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eutectic</title> <meta name="description" content="Search results for: eutectic"> <meta name="keywords" content="eutectic"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none navbar-toggler ml-auto" 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id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="eutectic"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 83</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: eutectic</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">83</span> Damage Strain Analysis of Parallel Fiber Eutectic</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jian%20Zheng">Jian Zheng</a>, <a href="https://publications.waset.org/abstracts/search?q=Xinhua%20Ni"> Xinhua Ni</a>, <a href="https://publications.waset.org/abstracts/search?q=Xiequan%20Liu"> Xiequan Liu</a> </p> <p class="card-text"><strong>Abstract:</strong></p> According to isotropy of parallel fiber eutectic, the no- damage strain field in parallel fiber eutectic is obtained from the flexibility tensor of parallel fiber eutectic. Considering the damage behavior of parallel fiber eutectic, damage variables are introduced to determine the strain field of parallel fiber eutectic. The damage strains in the matrix, interphase, and fiber of parallel fiber eutectic are quantitatively analyzed. Results show that damage strains are not only associated with the fiber volume fraction of parallel fiber eutectic, but also with the damage degree. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=damage%20strain" title="damage strain">damage strain</a>, <a href="https://publications.waset.org/abstracts/search?q=initial%20strain" title=" initial strain"> initial strain</a>, <a href="https://publications.waset.org/abstracts/search?q=fiber%20volume%20fraction" title=" fiber volume fraction"> fiber volume fraction</a>, <a href="https://publications.waset.org/abstracts/search?q=parallel%20fiber%20eutectic" title=" parallel fiber eutectic"> parallel fiber eutectic</a> </p> <a href="https://publications.waset.org/abstracts/60032/damage-strain-analysis-of-parallel-fiber-eutectic" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/60032.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">578</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">82</span> Limiting Fracture Stress of Composite Ceramics with Symmetric Triangle Eutectic</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jian%20Zheng">Jian Zheng</a>, <a href="https://publications.waset.org/abstracts/search?q=Jinfeng%20Yu"> Jinfeng Yu</a>, <a href="https://publications.waset.org/abstracts/search?q=Xinhua%20Ni"> Xinhua Ni</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The limiting fracture stress predicting model of composite ceramics with symmetric triangle eutectic was established based on its special microscopic structure. The symmetric triangle eutectic is consisted of matrix, the strong constraint inter-phase and reinforced fiber inclusions which are 120 degrees uniform symmetrical distribution. Considering the conditions of the rupture of the cohesive bond between matrix and fibers in eutectic and the stress concentration effect at the fiber end, the intrinsic fracture stress of eutectic was obtained. Based on the biggest micro-damage strain in eutectic, defining the load function, the macro-damage fracture stress of symmetric triangle eutectic was determined by boundary conditions. Introducing the conception of critical zone, the theoretical limiting fracture stress forecasting model of composite ceramics was got, and the stress was related to the fiber size and fiber volume fraction in eutectic. The calculated results agreed with the experimental results in the literature. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=symmetric%20triangle%20eutectic" title="symmetric triangle eutectic">symmetric triangle eutectic</a>, <a href="https://publications.waset.org/abstracts/search?q=composite%20ceramics" title=" composite ceramics"> composite ceramics</a>, <a href="https://publications.waset.org/abstracts/search?q=limiting%20stress" title=" limiting stress"> limiting stress</a>, <a href="https://publications.waset.org/abstracts/search?q=intrinsic%20fracture%20stress" title=" intrinsic fracture stress"> intrinsic fracture stress</a> </p> <a href="https://publications.waset.org/abstracts/72473/limiting-fracture-stress-of-composite-ceramics-with-symmetric-triangle-eutectic" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/72473.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">258</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">81</span> Effect of Y Addition on the Microstructure and Mechanical Properties of Sn-Zn Eutectic Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jung-Ho%20Moon">Jung-Ho Moon</a>, <a href="https://publications.waset.org/abstracts/search?q=Tae%20Kwon%20Ha"> Tae Kwon Ha</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The effect of Yttrium addition on the microstructure and mechanical properties of Sn-Zn eutectic alloy, which has been attracting intensive focus as a Pb-free solder material, was investigated in this study. Phase equilibrium has been calculated by using FactSage® to evaluate the composition and fraction of equilibrium intermetallic compounds and construct a phase diagram. In the case of Sn-8.8 Zn eutectic alloy, the as-cast microstructure was typical lamellar. With addition of 0.25 wt. %Y, a large amount of pro-eutectic phases have been observed and various YZnx intermetallic compounds were expected to successively form during cooling. Hardness of Sn-8.8 Zn alloy was not affected by Y-addition and both alloys could be rolled by 90% at room temperature. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sn-Zn%20eutectic%20alloy" title="Sn-Zn eutectic alloy">Sn-Zn eutectic alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=yttrium" title=" yttrium"> yttrium</a>, <a href="https://publications.waset.org/abstracts/search?q=FactSage%C2%AE" title=" FactSage®"> FactSage®</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=mechanical%20properties" title=" mechanical properties"> mechanical properties</a> </p> <a href="https://publications.waset.org/abstracts/7127/effect-of-y-addition-on-the-microstructure-and-mechanical-properties-of-sn-zn-eutectic-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/7127.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">470</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">80</span> Microstructural Characterization and Mechanical Properties of Al-2Mn-5Fe Ternary Eutectic Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Emin%20%C3%87adirli">Emin Çadirli</a>, <a href="https://publications.waset.org/abstracts/search?q=Izzettin%20Yilmazer"> Izzettin Yilmazer</a>, <a href="https://publications.waset.org/abstracts/search?q=U%C4%9Fur%20B%C3%BCy%C3%BCk"> Uğur Büyük</a>, <a href="https://publications.waset.org/abstracts/search?q=Hasan%20Kaya"> Hasan Kaya</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Al-2Mn-5Fe eutectic alloy (wt.