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Electrometallurgy - Wikipedia

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interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%B9%D9%84%D9%85_%D8%A7%D9%84%D9%81%D9%84%D8%B2%D8%A7%D8%AA_%D8%A7%D9%84%D9%83%D9%87%D8%B1%D8%A8%D8%A7%D8%A6%D9%8A" title="علم الفلزات الكهربائي – Arabic" lang="ar" hreflang="ar" data-title="علم الفلزات الكهربائي" data-language-autonym="العربية" data-language-local-name="Arabic" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-bn mw-list-item"><a href="https://bn.wikipedia.org/wiki/%E0%A6%A4%E0%A6%A1%E0%A6%BC%E0%A6%BF%E0%A7%8E-%E0%A6%A7%E0%A6%BE%E0%A6%A4%E0%A7%81%E0%A6%AC%E0%A6%BF%E0%A6%9C%E0%A7%8D%E0%A6%9E%E0%A6%BE%E0%A6%A8" title="তড়িৎ-ধাতুবিজ্ঞান – Bangla" lang="bn" hreflang="bn" data-title="তড়িৎ-ধাতুবিজ্ঞান" data-language-autonym="বাংলা" data-language-local-name="Bangla" class="interlanguage-link-target"><span>বাংলা</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Electrometalurgia" title="Electrometalurgia – Spanish" lang="es" hreflang="es" data-title="Electrometalurgia" data-language-autonym="Español" data-language-local-name="Spanish" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/%C3%89lectrom%C3%A9tallurgie" title="Électrométallurgie – French" lang="fr" hreflang="fr" data-title="Électrométallurgie" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%B5%E0%A4%BF%E0%A4%A6%E0%A5%8D%E0%A4%AF%E0%A5%81%E0%A4%A4%E0%A4%A7%E0%A4%BE%E0%A4%A4%E0%A5%81%E0%A4%95%E0%A4%B0%E0%A5%8D%E0%A4%AE" title="विद्युतधातुकर्म – Hindi" lang="hi" hreflang="hi" data-title="विद्युतधातुकर्म" data-language-autonym="हिन्दी" data-language-local-name="Hindi" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Elektrometalurgi" title="Elektrometalurgi – Indonesian" lang="id" hreflang="id" data-title="Elektrometalurgi" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesian" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Elettrometallurgia" title="Elettrometallurgia – Italian" lang="it" hreflang="it" data-title="Elettrometallurgia" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-kk mw-list-item"><a href="https://kk.wikipedia.org/wiki/%D0%AD%D0%BB%D0%B5%D0%BA%D1%82%D1%80%D0%BC%D0%B5%D1%82%D0%B0%D0%BB%D0%BB%D1%83%D1%80%D0%B3%D0%B8%D1%8F" title="Электрметаллургия – Kazakh" lang="kk" hreflang="kk" data-title="Электрметаллургия" data-language-autonym="Қазақша" data-language-local-name="Kazakh" class="interlanguage-link-target"><span>Қазақша</span></a></li><li class="interlanguage-link interwiki-ms mw-list-item"><a href="https://ms.wikipedia.org/wiki/Elektrometalurgi" title="Elektrometalurgi – Malay" lang="ms" hreflang="ms" data-title="Elektrometalurgi" data-language-autonym="Bahasa Melayu" data-language-local-name="Malay" class="interlanguage-link-target"><span>Bahasa Melayu</span></a></li><li class="interlanguage-link interwiki-uz mw-list-item"><a href="https://uz.wikipedia.org/wiki/Elektrometallurgiya" title="Elektrometallurgiya – Uzbek" lang="uz" hreflang="uz" data-title="Elektrometallurgiya" data-language-autonym="Oʻzbekcha / ўзбекча" data-language-local-name="Uzbek" class="interlanguage-link-target"><span>Oʻzbekcha / ўзбекча</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Elektrometalurgia" title="Elektrometalurgia – Polish" lang="pl" hreflang="pl" data-title="Elektrometalurgia" data-language-autonym="Polski" data-language-local-name="Polish" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%AD%D0%BB%D0%B5%D0%BA%D1%82%D1%80%D0%BE%D0%BC%D0%B5%D1%82%D0%B0%D0%BB%D0%BB%D1%83%D1%80%D0%B3%D0%B8%D1%8F" title="Электрометаллургия – Russian" lang="ru" hreflang="ru" data-title="Электрометаллургия" data-language-autonym="Русский" data-language-local-name="Russian" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%95%D0%BB%D0%B5%D0%BA%D1%82%D1%80%D0%BE%D0%BC%D0%B5%D1%82%D0%B0%D0%BB%D1%83%D1%80%D0%B3%D1%96%D1%8F" title="Електрометалургія – Ukrainian" lang="uk" hreflang="uk" data-title="Електрометалургія" 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.ambox{display:none!important}}</style><table class="box-One_source plainlinks metadata ambox ambox-content ambox-one_source" role="presentation"><tbody><tr><td class="mbox-image"><div class="mbox-image-div"><span typeof="mw:File"><a href="/wiki/File:Question_book-new.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/en/thumb/9/99/Question_book-new.svg/50px-Question_book-new.svg.png" decoding="async" width="50" height="39" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/9/99/Question_book-new.svg/75px-Question_book-new.