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酸碱电子理论 - 维基百科,自由的百科全书

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id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">序言</div> </a> </li> <li id="toc-路易斯酸" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#路易斯酸"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>路易斯酸</span> </div> </a> <button aria-controls="toc-路易斯酸-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>开关路易斯酸子章节</span> </button> <ul id="toc-路易斯酸-sublist" class="vector-toc-list"> <li id="toc-物理性质" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#物理性质"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.1</span> <span>物理性质</span> </div> </a> <ul id="toc-物理性质-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-化学性质" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#化学性质"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.2</span> <span>化学性质</span> </div> </a> <ul id="toc-化学性质-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-酸根型配合物" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#酸根型配合物"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.3</span> <span>酸根型配合物</span> </div> </a> <ul id="toc-酸根型配合物-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-路易斯鹼" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#路易斯鹼"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>路易斯鹼</span> </div> </a> <ul id="toc-路易斯鹼-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-优缺点" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#优缺点"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>优缺点</span> </div> </a> <button aria-controls="toc-优缺点-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>开关优缺点子章节</span> </button> <ul id="toc-优缺点-sublist" class="vector-toc-list"> <li id="toc-优点" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#优点"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.1</span> <span>优点</span> </div> </a> <ul id="toc-优点-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-缺点" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#缺点"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.2</span> <span>缺点</span> </div> </a> <ul id="toc-缺点-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-参考资料" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考资料"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>参考资料</span> </div> </a> <ul id="toc-参考资料-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-延伸閱讀" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#延伸閱讀"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>延伸閱讀</span> </div> </a> <ul id="toc-延伸閱讀-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-参见" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参见"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>参见</span> </div> </a> <ul id="toc-参见-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">酸碱电子理论</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。31种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-31" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">31种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-af mw-list-item"><a href="https://af.wikipedia.org/wiki/Lewis-suur_en_-basis" title="Lewis-suur en -basis – 南非荷兰语" lang="af" hreflang="af" data-title="Lewis-suur en -basis" data-language-autonym="Afrikaans" data-language-local-name="南非荷兰语" class="interlanguage-link-target"><span>Afrikaans</span></a></li><li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%A3%D8%AD%D9%85%D8%A7%D8%B6_%D9%88%D9%82%D9%88%D8%A7%D8%B9%D8%AF_%D9%84%D9%88%D9%8A%D8%B3" title="أحماض وقواعد لويس – 阿拉伯语" lang="ar" hreflang="ar" data-title="أحماض وقواعد لويس" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-bn mw-list-item"><a href="https://bn.wikipedia.org/wiki/%E0%A6%B2%E0%A7%81%E0%A6%87%E0%A6%B8_%E0%A6%85%E0%A6%AE%E0%A7%8D%E0%A6%B2_%E0%A6%93_%E0%A6%95%E0%A7%8D%E0%A6%B7%E0%A6%BE%E0%A6%B0" title="লুইস অম্ল ও ক্ষার – 孟加拉语" lang="bn" hreflang="bn" data-title="লুইস অম্ল ও ক্ষার" data-language-autonym="বাংলা" data-language-local-name="孟加拉语" class="interlanguage-link-target"><span>বাংলা</span></a></li><li class="interlanguage-link interwiki-bs mw-list-item"><a href="https://bs.wikipedia.org/wiki/Lewisova_kiselina_i_baza" title="Lewisova kiselina i baza – 波斯尼亚语" lang="bs" hreflang="bs" data-title="Lewisova kiselina i baza" data-language-autonym="Bosanski" data-language-local-name="波斯尼亚语" class="interlanguage-link-target"><span>Bosanski</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Teoria_%C3%A0cid-base_de_Lewis" title="Teoria àcid-base de Lewis – 加泰罗尼亚语" lang="ca" hreflang="ca" data-title="Teoria àcid-base de Lewis" data-language-autonym="Català" data-language-local-name="加泰罗尼亚语" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Lewisova_teorie_kyselin_a_z%C3%A1sad" title="Lewisova teorie kyselin a zásad – 捷克语" lang="cs" hreflang="cs" data-title="Lewisova teorie kyselin a