%) was prepared in a graphite crucible under vacuum atmosphere. The samples were directionally solidified upward at a constant temperature gradient in four different of growth rates by using a Bridgman method. The values of eutectic spacing were measured from longitudinal and transverse sections of the samples. The dependence of eutectic spacing on the growth rate was determined by using linear regression analysis. The microhardness and tensile strength of the studied alloy also were measured from directionally solidified samples. The dependency of the microhardness and tensile strength for directionally solidified Al-2Mn-5Fe eutectic alloy on the growth rate were investigated and the relationships between them were experimentally obtained by using regression analysis. The results obtained in present work were compared with the previous similar experimental results obtained for binary and ternary alloys. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=eutectic%20alloy" title="eutectic alloy">eutectic alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=microhardness" title=" microhardness"> microhardness</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=tensile%20strength" title=" tensile strength"> tensile strength</a> </p> <a href="https://publications.waset.org/abstracts/27071/microstructural-characterization-and-mechanical-properties-of-al-2mn-5fe-ternary-eutectic-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/27071.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">473</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">79</span> The Effects of Microstructure of Directionally Solidified Al-Si-Fe Alloys on Micro Hardness, Tensile Strength, and Electrical Resistivity</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sevda%20Engin">Sevda Engin</a>, <a href="https://publications.waset.org/abstracts/search?q=Ugur%20Buyuk"> Ugur Buyuk</a>, <a href="https://publications.waset.org/abstracts/search?q=Necmettin%20Marasli"> Necmettin Marasli</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Directional solidification of eutectic alloys attracts considerable attention because of microhardness, tensile strength, and electrical resistivity influenced by eutectic structures. In this research, we examined processing of Al–Si–Fe (Al–11.7wt.%Si–1wt.%Fe) eutectic by directional solidification. The alloy was prepared by vacuum furnace and directionally solidified in Bridgman-type equipment. During the directional solidification process, the growth rates utilized varied from 8.25 m/s to 164.80 m/s. The Al–Si–Fe system showed an eutectic transformation, which resulted in the matrix Al, Si and Al5SiFe plate phases. The eutectic spacing between (λ_Si-λ_Si, λ_(Al_5 SiFe)-λ_(Al_5 SiFe)) was measured. Additionally, the microhardness, tensile strength, and electrical resistivity of the alloy were determined using directionally solidified samples. The effects of growth rates on microhardness, tensile strength, and electrical resistivity for directionally solidified Al–Si–Fe eutectic alloy were investigated, and the relationships between them were experimentally obtained. It was found that the microhardness, tensile strength, and electrical resistivity were affected by both eutectic spacing and the solidification parameter. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=directional%20solidification" title="directional solidification">directional solidification</a>, <a href="https://publications.waset.org/abstracts/search?q=aluminum%20alloy" title=" aluminum alloy"> aluminum alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=electrical%20properties" title=" electrical properties"> electrical properties</a>, <a href="https://publications.waset.org/abstracts/search?q=tensile%20test" title=" tensile test"> tensile test</a>, <a href="https://publications.waset.org/abstracts/search?q=hardness%20test" title=" hardness test"> hardness test</a> </p> <a href="https://publications.waset.org/abstracts/45109/the-effects-of-microstructure-of-directionally-solidified-al-si-fe-alloys-on-micro-hardness-tensile-strength-and-electrical-resistivity" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/45109.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">295</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">78</span> Effect of Modifiers (Sr/Sb) and Heat Treatment on the Microstructures and Wear Properties of Al-11Si-3Cu-0.5Mg Alloys</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sheng-Long%20Lee">Sheng-Long Lee</a>, <a href="https://publications.waset.org/abstracts/search?q=Tse-An%20Pan"> Tse-An Pan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, an optical microscope (OM), electron microscope (SEM), electrical conductivity meter (% IACS), hardness test, and wear test were subjected to analyze the microstructure of the wrought Al-11Si-3Cu-0.5Mg alloys. The effect of eutectic silicon morphology and alloy hardness on wear properties was investigated. The results showed that in the cast state, the morphology of eutectic silicon modified by strontium and antimony is lamellar and finer fibrous structure. After homogenization, the eutectic Si modified by Sr coarsened, and the eutectic Si modified by Sb refined due to fragmentation. The addition of modifiers, hot rolling, and solution aging treatment can control eutectic silicon morphology and hardness. The finer eutectic silicon and higher hardness have better wear resistance. During the wearing process, a protective oxide layer, also known as Mechanical Mixed Layer (MML), is formed on the surface of the alloy. The MML has higher stability and cracking resistance in Sr-modified alloys than in Sb-modified alloys. The study found that the wearing behavior of Al-11Si-3Cu-0.5Mg alloy was enhanced by the combination of adding Sr with lower solution time and T6 peak aging. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Al-Si-Cu-Mg%20alloy" title="Al-Si-Cu-Mg alloy">Al-Si-Cu-Mg alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic%20silicon" title=" eutectic silicon"> eutectic silicon</a>, <a href="https://publications.waset.org/abstracts/search?q=heat%20treatment" title=" heat treatment"> heat treatment</a>, <a href="https://publications.waset.org/abstracts/search?q=wear%20property" title=" wear property"> wear property</a> </p> <a href="https://publications.waset.org/abstracts/162288/effect-of-modifiers-srsb-and-heat-treatment-on-the-microstructures-and-wear-properties-of-al-11si-3cu-05mg-alloys" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/162288.