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id="bodyContent" class="vector-body"> <div id="siteSub" class="noprint">aus Wikipedia, der freien Enzyklopädie</div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="contentSub2"></div> <div id="jump-to-nav"></div> <a class="mw-jump-link" href="#mw-head">Zur Navigation springen</a> <a class="mw-jump-link" href="#searchInput">Zur Suche springen</a> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="de" dir="ltr"><p>Die <b>Bindungslänge</b> ist laut <a href="/wiki/International_Union_of_Pure_and_Applied_Chemistry" title="International Union of Pure and Applied Chemistry">IUPAC</a>-Definition der Abstand zwischen zwei Atomzentren innerhalb einer <a href="/wiki/Chemische_Bindung" title="Chemische Bindung">chemischen Bindung</a>.<sup id="cite_ref-:0_1-0" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> Der Begriff der Bindungslänge wird im Rahmen verschiedener experimenteller Methoden unterschiedlich definiert, wodurch sich Abweichungen ergeben, die im Allgemeinen aber gering sind.<sup id="cite_ref-:0_1-1" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Chemie">Chemie</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Bindungsl%C3%A4nge&veaction=edit&section=1" title="Abschnitt bearbeiten: Chemie" class="mw-editsection-visualeditor"><span>Bearbeiten</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Bindungsl%C3%A4nge&action=edit&section=1" title="Quellcode des Abschnitts bearbeiten: Chemie"><span>Quelltext bearbeiten</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Bei <a href="/wiki/Kristallstruktur" title="Kristallstruktur">kristallinen</a> Festkörpern mit <a href="/wiki/Ionengitter" title="Ionengitter">Ionen-</a> oder <a href="/wiki/Metallgitter" class="mw-redirect" title="Metallgitter">Metallgitter</a> lassen sich die Abstände der Gitterbausteine durch <a href="/wiki/R%C3%B6ntgenbeugung" title="Röntgenbeugung">Röntgen-</a> oder <a href="/wiki/Elektronenbeugung" title="Elektronenbeugung">Elektronenbeugung</a> ermitteln. Da in Kristallgittern unterschiedliche Abstände der Netzebenen gemessen werden können, wird in Tabellen in der Regel der kleinste Abstand als Bindungslänge angegeben. </p><p>Im <a href="/wiki/Calciumfluorid" title="Calciumfluorid">Calciumfluorid</a> beträgt der Abstand zwischen den Calciumkationen Ca<sup>2+</sup> und den Fluorid-Anionen F<sup>−</sup> 235 <a href="/wiki/Pikometer" class="mw-redirect" title="Pikometer">pm</a> (1 pm = 10<sup>−12</sup> m). In Metallgittern beträgt der Abstand je nach Atomgröße zwischen 200 pm und 500 pm. </p><p>Für eine <a href="/wiki/Kohlenstoff" title="Kohlenstoff">Kohlenstoff</a>-Kohlenstoff-Bindung (einfach) beträgt dieser Abstand ca. 154 pm. Für Bindungslängen von <a href="/wiki/Kovalente_Bindung" title="Kovalente Bindung">kovalenten Bindungen</a> siehe <a href="/wiki/Kovalente_Bindung#Bindungslänge" title="Kovalente Bindung">hier</a>. <a href="/wiki/Wasserstoffbr%C3%BCckenbindung" title="Wasserstoffbrückenbindung">Wasserstoffbrückenbindungen</a> weisen je nach Polarisierungsgrad Abstände zwischen 120 pm und 300 pm auf. </p> <dl><dd><table class="wikitable centered" style="text-align:center"> <caption>Bindungslängen in organischen Verbindungen<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </caption> <tbody><tr> <th class="hintergrundfarbe6">C–H</th> <th class="hintergrundfarbe6">Länge in pm</th> <th></th> <th class="hintergrundfarbe6">C–C</th> <th class="hintergrundfarbe6">Länge in pm</th> <th></th> <th class="hintergrundfarbe6">Mehrfachbindungen</th> <th class="hintergrundfarbe6">Länge in pm </th></tr> <tr> <td>sp<sup>3</sup>–H</td> <td>110</td> <td></td> <td>sp<sup>3</sup>–sp<sup>3</sup></td> <td>154</td> <td></td> <td><a href="/wiki/Benzol" title="Benzol">Benzol</a></td> <td>140 </td></tr> <tr> <td>sp<sup>2</sup>–H</td> <td>109</td> <td></td> <td>sp<sup>3</sup>–sp<sup>2</sup></td> <td>150</td> <td></td> <td><a