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/9/99/Question_book-new.svg/100px-Question_book-new.svg.png 2x" data-file-width="512" data-file-height="399" /></a></span></div></td><td class="mbox-text"><div class="mbox-text-span">This article <b>relies largely or entirely on a <a href="/wiki/Wikipedia:Articles_with_a_single_source" title="Wikipedia:Articles with a single source">single source</a></b>.<span 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Please help <a class="external text" href="https://en.wikipedia.org/w/index.php?title=Electrometallurgy&amp;action=edit">improve this article</a> by <a href="/wiki/Help:Referencing_for_beginners" title="Help:Referencing for beginners">introducing citations to additional sources</a>.<br /><small><span class="plainlinks"><i>Find sources:</i>&#160;<a rel="nofollow" class="external text" href="https://www.google.com/search?as_eq=wikipedia&amp;q=%22Electrometallurgy%22">"Electrometallurgy"</a>&#160;–&#160;<a rel="nofollow" class="external text" href="https://www.google.com/search?tbm=nws&amp;q=%22Electrometallurgy%22+-wikipedia&amp;tbs=ar:1">news</a>&#160;<b>·</b> <a rel="nofollow" class="external text" href="https://www.google.com/search?&amp;q=%22Electrometallurgy%22&amp;tbs=bkt:s&amp;tbm=bks">newspapers</a>&#160;<b>·</b> <a rel="nofollow" class="external text" href="https://www.google.com/search?tbs=bks:1&amp;q=%22Electrometallurgy%22+-wikipedia">books</a>&#160;<b>·</b> <a rel="nofollow" class="external text" href="https://scholar.google.com/scholar?q=%22Electrometallurgy%22">scholar</a>&#160;<b>·</b> <a rel="nofollow" class="external text" href="https://www.jstor.org/action/doBasicSearch?Query=%22Electrometallurgy%22&amp;acc=on&amp;wc=on">JSTOR</a></span></small></span> <span class="date-container"><i>(<span class="date">February 2019</span>)</i></span></div></td></tr></tbody></table> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Anodized_titanium_(detail)_-_a.jpg" class="mw-file-description"><img alt="Anodized titanium (detail) - a.jpg" src="//upload.wikimedia.org/wikipedia/commons/thumb/d/d5/Anodized_titanium_%28detail%29_-_a.jpg/220px-Anodized_titanium_%28detail%29_-_a.jpg" decoding="async" width="220" height="146" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/d/d5/Anodized_titanium_%28detail%29_-_a.jpg/330px-Anodized_titanium_%28detail%29_-_a.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/d/d5/Anodized_titanium_%28detail%29_-_a.jpg/440px-Anodized_titanium_%28detail%29_-_a.jpg 2x" data-file-width="780" data-file-height="517" /></a><figcaption>Anodized titanium (detail) - a.jpg</figcaption></figure> <p><b>Electrometallurgy</b> is a method in <a href="/wiki/Metallurgy" title="Metallurgy">metallurgy</a> that uses electrical energy to produce metals by electrolysis. It is usually the last stage in metal production and is therefore preceded by <a href="/wiki/Pyrometallurgy" title="Pyrometallurgy">pyrometallurgical</a> or <a href="/wiki/Hydrometallurgy" title="Hydrometallurgy">hydrometallurgical</a> operations.<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> The electrolysis can be done on a molten metal oxide (smelt electrolysis) which is used for example to produce aluminium from aluminium oxide via the <a href="/wiki/Hall%E2%80%93H%C3%A9roult_process" title="Hall–Héroult process">Hall-Hérault process</a>. Electrolysis can be used as a final refining stage in pyrometallurgical metal production (electrorefining) and it is also used for reduction of a metal from an aqueous metal salt solution produced by hydrometallurgy (electrowinning). </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Processes">Processes</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Electrometallurgy&amp;action=edit&amp;section=1" title="Edit section: Processes"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Electrometallurgy is the field concerned with the processes of metal <a href="/wiki/Electrophoretic_deposition" title="Electrophoretic deposition">electrodeposition</a>. There are seven categories of these processes: </p> <ul><li><a href="/wiki/Electrolysis" title="Electrolysis">Electrolysis</a></li> <li><a href="/wiki/Electrowinning" title="Electrowinning">Electrowinning</a>, the extraction of metal from ores<sup id="cite_ref-:0_2-0" class="reference"><a href="#cite_note-:0-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/wiki/Electrorefining" class="mw-redirect" title="Electrorefining">Electrorefining</a>, the purification of metals.