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">79</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">77</span> Directional Solidification of Al–Cu–Mg Eutectic Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yusuf%20Kayg%C4%B1s%C4%B1z">Yusuf Kaygısız</a>, <a href="https://publications.waset.org/abstracts/search?q=Necmetti%CC%87n%20Mara%C5%9Fl%C4%B1"> Necmetti̇n Maraşlı</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Aluminum alloys are produced and used at various areas of industry and especially in the aerospace industry. The advantages of these alloys over traditional iron-based alloys are lightweight, corrosion resistance, and very good thermal and electrical conductivity. The aim of this work is to experimentally investigate the effect of growth rates on the eutectic spacings (λ), microhardness, tensile strength and electrical resistivity in Al–30wt.%Cu–6wt.%Mg eutectic alloy. Al–Cu–Mg eutectic alloy was directionally solidified at a constant temperature gradient (G=8.55 K/mm) with different growth rates, 9.43 to 173.3 µm/s by using a Bridgman-type furnace. The dependency of microstructure, microhardness, tensile strength and electrical resistivity for directionally solidified the Al-Cu-Mg eutectic alloy were investigated. Eutectic microstructure is consisting of regular Al2CuMg lamellar and Al2Cu rod phases with in the α (Al) solid solution matrix. The lamellar eutectic spacings were measured from transverse sections of the samples. It was found that the value of microstructures decrease with the increase the value the growth rates. The microhardness, tensile strength and electrical resistivity of the alloy also were measured from sample and relationships between them were experimentally analyzed by using regression analysis. According to present results, values tensile strength and electrical resistivity increase with increasing growth rates. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=directional%20solidification" title="directional solidification">directional solidification</a>, <a href="https://publications.waset.org/abstracts/search?q=aluminum%20alloys" title=" aluminum alloys"> aluminum alloys</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=electrical%20properties" title=" electrical properties"> electrical properties</a>, <a href="https://publications.waset.org/abstracts/search?q=hardness%20test" title=" hardness test"> hardness test</a> </p> <a href="https://publications.waset.org/abstracts/46600/directional-solidification-of-al-cu-mg-eutectic-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/46600.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">294</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">76</span> Development of High Temperature Eutectic Oxide Ceramic Matrix Composites</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ya%C4%9Fmur%20Can%20G%C3%BCndo%C4%9Fan">Yağmur Can Gündoğan</a>, <a href="https://publications.waset.org/abstracts/search?q=K%C3%BCbra%20G%C3%BCrcan%20Bayrak"> Kübra Gürcan Bayrak</a>, <a href="https://publications.waset.org/abstracts/search?q=Ece%20%C3%96zerdem"> Ece Özerdem</a>, <a href="https://publications.waset.org/abstracts/search?q=Buse%20Katipo%C4%9Flu"> Buse Katipoğlu</a>, <a href="https://publications.waset.org/abstracts/search?q=Erhan%20Ayas"> Erhan Ayas</a>, <a href="https://publications.waset.org/abstracts/search?q=Rifat%20Y%C4%B1lmaz"> Rifat Yılmaz</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Eutectic oxide based ceramic matrix composites have a unique microstructure that does not include grain boundary in the form of a continuous network. Because of this, these materials have the properties of perfect high-temperature strength, creep strength, and high oxidation strength. Mechanical properties of them are much related to occurring solidification structures during eutectic reactions. One of the most important production methods of this kind of material is the process of vacuum arc melting. Within scope of this studying, it is aimed to investigate the production of Al₂O₃-YAG-based eutectic ceramics by Arc melting and Spark Plasma Sintering methods for use in aerospace and defense industries where high-temperature environments play an important role and to examine the effects of ZrO₂ and LiF additions on microstructure development and mechanical properties. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=alumina" title="alumina">alumina</a>, <a href="https://publications.waset.org/abstracts/search?q=composites" title=" composites"> composites</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic" title=" eutectic"> eutectic</a>, <a href="https://publications.waset.org/abstracts/search?q=YAG" title=" YAG"> YAG</a> </p> <a href="https://publications.waset.org/abstracts/155170/development-of-high-temperature-eutectic-oxide-ceramic-matrix-composites" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/155170.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">118</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">75</span> Achievement of High L-Cysteine Yield from Enzymatic Conversion Using Eutectic Mixtures of the Substrate ATC</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Deokyeong%20Choe">Deokyeong Choe</a>, <a href="https://publications.waset.org/abstracts/search?q=Sung%20Hun%20Youn"> Sung Hun Youn</a>, <a href="https://publications.waset.org/abstracts/search?q=Younggon%20Kim"> Younggon Kim</a>, <a href="https://publications.waset.org/abstracts/search?q=Chul%20Soo%20Shin"> Chul Soo Shin</a> </p> <p class="card-text"><strong>Abstract:</strong></p> L-Cysteine, a sulfur-containing amino acid, has been often used in the pharmaceutical, cosmetic, food, and feed additive industries. This amino acid has been usually produced by acid-hydrolysis of human hair and poultry feathers. There are many problems, such as avoidance for use of animal hair, low yields, and formation of harmful waste material. As an alternative, the enzymatic conversion of D, L-2-amino-Δ2-thiazoline-4-carboxylic acid (ATC) to L-cysteine has been developed as an environmental-friendly method. However, the substrate solubility was too low to be used in industry. In this study, high concentrations of eutectic substrate solutions were prepared to solve the problem. Eutectic melting occurred at 39°C after mixing ATC and malonic acid at a molar ratio of 1:1. The characteristics of eutectic mixtures were analyzed by FE-SEM, EDS mapping, and XPS. However, since sorbitol, MnSO4, and NaOH should be added as supplements to the substrate mixture for the activation and stabilization of the enzyme, strategies for sequential addition of total five compounds, ATC, malonic acid, sorbitol, MnSO4, and NaOH were established. As a result, eutectic substrate mixtures of 670 mM ATC were successfully formulated. After 6 h of enzymatic reaction, 550 mM L-cysteine was made. