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(PDF) Effects of carbon nanotube and biochar on bioavailability of Pb, Cu and Sb in multi-metal contaminated soil | Anushka Upamali Rajapaksha - Academia.edu
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Commercially available multi-walled carbon nanotube (MWCNT) and biochar" /> <title>(PDF) Effects of carbon nanotube and biochar on bioavailability of Pb, Cu and Sb in multi-metal contaminated soil | Anushka Upamali Rajapaksha - Academia.edu</title> <link rel="canonical" href="https://www.academia.edu/35310342/Effects_of_carbon_nanotube_and_biochar_on_bioavailability_of_Pb_Cu_and_Sb_in_multi_metal_contaminated_soil" /> <script async src="https://www.googletagmanager.com/gtag/js?id=G-5VKX33P2DS"></script> <script> window.dataLayer = window.dataLayer || []; function gtag(){dataLayer.push(arguments);} gtag('js', new Date()); gtag('config', 'G-5VKX33P2DS', { cookie_domain: 'academia.edu', send_page_view: false, }); gtag('event', 'page_view', { 'controller': "single_work", 'action': "show", 'controller_action': 'single_work#show', 'logged_in': 'false', 'edge': 'unknown', // Send nil if there is no A/B test bucket, in case some records get logged // with missing data - that way we can distinguish between the two cases. // ab_test_bucket should be of the form <ab_test_name>:<bucket> 'ab_test_bucket': null, }) </script> <script> var $controller_name = 'single_work'; var $action_name = "show"; var $rails_env = 'production'; var $app_rev = '92477ec68c09d28ae4730a4143c926f074776319'; var $domain = 'academia.edu'; var $app_host = "academia.edu"; var $asset_host = "academia-assets.com"; var $start_time = new Date().getTime(); var $recaptcha_key = "6LdxlRMTAAAAADnu_zyLhLg0YF9uACwz78shpjJB"; var $recaptcha_invisible_key = "6Lf3KHUUAAAAACggoMpmGJdQDtiyrjVlvGJ6BbAj"; var $disableClientRecordHit = false; </script> <script> window.require = { config: function() { return function() {} } } </script> <script> window.Aedu = window.Aedu || {}; window.Aedu.hit_data = null; window.Aedu.serverRenderTime = new Date(1732814976000); window.Aedu.timeDifference = new Date().getTime() - 1732814976000; </script> <script type="application/ld+json">{"@context":"https://schema.org","@type":"ScholarlyArticle","abstract":"This study examined the effects of carbon nanotube and biochar on the bioavailability of Pb, Cu and Sb in the shooting range soils for developing low-cost remediation technology. Commercially available multi-walled carbon nanotube (MWCNT) and biochar pyrolyzed from soybean stover at 300 °C (BC) at 0.5, 1 and 2.5% (w w-1) were used to remediate the contaminated soil in an incubation experiment. Both DTPA (bioavailable) and TCLP (leaching) extraction procedures were used to compare the metal/loid availability and leaching by the amendments in soil. The addition of BC was more effective in immobilizing mobile Pb and Cu in the soil than that in MWCNT. The BC reduced the concentrations of Pb and Cu in the soil by 17.6 and 16.2%, respectively. However, both MWCNTs and BC increased Sb bioavailability by 1.4-fold and 1.6-fold, respectively, in DTPA extraction , compared to the control. The toxicity characteristic leaching procedure (TCLP) test showed that the leachability of Pb in the soil amended with 2.5% MWCNT was 1.3-fold higher than that the una-mended soil, whereas the BC at 2.5% decreased the TCLP-extractable Pb by 19.2%. Precipitation and adsorption via electrostatic and p–p electron donor– acceptor interactions were postulated to be involved in the interactions of Pb and Cu with surfaces of the BC in the amended soils, whereas ion exchange mechanisms might be involved in the immobiliza-tion of Cu in the MWCNT-amended soils. The application of BC derived from soybean stover can be a low-cost technology for simultaneously immobilizing bioavailable Pb and Cu in the shooting range soils; however, neither of amendments was effective in Sb immobilization.","author":[{"@context":"https://schema.org","@type":"Person","name":"Anushka Upamali Rajapaksha"}],"contributor":[],"dateCreated":"2017-12-01","dateModified":null,"datePublished":null,"headline":"Effects of carbon nanotube and biochar on