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class="title is-5 mathjax"> Unraveling the relaxation dynamics of Uracil: insights from time-resolved X-ray photoelectron spectroscopy </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/physics?searchtype=author&amp;query=Faccial%C3%A0%2C+D">Davide Faccial脿</a>, <a href="/search/physics?searchtype=author&amp;query=Bonanomi%2C+M">Matteo Bonanomi</a>, <a href="/search/physics?searchtype=author&amp;query=Tenorio%2C+B+N+C">Bruno Nunes Cabral Tenorio</a>, <a href="/search/physics?searchtype=author&amp;query=Avaldi%2C+L">Lorenzo Avaldi</a>, <a href="/search/physics?searchtype=author&amp;query=Bolognesi%2C+P">Paola Bolognesi</a>, <a href="/search/physics?searchtype=author&amp;query=Callegari%2C+C">Carlo Callegari</a>, <a href="/search/physics?searchtype=author&amp;query=Coreno%2C+M">Marcello Coreno</a>, <a href="/search/physics?searchtype=author&amp;query=Coriani%2C+S">Sonia Coriani</a>, <a href="/search/physics?searchtype=author&amp;query=Decleva%2C+P">Piero Decleva</a>, <a href="/search/physics?searchtype=author&amp;query=Devetta%2C+M">Michele Devetta</a>, <a href="/search/physics?searchtype=author&amp;query=Do%C5%A1li%C4%87%2C+N">Na膽a Do拧li膰</a>, <a href="/search/physics?searchtype=author&amp;query=De+Fanis%2C+A">Alberto De Fanis</a>, <a href="/search/physics?searchtype=author&amp;query=Di+Fraia%2C+M">Michele Di Fraia</a>, <a href="/search/physics?searchtype=author&amp;query=Lever%2C+F">Fabiano Lever</a>, <a href="/search/physics?searchtype=author&amp;query=Mazza%2C+T">Tommaso Mazza</a>, <a href="/search/physics?searchtype=author&amp;query=Meyer%2C+M">Michael Meyer</a>, <a href="/search/physics?searchtype=author&amp;query=Mullins%2C+T">Terry Mullins</a>, <a href="/search/physics?searchtype=author&amp;query=Ovcharenko%2C+Y">Yevheniy Ovcharenko</a>, <a href="/search/physics?searchtype=author&amp;query=Pal%2C+N">Nitish Pal</a>, <a href="/search/physics?searchtype=author&amp;query=Piancastelli%2C+M+N">Maria Novella Piancastelli</a>, <a href="/search/physics?searchtype=author&amp;query=Richter%2C+R">Robert Richter</a>, <a href="/search/physics?searchtype=author&amp;query=Rivas%2C+D+E">Daniel E. Rivas</a>, <a href="/search/physics?searchtype=author&amp;query=Sapunar%2C+M">Marin Sapunar</a>, <a href="/search/physics?searchtype=author&amp;query=Senfftleben%2C+B">Bj枚rn Senfftleben</a>, <a href="/search/physics?searchtype=author&amp;query=Usenko%2C+S">Sergey Usenko</a> , et al. (4 additional authors not shown) </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="2503.18723v1-abstract-short" style="display: inline;"> We report a study of the electronic and nuclear relaxation dynamics of the photoexcited RNA base uracil in the gas phase, using time-resolved core level photoelectron spectroscopy together with high level calculations. The dynamics was investigated by trajectory surface-hopping calculations, and the core ionization energies were calculated for geometries sampled from these. The molecule was excite&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2503.18723v1-abstract-full').style.display = 'inline'; document.getElementById('2503.18723v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="2503.18723v1-abstract-full" style="display: none;"> We report a study of the electronic and nuclear relaxation dynamics of the photoexcited RNA base uracil in the gas phase, using time-resolved core level photoelectron spectroscopy together with high level calculations. The dynamics was investigated by trajectory surface-hopping calculations, and the core ionization energies were calculated for geometries sampled from these. The molecule was excited by a UV laser and dynamics was probed on the oxygen, nitrogen and carbon site by core electron spectroscopy. Assuming a particular model, we find that the initially excited $S_2(蟺蟺^*)$ state of uracil decays with a time constant of 17 $\pm$ 4 fs to the ground state directly, or to the $S_1(n蟺^*)$ state via internal conversion. We find no evidence that the $S_1(n蟺^*)$ state decays to the ground state by internal conversion; instead it decays to triplet states with a time constant of 1.6 $\pm$ 0.4 ps. Oscillations of the $S_1(n蟺^*)$ state O 1s intensity as a function of time correlate with those of calculated C4=O8 and C5=C6 bond lengths, which undergo a sudden expansion following the initial $蟺\to 蟺^*$ excitation. We also observe oscillations in the mean energy of the main line (core ionized ionic state), which we tentatively assign to dynamics of the hot ground state. Our calculations support our interpretation of the data, and provide detailed insight into the relaxation processes of uracil. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2503.18723v1-abstract-full').style.display = 'none'; document.getElementById('2503.18723v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 24 March, 2025; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> March 2025. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/2111.05797">arXiv:2111.05797</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/2111.05797">pdf</a>, <a href="https://arxiv.org/format/2111.05797">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Chemical Physics">physics.chem-ph</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1039/D1CP04050B">10.1039/D1CP04050B <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> A systematic study of the valence electronic structure of cyclo(Gly-Phe), cyclo(Trp-Tyr) and cyclo(Trp-Trp) dipeptides in gas phase </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/physics?searchtype=author&amp;query=Molteni%2C+E">Elena Molteni</a>, <a href="/search/physics?searchtype=author&amp;query=Mattioli%2C+G">Giuseppe Mattioli</a>, <a href="/search/physics?searchtype=author&amp;query=Alippi%2C+P">Paola Alippi</a>, <a href="/search/physics?searchtype=author&amp;query=Avaldi%2C+L">Lorenzo Avaldi</a>, <a href="/search/physics?searchtype=author&amp;query=Bolognesi%2C+P">Paola Bolognesi</a>, <a href="/search/physics?searchtype=author&amp;query=Carlini%2C+L">Laura Carlini</a>, <a href="/search/physics?searchtype=author&amp;query=Vismarra%2C+F">Federico Vismarra</a>, <a href="/search/physics?searchtype=author&amp;query=Wu%2C+Y">Yingxuan Wu</a>, <a href="/search/physics?searchtype=author&amp;query=Varillas%2C+R+B">Rocio Borrego Varillas</a>, <a href="/search/physics?searchtype=author&amp;query=Nisoli%2C+M">Mauro Nisoli</a>, <a href="/search/physics?searchtype=author&amp;query=Singh%2C+M">Manjot Singh</a>, <a href="/search/physics?searchtype=author&amp;query=Valadan%2C+M">Mohammadhassan Valadan</a>, <a href="/search/physics?searchtype=author&amp;query=Altucci%2C+C">Carlo Altucci</a>, <a href="/search/physics?searchtype=author&amp;query=Richter%2C+R">Robert Richter</a>, <a href="/search/physics?searchtype=author&amp;query=Sangalli%2C+D">Davide Sangalli</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="2111.05797v1-abstract-short" style="display: inline;"> The electronic energy levels of cyclo(Glycine-Phenylalanine), cyclo(Tryptophan-Tyrosine) and cyclo(Tryptophan-Tryptophan) dipeptides are investigated with a joint experimental and theoretical approach. Experimentally, valence photoelectron spectra in the gas phase are measured using VUV radiation. Theoretically, we first obtain low-energy conformers through an automated conformer-rotamer ensemble&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2111.05797v1-abstract-full').style.display = 'inline'; document.getElementById('2111.05797v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="2111.05797v1-abstract-full" style="display: none;"> The electronic energy levels of cyclo(Glycine-Phenylalanine), cyclo(Tryptophan-Tyrosine) and cyclo(Tryptophan-Tryptophan) dipeptides are investigated with a joint experimental and theoretical approach. Experimentally, valence photoelectron spectra in the gas phase are measured using VUV radiation. Theoretically, we first obtain low-energy conformers through an automated conformer-rotamer ensemble sampling scheme based on tight-binding simulations. Then, different first principles computational schemes are considered to simulate the spectra: Hartree-Fock (HF), density functional theory (DFT) within the B3LYP approximation, the quasi--particle GW correction, and the quantum-chemistry CCSD method. Theory allows to assign the main features of the spectra. A discussion on the role of electronic correlation is provided, by comparing computationally cheaper DFT scheme (and GW) results with the accurate CCSD method. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2111.05797v1-abstract-full').style.display = 'none'; document.getElementById('2111.05797v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 10 November, 2021; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> November 2021. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">21 pages, 16 figures (including Supplementary Information)</span> </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1307.7967">arXiv:1307.7967</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1307.7967">pdf</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Instrumentation and Detectors">physics.ins-det</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="High Energy Physics - Experiment">hep-ex</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Accelerator Physics">physics.acc-ph</span> </div> </div> <p class="title is-5 mathjax"> IRIDE White Book, An Interdisciplinary Research Infrastructure based on Dual Electron linacs&amp;lasers </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/physics?searchtype=author&amp;query=Alesini%2C+D">D. Alesini</a>, <a href="/search/physics?searchtype=author&amp;query=Alessandroni%2C+M">M. Alessandroni</a>, <a href="/search/physics?searchtype=author&amp;query=Anania%2C+M+P">M. P. Anania</a>, <a href="/search/physics?searchtype=author&amp;query=Andreas%2C+S">S. Andreas</a>, <a href="/search/physics?searchtype=author&amp;query=Angelone%2C+M">M. Angelone</a>, <a href="/search/physics?searchtype=author&amp;query=Arcovito%2C+A">A. Arcovito</a>, <a href="/search/physics?searchtype=author&amp;query=Arnesano%2C+F">F. Arnesano</a>, <a href="/search/physics?searchtype=author&amp;query=Artioli%2C+M">M. Artioli</a>, <a href="/search/physics?searchtype=author&amp;query=Avaldi%2C+L">L. Avaldi</a>, <a href="/search/physics?searchtype=author&amp;query=Babusci%2C+D">D. Babusci</a>, <a href="/search/physics?searchtype=author&amp;query=Bacci%2C+A">A. Bacci</a>, <a href="/search/physics?searchtype=author&amp;query=Balerna%2C+A">A. Balerna</a>, <a href="/search/physics?searchtype=author&amp;query=Bartalucci%2C+S">S. Bartalucci</a>, <a href="/search/physics?searchtype=author&amp;query=Bedogni%2C+R">R. Bedogni</a>, <a href="/search/physics?searchtype=author&amp;query=Bellaveglia%2C+M">M. Bellaveglia</a>, <a href="/search/physics?searchtype=author&amp;query=Bencivenga%2C+F">F. Bencivenga</a>, <a href="/search/physics?searchtype=author&amp;query=Benfatto%2C+M">M. Benfatto</a>, <a href="/search/physics?searchtype=author&amp;query=Biedron%2C+S">S. Biedron</a>, <a href="/search/physics?searchtype=author&amp;query=Bocci%2C+V">V. Bocci</a>, <a href="/search/physics?searchtype=author&amp;query=Bolognesi%2C+M">M. Bolognesi</a>, <a href="/search/physics?searchtype=author&amp;query=Bolognesi%2C+P">P. Bolognesi</a>, <a href="/search/physics?searchtype=author&amp;query=Boni%2C+R">R. Boni</a>, <a href="/search/physics?searchtype=author&amp;query=Bonifacio%2C+R">R. Bonifacio</a>, <a href="/search/physics?searchtype=author&amp;query=Boscolo%2C+M">M. Boscolo</a>, <a href="/search/physics?searchtype=author&amp;query=Boscherini%2C+F">F. Boscherini</a> , et al. (189 additional authors not shown) </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1307.7967v1-abstract-short" style="display: inline;"> This report describes the scientific aims and potentials as well as the preliminary technical design of IRIDE, an innovative tool for multi-disciplinary investigations in a wide field of scientific, technological and industrial applications. IRIDE will be a high intensity &#39;particle factory&#39;, based on a combination of a high duty cycle radio-frequency superconducting electron linac and of high ener&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1307.7967v1-abstract-full').style.display = 'inline'; document.getElementById('1307.7967v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1307.7967v1-abstract-full" style="display: none;"> This report describes the scientific aims and potentials as well as the preliminary technical design of IRIDE, an innovative tool for multi-disciplinary investigations in a wide field of scientific, technological and industrial applications. IRIDE will be a high intensity &#39;particle factory&#39;, based on a combination of a high duty cycle radio-frequency superconducting electron linac and of high energy lasers. Conceived to provide unique research possibilities for particle physics, for condensed matter physics, chemistry and material science, for structural biology and industrial applications, IRIDE will open completely new research possibilities and advance our knowledge in many branches of science and technology. IRIDE will contribute to open new avenues of discoveries and to address most important riddles: What does matter consist of? What is the structure of proteins that have a fundamental role in life processes? What can we learn from protein structure to improve the treatment of diseases and to design more efficient drugs? But also how does an electronic chip behave under the effect of radiations? How can the heat flow in a large heat exchanger be optimized? The scientific potential of IRIDE is far reaching and justifies the construction of such a large facility in Italy in synergy with the national research institutes and companies and in the framework of the European and international research. It will impact also on R&amp;D work for ILC, FEL, and will be complementarity to other large scale accelerator projects. IRIDE is also intended to be realized in subsequent stages of development depending on the assigned priorities. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1307.7967v1-abstract-full').style.display = 'none'; document.getElementById('1307.7967v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 30 July, 2013; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> July 2013. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">270 pages</span> </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1202.6496">arXiv:1202.6496</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1202.6496">pdf</a>, <a href="https://arxiv.org/ps/1202.6496">ps</a>, <a href="https://arxiv.org/format/1202.6496">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Atomic and Molecular Clusters">physics.atm-clus</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Atomic Physics">physics.atom-ph</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1088/0953-4075/45/14/141002">10.1088/0953-4075/45/14/141002 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Interplay of the volume and surface plasmons in the electron energy loss spectra of C$_{60}$ </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/physics?searchtype=author&amp;query=Verkhovtsev%2C+A+V">Alexey V. Verkhovtsev</a>, <a href="/search/physics?searchtype=author&amp;query=Korol%2C+A+V">Andrei V. Korol</a>, <a href="/search/physics?searchtype=author&amp;query=Solov%27yov%2C+A+V">Andrey V. Solov&#39;yov</a>, <a href="/search/physics?searchtype=author&amp;query=Bolognesi%2C+P">Paola Bolognesi</a>, <a href="/search/physics?searchtype=author&amp;query=Ruocco%2C+A">Alessandro Ruocco</a>, <a href="/search/physics?searchtype=author&amp;query=Avaldi%2C+L">Lorenzo Avaldi</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1202.6496v2-abstract-short" style="display: inline;"> The results of a joint experimental and theoretical investigation of the C60 collective excitations in the process of inelastic scattering of electrons are presented. The shape of the electron energy loss spectrum is observed to vary when the scattering angle increases. This variation arising due to the electron diffraction of the fullerene shell is described by a new theoretical model which treat&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1202.6496v2-abstract-full').style.display = 'inline'; document.getElementById('1202.6496v2-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1202.6496v2-abstract-full" style="display: none;"> The results of a joint experimental and theoretical investigation of the C60 collective excitations in the process of inelastic scattering of electrons are presented. The shape of the electron energy loss spectrum is observed to vary when the scattering angle increases. This variation arising due to the electron diffraction of the fullerene shell is described by a new theoretical model which treats the fullerene as a spherical shell of a finite width and accounts for the two modes of the surface plasmon and for the volume plasmon as well. It is shown that at small angles, the inelastic scattering cross section is determined mostly by the symmetric mode of the surface plasmon, while at larger angles, the contributions of the antisymmetric surface plasmon and the volume plasmon become prominent. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1202.6496v2-abstract-full').style.display = 'none'; document.getElementById('1202.6496v2-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 26 October, 2013; <span class="has-text-black-bis has-text-weight-semibold">v1</span> submitted 29 February, 2012; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> February 2012. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">11 pages, 3 figures</span> </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Journal ref:</span> J. Phys. B: At. Mol. Opt. Phys. 45 (2012) 141002 (Fast Track Communication) </p> </li> </ol> <div class="is-hidden-tablet"> <!-- feedback for mobile only --> <span class="help" style="display: inline-block;"><a href="https://github.com/arXiv/arxiv-search/releases">Search v0.5.6 released 2020-02-24</a>&nbsp;&nbsp;</span> </div> </div> </main> <footer> <div class="columns is-desktop" role="navigation" aria-label="Secondary"> <!-- MetaColumn 1 --> <div class="column"> <div class="columns"> <div class="column"> <ul class="nav-spaced"> <li><a href="https://info.arxiv.org/about">About</a></li> <li><a href="https://info.arxiv.org/help">Help</a></li> </ul> </div> <div class="column"> <ul class="nav-spaced"> <li> <svg xmlns="http://www.w3.org/2000/svg" viewBox="0 0 512 512" class="icon filter-black" role="presentation"><title>contact arXiv</title><desc>Click here to contact arXiv</desc><path d="M502.3 190.8c3.9-3.1 9.7-.2 9.7 4.7V400c0 26.5-21.5 48-48 48H48c-26.5 0-48-21.5-48-48V195.6c0-5 5.7-7.8 9.7-4.7 22.4 17.4 52.1 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