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八氟合氙(VI)酸亚硝酰 - 维基百科,自由的百科全书

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class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">八氟合氙(VI)酸亚硝酰</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。8种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-8" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">8种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D9%86%DB%8C%D8%AA%D8%B1%D9%88%D8%B3%D9%88%D9%86%DB%8C%D9%88%D9%85_%D8%A7%D9%88%DA%A9%D8%AA%D8%A7%D9%81%D9%84%D9%88%D8%B1%D9%88%DA%A9%D8%B3%D9%86%D8%A7%D8%AA_(VI)" title="نیتروسونیوم اوکتافلوروکسنات (VI) – South Azerbaijani" lang="azb" hreflang="azb" data-title="نیتروسونیوم اوکتافلوروکسنات (VI)" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%94%CE%B9%CE%BD%CE%B9%CF%84%CF%81%CF%89%CE%B4%CE%BF%CE%BE%CE%B5%CE%BD%CE%BF%CE%BF%CE%BA%CF%84%CE%B1%CF%86%CE%B8%CE%BF%CF%81%CE%AF%CE%B4%CE%B9%CE%BF" title="Δινιτρωδοξενοοκταφθορίδιο – 希腊语" lang="el" hreflang="el" data-title="Δινιτρωδοξενοοκταφθορίδιο" data-language-autonym="Ελληνικά" data-language-local-name="希腊语" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Nitrosonium_octafluoroxenate(VI)" title="Nitrosonium octafluoroxenate(VI) – 英语" lang="en" hreflang="en" data-title="Nitrosonium octafluoroxenate(VI)" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D9%86%DB%8C%D8%AA%D8%B1%D9%88%D8%B3%D9%88%D9%86%DB%8C%D9%88%D9%85_%D8%A7%D9%88%DA%A9%D8%AA%D8%A7%D9%81%D9%84%D9%88%D8%B1%D9%88%DA%A9%D8%B3%D9%86%D8%A7%D8%AA_(VI)" title="نیتروسونیوم اوکتافلوروکسنات (VI) – 波斯语" lang="fa" hreflang="fa" data-title="نیتروسونیوم اوکتافلوروکسنات (VI)" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Octafluorox%C3%A9nate(VI)_de_nitrosonium" title="Octafluoroxénate(VI) de nitrosonium – 法语" lang="fr" hreflang="fr" data-title="Octafluoroxénate(VI) de nitrosonium" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Nitroz%C3%B3nium-oktafluoroxen%C3%A1t(VI)" title="Nitrozónium-oktafluoroxenát(VI) – 匈牙利语" lang="hu" hreflang="hu" data-title="Nitrozónium-oktafluoroxenát(VI)" data-language-autonym="Magyar" data-language-local-name="匈牙利语" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%82%AA%E3%82%AF%E3%82%BF%E3%83%95%E3%83%AB%E3%82%AA%E3%83%AD%E3%82%AD%E3%82%BB%E3%83%8E%E3%83%B3%E9%85%B8%E3%83%8B%E3%83%88%E3%83%AD%E3%82%BD%E3%83%8B%E3%82%A6%E3%83%A0" title="オクタフルオロキセノン酸ニトロソニウム – 日语" lang="ja" hreflang="ja" data-title="オクタフルオロキセノン酸ニトロソニウム" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%A8%E0%AF%88%E0%AE%9F%E0%AF%8D%E0%AE%B0%E0%AE%9A%E0%AF%8B%E0%AE%A9%E0%AE%BF%E0%AE%AF%E0%AE%AE%E0%AF%8D_%E0%AE%86%E0%AE%95%E0%AF%8D%E0%AE%9F%E0%AE%BE%E0%AE%AA%E0%AF%81%E0%AE%B3%E0%AF%8B%E0%AE%B0%E0%AF%8B%E0%AE%9A%E0%AF%86%E0%AE%A9%E0%AF%87%E0%AE%9F%E0%AF%8D%E0%AE%9F%E0%AF%81(VI)" title="நைட்ரசோனியம் ஆக்டாபுளோரோசெனேட்டு(VI) – 泰米尔语" lang="ta" hreflang="ta" data-title="நைட்ரசோனியம் ஆக்டாபுளோரோசெனேட்டு(VI)" data-language-autonym="தமிழ்" data-language-local-name="泰米尔语" class="interlanguage-link-target"><span>தமிழ்</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q3271899#sitelinks-wikipedia" title="编辑跨语言链接" class="wbc-editpage">编辑链接</a></span></div> </div> </div> </div> </header> 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border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">八氟合氙(VI)酸亚硝酰 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Octafluoroxenate(VI)-3D-balls-A.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/3/30/Octafluoroxenate%28VI%29-3D-balls-A.png/200px-Octafluoroxenate%28VI%29-3D-balls-A.png" decoding="async" width="200" height="147" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/3/30/Octafluoroxenate%28VI%29-3D-balls-A.png/300px-Octafluoroxenate%28VI%29-3D-balls-A.png 1.5x, //upload.wikimedia.org/wikipedia/commons/3/30/Octafluoroxenate%28VI%29-3D-balls-A.png 2x" data-file-width="371" data-file-height="272" /></a></span> </td></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"> <table class="borderless"> <tbody><tr> <td><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Nitrosonium-3D-vdW.