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Die Disulfid-Brücke ist <span style="color:blue;"><b>blau</b></span> markiert.</figcaption></figure> <p><b>Disulfide</b> sind <a href="/wiki/Chemische_Verbindung" title="Chemische Verbindung">chemische Verbindungen</a>, die zwei aneinander gebundene <a href="/wiki/Schwefel" title="Schwefel">Schwefelatome</a> enthalten. </p> <div id="toc" class="toc" role="navigation" aria-labelledby="mw-toc-heading"><input type="checkbox" role="button" id="toctogglecheckbox" class="toctogglecheckbox" style="display:none" /><div class="toctitle" lang="de" dir="ltr"><h2 id="mw-toc-heading">Inhaltsverzeichnis</h2><span class="toctogglespan"><label class="toctogglelabel" for="toctogglecheckbox"></label></span></div> <ul> <li class="toclevel-1 tocsection-1"><a href="#Ionische_Disulfide"><span class="tocnumber">1</span> <span class="toctext">Ionische Disulfide</span></a></li> <li class="toclevel-1 tocsection-2"><a href="#Kovalente_Disulfide"><span class="tocnumber">2</span> <span class="toctext">Kovalente Disulfide</span></a></li> <li class="toclevel-1 tocsection-3"><a href="#Vorkommen"><span class="tocnumber">3</span> <span class="toctext">Vorkommen</span></a></li> <li class="toclevel-1 tocsection-4"><a href="#Einzelnachweise"><span class="tocnumber">4</span> <span class="toctext">Einzelnachweise</span></a></li> </ul> </div> <div class="mw-heading mw-heading2"><h2 id="Ionische_Disulfide">Ionische Disulfide</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Disulfide&veaction=edit&section=1" title="Abschnitt bearbeiten: Ionische Disulfide" class="mw-editsection-visualeditor"><span>Bearbeiten</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Disulfide&action=edit&section=1" title="Quellcode des Abschnitts bearbeiten: Ionische Disulfide"><span>Quelltext bearbeiten</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Ionische Disulfide enthalten das <a href="/wiki/Anion" title="Anion">Anion</a> S<sub>2</sub><sup>2−</sup> und sind formal <a href="/wiki/Salze" title="Salze">Salze</a> des unbeständigen <a href="/wiki/Disulfan" title="Disulfan">Disulfans</a> H<sub>2</sub>S<sub>2</sub>. Das bekannteste Beispiel ist <a href="/wiki/Pyrit" title="Pyrit">Pyrit</a> (<a href="/wiki/Eisen(II)-disulfid" title="Eisen(II)-disulfid">FeS<sub>2</sub></a>), auch als Katzengold oder Narrengold bezeichnet. Weitere Vertreter sind <a href="/wiki/Cattierit" title="Cattierit">Cattierit</a> (<a href="/wiki/Cobaltdisulfid" title="Cobaltdisulfid">CoS<sub>2</sub></a>), <a href="/wiki/Vaesit" title="Vaesit">Vaesit</a> (<a href="/wiki/Nickeldisulfid" title="Nickeldisulfid">NiS<sub>2</sub></a>) und <a href="/wiki/Patr%C3%B3nit" title="Patrónit">Patrónit</a> (<a href="/wiki/Vanadiumtetrasulfid" class="mw-redirect" title="Vanadiumtetrasulfid">V[S<sub>2</sub>]<sub>2</sub></a>). </p> <div class="mw-heading mw-heading2"><h2 id="Kovalente_Disulfide">Kovalente Disulfide</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Disulfide&veaction=edit&section=2" title="Abschnitt bearbeiten: Kovalente Disulfide" class="mw-editsection-visualeditor"><span>Bearbeiten</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Disulfide&action=edit&section=2" title="Quellcode des Abschnitts bearbeiten: Kovalente Disulfide"><span>Quelltext bearbeiten</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/Datei:2010-09-26_Phallus_impudicus_crop.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/1/11/2010-09-26_Phallus_impudicus_crop.jpg/220px-2010-09-26_Phallus_impudicus_crop.jpg" decoding="async" width="220" height="286" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/11/2010-09-26_Phallus_impudicus_crop.jpg/330px-2010-09-26_Phallus_impudicus_crop.