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href="#参考资料"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>参考资料</span> </div> </a> <ul id="toc-参考资料-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-参见" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参见"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>参见</span> </div> </a> <ul id="toc-参见-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">四氟化氙</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。26种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-26" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">26种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%B1%D8%A8%D8%A7%D8%B9%D9%8A_%D9%81%D9%84%D9%88%D8%B1%D9%8A%D8%AF_%D8%A7%D9%84%D8%B2%D9%8A%D9%86%D9%88%D9%86" title="رباعي فلوريد الزينون – 阿拉伯语" lang="ar" hreflang="ar" data-title="رباعي فلوريد الزينون" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D8%B2%D9%86%D9%88%D9%86_%D8%AA%D8%AA%D8%B1%D8%A7%D9%81%D9%84%D9%88%D8%B1%DB%8C%D8%AF" title="زنون تترافلورید – South Azerbaijani" lang="azb" hreflang="azb" data-title="زنون تترافلورید" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Fluorid_xenoni%C4%8Dit%C3%BD" title="Fluorid xenoničitý – 捷克语" lang="cs" hreflang="cs" data-title="Fluorid xenoničitý" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Xenontetrafluorid" title="Xenontetrafluorid – 德语" lang="de" hreflang="de" data-title="Xenontetrafluorid" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%A4%CE%B5%CF%84%CF%81%CE%B1%CF%86%CE%B8%CE%BF%CF%81%CE%B9%CE%BF%CF%8D%CF%87%CE%BF_%CE%BE%CE%AD%CE%BD%CE%BF" title="Τετραφθοριούχο ξένο – 希腊语" lang="el" hreflang="el" data-title="Τετραφθοριούχο ξένο" data-language-autonym="Ελληνικά" data-language-local-name="希腊语" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Xenon_tetrafluoride" title="Xenon tetrafluoride – 英语" lang="en" hreflang="en" data-title="Xenon tetrafluoride" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Tetrafluoruro_de_xen%C3%B3n" title="Tetrafluoruro de xenón – 西班牙语" lang="es" hreflang="es" data-title="Tetrafluoruro de xenón" data-language-autonym="Español" data-language-local-name="西班牙语" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%B2%D9%86%D9%88%D9%86_%D8%AA%D8%AA%D8%B1%D8%A7%D9%81%D9%84%D9%88%D8%B1%DB%8C%D8%AF" title="زنون تترافلورید – 波斯语" lang="fa" hreflang="fa" data-title="زنون تترافلورید" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Ksenontetrafluoridi" title="Ksenontetrafluoridi – 芬兰语" lang="fi" hreflang="fi" data-title="Ksenontetrafluoridi" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/T%C3%A9trafluorure_de_x%C3%A9non" title="Tétrafluorure de xénon – 法语" lang="fr" hreflang="fr" data-title="Tétrafluorure de xénon" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%9C%E0%A5%87%E0%A4%A8%E0%A4%A8_%E0%A4%9F%E0%A5%87%E0%A4%9F%E0%A5%8D%E0%A4%B0%E0%A4%BE%E0%A4%AB%E0%A5%8D%E0%A4%B2%E0%A5%8B%E0%A4%B0%E0%A4%BE%E0%A4%87%E0%A4%A1" title="जेनन टेट्राफ्लोराइड – 印地语" lang="hi" hreflang="hi" data-title="जेनन टेट्राफ्लोराइड" data-language-autonym="हिन्दी" data-language-local-name="印地语" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Xenon-tetrafluorid" title="Xenon-tetrafluorid – 匈牙利语" lang="hu" hreflang="hu" data-title="Xenon-tetrafluorid" data-language-autonym="Magyar" data-language-local-name="匈牙利语" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Xenon_tetrafluorida" title="Xenon tetrafluorida – 印度尼西亚语" lang="id" hreflang="id" data-title="Xenon tetrafluorida" data-language-autonym="Bahasa Indonesia" data-language-local-name="印度尼西亚语" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Tetrafluoruro_di_xeno" title="Tetrafluoruro di xeno – 意大利语" lang="it" hreflang="it" data-title="Tetrafluoruro di xeno" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E5%9B%9B%E3%83%95%E3%83%83%E5%8C%96%E3%82%AD%E3%82%BB%E3%83%8E%E3%83%B3" title="四フッ化キセノン – 日语" lang="ja" hreflang="ja" data-title="四フッ化キセノン" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%EC%82%AC%ED%94%8C%EB%A3%A8%EC%98%A4%EB%A6%B0%ED%99%94_%EC%A0%9C%EB%85%BC" title="사플루오린화 제논 – 韩语" lang="ko" hreflang="ko" data-title="사플루오린화 제논" data-language-autonym="한국어" data-language-local-name="韩语" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-ms mw-list-item"><a href="https://ms.wikipedia.org/wiki/Xenon_tetrafluorida" title="Xenon tetrafluorida – 马来语" lang="ms" hreflang="ms" data-title="Xenon tetrafluorida" data-language-autonym="Bahasa Melayu" data-language-local-name="马来语" class="interlanguage-link-target"><span>Bahasa Melayu</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Xenontetrafluoride" title="Xenontetrafluoride – 荷兰语" lang="nl" hreflang="nl" data-title="Xenontetrafluoride" data-language-autonym="Nederlands" data-language-local-name="荷兰语" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Tetrafluorek_ksenonu" title="Tetrafluorek ksenonu – 波兰语" lang="pl" hreflang="pl" data-title="Tetrafluorek ksenonu" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Tetrafluoreto_de_xen%C3%B4nio" title="Tetrafluoreto de xenônio – 葡萄牙语" lang="pt" hreflang="pt" data-title="Tetrafluoreto de xenônio" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%A4%D1%82%D0%BE%D1%80%D0%B8%D0%B4_%D0%BA%D1%81%D0%B5%D0%BD%D0%BE%D0%BD%D0%B0(IV)" title="Фторид ксенона(IV) – 俄语" lang="ru" hreflang="ru" data-title="Фторид