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Ma</title> <meta name="description" content="Search results for: Hong-Fang Ma"> <meta name="keywords" content="Hong-Fang Ma"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none navbar-toggler ml-auto" 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id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="Hong-Fang Ma"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 13</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: Hong-Fang Ma</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13</span> Catalytic Cracking of Butene to Propylene over Modified HZSM-5 Zeolites</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jianwen%20Li">Jianwen Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Qiwen%20Sun"> Qiwen Sun</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Catalytic cracking of butene to propylene was carried out in a continuous-flow fixed-bed reactor over HZSM-5 catalysts modified by nickel and phosphorus. The structure and acidity of catalysts were measured by N2 adsorption, NH3-TPD and XPS. The results revealed that surface area and strong acid sites both decreased with increasing phosphorus loadings. The increment of phosphorus loadings reduced the butene conversion but enhanced the propylene selectivity and catalyst stability. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=butene" title="butene">butene</a>, <a href="https://publications.waset.org/abstracts/search?q=catalytic%20cracking" title=" catalytic cracking"> catalytic cracking</a>, <a href="https://publications.waset.org/abstracts/search?q=HZSM-5" title=" HZSM-5"> HZSM-5</a>, <a href="https://publications.waset.org/abstracts/search?q=modification" title=" modification"> modification</a> </p> <a href="https://publications.waset.org/abstracts/9660/catalytic-cracking-of-butene-to-propylene-over-modified-hzsm-5-zeolites" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/9660.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">393</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">12</span> The Preparation of High Surface Area Ni/MgAl2O4 Catalysts for Syngas Methanation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jingyu%20Zhou">Jingyu Zhou</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> High surface area MgAl2O4 supported Nickel catalysts with PVA loadings varying from 0% to 15% were prepared by precipitation and impregnation method. The catalysts were characterized by low temperature N2 adsorption/desorption, X-ray diffraction and H2 temperature programmed reduction. Compared with Ni/γ-Al2O3 catalyst, Ni/MgAl2O4 catalysts exhibited higher activity and selectivity in high temperature. Among the catalysts, Ni/MgAl2O4-5P with 5 wt% PVA showed the best performance, and achieved 95% CO conversion and 96% CH4 selectivity at 600°C, 2.0 MPa, and a WHSV of 12,000 mL·g⁻¹.h⁻¹. It also maintained good stability in 50h life test. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=methanation" title="methanation">methanation</a>, <a href="https://publications.waset.org/abstracts/search?q=MgAl2O4%20support" title=" MgAl2O4 support"> MgAl2O4 support</a>, <a href="https://publications.waset.org/abstracts/search?q=PVA" title=" PVA"> PVA</a>, <a href="https://publications.waset.org/abstracts/search?q=high%20surface%20area" title=" high surface area"> high surface area</a> </p> <a href="https://publications.waset.org/abstracts/60130/the-preparation-of-high-surface-area-nimgal2o4-catalysts-for-syngas-methanation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/60130.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">335</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">11</span> Na Promoted Ni/γ-Al2O3 Catalysts Prepared by Solution Combustion Method for Syngas Methanation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yan%20Zeng">Yan Zeng</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Ni-based catalysts with different amounts of Na as promoter from 2 to 6 wt % were prepared by solution combustion method. The catalytic activity was investigated in syngas methanation reaction. Carbon oxides conversion and methane selectivity are greatly influenced by sodium loading. Adding 2 wt% Na remarkably improves catalytic activity and long-term stability, attributed to its smaller mean NiO particle size, better distribution, and milder metal-support interaction. However, excess addition of Na results in deactivation distinctly due to the blockage of active sites. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nickel%20catalysts" title="nickel catalysts">nickel catalysts</a>, <a href="https://publications.waset.org/abstracts/search?q=syngas%20methanation" title=" syngas methanation"> syngas methanation</a>, <a href="https://publications.waset.org/abstracts/search?q=sodium" title=" sodium"> sodium</a>, <a href="https://publications.waset.org/abstracts/search?q=solution%20combustion%20method" title=" solution combustion method "> solution combustion method </a> </p> <a href="https://publications.waset.org/abstracts/9499/na-promoted-nigh-al2o3-catalysts-prepared-by-solution-combustion-method-for-syngas-methanation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/9499.