E0%AF%81%E0%AE%9A%E0%AF%8D_%E0%AE%9A%E0%AF%87%E0%AE%B0%E0%AF%8D%E0%AE%AE%E0%AE%99%E0%AF%8D%E0%AE%95%E0%AE%B3%E0%AF%8D" title="அணைவுச் சேர்மங்கள் – tamili" lang="ta" hreflang="ta" data-title="அணைவுச் சேர்மங்கள்" data-language-autonym="தமிழ்" data-language-local-name="tamili" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-th mw-list-item"><a href="https://th.wikipedia.org/wiki/%E0%B8%AA%E0%B8%B2%E0%B8%A3%E0%B8%9B%E0%B8%A3%E0%B8%B0%E0%B8%81%E0%B8%AD%E0%B8%9A%E0%B9%82%E0%B8%84%E0%B8%AD%E0%B8%AD%E0%B8%A3%E0%B9%8C%E0%B8%94%E0%B8%B4%E0%B9%80%E0%B8%99%E0%B8%8A%E0%B8%B1%E0%B8%99" title="สารประกอบโคออร์ดิเนชัน – tai" lang="th" hreflang="th" data-title="สารประกอบโคออร์ดิเนชัน" data-language-autonym="ไทย" data-language-local-name="tai" class="interlanguage-link-target"><span>ไทย</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Ph%E1%BB%A9c_ch%E1%BA%A5t" title="Phức chất – vietnami" lang="vi" hreflang="vi" data-title="Phức chất" data-language-autonym="Tiếng Việt" data-language-local-name="vietnami" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Kompleks_(kimya)" title="Kompleks (kimya) – türgi" lang="tr" hreflang="tr" data-title="Kompleks (kimya)" 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<div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">Allikas: Vikipeedia</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="et" dir="ltr"><figure typeof="mw:File/Thumb"><a href="/wiki/Fail:Cobalamin_skeletal.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/4/4c/Cobalamin_skeletal.svg/300px-Cobalamin_skeletal.svg.png" decoding="async" width="300" height="354" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/4c/Cobalamin_skeletal.svg/450px-Cobalamin_skeletal.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/4c/Cobalamin_skeletal.svg/600px-Cobalamin_skeletal.svg.png 2x" data-file-width="512" data-file-height="605" /></a><figcaption>B<sub>12</sub>-vitamiin on kompleksühend</figcaption></figure> <p><b>Kompleksühend</b> on <a href="/wiki/Keemiline_%C3%BChend" title="Keemiline ühend">keemiline ühend</a>, kus keskne aatom või ioon (tsentraalaatom või -ioon, enamasti metall) on seotud <a href="/wiki/Ligand" title="Ligand">ligandidega</a> <a href="/w/index.php?title=Koordinatiivne_side&action=edit&redlink=1" class="new" title="Koordinatiivne side (pole veel kirjutatud)">koordinatiivsete</a> ehk doonor-aktseptorsidemete kaudu. Iga ligand on seostunud tsentraalaatomiga vähemalt ühe <a href="/wiki/Kovalentne_side" title="Kovalentne side">kovalentse sideme</a> kaudu. Üks aatom annab sideme moodustamiseks vaba <a href="/wiki/Elektronpaar" title="Elektronpaar">elektronpaari</a>, teine aatom tühja <a href="/wiki/Orbitaal" title="Orbitaal">orbitaali</a>. Esimesena kirjeldas kompleksühendite struktuuri <a href="/w/index.php?title=Alfred_Werner&action=edit&redlink=1" class="new" title="Alfred Werner (pole veel kirjutatud)">Alfred Werner</a>.