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IR-30 - HLWU - RDGroups

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</a> <ul aria-expanded="false" class="child-menu dropdown-menu" role="menu"> <li class="" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_main_navigation_20" role="presentation"> <a class="dropdown-item" href="https://rdgroups.ciemat.es/web/hlwu/publicaciones" role="menuitem">Publicaciones</a> </li> <li class="" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_main_navigation_16" role="presentation"> <a class="dropdown-item" href="https://rdgroups.ciemat.es/web/hlwu/congresos" role="menuitem">Congresos</a> </li> <li class="" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_main_navigation_19" role="presentation"> <a class="dropdown-item" href="https://rdgroups.ciemat.es/web/hlwu/tesis" role="menuitem">Tesis</a> </li> </ul> </li> <li class="lfr-nav-item nav-item dropdown" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_main_navigation_37" role="presentation"> <a aria-haspopup='true' class="nav-link text-truncate dropdown-toggle" href='https://rdgroups.ciemat.es/web/hlwu/eventos' role="menuitem"> <span class="text-truncate"> Eventos <span class="lfr-nav-child-toggle"> <span class="c-inner" tabindex="-1" id="ffek____"><svg aria-hidden="true" class="lexicon-icon lexicon-icon-angle-down" focusable="false" ><use href="https://rdgroups.ciemat.es/o/ciemat2018-theme/images/clay/icons.svg#angle-down"></use></svg></span> </span> </span> </a> <ul aria-expanded="false" class="child-menu dropdown-menu" role="menu"> <li class="" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_main_navigation_43" role="presentation"> <a class="dropdown-item" href="https://rdgroups.ciemat.es/web/hlwu/eventos/raman-workshop" role="menuitem">Raman Workshop on the back-end of the nuclear fuel cycle</a> </li> </ul> </li> </ul> </div> <script> AUI().use( 'liferay-navigation-interaction', function(A) { (function() { var $ = AUI.$;var _ = AUI._; var navigation = A.one('#navbar_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_main_navigation'); Liferay.Data.NAV_INTERACTION_LIST_SELECTOR = '.navbar-site'; Liferay.Data.NAV_LIST_SELECTOR = '.navbar-site'; if (navigation) { navigation.plug(Liferay.NavigationInteraction); } })(); }); </script> </div> </div> </div> </section> </div> </div> </div> </div> <div class="navbar navbar-classic navbar-expand-md navbar-light order-2 order-md-2" id="breadcrums"> <div class="container-fluid container-fluid-max-xl breadcrumbs-container"> <div class="d-flex flex-column"> <h1>IR-30</h1> <div class="portlet-boundary portlet-boundary_com_liferay_site_navigation_breadcrumb_web_portlet_SiteNavigationBreadcrumbPortlet_ portlet-static portlet-static-end portlet-barebone portlet-breadcrumb " id="p_p_id_com_liferay_site_navigation_breadcrumb_web_portlet_SiteNavigationBreadcrumbPortlet_"> <span id="p_com_liferay_site_navigation_breadcrumb_web_portlet_SiteNavigationBreadcrumbPortlet"></span> <section class="portlet" id="portlet_com_liferay_site_navigation_breadcrumb_web_portlet_SiteNavigationBreadcrumbPortlet"> <div class="portlet-content"> <div class=" portlet-content-container"> <div class="portlet-body"> <nav aria-label="Ruta de navegación" id="_com_liferay_site_navigation_breadcrumb_web_portlet_SiteNavigationBreadcrumbPortlet_breadcrumbs-defaultScreen"> <ol class="breadcrumb"> <li class="breadcrumb-item"> <a class="breadcrumb-link" > <span class="breadcrumb-text-truncate">HLWU</span> </a> </li> <li class="breadcrumb-item"> <a class="breadcrumb-link" href="https://rdgroups.ciemat.es/web/hlwu/laboratorios" > <span class="breadcrumb-text-truncate">Laboratorios</span> </a> </li> <li class="breadcrumb-item"> <span class="active breadcrumb-text-truncate">IR-30</span> </li> </ol> </nav> </div> </div> </div> </section> </div> </div> </div> </div> </header> <section class="container flex-fill" id="content"> <h2 class="sr-only" role="heading" aria-level="1">IR-30 - HLWU</h2> <style