ксенона(IV)" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Ksenon-tetrafluorid" title="Ksenon-tetrafluorid – 塞尔维亚-克罗地亚语" lang="sh" hreflang="sh" data-title="Ksenon-tetrafluorid" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="塞尔维亚-克罗地亚语" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/%D0%9A%D1%81%D0%B5%D0%BD%D0%BE%D0%BD-%D1%82%D0%B5%D1%82%D1%80%D0%B0%D1%84%D0%BB%D1%83%D0%BE%D1%80%D0%B8%D0%B4" title="Ксенон-тетрафлуорид – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Ксенон-тетрафлуорид" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%9A%E0%AF%86%E0%AE%A9%E0%AE%BE%E0%AE%A9%E0%AF%8D_%E0%AE%A8%E0%AE%BE%E0%AE%A9%E0%AF%8D%E0%AE%95%E0%AF%81%E0%AE%AA%E0%AF%81%E0%AE%B3%E0%AF%8B%E0%AE%B0%E0%AF%88%E0%AE%9F%E0%AF%81" title="செனான் நான்குபுளோரைடு – 泰米尔语" lang="ta" hreflang="ta" data-title="செனான் நான்குபுளோரைடு" data-language-autonym="தமிழ்" data-language-local-name="泰米尔语" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Ksenon_tetraflor%C3%BCr" title="Ksenon tetraflorür – 土耳其语" lang="tr" hreflang="tr" data-title="Ksenon tetraflorür" data-language-autonym="Türkçe" 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<div class="vector-pinnable-header vector-appearance-pinnable-header vector-pinnable-header-pinned" data-feature-name="appearance-pinned" data-pinnable-element-id="vector-appearance" data-pinned-container-id="vector-appearance-pinned-container" data-unpinned-container-id="vector-appearance-unpinned-container" > <div class="vector-pinnable-header-label">外观</div> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-appearance.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-appearance.unpin">隐藏</button> </div> </div> </div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> <div id="mw-indicator-noteTA-f683ec12" class="mw-indicator"><div class="mw-parser-output"><span class="skin-invert" typeof="mw:File"><span title="本页使用了标题或全文手工转换"><img alt="本页使用了标题或全文手工转换" src="//upload.wikimedia.org/wikipedia/commons/thumb/c/cd/Zh_conversion_icon_m.svg/35px-Zh_conversion_icon_m.svg.png" decoding="async" width="35" height="22" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/cd/Zh_conversion_icon_m.svg/53px-Zh_conversion_icon_m.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/cd/Zh_conversion_icon_m.svg/70px-Zh_conversion_icon_m.svg.png 2x" data-file-width="32" data-file-height="20" /></span></span></div></div> </div> <div id="siteSub" class="noprint">维基百科，自由的百科全书</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="zh" dir="ltr"><div id="noteTA-f683ec12" class="noteTA"><div class="noteTA-group"><div data-noteta-group-source="module" data-noteta-group="Chemistry"></div></div></div> <style data-mw-deduplicate="TemplateStyles:r84001320">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox nounderlines" cellspacing="0" cellpadding="3" rules="all" style="background-color:#f0f0f0; float:right; margin: 0 0 1em 1em; border-color: #aaaaaa; border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">四氟化氙 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Xenon_tetrafluoride.png" class="mw-file-description" title="XeF4晶体，1962"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/c/cb/Xenon_tetrafluoride.png/300px-Xenon_tetrafluoride.png" decoding="async" width="300" height="388" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/c/cb/Xenon_tetrafluoride.png 1.5x" data-file-width="334" data-file-height="432" /></a></span> </td></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"> <table class="borderless"> <tbody><tr> <td><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Xenon-tetrafluoride-3D-balls.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/b/bf/Xenon-tetrafluoride-3D-balls.png/150px-Xenon-tetrafluoride-3D-balls.png" decoding="async" width="150" height="119" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/bf/Xenon-tetrafluoride-3D-balls.png/225px-Xenon-tetrafluoride-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/bf/Xenon-tetrafluoride-3D-balls.png/300px-Xenon-tetrafluoride-3D-balls.png 2x" data-file-width="1100" data-file-height="875" /></a><figcaption></figcaption></figure> </td> <td><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Xenon-tetrafluoride-3D-vdW.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/e/e3/Xenon-tetrafluoride-3D-vdW.png/150px-Xenon-tetrafluoride-3D-vdW.png" decoding="async" width="150" height="128" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/e/e3/Xenon-tetrafluoride-3D-vdW.png/225px-Xenon-tetrafluoride-3D-vdW.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/e/e3/Xenon-tetrafluoride-3D-vdW.png/300px-Xenon-tetrafluoride-3D-vdW.png 2x" data-file-width="1100" data-file-height="942" /></a><figcaption></figcaption></figure> </td></tr></tbody></table> </td></tr> <tr> <td colspan="2" style="max-width:305px; word-wrap: break-word; text-align: center;"><a href="/wiki/IUPAC%E5%91%BD%E5%90%8D%E6%B3%95" title="IUPAC命名法">IUPAC名</a><br />Xenon tetrafluoride </td></tr> <tr> <td>别名 </td> <td>氟化氙(IV) </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=13709-61-0">13709-61-0</a></span> <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/PubChem" title="PubChem">PubChem</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/123324">123324</a></span> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.chemspider.com/109927">109927</a></span> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">F[Xe](F)(F)F</span></li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChI</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0">1/F4Xe/c1-5(2,3)4</li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChIKey</a> </td> <td><small>RPSSQXXJRBEGEE-UHFFFAOYAW</small> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td><span