href="/wiki/Alkene" title="Alkene">Alken</a> (C=C)</td> <td>134 </td></tr> <tr> <td>sp–H</td> <td>108</td> <td></td> <td>sp<sup>2</sup>–sp<sup>2</sup></td> <td>147</td> <td></td> <td><a href="/wiki/Alkin" class="mw-redirect" title="Alkin">Alkin</a> (C≡C)</td> <td>120 </td></tr> <tr> <td></td> <td></td> <td></td> <td>sp<sup>3</sup>–sp</td> <td>146</td> <td></td> <td></td> <td> </td></tr> <tr> <td></td> <td></td> <td></td> <td>sp<sup>2</sup>–sp</td> <td>143</td> <td></td> <td></td> <td> </td></tr> <tr> <td></td> <td></td> <td></td> <td>sp–sp</td> <td>137</td> <td></td> <td></td> <td> </td></tr></tbody></table></dd></dl> <div class="mw-heading mw-heading3"><h3 id="Weitere_Bindungslängen_kovalenter_Bindungen"><span id="Weitere_Bindungsl.C3.A4ngen_kovalenter_Bindungen"></span>Weitere Bindungslängen kovalenter Bindungen</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Bindungsl%C3%A4nge&veaction=edit&section=2" title="Abschnitt bearbeiten: Weitere Bindungslängen kovalenter Bindungen" class="mw-editsection-visualeditor"><span>Bearbeiten</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Bindungsl%C3%A4nge&action=edit&section=2" title="Quellcode des Abschnitts bearbeiten: Weitere Bindungslängen kovalenter Bindungen"><span>Quelltext bearbeiten</span></a><span class="mw-editsection-bracket">]</span></span></div> <dl><dd><table class="wikitable centered" style="text-align:center"> <tbody><tr class="hintergrundfarbe6"> <th>Bindung</th> <th>Bindungslänge in pm </th></tr> <tr> <td>H-H</td> <td>74 </td></tr> <tr> <td>F-F</td> <td>142 </td></tr> <tr> <td>Cl-Cl</td> <td>199 </td></tr> <tr> <td>Br-Br</td> <td>228 </td></tr> <tr> <td>I-I</td> <td>267 </td></tr> <tr> <td>O=O</td> <td>121 </td></tr> <tr> <td>N≡N</td> <td>110 </td></tr> <tr> <td>N-H</td> <td>101 </td></tr> <tr> <td>O-H</td> <td>96 </td></tr> <tr> <td>F-H</td> <td>92 </td></tr> <tr> <td>Cl-H</td> <td>127 </td></tr> <tr> <td>Br-H</td> <td>141 </td></tr> <tr> <td>I-H</td> <td>161 </td></tr> <tr> <td>C-O</td> <td>143 </td></tr> <tr> <td>C=O</td> <td>120 </td></tr> <tr> <td>C-N</td> <td>147 </td></tr> <tr> <td>C(sp)-Li</td> <td>188 - 193<sup id="cite_ref-ac_6-0" class="reference"><a href="#cite_note-ac-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>C(sp)-Na</td> <td>222<sup id="cite_ref-ac_6-1" class="reference"><a href="#cite_note-ac-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>C(sp)-K</td> <td>254<sup id="cite_ref-ac_6-2" class="reference"><a href="#cite_note-ac-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </td></tr></tbody></table></dd></dl> <div class="mw-heading mw-heading2"><h2 id="Einzelnachweise">Einzelnachweise</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Bindungsl%C3%A4nge&veaction=edit&section=3" title="Abschnitt bearbeiten: Einzelnachweise" class="mw-editsection-visualeditor"><span>Bearbeiten</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Bindungsl%C3%A4nge&action=edit&section=3" title="Quellcode des Abschnitts bearbeiten: Einzelnachweise"><span>Quelltext bearbeiten</span></a><span class="mw-editsection-bracket">]</span></span></div> <ol class="references"> <li id="cite_note-:0-1"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-:0_1-0">a</a></sup> <sup><a href="#cite_ref-:0_1-1">b</a></sup></span> <span class="reference-text"><span class="cite">International Union of Pure and Applied Chemistry: <a rel="nofollow" class="external text" href="https://goldbook.iupac.org/html/B/BT07003.html"><i>IUPAC Gold Book - bond length.</i></a><span class="Abrufdatum"> Abgerufen am 20. Januar 2019</span> (englisch).