<sup id="cite_ref-:0_2-1" class="reference"><a href="#cite_note-:0-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> <a href="/wiki/Powder_metallurgy" title="Powder metallurgy">Metal powder production</a> by electrodeposition is included in this category, or sometimes electrowinning, or a separate category depending on application.<sup id="cite_ref-:0_2-2" class="reference"><a href="#cite_note-:0-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/wiki/Electroplating" title="Electroplating">Electroplating</a>, the deposition of a layer of one metal on another<sup id="cite_ref-:0_2-3" class="reference"><a href="#cite_note-:0-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/wiki/Electroforming" title="Electroforming">Electroforming</a>, the manufacture of, usually thin, metal parts through electroplating<sup id="cite_ref-:0_2-4" class="reference"><a href="#cite_note-:0-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/wiki/Electropolishing" title="Electropolishing">Electropolishing</a>, the removal of material from a metallic workpiece</li> <li><a href="/wiki/Etching" title="Etching">Etching</a>, industrially known to Wikipedia as <a href="/wiki/Chemical_milling" title="Chemical milling">chemical milling</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="Research_trends">Research trends</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Electrometallurgy&amp;action=edit&amp;section=2" title="Edit section: Research trends"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Molten_Oxide_Electrolysis">Molten Oxide Electrolysis</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Electrometallurgy&amp;action=edit&amp;section=3" title="Edit section: Molten Oxide Electrolysis"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure typeof="mw:File/Thumb"><a href="/wiki/File:Molten_Oxide_Electrolysis.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/b/b4/Molten_Oxide_Electrolysis.png/283px-Molten_Oxide_Electrolysis.png" decoding="async" width="283" height="257" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/b4/Molten_Oxide_Electrolysis.png/425px-Molten_Oxide_Electrolysis.png 1.5x, //upload.wikimedia.org/wikipedia/commons/b/b4/Molten_Oxide_Electrolysis.png 2x" data-file-width="474" data-file-height="430" /></a><figcaption>MOE scheme <sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup></figcaption></figure> <p>Molten Oxide <a href="/wiki/Electrolysis" title="Electrolysis">Electrolysis</a> in steelmaking is utilizing electrons as the reducing agent instead of <a href="/wiki/Coke_(fuel)" title="Coke (fuel)">coke</a> as in conventional <a href="/wiki/Blast_furnace" title="Blast furnace">blast furnace</a>. For steel production, this method uses an inert anode (Carbon, Platinum, Iridium or Chromium-based alloy)<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">&#91;</span>4<span class="cite-bracket">&#93;</span></a></sup> and places iron ore in the cathode. The electrochemical reaction in this Molten Oxide cell can reach up to 1600&#160;°C, a temperature that melts iron ore and electrolyte oxide.<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup> Then the molten iron ore decompose following this reaction. </p><p><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {Fe2O3(l) + e- -&gt; Fe(l) + O2(g)}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <msubsup> <mtext>Fe</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <msubsup> <mtext>O</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>l</mtext> <mo stretchy="false">)</mo> </mrow> <mo>+</mo> <msup> <mtext>e</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </msup> <mo stretchy="false">&#x27F6;<!-- ⟶ --></mo> <mtext>Fe</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>l</mtext> <mo stretchy="false">)</mo> </mrow> <mo>+</mo> <msubsup> <mtext>O</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>g</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {Fe2O3(l) + e- -&gt; Fe(l) + O2(g)}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/2e4b71e1f3a8d215eb0d7db4cc3fc3b3dc2dd390" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.005ex; width:33.083ex; height:3.176ex;" alt="{\displaystyle {\ce {Fe2O3(l) + e- -&gt; Fe(l) + O2(g)}}}"></span><sup id="cite_ref-:1_6-0" class="reference"><a href="#cite_note-:1-6"><span class="cite-bracket">&#91;</span>6<span class="cite-bracket">&#93;</span></a></sup> </p><p>The electrolysis reaction will produce molten pure iron as a main product and oxygen as its by-product. Because this process does not add coke in the process, no CO<sub>2</sub> gas is produced. So no direct <a href="/wiki/Greenhouse_gas_emissions" title="Greenhouse gas emissions">greenhouse gas emission</a>. Moreover, if the electricity to run such cells comes from renewable sources, this process may have zero emissions. This technology also can be implemented for producing Nickel, Chromium, and Ferrochromium. </p><p>Currently Massachusetts-based Boston Metal company is in a process to scale up this technology to an industrial level.