<sup id="cite_ref-:0_1-0" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p><p>Kompleksühend koosneb kompleksimoodustajast (tsentraalaatom, tsentraalioon), milleks on enamasti <a href="/wiki/Metallid" title="Metallid">metalliaatomid</a> või -<a href="/wiki/Ioon" title="Ioon">ioonid</a>, ning ligandidest (neutraalsed <a href="/wiki/Molekul" title="Molekul">molekulid</a> või negatiivselt laetud ioonid). Veel saab jagada kompleksühendi sisesfääriks ja välissfääriks. Sisesfääri moodustab kompleksimoodustaja koos tema külge seondunud ligandidega, välissfäär moodustub siis, kui sisesfäär on laetud (positiivselt või negatiivselt), et saavutada elektroneutraalne ühend. Tsentraalaatomiga seostunud ligandide arvu väljendab <a href="/w/index.php?title=Koordinatsiooniarv&action=edit&redlink=1" class="new" title="Koordinatsiooniarv (pole veel kirjutatud)">koordinatsiooniarv</a>. Enamasti on koordinatsiooniarv paarisarv (2, 4, 6).<sup id="cite_ref-:0_1-1" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Nomenklatuur">Nomenklatuur</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Kompleks%C3%BChend&veaction=edit&section=1" title="Muuda alaosa "Nomenklatuur"" class="mw-editsection-visualeditor"><span>muuda</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Kompleks%C3%BChend&action=edit&section=1" title="Muuda alaosa "Nomenklatuur" lähteteksti"><span>muuda lähteteksti</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Nimetuse andmist alustatakse <a href="/wiki/Katioon" title="Katioon">katiooni(de)st</a>, seejärel nimetatakse <a href="/wiki/Anioon" title="Anioon">anioon(id)</a>. Kui tsentraalaatomiga on seostunud erinevad ligandid, siis loetletakse need üles tähestikulises järjekorras (<a href="/wiki/Prefiks" title="Prefiks">eesliiteid</a> arvestamata). Ühesuguste ligandide arv tähistatakse vastava eesliitega (di, tri jne). Kui tsentraalaatom võib olla ühendites erineva <a href="/wiki/Oks%C3%BCdatsiooniaste" title="Oksüdatsiooniaste">oksüdatsiooniastmega</a>, siis märgitakse vastav oksüdatsiooniaste elemendi nimetuse järel sulgudes. Kui kompleksi sisesfäär on negatiivselt laetud, siis kasutatakse nimetamisel tsentraalaatomi ladinakeelset nimetust järelliitega -aat.<sup id="cite_ref-:0_1-2" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <table class="wikitable"> <caption> </caption> <tbody><tr> <th>Elemendi nimetus </th> <th>Nimetus negatiivse sisesfääri korral </th></tr> <tr> <td>alumiinium (Al) </td> <td>aluminaat (nimetus ei muutu võrreldes elemendi eestikeelse nimega) </td></tr> <tr> <td>elavhõbe (Hg) </td> <td>merkuraat </td></tr> <tr> <td>hõbe (Ag) </td> <td>argentaat </td></tr> <tr> <td>kuld (Au) </td> <td>auraat </td></tr> <tr> <td>plii (Pb) </td> <td>plumbaat </td></tr> <tr> <td>raud (Fe) </td> <td>ferraat </td></tr> <tr> <td>tina (Sn) </td> <td>stannaat </td></tr> <tr> <td>vask (Cu) </td> <td>kupraat </td></tr> <tr> <td>vismut (Bi) </td> <td>bismutaat </td></tr></tbody></table> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/Fail:Potassium_hexacyanidoferrate(II).jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/c/c2/Potassium_hexacyanidoferrate%28II%29.jpg/220px-Potassium_hexacyanidoferrate%28II%29.jpg" decoding="async" width="220" height="293" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/c2/Potassium_hexacyanidoferrate%28II%29.jpg/330px-Potassium_hexacyanidoferrate%28II%29.