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">407</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">10</span> The Catalytic Properties of PtSn/Al2O3 for Acetic Acid Hydrogenation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mingchuan%20Zhou">Mingchuan Zhou</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Alumina supported platinum and tin catalysts with different loadings of Pt and Sn were prepared and characterized by low temperature N<sub>2</sub> adsorption/desorption, H<sub>2</sub>-temperature programed reduction and CO pulse chemisorption. Pt and Sn below 1% loading were suitable for acetic acid hydrogenation. The best performance over 0.75Pt1Sn/Al<sub>2</sub>O<sub>3</sub> can reach 87.55% conversion of acetic acid and 47.39% selectivity of ethanol. The operating conditions of acetic acid hydrogenation over 1Pt1Sn/Al<sub>2</sub>O<sub>3</sub> were investigated. High reaction temperature can enhance the conversion of acetic acid, but it decreased total selectivity of ethanol and acetyl acetate. High pressure and low weight hourly space velocity were beneficial to both conversion of acetic acid and selectivity to ethanol. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=acetic%20acid" title="acetic acid">acetic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogenation" title=" hydrogenation"> hydrogenation</a>, <a href="https://publications.waset.org/abstracts/search?q=operating%20condition" title=" operating condition"> operating condition</a>, <a href="https://publications.waset.org/abstracts/search?q=PtSn" title=" PtSn"> PtSn</a> </p> <a href="https://publications.waset.org/abstracts/46773/the-catalytic-properties-of-ptsnal2o3-for-acetic-acid-hydrogenation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/46773.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">355</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">9</span> Catalytic Study of Methanol-to-Propylene Conversion over Nano-Sized HZSM-5</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jianwen%20Li">Jianwen Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Weixin%20Qian"> Weixin Qian</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Methanol-to-propylene conversion was carried out in a continuous-flow fixed-bed reactor over nano-sized HZSM-5 zeolites. The HZSM-5 catalysts were synthesized with different Si/Al ratio and silicon sources, and treated with NaOH. The structural property, morphology, and acidity of catalysts were measured by XRD, N<sub>2</sub> adsorption, FE-SEM, TEM, and NH<sub>3</sub>-TPD. The results indicate that the increment of Si/Al ratio decreased the acidity of catalysts and then improved propylene selectivity, while silicon sources had slight impact on the acidity but affected the product distribution. The desilication after alkali treatment could increase intracrystalline mesopores and enhance propylene selectivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=alkali%20treatment" title="alkali treatment">alkali treatment</a>, <a href="https://publications.waset.org/abstracts/search?q=HZSM-5" title=" HZSM-5"> HZSM-5</a>, <a href="https://publications.waset.org/abstracts/search?q=methanol-to-propylene" title=" methanol-to-propylene"> methanol-to-propylene</a>, <a href="https://publications.waset.org/abstracts/search?q=synthesis%20condition" title=" synthesis condition"> synthesis condition</a> </p> <a href="https://publications.waset.org/abstracts/86788/catalytic-study-of-methanol-to-propylene-conversion-over-nano-sized-hzsm-5" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/86788.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">217</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">8</span> Butene Catalytic Cracking to Propylene over Iron and Phosphorus Modified HZSM-5</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jianwen%20Li">Jianwen Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Qiwen%20Sun"> Qiwen Sun</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> HZSM-5 zeolites modified by iron and phosphorus were applied in catalytic cracking of butene. N2 adsorption and NH3-TPD were employed to measure the structure and acidity of catalysts. The results indicate that increasing phosphorus loading decreased surface area, pore volume and strong acidity of catalysts. The introduction of phosphorus significantly decreased butene conversion and promoted propylene selectivity. The catalytic performance of catalyst was strongly dependent on the reaction conditions. Appropriate reaction conditions could suppress side reactions and enhance propylene selectivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=butene%20catalytic%20cracking" title="butene catalytic cracking">butene catalytic cracking</a>, <a href="https://publications.waset.org/abstracts/search?q=HZSM-5" title=" HZSM-5"> HZSM-5</a>, <a href="https://publications.waset.org/abstracts/search?q=modification" title=" modification"> modification</a>, <a href="https://publications.waset.org/abstracts/search?q=reaction%20conditions" title=" reaction conditions"> reaction conditions</a> </p> <a href="https://publications.waset.org/abstracts/22176/butene-catalytic-cracking-to-propylene-over-iron-and-phosphorus-modified-hzsm-5" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/22176.