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/11/2010-09-26_Phallus_impudicus_crop.jpg/440px-2010-09-26_Phallus_impudicus_crop.jpg 2x" data-file-width="600" data-file-height="780" /></a><figcaption>Gemeine Stinkmorchel (<i>Phallus impudicus</i>) sondert unter anderem Dimethyldisulfid als Geruchsstoff ab.</figcaption></figure> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/Datei:Dimethyldisulfide_V1.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/96/Dimethyldisulfide_V1.svg/220px-Dimethyldisulfide_V1.svg.png" decoding="async" width="220" height="62" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/96/Dimethyldisulfide_V1.svg/330px-Dimethyldisulfide_V1.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/96/Dimethyldisulfide_V1.svg/440px-Dimethyldisulfide_V1.svg.png 2x" data-file-width="225" data-file-height="63" /></a><figcaption>Strukturformel von Dimethyldisulfid, des einfachsten kovalenten Disulfids.</figcaption></figure> <p><a href="/wiki/Atombindung" class="mw-redirect" title="Atombindung">Kovalente</a> Disulfide, veraltet auch Disulfane genannt,<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> haben die allgemeine Formel R<sup>1</sup>–S–S–R<sup>2</sup>. Bei symmetrischen Disulfiden gilt R<sup>1</sup> = R<sup>2</sup>, bei unsymmetrischen Disulfiden sind die organischen Reste R<sup>1</sup> und R<sup>2</sup> verschieden. </p><p>Niedermolekulare organische Disulfide sind unpolare, leicht flüchtige, übelriechende Stoffe. Der einfachste Vertreter dieser Stoffklasse ist <a href="/wiki/Dimethyldisulfid" title="Dimethyldisulfid">Dimethyldisulfid</a>. Bekannt ist das den charakteristischen Knoblauch- und Zwiebelgeruch hervorrufende <a href="/wiki/Diallyldisulfid" title="Diallyldisulfid">Diallyldisulfid</a>.<sup id="cite_ref-Gossauer229-230_2-0" class="reference"><a href="#cite_note-Gossauer229-230-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> Organische Disulfide mit einer höheren <a href="/wiki/Molare_Masse" title="Molare Masse">molaren Masse</a> sind dagegen geruchlos. </p> <div class="mw-heading mw-heading2"><h2 id="Vorkommen">Vorkommen</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Disulfide&veaction=edit&section=3" title="Abschnitt bearbeiten: Vorkommen" class="mw-editsection-visualeditor"><span>Bearbeiten</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Disulfide&action=edit&section=3" title="Quellcode des Abschnitts bearbeiten: Vorkommen"><span>Quelltext bearbeiten</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/Disulfidbr%C3%BCcke" title="Disulfidbrücke">Disulfidbrücken</a> in <a href="/wiki/Cystin" title="Cystin">Cystineinheiten</a> von <a href="/wiki/Protein" title="Protein">Proteinen</a> (<a href="/wiki/Insulin" title="Insulin">Insulin</a>, <a href="/wiki/Keratin" class="mw-redirect" title="Keratin">Keratin</a>, <a href="/wiki/Oxytocin" title="Oxytocin">Oxytocin</a> etc.) spielen für deren Tertiärstruktur eine wichtige Rolle. Weiterhin findet sich die Disulfidstruktur in <a href="/wiki/Heterocyclus" class="mw-redirect" title="Heterocyclus">heterocyclischen</a> <a href="/wiki/Naturstoffe" class="mw-redirect" title="Naturstoffe">Naturstoffen</a> wie (+)-<a href="/wiki/Lipons%C3%A4ure" title="Liponsäure">Liponsäure</a> und <a href="/wiki/Asparagusins%C3%A4ure" title="Asparagusinsäure">Asparagusinsäure</a>.