type="text/css"> .master-layout-fragment .portlet-header { display: none; } </style> <div class="columns-1" id="main-content" role="main"> <div class="portlet-layout row"> <div class="col-md-12 portlet-column portlet-column-only" id="column-1"> <div class="portlet-dropzone portlet-column-content portlet-column-content-only" id="layout-column_column-1"> <div class="portlet-boundary portlet-boundary_com_liferay_journal_content_web_portlet_JournalContentPortlet_ portlet-static portlet-static-end portlet-barebone portlet-journal-content " id="p_p_id_com_liferay_journal_content_web_portlet_JournalContentPortlet_INSTANCE_79Y1MAXMwm7M_"> <span id="p_com_liferay_journal_content_web_portlet_JournalContentPortlet_INSTANCE_79Y1MAXMwm7M"></span> <section class="portlet" id="portlet_com_liferay_journal_content_web_portlet_JournalContentPortlet_INSTANCE_79Y1MAXMwm7M"> <div class="portlet-content"> <div class="autofit-float autofit-row portlet-header"> <div class="autofit-col autofit-col-end"> <div class="autofit-section"> <div class="visible-interaction"> </div> </div> </div> </div> <div class=" portlet-content-container"> <div class="portlet-body"> <div class="" data-fragments-editor-item-id="10108-6994951" data-fragments-editor-item-type="fragments-editor-mapped-item" > <div class="journal-content-article " data-analytics-asset-id="6994949" data-analytics-asset-title="IR30" data-analytics-asset-type="web-content"> <style> ol > li { font-size: 13px !important; line-height: 21px; font-weight: 400; margin-bottom:7px; color: #777!important; text-align: justify!important; } </style> <script> $(function() { $("#accordion6994949").accordion({ autoHeight: false, navigation: true, heightStyle: "content", collapsible: true, active:"none" }); }); </script> <div class="ev-content-container"> <div class="mx-page-title row left line-bottom"> <div class="mx-pagetitle-line"></div> <span class="fa-stack fa-2x icon-color"> <i class="fa-solid fa-circle fa-stack-2x"></i> <i class="fa-solid fa-flask fa-stack-1x fa-inverse"></i> </span> <span class="mx-page-title-extra ">IR-30</span> </div> <p></p><p>&nbsp;</p> <p><span style="font-size:16px;">&nbsp; <a href="http://rdgroups.ciemat.es/web/hlwu/ir35">Ir a IR-35</a>&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; <a href="http://rdgroups.ciemat.es/web/hlwu/laboratorios-convencionales">Ir a Laboratorios Convencionales</a></span></p> <p>&nbsp;</p> <p><span style="font-size:16px;"><picture data-fileentryid="6684587"><source media="(max-width:128px)" srcset="/o/adaptive-media/image/6684587/Thumbnail-128x128/IR30+cajas+de+guantes.jpg?t=1671538086548" /><source media="(max-width:1000px) and (min-width:128px)" srcset="/o/adaptive-media/image/6684587/Preview-1000x0/IR30+cajas+de+guantes.jpg?t=1671538086548" /><img alt="" src="/documents/6058581/6110709/IR30+cajas+de+guantes.jpg/9683f8af-7970-4133-9120-0f0bebe74c55?t=1671538086548" style="width: 290px; border-width: 0px; border-style: solid; margin: 10px 20px; height: 218px; float: right;" /></picture></span></p> <p style="text-align: justify;"><span style="font-size:16px;"><strong style="text-align: justify;">Laboratorios radiactivos IR-30</strong><span style="text-align: justify;">: Laboratorios para manipular radionucleidos de larga vida, que incluyen dos instalaciones radiactivas asociadas.</span></span></p> <p style="margin-left: 40px; text-align: justify;"><span style="font-size:16px;"><u><strong>IR- 30-(S1.26) Laboratorio experimental.</strong></u></span></p> <p style="margin-left: 40px; text-align: justify;"><span style="font-size:16px;">Es un&nbsp;laboratorio equipado y autorizado para realizar experimentos con una gran variedad de radioisótopos. Se pueden realizar pruebas de solubilidad, oxidación y lixiviación a escala a largo plazo en condiciones geológicas finales, fabricación de nuevos sistemas basados en diferentes matrices sólidas y estudios para la mejora o desarrollo de procesos de reprocesado de combustible nuclear, como son: procesos de extracción entre dos fases líquido-líquido, estudios de complejación de radionúclidos, estudios de capacidad de carga de un determinado elemento, estudios de transferencia de masa entre fases y estudios estabilidad de sistemas frente a la hidrólisis y/o radiólisis.