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">462</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">7</span> Cold Model Experimental Research on Particle Velocity Distribution in Gas-Solid Circulating Fluidized Bed for Methanol-To-Olefins Process</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yongzheng%20Li">Yongzheng Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Qiwen%20Sun"> Qiwen Sun</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Radial profiles of particle velocities were investigated in a 6.1 m tall methanol-to-olefins cold model experimental device using a TSI laser Doppler velocimeter. The measurement of axial levels was conducted in the full developed region. The effect of axial level on flow development was not obvious under the same operating condition. Superficial gas velocity and solid circulating rate had significant influence on particle velocity in the center region of the riser. Besides, comparisons between upward, downward and average particle velocity were conducted. The average particle velocity was close to upward velocity and higher than downward velocity in radial locations except the wall region of riser. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=circulating%20fluidized%20bed" title="circulating fluidized bed">circulating fluidized bed</a>, <a href="https://publications.waset.org/abstracts/search?q=laser%20doppler%20velocimeter" title=" laser doppler velocimeter"> laser doppler velocimeter</a>, <a href="https://publications.waset.org/abstracts/search?q=particle%20velocity" title=" particle velocity"> particle velocity</a>, <a href="https://publications.waset.org/abstracts/search?q=radial%20profile" title=" radial profile"> radial profile</a> </p> <a href="https://publications.waset.org/abstracts/25000/cold-model-experimental-research-on-particle-velocity-distribution-in-gas-solid-circulating-fluidized-bed-for-methanol-to-olefins-process" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/25000.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">370</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">6</span> Effect of the Support Shape on Fischer-Tropsch Cobalt Catalyst Performance</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jian%20Huang">Jian Huang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weixin%20Qian"> Weixin Qian</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Cobalt catalysts were supported on extruded silica carrier and different-type (SiO<sub>2</sub>, γ-Al<sub>2</sub>O<sub>3</sub>) commercial supports with different shapes and sizes to produce heavy hydrocarbons for Fischer-Tropsch synthesis. The catalysts were characterized by N<sub>2</sub> physisorption and H<sub>2</sub>-TPR. The catalytic performance of the catalysts was tested in a fixed bed reactor. The results of Fischer-Tropsch synthesis performance showed that the cobalt catalyst supported on spherical silica supports displayed a higher activity and a higher selectivity to C<sub>5</sub><sup>+</sup> products, due to the fact that the active components were only distributed in the surface layer of spherical carrier, and the influence of gas diffusion restriction on catalytic performance was weakened. Therefore, it can be concluded that the eggshell cobalt catalyst was superior to precious metals modified catalysts in the synthesis of heavy hydrocarbons. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=fischer-tropsch%20synthesis" title="fischer-tropsch synthesis">fischer-tropsch synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=cobalt%20catalyst" title=" cobalt catalyst"> cobalt catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=support%20shape" title=" support shape"> support shape</a>, <a href="https://publications.waset.org/abstracts/search?q=heavy%20hydrocarbons" title=" heavy hydrocarbons"> heavy hydrocarbons</a> </p> <a href="https://publications.waset.org/abstracts/86645/effect-of-the-support-shape-on-fischer-tropsch-cobalt-catalyst-performance" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/86645.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">283</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5</span> The Performance of PtSn/Al₂O₃ with Cylindrical Particles for Acetic Acid Hydrogenation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mingchuan%20Zhou">Mingchuan Zhou</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Alumina supported PtSn catalysts with cylindrical particles were prepared and characterized by using low temperature N2 adsorption/desorption and X-ray diffraction. Low temperature N2 adsorption/desorption demonstrate that the tableting changed the texture properties of catalysts. XRD pattern indicate that the crystal structure of supports had no change after reaction. The performances over particles of PtSn/Al2O3 catalysts were investigated with regards to reaction temperature, pressure, and H2/AcOH mole ratio. After tableting, the conversion of acetic acid and selectivity of ethanol and acetyl acetate decreased. High reaction temperature and pressure can improve conversion of acetic acid. H2/AcOH mole ratio of 9.36 showed the best performance on acetic acid hydrogenation. High pressure had benefits for the selectivity of ethanol and other two parameters had no obvious effect on selectivity.   <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=acetic%20acid%20hydrogenation" title="acetic acid hydrogenation">acetic acid hydrogenation</a>, <a href="https://publications.waset.org/abstracts/search?q=cylindrical%20particles" title=" cylindrical particles"> cylindrical particles</a>, <a href="https://publications.waset.org/abstracts/search?q=ethanol" title=" ethanol"> ethanol</a>, <a href="https://publications.waset.org/abstracts/search?q=PtSn" title=" PtSn"> PtSn</a> </p> <a href="https://publications.waset.org/abstracts/49368/the-performance-of-ptsnal2o3-with-cylindrical-particles-for-acetic-acid-hydrogenation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/49368.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">319</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4</span> Effect of Si/Al Ratio on SSZ-13 Crystallization and Its Methanol-To-Olefins Catalytic Properties</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Zhiqiang%20Xu">Zhiqiang Xu</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weixin%20Qian"> Weixin Qian</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> SSZ-13 materials with different Si/Al ratio were prepared by varying the composition of aluminosilicate precursor solutions upon hydrothermal treatment at 150 °C. The Si/Al ratio of the initial system was systematically changed from 12.5 to infinity in order to study the limits of Al composition in precursor solutions for constructing CHA structure. The intermediates and final products were investigated by complementary techniques such as XRD, HRTEM, FESEM, and chemical analysis. NH<sub>3</sub>-TPD was used to study the Brønsted acidity of SSZ-13 samples with different Si/Al ratios. The effect of the Si/Al ratio on the precursor species, ultimate crystal size, morphology and yield was investigated. The results revealed that Al species determine the nucleation rate and the number of nuclei, which is tied to the morphology and yield of SSZ-13. The size of SSZ-13 increased and the yield decreased as the Si/Al ratio was improved. Varying Si/Al ratio of the initial system is a facile, commercially viable method of tailoring SSZ-13 crystal size and morphology. Furthermore, SSZ-13 materials with different Si/Al ratio were tested as catalysts for the methanol to olefins (MTO) reaction at 350 °C. SSZ-13 with the Si/Al ratio of 35 shows the best MTO catalytic performance. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=crystallization" title="crystallization">crystallization</a>, <a href="https://publications.waset.org/abstracts/search?q=MTO" title=" MTO"> MTO</a>, <a href="https://publications.waset.org/abstracts/search?q=Si%2FAl%20ratio" title=" Si/Al ratio"> Si/Al ratio</a>, <a href="https://publications.waset.org/abstracts/search?q=SSZ-13" title=" SSZ-13"> SSZ-13</a> </p> <a href="https://publications.waset.org/abstracts/93128/effect-of-sial-ratio-on-ssz-13-crystallization-and-its-methanol-to-olefins-catalytic-properties" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/93128.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">294</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3</span> One Dimensional Reactor Modeling for Methanol Steam Reforming to Hydrogen</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma">Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Mingchuan%20Zhou"> Mingchuan Zhou</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> One dimensional pseudo-homogenous modeling has been performed for methanol steam reforming reactor. The results show that the models can well predict the industrial data. The reactor had minimum temperature along axial because of endothermic reaction. Hydrogen productions and temperature profiles along axial were investigated regarding operation conditions such as inlet mass flow rate and mass fraction of methanol, inlet temperature of external thermal oil. Low inlet mass flow rate of methanol, low inlet temperature, and high mass fraction of methanol decreased minimum temperature along axial. Low inlet mass flow rate of methanol, high mass fraction of methanol, and high inlet temperature of thermal oil made cold point forward. Low mass fraction, high mass flow rate, and high inlet temperature of thermal oil increased hydrogen production. One dimensional models can be a guide for industrial operation. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=reactor" title="reactor">reactor</a>, <a href="https://publications.waset.org/abstracts/search?q=modeling" title=" modeling"> modeling</a>, <a href="https://publications.waset.org/abstracts/search?q=methanol" title=" methanol"> methanol</a>, <a href="https://publications.waset.org/abstracts/search?q=steam%20reforming" title=" steam reforming"> steam reforming</a> </p> <a href="https://publications.waset.org/abstracts/86646/one-dimensional-reactor-modeling-for-methanol-steam-reforming-to-hydrogen" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/86646.