zásad" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Lewis-S%C3%A4ure-Base-Konzept" title="Lewis-Säure-Base-Konzept – 德语" lang="de" hreflang="de" data-title="Lewis-Säure-Base-Konzept" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%9F%CE%BE%CE%AD%CE%B1_%CE%BA%CE%B1%CE%B9_%CE%B2%CE%AC%CF%83%CE%B5%CE%B9%CF%82_%CE%BA%CE%B1%CF%84%CE%AC_%CE%9B%CE%B9%CE%BF%CF%8D%CE%B9%CF%82" title="Οξέα και βάσεις κατά Λιούις – 希腊语" lang="el" hreflang="el" data-title="Οξέα και βάσεις κατά Λιούις" data-language-autonym="Ελληνικά" data-language-local-name="希腊语" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Lewis_acids_and_bases" title="Lewis acids and bases – 英语" lang="en" hreflang="en" data-title="Lewis acids and bases" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Teor%C3%ADa_%C3%A1cido-base_de_Lewis" title="Teoría ácido-base de Lewis – 西班牙语" lang="es" hreflang="es" data-title="Teoría ácido-base de Lewis" data-language-autonym="Español" data-language-local-name="西班牙语" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-et mw-list-item"><a href="https://et.wikipedia.org/wiki/Lewisi_happed_ja_alused" title="Lewisi happed ja alused – 爱沙尼亚语" lang="et" hreflang="et" data-title="Lewisi happed ja alused" data-language-autonym="Eesti" data-language-local-name="爱沙尼亚语" class="interlanguage-link-target"><span>Eesti</span></a></li><li class="interlanguage-link interwiki-eu mw-list-item"><a href="https://eu.wikipedia.org/wiki/Lewisen_azido_eta_baseak" title="Lewisen azido eta baseak – 巴斯克语" lang="eu" hreflang="eu" data-title="Lewisen azido eta baseak" data-language-autonym="Euskara" data-language-local-name="巴斯克语" class="interlanguage-link-target"><span>Euskara</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%A7%D8%B3%DB%8C%D8%AF_%D9%88_%D8%A8%D8%A7%D8%B2_%D9%84%D9%88%DB%8C%DB%8C%D8%B3" title="اسید و باز لوییس – 波斯语" lang="fa" hreflang="fa" data-title="اسید و باز لوییس" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Acides_et_bases_de_Lewis" title="Acides et bases de Lewis – 法语" lang="fr" hreflang="fr" data-title="Acides et bases de Lewis" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%B2%E0%A5%81%E0%A4%88%E0%A4%B8_%E0%A4%95%E0%A5%87_%E0%A4%85%E0%A4%AE%E0%A5%8D%E0%A4%B2_%E0%A4%94%E0%A4%B0_%E0%A4%95%E0%A5%8D%E0%A4%B7%E0%A4%BE%E0%A4%B0" title="लुईस के अम्ल और क्षार – 印地语" lang="hi" hreflang="hi" data-title="लुईस के अम्ल और क्षार" data-language-autonym="हिन्दी" data-language-local-name="印地语" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-hr mw-list-item"><a href="https://hr.wikipedia.org/wiki/Lewisove_kiseline_i_baze" title="Lewisove kiseline i baze – 克罗地亚语" lang="hr" hreflang="hr" data-title="Lewisove kiseline i baze" data-language-autonym="Hrvatski" data-language-local-name="克罗地亚语" class="interlanguage-link-target"><span>Hrvatski</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Asam_dan_basa_Lewis" title="Asam dan basa Lewis – 印度尼西亚语" lang="id" hreflang="id" data-title="Asam dan basa Lewis" data-language-autonym="Bahasa Indonesia" data-language-local-name="印度尼西亚语" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Teoria_acido-base_di_Lewis" title="Teoria acido-base di Lewis – 意大利语" lang="it" hreflang="it" data-title="Teoria acido-base di Lewis" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%83%AB%E3%82%A4%E3%82%B9%E3%81%AE%E7%90%86%E8%AB%96" title="ルイスの理論 – 日语" lang="ja" hreflang="ja" data-title="ルイスの理論" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-lv mw-list-item"><a href="https://lv.wikipedia.org/wiki/L%C5%ABisa_sk%C4%81bes_un_b%C4%81zes" title="Lūisa skābes un bāzes – 拉脱维亚语" lang="lv" hreflang="lv" data-title="Lūisa skābes un bāzes" data-language-autonym="Latviešu" data-language-local-name="拉脱维亚语" class="interlanguage-link-target"><span>Latviešu</span></a></li><li class="interlanguage-link interwiki-ml mw-list-item"><a href="https://ml.wikipedia.org/wiki/%E0%B4%B2%E0%B5%82%E0%B4%AF%E0%B4%BF%E0%B4%B8%E0%B5%8D_%E0%B4%85%E0%B4%AE%E0%B5%8D%E0%B4%B2%E0%B4%99%E0%B5%8D%E0%B4%99%E0%B4%B3%E0%B5%81%E0%B4%82_%E0%B4%B2%E0%B5%82%E0%B4%AF%E0%B4%BF%E0%B4%B8%E0%B5%8D_%E0%B4%95%E0%B5%8D%E0%B4%B7%E0%B4%BE%E0%B4%B0%E0%B4%99%E0%B5%8D%E0%B4%99%E0%B4%B3%E0%B5%81%E0%B4%82" title="ലൂയിസ് അമ്ലങ്ങളും ലൂയിസ് ക്ഷാരങ്ങളും – 马拉雅拉姆语" lang="ml" hreflang="ml" data-title="ലൂയിസ് അമ്ലങ്ങളും ലൂയിസ് ക്ഷാരങ്ങളും" data-language-autonym="മലയാളം" data-language-local-name="马拉雅拉姆语" class="interlanguage-link-target"><span>മലയാളം</span></a></li><li class="interlanguage-link interwiki-no mw-list-item"><a href="https://no.wikipedia.org/wiki/Lewis_syrer_og_baser" title="Lewis syrer og baser – 书面挪威语" lang="nb" hreflang="nb" data-title="Lewis syrer og baser" data-language-autonym="Norsk bokmål" data-language-local-name="书面挪威语" class="interlanguage-link-target"><span>Norsk bokmål</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Teoria_kwas%C3%B3w_i_zasad_Lewisa" title="Teoria kwasów i zasad Lewisa – 波兰语" lang="pl" hreflang="pl" data-title="Teoria