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/c2/Potassium_hexacyanidoferrate%28II%29.jpg/440px-Potassium_hexacyanidoferrate%28II%29.jpg 2x" data-file-width="500" data-file-height="667" /></a><figcaption>K<sub>4</sub>[Fe(CN)<sub>6</sub>] ehk kaaliumheksatsüanoferraat(II)</figcaption></figure> <p>Anioonsete ligandide korral asendub varasem <a href="/wiki/Sufiks" title="Sufiks">järelliide</a> uue järelliitega -o. Neutraalseid ligande nimetatakse nagu vastavaid molekule, kuid eranditega: <a href="/wiki/Vesi" title="Vesi">vesi</a> (H<sub>2</sub>O) on akva, <a href="/wiki/Ammoniaak" title="Ammoniaak">ammoniaak</a> (NH<sub>3</sub>) ammiin, <a href="/wiki/Vingugaas" title="Vingugaas">süsinikmonooksiid</a> (CO) karbonüül ja <a href="/wiki/L%C3%A4mmastikoksiid" title="Lämmastikoksiid">lämmastikoksiid</a> (NO) nitrosüül.<sup id="cite_ref-:0_1-3" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <table class="wikitable"> <caption> </caption> <tbody><tr> <th>Aniooni nimetus </th> <th>Ligandi nimetus </th></tr> <tr> <td>kloriid </td> <td>kloro </td></tr> <tr> <td>bromiid </td> <td>bromo </td></tr> <tr> <td>tsüaniid </td> <td>tsüano </td></tr> <tr> <td>oksiid </td> <td>okso </td></tr> <tr> <td>hüdriid </td> <td>hüdrido </td></tr> <tr> <td>sulfaat </td> <td>sulfato </td></tr> <tr> <td>karbonaat </td> <td>karbonato </td></tr> <tr> <td>oksalaat </td> <td>oksalato </td></tr> <tr> <td>tiotsüanaat </td> <td>tiotsüanato </td></tr> <tr> <td>nitrit </td> <td>nitrito </td></tr></tbody></table> <div class="mw-heading mw-heading2"><h2 id="Liigitamine">Liigitamine</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Kompleks%C3%BChend&veaction=edit&section=2" title="Muuda alaosa "Liigitamine"" class="mw-editsection-visualeditor"><span>muuda</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Kompleks%C3%BChend&action=edit&section=2" title="Muuda alaosa "Liigitamine" lähteteksti"><span>muuda lähteteksti</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Kompleksühendeid saab liigitada omaduste järgi: </p><p><b>1)</b> <b>Sisesfääri laengu järgi:</b> </p> <ul><li>Katioonsed kompleksid – sisesfäär on positiivselt laetud, välissfääri moodustavad anioonid</li> <li>Anioonsed kompleksid – sisesfäär on negatiivselt laetud, välissfääri moodustavad katioonid</li> <li>Neutraalsed kompleksid – sisesfäär on neutraalne, välissfäär puudub, tsentraalaatomil laeng võib, aga ei pea olema</li> <li>Bikompleksid – nii katioonid kui ka anioonid on kompleksioonid</li></ul> <p><b>2)</b> <b>Ligandide tüübi järgi:</b> </p> <ul><li>Akvakompleksid</li> <li>Ammiinkompleksid</li> <li>Tsüanokompleksid</li> <li>Hüdroksokompleksid</li></ul> <p><b>3)</b> <b>Välissfääri koostise järgi:</b> </p> <ul><li>Komplekshapped (reeglina tugevad happed)</li> <li>Kompleksalused (reeglina tugevad alused)</li> <li>Komplekssoolad</li></ul> <p><b>4)</b> <b>Struktuuri järgi:</b> </p> <ul><li>Koordinatsiooniarvu ja kompleksi kuju järgi</li> <li>Tuumade arvu järgi (ühe- ja mitmetuumalised kompleksid)</li> <li>Ligandi poolt täidetud koordinatsioonikohtade arvu järgi (ühe- ja mitmehambalised ligandid).<sup id="cite_ref-:0_1-4" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup></li></ul> <div class="mw-heading mw-heading2"><h2 id="Tüüpilised_koordinatsiooniarvud"><span id="T.C3.BC.C3.BCpilised_koordinatsiooniarvud"></span>Tüüpilised koordinatsiooniarvud</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Kompleks%C3%BChend&veaction=edit&section=3" title="Muuda alaosa "Tüüpilised koordinatsiooniarvud"" class="mw-editsection-visualeditor"><span>muuda</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Kompleks%C3%BChend&action=edit&section=3" title="Muuda alaosa "Tüüpilised