</span><span style="display: none;" class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rfr_id=info%3Asid%2Fde.wikipedia.org%3ABindungsl%C3%A4nge&rft.title=IUPAC+Gold+Book+-+bond+length&rft.description=IUPAC+Gold+Book+-+bond+length&rft.identifier=https%3A%2F%2Fgoldbook.iupac.org%2Fhtml%2FB%2FBT07003.html&rft.creator=International+Union+of+Pure+and+Applied+Chemistry&rft.language=en"> </span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><a href="#cite_ref-2">↑</a></span> <span class="reference-text">Norman L. Allinger: <cite style="font-style:italic">Molecular Structure</cite>. Wiley, 2010, <a href="/wiki/Spezial:ISBN-Suche/9780470195574" class="internal mw-magiclink-isbn">ISBN 978-0-470-19557-4</a>, <a href="/wiki/Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1002/9780470608852">10.1002/9780470608852</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rfr_id=info:sid/de.wikipedia.org:Bindungsl%C3%A4nge&rft.au=Norman+L.+Allinger&rft.btitle=Molecular+Structure&rft.date=2010-07-19&rft.doi=10.1002%2F9780470608852&rft.genre=book&rft.isbn=9780470195574&rft.pub=Wiley" style="display:none"> </span></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><a href="#cite_ref-3">↑</a></span> <span class="reference-text">Marye A. Fox, James K. Whitesell: <cite style="font-style:italic">Organische Chemie</cite>. Spektrum Akademischer Verlag, 1995, <a href="/wiki/Spezial:ISBN-Suche/3860252496" class="internal mw-magiclink-isbn">ISBN 3-86025-249-6</a>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rfr_id=info:sid/de.wikipedia.org:Bindungsl%C3%A4nge&rft.au=Marye+A.+Fox%2C+James+K.+Whitesell&rft.btitle=Organische+Chemie&rft.date=1995&rft.genre=book&rft.isbn=3860252496&rft.pub=Spektrum+Akademischer+Verlag" style="display:none"> </span></span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><a href="#cite_ref-4">↑</a></span> <span class="reference-text">Frank H. Allen, Olga Kennard, David G. Watson, Lee Brammer, A. Guy Orpen: <cite style="font-style:italic">Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds</cite>. In: <cite style="font-style:italic">Journal of the Chemical Society, Perkin Transactions 2</cite>. <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em"> </span>12</span>, 1987, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>S1</span>, <a href="/wiki/Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1039/p298700000s1">10.1039/p298700000s1</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rfr_id=info:sid/de.wikipedia.org:Bindungsl%C3%A4nge&rft.atitle=Tables+of+bond+lengths+determined+by+X-ray+and+neutron+diffraction.+Part+1.+Bond+lengths+in+organic+compounds&rft.au=Frank+H.+Allen%2C+Olga+Kennard%2C+David+G.+Watson%2C+...&rft.date=1987&rft.doi=10.1039%2Fp298700000s1&rft.genre=journal&rft.issue=12&rft.jtitle=Journal+of+the+Chemical+Society%2C+Perkin+Transactions+2&rft.pages=S1" style="display:none"> </span></span> </li> <li id="cite_note-5"><span class="mw-cite-backlink"><a href="#cite_ref-5">↑</a></span> <span class="reference-text">A. Guy Orpen, Lee Brammer, Frank H. Allen, Olga Kennard, David G. Watson: <cite style="font-style:italic">Supplement. Tables of bond lengths determined by X-ray and neutron diffraction. Part 2. Organometallic compounds and co-ordination complexes of the d- and f-block metals</cite>. In: <cite style="font-style:italic">Journal of the Chemical Society, Dalton Transactions</cite>. <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em"> </span>12</span>, 1989, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>S1</span>, <a href="/wiki/Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1039/dt98900000s1">10.1039/dt98900000s1</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rfr_id=info:sid/de.wikipedia.org:Bindungsl%C3%A4nge&rft.atitle=Supplement.+Tables+of+bond+lengths+determined+by+X-ray+and+neutron+diffraction.+Part+2.+Organometallic+compounds+and+co-ordination+complexes+of+the+d-+and+f-block+metals&rft.au=A.+Guy+Orpen%2C+Lee+Brammer%2C+Frank+H.+Allen%2C+...