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=D" title="D">D</a>, <a href="https://publications.waset.org/abstracts/search?q=L-2-amino-%CE%942-thiazoline-4-carboxylicacid" title=" L-2-amino-Δ2-thiazoline-4-carboxylicacid"> L-2-amino-Δ2-thiazoline-4-carboxylicacid</a>, <a href="https://publications.waset.org/abstracts/search?q=enzymatic%20conversion" title=" enzymatic conversion"> enzymatic conversion</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic%20solution" title=" eutectic solution"> eutectic solution</a>, <a href="https://publications.waset.org/abstracts/search?q=l-cysteine" title=" l-cysteine"> l-cysteine</a> </p> <a href="https://publications.waset.org/abstracts/4129/achievement-of-high-l-cysteine-yield-from-enzymatic-conversion-using-eutectic-mixtures-of-the-substrate-atc" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/4129.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">426</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">74</span> Effect of Lead Content on Physical Properties of the Al–Si Eutectic Alloys</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hasan%20Kaya">Hasan Kaya</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Effect of lead content on the microstructure, mechanical (microhardness, ultimate tensile strength) and electrical resistivity properties of Al–Si eutectic alloys has been investigated. Al–12.6 Si–xSn (x=1, 2, 4, 6 and 8 wt. %) were prepared using metals of 99.99% high purity in the vacuum atmosphere. These alloys were directionally solidified under constant temperature gradient (5.50 K/mm) and growth rate (8.25 μm/s) by using a Bridgman–type directional solidification furnace. Eutectic spacing, microhardness, ultimate tensile strength and electrical resistivity were expressed as functions of the composition by using a linear regression analysis. The dependency of the eutectic spacing, microhardness, tensile strength and electrical resistivity on the composition (Sn content) were determined. According to experimental results, the microhardness, ultimate tensile strength and electrical resistivity of the solidified samples increase with increasing the Sn content, but decrease eutectic spacing. Variation of electrical resistivity with the temperature in the range of 300-500 K for studied alloys was also measured by using a standard d.c. four-point probe technique. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=content%20elements" title="content elements">content elements</a>, <a href="https://publications.waset.org/abstracts/search?q=solidification" title=" solidification"> solidification</a>, <a href="https://publications.waset.org/abstracts/search?q=microhardness" title=" microhardness"> microhardness</a>, <a href="https://publications.waset.org/abstracts/search?q=strength" title=" strength"> strength</a> </p> <a href="https://publications.waset.org/abstracts/45734/effect-of-lead-content-on-physical-properties-of-the-al-si-eutectic-alloys" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/45734.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">297</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">73</span> An Eco-Friendly Preparations of Izonicotinamide Quaternary Salts in Deep Eutectic Solvents </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dajana%20Ga%C5%A1o-Soka%C4%8D">Dajana Gašo-Sokač</a>, <a href="https://publications.waset.org/abstracts/search?q=Valentina%20Bu%C5%A1i%C4%87"> Valentina Bušić</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Deep eutectic solvents (DES) are liquids composed of two or three safe, inexpensive components, often interconnected by noncovalent hydrogen bonds which produce eutectic mixture whose melting point is lower than that of each component. No data in literature have been found on the quaternization reaction in DES. The use of DES have several advantages: they are environmentally benign and biodegradable, easy for purification and simple for preparation. An environmentally sustainable method for preparing quaternary salts of izonicotinamide and substituted 2-bromoacetophenones was demonstrated here using choline chloride-based DES. The quaternization reaction was carried out by three synthetic approaches: conventional method, microwave and ultrasonic irradiation. We showed that the highest yields were obtained by the microwave method. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvents" title="deep eutectic solvents">deep eutectic solvents</a>, <a href="https://publications.waset.org/abstracts/search?q=izonicotinamide%20salts" title=" izonicotinamide salts"> izonicotinamide salts</a>, <a href="https://publications.waset.org/abstracts/search?q=microwave%20synthesis" title=" microwave synthesis"> microwave synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=ultrasonic%20irradiation" title=" ultrasonic irradiation"> ultrasonic irradiation</a> </p> <a href="https://publications.waset.org/abstracts/118856/an-eco-friendly-preparations-of-izonicotinamide-quaternary-salts-in-deep-eutectic-solvents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/118856.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">130</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">72</span> X Ray Analysis of InAs-CrAs Eutectic Systems</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mobil%20Kazimov">Mobil Kazimov</a>, <a href="https://publications.waset.org/abstracts/search?q=Guseyn%20%C4%B0bragimov"> Guseyn İbragimov</a> </p> <p class="card-text"><strong>Abstract:</strong></p> InAs-CrAs systems are synthesized by the vertical Bridgman–Stockbarger method. XRD analysis and microstructural study of InAs-CrAs composites show that CrAs metallic inclusions are uniformly distributed in the InAs matrices. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=XRD" title="XRD">XRD</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic%20alloy" title=" eutectic alloy"> eutectic alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=SEM" title=" SEM"> SEM</a>, <a href="https://publications.waset.org/abstracts/search?q=EDX" title=" EDX"> EDX</a> </p> <a href="https://publications.waset.org/abstracts/162058/x-ray-analysis-of-inas-cras-eutectic-systems" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/162058.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">77</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">71</span> Phase Equilibria in Zn-Al-Sn Alloy for Lead-free Solder Application</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ji%20Chan%20Kim">Ji Chan Kim</a>, <a href="https://publications.waset.org/abstracts/search?q=Seok%20Hong%20Min"> Seok Hong Min</a>, <a href="https://publications.waset.org/abstracts/search?q=Tae%20Kwon%20Ha"> Tae Kwon Ha</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The effect of Yttrium addition on the microstructure and mechanical properties of Sn-Zn eutectic alloy, which has been attracting intensive focus as a Pb-free solder material, was investigated in this study. Phase equilibrium has been calculated by using FactSage® to evaluate the composition and fraction of equilibrium intermetallic compounds and construct a phase diagram. In the case of Sn-8.8 Zn eutectic alloy, the as-cast microstructure was typical lamellar. With addition of 0.25 wt. %Y, a large amount of pro-eutectic phases have been observed and various YZnx intermetallic compounds were expected to successively form during cooling. Hardness of Sn-8.8 Zn alloy was not affected by Y-addition and both alloys could be rolled by 90% at room temperature. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=lead-free%20solder" title="lead-free solder">lead-free solder</a>, <a href="https://publications.waset.org/abstracts/search?q=zn-al-sn%20alloy" title=" zn-al-sn alloy"> zn-al-sn alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=phase%20equilibrium" title=" phase equilibrium"> phase equilibrium</a>, <a href="https://publications.waset.org/abstracts/search?q=rolling" title=" rolling"> rolling</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=hardness" title=" hardness"> hardness</a> </p> <a href="https://publications.waset.org/abstracts/35718/phase-equilibria-in-zn-al-sn-alloy-for-lead-free-solder-application" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/35718.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">309</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">70</span> Raman Spectroscopy Analysis of MnTiO₃-TiO₂ Eutectic</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Adrian%20Niewiadomski">Adrian Niewiadomski</a>, <a href="https://publications.waset.org/abstracts/search?q=Barbara%20Surma"> Barbara Surma</a>, <a href="https://publications.waset.org/abstracts/search?q=Katarzyna%20Kolodziejak"> Katarzyna Kolodziejak</a>, <a href="https://publications.waset.org/abstracts/search?q=Dorota%20A.%20Pawlak"> Dorota A. Pawlak</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Oxide-oxide eutectic is attracting increasing interest of scientific community because of their unique properties and numerous potential applications. Some of the most interesting examples of applications are metamaterials, glucose sensors, photoactive materials, thermoelectric materials, and photocatalysts. Their unique properties result from the fact that composite materials consist of two or more phases. As a result, these materials have additive and product properties. Additive properties originate from particular phases while product properties originate from the interaction between phases. MnTiO3-TiO2 eutectic is one of such materials. TiO2 is a well-known semiconductor, and it is used as a photocatalyst. Moreover, it may be used to produce solar cells, in a gas sensing devices and in electrochemistry. MnTiO3 is a semiconductor and antiferromagnetic. Therefore it has potential application in integrated circuits devices, and as a gas and humidity sensor, in non-linear optics and as a visible-light activated photocatalyst. The above facts indicate that eutectic MnTiO3-TiO2 constitutes an extremely promising material that should be studied. Despite that Raman spectroscopy is a powerful method to characterize materials, to our knowledge Raman studies of eutectics are very limited, and there are no studies of the MnTiO3-TiO2 eutectic. While to our knowledge the papers regarding this material are scarce. The MnTiO3-TiO2 eutectic, as well as TiO2 and MnTiO3 single crystals, were grown by the micro-pulling-down method at the Institute of Electronic Materials Technology in Warsaw, Poland. A nitrogen atmosphere was maintained during whole crystal growth process. The as-grown samples of MnTiO3-TiO2 eutectic, as well as TiO2 and MnTiO3 single crystals, are black and opaque. Samples were cut perpendicular to the growth direction. Cross sections were examined with scanning electron microscopy (SEM) and with Raman spectroscopy. The present studies showed that maintaining nitrogen atmosphere during crystal growth process may result in obtaining black TiO2 crystals. SEM and Raman experiments showed that studied eutectic consists of three distinct regions. Furthermore, two of these regions correspond with MnTiO3, while the third region corresponds with the TiO2-xNx phase. Raman studies pointed out that TiO2-xNx phase crystallizes in rutile structure. The studies show that Raman experiments may be successfully used to characterize eutectic materials. The MnTiO3-TiO2 eutectic was grown by the micro-pulling-down method. SEM and micro-Raman experiments were used to establish phase composition of studied eutectic. The studies revealed that the TiO2 phase had been doped with nitrogen. Therefore the TiO2 phase is, in fact, a solid solution with TiO2-xNx composition. The remaining two phases exhibit Raman lines of both rutile TiO2 and MnTiO3. This points out to some kind of coexistence of these phases in studied eutectic. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=compound%20materials" title="compound materials">compound materials</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic%20growth%20and%20characterization" title=" eutectic growth and characterization"> eutectic growth and characterization</a>, <a href="https://publications.waset.org/abstracts/search?q=Raman%20spectroscopy" title=" Raman spectroscopy"> Raman spectroscopy</a>, <a href="https://publications.waset.org/abstracts/search?q=rutile%20TiO%E2%82%82" title=" rutile TiO₂"> rutile TiO₂</a> </p> <a href="https://publications.waset.org/abstracts/76369/raman-spectroscopy-analysis-of-mntio3-tio2-eutectic" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/76369.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">195</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">69</span> Microstructure and Mechanical Properties of A201 Alloys with Additions of Si</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Suzan%20Abd%20El%20Majid">Suzan Abd El Majid</a>, <a href="https://publications.waset.org/abstracts/search?q=Menachem%20Bamberger"> Menachem Bamberger</a>, <a href="https://publications.waset.org/abstracts/search?q=Alexander%20Katsman"> Alexander Katsman</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Two Al-4 wt. % Cu based alloys, A201 and A201+Si were investigated in the as-cast, solution treated and aged conditions. The addition of Si was used to improve the castability of the basic alloy. The all investigated alloys in the as-cast condition contained a eutectic structure along grain boundaries (GBs) with the composition Al-50at. %Cu that was found by HRSEM EDS. Addition of Si refined the grain structure and changed the amount of the eutectic regions, their size and shape. Additionally, the A201+Si microstructure contained Si rods and small amount of Al6Mn4Cu3Fe2Si-phase. Solution treatment (ST) at 550°C for ~ 20 hours resulted in a slight dissolution