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">298</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">2</span> Impact of Zn/Cr Ratio on ZnCrOx-SAPO-34 Bifunctional Catalyst for Direct Conversion of Syngas to Light Olefins</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yuxuan%20Huang">Yuxuan Huang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weixin%20Qian"> Weixin Qian</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Ma"> Hongfang Ma</a>, <a href="https://publications.waset.org/abstracts/search?q=Haitao%20Zhang"> Haitao Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Weiyong%20Ying"> Weiyong Ying</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Light olefins are important building blocks for chemical industry. Direct conversion of syngas to light olefins has been investigated for decades. Meanwhile, the limit for light olefins selectivity described by Anderson-Schulz-Flory (ASF) distribution model is still a great challenge to conventional Fischer-Tropsch synthesis. The emerging strategy called oxide-zeolite concept (OX-ZEO) is a promising way to get rid of this limit. ZnCrO<sub>x</sub> was prepared by co-precipitation method and (NH<sub>4</sub>)<sub>2</sub>CO<sub>3</sub> was used as precipitant. SAPO-34 was prepared by hydrothermal synthesis, and Tetraethylammonium hydroxide (TEAOH) was used as template, while silica sol, pseudo-boehmite, and phosphoric acid were Al, Si and P source, respectively. The bifunctional catalyst was prepared by mechanical mixing of ZnCrO<sub>x</sub> and SAPO-34. Catalytic reactions were carried out under H<sub>2</sub>/CO=2, 380 ℃, 1 MPa and 6000 mL·g<sub>cat</sub><sup>-1</sup>·h<sup>-1</sup> in a fixed-bed reactor with a quartz lining. Catalysts were characterized by XRD, N<sub>2</sub> adsorption-desorption, NH<sub>3</sub>-TPD, H<sub>2</sub>-TPR, and CO-TPD. The addition of Al as structure promoter enhances CO conversion and selectivity to light olefins. Zn/Cr ratio, which decides the active component content and chemisorption property of the catalyst, influences CO conversion and selectivity to light olefins at the same time. C<sub>2-4</sub><sup>=</sup> distribution of 86% among hydrocarbons at CO conversion of 14% was reached when Zn/Cr=1.5. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=light%20olefins" title="light olefins">light olefins</a>, <a href="https://publications.waset.org/abstracts/search?q=OX-ZEO" title=" OX-ZEO"> OX-ZEO</a>, <a href="https://publications.waset.org/abstracts/search?q=Syngas" title=" Syngas"> Syngas</a>, <a href="https://publications.waset.org/abstracts/search?q=ZnCrO%E2%82%93" title=" ZnCrOₓ"> ZnCrOₓ</a> </p> <a href="https://publications.waset.org/abstracts/93131/impact-of-zncr-ratio-on-zncrox-sapo-34-bifunctional-catalyst-for-direct-conversion-of-syngas-to-light-olefins" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/93131.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">180</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">1</span> Research on the Calculation Method of Smartization Rate of Concrete Structure Building Construction</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hongyu%20Ye">Hongyu Ye</a>, <a href="https://publications.waset.org/abstracts/search?q=Hong%20Zhang"> Hong Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Minjie%20Sun"> Minjie Sun</a>, <a href="https://publications.waset.org/abstracts/search?q=Hongfang%20Xu"> Hongfang Xu</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In the context of China's promotion of smart construction and building industrialization, there is a need for evaluation standards for the development of building industrialization based on assembly-type construction. However, the evaluation of smart construction remains a challenge in the industry's development process. This paper addresses this issue by proposing a calculation and evaluation method for the smartization rate of concrete structure building construction. The study focuses on examining the factors of smart equipment application and their impact on costs throughout the process of smart construction design, production, transfer, and construction. Based on this analysis, the paper presents an evaluation method for the smartization rate based on components. Furthermore, it introduces calculation methods for assessing the smartization rate of buildings. The paper also suggests a rapid calculation method for determining the smartization rate using Building Information Modeling (BIM) and information expression technology. The proposed research provides a foundation for the swift calculation of the smartization rate based on BIM and information technology. Ultimately, it aims to promote the development of smart construction and the construction of high-quality buildings in China. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=building%20industrialization" title="building industrialization">building industrialization</a>, <a href="https://publications.waset.org/abstracts/search?q=high%20quality%20building" title=" high quality building"> high quality building</a>, <a href="https://publications.waset.org/abstracts/search?q=smart%20construction" title=" smart construction"> smart construction</a>, <a href="https://publications.waset.org/abstracts/search?q=smartization%20rate" title=" smartization rate"> smartization rate</a>, <a href="https://publications.waset.org/abstracts/search?q=component" title=" component"> component</a> </p> <a href="https://publications.waset.org/abstracts/181557/research-on-the-calculation-method-of-smartization-rate-of-concrete-structure-building-construction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/181557.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">70</span> </span> </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/WASET-16th-foundational-anniversary.pdf">WASET celebrates its 16th foundational anniversary</a></li> 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