</span></p> <p style="margin-left: 40px; text-align: justify;"><span style="font-size:16px;">Este laboratorio está equipado con: 3 cajas de guantes anóxicas (atmósfera de Ar para ensayos en condiciones de atmósfera controlada), 5 campanas extractoras, prensa uniaxial (25Tn), horno (1700°C); molino mezclador, pulidor y preparación de superficies metalográficas, ultracentrifugación, valoradores, viscosímetro, colorimetría y quimioluminiscencia, electrodeposición para análisis de muestras alfa, espectroscopia UV-Vis, cámara climática, tratamientos térmicos, etc.</span></p> <p style="margin-left: 40px; text-align: justify;"><span style="font-size:16px;"><u><strong>IR- 30-(S1.21) Laboratorio de análisis</strong></u></span></p> <p style="margin-left: 40px; text-align: justify;"><span style="font-size:16px;">Este laboratorio&nbsp;está equipado para el análisis cualitativo y cuantitativo de la composición de muestras acuosas y orgánicas mediante espectrometría gamma y alfa, ICP-MS y HPLC-MS.</span></p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><span style="font-size:16px;">Supervisores de las Instalaciones Radiactivas IR30/IR35:</span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:nieves.rodriguez@ciemat.es">nieves.rodriguez@ciemat.es</a></span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:sergio.fernandez@ciemat.es">sergio.fernandez@ciemat.es</a></span></p><p></p> <div id="accordion6994949"> <h4>Espectrometría gamma y alfa</h4> <div><p></p><p style="text-align: justify;"><span style="font-size:16px;"><span style="text-align: justify;">Generalmente, en la URRAA evaluamos la variación de la capacidad de extracción de un determinado metal (o familia de metales) entre dos fases, una acuosa y una orgánica a lo largo de diferentes procesos de separación y&nbsp; bajo condiciones de extrema acidez y radiación. Para ello es necesario evaluar cuánto metal pasa de una fase a otra variando esas condiciones. La concentración de cada uno de los isótopos se determina en la fase orgánica y en la fase acuosa empleando diferentes técnicas en función de las características propias del elemento/radionucleido/isótopo en cuestión.</span></span></p> <p style="text-align: justify;"><span style="font-size:16px;"><picture data-fileentryid="6110839"><source media="(max-width:66px)" srcset="/o/adaptive-media/image/6110839/Thumbnail-128x128/espectrometriaGamma.jpg?t=1652178768913" /><source media="(max-width:404px) and (min-width:66px)" srcset="/o/adaptive-media/image/6110839/Preview-1000x0/espectrometriaGamma.jpg?t=1652178768913" /><img alt="" src="/documents/6058581/6110709/espectrometriaGamma.jpg/67d057e8-0de0-4b9a-9e0f-243d82abe7ba?t=1652178768913" style="height: 290px; border-style: solid; text-align: justify; width: 150px; margin: 10px 20px; float: right;" /></picture></span></p> <p style="text-align: justify;"><span style="font-size:16px;"><span style="text-align: justify;">En la instalación IR-30 (Edificio 12 S1. d21) del CIEMAT (Madrid, España) disponemos de dos&nbsp;detectores de semiconductor GeHP&nbsp;del 20% de eficiencia intrínseca, asociado a una cadena electrónica y un analizador multicanal (AMC) DSA-1000 (Canberra Industries Inc., Meriden, EEUU). Los análisis de los espectros se realizan con el software Genie-2000 (Canberra Industries Inc., Meriden, EEUU). Por ejemplo, la determinación de la concentración de&nbsp;241Am y&nbsp;152Eu en las disoluciones orgánica y acuosa se lleva a cabo, utilizando sus energías características de 59.5 keV (35.9%) y 122 keV (28.4%), respectivamente. Las calibraciones en energías y eficiencias se realizaron utilizando el cóctel de emisores gamma QCY-48 (Amersham, U.K.). Los elementos con los que trabajamos habitualmente son&nbsp; (principalmente&nbsp;241Am y&nbsp;152Eu, y en contadas ocasiones&nbsp;&nbsp;238Pu,&nbsp;237Np,&nbsp;233-235U,&nbsp;230-232Th). La concentración de actividad de determinados isotopos, como puede ser el&nbsp;238U, mediante espectrometría gamma se determina a partir del análisis de las emisiones gamma de sus descendientes. Si bien la espectrometría gamma no es la mejor técnica para la cuantificación del uranio (como sí lo es el ICP-MS) nos permite llevar a cabo una buena estimación en muy poco tiempo, además de no ser una técnica destructiva.