<sup id="cite_ref-Gossauer229-232_3-0" class="reference"><a href="#cite_note-Gossauer229-232-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Einzelnachweise">Einzelnachweise</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Disulfide&veaction=edit&section=4" title="Abschnitt bearbeiten: Einzelnachweise" class="mw-editsection-visualeditor"><span>Bearbeiten</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Disulfide&action=edit&section=4" title="Quellcode des Abschnitts bearbeiten: Einzelnachweise"><span>Quelltext bearbeiten</span></a><span class="mw-editsection-bracket">]</span></span></div> <ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><a href="#cite_ref-1">↑</a></span> <span class="reference-text">Eintrag zu <i>sulfanes.</i> In: <a href="/wiki/International_Union_of_Pure_and_Applied_Chemistry" title="International Union of Pure and Applied Chemistry">IUPAC</a> (Hrsg.): <i><a href="/wiki/Compendium_of_Chemical_Terminology" title="Compendium of Chemical Terminology">Compendium of Chemical Terminology</a>.</i> The “Gold Book”. <a href="/wiki/Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1351/goldbook.S06092">10.1351/goldbook.S06092</a></span> – Version: 2.3.3.</span> </li> <li id="cite_note-Gossauer229-230-2"><span class="mw-cite-backlink"><a href="#cite_ref-Gossauer229-230_2-0">↑</a></span> <span class="reference-text"><a href="/wiki/Albert_Gossauer" title="Albert Gossauer">Albert Gossauer</a>: <i>Struktur und Reaktivität der Biomoleküle</i>, Verlag Helvetica Chimica Acta, Zürich, 2006, S. 229–230, <a href="/wiki/Spezial:ISBN-Suche/9783906390291" class="internal mw-magiclink-isbn">ISBN 978-3-906390-29-1</a>.</span> </li> <li id="cite_note-Gossauer229-232-3"><span class="mw-cite-backlink"><a href="#cite_ref-Gossauer229-232_3-0">↑</a></span> <span class="reference-text">Albert Gossauer: <i>Struktur und Reaktivität der Biomoleküle</i>, Verlag Helvetica Chimica Acta, Zürich, 2006, S. 229–232, <a href="/wiki/Spezial:ISBN-Suche/9783906390291" class="internal mw-magiclink-isbn">ISBN 978-3-906390-29-1</a>.</span> </li> </ol></div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1&useformat=desktop" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">Abgerufen von „<a dir="ltr" href="https://de.wikipedia.org/w/index.php?title=Disulfide&oldid=244291607">https://de.wikipedia.org/w/index.php?title=Disulfide&oldid=244291607</a>“</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Wikipedia:Kategorien" title="Wikipedia:Kategorien">Kategorien</a>: <ul><li><a href="/wiki/Kategorie:Organisches_Disulfid" title="Kategorie:Organisches Disulfid">Organisches Disulfid</a></li><li><a href="/wiki/Kategorie:Stoffgruppe" title="Kategorie:Stoffgruppe">Stoffgruppe</a></li></ul></div></div> </div> </div> <div id="mw-navigation"> <h2>Navigationsmenü</h2> <div id="mw-head"> <nav id="p-personal" class="mw-portlet mw-portlet-personal vector-user-menu-legacy vector-menu" aria-labelledby="p-personal-label" > <h3 id="p-personal-label" class="vector-menu-heading " > <span class="vector-menu-heading-label">Meine Werkzeuge</span> </h3> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="pt-anonuserpage" class="mw-list-item"><span title="Benutzerseite der IP-Adresse, von der aus du Änderungen durchführst">Nicht angemeldet</span></li><li id="pt-anontalk" class="mw-list-item"><a href="/wiki/Spezial:Meine_Diskussionsseite" title="Diskussion über Änderungen von dieser IP-Adresse [n]" accesskey="n"><span>Diskussionsseite</span></a></li><li id="pt-anoncontribs" class="mw-list-item"><a href="/wiki/Spezial:Meine_Beitr%C3%A4ge" title="Eine Liste der Bearbeitungen, die von dieser IP-Adresse gemacht wurden [y]" accesskey="y"><span>Beiträge</span></a></li><li id="pt-createaccount" class="mw-list-item"><a href="/w/index.php?title=Spezial:Benutzerkonto_anlegen&returnto=Disulfide" title="Wir ermutigen dich dazu, ein Benutzerkonto zu erstellen und dich anzumelden. 