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/6/68/Nitrosonium-3D-vdW.png/100px-Nitrosonium-3D-vdW.png" decoding="async" width="100" height="56" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/68/Nitrosonium-3D-vdW.png/150px-Nitrosonium-3D-vdW.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/68/Nitrosonium-3D-vdW.png/200px-Nitrosonium-3D-vdW.png 2x" data-file-width="1100" data-file-height="612" /></a><figcaption></figcaption></figure> </td> <td><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Nitrosonium-3D-vdW.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/6/68/Nitrosonium-3D-vdW.png/100px-Nitrosonium-3D-vdW.png" decoding="async" width="100" height="56" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/68/Nitrosonium-3D-vdW.png/150px-Nitrosonium-3D-vdW.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/68/Nitrosonium-3D-vdW.png/200px-Nitrosonium-3D-vdW.png 2x" data-file-width="1100" data-file-height="612" /></a><figcaption></figcaption></figure> </td></tr></tbody></table> </td></tr> <tr> <td colspan="2" style="max-width:305px; word-wrap: break-word; text-align: center;"><a href="/wiki/IUPAC%E5%91%BD%E5%90%8D%E6%B3%95" title="IUPAC命名法">IUPAC名</a><br />Nitrosonium octafluoroxenate(VI) </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=17501-82-5">17501-82-5</a></span> <sup>&#160;<span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div>&#160;</div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">N#[O+].N#[O+].F[Xe-2](F)(F)(F)(F)(F)(F)F</span></li></ul> </div></div> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td><span lang="en"><span class="chemf nowrap">(NO)<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>XeF<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />8</span></span></span> </td></tr> <tr> <td><a href="/wiki/%E5%AF%86%E5%BA%A6" title="密度">密度</a> </td> <td>3.354 g/cm³ </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明,所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态(25 ℃,100 kPa)</a>下。 </td></tr></tbody></table> <p><b>八氟合氙(VI)酸亚硝酰</b>(<span class="chemf nowrap">(NO)<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>XeF<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />8</span></span>),是由<a href="/w/index.php?title=%E4%BA%9A%E7%A1%9D%E9%85%B0%E7%A6%BB%E5%AD%90&amp;action=edit&amp;redlink=1" class="new" title="亚硝酰离子(页面不存在)">亚硝酰离子</a>(NO<sup>+</sup>)与八<a href="/wiki/%E6%B0%9F" title="氟">氟</a>合<a href="/wiki/%E6%B0%99" title="氙">氙</a>(VI)酸根离子(XeF<sub>8</sub><sup>2−</sup>)结合而成的化合物。其中 XeF<sub>8</sub><sup>2−</sup> 离子为<a href="/wiki/%E6%96%B9%E5%BD%A2%E5%8F%8D%E7%A8%9C%E6%9F%B1%E5%88%86%E5%AD%90%E6%A7%8B%E5%9E%8B" class="mw-redirect" title="方形反稜柱分子構型">方形反稜柱分子構型</a>,Xe-F 键长分别为 1.971 Å、1.946 Å、1.958 Å、2.052 Å 和 2.099 Å。<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup>它可通过<a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E6%B0%99" title="六氟化氙">六氟化氙</a>与<a href="/wiki/%E4%BA%9A%E7%A1%9D%E9%85%B0%E6%B0%9F" title="亚硝酰氟">亚硝酰氟</a>反应制取。<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> </p> <dl><dd><span class="chemf nowrap">XeF<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />6</span></span> + 2 NOF → <span class="chemf nowrap">(NO)<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>XeF<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />8</span></span></dd></dl> <p>类似化合物还有八氟合氙(VI)酸的碱金属盐类,例如 Cs<sub>2</sub>XeF<sub>8</sub> 和 Rb<sub>2</sub>XeF<sub>8</sub>,它们在400°C以下都是稳定的。