</span></span></p> <p>&nbsp;</p> <div> <p style="text-align: justify;"><span style="font-size:16px;"><picture data-fileentryid="6620895"><source media="(max-width:128px)" srcset="/o/adaptive-media/image/6620895/Thumbnail-128x128/alfa2.jpg?t=1669379456170" /><source media="(max-width:1000px) and (min-width:128px)" srcset="/o/adaptive-media/image/6620895/Preview-1000x0/alfa2.jpg?t=1669379456170" /><img alt="" src="/documents/6058581/6110709/alfa2.jpg/7a54ffdb-49c0-4079-a302-d4e2593e9270?t=1669379456170" style="height: 143px; border-style: solid; width: 190px; margin: 11px; float: left;" /></picture>También contamos con un&nbsp;<strong>equipo Alpha Analyst</strong>&nbsp;de la marca Canberra con cuatro cámaras independientes de medida de emisores alfa, cada una de ellas con un detector semiconductor tipo PIPS en su interior. Estos detectores son del modelo A450-18AM, con una superficie activa de 450 mm2 y una resolución energética certificada de 18 keV para la emisión de 5486 keV del&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">241</span></span>Am. La calibración en energías se lleva a cabo mediante una fuente patrón de&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">233</span></span>U,&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">239</span></span>Pu y&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">241</span></span>Am. Y la metodología normalmente empleada, dadas la concentración de actividad presente en nuestras muestras, es la deposición de la muestra (previa separación radioquímica) en la plancheta y/o evaporación bajo lámpara de IR. Está técnica nos permite la determinación de la concentración de&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">241</span></span>Am&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">244</span></span>Cm,&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">233-235</span></span>U y, eventualmente,&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">237</span></span>Np,&nbsp;<span style="font-size:12px;"><span style="position: relative; line-height: 0; vertical-align: baseline; top: -0.5em;">239</span></span>Pu, entre otros.</span></p> <p>&nbsp;</p> <p><span style="font-size:16px;">Encargados de las&nbsp;técnicas:</span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:pablo.vacas@ciemat.es">pablo.vacas@ciemat.es</a></span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:ivan.sanchez@ciemat.es">ivan.sanchez@ciemat.es</a></span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:ana.nunez@ciemat.es">ana.nunez@ciemat.es</a></span></p> </div><p></p></div> <h4>HPLC-MS</h4> <div><p></p><p style="text-align: justify;"><span style="font-size:16px;"><span style="text-align: justify;">En la instalación IR-30 (Edificio 12 S1. d21) del CIEMAT (Madrid, España) disponemos&nbsp;un equipo Bruker LCMS Triple Cuadrupolo EVOQ QUBE con HPLC Advance.&nbsp;</span></span></p> <span style="font-size:16px;"><picture data-fileentryid="6618318"><source media="(max-width:128px)" srcset="/o/adaptive-media/image/6618318/Thumbnail-128x128/HPLCMS.jpg?t=1669315233001" /><source media="(max-width:1000px) and (min-width:128px)" srcset="/o/adaptive-media/image/6618318/Preview-1000x0/HPLCMS.jpg?t=1669315233001" /><img alt="" src="/documents/6058581/6110709/HPLCMS.jpg/0e08a81b-c795-4ebe-b648-48dc131afaa3?t=1669315233001" style="height: 158px; text-align: justify; width: 210px; float: right; margin: 15px;" /></picture></span> <div> <p style="text-align: justify;"><span style="font-size:16px;"><span style="text-align: justify;">Este equipo se puede dividir en tres módulos bien diferenciados entre ellos, que son el sistema de&nbsp;&nbsp;cromatografía líquida de alta eficacia (HPLC) Bruker Advance, el inyector automático robotizado Bruker PAL-xt, y por último el detector Bruker EVOQ QUBE triple cuadrupolo.