&rft.date=1989&rft.doi=10.1039%2Fdt98900000s1&rft.genre=journal&rft.issue=12&rft.jtitle=Journal+of+the+Chemical+Society%2C+Dalton+Transactions&rft.pages=S1" style="display:none"> </span></span> </li> <li id="cite_note-ac-6"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-ac_6-0">a</a></sup> <sup><a href="#cite_ref-ac_6-1">b</a></sup> <sup><a href="#cite_ref-ac_6-2">c</a></sup></span> <span class="reference-text"> Grotjahn D. B.; Apponi, A.J.; Brewster, M.A.; Ju Xin; Ziurys L.M. <i>Angew. Chem.</i> <b>1998</b>, <i>110(19)</i>, 2824-2827.</span> </li> </ol></div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">Abgerufen von „<a dir="ltr" href="https://de.wikipedia.org/w/index.php?title=Bindungslänge&oldid=248154842">https://de.wikipedia.org/w/index.php?title=Bindungslänge&oldid=248154842</a>“</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Wikipedia:Kategorien" title="Wikipedia:Kategorien">Kategorie</a>: <ul><li><a href="/wiki/Kategorie:Chemische_Bindung" title="Kategorie:Chemische Bindung">Chemische Bindung</a></li></ul></div></div> </div> </div> <div id="mw-navigation"> <h2>Navigationsmenü</h2> <div id="mw-head"> <nav id="p-personal" class="mw-portlet mw-portlet-personal vector-user-menu-legacy vector-menu" aria-labelledby="p-personal-label" > <h3 id="p-personal-label" class="vector-menu-heading " > <span class="vector-menu-heading-label">Meine Werkzeuge</span> </h3> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="pt-anonuserpage" class="mw-list-item"><span title="Benutzerseite der IP-Adresse, von der aus du Änderungen durchführst">Nicht angemeldet</span></li><li id="pt-anontalk" class="mw-list-item"><a href="/wiki/Spezial:Meine_Diskussionsseite" title="Diskussion über Änderungen von dieser IP-Adresse [n]" accesskey="n"><span>Diskussionsseite</span></a></li><li id="pt-anoncontribs" class="mw-list-item"><a href="/wiki/Spezial:Meine_Beitr%C3%A4ge" title="Eine Liste der Bearbeitungen, die von dieser IP-Adresse gemacht wurden [y]" accesskey="y"><span>Beiträge</span></a></li><li id="pt-createaccount" class="mw-list-item"><a href="/w/index.php?title=Spezial:Benutzerkonto_anlegen&returnto=Bindungsl%C3%A4nge" title="Wir ermutigen dich dazu, ein Benutzerkonto zu erstellen und dich anzumelden. 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interwiki-sk mw-list-item"><a href="https://sk.wikipedia.org/wiki/D%C4%BA%C5%BEka_v%C3%A4zby" title="Dĺžka väzby – Slowakisch" lang="sk" hreflang="sk" data-title="Dĺžka väzby" data-language-autonym="Slovenčina" data-language-local-name="Slowakisch" class="interlanguage-link-target"><span>Slovenčina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Du%C5%BEina_hemijske_veze" title="Dužina hemijske veze – Serbisch" lang="sr" hreflang="sr" data-title="Dužina hemijske veze" data-language-autonym="Српски / srpski" data-language-local-name="Serbisch" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-th mw-list-item"><a href="https://th.wikipedia.org/wiki/%E0%B8%84%E0%B8%A7%E0%B8%B2%E0%B8%A1%E0%B8%A2%E0%B8%B2%E0%B8%A7%E0%B8%9E%E0%B8%B1%E0%B8%99%E0%B8%98%E0%B8%B0" title="ความยาวพันธะ – Thailändisch" lang="th" hreflang="th" data-title="ความยาวพันธะ" data-language-autonym="ไทย" data-language-local-name="Thailändisch" class="interlanguage-link-target"><span>ไทย</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Ba%C4%9F_uzunlu%C4%9Fu" title="Bağ uzunluğu – Türkisch" lang="tr" hreflang="tr" data-title="Bağ uzunluğu" data-language-autonym="Türkçe" data-language-local-name="Türkisch" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%94%D0%BE%D0%B2%D0%B6%D0%B8%D0%BD%D0%B0_%D1%85%D1%96%D0%BC%D1%96%D1%87%D0%BD%D0%BE%D0%B3%D0%BE_%D0%B7%D0%B2%27%D1%8F%D0%B7%D0%BA%D1%83" title="Довжина хімічного зв'язку – Ukrainisch" lang="uk" hreflang="uk" data-title="Довжина хімічного зв'язку" data-language-autonym="Українська" data-language-local-name="Ukrainisch" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-zh 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