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Rhenium trioxide chloride - Wikipedia

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class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">From Wikipedia, the free encyclopedia</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="en" dir="ltr"><style data-mw-deduplicate="TemplateStyles:r1084375498">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox"> <caption>Rhenium trioxide chloride </caption> <tbody><tr> <td colspan="2" style="text-align:center; padding:2px;"><span typeof="mw:File"><a href="/wiki/File:ReO3ClTd.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/3/38/ReO3ClTd.svg/120px-ReO3ClTd.svg.png" decoding="async" width="120" height="116" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/3/38/ReO3ClTd.svg/180px-ReO3ClTd.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/3/38/ReO3ClTd.svg/240px-ReO3ClTd.svg.png 2x" data-file-width="67" data-file-height="65" /></a></span> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Names </th></tr> <tr> <td colspan="2" style="text-align:left;">Other names <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;">Rhenium oxychloride</div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Identifiers </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CAS_Registry_Number" title="CAS Registry Number">CAS Number</a></div> </td> <td><style data-mw-deduplicate="TemplateStyles:r1126788409">.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}</style><div class="plainlist"><ul><li><span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=42246-25-3">42246-25-3</a></span></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">3D model (<a href="/wiki/JSmol" class="mw-redirect" title="JSmol">JSmol</a>)</div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="chemapps.stolaf.edu (3D interactive model)"><a rel="nofollow" class="external text" href="https://chemapps.stolaf.edu/jmol/jmol.php?model=O%3D%5BRe%5D%28%3DO%29%28%3DO%29Cl">Interactive image</a></span></li></ul></div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal; background:transparent;"><div><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key:&#160;YDGWOHYNESLUAQ-UHFFFAOYSA-M</div></div></li></ul> </div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal; background:transparent;"><div><a href="/wiki/Simplified_molecular-input_line-entry_system" class="mw-redirect" title="Simplified molecular-input line-entry system">SMILES</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.6em; word-wrap:break-word; text-indent:-1.5em; text-align:left; font-size:97%; line-height:120%;">O=[Re](=O)(=O)Cl</div></li></ul> </div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Properties </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></div> </td> <td><span title="Chlorine">Cl</span><span title="Oxygen">O</span><sub>3</sub><span title="Rhenium">Re</span> </td></tr> <tr> <td><a href="/wiki/Molar_mass" title="Molar mass">Molar mass</a> </td> <td><span class="nowrap"><span data-sort-value="7002269649999999999♠"></span>269.65</span>&#160;g·mol<sup>−1</sup> &#x20; </td></tr> <tr> <td>Appearance </td> <td>colorless liquid </td></tr> <tr> <td><a href="/wiki/Density" title="Density">Density</a> </td> <td>4.665 g/cm<sup>3</sup> (-100 °C) </td></tr> <tr> <td><a href="/wiki/Melting_point" title="Melting point">Melting point</a> </td> <td>4.5&#160;°C (40.1&#160;°F; 277.6&#160;K) </td></tr> <tr> <td><a href="/wiki/Boiling_point" title="Boiling point">Boiling point</a> </td> <td>113&#160;°C (235&#160;°F; 386&#160;K) </td></tr> <tr> <td colspan="2" style="text-align:left; background:#f8eaba; border:1px solid #a2a9b1;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Except where otherwise noted, data are given for materials in their <a href="/wiki/Standard_state" title="Standard state">standard state</a> (at 25&#160;°C [77&#160;°F], 100&#160;kPa).