</span></span></p> </div> <div> <p style="text-align: justify;"><span style="font-size:16px;"><span style="text-align: justify;">La cromatografía líquida (LC) combinada con la espectroscopía de masas (MS) es una técnica analítica que nos permite el análisis cuali y cuantitativo de diferentes compuestos orgánicos con los que llevamos años trabajando dentro de la línea de separación de radionucleidos del combustible nuclear.</span></span></p> <p style="text-align: justify;">&nbsp;</p> <p style="text-align: justify;"><span style="font-size:16px;">Encargados&nbsp;de la técnica:</span></p> <p style="text-align: justify;"><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:lorena.serrano@ciemat.es"><span style="color:#6cb3ef;">lorena.serrano@ciemat.es</span></a></span></p> <p style="text-align: justify;"><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:ivan.sanchez@ciemat.es"><span style="color:#6cb3ef;">ivan.sanchez@ciemat.es</span></a></span></p> </div><p></p></div> <h4>ICP-MS</h4> <div><p></p><p style="text-align: justify;"><span style="font-size:16px;">En la instalación IR-30 (Edificio 12 S1. d21) del CIEMAT (Madrid, España) disponemos un espectrometro de masas con fuente de plasma de acoplamiento inducido (ICP-MS) (Thermo Scientific ™ iCAP ™ Q ICP-MS), con el modo celda de colisión (CCT). Y de un purificador de ácido nítrico para la preparación de muestras (Milestone Sub-DuoPUR).</span></p> <p style="text-align: justify;"><span style="font-size:16px;">Las ventajas principales de esta técnica radican en la alta precisión, bajos límites de detección y bajo coste económico, analizando la mayoría de los elementos e isótopos presentes en la tabla periódica de manera simultánea en no más de un par de minutos. Es por lo tanto, una técnica ideal en el análisis de aguas, lixiviados de rocas y minerales, etc.</span></p> <span style="font-size:16px;"><picture data-fileentryid="6671681"><source media="(max-width:128px)" srcset="/o/adaptive-media/image/6671681/Thumbnail-128x128/IR30+ICP-MS.jpg?t=1671104479203" /><source media="(max-width:1000px) and (min-width:128px)" srcset="/o/adaptive-media/image/6671681/Preview-1000x0/IR30+ICP-MS.jpg?t=1671104479203" /><img alt="" src="/documents/6058581/6110709/IR30+ICP-MS.jpg/7393dbb7-d392-4622-bcd6-c7a6b73c1c36?t=1671104479203" style="height: 158px; border-style: solid; text-align: justify; width: 210px; float: left; margin: 10px 15px;" /></picture></span> <p style="text-align: justify;"><span style="font-size:16px;">Existen numerosos ejemplos en los que se requiere la determinación precisa y exacta de los ratios (o proporciones) isotópicos de radionucleidos de vida larga en la caracterización de materiales nucleares, para lo que la técnica ICP es válida.&nbsp;</span></p> <p style="text-align: justify;"><span style="font-size:16px;">Por ejemplo, en la caracterización de los residuos radiactivos es necesaria especialmente con respecto a los transuránidos de vida larga (<sup>237</sup>Np , <sup>239</sup>Pu, <sup>240</sup>Pu, <sup>242</sup>Pu, &nbsp;<sup>241</sup>Am,<sup> 243</sup>Am) y productos de fisión y activación (<sup>79</sup>Se, <sup>93</sup>Zr, <sup>99</sup>Tc, <sup>107</sup>Pd, <sup>126</sup>Sn, <sup>129</sup>I y <sup>135</sup>Cs).&nbsp;</span></p> <p style="text-align: justify;"><span style="font-size:16px;">Los métodos radioquímicos convencionales a niveles bajos de concentración requieren una separación química cuidadosa del analito, para lograr límites de detección bajos y esto suele llevar mucho tiempo. El desarrollo de métodos analíticos para la determinación de radionucleidos de vida larga a niveles de concentración de ultratrazas en muestras radiactivas se centra en reducir el volumen de la muestra y en mejorar los límites de detección, la precisión y la exactitud de las medidas.