kwasów i zasad Lewisa" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Teoria_%C3%A1cido-base_de_Lewis" title="Teoria ácido-base de Lewis – 葡萄牙语" lang="pt" hreflang="pt" data-title="Teoria ácido-base de Lewis" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Lewisove_kiseline_i_baze" title="Lewisove kiseline i baze – 塞尔维亚-克罗地亚语" lang="sh" hreflang="sh" data-title="Lewisove kiseline i baze" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="塞尔维亚-克罗地亚语" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sl mw-list-item"><a href="https://sl.wikipedia.org/wiki/Lewisova_teorija_kislin_in_baz" title="Lewisova teorija kislin in baz – 斯洛文尼亚语" lang="sl" hreflang="sl" data-title="Lewisova teorija kislin in baz" data-language-autonym="Slovenščina" data-language-local-name="斯洛文尼亚语" class="interlanguage-link-target"><span>Slovenščina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Luisove_kiseline_i_baze" title="Luisove kiseline i baze – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Luisove kiseline i baze" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%B2%E0%AF%82%E0%AE%AF%E0%AE%BF%E0%AE%9A%E0%AF%81_%E0%AE%85%E0%AE%AE%E0%AE%BF%E0%AE%B2%E0%AE%99%E0%AF%8D%E0%AE%95%E0%AE%B3%E0%AF%81%E0%AE%AE%E0%AF%8D_%E0%AE%95%E0%AE%BE%E0%AE%B0%E0%AE%99%E0%AF%8D%E0%AE%95%E0%AE%B3%E0%AF%81%E0%AE%AE%E0%AF%8D" title="லூயிசு அமிலங்களும் காரங்களும் – 泰米尔语" lang="ta" hreflang="ta" data-title="லூயிசு அமிலங்களும் காரங்களும்" data-language-autonym="தமிழ்" data-language-local-name="泰米尔语" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Lewis_asit_ve_baz%C4%B1" title="Lewis asit ve bazı – 土耳其语" lang="tr" hreflang="tr" data-title="Lewis asit ve bazı" data-language-autonym="Türkçe" data-language-local-name="土耳其语" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-ur mw-list-item"><a href="https://ur.wikipedia.org/wiki/%D9%84%DB%8C%D9%88%D8%B3_%D8%AA%DB%8C%D8%B2%D8%A7%D8%A8_%D8%A7%D9%88%D8%B1_%D8%A7%D8%B3%D8%A7%D8%B3" title="لیوس تیزاب اور اساس – 乌尔都语" lang="ur" hreflang="ur" data-title="لیوس تیزاب اور اساس" data-language-autonym="اردو" data-language-local-name="乌尔都语" class="interlanguage-link-target"><span>اردو</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Acid_v%C3%A0_base_Lewis" title="Acid và base Lewis – 越南语" lang="vi" hreflang="vi" 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.ambox-style{border-left-color:#fc3!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-move{border-left-color:#9932cc!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-protection{border-left-color:#a2a9b1!important}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ambox{border-left-color:#36c!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-speedy,html.skin-theme-clientpref-os .mw-parser-output .ambox-delete{border-left-color:#b32424!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-speedy{background-color:#300!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-content{border-left-color:#f28500!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-style{border-left-color:#fc3!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-move{border-left-color:#9932cc!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-protection{border-left-color:#a2a9b1!important}}</style><table class="box-Refimprove plainlinks metadata ambox ambox-content" role="presentation"><tbody><tr><td class="mbox-image"><div style="width:52px"><span typeof="mw:File"><a href="/wiki/File:Tango-nosources.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/4/4e/Tango-nosources.svg/45px-Tango-nosources.svg.png" decoding="async" width="45" height="45" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/4e/Tango-nosources.svg/68px-Tango-nosources.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/4e/Tango-nosources.svg/90px-Tango-nosources.svg.png 2x" data-file-width="48" data-file-height="48" /></a></span></div></td><td class="mbox-text"><div class="mbox-text-span">此條目<b>需要补充更多<a href="/wiki/Wikipedia:%E5%88%97%E6%98%8E%E6%9D%A5%E6%BA%90" title="Wikipedia:列明来源">来源</a></b>。<span class="hide-when-compact"></span> <small 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href="//www.google.com/search?tbm=nws&amp;q=&amp;as_src=-newswire+-wire+-presswire+-PR+-press+-release+-wikipedia&amp;q=%22%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA%22">新闻</a>、<a rel="nofollow" class="external text" href="//books.google.com/books?&amp;as_brr=0&amp;as_pub=-icon&amp;q=%22%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA%22">书籍</a>、<a rel="nofollow" class="external text" href="//scholar.google.com/scholar?&amp;q=%22%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA%22">学术</a>、<a rel="nofollow" class="external text" href="//www.google.com/search?tbm=isch&amp;safe=off&amp;q=%22%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA%22">图像</a></span>),以检查网络上是否存在该主题的更多可靠来源(<a href="/wiki/Wikipedia:%E5%8F%AF%E9%9D%A0%E6%9D%A5%E6%BA%90" title="Wikipedia:可靠来源">判定指引</a>)。