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Comparison of Transparent Nickel Doped Cobalt Sulfide and Platinum Counter Electrodes Used in QuasiSolid State Dye Sensitized Solar Cells

<?xml version="1.0" encoding="UTF-8"?> <article key="pdf/10002077" mdate="2015-07-04 00:00:00"> <author>Dimitra Sygkridou and Dimitrios Karageorgopoulos and Elias Stathatos and Evangelos Vitoratos</author> <title>Comparison of Transparent Nickel Doped Cobalt Sulfide and Platinum Counter Electrodes Used in QuasiSolid State Dye Sensitized Solar Cells</title> <pages>606 - 611</pages> <year>2015</year> <volume>9</volume> <number>6</number> <journal>International Journal of Electrical and Computer Engineering</journal> <ee>https://publications.waset.org/pdf/10002077</ee> <url>https://publications.waset.org/vol/102</url> <publisher>World Academy of Science, Engineering and Technology</publisher> <abstract>Transparent nickel doped cobalt sulfide was fabricated on a SnO2F electrode and tested as an efficient electrocatalyst and as an alternative to the expensive platinum counter electrode. In order to investigate how this electrode could affect the electrical characteristics of a dyesensitized solar cell, we manufactured cells with the same TiO2 photoanode sensitized with dye (N719) and employing the same quasisolid electrolyte, altering only the counter electrode used. The cells were electrically and electrochemically characterized and it was observed that the ones with the Ni doped CoS2 outperformed the efficiency of the cells with the Pt counter electrode (3.76 and 3.44 respectively). Particularly, the higher efficiency of the cells with the Ni doped CoS2 counter electrode (CE) is mainly because of the enhanced photocurrent density which is attributed to the enhanced electrocatalytic ability of the CE and the low charge transfer resistance at the CEelectrolyte interface.</abstract> <index>Open Science Index 102, 2015</index> </article>