bioavailability of Pb, Cu and Sb in multi-metal contaminated soil","inLanguage":"en","keywords":["BIOCHAR","Carbon Nanotubes"],"locationCreated":null,"publication":null,"publisher":{"@context":"https://schema.org","@type":"Organization","name":null},"image":null,"thumbnailUrl":null,"url":"https://www.academia.edu/35310342/Effects_of_carbon_nanotube_and_biochar_on_bioavailability_of_Pb_Cu_and_Sb_in_multi_metal_contaminated_soil","sourceOrganization":[{"@context":"https://schema.org","@type":"EducationalOrganization","name":"sjp"}]}</script><link rel="stylesheet" media="all" href="//a.academia-assets.com/assets/single_work_page/loswp-102fa537001ba4d8dcd921ad9bd56c474abc201906ea4843e7e7efe9dfbf561d.css" /><link rel="stylesheet" media="all" href="//a.academia-assets.com/assets/design_system/body-8d679e925718b5e8e4b18e9a4fab37f7eaa99e43386459376559080ac8f2856a.css" /><link rel="stylesheet" media="all" href="//a.academia-assets.com/assets/design_system/button-3cea6e0ad4715ed965c49bfb15dedfc632787b32ff6d8c3a474182b231146ab7.css" /><link rel="stylesheet" media="all" 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[{"id":55170718,"identifier":"Attachment_55170718","shouldShowBulkDownload":false}]; window.loswp.shouldDetectTimezone = true; window.loswp.shouldShowBulkDownload = true; window.loswp.showSignupCaptcha = false window.loswp.willEdgeCache = false; window.loswp.work = {"work":{"id":35310342,"created_at":"2017-12-01T08:09:56.446-08:00","from_world_paper_id":null,"updated_at":"2024-11-26T23:08:25.293-08:00","_data":{"abstract":"This study examined the effects of carbon nanotube and biochar on the bioavailability of Pb, Cu and Sb in the shooting range soils for developing low-cost remediation technology. Commercially available multi-walled carbon nanotube (MWCNT) and biochar pyrolyzed from soybean stover at 300 °C (BC) at 0.5, 1 and 2.5% (w w-1) were used to remediate the contaminated soil in an incubation experiment. Both DTPA (bioavailable) and TCLP (leaching) extraction procedures were used to compare the metal/loid availability and leaching by the amendments in soil. The addition of BC was more effective in immobilizing mobile Pb and Cu in the soil than that in MWCNT. The BC reduced the concentrations of Pb and Cu in the soil by 17.6 and 16.2%, respectively. However, both MWCNTs and BC increased Sb bioavailability by 1.4-fold and 1.6-fold, respectively, in DTPA extraction , compared to the control. The toxicity characteristic leaching procedure (TCLP) test showed that the leachability of Pb in the soil amended with 2.5% MWCNT was 1.3-fold higher than that the una-mended soil, whereas the BC at 2.5% decreased the TCLP-extractable Pb by 19.2%. Precipitation and adsorption via electrostatic and p–p electron donor– acceptor interactions were postulated to be involved in the interactions of Pb and Cu with surfaces of the BC in the amended soils, whereas ion exchange mechanisms might be involved in the immobiliza-tion of Cu in the MWCNT-amended soils. The application of BC derived from soybean stover can be a low-cost technology for simultaneously immobilizing bioavailable Pb and Cu in the shooting range soils; however, neither of amendments was effective in Sb immobilization.","ai_title_tag":"Impact of Biochar and Carbon Nanotubes on Pb, Cu, Sb in Soil"},"document_type":"paper","pre_hit_view_count_baseline":null,"quality":"high","language":"en","title":"Effects of carbon nanotube and biochar on bioavailability of Pb, Cu and Sb in multi-metal contaminated soil","broadcastable":true,"draft":false,"has_indexable_attachment":true,"indexable":true}}["work"]; window.loswp.workCoauthors = [12542231]; window.loswp.locale = "en"; window.loswp.countryCode = "SG"; window.loswp.cwvAbTestBucket = ""; window.loswp.designVariant = "ds_vanilla"; window.loswp.fullPageMobileSutdModalVariant = "control"; window.loswp.useOptimizedScribd4genScript = false; window.loswp.appleClientId = 'edu.academia.applesignon';</script><script defer="" src="https://accounts.google.com/gsi/client"></script><div class="ds-loswp-container"><div class="ds-work-card--grid-container"><div class="ds-work-card--container js-loswp-work-card"><div class="ds-work-card--cover"><div