lang="en">XeF<sub>4</sub></span> </td></tr> <tr> <td><a href="/wiki/%E6%91%A9%E5%B0%94%E8%B4%A8%E9%87%8F" title="摩尔质量">摩尔质量</a> </td> <td>207.2836 g·mol⁻¹ </td></tr> <tr> <td>外观 </td> <td>白色固体 </td></tr> <tr> <td><a href="/wiki/%E5%AF%86%E5%BA%A6" title="密度">密度</a> </td> <td>4.040 g/cm<sup>3</sup> (固) </td></tr> <tr> <td><a href="/wiki/%E5%8D%87%E5%8D%8E" title="升华">升华</a>条件 </td> <td>117 °C (390 K)<sup id="cite_ref-holleman1_1-0" class="reference"><a href="#cite_note-holleman1-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">结构 </th></tr> <tr> <td><a href="/wiki/%E9%85%8D%E5%90%88%E7%89%A9%E7%BB%93%E6%9E%84" title="配合物结构">配位几何</a> </td> <td>D<sub>4h</sub> </td></tr> <tr> <td><a href="/wiki/%E5%88%86%E5%AD%90%E7%BB%93%E6%9E%84" title="分子结构">分子构型</a> </td> <td><a href="/wiki/%E5%B9%B3%E9%9D%A2%E6%AD%A3%E6%96%B9%E5%BD%A2" class="mw-redirect" title="平面正方形">平面正方形</a> </td></tr> <tr> <td><a href="/wiki/%E5%81%B6%E6%A5%B5%E5%AD%90#分子的電偶極矩" title="偶極子">偶极矩</a> </td> <td>0 <a href="/wiki/%E5%BE%B7%E6%8B%9C" title="德拜">D</a> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">危险性 </th></tr> <tr> <td><a href="/wiki/%E9%97%AA%E7%82%B9" title="闪点">闪点</a> </td> <td>? °C </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">相关物质 </th></tr> <tr> <td>相关化学品 </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%9F%E5%8C%96%E6%B0%99" title="二氟化氙">二氟化氙</a>、<a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E6%B0%99" title="六氟化氙">六氟化氙</a> </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明，所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态（25 ℃，100 kPa）</a>下。 </td></tr></tbody></table> <p><b>四氟化氙</b>（<a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a>：<a href="/wiki/%E6%B0%99" title="氙">Xe</a><a href="/wiki/%E6%B0%9F" title="氟">F<sub>4</sub></a>）是<a href="/wiki/%E7%A8%80%E6%9C%89%E6%B0%94%E4%BD%93" title="稀有气体">稀有气体</a><a href="/wiki/%E6%B0%99" title="氙">氙</a>的<a href="/wiki/%E6%B0%9F%E5%8C%96%E7%89%A9" title="氟化物">氟化物</a>之一，是第一个发现的<a href="/wiki/%E7%A8%80%E6%9C%89%E6%B0%94%E4%BD%93%E5%8C%96%E5%90%88%E7%89%A9" title="稀有气体化合物">稀有气体</a><a href="/wiki/%E4%BA%8C%E5%85%83%E5%8C%96%E5%90%88%E7%89%A9" title="二元化合物">二元化合物</a>。<sup id="cite_ref-zumdahlpg243_2-0" class="reference"><a href="#cite_note-zumdahlpg243-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="製造"><span id=".E8.A3.BD.E9.80.A0"></span>製造</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&section=1" title="编辑章节：製造"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li>首次制备的方法：由Xe与F<sub>2</sub>以1:2摩尔比反应得到。<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>该反应是<a href="/wiki/%E6%94%BE%E7%83%AD%E5%8F%8D%E5%BA%94" title="放热反应">放热反应</a>，每摩尔反应放出251kJ的热量。<sup id="cite_ref-zumdahlpg243_2-1" class="reference"><a href="#cite_note-zumdahlpg243-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup></li> <li>放电合成法：将氙与氟按体积比1：2加入反应容器（温度需控制在-78℃），放电条件为1100V、31mA到2800V、12mA，反应历时3小时。电压不能太高否则氙与氟发生燃烧反应。为了主要获得四氟化氙，氟需要略微过量。</li></ul> <ul><li>光化学合成法：在近紫外光照射下，氟与氙反应得到<a href="/wiki/%E4%BA%8C%E6%B0%9F%E5%8C%96%E6%B0%99" title="二氟化氙">二氟化氙</a>。它与氟混合在<a href="/wiki/%E7%B4%AB%E5%A4%96%E7%BA%BF" title="紫外线">紫外线</a>下继续照射可得四氟化氙。如果条件适当，该法纯度高，而且可以连续进行。</li></ul> <ul><li>二氟化二氮氟化法：在200℃以下将<a href="/wiki/%E4%BA%8C%E6%B0%9F%E5%8C%96%E4%BA%8C%E6%B0%AE" title="二氟化二氮">二氟化二氮</a>与氙共热，主要得到四氟化氙。该法可以避免使用危险且难以制备的氟单质。</li></ul> <ul><li>高能辐射合成法：用<sup>60</sup>Co产生的<a href="/wiki/%CE%93%E5%B0%84%E7%BA%BF" class="mw-redirect" title="Γ射线">γ射线</a>或1.5M<a href="/wiki/%E9%9B%BB%E5%AD%90%E4%BC%8F%E7%89%B9" title="電子伏特">eV</a>的电子流照射氙与氟的混合物。<sup id="cite_ref-无机化学丛书_5-0" class="reference"><a href="#cite_note-无机化学丛书-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup></li></ul> <div class="mw-heading mw-heading2"><h2 id="物理性质"><span id=".E7.89.A9.E7.90.86.E6.80.A7.E8.B4.A8"></span>物理性质</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&section=2" title="编辑章节：物理性质"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>四氟化氙是一种无色固体，室温下易升华。四氟化氙微溶于无水<a href="/wiki/%E6%B0%9F%E5%8C%96%E6%B0%A2" title="氟化氢">氟化氢</a>，但并不电离。它不溶于全氟<a href="/wiki/%E5%BA%9A%E7%83%B7" title="庚烷">庚烷</a>中，但可溶于NOF·3HF。<sup id="cite_ref-无机化学丛书_5-1" class="reference"><a href="#cite_note-无机化学丛书-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="结构"><span id=".E7.BB.93.E6.9E.84"></span>结构</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&section=3" title="编辑章节：结构"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>1963年<a href="/wiki/%E6%A0%B8%E7%A3%81%E5%85%B1%E6%8C%AF" title="核磁共振">核磁共振</a>谱与<a href="/wiki/X%E5%B0%84%E7%BA%BF%E6%99%B6%E4%BD%93%E5%AD%A6" title="X射线晶体学">X射线晶体学</a>数据显示其四氟化氙的空间构型为<a href="/wiki/%E5%B9%B3%E9%9D%A2%E6%AD%A3%E6%96%B9%E5%BD%A2" class="mw-redirect" title="平面正方形">平面正方形</a>。<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup>四氟化氙为体心<a href="/wiki/%E5%8D%95%E6%96%9C%E6%99%B6%E7%B3%BB" title="单斜晶系">单斜晶系</a>，X射线衍射法和<a href="/wiki/%E4%B8%AD%E5%AD%90%E8%A1%8D%E5%B0%84" class="mw-redirect" title="中子衍射">中子衍射</a>法测得Xe-F键键长约为190pm。 </p> <div class="mw-heading mw-heading2"><h2 id="化学性质"><span id=".E5.8C.96.E5.AD.A6.E6.80.A7.E8.B4.A8"></span>化学性质</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&section=4" title="编辑章节：化学性质"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>四氟化氙在室温下稳定，可以长期储存在<a href="/wiki/%E9%95%8D" title="镍">镍</a>制容器中，如果去除水和氟化氢也可保存在玻璃容器中。 </p> <ul><li>它能被<a href="/wiki/%E6%B0%A2" title="氢">氢</a>气还原，该反应可用于分析鉴定：</li></ul> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ XeF_{4}+2H_{2}{\xrightarrow {403K}}Xe+4HF}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <mn>2</mn> <msub> <mi mathvariant="normal">H</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mrow class="MJX-TeXAtom-ORD"> <mover> <mo>→</mo> <mpadded width="+0.611em" lspace="0.278em" voffset=".15em"> <mn>403</mn> <mi mathvariant="normal">K</mi> </mpadded> </mover> </mrow> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <mo>+</mo> <mn>4</mn> <mi mathvariant="normal">H</mi> <mi mathvariant="normal">F</mi> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ XeF_{4}+2H_{2}{\xrightarrow {403K}}Xe+4HF}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/0bb2f109b8649b342cc3bd49eab785e54d768d63" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; margin-top: -0.329ex; width:27.836ex; height:4.009ex;" alt="{\displaystyle {\rm {\ XeF_{4}+2H_{2}{\xrightarrow {403K}}Xe+4HF}}}"></span></dd></dl> <ul><li>它与水强烈反应<a href="/wiki/%E6%AD%A7%E5%8C%96" class="mw-redirect" title="歧化">歧化</a>，不需要<a href="/wiki/%E9%85%B8%E6%80%A7" class="mw-redirect" title="酸性">酸性</a>或<a href="/wiki/%E7%A2%B1%E6%80%A7" class="mw-redirect" title="碱性">碱性</a>介质：</li></ul> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ 6XeF_{4}+12H_{2}O\rightarrow 2XeO_{3}+4Xe\uparrow +3O_{2}\uparrow +24HF}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mn>6</mn> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <mn>12</mn> <msub> <mi mathvariant="normal">H</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mi mathvariant="normal">O</mi> <mo stretchy="false">→</mo> <mn>2</mn> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">O</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> </mrow> </msub> <mo>+</mo> <mn>4</mn> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <mo stretchy="false">↑</mo> <mo>+</mo> <mn>3</mn> <msub> <mi mathvariant="normal">O</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mo stretchy="false">↑</mo> <mo>+</mo> <mn>24</mn> <mi mathvariant="normal">H</mi> <mi mathvariant="normal">F</mi> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ 6XeF_{4}+12H_{2}O\rightarrow 2XeO_{3}+4Xe\uparrow +3O_{2}\uparrow +24HF}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/5ccdad0d1d87584960111718886b12e2acf96f3c" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:52.187ex; height:2.509ex;" alt="{\displaystyle {\rm {\ 6XeF_{4}+12H_{2}O\rightarrow 2XeO_{3}+4Xe\uparrow +3O_{2}\uparrow +24HF}}}"></span></dd> <dd>这个反应机理很复杂，Xe（IV）先发生<a href="/wiki/%E6%AD%A7%E5%8C%96%E5%8F%8D%E5%BA%94" title="歧化反应">歧化反应</a>得到Xe（0）和Xe（VI），然后分别氧化水并放出氧气。</dd></dl> <ul><li>可被氙还原成<a href="/wiki/%E4%BA%8C%E6%B0%9F%E5%8C%96%E6%B0%99" title="二氟化氙">二氟化氙</a>，也可被氟或<a href="/wiki/%E4%BA%8C%E6%B0%9F%E5%8C%96%E4%BA%8C%E6%B0%A7" title="二氟化二氧">二氟化二氧</a>等强氟化剂氧化成<a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E6%B0%99" title="六氟化氙">六氟化氙</a>：</li></ul> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ XeF_{4}+Xe{\xrightarrow {673K}}2XeF_{2}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <mrow class="MJX-TeXAtom-ORD"> <mover> <mo>→</mo> <mpadded width="+0.611em" lspace="0.278em" voffset=".15em"> <mn>673</mn> <mi mathvariant="normal">K</mi> </mpadded> </mover> </mrow> <mn>2</mn> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ XeF_{4}+Xe{\xrightarrow {673K}}2XeF_{2}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/6d688225bceab80d7da0ea13c701c3e32ffa6a8c" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; margin-top: -0.329ex; width:23.122ex; height:4.009ex;" alt="{\displaystyle {\rm {\ XeF_{4}+Xe{\xrightarrow {673K}}2XeF_{2}}}}"></span></dd> <dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ XeF_{4}+F_{2}{\xrightarrow {673K}}XeF_{6}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mrow class="MJX-TeXAtom-ORD"> <mover> <mo>→</mo> <mpadded width="+0.611em" lspace="0.278em" voffset=".15em"> <mn>673</mn> <mi mathvariant="normal">K</mi> </mpadded> </mover> </mrow> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>6</mn> </mrow> </msub> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ XeF_{4}+F_{2}{\xrightarrow {673K}}XeF_{6}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/b6c93251b5bf8e96aeb3385bd142ffa8af584dc7" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; margin-top: -0.329ex; width:21.756ex; height:4.009ex;" alt="{\displaystyle {\rm {\ XeF_{4}+F_{2}{\xrightarrow {673K}}XeF_{6}}}}"></span></dd> <dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ XeF_{4}+O_{2}F_{2}{\xrightarrow {140-195K}}XeF_{6}+O_{2}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <msub> <mi mathvariant="normal">O</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mrow class="MJX-TeXAtom-ORD"> <mover> <mo>→</mo> <mpadded width="+0.611em" lspace="0.278em" voffset=".15em"> <mn>140</mn> <mo>−</mo> <mn>195</mn> <mi mathvariant="normal">K</mi> </mpadded> </mover> </mrow> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>6</mn> </mrow> </msub> <mo>+</mo> <msub> <mi