of the eutectic structure in the A201 alloy while substantial dissolution and change of the eutectic composition was detected in the A201+Si alloy. After ST, the A201alloy contained θ-Al2Cu, Al5Cu2Mn3 and Al9Cu7Mn3(Fe) phases associated to the GBs, while the ST A201+Si alloy contained θ-Al2Cu, Al6Mn4Cu3(Fe,Si) and Si94Mn3Al2Cu phases. Precipitation hardening during aging at 170°C was investigated for both alloys. The microhardness of the ST A201alloy increased during aging and reached the maximum value ~ 140 HV after 2 h of aging. Initial microhardness of the ST A201+Si alloy was distinctly higher than one of the ST A201 alloy, but it decreased during the first hour of aging, then increased and reached the same maximum value ~ 140 HV after ~ 4 h of aging. It was concluded that the Si addition influenced the precipitation sequence and slowed down the age hardening process. The Si induced grain refining and evolution of the eutectic structure during the heat treatments applied are discussed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=A201%20alloys" title="A201 alloys">A201 alloys</a>, <a href="https://publications.waset.org/abstracts/search?q=castability" title=" castability"> castability</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=micro-hardness" title=" micro-hardness"> micro-hardness</a> </p> <a href="https://publications.waset.org/abstracts/24114/microstructure-and-mechanical-properties-of-a201-alloys-with-additions-of-si" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/24114.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">292</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">68</span> Effect of Composition and Cooling Rate on the Solidification Structure of Al-Er Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jing%20Ning">Jing Ning</a>, <a href="https://publications.waset.org/abstracts/search?q=Kunyuan%20Gao"> Kunyuan Gao</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The microstructure and phase structure of Al-Er alloys with Er content of 10, 20, 30wt% at cooling rate of 60, 40 and 5℃/h were analyzed using scanning electron microscope (SEM) and X-ray diffraction (XRD). Experimental results showed that for solidification of the hypereutectic Al-Er alloys at different conditions, a halo of α-Al appeared around the primary Al₃Er phase. Analysis of the solidification process indicated that after the primary Al₃Er phase formed, the composition of supercooled liquid phase located outside the coupled zone of eutectic growth below the eutectic line, which leaded to the formation of Al halo. With the increase of Er content, the blocky primary Al₃Er phase expanded from 200μm to 1mm in size. With the decrease of cooling rate, the morphology and phase structure of alloy were different. At the cooling rate of 60℃/h, it was obtained the primary Al3Er phase with L1₂ structure, whose profile was straight. Meanwhile, the eutectic structure was flocculent. At the quite slow cooling rate of 5℃/h, it was obtained the primary Al₃Er phase with hR20 structure with irregular jagged profile, and the eutectic structure was approximately strip-shaped. These characteristics were closely related to the cooling rate of solidification. The XRD analysis showed that for Al₃Er phase, the lattice constant a of L1₂ structure was 4.2158Å, and a, c of hR20 structure were 6.0321Å and 35.6290Å, respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Al-Er%20alloy" title="Al-Er alloy">Al-Er alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=composition" title=" composition"> composition</a>, <a href="https://publications.waset.org/abstracts/search?q=cooling%20rate" title=" cooling rate"> cooling rate</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a> </p> <a href="https://publications.waset.org/abstracts/165095/effect-of-composition-and-cooling-rate-on-the-solidification-structure-of-al-er-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/165095.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">109</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">67</span> COSMO-RS Prediction for Choline Chloride/Urea Based Deep Eutectic Solvent: Chemical Structure and Application as Agent for Natural Gas Dehydration</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Tayeb%20Aissaoui">Tayeb Aissaoui</a>, <a href="https://publications.waset.org/abstracts/search?q=Inas%20M.%20AlNashef"> Inas M. AlNashef</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In recent years, green solvents named deep eutectic solvents (DESs) have been found to possess significant properties and to be applicable in several technologies. Choline chloride (ChCl) mixed with urea at a ratio of 1:2 and 80 °C was the first discovered DES. In this article, chemical structure and combination mechanism of ChCl: urea based DES were investigated. Moreover, the implementation of this DES in water removal from natural gas was reported. Dehydration of natural gas by ChCl:urea shows significant absorption efficiency compared to triethylene glycol. All above operations were retrieved from COSMOthermX software. This article confirms the potential application of DESs in gas industry. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=COSMO-RS" title="COSMO-RS">COSMO-RS</a>, <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvents" title=" deep eutectic solvents"> deep eutectic solvents</a>, <a href="https://publications.waset.org/abstracts/search?q=dehydration" title=" dehydration"> dehydration</a>, <a href="https://publications.waset.org/abstracts/search?q=natural%20gas" title=" natural gas"> natural gas</a>, <a href="https://publications.waset.org/abstracts/search?q=structure" title=" structure"> structure</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20salt" title=" organic salt"> organic salt</a> </p> <a href="https://publications.waset.org/abstracts/54007/cosmo-rs-prediction-for-choline-chlorideurea-based-deep-eutectic-solvent-chemical-structure-and-application-as-agent-for-natural-gas-dehydration" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/54007.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">293</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">66</span> Ag-Cu and Bi-Cd Eutectics Ribbons under Superplastic Tensile Test Regime</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Edgar%20Ochoa">Edgar Ochoa</a>, <a href="https://publications.waset.org/abstracts/search?q=G.