class="ds-work-cover--wrapper"><div class="ds-work-cover--container"><button class="ds-work-cover--clickable js-swp-download-button" data-signup-modal="{"location":"swp-splash-paper-cover","attachmentId":55170718,"attachmentType":"pdf"}"><img alt="First page of “Effects of carbon nanotube and biochar on bioavailability of Pb, Cu and Sb in multi-metal contaminated soil”" class="ds-work-cover--cover-thumbnail" src="https://0.academia-photos.com/attachment_thumbnails/55170718/mini_magick20190115-9969-y833up.png?1547548483" /><img alt="PDF Icon" class="ds-work-cover--file-icon" src="//a.academia-assets.com/assets/single_work_splash/adobe.icon-574afd46eb6b03a77a153a647fb47e30546f9215c0ee6a25df597a779717f9ef.svg" /><div class="ds-work-cover--hover-container"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">download</span><p>Download Free PDF</p></div><div class="ds-work-cover--ribbon-container">Download Free PDF</div><div class="ds-work-cover--ribbon-triangle"></div></button></div></div></div><div class="ds-work-card--work-information"><h1 class="ds-work-card--work-title">Effects of carbon nanotube and biochar on bioavailability of Pb, Cu and Sb in multi-metal contaminated soil</h1><div class="ds-work-card--work-authors ds-work-card--detail"><a class="ds-work-card--author js-wsj-grid-card-author ds2-5-body-md ds2-5-body-link" data-author-id="12542231" href="https://sjp.academia.edu/AnushkaUpamaliRajapaksha"><img alt="Profile image of Anushka Upamali Rajapaksha" class="ds-work-card--author-avatar" src="https://0.academia-photos.com/12542231/3580922/12700079/s65_anushka_upamali.rajapaksha.jpg" />Anushka Upamali Rajapaksha</a></div><div class="ds-work-card--detail"><div class="ds-work-card--work-metadata"><div class="ds-work-card--work-metadata__stat"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">visibility</span><p class="ds2-5-body-sm" id="work-metadata-view-count">…</p></div><div class="ds-work-card--work-metadata__stat"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">description</span><p class="ds2-5-body-sm">12 pages</p></div><div class="ds-work-card--work-metadata__stat"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">link</span><p class="ds2-5-body-sm">1 file</p></div></div><script>(async () => { const workId = 35310342; const worksViewsPath = "/v0/works/views?subdomain_param=api&work_ids%5B%5D=35310342"; const getWorkViews = async (workId) => { const response = await fetch(worksViewsPath); if (!response.ok) { throw new Error('Failed to load work views'); } const data = await response.json(); return data.views[workId]; }; // Get the view count for the work - we send this immediately rather than waiting for // the DOM to load, so it can be available as soon as possible (but without holding up // the backend or other resource requests, because it's a bit expensive and not critical). const viewCount = await getWorkViews(workId); const updateViewCount = (viewCount) => { const viewCountNumber = Number(viewCount); if (!viewCountNumber) { throw new Error('Failed to parse view count'); } const commaizedViewCount = viewCountNumber.toLocaleString(); const viewCountBody = document.getElementById('work-metadata-view-count'); if (viewCountBody) { viewCountBody.textContent = `${commaizedViewCount} views`; } else { throw new Error('Failed to find work views element'); } }; // If the DOM is still loading, wait for it to be ready before updating the view count. if (document.readyState === "loading") { document.addEventListener('DOMContentLoaded', () => { updateViewCount(viewCount); }); // Otherwise, just update it immediately. } else { updateViewCount(viewCount); } })();</script></div><p class="ds-work-card--work-abstract ds-work-card--detail ds2-5-body-md">This study examined the effects of carbon nanotube and biochar on the bioavailability of Pb, Cu and Sb in the shooting range soils for developing low-cost remediation technology. Commercially available multi-walled carbon nanotube (MWCNT) and biochar pyrolyzed from soybean stover at 300 °C (BC) at 0.5, 1 and 2.5% (w w-1) were used to remediate the contaminated soil in an incubation experiment. Both DTPA (bioavailable) and TCLP (leaching) extraction procedures were used