koordinatsiooniarvud" lähteteksti"><span>muuda lähteteksti</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><b>Koordinatsiooniarv 2</b> </p><p>Esineb enamasti I B või II B rühma metallidel oksüdatsiooniastmes I (Ag<sup>+</sup>, Cu<sup>+</sup>, Au<sup>+</sup>, Hg<sub>2</sub><sup>2+</sup>), kuid erandina võib see esineda ka mõnedes teiste katioonide kompleksides. Ligandid paiknevad lineaarselt, teine teisel pool tuuma. </p> <figure class="mw-halign-none" typeof="mw:File/Thumb"><a href="/wiki/Fail:Linear-3D-balls.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/7/78/Linear-3D-balls.png/172px-Linear-3D-balls.png" decoding="async" width="172" height="79" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/7/78/Linear-3D-balls.png/258px-Linear-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/7/78/Linear-3D-balls.png/344px-Linear-3D-balls.png 2x" data-file-width="1100" data-file-height="508" /></a><figcaption>Ligandide paigutus lineaarses kompleksühendis</figcaption></figure> <p><b>Koordinatsiooniarv 4</b> </p><p> Esineb nii väiksemate (näiteks Zn<sup>2+</sup>, Be<sup>2+</sup>) kui ka teiste katioonide (nt Pt<sup>2+</sup>, Pd<sup>2+</sup>) korral (eelkõige suhteliselt suuremate ligandide puhul). Enamasti paiknevad ligandid tetraeedriliselt ümber tuuma, kuid võimalik on ka ruuttasapinnaline paigutus. </p><ul class="gallery mw-gallery-traditional"> <li class="gallerybox" style="width: 185px"> <div class="thumb" style="width: 180px; height: 180px;"><span typeof="mw:File"><a href="/wiki/Fail:Tetrahedral-3D-balls.png" class="mw-file-description" title="Ligandide paigutus tetraeedrilises kompleksühendis"><img alt="Ligandide paigutus tetraeedrilises kompleksühendis" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Tetrahedral-3D-balls.png/143px-Tetrahedral-3D-balls.png" decoding="async" width="143" height="150" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Tetrahedral-3D-balls.png/214px-Tetrahedral-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Tetrahedral-3D-balls.png/286px-Tetrahedral-3D-balls.png 2x" data-file-width="1047" data-file-height="1100" /></a></span></div> <div class="gallerytext">Ligandide paigutus tetraeedrilises kompleksühendis</div> </li> <li class="gallerybox" style="width: 185px"> <div class="thumb" style="width: 180px; height: 180px;"><span typeof="mw:File"><a href="/wiki/Fail:Square-planar-3D-balls.png" class="mw-file-description" title="Ligandide paigutus ruutplanaarses kompleksühendis"><img alt="Ligandide paigutus ruutplanaarses kompleksühendis" src="//upload.wikimedia.org/wikipedia/commons/thumb/5/5b/Square-planar-3D-balls.png/150px-Square-planar-3D-balls.png" decoding="async" width="150" height="109" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/5b/Square-planar-3D-balls.png/225px-Square-planar-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/5/5b/Square-planar-3D-balls.png/300px-Square-planar-3D-balls.png 2x" data-file-width="1100" data-file-height="796" /></a></span></div> <div class="gallerytext">Ligandide paigutus ruutplanaarses kompleksühendis</div> </li> </ul><p><b>Koordinatsiooniarv 6</b> Põhiline koordinatsiooniarv enamiku tuntumate <a href="/wiki/D-elemendid" title="D-elemendid">d-metallide</a> ja <a href="/w/index.php?title=P-elemendid&action=edit&redlink=1" class="new" title="P-elemendid (pole veel kirjutatud)">p-metallide</a> katioonide (nt Cr<sup>3+</sup>, Fe<sup>2+</sup>, Fe<sup>3+</sup>, Ni<sup>2+</sup>, Al<sup>3+</sup>) korral. Ligandid paiknevad enamasti oktaeedriliselt ümber tuuma, kuid võimalik on ka kolmnurkse prisma paigutus.