[B! 化学] R2Mのブックマーク

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<a href="/R2M/%E5%8C%96%E5%AD%A6/%E7%A0%94%E7%A9%B6/" > 研究 </a> </li> <li> <a href="/R2M/%E5%8C%96%E5%AD%A6/%E7%B1%B3%E5%9B%BD/" > 米国 </a> </li> <li> <a href="/R2M/%E5%8C%96%E5%AD%A6/%E7%B5%8C%E6%B8%88/" > 経済 </a> </li> <li> <a href="/R2M/%E5%8C%96%E5%AD%A6/%E8%AA%AD%E3%81%BF%E7%89%A9/" > 読み物 </a> </li> <li> <a href="/R2M/%E5%8C%96%E5%AD%A6/%E8%AB%96%E6%96%87/" > 論文 </a> </li> <li> <a href="/R2M/%E5%8C%96%E5%AD%A6/%E9%9B%BB%E5%AD%90/" > 電子 </a> </li> </ul> <p class="centerarticle-sub-navi-more"> <a href="/R2M/bookmark">タグの絞り込みを解除</a> </p> </div> </div> <div class="center-container"> <div class="centerarticle-title-container"> <h2 class="centerarticle-title"> 化学に関するR2Mのブックマーク (28) </h2> </div> <div class="js-user-bookmark-item-autoload-container" data-next-page-path="/R2M/%E5%8C%96%E5%AD%A6/?page=2" data-next-xhr-path="/api/users/R2M/bookmarks?tag=%E5%8C%96%E5%AD%A6&page=2" data-next-label="次のページ" > <script type="text/x-template" id="template-short-url-click"> {{#tweet_url}} <a 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js-list-star-container"></span> <span class="twitter-click js-short-url-clicks"></span> </div> <ul class="centerarticle-reaction-menu"> <li class="js-add-star-container add-star-container"></li> </ul> </div> </div> </div> </div> <ul class="centerarticle-reaction-following js-user-following-bookmarks-icon"> </ul> <div class="js-user-following-bookmarks-detail is-hidden"> </div> </li> <li class="bookmark-item js-user-bookmark-item js-intent-share-bookmark" data-target-url="http://blog.livedoor.jp/route408/archives/52340295.html"> <div class="centerarticle-entry is-image-entry-unit"> <h3 class="centerarticle-entry-title"> <a href="http://blog.livedoor.jp/route408/archives/52340295.html" class="js-clickable-link js-keyboard-openable" target="_blank" rel="noopener" data-gtm-click-label="user-bookmark-title"><img class="centerarticle-entry-favicon" src="https://cdn-ak2.favicon.st-hatena.com/64?url=http%3A%2F%2Fblog.livedoor.jp%2Froute408%2Farchives%2F52340295.html" alt="">「C2」が合成された話 : 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data-gtm-click-label="user-bookmark-category">テクノロジー</a></li> </ul> <div class="centerarticle-entry-contents"> <p class="centerarticle-entry-summary">シリコン（ケイ素）の大きな単結晶（純度99.999999999％）を、ダイヤモンドブレードでスライスして、薄いシリコンウェーハを作ります。</p> </div> </div> <div class="centerarticle-reaction js-user-bookmark-id-container" id="bookmark-243690012"> <div class="centerarticle-reaction-comment js-user-bookmark-comment " data-url="http://www.fujitsu.com/jp/about/businesspolicy/tech/k/whatis/processor/cpu.html" data-user-name="R2M"> <a href="/R2M/" data-gtm-click-label="user-reaction-usericon" class="centerarticle-reaction-thumb"> <img src="https://cdn.profile-image.st-hatena.com/users/R2M/profile.png" alt="R2M" title="R2M" class="centerarticle-reaction-image"> </a> <div class="centerarticle-reaction-main"> <span class="centerarticle-reaction-username"><a href="https://b.hatena.ne.jp/R2M/20181106#bookmark-243690012" class="js-anchor-path" data-gtm-click-label="user-reaction-username">R2M</a></span> <span 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href="/q/%E6%A8%AA%E6%B5%9C">横浜</a>国立大学の量子化学研究グループが、炭素化合物の不飽和結合において、シリコン化合物とは異なり、内殻電子が結合性に寄与することを世界で初めて発見しました。世界最高精度の第一原理計算の結果、炭素分子は内殻電子のトポロジーを変えられ、価電子が自在に共有結合を形成できるのに対し、シリコンを含むほとんどの元素では結合形成をしても内殻のトポロジーを変えないため柔軟な結合形成は阻害されることがわかりました。