</small></span><span class="hide-when-compact"></span></div></td></tr></tbody></table> <div id="noteTA-f683ec12" class="noteTA"><div class="noteTA-group"><div 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.mw-parser-output .sidebar:not(.notheme) .sidebar-title,html.skin-theme-clientpref-night .mw-parser-output .sidebar:not(.notheme) .sidebar-title-with-pretitle,html.skin-theme-clientpref-night .mw-parser-output .sidebar:not(.notheme) .sidebar-heading,html.skin-theme-clientpref-night .mw-parser-output .sidebar:not(.notheme) .sidebar-above,html.skin-theme-clientpref-night .mw-parser-output .sidebar:not(.notheme) .sidebar-below{background:inherit!important;color:inherit!important;border-color:#54595d!important}html.skin-theme-clientpref-night .mw-parser-output .sidebar a:not(.new):not(.mw-selflink):link{color:var(--color-progressive)!important}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-list-title,html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-subgroup,html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-pretitle,html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-title,html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-title-with-pretitle,html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-heading,html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-above,html.skin-theme-clientpref-os .mw-parser-output .sidebar:not(.notheme) .sidebar-below{background:inherit!important;color:inherit!important;border-color:#54595d!important}html.skin-theme-clientpref-os .mw-parser-output .sidebar a:not(.new):not(.mw-selflink):link{color:var(--color-progressive)!important}}@media print{body.ns-0 .mw-parser-output .sidebar{display:none!important}}</style><table class="sidebar nomobile nowraplinks" style="width:15.0 em;"><tbody><tr><th class="sidebar-title" style="background:#d3d3d3;"><a href="/wiki/%E9%85%B8" title="酸">酸</a><a href="/wiki/%E7%A2%B1" title="碱">碱</a>化学</th></tr><tr><td class="sidebar-image"><span typeof="mw:File"><a href="/wiki/File:Acetic-acid-dissociation-3D-balls.png" class="mw-file-description" title="Diagrammatic representation of the dissociation of acetic acid in aqueous solution to for acetate and hydronium ions."><img alt="Diagrammatic representation of the dissociation of acetic acid in aqueous solution to for acetate and hydronium ions." src="//upload.wikimedia.org/wikipedia/commons/thumb/9/96/Acetic-acid-dissociation-3D-balls.png/220px-Acetic-acid-dissociation-3D-balls.png" decoding="async" width="220" height="52" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/96/Acetic-acid-dissociation-3D-balls.png/330px-Acetic-acid-dissociation-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/96/Acetic-acid-dissociation-3D-balls.png/440px-Acetic-acid-dissociation-3D-balls.png 2x" data-file-width="2150" data-file-height="513" /></a></span></td></tr><tr><td class="sidebar-content" style="padding:0.2em 0 0.75em;"> <div class="plainlist"> <ul><li><a href="/wiki/%E9%85%B8%E5%BA%A6%E7%B3%BB%E6%95%B0" title="酸度系数">酸度系数</a></li> <li><a href="/wiki/%E9%85%B8%E9%B9%BC%E8%90%83%E5%8F%96" title="酸鹼萃取">酸鹼萃取</a></li> <li><a href="/wiki/%E9%85%B8%E7%A2%B1%E7%90%86%E8%AE%BA" title="酸碱理论">酸碱理论</a></li> <li><a href="/wiki/%E9%85%B8%E9%B9%BC%E4%B8%AD%E5%92%8C%E6%BB%B4%E5%AE%9A" title="酸鹼中和滴定">酸鹼中和滴定</a></li> <li><a href="/wiki/%E8%A7%A3%E7%A6%BB%E5%B8%B8%E6%95%B0" title="解离常数">解离常數</a></li> <li><a href="/wiki/%E7%BC%93%E5%86%B2%E6%BA%B6%E6%B6%B2" title="缓冲溶液">缓冲溶液</a></li> <li><a href="/wiki/PH%E5%80%BC" title="PH值">pH</a></li> <li><span class="ilh-all" data-orig-title="質子亲和力" data-lang-code="en" data-lang-name="英语" data-foreign-title="Proton affinity"><span class="ilh-page"><a href="/w/index.php?title=%E8%B3%AA%E5%AD%90%E4%BA%B2%E5%92%8C%E5%8A%9B&amp;action=edit&amp;redlink=1" class="new" title="質子亲和力(页面不存在)">質子亲和力</a></span><span class="noprint ilh-comment">(<span class="ilh-lang">英语</span><span class="ilh-colon">:</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Proton_affinity" class="extiw" title="en:Proton affinity"><span lang="en" dir="auto">Proton affinity</span></a></span>)</span></span></li> <li><a href="/wiki/%E5%85%A9%E6%80%A7_(%E5%8C%96%E5%AD%B8)" title="兩性 (化學)">兩性物質</a></li> <li><a href="/wiki/%E6%B0%B4%E7%9A%84%E7%94%B5%E7%A6%BB" title="水的电离">水的自偶電離</a></li> <li><a href="/wiki/%E9%85%B8%E7%A2%B1%E8%B4%A8%E5%AD%90%E7%90%86%E8%AE%BA" title="酸碱质子理论">酸碱质子理论</a></li></ul> </div></td> </tr><tr><th class="sidebar-heading" style="background:#e5e5e5;"> <a href="/wiki/%E9%85%B8" title="酸">酸</a></th></tr><tr><td class="sidebar-content" style="padding:0.2em 0 0.75em;"> <div class="hlist"> <ul><li><a href="/wiki/%E9%85%B8%E7%A2%B1%E8%B4%A8%E5%AD%90%E7%90%86%E8%AE%BA" title="酸碱质子理论">布仑斯惕酸</a></li> <li><a class="mw-selflink selflink">路易斯酸</a></li> <li><a