</p><figure class="mw-halign-none" typeof="mw:File/Thumb"><a href="/wiki/Fail:Octahedral-3D-balls.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/1/1a/Octahedral-3D-balls.png/150px-Octahedral-3D-balls.png" decoding="async" width="150" height="157" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/1a/Octahedral-3D-balls.png/226px-Octahedral-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/1a/Octahedral-3D-balls.png/301px-Octahedral-3D-balls.png 2x" data-file-width="1054" data-file-height="1100" /></a><figcaption>Ligandide paigutus oktaeedrilises kompleksühendis</figcaption></figure><p><b>Teised koordinatsiooniarvud</b> </p><p>Võimalikud on ka teised koordinatsiooniarvud, <a href="/w/index.php?title=F-elemendid&action=edit&redlink=1" class="new" title="F-elemendid (pole veel kirjutatud)">f-elementidel</a> kuni 12. Neist olulisemad on koordinatsiooniarv 5 (nt Ni(CO)<sub>5</sub>), mille korral on ligandide ruumiline paiknemine kas kolmnurkne bipüramidaalne või ruutpüramidaalne.<sup id="cite_ref-:0_1-5" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Isomeeria">Isomeeria</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Kompleks%C3%BChend&veaction=edit&section=4" title="Muuda alaosa "Isomeeria"" class="mw-editsection-visualeditor"><span>muuda</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Kompleks%C3%BChend&action=edit&section=4" title="Muuda alaosa "Isomeeria" lähteteksti"><span>muuda lähteteksti</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Kompleksühendites esineva isomeeria saab jagada kaheks: </p><p><b>1) isomeeria, mis ei seostu ainult kompleksühenditega:</b> </p><p><b><a href="/wiki/Cis-trans-isomeeria" title="Cis-trans-isomeeria">Geomeetriline isomeeria</a></b> </p><p> Põhineb ligandide erineval paigutusel kompleksühendis, <i>cis</i>-isomeeri korral paiknevad sama tüüpi ligandid kõrvuti, <i>trans</i>-isomeeri korral paiknevad need üksteise suhtes vastasasendis.</p><ul class="gallery mw-gallery-traditional"> <li class="gallerybox" style="width: 185px"> <div class="thumb" style="width: 180px; height: 180px;"><span typeof="mw:File"><a href="/wiki/Fail:Cis-dichlorotetraamminecobalt(III).png" class="mw-file-description" title="Diklorotetraammiinkoobalt(III) cis-isomeer"><img alt="Diklorotetraammiinkoobalt(III) cis-isomeer" src="//upload.wikimedia.org/wikipedia/commons/thumb/b/be/Cis-dichlorotetraamminecobalt%28III%29.png/150px-Cis-dichlorotetraamminecobalt%28III%29.png" decoding="async" width="150" height="137" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/be/Cis-dichlorotetraamminecobalt%28III%29.png/225px-Cis-dichlorotetraamminecobalt%28III%29.