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<!DOCTYPE html><html><head><title>Catalysis in Petrochemical Processes - Google Libri</title><link rel="stylesheet" href="/books/css/_c5f9cd9e241b1329c3ee374578edd3c4/kl_viewport_kennedy_full_bundle.css" type="text/css" /><link rel="stylesheet"href="https://fonts.googleapis.com/css2?family=Product+Sans:wght@400"><script src="/books/javascript/v2_c5f9cd9e241b1329c3ee374578edd3c4__it.js"></script><script>_OC_Hooks = ["_OC_Page", "_OC_SearchReload", "_OC_TocReload", "_OC_EmptyFunc", "_OC_SearchPage", "_OC_QuotePage" ];for (var _OC_i = 0; _OC_i < _OC_Hooks.length; _OC_i++) {eval("var " + _OC_Hooks[_OC_i] + ";");}function _OC_InitHooks () {for (var i = 0; i < _OC_Hooks.length; i++) {var func = arguments[i];eval( _OC_Hooks[i] + " = func;");}}</script><link rel="canonical" href="https://books.google.com/books/about/Catalysis_in_Petrochemical_Processes.html?hl=it&id=MkD2JnDkZYYC"/><meta property="og:url" content="https://books.google.com/books/about/Catalysis_in_Petrochemical_Processes.html?hl=it&id=MkD2JnDkZYYC"/><meta name="title" content="Catalysis in Petrochemical Processes"/><meta name="description" content="The field of petrochemicals started some years ago with the simple addition reaction of water to propylene for the production of isopropyl alcohol. Currently, the petrochemical industry has become a multi-billion dollar enterprise which encompasses a wide field of chemical products. Almost all the basic organic reactions such as hydrogenation, alkylation, substitution, polymerization, etc. are utilized for the production of these chemicals. It may not, however, have been possible to establish this huge industry without the use of different catalysts. In other words, the great advancements in the catalytic area have supported the vast developments in the petrochemical field. In this book, we have adopted the idea of discussing the petrochemical industry from the point of view of reactants' activities and susceptibilities toward different catalysts. The book is thus classified according to the reaction type. This will eriable students and other users of the book to base their understanding of the petrochemical field on the fundamental principles learned in chemistry. How ever, the first chapter is aimed at establishing some basic facts on the petro chemical industry and its major uses. It discusses, without going into details, the raw materials used, the intermediates and the downstream products. The next eight chapters discuss in some detail the main reactions and the catalysts used for the production of chemicals and polymers from petroleum. 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href=\"https://books.google.com.sg/url?id=MkD2JnDkZYYC\u0026pg=PA178\u0026q=http://www.springer.com/shop\u0026clientid=ca-print-springer-kluwer_academic\u0026linkid=1\u0026usg=AOvVaw3zyJDUDtPS2rnCJN9vZLJS\u0026source=gbs_pub_info_r\"\u003eSpringer Science \u0026amp; Business Media\u003c/a\u003e","is_ebook":false,"volumeresult":{"has_flowing_text":false,"has_scanned_text":true,"can_download_pdf":false,"can_download_epub":false,"is_pdf_drm_enabled":false,"is_epub_drm_enabled":false},"publisher":"Springer Science \u0026 Business Media","publication_date":"1988.12.31","num_pages":216,"sample_url":"https://play.google.com/books/reader?id=MkD2JnDkZYYC\u0026hl=it\u0026source=gbs_vpt_hover","synposis":"The field of petrochemicals started some years ago with the simple addition reaction of water to propylene for the production of isopropyl alcohol. Currently, the petrochemical industry has become a multi-billion dollar enterprise which encompasses a wide field of chemical products. Almost all the basic organic