<sup id="cite_ref-:1_6-1" class="reference"><a href="#cite_note-:1-6"><span class="cite-bracket">&#91;</span>6<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Direct_Decarburization_Electrorefining">Direct Decarburization Electrorefining</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Electrometallurgy&amp;action=edit&amp;section=4" title="Edit section: Direct Decarburization Electrorefining"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-halign-left" typeof="mw:File/Thumb"><a href="/wiki/File:Direct_Decarburization.webp" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/a/ab/Direct_Decarburization.webp/383px-Direct_Decarburization.webp.png" decoding="async" width="383" height="269" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/ab/Direct_Decarburization.webp/575px-Direct_Decarburization.webp.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/ab/Direct_Decarburization.webp/766px-Direct_Decarburization.webp.png 2x" data-file-width="1491" data-file-height="1047" /></a><figcaption>Direct Decarburization Reaction<sup id="cite_ref-:2_7-0" class="reference"><a href="#cite_note-:2-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup></figcaption></figure> <p>The purpose of this method is to reduce carbon content from steel. This process is suitable for secondary steelmaking industry which recycling steel <a href="/wiki/Scrap" title="Scrap">scrap</a> that has variety of carbon content in their feedstock.<sup id="cite_ref-:2_7-1" class="reference"><a href="#cite_note-:2-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup> This method aim to replace current conventional method that utilizing <a href="/wiki/Basic_oxygen_steelmaking" title="Basic oxygen steelmaking">Basic Oxygen Furnace</a> (BOF) to reduce carbon content of iron by blowing oxygen to make it react with carbon and forming CO<sub>2</sub>. </p><p>In electrorefining, decarburization process happened in electrochemical cell that composed of inert electrode, slag and steel. During the process, current passing through the cell and made slag and steel melted. Oxygen ion from slag decompose and oxidize carbon on steel and to form CO. That decarburizing reaction is occurred in three steps as follow.<sup id="cite_ref-:2_7-2" class="reference"><a href="#cite_note-:2-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup> (ads) means adsorbed intermediate </p> <ol><li><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {O2- + C &lt;=&gt; C(O^{-}_{(ads)}) +e-}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <msubsup> <mtext>O</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </msubsup> <mo>+</mo> <mtext>C</mtext> <mrow class="MJX-TeXAtom-REL"> <mover> <mrow class="MJX-TeXAtom-OP MJX-fixedlimits"> <mrow class="MJX-TeXAtom-ORD"> <mpadded height="0" depth="0"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21BD;<!-- ↽ --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </mpadded> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="false" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21C0;<!-- ⇀ --></mo> </mrow> </mrow> </mstyle> </mrow> </mover> </mrow> <mtext>C</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <msubsup> <mtext>O</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>ads</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </msubsup> <mo stretchy="false">)</mo> </mrow> <mo>+</mo> <msup> <mtext>e</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </msup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {O2- + C &lt;=&gt; C(O^{-}_{(ads)}) +e-}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/92de87dd08c121dd8c9eb845a9a3e5a0d9b408e4" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.505ex; width:27.06ex; height:3.843ex;" alt="{\displaystyle {\ce {O2- + C &lt;=&gt; C(O^{-}_{(ads)}) +e-}}}"></span></li> <li><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {C(O_{(ads)}^{-})&lt;=&gt;C(O_{(ads)}^{})}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mtext>C</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <msubsup> <mtext>O</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>ads</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </msubsup> <mo stretchy="false">)</mo> </mrow> <mrow class="MJX-TeXAtom-REL"> <mover> <mrow class="MJX-TeXAtom-OP MJX-fixedlimits"> <mrow class="MJX-TeXAtom-ORD"> <mpadded height="0" depth="0"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21BD;<!