%20Torres-Villasenor"> G. Torres-Villasenor</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Superplastic deformation is shown by materials with a fine grain size, usually less than 10 μm, when they are deformed within the strain rate range 10-5 10-1 s-1 at temperatures greater than 0.5Tm, where Tm is the melting point in Kelvin. According to the constitutive equation for superplastic flow, refinement of the grain size would be expected to increase the optimum strain rate and decrease the temperature required for superplastic flow. Ribbons of eutectic Ag-Cu and Bi-Cd alloys were manufactured by using a single roller melt-spinning technique to obtain a fine grain structure for later test in superplastic regime. The eutectics ribbons were examined by scanning electron microscopy and X-Ray diffraction, and the grain size was determined using the image analysis software ImageJ. The average grain size was less than 1 μm. Tensile tests were carried out from 10-4 to 10-1 s-1, at room temperature, to evaluate the superplastic behavior. The largest deformation was shown by the Bi-Cd eutectic ribbons, Ɛ=140 %, despite that these ribbons have a hexagonal unit cell. On the other hand, Ag-Cu eutectic ribbons have a minor grain size and cube unit cell, however they showed a lower deformation in tensile test under the same conditions than Bi-Cd ribbons. This is because the Ag-Cu grew in a strong cube-cube orientation relationship. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=eutectic%20ribbon" title="eutectic ribbon">eutectic ribbon</a>, <a href="https://publications.waset.org/abstracts/search?q=fine%20grain" title=" fine grain"> fine grain</a>, <a href="https://publications.waset.org/abstracts/search?q=superplastic%20deformation" title=" superplastic deformation"> superplastic deformation</a>, <a href="https://publications.waset.org/abstracts/search?q=cube-cube%20orientation" title=" cube-cube orientation"> cube-cube orientation</a> </p> <a href="https://publications.waset.org/abstracts/96469/ag-cu-and-bi-cd-eutectics-ribbons-under-superplastic-tensile-test-regime" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/96469.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">170</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">65</span> Novel Synthesis of Metal Oxide Nanoparticles from Type IV Deep Eutectic Solvents</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Lorenzo%20Gontrani">Lorenzo Gontrani</a>, <a href="https://publications.waset.org/abstracts/search?q=Marilena%20Carbone"> Marilena Carbone</a>, <a href="https://publications.waset.org/abstracts/search?q=Domenica%20Tommasa%20Donia"> Domenica Tommasa Donia</a>, <a href="https://publications.waset.org/abstracts/search?q=Elvira%20Maria%20Bauer"> Elvira Maria Bauer</a>, <a href="https://publications.waset.org/abstracts/search?q=Pietro%20Tagliatesta"> Pietro Tagliatesta</a> </p> <p class="card-text"><strong>Abstract:</strong></p> One of the fields where DES shows remarkable added values is the synthesis Of inorganic materials, in particular nanoparticles. In this field, the higher- ent and highly-tunable nano-homogeneities of DES structure give origin to a marked templating effect, a precious role that has led to the recent bloom of a vast number of studies exploiting these new synthesis media to prepare Nanomaterials and composite structures of various kinds. In this contribution, the most recent developments in the field will be reviewed, and some ex-citing examples of novel metal oxide nanoparticles syntheses using non-toxic type-IV Deep Eutectic Solvents will be described. The prepared materials possess nanometric dimensions and show flower-like shapes. The use of the pre- pared nanoparticles as fluorescent materials for the detection of various contaminants is under development. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20deep%20eutectic%20solvents" title="metal deep eutectic solvents">metal deep eutectic solvents</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title=" nanoparticles"> nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=inorganic%20synthesis" title=" inorganic synthesis"> inorganic synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=type%20IV%20DES" title=" type IV DES"> type IV DES</a>, <a href="https://publications.waset.org/abstracts/search?q=lamellar" title=" lamellar"> lamellar</a> </p> <a href="https://publications.waset.org/abstracts/149730/novel-synthesis-of-metal-oxide-nanoparticles-from-type-iv-deep-eutectic-solvents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/149730.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">135</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">64</span> Application of Deep Eutectic Solvent in the Extraction of Ferulic Acid from Palm Pressed Fibre</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ng%20Mei%20Han">Ng Mei Han</a>, <a href="https://publications.waset.org/abstracts/search?q=Nu%27man%20Abdul%20Hadi"> Nu'man Abdul Hadi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Extraction of ferulic acid from palm pressed fiber using deep eutectic solvent (DES) of choline chloride-acetic acid (ChCl-AA) and choline chloride-citric acid (ChCl-CA) are reported. Influence of water content in DES on the extraction efficiency was investigated. ChCl-AA and ChCl-CA experienced a drop in viscosity from 9.678 to 1.429 and 22.658 ± 1.655 mm2/s, respectively as the water content in the DES increased from 0 to 50 wt% which contributed to higher extraction efficiency for the ferulic acid. Between 41,155 ± 940 mg/kg ferulic acid was obtained after 6 h reflux when ChCl-AA with 30 wt% water was used for the extraction compared to 30,940 ± 621 mg/kg when neat ChCl-AA was used. Although viscosity of the DES could be improved with the addition of water, there is a threshold where the DES could tolerate the presence of water without changing its solvent behavior. The optimum condition for extraction of ferulic acid from palm pressed fiber was heating for 6 h with DES containing 30 wt% water. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvent" title="deep eutectic solvent">deep eutectic solvent</a>, <a href="https://publications.waset.org/abstracts/search?q=extraction" title=" extraction"> extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=ferulic%20acid" title=" ferulic acid"> ferulic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=palm%20fibre" title=" palm fibre"> palm fibre</a> </p> <a href="https://publications.waset.org/abstracts/165450/application-of-deep-eutectic-solvent-in-the-extraction-of-ferulic-acid-from-palm-pressed-fibre" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/165450.