<a data-gtm-click-label="entry-summary-keyword" href="/q/%E6%9C%AC">本</a>研究から、生命における有機化合物の炭素は他の元素で置き換えられな</p> <a href="https://research-er.jp/articles/view/71460" class="centerarticle-entry-image" target="_blank" rel="noopener" data-gtm-click-label="user-bookmark-thumb"> <img src="https://cdn-ak-scissors.b.st-hatena.com/image/square/e3498ac485839b87a110da893ebbda874af6d269/height=288;version=1;width=512/https%3A%2F%2Fresearch-er.jp%2Fimg%2Farticle%2F20180611%2F20180611165957.png" alt="【プレスリリース】有機化学は炭素に限るか？～有機化学と無機化学を隔てる百年の謎に終止符～ | 日本の研究.com"> </a> </div> </div> <div class="centerarticle-reaction js-user-bookmark-id-container" id="bookmark-365709562"> <div class="centerarticle-reaction-comment js-user-bookmark-comment " data-url="https://research-er.jp/articles/view/71460" data-user-name="R2M"> <a href="/R2M/" data-gtm-click-label="user-reaction-usericon" class="centerarticle-reaction-thumb"> <img src="https://cdn.profile-image.st-hatena.com/users/R2M/profile.png" alt="R2M" title="R2M" class="centerarticle-reaction-image"> </a> <div class="centerarticle-reaction-main"> <span class="centerarticle-reaction-username"><a href="https://b.hatena.ne.jp/R2M/20180612#bookmark-365709562" class="js-anchor-path" data-gtm-click-label="user-reaction-username">R2M</a></span> <span class="centerarticle-reaction-timestamp">2018/06/12</span> <span class="js-private-icon status is-hidden"><img src="/images/v4/public/userpage/icon-private.svg" alt="非公開" width="10px" height="10px"></span> <div class="centerarticle-reaction-main-comment-tags"> <span class="js-comment"></span> <ul class="centerarticle-reaction-tags js-tag-text"> <li><a href="/R2M/%E7%A0%94%E7%A9%B6/" data-gtm-click-label="user-reaction-tag">研究</a></li> 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news.yahoo.co.jp </a> </li> <li><a href="/hotentry/economics" data-gtm-click-label="user-bookmark-category">政治と経済</a></li> </ul> <div class="centerarticle-entry-contents"> <p class="centerarticle-entry-summary">化学兵器は問題のほんの一部　人道的観点からいえば、シリアでの最大の問題は、戦闘員でない民間人（もちろん女性や子供までが含まれる）が日々大量に殺害され続けていることです。誰が殺害しているのかというと、人数的には圧倒的にアサド政権軍になります。ただし、アサド政権軍は軍事的に、もはや完全に駐留<a data-gtm-click-label="entry-summary-keyword" href="/q/%E3%83%AD%E3%82%B7%E3%82%A2">ロシア</a>軍、およびイラン陣営（イラン革命防衛隊、ヒズボラ、アフガニスタン人傭兵、イラク人シーア派民兵など）と一体化しています。つまり、アサド＝<a data-gtm-click-label="entry-summary-keyword" href="/q/%E3%83%AD%E3%82%B7%E3%82%A2">ロシア</a>＝イラン同盟軍が、シリアの民間人を圧倒的に殺害し続けているわけです。その殺害手法は、反体制派地域の<a data-gtm-click-label="entry-summary-keyword" href="/q/%E4%BD%8F%E5%AE%85">住宅</a>地に対する樽爆弾やミサイルなどによる空爆、あるいは無差別な砲撃などが多い。したがって、<a data-gtm-click-label="entry-summary-keyword" href="/q/%E6%88%A6%E4%BA%89">戦争</a>犯罪である民間人居住地域への無差別攻撃をやめさせることが重要です。化学兵器使用は、その攻撃の中では被害も大きいものですが、アサド政権の<a data-gtm-click-label="entry-summary-keyword" 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Giri, et al., Nature, 527, 216-220 (2015). ナノ～メゾスコピックなサイズの穴が無数にあいた多孔質物質，例えばシリカゲル，活性炭，ゼオライトなどは，ガス吸着やさまざまな分子の選択的な分離，触媒担体としての利用など，工業的にさまざまな分野で使用されている．さらに，近年の向上等における排ガス処理の要求のもと，各種ガスの選択的分離への応用を目指し各地で研究が行われている．このように固体の多孔質物質は確かに非常に便利であるのだが，固体であるがゆえに移送などの面では取り扱いが面倒であることも否めない．例えば液体であればポンプを使って連続的に移動させる事が可能であり，吸着・反応・脱着などを位置を変えながら連続して行うフロー処理・バッチ処理に向いている．