</div> <div style="margin-top: 0.3em;"></div> <div style="margin-top: 0.3em; text-align: center;"><a href="/wiki/Wikipedia:Chemical_infobox#References" title="Wikipedia:Chemical infobox">Infobox references</a></div> </td></tr> </tbody></table><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Chemical compound</div> <p><b>Rhenium trioxide chloride</b> is an <a href="/wiki/Inorganic_compound" title="Inorganic compound">inorganic compound</a> with the formula <style data-mw-deduplicate="TemplateStyles:r1123817410">.mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}</style><span class="chemf nowrap">ReO<sub class="template-chem2-sub">3</sub>Cl</span>. It is a colorless, distillable, diamagnetic liquid. It is a <a href="/wiki/Rhenium_oxychloride" title="Rhenium oxychloride">rhenium oxychloride</a>.<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> The material is used as a reagent in the preparation of rhenium compounds. </p> <div class="mw-heading mw-heading2"><h2 id="Synthesis_and_reactions">Synthesis and reactions</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Rhenium_trioxide_chloride&amp;action=edit&amp;section=1" title="Edit section: Synthesis and reactions"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Rhenium trioxide chloride can be prepared by <a href="/wiki/Chlorination_reaction" class="mw-redirect" title="Chlorination reaction">chlorination</a> of <a href="/wiki/Rhenium_trioxide" title="Rhenium trioxide">rhenium trioxide</a>:<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> </p> <dl><dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">2 ReO<sub class="template-chem2-sub">3</sub> + Cl<sub class="template-chem2-sub">2</sub> → 2 ReO<sub class="template-chem2-sub">3</sub>Cl</span></dd></dl> <p>With <a href="/wiki/Lewis_base" class="mw-redirect" title="Lewis base">Lewis bases</a> (L), rhenium trioxide chloride reacts to form adducts with the formula <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">ReO<sub class="template-chem2-sub">3</sub>ClL<sub class="template-chem2-sub">2</sub></span>.<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> </p><p>The compound hydrolyzes readily to give <a href="/wiki/Perrhenic_acid" title="Perrhenic acid">perrhenic acid</a>. </p> <div class="mw-heading mw-heading2"><h2 id="Structure">Structure</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Rhenium_trioxide_chloride&amp;action=edit&amp;section=2" title="Edit section: Structure"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The compound adopts a tetrahedral structure with Re-O and Re-Cl bond distances of 1.71 and 2.22 Å.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">&#91;</span>4<span class="cite-bracket">&#93;</span></a></sup> In contrast <a href="/wiki/Rhenium_trioxide_fluoride" title="Rhenium trioxide fluoride">rhenium trioxide fluoride</a> (<link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">ReO<sub class="template-chem2-sub">3</sub>F</span>) is polymeric with octahedral Re centers. </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Rhenium_trioxide_chloride&amp;action=edit&amp;section=3" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist"> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFGreenwoodEarnshaw1997" class="citation book cs1"><a href="/wiki/Norman_Greenwood" title="Norman Greenwood">Greenwood, Norman N.</a>; Earnshaw, Alan (1997). <i>Chemistry of the Elements</i> (2nd&#160;ed.). <a href="/wiki/Butterworth-Heinemann" title="Butterworth-Heinemann">Butterworth-Heinemann</a>. p.&#160;1052. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/978-0-08-037941-8" title="Special:BookSources/978-0-08-037941-8"><bdi>978-0-08-037941-8</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Chemistry+of+the+Elements&amp;rft.pages=1052&amp;rft.edition=2nd&amp;rft.pub=Butterworth-Heinemann&amp;rft.date=1997&amp;rft.isbn=978-0-08-037941-8&amp;rft.aulast=Greenwood&amp;rft.aufirst=Norman+N.&amp;rft.au=Earnshaw%2C+Alan&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ARhenium+trioxide+chloride" class="Z3988"></span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFO._GlemserR._Sauer1963" class="citation book cs1 cs1-prop-long-vol">O. Glemser; R. Sauer (1963). "Rhenium (VII) Oxychloride". In G. Brauer (ed.). <i>Handbook of Preparative Inorganic Chemistry, 2nd Ed</i>. Vol.&#160;2pages=1480. NY, NY: Academic Press.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=bookitem&amp;rft.atitle=Rhenium+%28VII%29+Oxychloride&amp;rft.btitle=Handbook+of+Preparative+Inorganic+Chemistry%2C+2nd+Ed.