href="/wiki/%E6%97%A0%E6%9C%BA%E9%85%B8" title="无机酸">无机酸</a></li> <li><br /><a href="/wiki/%E6%9C%89%E6%9C%BA%E9%85%B8" title="有机酸">有机酸</a></li> <li><a href="/wiki/%E5%BC%B1%E9%85%B8" title="弱酸">弱酸</a></li> <li><a href="/wiki/%E5%BC%BA%E9%85%B8" title="强酸">強酸</a></li> <li><a href="/wiki/%E8%B6%85%E5%BC%BA%E9%85%B8" title="超强酸">超强酸</a></li></ul> </div></td> </tr><tr><th class="sidebar-heading" style="background:#e5e5e5;"> <a href="/wiki/%E7%A2%B1" title="碱">碱</a></th></tr><tr><td class="sidebar-content" style="padding:0.2em 0 0.75em;"> <div class="hlist"> <ul><li><a href="/wiki/%E9%85%B8%E7%A2%B1%E8%B4%A8%E5%AD%90%E7%90%86%E8%AE%BA" title="酸碱质子理论">布仑斯惕鹼</a></li> <li><a class="mw-selflink selflink">路易斯鹼</a></li> <li><a href="/wiki/%E9%9D%9E%E8%A6%AA%E6%A0%B8%E9%B9%BC" title="非親核鹼">非親核鹼</a></li> <li><br /><a href="/wiki/%E6%9C%89%E6%A9%9F%E9%B9%BC" title="有機鹼">有機鹼</a></li> <li><a href="/wiki/%E5%BC%B1%E7%A2%B1" title="弱碱">弱鹼</a></li> <li><a href="/wiki/%E7%A2%B1" title="碱">強鹼</a></li> <li><a href="/wiki/%E8%B6%85%E5%BC%BA%E7%A2%B1" title="超强碱">超强碱</a></li></ul> </div></td> </tr><tr><td class="sidebar-navbar" style="line-height:1.6"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><style data-mw-deduplicate="TemplateStyles:r84244141">.mw-parser-output .navbar{display:inline;font-weight:normal}.mw-parser-output .navbar-collapse{float:left;text-align:left}.mw-parser-output .navbar-boxtext{word-spacing:0}.mw-parser-output .navbar ul{display:inline-block;white-space:nowrap;line-height:inherit}.mw-parser-output .navbar-brackets::before{margin-right:-0.125em;content:"[ "}.mw-parser-output .navbar-brackets::after{margin-left:-0.125em;content:" ]"}.mw-parser-output .navbar li{word-spacing:-0.125em}.mw-parser-output .navbar a>span,.mw-parser-output .navbar a>abbr{text-decoration:inherit}.mw-parser-output .navbar-mini abbr{font-variant:small-caps;border-bottom:none;text-decoration:none;cursor:inherit}.mw-parser-output .navbar-ct-full{font-size:110%;margin:0 8em}.mw-parser-output .navbar-ct-mini{font-size:110%;margin:0 5em}html.skin-theme-clientpref-night .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}@media(prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}}@media print{.mw-parser-output .navbar{display:none!important}}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E9%85%B8%E9%B9%BC" title="Template:酸鹼"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E9%85%B8%E9%B9%BC" title="Template talk:酸鹼"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E9%85%B8%E9%B9%BC" title="Special:编辑页面/Template:酸鹼"><abbr title="编辑该模板">编</abbr></a></li></ul></div></td></tr></tbody></table> <p><b>酸碱电子理论</b>,也称<b>广义酸碱理论</b>、<b>路易斯酸碱理论</b>,是1923年<a href="/wiki/%E7%BE%8E%E5%9B%BD" title="美国">美国</a><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%AE%B6" title="化学家">化学家</a><a href="/wiki/%E5%90%89%E5%B0%94%E4%BC%AF%E7%89%B9%C2%B7%E8%B7%AF%E6%98%93%E6%96%AF" class="mw-redirect" title="吉尔伯特·路易斯">吉尔伯特·路易斯</a>提出的一种<a href="/wiki/%E9%85%B8%E7%A2%B1%E7%90%86%E8%AE%BA" title="酸碱理论">酸碱理论</a>。该理论认为:凡是可以接受外来<a href="/wiki/%E9%9B%BB%E5%AD%90%E5%B0%8D" title="電子對">电子对</a>的<a href="/wiki/%E5%88%86%E5%AD%90" title="分子">分子</a>、<a href="/wiki/%E5%9F%BA%E5%9B%A2" class="mw-redirect" title="基团">基团</a>或<a href="/wiki/%E7%A6%BB%E5%AD%90" title="离子">离子</a>为酸(路易斯酸,L酸);凡可以提供电子对的分子、基团或离子为碱(路易斯碱,L碱)。因為跳脫了限定氫離子與氫氧根的酸鹼概念,这种理论包含的酸碱范围很广,但是,它对确定酸碱的相对强弱来说,没有统一的标度,对酸碱的反应方向难以判断。后来,<span class="ilh-all" data-orig-title="拉爾夫·皮爾森" data-lang-code="en" data-lang-name="英语" data-foreign-title="Ralph Pearson"><span class="ilh-page"><a href="/w/index.php?title=%E6%8B%89%E7%88%BE%E5%A4%AB%C2%B7%E7%9A%AE%E7%88%BE%E6%A3%AE&amp;action=edit&amp;redlink=1" class="new" title="拉爾夫·皮爾森(页面不存在)">拉爾夫·皮爾森</a></span><span class="noprint ilh-comment">(<span class="ilh-lang">英语</span><span class="ilh-colon">:</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Ralph_Pearson" class="extiw" title="en:Ralph Pearson"><span lang="en" dir="auto">Ralph Pearson</span></a></span>)</span></span>提出的<a href="/wiki/%E8%BD%AF%E7%A1%AC%E9%85%B8%E7%A2%B1%E7%90%86%E8%AE%BA" title="软硬酸碱理论">软硬酸碱理论</a>弥补了这种理论的缺陷。 </p><p>常見的路易斯酸有: </p> <ul><li><a href="/wiki/%E6%AD%A3%E7%A6%BB%E5%AD%90" class="mw-redirect" title="正离子">正离子</a>、<a href="/wiki/%E9%87%91%E5%B1%9E%E7%A6%BB%E5%AD%90" title="金属离子">金属离子</a>:<a href="/wiki/%E9%88%89%E9%9B%A2%E5%AD%90" class="mw-redirect" title="鈉離子">钠离子</a>、<a href="/wiki/%E7%83%B7%E5%9F%BA" title="烷基">烷基</a>正离子、<a href="/wiki/%E7%A1%9D%E5%9F%BA%E5%8C%96%E5%90%88%E7%89%A9" title="硝基化合物">硝基</a>正离子</li> <li><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%9D" title="氯化铝">氯化鋁</a>、<a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%81" title="氯化铁">氯化鐵</a>、<a href="/wiki/%E4%B8%89%E6%B0%9F%E5%8C%96%E7%A1%BC" title="三氟化硼">三氟化硼</a>、<a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%93%8C" title="五氯化铌">五氯化鈮</a>以及<a href="/wiki/%E9%95%A7%E7%B3%BB" class="mw-redirect" title="镧系">鑭系</a>元素的<a href="/wiki/%E4%B8%89%E6%B0%9F%E7%94%B2%E7%A3%BA%E9%85%B8" title="三氟甲磺酸">三氟甲磺酸盐</a>。