to compare the metal/loid availability and leaching by the amendments in soil. The addition of BC was more effective in immobilizing mobile Pb and Cu in the soil than that in MWCNT. The BC reduced the concentrations of Pb and Cu in the soil by 17.6 and 16.2%, respectively. However, both MWCNTs and BC increased Sb bioavailability by 1.4-fold and 1.6-fold, respectively, in DTPA extraction , compared to the control. The toxicity characteristic leaching procedure (TCLP) test showed that the leachability of Pb in the soil amended with 2.5% MWCNT was 1.3-fold higher than that the una-mended soil, whereas the BC at 2.5% decreased the TCLP-extractable Pb by 19.2%. Precipitation and adsorption via electrostatic and p–p electron donor– acceptor interactions were postulated to be involved in the interactions of Pb and Cu with surfaces of the BC in the amended soils, whereas ion exchange mechanisms might be involved in the immobiliza-tion of Cu in the MWCNT-amended soils. The application of BC derived from soybean stover can be a low-cost technology for simultaneously immobilizing bioavailable Pb and Cu in the shooting range soils; however, neither of amendments was effective in Sb immobilization.</p><div class="ds-work-card--button-container"><button class="ds2-5-button js-swp-download-button" data-signup-modal="{"location":"continue-reading-button--work-card","attachmentId":55170718,"attachmentType":"pdf","workUrl":"https://www.academia.edu/35310342/Effects_of_carbon_nanotube_and_biochar_on_bioavailability_of_Pb_Cu_and_Sb_in_multi_metal_contaminated_soil"}">See full PDF</button><button class="ds2-5-button ds2-5-button--secondary js-swp-download-button" data-signup-modal="{"location":"download-pdf-button--work-card","attachmentId":55170718,"attachmentType":"pdf","workUrl":"https://www.academia.edu/35310342/Effects_of_carbon_nanotube_and_biochar_on_bioavailability_of_Pb_Cu_and_Sb_in_multi_metal_contaminated_soil"}"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">download</span>Download PDF</button></div></div></div></div><div data-auto_select="false" data-client_id="331998490334-rsn3chp12mbkiqhl6e7lu2q0mlbu0f1b" data-doc_id="55170718" data-landing_url="https://www.academia.edu/35310342/Effects_of_carbon_nanotube_and_biochar_on_bioavailability_of_Pb_Cu_and_Sb_in_multi_metal_contaminated_soil" data-login_uri="https://www.academia.edu/registrations/google_one_tap" data-moment_callback="onGoogleOneTapEvent" id="g_id_onload"></div><div class="ds-top-related-works--grid-container"><div class="ds-related-content--container ds-top-related-works--container"><h2 class="ds-related-content--heading">Related papers</h2><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="0" data-entity-id="86533503" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/86533503/Immobilization_of_Pb_and_Cu_in_polluted_soil_by_superphosphate_multi_walled_carbon_nanotube_rice_straw_and_its_derived_biochar">Immobilization of Pb and Cu in polluted soil by superphosphate, multi-walled carbon nanotube, rice straw and its derived biochar</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="54239244" href="https://independent.academia.edu/AfzalChhajro">Afzal Chhajro</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Environmental science and pollution research international, 2016</p><p class="ds-related-work--abstract ds2-5-body-sm">Lead (Pb) and copper (Cu) contamination in croplands pose severe health hazards and environmental concerns throughout soil-food chain transfer. In the present study, BCR, TCLP, CaCl2, and SBET techniques were employed to evaluate the simultaneous effectiveness of rice straw (RS) and its derived biochar (BC), multiwall carbon nanotube (MWCNT), and single superphosphate (SSP) to immobilize the Pb and Cu in co-contaminated soil. The BCR sequential extraction results suggested that with increasing BC and SSP amount, the acid-soluble fractions decreased while oxidizable and residual proportions of Pb and Cu were increased significantly. Compared to SSP, the application of BC amendment substantially modified partitioning of Cu from easily exchangeable phase to less bioavailable residual bound fraction. The immobilized Pb and Cu were mainly transformed to reducible forms. The TCLP and CaCl2-extracted Pb and Cu were reduced significantly by the addition of BC compared to RS and MWCNT, where...