<sup id="cite_ref-chandra_3-0" class="reference"><a href="#cite_note-chandra-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-holleman1_4-0" class="reference"><a href="#cite_note-holleman1-4"><span class="cite-bracket">&#91;</span>4<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="参考资料"><span id=".E5.8F.82.E8.80.83.E8.B5.84.E6.96.99"></span>参考资料</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AB%E6%B0%9F%E5%90%88%E6%B0%99(VI)%E9%85%B8%E4%BA%9A%E7%A1%9D%E9%85%B0&amp;action=edit&amp;section=1" title="编辑章节:参考资料"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><cite class="citation journal">Peterson, W.; Holloway, H.; Coyle, A.; Williams, M. Antiprismatic Coordination about Xenon: the Structure of Nitrosonium Octafluoroxenate(VI). Science (New York, N.Y.). Sep 1971, <b>173</b> (4003): 1238–1239. <a rel="nofollow" class="external text" href="//www.worldcat.org/issn/0036-8075"><span title="国际标准连续出版物号">ISSN&#160;0036-8075</span></a>. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/17775218"><span title="公共医学识别码">PMID&#160;17775218</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.173.4003.1238"><span title="數位物件識別號">doi:10.1126/science.173.4003.1238</span></a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AB%E6%B0%9F%E5%90%88%E6%B0%99%28VI%29%E9%85%B8%E4%BA%9A%E7%A1%9D%E9%85%B0&amp;rft.atitle=Antiprismatic+Coordination+about+Xenon%3A+the+Structure+of+Nitrosonium+Octafluoroxenate%28VI%29&amp;rft.au=Coyle%2C+A.&amp;rft.au=Holloway%2C+H.&amp;rft.au=Williams%2C+M.&amp;rft.aufirst=W.&amp;rft.aulast=Peterson&amp;rft.date=1971-09&amp;rft.genre=article&amp;rft.issn=0036-8075&amp;rft.issue=4003&amp;rft.jtitle=Science+%28New+York%2C+N.Y.%29&amp;rft.pages=1238-1239&amp;rft.volume=173&amp;rft_id=info%3Adoi%2F10.1126%2Fscience.173.4003.1238&amp;rft_id=info%3Apmid%2F17775218&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;">&#160;</span></span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text">Cotton (2007). <i>Advanced Inorganic Chemistry</i> (6th ed.). Wiley-India. p. 588. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/8126513381" class="internal mw-magiclink-isbn">ISBN 8126513381</a>.</span> </li> <li id="cite_note-chandra-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-chandra_3-0">^</a></b></span> <span class="reference-text">Chandra, Sulekh (2004). <i>Comprehensive Inorganic Chemistry</i>. New Age International. p. 308. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/8122415121" class="internal mw-magiclink-isbn">ISBN 8122415121</a>.</span> </li> <li id="cite_note-holleman1-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-holleman1_4-0">^</a></b></span> <span class="reference-text">Holleman, A. F.; Wiberg,, E. (2001). <i>Inorganic Chemistry</i>. San Diego: Academic Press. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0123526515" class="internal mw-magiclink-isbn">ISBN 0-12-352651-5</a>.</span> </li> </ol></div> <!-- NewPP limit report Parsed by mw‐api‐int.codfw.main‐dd89579f7‐tpdv4 Cached time: 20241203025936 Cache expiry: 2592000 Reduced expiry: false Complications: [] CPU time usage: 0.232 seconds Real time usage: 0.298 seconds Preprocessor visited node count: 2922/1000000 Post‐expand include size: 30772/2097152 bytes Template argument size: 6398/2097152 bytes Highest expansion depth: 20/100 Expensive parser function count: 10/500 Unstrip recursion depth: 0/20 Unstrip post‐expand size: 3749/5000000 bytes Lua time usage: 0.061/10.000 seconds Lua memory usage: 2126124/52428800 bytes Number of Wikibase entities loaded: 0/400 --> <!-- Transclusion expansion time report (%,ms,calls,template) 100.00% 235.085 1 -total 67.34% 158.300 1 Template:Chembox 30.77% 72.332 1 Template:Chembox_Identifiers 23.64% 55.582 1 Template:Reflist 20.17% 47.419 1 Template:Cite_journal_en 17.31% 40.694 1 Template:Chembox_Properties 12.37% 29.079 4 Template:Chem 10.77% 25.311 4 Template:Chem/link 8.84% 20.781 63 Template:Chembox_entry 8.48% 19.924 14 Template:Chem/atom --> <!-- Saved in parser cache with key zhwiki:pcache:1248738:|#|:idhash:canonical!zh and timestamp 20241203025936 and revision id 68604044. 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