&amp;rft.place=NY%2C+NY&amp;rft.pub=Academic+Press&amp;rft.date=1963&amp;rft.au=O.+Glemser&amp;rft.au=R.+Sauer&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ARhenium+trioxide+chloride" class="Z3988"></span></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFNohGirolami2007" class="citation journal cs1">Noh, Wontae; Girolami, Gregory S. (2007). "Rhenium Oxohalides: Synthesis and Crystal Structures of ReO<sub>3</sub>Cl(THF)<sub>2</sub>, ReOCl<sub>4</sub>(THF), Re<sub>2</sub>O<sub>3</sub>Cl<sub>6</sub>(THF)<sub>2</sub>, and Re<sub>2</sub>O<sub>3</sub>Cl<sub>6</sub>(H<sub>2</sub>O)<sub>2</sub>". <i>Dalton Transactions</i> (6): 674–679. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1039%2Fb616495a">10.1039/b616495a</a>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a>&#160;<a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/17268601">17268601</a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rft.genre=article&amp;rft.jtitle=Dalton+Transactions&amp;rft.atitle=Rhenium+Oxohalides%3A+Synthesis+and+Crystal+Structures+of+ReO%3Csub%3E3%3C%2Fsub%3ECl%28THF%29%3Csub%3E2%3C%2Fsub%3E%2C+ReOCl%3Csub%3E4%3C%2Fsub%3E%28THF%29%2C+Re%3Csub%3E2%3C%2Fsub%3EO%3Csub%3E3%3C%2Fsub%3ECl%3Csub%3E6%3C%2Fsub%3E%28THF%29%3Csub%3E2%3C%2Fsub%3E%2C+and+Re%3Csub%3E2%3C%2Fsub%3EO%3Csub%3E3%3C%2Fsub%3ECl%3Csub%3E6%3C%2Fsub%3E%28H%3Csub%3E2%3C%2Fsub%3EO%29%3Csub%3E2%3C%2Fsub%3E&amp;rft.issue=6&amp;rft.pages=674-679&amp;rft.date=2007&amp;rft_id=info%3Adoi%2F10.1039%2Fb616495a&amp;rft_id=info%3Apmid%2F17268601&amp;rft.aulast=Noh&amp;rft.aufirst=Wontae&amp;rft.au=Girolami%2C+Gregory+S.&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ARhenium+trioxide+chloride" class="Z3988"></span></span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-4">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFSpandlSupełDrewsSeppelt2006" class="citation journal cs1">Spandl, Johann; Supeł, Joanna; Drews, Thomas; Seppelt, Konrad (2006). "MnO<sub>3</sub>Cl, Isolation and Crystal Structure". <i>Zeitschrift für Anorganische und Allgemeine Chemie</i>. <b>632</b> (14): 2222–2225. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1002%2Fzaac.200600186">10.1002/zaac.200600186</a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rft.genre=article&amp;rft.jtitle=Zeitschrift+f%C3%BCr+Anorganische+und+Allgemeine+Chemie&amp;rft.atitle=MnO%3Csub%3E3%3C%2Fsub%3ECl%2C+Isolation+and+Crystal+Structure&amp;rft.volume=632&amp;rft.issue=14&amp;rft.pages=2222-2225&amp;rft.date=2006&amp;rft_id=info%3Adoi%2F10.1002%2Fzaac.200600186&amp;rft.aulast=Spandl&amp;rft.aufirst=Johann&amp;rft.au=Supe%C5%82%2C+Joanna&amp;rft.au=Drews%2C+Thomas&amp;rft.au=Seppelt%2C+Konrad&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ARhenium+trioxide+chloride" class="Z3988"></span></span> </li> </ol></div></div> <!-- NewPP limit report Parsed by mw‐api‐ext.eqiad.main‐6696b4cc84‐pvscd Cached time: 20241124025608 Cache expiry: 2592000 Reduced expiry: false Complications: [vary‐revision‐sha1] CPU time usage: 0.360 seconds Real time usage: 1.279 seconds Preprocessor visited node count: 5729/1000000 Post‐expand include size: 47260/2097152 bytes Template argument size: 9781/2097152 bytes Highest expansion depth: 23/100 Expensive parser function count: 2/500 Unstrip recursion depth: 1/20 Unstrip post‐expand size: 17903/5000000 bytes Lua time usage: 0.170/10.000 seconds Lua memory usage: 6360784/52428800 bytes Number of Wikibase entities loaded: 1/400 --> <!-- Transclusion expansion time report (%,ms,calls,template) 100.00% 1003.462 1 -total 85.06% 853.549 1 Template:Chembox 39.82% 399.550 1 Template:Chembox_Identifiers 24.59% 246.785 1 Template:Chembox_Properties 20.41% 204.777 14 Template:Unbulleted_list 14.93% 149.838 11 Template:Trim 14.89% 149.438 3 Template:Chembox_headerbar 13.95% 139.999 1 Template:Chembox_Elements 11.73% 117.664 12 Template:Main_other 9.98% 100.140 1 Template:Reflist --> <!-- Saved in parser cache with key enwiki:pcache:idhash:74066408-0!canonical and timestamp 20241124025608 and revision id 1192199824. 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