これが固体となると同様の事を行うのは</p> </div> </div> <div class="centerarticle-reaction js-user-bookmark-id-container" id="bookmark-272755475"> <div class="centerarticle-reaction-comment js-user-bookmark-comment " data-url="http://srad.jp/~phason/journal/598007/" data-user-name="R2M"> <a href="/R2M/" data-gtm-click-label="user-reaction-usericon" class="centerarticle-reaction-thumb"> <img src="https://cdn.profile-image.st-hatena.com/users/R2M/profile.png" alt="R2M" title="R2M" class="centerarticle-reaction-image"> </a> <div class="centerarticle-reaction-main"> <span class="centerarticle-reaction-username"><a href="https://b.hatena.ne.jp/R2M/20151204#bookmark-272755475" class="js-anchor-path" data-gtm-click-label="user-reaction-username">R2M</a></span> <span class="centerarticle-reaction-timestamp">2015/12/04</span> <span class="js-private-icon status is-hidden"><img src="/images/v4/public/userpage/icon-private.svg" alt="非公開" width="10px" height="10px"></span> <div class="centerarticle-reaction-main-comment-tags"> <span class="js-comment"></span> <ul class="centerarticle-reaction-tags js-tag-text"> <li><a href="/R2M/%E5%8C%96%E5%AD%A6/" data-gtm-click-label="user-reaction-tag">化学</a></li> </ul> </div> <div class="centerarticle-reaction-foot"> <div class="centerarticle-reaction-meta"> <span class="comment-permalink js-comment-permalink"> <a href="/entry/272755475/comment/R2M" data-gtm-click-label="user-reaction-permalink" rel="nofollow">リンク</a> </span> <span class="list-star-container js-list-star-container"></span> <span class="twitter-click js-short-url-clicks"></span> </div> <ul class="centerarticle-reaction-menu"> <li class="js-add-star-container add-star-container"></li> </ul> </div> </div> </div> </div> <ul class="centerarticle-reaction-following js-user-following-bookmarks-icon"> </ul> <div class="js-user-following-bookmarks-detail is-hidden"> </div> </li> <li class="bookmark-item js-user-bookmark-item js-intent-share-bookmark" data-target-url="http://www.chem-station.com/blog/2014/12/adipicacid.html"> <div class="centerarticle-entry "> <h3 class="centerarticle-entry-title"> <a href="http://www.chem-station.com/blog/2014/12/adipicacid.html" class="js-clickable-link js-keyboard-openable" target="_blank" rel="noopener" data-gtm-click-label="user-bookmark-title"><img class="centerarticle-entry-favicon" src="https://cdn-ak2.favicon.st-hatena.com/64?url=https%3A%2F%2Fwww.chem-station.com%2Fblog%2F2014%2F12%2Fadipicacid.html" alt="">オゾンと光だけでアジピン酸をつくる | Chem-Station (ケムステ)</a> </h3> <ul class="centerarticle-entry-data"> <li> <span class="centerarticle-users"> <a href="/entry/s/www.chem-station.com/blog/2014/12/adipicacid.html" class="js-keyboard-entry-page-openable" title="オゾンと光だけでアジピン酸をつくる | Chem-Station (ケムステ) (8ブックマーク)" data-gtm-click-label="user-bookmark-users">8 users</a> </span> </li> <li> <a href="/R2M/?url=https%3A%2F%2Fwww.chem-station.com%2F" title="『www.chem-station.com』の新着エントリー" data-gtm-click-label="user-bookmark-domain"> www.chem-station.com </a> </li> <li><a href="/hotentry/knowledge" data-gtm-click-label="user-bookmark-category">学び</a></li> </ul> <div class="centerarticle-entry-contents"> <p class="centerarticle-entry-summary">化学者のつぶやきオゾンと光だけでアジピン酸をつくる 2014/12/26 化学者のつぶやき, 論文合成法コメント: 1 投稿者: webmaster さアジピン酸(adipic acid)といえば高校でも習うナイロン6-6の原料であり、現在でも最も重要な化学工業の原料の一つと言っても過言ではありません。 2013年現在、350トン以上生産され、過去5年の生産量の推移をみると、その生産量は毎年5%以上増加しています。この度、そのアジピン酸を、オゾン（O3）と光だけでつくってしまうという驚愕な研究結果がScienceに報告されました。 One-pot room-<a data-gtm-click-label="entry-summary-keyword" href="/q/temp">temp</a>erature conversion of cyclohexane to adipic acid by ozone and UV light Hwang, K.; Sagadevan, A. 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