</li></ul> <p>常見的路易斯鹼有: </p> <ul><li><a href="/wiki/%E7%A6%BB%E5%AD%90#阴离子" title="离子">负离子</a>:<a href="/wiki/%E5%8D%A4%E7%A6%BB%E5%AD%90" class="mw-redirect" title="卤离子">卤离子</a>、<a href="/wiki/%E6%B0%A2%E6%B0%A7%E6%A0%B9" title="氢氧根">氢氧根</a>离子、<a href="/wiki/%E7%83%B7%E6%B0%A7%E5%9F%BA" title="烷氧基">烷氧基</a>离子、<a href="/wiki/%E7%83%AF%E7%83%83" title="烯烃">烯烃</a>、<a href="/wiki/%E8%8A%B3%E9%A6%99%E5%8C%96%E5%90%88%E7%89%A9" title="芳香化合物">芳香化合物</a></li> <li><a href="/wiki/%E6%B0%A8%E6%B0%94" class="mw-redirect" title="氨气">氨氣</a>、<a href="/wiki/%E6%B0%B4" title="水">水</a>、<a href="/wiki/%E6%B0%9F%E7%A6%BB%E5%AD%90" class="mw-redirect" title="氟离子">氟離子</a>、<a href="/wiki/%E6%B0%B0%E7%A6%BB%E5%AD%90" class="mw-redirect" title="氰离子">氰離子</a>、<a href="/wiki/%E4%B8%80%E6%B0%A7%E5%8C%96%E7%A2%B3" title="一氧化碳">一氧化碳</a>。</li></ul> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="路易斯酸"><span id=".E8.B7.AF.E6.98.93.E6.96.AF.E9.85.B8"></span>路易斯酸</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=1" title="编辑章节:路易斯酸"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r83732082">.mw-parser-output .infobox-subbox{padding:0;border:none;margin:-3px;width:auto;min-width:100%;font-size:100%;clear:none;float:none;background-color:transparent}.mw-parser-output .infobox-3cols-child{margin:auto}.mw-parser-output .infobox .navbar{font-size:100%}body.skin-minerva .mw-parser-output .infobox-header,body.skin-minerva .mw-parser-output .infobox-subheader,body.skin-minerva .mw-parser-output .infobox-above,body.skin-minerva .mw-parser-output .infobox-title,body.skin-minerva .mw-parser-output .infobox-image,body.skin-minerva .mw-parser-output .infobox-full-data,body.skin-minerva .mw-parser-output .infobox-below{text-align:center}@media screen{html.skin-theme-clientpref-night .mw-parser-output .infobox-full-data:not(.notheme)>div:not(.notheme)[style]{background:#1f1f23!important;color:#f8f9fa}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .infobox-full-data:not(.notheme) div:not(.notheme){background:#1f1f23!important;color:#f8f9fa}}html.skin-theme-clientpref-night .mw-parser-output .infobox td div:not(.notheme)[style]{background:transparent!important;color:var(--color-base,#202122)}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .infobox td div:not(.notheme)[style]{background:transparent!important;color:var(--color-base,#202122)}}html.skin-theme-clientpref-night .mw-parser-output .infobox td div.NavHead:not(.notheme)[style]{background:transparent!important}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .infobox td div.NavHead:not(.notheme)[style]{background:transparent!important}}@media(min-width:640px){body.skin--responsive .mw-parser-output .infobox-table{display:table!important}body.skin--responsive .mw-parser-output .infobox-table>caption{display:table-caption!important}body.skin--responsive .mw-parser-output .infobox-table>tbody{display:table-row-group}body.skin--responsive .mw-parser-output .infobox-table tr{display:table-row!important}body.skin--responsive .mw-parser-output .infobox-table th,body.skin--responsive .mw-parser-output .infobox-table td{padding-left:inherit;padding-right:inherit}}</style><table class="infobox" style="margin: 0 0 1em 1em; float: right;"><tbody><tr><th colspan="2" class="infobox-above" style="background-color:;">「路易士酸」的各地常用名稱</th></tr><tr><th scope="row" class="infobox-label" style="white-space: nowrap; background-color:; width:4em;;">中国大陸</th><td class="infobox-data" style="white-space: nowrap; font-size: 1rem;;">路易斯酸 </td></tr><tr><th scope="row" class="infobox-label" style="white-space: nowrap; background-color:; width:4em;;">臺灣</th><td class="infobox-data" style="white-space: nowrap; font-size: 1rem;;">路易士酸 </td></tr><tr><th scope="row" class="infobox-label" style="white-space: nowrap; background-color:; width:4em;;">港澳</th><td class="infobox-data" style="white-space: nowrap; font-size: 1rem;;">路易斯酸 </td></tr></tbody></table> <div class="mw-heading mw-heading3"><h3 id="物理性质"><span id=".E7.89.A9.E7.90.86.E6.80.A7.E8.B4.A8"></span>物理性质</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=2" title="编辑章节:物理性质"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>路易斯酸,简称L酸,其多具<a href="/wiki/%E8%85%90%E8%9D%95%E6%80%A7" class="mw-redirect" title="腐蝕性">腐蝕性</a>。<a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%8C" title="氯化锌">氯化锌</a>,對<a href="/wiki/%E7%BA%96%E7%B6%AD%E7%B4%A0" class="mw-redirect" title="纖維素">纖維素</a>具腐蝕性,是一個路易斯酸腐蝕性的典型例子。由於水显路易斯鹼性,多數路易斯酸會和水反應并產生具有布仑斯惕酸性的<a href="/wiki/%E6%B0%B4%E5%90%88%E7%89%A9" title="水合物">水合物</a>。因此,很多路易斯酸的水溶液都是呈<a href="/wiki/%E5%B8%83%E4%BB%91%E6%96%AF%E6%83%95" class="mw-redirect" title="布仑斯惕">布仑斯惕</a>酸性的。