-- ↽ --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </mpadded> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="false" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21C0;<!-- ⇀ --></mo> </mrow> </mrow> </mstyle> </mrow> </mover> </mrow> <mtext>C</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <msubsup> <mtext>O</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>ads</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo stretchy="false">)</mo> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {C(O_{(ads)}^{-})&lt;=&gt;C(O_{(ads)}^{})}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/a4b30b2df80c149388c823d1740d4688a1fcbaaa" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.505ex; width:23.03ex; height:3.843ex;" alt="{\displaystyle {\ce {C(O_{(ads)}^{-})&lt;=&gt;C(O_{(ads)}^{})}}}"></span><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {+ e-}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mo>+</mo> <msup> <mtext>e</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </msup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {+ e-}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/9bd7848c58607ea82b86509efd6aeba321dc3992" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.505ex; width:4.351ex; height:2.676ex;" alt="{\displaystyle {\ce {+ e-}}}"></span></li> <li><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {C(O_{(ads)}^{})&lt;=&gt;CO_{(}g)}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mtext>C</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <msubsup> <mtext>O</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>ads</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo stretchy="false">)</mo> </mrow> <mrow class="MJX-TeXAtom-REL"> <mover> <mrow class="MJX-TeXAtom-OP MJX-fixedlimits"> <mrow class="MJX-TeXAtom-ORD"> <mpadded height="0" depth="0"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21BD;<!-- ↽ --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </mpadded> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="false" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21C0;<!-- ⇀ --></mo> </mrow> </mrow> </mstyle> </mrow> </mover> </mrow> <msubsup> <mtext>CO</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> </mrow> <mtext>g</mtext> <mo stretchy="false">)</mo> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {C(O_{(ads)}^{})&lt;=&gt;CO_{(}g)}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/e3131cf65adfbc69580914fea5426f85025ccf64" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.505ex; width:19.659ex; height:3.843ex;" alt="{\displaystyle {\ce {C(O_{(ads)}^{})&lt;=&gt;CO_{(}g)}}}"></span></li></ol> <p>The total reaction from this cell is following this scheme<sup id="cite_ref-:2_7-3" class="reference"><a href="#cite_note-:2-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup> </p><p><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {C{}+1/2SiO2&lt;=&gt;CO_{(g)}{}+1/2Si_{(}l)}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mtext>C</mtext> <mrow class="MJX-TeXAtom-ORD"> </mrow> <mo>+</mo> <mstyle displaystyle="false" scriptlevel="0"> <mfrac> <mn>1</mn> <mn>2</mn> </mfrac> </mstyle> <msubsup> <mtext>SiO</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-REL"> <mover> <mrow class="MJX-TeXAtom-OP MJX-fixedlimits"> <mrow class="MJX-TeXAtom-ORD"> <mpadded height="0" depth="0"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21BD;<!-- ↽ --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> </mpadded> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="false" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo>&#x2212;<!-- − --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">&#x21C0;<!