mathvariant="normal">O</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ XeF_{4}+O_{2}F_{2}{\xrightarrow {140-195K}}XeF_{6}+O_{2}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/8f71643584db2c462a9eb3ce0b7f263192e9848e" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; margin-top: -0.329ex; width:34.066ex; height:4.009ex;" alt="{\displaystyle {\rm {\ XeF_{4}+O_{2}F_{2}{\xrightarrow {140-195K}}XeF_{6}+O_{2}}}}"></span></dd></dl> <ul><li>四氟化氙是一种强氟化剂，在无水<a href="/wiki/%E6%B0%9F%E5%8C%96%E6%B0%A2" title="氟化氢">氟化氢</a>中可将金属<a href="/wiki/%E9%93%82" title="铂">铂</a>氟化成<a href="/wiki/%E5%9B%9B%E6%B0%9F%E5%8C%96%E9%93%82" title="四氟化铂">四氟化铂</a>：</li></ul> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ XeF_{4}+Pt{\xrightarrow {HF}}Xe+PtF_{4}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <mi mathvariant="normal">P</mi> <mi mathvariant="normal">t</mi> <mrow class="MJX-TeXAtom-ORD"> <mover> <mo>→</mo> <mpadded width="+0.611em" lspace="0.278em" voffset=".15em"> <mi mathvariant="normal">H</mi> <mi mathvariant="normal">F</mi> </mpadded> </mover> </mrow> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <mo>+</mo> <mi mathvariant="normal">P</mi> <mi mathvariant="normal">t</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ XeF_{4}+Pt{\xrightarrow {HF}}Xe+PtF_{4}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/f736d94a2d56714b1a54281af729eb52f328dda1" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; margin-top: -0.329ex; width:25.561ex; height:4.009ex;" alt="{\displaystyle {\rm {\ XeF_{4}+Pt{\xrightarrow {HF}}Xe+PtF_{4}}}}"></span></dd> <dd>它还能将稀土元素的三氟化物转化为四氟化物，将<a href="/wiki/%E5%9B%9B%E6%B0%9F%E5%8C%96%E7%A1%AB" title="四氟化硫">四氟化硫</a>氟化成<a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E7%A1%AB" title="六氟化硫">六氟化硫</a>（反应较慢）。</dd></dl> <ul><li>四氟化氙能与多种有机物发生氟化反应，<a href="/wiki/%E8%8A%B3%E9%A6%99%E6%97%8F%E5%8C%96%E5%90%88%E7%89%A9" class="mw-redirect" title="芳香族化合物">芳香族化合物</a>主要发生取代反应：<sup id="cite_ref-无机化学丛书_5-2" class="reference"><a href="#cite_note-无机化学丛书-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup></li></ul> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ XeF_{4}+2CF_{3}CF=CF_{2}\rightarrow 2CF_{3}CF_{2}CF_{3}+Xe}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <mn>2</mn> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> </mrow> </msub> <mi mathvariant="normal">C</mi> <mi mathvariant="normal">F</mi> <mo>=</mo> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mo stretchy="false">→</mo> <mn>2</mn> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> </mrow> </msub> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> </mrow> </msub> <mo>+</mo> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ XeF_{4}+2CF_{3}CF=CF_{2}\rightarrow 2CF_{3}CF_{2}CF_{3}+Xe}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/02499b59563d018fa0bd6ebff752ba3c0885251a" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:47.868ex; height:2.509ex;" alt="{\displaystyle {\rm {\ XeF_{4}+2CF_{3}CF=CF_{2}\rightarrow 2CF_{3}CF_{2}CF_{3}+Xe}}}"></span></dd></dl> <ul><li>它在撞击或震动下都很稳定，不会爆炸性分解。但与有机物（例如<a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%91%8B%E5%96%83" title="四氢呋喃">四氢呋喃</a>、<a href="/wiki/%E4%BA%8C%E6%B0%A7%E5%85%AD%E7%8E%AF" class="mw-redirect" title="二氧六环">二氧六环</a>、<a href="/wiki/%E4%B8%99%E9%85%AE" title="丙酮">丙酮</a>、<a href="/wiki/%E4%B9%99%E7%83%AF" title="乙烯">乙烯</a>）接触时会剧烈反应而引起燃烧。如果与气态的乙醇或丙酮反应将发生爆炸。</li> <li><a href="/wiki/%E6%B0%9F%E7%A3%BA%E9%85%B8" title="氟磺酸">氟磺酸</a>中的-OSO<sub>2</sub>F是电负性很高的基团，可取代四氟化氙中的氟原子形成衍生物：</li></ul> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\rm {\ XeF_{4}+2HOSO_{2}F\rightarrow F_{2}Xe(OSO_{2}F)_{2}+2HF}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mtext> </mtext> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> </msub> <mo>+</mo> <mn>2</mn> <mi mathvariant="normal">H</mi> <mi mathvariant="normal">O</mi> <mi mathvariant="normal">S</mi> <msub> <mi mathvariant="normal">O</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mi mathvariant="normal">F</mi> <mo stretchy="false">→</mo> <msub> <mi mathvariant="normal">F</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mi mathvariant="normal">X</mi> <mi mathvariant="normal">e</mi> <mo stretchy="false">(</mo> <mi mathvariant="normal">O</mi> <mi mathvariant="normal">S</mi> <msub> <mi mathvariant="normal">O</mi> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mi mathvariant="normal">F</mi> <msub> <mo stretchy="false">)</mo> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> </msub> <mo>+</mo> <mn>2</mn> <mi mathvariant="normal">H</mi> <mi mathvariant="normal">F</mi> </mrow> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\rm {\ XeF_{4}+2HOSO_{2}F\rightarrow F_{2}Xe(OSO_{2}F)_{2}+2HF}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/08663215608a726348cefef209dfd8f48decdad3" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.838ex; width:45.725ex; height:2.843ex;" alt="{\displaystyle {\rm {\ XeF_{4}+2HOSO_{2}F\rightarrow F_{2}Xe(OSO_{2}F)_{2}+2HF}}}"></span></dd> <dd>但后来化学家再次进行该实验时，只得到了二氟化氙的衍生物。这可能是过去使用的四氟化氙不纯造成的。<sup id="cite_ref-无机化学丛书_5-3" class="reference"><a href="#cite_note-无机化学丛书-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup></dd></dl> <ul><li>以下是四氟化氙参与的有机反应:</li></ul> <p><span typeof="mw:File"><a href="/wiki/File:XeF4-organic-reactions.