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/be/Cis-dichlorotetraamminecobalt%28III%29.png/300px-Cis-dichlorotetraamminecobalt%28III%29.png 2x" data-file-width="1100" data-file-height="1004" /></a></span></div> <div class="gallerytext">Diklorotetraammiinkoobalt(III) cis-isomeer</div> </li> <li class="gallerybox" style="width: 185px"> <div class="thumb" style="width: 180px; height: 180px;"><span typeof="mw:File"><a href="/wiki/Fail:Trans-dichlorotetraamminecobalt(III).png" class="mw-file-description" title="Diklorotetraammiinkoobalt(III) trans-isomeer"><img alt="Diklorotetraammiinkoobalt(III) trans-isomeer" src="//upload.wikimedia.org/wikipedia/commons/thumb/5/56/Trans-dichlorotetraamminecobalt%28III%29.png/150px-Trans-dichlorotetraamminecobalt%28III%29.png" decoding="async" width="150" height="120" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/56/Trans-dichlorotetraamminecobalt%28III%29.png/225px-Trans-dichlorotetraamminecobalt%28III%29.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/5/56/Trans-dichlorotetraamminecobalt%28III%29.png/300px-Trans-dichlorotetraamminecobalt%28III%29.png 2x" data-file-width="1100" data-file-height="878" /></a></span></div> <div class="gallerytext">Diklorotetraammiinkoobalt(III) trans-isomeer</div> </li> </ul><p><b><a href="/wiki/Stereoisomeer" title="Stereoisomeer">Optiline isomeeria</a></b> </p><p>Esineb keerulisemate komplekside korral, kus ligandide vahekaugused on võrdsed, kuid isomeerid üksteise peegelpildid. </p><p><b>2)</b> <b>isomeeria, mis on omane ainult kompleksühenditele (struktuuriisomeeria):</b> </p><p><b>Ionisatsiooniisomeeria</b> </p><p>Anioonsed ligandid jaotuvad sise- ja välissfääri vahel erinevalt, näiteks [Co(NH<sub>3</sub>)<sub>4</sub>Cl<sub>2</sub>]Br ja [Co(NH<sub>3</sub>)<sub>4</sub>ClBr]Cl. </p><p><b>Hüdraatisomeerid</b> </p><p>Ionisatsiooniisomeeria erijuht, kus vee molekulid jagunevad erinevalt sise- ja välissfääri vahel. See avaldub <a href="/wiki/Kristallvesi" title="Kristallvesi">kristallveega</a> komplekside korral, kusjuures kompleksühendite värvus võib sellest tingitult olla erinev: [Cr(H<sub>2</sub>O)<sub>6</sub>]Cl<sub>3</sub> on violetne, [Cr(H<sub>2</sub>O)<sub>5</sub>Cl]Cl<sub>2</sub>⋅H<sub>2</sub>O on heleroheline ja [Cr(H<sub>2</sub>O)<sub>4</sub>Cl<sub>2</sub>]Cl⋅2H<sub>2</sub>O on tumeroheline. </p><p><b>Seoseisomeerid</b> </p><p>Esineb ligandide korral, kus ligand võib seostuda tsentraalaatomiga erinevate aatomite juurest, näiteks [CoCl(NO<sub>2</sub>)(NH<sub>3</sub>)<sub>4</sub>]<sup>+</sup> ja [CoCl(ONO)(NH<sub>3</sub>)<sub>4</sub>]<sup>+</sup> (esimesel juhul seostunud lämmastikuaatom, teisel aga hapnikuaatom). </p><p><b>Koordinatsiooniisomeerid</b> </p><p>Niisuguse isomeeria korral tsentraalaatomite koordinatsiooniarvud jäävad samaks, kuid vahetuvad ligandid, näiteks [Cr(NH<sub>3</sub>)<sub>6</sub>][Fe(CN)<sub>6</sub>] ja [Fe(NH<sub>3</sub>)<sub>6</sub>][Cr(CN)<sub>6</sub>].<sup id="cite_ref-:0_1-6" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Vaata_ka">Vaata ka</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Kompleks%C3%BChend&veaction=edit&section=5" title="Muuda alaosa "Vaata ka"" class="mw-editsection-visualeditor"><span>muuda</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Kompleks%C3%BChend&action=edit&section=5" title="Muuda alaosa "Vaata ka" lähteteksti"><span>muuda lähteteksti</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Kaksiksoolad" title="Kaksiksoolad">Kaksiksoolad</a></li> <li><a href="/wiki/Kelaadid" title="Kelaadid">Kelaadid</a></li> <li><a href="/wiki/Kelaatumine" title="Kelaatumine">Kelaatumine</a></li> <li><a href="/wiki/Supramolekulaarkompleks" class="mw-redirect" title="Supramolekulaarkompleks">Supramolekulaarkompleks</a></li> <li><a