</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Immobilization of Pb and Cu in polluted soil by superphosphate, multi-walled carbon nanotube, rice straw and its derived biochar","attachmentId":90963539,"attachmentType":"pdf","work_url":"https://www.academia.edu/86533503/Immobilization_of_Pb_and_Cu_in_polluted_soil_by_superphosphate_multi_walled_carbon_nanotube_rice_straw_and_its_derived_biochar","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/86533503/Immobilization_of_Pb_and_Cu_in_polluted_soil_by_superphosphate_multi_walled_carbon_nanotube_rice_straw_and_its_derived_biochar"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="1" data-entity-id="38049848" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/38049848/Influence_of_bioenergy_waste_biochar_on_proton_and_ligand_promoted_release_of_Pb_and_Cu_in_a_shooting_range_soil">Influence of bioenergy waste biochar on proton-and ligand-promoted release of Pb and Cu in a shooting range soil</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="60911154" href="https://usq.academia.edu/PrasannaKumarathilaka">Prasanna Kumarathilaka</a><span>, </span><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="29875" href="https://king-saud.academia.edu/MohammadAlwabel">Mohammad Alwabel</a></div><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Influence of bioenergy waste biochar on proton-and ligand-promoted release of Pb and Cu in a shooting range soil","attachmentId":58074554,"attachmentType":"pdf","work_url":"https://www.academia.edu/38049848/Influence_of_bioenergy_waste_biochar_on_proton_and_ligand_promoted_release_of_Pb_and_Cu_in_a_shooting_range_soil","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/38049848/Influence_of_bioenergy_waste_biochar_on_proton_and_ligand_promoted_release_of_Pb_and_Cu_in_a_shooting_range_soil"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="2" data-entity-id="105255738" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/105255738/The_Use_of_biochar_in_the_Remediation_of_Pb_Cd_and_Cu_Contaminated_Soils_The_Impact_of_biochar_Feedstock_and_Preparation_Conditions_on_Its_Remediation_Capacity">The Use of biochar in the Remediation of Pb, Cd, and Cu-Contaminated Soils. The Impact of biochar Feedstock and Preparation Conditions on Its Remediation Capacity</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="58809907" href="https://independent.academia.edu/EvangeliaGolia">Evangelia Golia</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Land</p><p class="ds-related-work--abstract ds2-5-body-sm">Soil constitutes an important part of terrestrial ecosystems, prone to be adversely impacted by human activities. During the last decades, several methods have been developed aiming at its remediation, including the use of biochar as a soil amendment. In the present work, we have assessed the reduction of Pb, Cd, and Cu soil concentrations as a function of the mixing ratio of biochar added to soil, as well as the source of biochar employed. Furthermore, we have investigated the effects of biochar addition relating to the chemical forms of heavy metals (HMs) related to their bioavailability and mobility. The concentrations of HMs were determined by the BCR (European Community Bureau of Reference) sequential extraction procedure before and after biochar addition to the soils. Five types of biochar were used, obtained as by-products of sugarcane bagasse (Β), bamboo (ΒΒ), rice straw (RSB), garden waste (GB), and paulownia (PB) treatment, respectively. Biochar derived from sugarcane (B) ...