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class="mw-list-item"><a href="/w/index.php?title=Spezial:DownloadAsPdf&page=Disulfide&action=show-download-screen"><span>Als PDF herunterladen</span></a></li><li id="t-print" class="mw-list-item"><a href="/w/index.php?title=Disulfide&printable=yes" title="Druckansicht dieser Seite [p]" accesskey="p"><span>Druckversion</span></a></li> </ul> </div> </nav> <nav id="p-wikibase-otherprojects" class="mw-portlet mw-portlet-wikibase-otherprojects vector-menu-portal portal vector-menu" aria-labelledby="p-wikibase-otherprojects-label" > <h3 id="p-wikibase-otherprojects-label" class="vector-menu-heading " > <span class="vector-menu-heading-label">In anderen Projekten</span> </h3> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="wb-otherproject-link wb-otherproject-commons mw-list-item"><a href="https://commons.wikimedia.org/wiki/Category:Disulfides" hreflang="en"><span>Commons</span></a></li><li id="t-wikibase" class="wb-otherproject-link wb-otherproject-wikibase-dataitem mw-list-item"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q1230226" title="Link zum verbundenen Objekt im Datenrepositorium [g]" accesskey="g"><span>Wikidata-Datenobjekt</span></a></li> </ul> </div> </nav> <nav id="p-lang" class="mw-portlet mw-portlet-lang vector-menu-portal portal vector-menu" aria-labelledby="p-lang-label" > <h3 id="p-lang-label" class="vector-menu-heading " > <span class="vector-menu-heading-label">In anderen Sprachen</span> </h3> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%AB%D9%86%D8%A7%D8%A6%D9%8A_%D9%83%D8%A8%D8%B1%D9%8A%D8%AA%D9%8A%D8%AF" title="ثنائي كبريتيد – Arabisch" lang="ar" hreflang="ar" data-title="ثنائي كبريتيد" data-language-autonym="العربية" data-language-local-name="Arabisch" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-bg mw-list-item"><a href="https://bg.wikipedia.org/wiki/%D0%94%D0%B8%D1%81%D1%83%D0%BB%D1%84%D0%B8%D0%B4" title="Дисулфид – Bulgarisch" lang="bg" hreflang="bg" data-title="Дисулфид" data-language-autonym="Български" data-language-local-name="Bulgarisch" class="interlanguage-link-target"><span>Български</span></a></li><li class="interlanguage-link interwiki-bs mw-list-item"><a href="https://bs.wikipedia.org/wiki/Disulfid" title="Disulfid – Bosnisch" lang="bs" hreflang="bs" data-title="Disulfid" data-language-autonym="Bosanski" data-language-local-name="Bosnisch" class="interlanguage-link-target"><span>Bosanski</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Disulfidy" title="Disulfidy – Tschechisch" lang="cs" hreflang="cs" data-title="Disulfidy" data-language-autonym="Čeština" data-language-local-name="Tschechisch" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Disulfide" title="Disulfide – Englisch" lang="en" hreflang="en" data-title="Disulfide" data-language-autonym="English" data-language-local-name="Englisch" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-eo mw-list-item"><a href="https://eo.wikipedia.org/wiki/Dusulfido" title="Dusulfido – Esperanto" lang="eo" hreflang="eo" data-title="Dusulfido" data-language-autonym="Esperanto" data-language-local-name="Esperanto" class="interlanguage-link-target"><span>Esperanto</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Disulfuro" title="Disulfuro – Spanisch" lang="es" hreflang="es" data-title="Disulfuro" data-language-autonym="Español" data-language-local-name="Spanisch" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%AF%DB%8C%E2%80%8C%D8%B3%D9%88%D9%84%D9%81%DB%8C%D8%AF" title="دی‌سولفید – Persisch" lang="fa" hreflang="fa" data-title="دی‌سولفید" data-language-autonym="فارسی" data-language-local-name="Persisch" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Disulfidi" title="Disulfidi – Finnisch" lang="fi" hreflang="fi" data-title="Disulfidi" data-language-autonym="Suomi" data-language-local-name="Finnisch" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Disulfure" title="Disulfure – Französisch" lang="fr" hreflang="fr" data-title="Disulfure" data-language-autonym="Français" data-language-local-name="Französisch" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hr mw-list-item"><a href="https://hr.wikipedia.org/wiki/Disulfid" title="Disulfid – Kroatisch" lang="hr" hreflang="hr" data-title="Disulfid" data-language-autonym="Hrvatski" data-language-local-name="Kroatisch" class="interlanguage-link-target"><span>Hrvatski</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Disulfida" title="Disulfida – Indonesisch" lang="id" hreflang="id" data-title="Disulfida" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesisch" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Disolfuro" title="Disolfuro – Italienisch" lang="it" hreflang="it" data-title="Disolfuro" data-language-autonym="Italiano" data-language-local-name="Italienisch" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%82%B8%E3%82%B9%E3%83%AB%E3%83%95%E3%82%A3%E3%83%89" title="ジスルフィド – Japanisch" lang="ja" hreflang="ja" data-title="ジスルフィド" data-language-autonym="日本語" data-language-local-name="Japanisch" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-kk mw-list-item"><a href="https://kk.wikipedia.org/wiki/%D0%94%D0%B8%D1%81%D1%83%D0%BB%D1%8C%D1%84%D0%B8%D0%B4%D1%82%D0%B5%D1%80" title="Дисульфидтер – Kasachisch" lang="kk" hreflang="kk" data-title="Дисульфидтер" data-language-autonym="Қазақша" data-language-local-name="Kasachisch" class="interlanguage-link-target"><span>Қазақша</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%EC%9D%B4%ED%99%A9%ED%99%94%EB%AC%BC" title="이황화물 – Koreanisch" lang="ko" hreflang="ko" data-title="이황화물" data-language-autonym="한국어" data-language-local-name="Koreanisch" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-ms mw-list-item"><a href="https://ms.wikipedia.org/wiki/Disulfida" title="Disulfida – Malaiisch" lang="ms" hreflang="ms" data-title="Disulfida" data-language-autonym="Bahasa Melayu" data-language-local-name="Malaiisch" class="interlanguage-link-target"><span>Bahasa Melayu</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Disiarczki" title="Disiarczki – Polnisch" lang="pl" hreflang="pl" data-title="Disiarczki" data-language-autonym="Polski" data-language-local-name="Polnisch" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Dissulfeto" title="Dissulfeto – Portugiesisch" lang="pt" hreflang="pt" data-title="Dissulfeto" data-language-autonym="Português" data-language-local-name="Portugiesisch" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Disulfur%C4%83" title="Disulfură – Rumänisch" lang="ro" hreflang="ro" data-title="Disulfură" data-language-autonym="Română" data-language-local-name="Rumänisch" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Disulfid" title="Disulfid – Serbokroatisch" lang="sh" hreflang="sh" data-title="Disulfid" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="Serbokroatisch" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Disulfid" title="Disulfid – Serbisch" lang="sr" hreflang="sr" data-title="Disulfid" data-language-autonym="Српски / srpski" 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