href="/wiki/Trans-efekt" title="Trans-efekt">Trans-efekt</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="Viited">Viited</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Kompleks%C3%BChend&veaction=edit&section=6" title="Muuda alaosa "Viited"" class="mw-editsection-visualeditor"><span>muuda</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Kompleks%C3%BChend&action=edit&section=6" title="Muuda alaosa "Viited" lähteteksti"><span>muuda lähteteksti</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-:0-1"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-:0_1-0">1,0</a></sup> <sup><a href="#cite_ref-:0_1-1">1,1</a></sup> <sup><a href="#cite_ref-:0_1-2">1,2</a></sup> <sup><a href="#cite_ref-:0_1-3">1,3</a></sup> <sup><a href="#cite_ref-:0_1-4">1,4</a></sup> <sup><a href="#cite_ref-:0_1-5">1,5</a></sup> <sup><a href="#cite_ref-:0_1-6">1,6</a></sup></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r6066747">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free a,.mw-parser-output .citation .cs1-lock-free a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited a,.mw-parser-output .id-lock-registration a,.mw-parser-output .citation .cs1-lock-limited a,.mw-parser-output .citation .cs1-lock-registration a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription a,.mw-parser-output .citation .cs1-lock-subscription a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:#d33}.mw-parser-output .cs1-visible-error{color:#d33}.mw-parser-output .cs1-maint{display:none;color:#3a3;margin-left:0.3em}.mw-parser-output .cs1-format{font-size:95%}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}</style><cite id="CITEREFTamm,_L.,_Tamm,_T.2005" class="citation book cs1">Tamm, L., Tamm, T. (2005). <i>Kompleksühendid</i>. Tartu: Tartu Ülikool.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Kompleks%C3%BChendid&rft.place=Tartu&rft.pub=Tartu+%C3%9Clikool&rft.date=2005&rft.au=Tamm%2C+L.%2C+Tamm%2C+T.&rfr_id=info%3Asid%2Fet.wikipedia.org%3AKompleks%C3%BChend" class="Z3988"></span><span class="cs1-maint citation-comment"><code class="cs1-code">{{<a href="/wiki/Mall:Raamatuviide" title="Mall:Raamatuviide">raamatuviide</a>}}</code>: CS1 hooldus: mitu nime: autorite loend (<a href="/wiki/Kategooria:CS1_hooldus:_mitu_nime:_autorite_loend" title="Kategooria:CS1 hooldus: mitu nime: autorite loend">link</a>)</span></span> </li> </ol></div></div> <!-- NewPP limit report Parsed by mw‐web.codfw.main‐5c59558b9d‐jbnw5 Cached time: 20241129073409 Cache expiry: 2592000 Reduced expiry: false Complications: [show‐toc] CPU time usage: 0.169 seconds Real time usage: 0.304 seconds Preprocessor visited node count: 207/1000000 Post‐expand include size: 1669/2097152 bytes Template argument size: 0/2097152 bytes Highest expansion depth: 6/100 Expensive parser function count: 0/500 Unstrip recursion depth: 1/20 Unstrip post‐expand size: 8131/5000000 bytes Lua time usage: 0.081/10.000 seconds Lua memory usage: 2100648/52428800 bytes Number of Wikibase entities loaded: 0/400 --> <!-- Transclusion expansion time report (%,ms,calls,template) 100.00% 125.724 1 -total 100.00% 125.724 1 Mall:Viited 94.26% 118.505 1 Mall:Raamatuviide --> <!-- Saved in parser cache with key etwiki:pcache:157800:|#|:idhash:canonical and timestamp 20241129073409 and revision id 6668857. 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