reactions such as hydrogenation, alkylation, substitution, polymerization, etc. are utilized for the production of these chemicals. It may not, however, have been possible to establish this huge industry without the use of different catalysts. In other words, the great advancements in the catalytic area have supported the vast developments in the petrochemical field. In this book, we have adopted the idea of discussing the petrochemical industry from the point of view of reactants' activities and susceptibilities toward different catalysts. The book is thus classified according to the reaction type. This will eriable students and other users of the book to base their understanding of the petrochemical field on the fundamental principles learned in chemistry. How ever, the first chapter is aimed at establishing some basic facts on the petro chemical industry and its major uses. It discusses, without going into details, the raw materials used, the intermediates and the downstream products. The next eight chapters discuss in some detail the main reactions and the catalysts used for the production of chemicals and polymers from petroleum. The last chapter is devoted to a discussion of some of the practical techniques used in the catalytic field.","my_library_url":"https://www.google.com/accounts/Login?service=print\u0026continue=https://books.google.com.sg/books%3Fop%3Dlibrary%26hl%3Dit\u0026hl=it","is_magazine":false,"is_public_domain":false},{"enableUserFeedbackUI":true,"pseudocontinuous":true,"is_cobrand":false,"sign_in_url":"https://www.google.com/accounts/Login?service=print\u0026continue=https://books.google.com.sg/books%3Fid%3DMkD2JnDkZYYC%26q%3Dpolypropylene%26hl%3Dit%26source%3Dgbs_word_cloud_r\u0026hl=it","isEntityPageViewport":false,"showViewportOnboarding":false,"showViewportPlainTextOnboarding":false},{"page":[{"pid":"PA178","highlights":[{"X":200,"Y":72,"W":119,"H":10},{"X":96,"Y":95,"W":87,"H":15},{"X":55,"Y":462,"W":88,"H":13},{"X":174,"Y":516,"W":86,"H":14},{"X":134,"Y":625,"W":87,"H":14},{"X":74,"Y":643,"W":87,"H":14},{"X":451,"Y":643,"W":86,"H":14},{"X":195,"Y":717,"W":70,"H":13}],"flags":8,"order":193,"vq":"polypropylene"}]},null,{"number_of_results":14,"search_results":[{"page_id":"PR8","page_number":"viii","snippet_text":"... \u003cb\u003ePolypropylene\u003c/b\u003e 9.5.6 . Polybutadiene 9.5.7 . Polyisoprene 178 179 179 9.5.8 . Trans - Polypentamer 9.5.9 . Polychloroprene 180 180 References Chapter 10 / Experimental Techniques in Catalysis 10.1 . Introduction 10.2 . Preparation of\u0026nbsp;..."},{"page_id":"PA11","page_number":"11","snippet_text":"... \u003cb\u003ePolypropylene\u003c/b\u003e oxide Polyurethanes Flexible \u0026amp; Rigid foam Cat . oxid . CH2 - CH - CH2 Oxid . Acrylic acid Plastics Acrolein Resins Hydrodimer . HOOC ( CH , ) , COOH Nylon 6/6 Adipic acid CH3 Polym . CH2 = CH - CH3 + CH2CH + \u003cb\u003ePolypropylene\u003c/b\u003e\u0026nbsp;..."},{"page_id":"PA21","page_number":"21","snippet_text":"... \u003cb\u003epolypropylene\u003c/b\u003e or polyvinylchloride , and inorganic polymers such as silica , alumina or zeolites are used as heterogenizing agents . The catalyst metal atom is anchored to these CATALYSTS USED IN PETROCHEMICAL PROCESSES 21 2.1.2\u0026nbsp;..."},{"page_id":"PA145","page_number":"145","snippet_text":"... \u003cb\u003epolypropylene\u003c/b\u003e glycol or other propoxylated products by an acid- or base - catalyzed addition of propylene glycol or other polyfunctional alcohols , respectively . The propoxylated alcohols are used for the production of polyurethanes\u0026nbsp;..."},{"page_id":"PA160","page_number":"160","snippet_text":"... \u003cb\u003epolypropylene\u003c/b\u003e made by addition polymerization . 