</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"The Use of biochar in the Remediation of Pb, Cd, and Cu-Contaminated Soils. The Impact of biochar Feedstock and Preparation Conditions on Its Remediation Capacity","attachmentId":104760397,"attachmentType":"pdf","work_url":"https://www.academia.edu/105255738/The_Use_of_biochar_in_the_Remediation_of_Pb_Cd_and_Cu_Contaminated_Soils_The_Impact_of_biochar_Feedstock_and_Preparation_Conditions_on_Its_Remediation_Capacity","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/105255738/The_Use_of_biochar_in_the_Remediation_of_Pb_Cd_and_Cu_Contaminated_Soils_The_Impact_of_biochar_Feedstock_and_Preparation_Conditions_on_Its_Remediation_Capacity"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="3" data-entity-id="42017394" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/42017394/Bioavailability_and_leaching_of_Cd_and_Pb_from_contaminated_soil_amended_with_different_sizes_of_biochar">Bioavailability and leaching of Cd and Pb from contaminated soil amended with different sizes of biochar</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="40444958" href="https://independent.academia.edu/SamsuriBinAbdWahid">Samsuri Bin Abd. Wahid</a><span>, </span><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="29841009" href="https://uodiyala.academia.edu/AlaaFahmi">Alaa H . Fahmi</a></div><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Bioavailability and leaching of Cd and Pb from contaminated soil amended with different sizes of biochar","attachmentId":62142180,"attachmentType":"pdf","work_url":"https://www.academia.edu/42017394/Bioavailability_and_leaching_of_Cd_and_Pb_from_contaminated_soil_amended_with_different_sizes_of_biochar","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/42017394/Bioavailability_and_leaching_of_Cd_and_Pb_from_contaminated_soil_amended_with_different_sizes_of_biochar"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="4" data-entity-id="107611395" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/107611395/Beneficial_effects_of_tobacco_biochar_combined_with_mineral_additives_on_im_mobilization_and_bio_availability_of_Pb_Cd_Cu_and_Zn_from_Pb_Zn_smelter_contaminated_soils">Beneficial effects of tobacco biochar combined with mineral additives on (im)mobilization and (bio)availability of Pb, Cd, Cu and Zn from Pb/Zn smelter contaminated soils</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="93922907" href="https://independent.academia.edu/AltafHussainLahori">Altaf Hussain Lahori</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Ecotoxicology and Environmental Safety, 2017</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Beneficial effects of tobacco biochar combined with mineral additives on (im)mobilization and (bio)availability of Pb, Cd, Cu and Zn from Pb/Zn smelter contaminated soils","attachmentId":106257472,"attachmentType":"pdf","work_url":"https://www.academia.edu/107611395/Beneficial_effects_of_tobacco_biochar_combined_with_mineral_additives_on_im_mobilization_and_bio_availability_of_Pb_Cd_Cu_and_Zn_from_Pb_Zn_smelter_contaminated_soils","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/107611395/Beneficial_effects_of_tobacco_biochar_combined_with_mineral_additives_on_im_mobilization_and_bio_availability_of_Pb_Cd_Cu_and_Zn_from_Pb_Zn_smelter_contaminated_soils"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="5" data-entity-id="35647434" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/35647434/BIOCHAR_A_SOLUTION_FOR_SOIL_LEAD_Pb_POLLUTION">BIOCHAR: A SOLUTION FOR SOIL LEAD (Pb) POLLUTION</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="8186974" href="https://aun.academia.edu/DrMahdyHamed">Prof. Dr. Mahdy H . Hamed</a></div><p class="ds-related-work--abstract ds2-5-body-sm">Restoration of shooting range soils is an emerging environmental issue for nature conservation. A large number of shooting ranges is present in Egypt without paying attention to controlling the environmental pollution. The main objective of this research was to investigate the integrated effect of applying biochar (BC) derived from sugar cane wastes for soil fertility improvement and lead (Pb) stabilization. To achieve this goal, sugar cane wastes were collected, and used for producing the BC. A small-scale BC production unit was designed by using double metal barrels; thereafter, sugar cane wastes were placed and burned inside the BC producing unit. The produced BC was used to restore the biological function of a polluted shooting range soil by immobilizing Pb and improving the soil fertility. A surface sandy loam soil was collected from a shooting range site in the Giza Governorate-Egypt and was incubated for 365 