水合物中的路易斯酸與水分子之間有強的<a href="/wiki/%E5%8C%96%E5%AD%B8%E9%8D%B5" class="mw-redirect" title="化學鍵">化學鍵</a>連系著,因此很難把路易斯酸水合物<a href="/wiki/%E4%B9%BE%E7%87%A5" class="mw-redirect" title="乾燥">乾燥</a>,即使路易斯酸水合物通常是可分离出的<a href="/wiki/%E5%8C%96%E5%90%88%E7%89%A9" title="化合物">化合物</a>。例如,如果试图加熱干燥金属氯化物(路易斯酸)中的水分,則会生成<a href="/wiki/%E6%B0%AF%E5%8C%96%E6%B0%A2" title="氯化氢">氯化氫</a>及其金屬的<a href="/wiki/%E6%B0%A2%E6%B0%A7%E5%8C%96%E7%89%A9" class="mw-redirect" title="氢氧化物">氫氧化物</a>。 </p> <div class="mw-heading mw-heading3"><h3 id="化学性质"><span id=".E5.8C.96.E5.AD.A6.E6.80.A7.E8.B4.A8"></span>化学性质</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=3" title="编辑章节:化学性质"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/%E8%A6%AA%E9%9B%BB%E8%A9%A6%E5%8A%91" class="mw-redirect" title="親電試劑">親電試劑</a>或電子受體都是路易斯酸。路易斯酸通常含低能量LUMO(最低未占轨道),會與<a href="/wiki/%E8%B7%AF%E6%98%93%E6%96%AF%E9%B9%BC" class="mw-redirect" title="路易斯鹼">路易斯鹼</a>的HOMO(最高占有轨道)反应。它與<a href="/wiki/%E9%85%B8%E7%A2%B1%E8%B4%A8%E5%AD%90%E7%90%86%E8%AE%BA" title="酸碱质子理论">布仑斯惕-劳里酸</a>不同的是,路易斯酸并不一定需要有<a href="/wiki/%E8%B4%A8%E5%AD%90" class="mw-redirect" title="质子">质子</a>(H<sup>+</sup>)的轉移,對路易斯酸理論來說,所有親電試劑都可以叫做路易斯酸(包括H<sup>+</sup>)。雖然所有布仑斯惕-劳里酸都屬於路易斯酸,但实际上路易斯酸這個名詞多指那些不屬於布仑斯惕-劳里酸的路易斯酸。 </p><p>路易斯酸的化學反應<a href="/wiki/%E6%B4%BB%E6%80%A7" class="mw-redirect" title="活性">活性</a>可以用<a href="/wiki/%E8%BD%AF%E7%A1%AC%E9%85%B8%E7%A2%B1%E7%90%86%E8%AE%BA" title="软硬酸碱理论">软硬酸碱理论</a>來判斷。現時科學家仍沒有知道路易斯酸“強度”的通用定義,這是因為路易斯酸的強度與其特有的路易斯鹼的反應特性有關。一個模型<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> 曾以气态路易斯酸对<a href="/wiki/%E6%B0%9F%E7%A6%BB%E5%AD%90" class="mw-redirect" title="氟离子">氟离子</a>的亲合能来預測路易斯酸的強度,从而得出在常见可分离出的路易斯酸中,以<a href="/wiki/%E4%BA%94%E6%B0%9F%E5%8C%96%E9%94%91" title="五氟化锑">SbF<sub>5</sub></a>(五氟化銻)的路易斯酸性最强。氟离子是“硬”的路易斯鹼,<a href="/wiki/%E6%B0%AF%E7%A6%BB%E5%AD%90" class="mw-redirect" title="氯离子">氯离子</a>及一些較“軟”的路易斯鹼,以及溶液中的路易斯酸性,都受到计算复杂的限制而較難研究。 </p> <div class="mw-heading mw-heading3"><h3 id="酸根型配合物"><span id=".E9.85.B8.E6.A0.B9.E5.9E.8B.E9.85.8D.E5.90.88.E7.89.A9"></span>酸根型配合物</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=4" title="编辑章节:酸根型配合物"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><b>酸根型配合物</b>(Ate complex)是指路易斯酸與特定的鹼生成的中心原子<a href="/wiki/%E5%8C%96%E5%90%88%E4%BB%B7" title="化合价">價</a>升高的<a href="/wiki/%E7%9B%90_(%E5%8C%96%E5%AD%A6)" title="盐 (化学)">盐</a>。<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> 英文<a href="/wiki/%E6%9C%89%E6%9C%BA%E5%8C%96%E5%AD%A6%E5%91%BD%E5%90%8D%E6%B3%95" class="mw-redirect" title="有机化学命名法">有机化學命名法</a>中,<i>ate</i>這個字是一個後輟,用在被描述的原子上。例如,硼化合物的酸根型配合物被叫作<i>borate</i><a href="/wiki/%E7%A1%BC%E9%85%B8%E9%B9%BD" title="硼酸鹽">硼酸盐</a>。因此,三甲基硼烷可和<a href="/wiki/%E7%94%B2%E5%9F%BA%E9%94%82" title="甲基锂">甲基鋰</a>反應生成酸根型配合物Me<sub>4</sub>B<sup>−</sup>Li<sup>+</sup>。這個概念是由<a href="/wiki/%E6%A0%BC%E5%A5%A5%E5%B0%94%E6%A0%BC%C2%B7%E7%BB%B4%E8%92%82%E5%B8%8C" title="格奥尔格·维蒂希">格奥尔格·维蒂希</a>在1958年引入的。<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> 相似地,路易斯鹼可以生成<a href="/wiki/%E9%8E%93%E7%9B%90" class="mw-redirect" title="鎓盐">鎓盐</a>。 </p> <div class="mw-heading mw-heading2"><h2 id="路易斯鹼"><span id=".E8.B7.AF.E6.98.93.E6.96.AF.E9.B9.BC"></span>路易斯鹼</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=5" title="编辑章节:路易斯鹼"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r83732082"><table class="infobox" style="margin: 0 0 1em 1em; float: right;"><tbody><tr><th colspan="2" class="infobox-above" style="background-color:;">「路易斯鹼」的各地常用名稱</th></tr><tr><th scope="row" class="infobox-label" style="white-space: nowrap; background-color:; width:4em;;">中国大陸</th><td class="infobox-data" style="white-space: nowrap; font-size: 1rem;;">路易斯碱 </td></tr><tr><th scope="row" class="infobox-label" style="white-space: nowrap; background-color:; width:4em;;">臺灣</th><td class="infobox-data" style="white-space: nowrap; font-size: 1rem;;">路易士鹼 </td></tr><tr><th scope="row" class="infobox-label" style="white-space: nowrap; background-color:; width:4em;;">港澳</th><td class="infobox-data" style="white-space: nowrap; font-size: 1rem;;">路易斯鹼 </td></tr></tbody></table> <p><a href="/wiki/%E6%B0%A2%E9%94%AE" title="氢键">氢键</a>X—H…Y中的电子给予体Y是路易斯碱,简称L碱。路易斯碱在<a href="/wiki/%E6%9C%89%E6%9C%BA%E5%8F%8D%E5%BA%94" title="有机反应">有机反应</a>中为<a href="/wiki/%E4%BA%B2%E6%A0%B8%E8%AF%95%E5%89%82" class="mw-redirect" title="亲核试剂">亲核试剂</a>。若路易斯碱与路易斯酸反应,形成<a href="/wiki/%E9%85%8D%E5%90%88%E7%89%A9" title="配合物">配合物</a>时,路易斯碱为<a href="/wiki/%E9%85%8D%E4%BD%93" class="mw-redirect" title="配体">配体</a>。 </p> <div class="mw-heading mw-heading2"><h2 id="优缺点"><span id=".E4.BC.98.E7.BC.BA.E7.82.B9"></span>优缺点</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=6" title="编辑章节:优缺点"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="优点"><span id=".E4.BC.98.E7.82.B9"></span>优点</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=7" title="编辑章节:优点"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>酸碱电子理论扩大了酸碱范围,可把酸碱概念用于许多有机反应和无溶剂反应 </p> <div class="mw-heading mw-heading3"><h3 id="缺点"><span id=".E7.BC.BA.E7.82.B9"></span>缺点</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=8" title="编辑章节:缺点"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>如果选择不同的反应对象,酸碱的强弱次序可能不同,它对确定酸碱的相对强弱来说,没有统一的标度,因此对酸碱的反应方向难以判断。 </p> <div class="mw-heading mw-heading2"><h2 id="参考资料"><span id=".E5.8F.82.E8.80.83.E8.B5.84.E6.96.99"></span>参考资料</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=9" title="编辑章节:参考资料"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><cite class="citation journal">Christe, K.O.; Dixon, D.A.; McLemore, D.; Wilson, W.W.; Sheehy, J.A.; and Boatz, J.A. On a quantitative scale for Lewis acidity and recent progress in polynitrogen chemistry. Journal of Fluorine Chemistry. 2000, <b>101</b> (2): 101, 151–153. ISSN 0022-1139.</cite><span title="ctx_ver=Z39.88-2004&amp;rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;rft.atitle=On+a+quantitative+scale+for+Lewis+acidity+and+recent+progress+in+polynitrogen+chemistry&amp;rft.aufirst=K.O.&amp;rft.aulast=Christe&amp;rft.date=2000&amp;rft.genre=article&amp;rft.issue=2&amp;rft.jtitle=Journal+of+Fluorine+Chemistry&amp;rft.pages=101%2C+151-153&amp;rft.volume=101&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;">&#160;</span></span> <span style="display:none;font-size:100%" class="error citation-comment">引文使用过时参数<code style="color:inherit; border:inherit; padding:inherit;">coauthors</code> (<a href="/wiki/Help:%E5%BC%95%E6%96%87%E6%A0%BC%E5%BC%8F1%E9%94%99%E8%AF%AF#deprecated_params" title="Help:引文格式1错误">帮助</a>)</span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text"><i>Advanced organic Chemistry, Reactions, mechanisms and structure</i> 3ed. Jerry March <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0471854727" class="internal mw-magiclink-isbn">ISBN 0-471-85472-7</a> </span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text"><i>Komplexbildung und Reaktivität in der metallorganischen Chemie</i> <a href="/wiki/Angewandte_Chemie" class="mw-redirect" title="Angewandte Chemie">Angewandte Chemie</a> Volume 70, Issue 3, Date: 7 Februar <b>1958</b>, Pages: 65-71 G. Wittig <a href="/wiki/DOI" title="DOI">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1002%2Fange.1760700302">10.1002/ange.1760700302</a></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="延伸閱讀"><span id=".E5.BB.B6.E4.BC.B8.E9.96.B1.E8.AE.80"></span>延伸閱讀</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=10" title="编辑章节:延伸閱讀"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><i>The Lewis acid-base concepts: an overview</i>, 1980, <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0471039020" class="internal mw-magiclink-isbn">ISBN 0-471-03902-0</a></li> <li><i>Selectivities in Lewis acid promoted reactions</i>, 1989, <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0792304527" class="internal mw-magiclink-isbn">ISBN 0-7923-0452-7</a></li> <li><i>Lewis acid reagents: a practical approach</i>, 1999, <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0198500998" class="internal mw-magiclink-isbn">ISBN 0-19-850099-8</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="参见"><span id=".E5.8F.82.E8.A7.81"></span>参见</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%85%B8%E7%A2%B1%E7%94%B5%E5%AD%90%E7%90%86%E8%AE%BA&amp;action=edit&amp;section=11" title="编辑章节:参见"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/%E9%85%B8%E7%A2%B1%E7%94%B5%E7%A6%BB%E8%AE%BA" class="mw-redirect" title="酸碱电离论">酸碱电离论</a></li> <li><a href="/wiki/%E9%85%B8%E7%A2%B1%E8%B4%A8%E5%AD%90%E7%90%86%E8%AE%BA" title="酸碱质子理论">酸碱质子理论</a></li> <li><a href="/wiki/%E8%BD%AF%E7%A1%AC%E9%85%B8%E7%A2%B1%E7%90%86%E8%AE%BA" title="软硬酸碱理论">软硬酸碱理论</a></li></ul> <!-- NewPP limit report Parsed by mw‐web.eqiad.main‐559c9fd9f4‐4v2dt Cached time: 20241126130135 Cache expiry: 2592000 Reduced expiry: false Complications: [show‐toc] CPU time usage: 0.410 seconds Real time usage: 0.531 seconds Preprocessor visited node count: 1469/1000000 Post‐expand include size: 61120/2097152 bytes Template argument size: 654/2097152 bytes Highest expansion depth: 23/100 Expensive parser function count: 4/500 Unstrip recursion depth: 0/20 Unstrip post‐expand size: 21140/5000000 bytes Lua time usage: 0.220/10.000 seconds Lua memory usage: 3643243/52428800 bytes Number of Wikibase entities loaded: 0/400 --> <!-- Transclusion expansion time report (%,ms,calls,template) 100.00% 459.589 1 -total 26.15% 120.201 1 Template:酸鹼 25.93% 119.176 1 Template:Not 25.67% 117.954 1 Template:Sidebar 25.06% 115.155 1 Template:Hatnote 15.36% 70.597 1 Template:Refimprove 13.84% 63.593 1 Template:Ambox 13.23% 60.801 2 Template:各地中文名 12.36% 56.795 2 Template:各地中文名/infobox 11.89% 54.639 1 Template:Reflist --> <!-- Saved in parser cache with key zhwiki:pcache:650257:|#|:idhash:canonical!zh and timestamp 20241126130135 and revision id 83979886. 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