9.2.3 . ELASTOMERS Elastomers differ from plastics and fibers in the presence of residual double bonds in the backbone of the polymer . Unsaturation provides some centers for weak\u0026nbsp;..."},{"page_id":"PA161","page_number":"161","snippet_text":"... \u003cb\u003ePolypropylene\u003c/b\u003e PP Polyolefin CH3 -CH2 - CH- 175 ( Tm ) 0.902 P \u0026amp; CH , Polyvinyl acetate PVA Vinyl -CH2 - CH- • Сосн , OCH , Polymethylmethacrylate Acrylic -CH2 - C- CH3 Polyhexamethylenediamide Nylon 66 Polyamide CHINH CH —NH- ( CH2 )\u0026nbsp;..."},{"page_id":"PA169","page_number":"169","snippet_text":"... \u003cb\u003epolypropylene\u003c/b\u003e was the major product . Propylene polymerized with free radical and some ionic initiators can produce a mixture of three different stereo forms ( Fig . 9-1 ) . b - a - Atactic : An irregular form where the methyl groups\u0026nbsp;..."},{"page_id":"PA171","page_number":"171","snippet_text":"... \u003cb\u003epolypropylene\u003c/b\u003e . The stereospecific nature of these catalysts has been explained by the Cosse - Arlman model which provides information regarding the crystalline nature of a - TiCl , as a hexagonal close packing . This structure has\u0026nbsp;..."},{"page_id":"PA175","page_number":"175","snippet_text":"... \u003cb\u003epolypropylene\u003c/b\u003e for plastics , polybutadiene , polyisoprene and trans- polypentamer for rubber . A brief discussion of the production of these polymers is given below . 9.5.1 . PRODUCTION OF 1 - BUTENE Ethylene may be dimerized to 1\u0026nbsp;..."},{"page_id":"PA177","page_number":"177","snippet_text":"... \u003cb\u003ePOLYPROPYLENE\u003c/b\u003e Isotactic \u003cb\u003epolypropylene\u003c/b\u003e is produced by CATALYTIC POLYMERIZATION 177 9.5.4. PRODUCTION OF LINEAR POLYETHYLENES."},{"page_id":"PA178","page_number":"178","snippet_text":"M.S. Matar, M.J. Mirbach, H.A. Tayim. 9.5.5 . PRODUCTION OF \u003cb\u003ePOLYPROPYLENE\u003c/b\u003e Isotactic \u003cb\u003epolypropylene\u003c/b\u003e is produced by the use of a Ziegler type catalyst . The stereoregular polymer is highly crystalline . Polymerization may be carried in the\u0026nbsp;..."},{"page_id":"PA179","page_number":"179","snippet_text":"... \u003cb\u003ePolypropylene\u003c/b\u003e fibers are used in tufted carpets , upholstery fabrics and underwear blends . 9.5.6 . POLYBUTADIENE Butadiene can be polymerized using different initiator types . When free radicals are used the addition is predominantly a\u0026nbsp;..."},{"page_id":"PA181","page_number":"181","snippet_text":"... \u003cb\u003ePolypropylene\u003c/b\u003e - Process , Selection Criteria \u0026#39; , Hydrocarbon Processing , Nov. 1984 , pp . 113-117 . Gates , B. , Katzer , J. , and Schuit , G .: Chemistry of Catalytic Processes , McGraw - Hill Book Co. , New York , 1979 . Hatch , L\u0026nbsp;..."},{"page_id":"PA199","page_number":"199","snippet_text":"... \u003cb\u003ePolypropylene\u003c/b\u003e isotactic , mechanism 171 production 178 properties 178 ( t ) tactic forms 169 ( f ) \u003cb\u003ePolypropylene\u003c/b\u003e glycol 145 from propylene oxide 145 Polystyrene 161 polymer - bound metal complexes from 22 Polyurethane 76 Polyvinyl\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=MkD2JnDkZYYC\u0026pg=PA199\u0026vq=polypropylene\u0026hl=it"}],"search_query_escaped":"polypropylene"},{});</script></div></div></div><script>(function() {var href = window.location.href;if (href.indexOf('?') !== -1) {var parameters = href.split('?')[1].split('&');for (var i = 0; i < parameters.length; i++) {var param = parameters[i].split('=');if (param[0] == 'focus') {var elem = document.getElementById(param[1]);if (elem) {elem.focus();}}}}})();</script>