days with different application levels (0.0, 1.0, 2.5, 5.0, 10.0, 20.0 and 30.0% w/w) of BC. The results showed that the addition of BC significantly increased the soil water holding capacity, available nutrients (N and P) and cation exchange capacity as well as stimulated the microbial growth (bacteria and fungi) in the soil. Moreover, the addition of BC led to a significant decrease in the available Pb fraction by 97.0%, as compared to the untreated soil. The phytotoxicity test revealed that the addition of BC significantly increased maize biomass (shoots and roots), especially with applications of 3% and 5% treatments. However, no plant growth occurred on the untreated soil. Furthermore, Pb uptake by maize plants significantly decreased with increasing the level of applied BC. Our findings provide evidence that BC application decreased Pb toxicity by immobilizing Pb and improving soil quality. Therefore, BC can be effectively used for sustainable development and environmental protection.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"BIOCHAR: A SOLUTION FOR SOIL LEAD (Pb) POLLUTION","attachmentId":55516937,"attachmentType":"pdf","work_url":"https://www.academia.edu/35647434/BIOCHAR_A_SOLUTION_FOR_SOIL_LEAD_Pb_POLLUTION","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/35647434/BIOCHAR_A_SOLUTION_FOR_SOIL_LEAD_Pb_POLLUTION"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="6" data-entity-id="31764523" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/31764523/Lead_and_copper_immobilization_in_a_shooting_range_soil_using_soybean_stover_and_pine_needle_derived_biochars_Chemical_microbial_and_spectroscopic_assessments">Lead and copper immobilization in a shooting range soil using soybean stover- and pine needle-derived biochars: Chemical, microbial and spectroscopic assessments</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="12542231" href="https://sjp.academia.edu/AnushkaUpamaliRajapaksha">Anushka Upamali Rajapaksha</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Hazardous Materials, 2015</p><p class="ds-related-work--abstract ds2-5-body-sm">Biochar (BC) could be a potential candidate for the remediation of metal contaminated soil. Mechanistic understandings are needed for the appropriate selection of BC and investigating molecular microbial ecological interactions. The soybean stover-derived BCs were more effective in immobilizing Pb (88%) and Cu (87%) than the pine needle-derived BCs in a contaminated shooting range soil. The sequential chemical extractions indicated that BCs stimulated the geochemical transformation of metal species. Spectroscopic investigations using scanning electron microscopic elemental dot mapping and extended X-ray absorption fine structure spectroscopic measurements showed that Pb in the BCs amended soils was immobilized by the formation of stable chloropyromorphite. Soil organic C and microbial activity were also enhanced by BC. The non-labile C fraction in the soil amended with BCs produced at 700°C was increased. Biochars showed less impact on the bacterial community than feedstock biomass as promulgated by the pyrosequencing of 16S rRNA gene. The feedstock type (namely soybean stover and pine needles) was the main factor influencing the BCs efficacy on metals&amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;#39; (im) mobilization and bacterial health in soils.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Lead and copper immobilization in a shooting range soil using soybean stover- and pine needle-derived biochars: Chemical, microbial and spectroscopic assessments","attachmentId":54871143,"attachmentType":"pdf","work_url":"https://www.academia.edu/31764523/Lead_and_copper_immobilization_in_a_shooting_range_soil_using_soybean_stover_and_pine_needle_derived_biochars_Chemical_microbial_and_spectroscopic_assessments","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/31764523/Lead_and_copper_immobilization_in_a_shooting_range_soil_using_soybean_stover_and_pine_needle_derived_biochars_Chemical_microbial_and_spectroscopic_assessments"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="7" data-entity-id="111253116" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/111253116/Dose_dependent_Effect_of_Biochar_as_Soil_Amendment_on_Reducing_Copper_Phytotoxicity_and_Mobility">Dose-dependent