</span></p> <p>&nbsp;</p> <p><span style="font-size:16px;">Encargada&nbsp;de la&nbsp;técnica:</span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:Sofia.duran@ciemat.es" style="text-align: justify;">sofia.duran@ciemat.es</a></span></p><p></p></div> <h4>Purificación de uranio</h4> <div><p></p><p style="text-align: justify;"><span style="font-size:16px;"><span style="text-align: justify;">Hasta la fecha, en la unidad había una gran cantidad de muestras de uranio de muy diversa procedencia que era almacenada en la IR30 para ser tratada como residuo. Gran parte de estas muestras proceden de diferentes procesos de preparación de pastillas y están compuestas por diferentes partículas residuales generadas como desgaste de la fricción entre los materiales usados además de diferentes dopantes y el propio óxido de uranio. Teniendo en cuenta la experiencia en la URRAA en los procesos de separación, se planteó purificar el uranio llevando a cabo la separación del uranio de las demás impurezas que pueda haber.</span></span></p> <p style="text-align: justify;"><span style="font-size:16px;"><span style="text-align: justify;">Se llevó a cabo una búsqueda de métodos de purificación de uranio mediante procesos de separación hidrometalúrgicos y el que mostró un mayor rendimiento de extracción, una menor generación de residuos finales y menor el coste se consiguió cuando se empleó la técnica de extracción liquido-liquido empleando el agente extractante TBP (Tributilfosfato). En estos últimos años se han purificado más de 100 gramos de uranio que en años anteriores habrían sido considerados como residuo.</span></span></p> <p>&nbsp;</p> <p><span style="font-size:16px;"><span style="text-align: justify;">Encargados de la&nbsp;técnica:</span></span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:ana.nunez@ciemat.es" title="Correo electrónico">ana.nunez@ciemat.es</a></span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:L.Anta@ciemat.es" target="_blank" title="Correo electrónico">L.Anta@ciemat.es</a></span></p> <p><span style="font-size:16px;"><picture data-fileentryid="6734368"><source media="(max-width:128px)" srcset="/o/adaptive-media/image/6734368/Thumbnail-128x128/Puri+corregido.jpg?t=1673264749215" /><source media="(max-width:960px) and (min-width:128px)" srcset="/o/adaptive-media/image/6734368/Preview-1000x0/Puri+corregido.jpg?t=1673264749215" /><img alt="" src="/documents/6058581/6110709/Puri+corregido.jpg/4225620a-7723-4ee3-88d4-71a1687b855e?t=1673264749215" /></picture></span></p> <p>&nbsp;</p><p></p></div> <h4>Autoclaves</h4> <div><p></p><p style="text-align: justify;"><span style="font-size:16px;"><span style="color:#888;">En la instalación IR-30 (Edificio 12 S1. d21) del CIEMAT (Madrid, España) disponemos de un sistema de autoclaves para realización de diferentes experimentos simulando condiciones de almacenamiento de combustible irradiado, tanto de almacenamiento temporal (seco) como definitivo (húmedo). Los autoclaves consisten en reactores de forma tubular de acero inoxidable que se acoplan a un bloque isotermo de aluminio, el cual se conecta a un controlador de temperatura para establecer las condiciones experimentales. Cada autoclave dispone de dos tubos auxiliares para entrada y salida de gas, por lo que la atmósfera dentro de cada reactor está controlada de acuerdo a las necesidades del experimento.