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/4/40/XeF4-organic-reactions.png/550px-XeF4-organic-reactions.png" decoding="async" width="550" height="374" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/40/XeF4-organic-reactions.png/825px-XeF4-organic-reactions.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/40/XeF4-organic-reactions.png/1100px-XeF4-organic-reactions.png 2x" data-file-width="2650" data-file-height="1804" /></a></span> </p> <div class="mw-heading mw-heading2"><h2 id="参考资料"><span id=".E5.8F.82.E8.80.83.E8.B5.84.E6.96.99"></span>参考资料</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&section=5" title="编辑章节：参考资料"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-holleman1-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-holleman1_1-0">^</a></b></span> <span class="reference-text"><cite class="citation book">Holleman, Arnold F.; Wiberg, Egon. Wiberg, Nils , 编. Inorganic Chemistry. 由Eagleson, Mary; Brewer, William翻译. Academic Press. 2001: 394. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0-12-352651-5" title="Special:网络书源/0-12-352651-5"><span title="国际标准书号">ISBN</span> 0-12-352651-5</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&rft.au=Wiberg%2C+Egon&rft.aufirst=Arnold+F.&rft.aulast=Holleman&rft.btitle=Inorganic+Chemistry&rft.date=2001&rft.genre=book&rft.isbn=0-12-352651-5&rft.pages=394&rft.pub=Academic+Press&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-zumdahlpg243-2"><span class="mw-cite-backlink">^ <a href="#cite_ref-zumdahlpg243_2-0"><sup><b>2.0</b></sup></a> <a href="#cite_ref-zumdahlpg243_2-1"><sup><b>2.1</b></sup></a></span> <span class="reference-text"><cite class="citation book">Zumdahl. Chemistry. : 243. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0-618-52844-X" title="Special:网络书源/0-618-52844-X"><span title="国际标准书号">ISBN</span> 0-618-52844-X</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&rft.au=Zumdahl&rft.btitle=Chemistry&rft.genre=book&rft.isbn=0-618-52844-X&rft.pages=243&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text"><cite class="citation journal">Claassen, H. H.; Selig, H.; Malm, J. G. Xenon Tetrafluoride. <a href="/wiki/J._Am._Chem._Soc." class="mw-redirect" title="J. Am. Chem. Soc.">J. Am. Chem. Soc.</a> 1962, <b>84</b> (18): 3593. <a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fja00877a042"><span title="數位物件識別號">doi:10.1021/ja00877a042</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&rft.atitle=Xenon+Tetrafluoride&rft.au=Claassen%2C+H.+H.%3B+Selig%2C+H.%3B+Malm%2C+J.+G.&rft.date=1962&rft.genre=article&rft.issue=18&rft.jtitle=J.+Am.+Chem.+Soc.&rft.pages=3593&rft.volume=84&rft_id=info%3Adoi%2F10.1021%2Fja00877a042&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-4">^</a></b></span> <span class="reference-text"><cite class="citation journal">C. L. Chernick, H. H. Claassen, P. R. Fields 1, H. H. Hyman, J. G. Malm, W. M. Manning, M. S. Matheson, L. A. Quarterman, F. Schreiner, H. H. Selig, I. Sheft, S. Siegel, E. N. Sloth, L. Stein, M. H. Studier, J. L. Weeks, and M. H. Zirin. Fluorine Compounds of Xenon and Radon. Science. 1962, <b>138</b> (3537): 136–138. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/17818399"><span title="公共医学识别码">PMID 17818399</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.138.3537.136"><span title="數位物件識別號">doi:10.1126/science.138.3537.136</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&rft.atitle=Fluorine+Compounds+of+Xenon+and+Radon&rft.au=C.+L.+Chernick%2C+H.+H.+Claassen%2C+P.+R.+Fields+1%2C+H.+H.+Hyman%2C+J.+G.+Malm%2C+W.+M.+Manning%2C+M.+S.+Matheson%2C+L.+A.+Quarterman%2C+F.+Schreiner%2C+H.+H.+Selig%2C+I.+Sheft%2C+S.+Siegel%2C+E.+N.+Sloth%2C+L.+Stein%2C+M.+H.+Studier%2C+J.+L.+Weeks%2C+and+M.+H.+Zirin&rft.date=1962&rft.genre=article&rft.issue=3537&rft.jtitle=Science&rft.pages=136-138&rft.volume=138&rft_id=info%3Adoi%2F10.1126%2Fscience.138.3537.136&rft_id=info%3Apmid%2F17818399&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-无机化学丛书-5"><span class="mw-cite-backlink">^ <a href="#cite_ref-无机化学丛书_5-0"><sup><b>5.0</b></sup></a> <a href="#cite_ref-无机化学丛书_5-1"><sup><b>5.1</b></sup></a> <a href="#cite_ref-无机化学丛书_5-2"><sup><b>5.2</b></sup></a> <a href="#cite_ref-无机化学丛书_5-3"><sup><b>5.3</b></sup></a></span> <span class="reference-text"><cite class="citation book">张青莲. 《无机化学丛书》第一卷：稀有气体、氢、碱金属. 北京: 科学出版社. 1991年11月: P45–51. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/7-03-002238-6" title="Special:网络书源/7-03-002238-6"><span title="国际标准书号">ISBN</span> 7-03-002238-6</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&rft.au=%E5%BC%A0%E9%9D%92%E8%8E%B2&rft.btitle=%E3%80%8A%E6%97%A0%E6%9C%BA%E5%8C%96%E5%AD%A6%E4%B8%9B%E4%B9%A6%E3%80%8B%E7%AC%AC%E4%B8%80%E5%8D%B7%EF%BC%9A%E7%A8%80%E6%9C%89%E6%B0%94%E4%BD%93%E3%80%81%E6%B0%A2%E3%80%81%E7%A2%B1%E9%87%91%E5%B1%9E&rft.date=1991-11&rft.genre=book&rft.isbn=7-03-002238-6&rft.pages=P45-51&rft.place=%E5%8C%97%E4%BA%AC&rft.pub=%E7%A7%91%E5%AD%A6%E5%87%BA%E7%89%88%E7%A4%BE&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-6"><span class="mw-cite-backlink"><b><a href="#cite_ref-6">^</a></b></span> <span class="reference-text"><cite class="citation journal">Thomas H. Brown, E. B. Whipple, and Peter H. Verdier. Xenon Tetrafluoride: Fluorine-19 High-Resolution Magnetic Resonance Spectrum. Science. 1963, <b>140</b> (3563): 178. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/17819836"><span title="公共医学识别码">PMID 17819836</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.140.3563.178"><span title="數位物件識別號">doi:10.1126/science.140.3563.178</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&rft.atitle=Xenon+Tetrafluoride%3A+Fluorine-19+High-Resolution+Magnetic+Resonance+Spectrum&rft.au=Thomas+H.+Brown%2C+E.+B.+Whipple%2C+and+Peter+H.+Verdier&rft.date=1963&rft.genre=article&rft.issue=3563&rft.jtitle=Science&rft.pages=178&rft.volume=140&rft_id=info%3Adoi%2F10.1126%2Fscience.140.3563.178&rft_id=info%3Apmid%2F17819836&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-7"><span class="mw-cite-backlink"><b><a href="#cite_ref-7">^</a></b></span> <span class="reference-text"><cite class="citation journal">James A. Ibers and Walter C. Hamilton. Xenon Tetrafluoride: Crystal Structure. Science. 1963:, <b>139</b> (3550): 106–107. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/17798707"><span title="公共医学识别码">PMID 17798707</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.139.3550.106"><span title="數位物件識別號">doi:10.1126/science.139.3550.106</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&rft.atitle=Xenon+Tetrafluoride%3A+Crystal+Structure&rft.au=James+A.+Ibers+and+Walter+C.+Hamilton&rft.chron=1963%3A&rft.genre=article&rft.issue=3550&rft.jtitle=Science&rft.pages=106-107&rft.volume=139&rft_id=info%3Adoi%2F10.1126%2Fscience.139.3550.106&rft_id=info%3Apmid%2F17798707&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span> <span style="display:none;font-size:100%" class="error citation-comment">请检查<code style="color:inherit; border:inherit; padding:inherit;">|date=</code>中的日期值 (<a href="/wiki/Help:%E5%BC%95%E6%96%87%E6%A0%BC%E5%BC%8F1%E9%94%99%E8%AF%AF#bad_date" title="Help:引文格式1错误">帮助</a>)</span></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="参见"><span id=".E5.8F.82.E8.A7.81"></span>参见</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%9B%9B%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&section=6" title="编辑章节：参见"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E6%B0%99" title="四氯化氙">四氯化氙</a></li></ul> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r84265675">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist dt,.mw-parser-output .hlist li{margin:0;display:inline}.mw-parser-output .hlist.inline,.mw-parser-output .hlist.inline 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href="/wiki/Template_talk:%E6%B0%99%E5%8C%96%E5%90%88%E7%89%A9" title="Template talk:氙化合物"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E6%B0%99%E5%8C%96%E5%90%88%E7%89%A9" title="Special:编辑页面/Template:氙化合物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="氙化合物" style="font-size:110%;margin:0 5em"><a href="/wiki/%E6%B0%99#化合物" title="氙">氙化合物</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">氙(0)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%9B%9B%E6%B0%99%E5%90%88%E9%87%91(II)%E7%A6%BB%E5%AD%90" title="四氙合金(II)离子">AuXe<sub>4</sub>(Sb<sub>2</sub>F<sub>11</sub>)<sub>2</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氙(I)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><span class="ilh-all" data-orig-title="一氯化氙" data-lang-code="en" data-lang-name="英语" data-foreign-title="Xenon monochloride"><span class="ilh-page"><a href="/w/index.php?title=%E4%B8%80%E6%B0%AF%E5%8C%96%E6%B0%99&action=edit&redlink=1" class="new" title="一氯化氙（页面不存在）">XeCl</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Xenon_monochloride" class="extiw" title="en:Xenon monochloride"><span lang="en" dir="auto">Xenon monochloride</span></a></span>）</span></span></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%90%88%E9%93%82%E9%85%B8%E6%B0%99" title="六氟合铂酸氙">XePtF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%90%88%E9%93%91%E9%85%B8%E6%B0%99" title="六氟合铑酸氙">XeRhF<sub>6</sub></a></li> <li><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%90%88%E9%92%8C%E9%85%B8%E6%B0%99&action=edit&redlink=1" class="new" title="六氟合钌酸氙（页面不存在）">XeRuF<sub>6</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氙(II)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><span class="ilh-all" data-orig-title="二氢化氙" data-lang-code="fr" data-lang-name="法语" data-foreign-title="Dihydrure de xénon"><span class="ilh-page"><a href="/w/index.php?title=%E4%BA%8C%E6%B0%A2%E5%8C%96%E6%B0%99&action=edit&redlink=1" class="new" title="二氢化氙（页面不存在）">XeH<sub>2</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">法语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://fr.wikipedia.org/wiki/Dihydrure_de_x%C3%A9non" class="extiw" title="fr:Dihydrure de xénon"><span lang="fr" dir="auto">Dihydrure de xénon</span></a></span>）</span></span></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%9F%E5%8C%96%E6%B0%99" title="二氟化氙">XeF<sub>2</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%90%88%E9%93%82%E9%85%B8%E6%B0%99" title="六氟合铂酸氙">XeFPtF<sub>5</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%90%88%E9%93%82%E9%85%B8%E6%B0%99" title="六氟合铂酸氙">XeFPt<sub>2</sub>F<sub>11</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%90%88%E9%93%82%E9%85%B8%E6%B0%99" title="六氟合铂酸氙">Xe<sub>2</sub>F<sub>3</sub>PtF<sub>6</sub></a></li> <li><a href="/w/index.php?title=%E6%B0%9F%E7%A3%BA%E9%85%B8%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&redlink=1" class="new" title="氟磺酸氟化氙（页面不存在）">XeF(SO<sub>3</sub>F)</a></li> <li><a