Effect of Biochar as Soil Amendment on Reducing Copper Phytotoxicity and Mobility</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="60688571" href="https://independent.academia.edu/MahatoGenaRahm">GenaRahm Mahato</a></div><p class="ds-related-work--metadata ds2-5-body-xs">International Journal of Environmental Research, 2020</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Dose-dependent Effect of Biochar as Soil Amendment on Reducing Copper Phytotoxicity and Mobility","attachmentId":108839503,"attachmentType":"pdf","work_url":"https://www.academia.edu/111253116/Dose_dependent_Effect_of_Biochar_as_Soil_Amendment_on_Reducing_Copper_Phytotoxicity_and_Mobility","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/111253116/Dose_dependent_Effect_of_Biochar_as_Soil_Amendment_on_Reducing_Copper_Phytotoxicity_and_Mobility"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="8" data-entity-id="108766027" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/108766027/Using_Industrial_Sewage_Sludge_Derived_Biochar_to_Immobilize_Selected_Heavy_Metals_in_a_Contaminated_Calcareous_Soil">Using Industrial Sewage Sludge-Derived Biochar to Immobilize Selected Heavy Metals in a Contaminated Calcareous Soil</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="213438178" href="https://independent.academia.edu/GhasemRahimi1">Ghasem Rahimi</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Waste and Biomass Valorization, 2019</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Using Industrial Sewage Sludge-Derived Biochar to Immobilize Selected Heavy Metals in a Contaminated Calcareous Soil","attachmentId":107067759,"attachmentType":"pdf","work_url":"https://www.academia.edu/108766027/Using_Industrial_Sewage_Sludge_Derived_Biochar_to_Immobilize_Selected_Heavy_Metals_in_a_Contaminated_Calcareous_Soil","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" 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class="ds-related-work--metadata ds2-5-body-xs">Journal of Hazardous Materials, 2011</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Immobilization of Cu, Pb and Zn in mine-contaminated soils using reactive materials","attachmentId":43342564,"attachmentType":"pdf","work_url":"https://www.academia.edu/22787957/Immobilization_of_Cu_Pb_and_Zn_in_mine_contaminated_soils_using_reactive_materials","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/22787957/Immobilization_of_Cu_Pb_and_Zn_in_mine_contaminated_soils_using_reactive_materials"><span class="ds2-5-text-link__content">View PDF</span><span 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You can download the paper by clicking the button above.</p></div></div></div></div><div class="ds-sidebar--container js-work-sidebar"><div class="ds-related-content--container"><h2 class="ds-related-content--heading">Related papers</h2><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="0" data-entity-id="7347959" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/7347959/Immobilization_of_Zn_Cu_and_Pb_in_contaminated_soils_using_phosphate_rock_and_phosphoric_acid">Immobilization of Zn, Cu, and Pb in contaminated soils using phosphate rock and phosphoric acid</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="12937898" href="https://independent.academia.edu/yongliangyang1">yongliang yang</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Hazardous Materials, 2009</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Immobilization of Zn, Cu, and Pb in contaminated soils using phosphate rock and phosphoric acid","attachmentId":33948945,"attachmentType":"pdf","work_url":"https://www.academia.edu/7347959/Immobilization_of_Zn_Cu_and_Pb_in_contaminated_soils_using_phosphate_rock_and_phosphoric_acid","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-related-work-grid-card-view-pdf" href="https://www.academia.edu/7347959/Immobilization_of_Zn_Cu_and_Pb_in_contaminated_soils_using_phosphate_rock_and_phosphoric_acid"><span class="ds2-5-text-link__content">View PDF</span><span 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