-- ⇀ --></mo> </mrow> </mrow> </mstyle> </mrow> </mover> </mrow> <msubsup> <mtext>CO</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>g</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> </mrow> <mo>+</mo> <mstyle displaystyle="false" scriptlevel="0"> <mfrac> <mn>1</mn> <mn>2</mn> </mfrac> </mstyle> <msubsup> <mtext>Si</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> </mrow> <mtext>l</mtext> <mo stretchy="false">)</mo> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {C{}+1/2SiO2&lt;=&gt;CO_{(g)}{}+1/2Si_{(}l)}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/9a1ed95ec725a9f158630fe9dddbc3ccb04c3bc6" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.505ex; width:29.853ex; height:3.843ex;" alt="{\displaystyle {\ce {C{}+1/2SiO2&lt;=&gt;CO_{(g)}{}+1/2Si_{(}l)}}}"></span> </p><p>The SiO<sub>2</sub> is come from the slag, based on the reaction above, beside producing CO gas, this method also producing pure silicon (depending on the slag). The benefit of this direct decarburization process is it does not produce CO<sub>2</sub> but CO which is not considered as greenhouse gas. </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Electrometallurgy&amp;action=edit&amp;section=5" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist"> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite class="citation cs2"><a rel="nofollow" class="external text" href="https://onlinelibrary.wiley.com/doi/abs/10.1002/9781119078326.ch12">"Electrometallurgy"</a>, <i>Physical Chemistry of Metallurgical Processes</i>, John Wiley &amp; Sons, Ltd, pp.&#160;523–557, 2016, <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1002%2F9781119078326.ch12">10.1002/9781119078326.ch12</a>, <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/978-1-119-07832-6" title="Special:BookSources/978-1-119-07832-6"><bdi>978-1-119-07832-6</bdi></a><span class="reference-accessdate">, retrieved <span class="nowrap">2020-09-24</span></span></cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rft.genre=article&amp;rft.jtitle=Physical+Chemistry+of+Metallurgical+Processes&amp;rft.atitle=Electrometallurgy&amp;rft.pages=523-557&amp;rft.date=2016&amp;rft_id=info%3Adoi%2F10.1002%2F9781119078326.ch12&amp;rft.isbn=978-1-119-07832-6&amp;rft_id=https%3A%2F%2Fonlinelibrary.wiley.com%2Fdoi%2Fabs%2F10.1002%2F9781119078326.ch12&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3AElectrometallurgy" class="Z3988"></span></span> </li> <li id="cite_note-:0-2"><span class="mw-cite-backlink">^ <a href="#cite_ref-:0_2-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-:0_2-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-:0_2-2"><sup><i><b>c</b></i></sup></a> <a href="#cite_ref-:0_2-3"><sup><i><b>d</b></i></sup></a> <a href="#cite_ref-:0_2-4"><sup><i><b>e</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFPopov,_K._I._(Konstantin_Ivanovich)2002" class="citation book cs1">Popov, K. 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New York: Kluwer Academic/Plenum Publishers. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/0-306-47564-2" title="Special:BookSources/0-306-47564-2"><bdi>0-306-47564-2</bdi></a>. <a href="/wiki/OCLC_(identifier)" class="mw-redirect" title="OCLC (identifier)">OCLC</a>&#160;<a rel="nofollow" class="external text" href="https://search.worldcat.org/oclc/51893969">51893969</a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Fundamental+aspects+of+electrometallurgy&amp;rft.place=New+York&amp;rft.pub=Kluwer+Academic%2FPlenum+Publishers&amp;rft.date=2002&amp;rft_id=info%3Aoclcnum%2F51893969&amp;rft.isbn=0-306-47564-2&amp;rft.au=Popov%2C+K.+I.+%28Konstantin+Ivanovich%29&amp;rft_id=https%3A%2F%2Fwww.worldcat.org%2Foclc%2F51893969&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3AElectrometallurgy" class="Z3988"></span></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFD.R." class="citation book cs1">D.R., George C. 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href="https://www.nature.com/articles/s41563-021-01106-z">"Electrorefining for direct decarburization of molten iron"</a>. <i>Nature Materials</i>. <b>21</b> (10): 1130–1136. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/2022NatMa..21.1130J">2022NatMa..21.1130J</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1038%2Fs41563-021-01106-z">10.1038/s41563-021-01106-z</a>. <a href="/wiki/ISSN_(identifier)" class="mw-redirect" title="ISSN (identifier)">ISSN</a>&#160;<a rel="nofollow" class="external text" href="https://search.worldcat.org/issn/1476-4660">1476-4660</a>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a>&#160;<a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/34580434">34580434</a>. <a href="/wiki/S2CID_(identifier)" class="mw-redirect" title="S2CID (identifier)">S2CID</a>&#160;<a rel="nofollow" class="external text" href="https://api.semanticscholar.org/CorpusID:237947963">237947963</a>.</cite><span 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