href="/wiki/%E6%B0%9F%E7%A3%BA%E9%85%B8%E6%B0%99(II)" title="氟磺酸氙(II)">Xe(SO<sub>3</sub>F)<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E6%B0%99" title="二氯化氙">XeCl<sub>2</sub></a></li></ul> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="有机氙(II)化合物" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E6%9C%89%E6%9C%BA%E6%B0%99%E5%8C%96%E5%90%88%E7%89%A9#二氟化氙衍生物" title="有机氙化合物">有机氙(II)化合物</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E4%BA%94%E6%B0%9F%E8%8B%AF%E5%9F%BA%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&redlink=1" class="new" title="五氟苯基氟化氙（页面不存在）">XeC<sub>6</sub>F<sub>5</sub>F</a></li> <li><a href="/w/index.php?title=%E4%B8%89%E6%B0%9F%E4%B9%99%E7%83%AF%E5%9F%BA(%E4%BA%94%E6%B0%9F%E8%8B%AF%E5%9F%BA)%E6%B0%99&action=edit&redlink=1" class="new" title="三氟乙烯基(五氟苯基)氙（页面不存在）">XeC<sub>6</sub>F<sub>5</sub>C<sub>2</sub>F<sub>3</sub></a></li> <li><a href="/w/index.php?title=%E4%B8%89%E6%B0%9F%E7%94%B2%E5%9F%BA(%E4%BA%94%E6%B0%9F%E8%8B%AF%E5%9F%BA)%E6%B0%99&action=edit&redlink=1" class="new" title="三氟甲基(五氟苯基)氙（页面不存在）">XeC<sub>6</sub>F<sub>5</sub>CF<sub>3</sub></a></li> <li><a href="/wiki/%E4%BA%8C(%E4%BA%94%E6%B0%9F%E8%8B%AF%E5%9F%BA)%E6%B0%99" title="二(五氟苯基)氙">Xe(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub></a></li> <li><a href="/w/index.php?title=%E4%B8%89%E6%B0%9F%E8%8B%AF%E5%9F%BA(%E4%BA%94%E6%B0%9F%E8%8B%AF%E5%9F%BA)%E6%B0%99&action=edit&redlink=1" class="new" title="三氟苯基(五氟苯基)氙（页面不存在）">XeC<sub>6</sub>F<sub>5</sub>C<sub>6</sub>H<sub>2</sub>F<sub>3</sub></a></li> <li><a href="/w/index.php?title=%E4%BA%94%E6%B0%9F%E8%8B%AF%E5%9F%BA%E6%B0%B0%E5%8C%96%E6%B0%99&action=edit&redlink=1" class="new" title="五氟苯基氰化氙（页面不存在）">XeC<sub>6</sub>F<sub>5</sub>CN</a></li> <li><a href="/w/index.php?title=%E4%BA%8C(%E4%B8%89%E6%B0%9F%E7%94%B2%E5%9F%BA)%E6%B0%99&action=edit&redlink=1" class="new" title="二(三氟甲基)氙（页面不存在）">Xe(CF<sub>3</sub>)<sub>2</sub></a></li></ul> </div></td></tr></tbody></table><div> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氙(IV)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%BA%8C%E6%B0%A7%E5%8C%96%E6%B0%99" title="二氧化氙">XeO<sub>2</sub></a></li> <li><a class="mw-selflink selflink">XeF<sub>4</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E6%B0%99" title="四氯化氙">XeCl<sub>4</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%9F%E4%B8%80%E6%B0%A7%E5%8C%96%E6%B0%99" title="二氟一氧化氙">XeOF<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%94%E6%B0%9F%E5%90%88%E6%B0%99%E9%85%B8%E5%9B%9B%E7%94%B2%E5%9F%BA%E9%93%B5" title="五氟合氙酸四甲基铵">N(CH<sub>3</sub>)<sub>4</sub>XeF<sub>5</sub></a></li></ul></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="有机氙(IV)化合物" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E6%9C%89%E6%9C%BA%E6%B0%99%E5%8C%96%E5%90%88%E7%89%A9#四氟化氙衍生物" title="有机氙化合物">有机氙(IV)化合物</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <li><a href="/w/index.php?title=%E5%9B%9B%E6%B0%9F%E7%A1%BC%E9%85%B8(%E4%BA%94%E6%B0%9F%E8%8B%AF%E5%9F%BA)%E4%BA%8C%E6%B0%9F%E5%8C%96%E6%B0%99&action=edit&redlink=1" class="new" title="四氟硼酸(五氟苯基)二氟化氙（页面不存在）">XeF<sub>2</sub>C<sub>6</sub>F<sub>5</sub>BF<sub>4</sub></a></li> </div></td></tr></tbody></table><div> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氙(VI)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E6%B0%99" title="六氟化氙">XeF<sub>6</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%9F%E4%B8%80%E6%B0%A7%E5%8C%96%E6%B0%99" title="四氟一氧化氙">XeOF<sub>4</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%9F%E4%BA%8C%E6%B0%A7%E5%8C%96%E6%B0%99" title="二氟二氧化氙">XeO<sub>2</sub>F<sub>2</sub></a></li> <li><a href="/wiki/%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%99" title="三氧化氙">XeO<sub>3</sub></a></li> <li><a href="/wiki/%E6%B0%99%E9%85%B8" title="氙酸">H<sub>2</sub>XeO<sub>4</sub></a></li> <li><a href="/wiki/%E5%85%AB%E6%B0%9F%E5%90%88%E6%B0%99(VI)%E9%85%B8%E4%BA%9A%E7%A1%9D%E9%85%B0" title="八氟合氙(VI)酸亚硝酰">(NO)<sub>2</sub>XeF<sub>8</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E7%A0%B7%E9%85%B8%E4%BA%94%E6%B0%9F%E5%90%88%E6%B0%99(VI)" title="六氟砷酸五氟合氙(VI)">[XeF<sub>5</sub>]<sup>+</sup>[AsF<sub>6</sub>]<sup>-</sup></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氙(VIII)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%9B%9B%E6%B0%A7%E5%8C%96%E6%B0%99" title="四氧化氙">XeO<sub>4</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%9F%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%99" title="二氟三氧化氙">XeO<sub>3</sub>F<sub>2</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%9F%E4%BA%8C%E6%B0%A7%E5%8C%96%E6%B0%99" title="四氟二氧化氙">XeO<sub>2</sub>F<sub>4</sub></a></li> <li><a href="/wiki/%E5%85%AB%E6%B0%9F%E5%8C%96%E6%B0%99" title="八氟化氙">XeF<sub>8</sub></a></li> <li><a href="/wiki/%E9%AB%98%E6%B0%99%E9%85%B8" title="高氙酸">H<sub>4</sub>XeO<sub>6</sub></a></li> <li><a href="/wiki/%E9%AB%98%E6%B0%99%E9%85%B8%E7%9B%90" title="高氙酸盐">XeO<sub>6</sub><sup>4-</sup></a></li></ul> </div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">检索自“<a dir="ltr" href="https://zh.wikipedia.org/w/index.php?title=四氟化氙&oldid=84647362">https://zh.wikipedia.org/w/index.php?title=四氟化氙&oldid=84647362</a>”</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Special:%E9%A1%B5%E9%9D%A2%E5%88%86%E7%B1%BB" title="Special:页面分类">分类</a>：<ul><li><a 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