</span></span></p> <p>&nbsp;</p> <p><span style="font-size:16px;">Encargados de la&nbsp;técnica:</span></p> <p style="text-align: justify;"><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:ivan.sanchez@ciemat.es">abel.milena@ciemat.es</a></span></p> <p style="text-align: justify;"><span style="font-size:16px;"><picture data-fileentryid="6062178"><source media="(max-width:30px)" srcset="/o/adaptive-media/image/6062178/Preview-1000x0/email.png?t=1650546030574" /><source media="(max-width:30px) and (min-width:30px)" srcset="/o/adaptive-media/image/6062178/Thumbnail-128x128/email.png?t=1650546030574" /><img alt="" src="/documents/6058581/6109960/email.png/15f9babd-8d07-48b5-9e6b-f1f438c6ff0b?t=1650546030574" style="height: 35px; text-align: justify; width: 30px; margin-left: 5px; margin-right: 5px;" /></picture><a href="mailto:ivan.sanchez@ciemat.es">l.anta@ciemat.es</a></span></p> <p style="text-align: justify;"><span style="font-size:16px;"><a href="mailto:ivan.sanchez@ciemat.es"><picture data-fileentryid="6672778"><source media="(max-width:128px)" srcset="/o/adaptive-media/image/6672778/Thumbnail-128x128/Autoclaves1.jpg?t=1671127075226" /><source media="(max-width:960px) and (min-width:128px)" srcset="/o/adaptive-media/image/6672778/Preview-1000x0/Autoclaves1.jpg?t=1671127075226" /><img alt="" src="/documents/6058581/6618111/Autoclaves1.jpg/79a27b31-2ee7-492a-856d-fa31c860fb91?t=1671127075226" /></picture></a></span></p><p></p></div> </div> </div> </div> </div> </div> </div> </div> </section> </div> </div> </div> </div> </div> <form action="#" aria-hidden="true" class="hide" id="hrefFm" method="post" name="hrefFm"><span></span><button hidden type="submit">Oculto</button></form> </section> <footer id="footer" role="contentinfo"> <div class="navbar d-none d-md-block"> <div class="container-fluid container-fluid-max-xl"> <div id="navigation_footer"> <div class="portlet-boundary portlet-boundary_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_ portlet-static portlet-static-end portlet-barebone portlet-navigation " id="p_p_id_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_"> <span id="p_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation"></span> <section class="portlet" id="portlet_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation"> <div class="portlet-content"> <div class=" portlet-content-container"> <div class="portlet-body"> <div id="navbar_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation"> <ul aria-label="Páginas del sitio web" class="navbar-blank navbar-nav navbar-site" role="menubar"> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_1" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/inicio' role="menuitem"> <span class="text-truncate"> Inicio </span> </a> </li> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_2" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/personal' role="menuitem"> <span class="text-truncate"> Personal </span> </a> </li> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_3" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/laboratorios' role="menuitem"> <span class="text-truncate"> Laboratorios </span> </a> </li> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_9" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/lineas-de-investigacion' role="menuitem"> <span class="text-truncate"> Líneas de investigación </span> </a> </li> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_4" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/proyectos' role="menuitem"> <span class="text-truncate"> Proyectos </span> </a> </li> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_26" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/noticias' role="menuitem"> <span class="text-truncate"> Noticias </span> </a> </li> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_6" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/produccion-cientifica' role="menuitem"> <span class="text-truncate"> Producción Científica </span> </a> </li> <li class="lfr-nav-item nav-item" id="layout_com_liferay_site_navigation_menu_web_portlet_SiteNavigationMenuPortlet_INSTANCE_footer_navigation_37" role="presentation"> <a class="nav-link text-truncate" href='https://rdgroups.ciemat.es/web/hlwu/eventos' role="menuitem"> <span class="text-truncate"> Eventos </span> </a> </li> </ul> </div> <script> AUI().use( 'liferay-navigation-interaction', function(A) { (function() { var $ = AUI.$;var _ = AUI._; 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