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">87</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">63</span> The Evaluation of Fuel Desulfurization Performance of Choline-Chloride Based Deep Eutectic Solvents with Addition of Graphene Oxide as Catalyst </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Chiau%20Yuan%20Lim">Chiau Yuan Lim</a>, <a href="https://publications.waset.org/abstracts/search?q=Hayyiratul%20Fatimah%20Mohd%20Zaid"> Hayyiratul Fatimah Mohd Zaid</a>, <a href="https://publications.waset.org/abstracts/search?q=Fai%20Kait%20Chong"> Fai Kait Chong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Deep Eutectic Solvent (DES) is used in various applications due to its simplicity in synthesis procedure, biodegradable, inexpensive and easily available chemical ingredients. Graphene Oxide is a popular catalyst that being used in various processes due to its stacking carbon sheets in layer which theoretically rapid up the catalytic processes. In this study, choline chloride based DESs were synthesized and ChCl-PEG(1:4) was found to be the most effective DES in performing desulfurization, which it is able to remove up to 47.4% of the sulfur content in the model oil in just 10 minutes, and up to 95% of sulfur content after repeat the process for six times. ChCl-PEG(1:4) able to perform up to 32.7% desulfurization on real diesel after 6 multiple stages. Thus, future research works should focus on removing the impurities on real diesel before utilising DESs in petroleum field. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=choline%20chloride" title="choline chloride">choline chloride</a>, <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvent" title=" deep eutectic solvent"> deep eutectic solvent</a>, <a href="https://publications.waset.org/abstracts/search?q=fuel%20desulfurization" title=" fuel desulfurization"> fuel desulfurization</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene%20oxide" title=" graphene oxide"> graphene oxide</a> </p> <a href="https://publications.waset.org/abstracts/128180/the-evaluation-of-fuel-desulfurization-performance-of-choline-chloride-based-deep-eutectic-solvents-with-addition-of-graphene-oxide-as-catalyst" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/128180.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">153</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">62</span> Alcohols as a Phase Change Material with Excellent Thermal Storage Properties in Buildings</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dehong%20Li">Dehong Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Yuchen%20Chen"> Yuchen Chen</a>, <a href="https://publications.waset.org/abstracts/search?q=Alireza%20Kaboorani"> Alireza Kaboorani</a>, <a href="https://publications.waset.org/abstracts/search?q=Denis%20Rodrigue"> Denis Rodrigue</a>, <a href="https://publications.waset.org/abstracts/search?q=Xiaodong%20%28Alice%29%20Wang"> Xiaodong (Alice) Wang</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Utilizing solar energy for thermal energy storage has emerged as an appealing option for lowering the amount of energy that is consumed by buildings. Due to their high heat storage density, and non-corrosive and non-polluting properties, alcohols can be a good alternative to petroleum-derived paraffin phase change materials (PCMs). In this paper, ternary eutectic PCMs with suitable phase change temperatures were designed and prepared using lauryl alcohol (LA), cetyl alcohol (CA), stearyl alcohol (SA), and xylitol (X). The differential scanning calorimetry (DSC) results revealed that the phase change temperatures of LA-CA-SA, LA-CA-X, and LA-SA-X were 20.52°C, 20.37°C, and 22.18°C, respectively. The latent heat of phase change of the ternary eutectic PCMs was all stronger than that of the paraffinic PCMs at roughly the same temperature. The highest latent heat was 195 J/g. It had good thermal energy storage capacity. The preparation mechanism was investigated using Fourier-transform Infrared Spectroscopy (FTIR), and it was found that the ternary eutectic PCMs were only physically mixed among the components. Ternary eutectic PCMs had a simple preparation process, suitable phase change temperature, and high energy storage density. They are suitable for low-temperature architectural packaging applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=thermal%20energy%20storage" title="thermal energy storage">thermal energy storage</a>, <a href="https://publications.waset.org/abstracts/search?q=buildings" title=" buildings"> buildings</a>, <a href="https://publications.waset.org/abstracts/search?q=phase%20change%20materials" title=" phase change materials"> phase change materials</a>, <a href="https://publications.waset.org/abstracts/search?q=alcohols" title=" alcohols"> alcohols</a> </p> <a href="https://publications.waset.org/abstracts/164542/alcohols-as-a-phase-change-material-with-excellent-thermal-storage-properties-in-buildings" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/164542.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">98</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">61</span> Microstructural Interactions of Ag and Sc Alloying Additions during Casting and Artificial Ageing to a T6 Temper in a A356 Aluminium Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dimitrios%20Bakavos">Dimitrios Bakavos</a>, <a href="https://publications.waset.org/abstracts/search?q=Dimitrios%20Tsivoulas"> Dimitrios Tsivoulas</a>, <a href="https://publications.waset.org/abstracts/search?q=Chaowalit%20Limmaneevichitr"> Chaowalit Limmaneevichitr</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Aluminium cast alloys, of the Al-Si system, are widely used for shape castings. Their microstructures can be further improved on one hand, by alloying modification and on the other, by optimised artificial ageing. In this project four hypoeutectic Al-alloys, the A356, A356+ Ag, A356+Sc, and A356+Ag+Sc have been studied. The interactions of Ag and Sc during solidification and artificial ageing at 170°C to a T6 temper have been investigated in details. The evolution of the eutectic microstructure is studied by thermal analysis and interrupted solidification. The ageing kinetics of the alloys has been identified by hardness measurements. The precipitate phases, number density, and chemical composition has been analysed by means of transmission electron microscopy (TEM) and EDS analysis. Furthermore, the SHT effect onto the Si eutectic particles for the four alloys has been investigated by means of optical microscopy, image analysis, and the UTS strength has been compared with the UTS of the alloys after casting. The results suggest that the Ag additions, significantly enhance the ageing kinetics of the A356 alloy. The formation of β” precipitates were kinetically accelerated and an increase of 8% and 5% in peak hardness strength has been observed compared to the base A356 and A356-Sc alloy. The EDS analysis demonstrates that Ag is present on the β” precipitate composition. After prolonged ageing 100 hours at 170°C, the A356-Ag exhibits 17% higher hardness strength compared to the other three alloys. During solidification, Sc additions change the macroscopic eutectic growth mode to the propagation of a defined eutectic front from the mold walls opposite to the heat flux direction. In contrast, Ag has no significance effect on the solidification mode revealing a macroscopic eutectic growth similar to A356 base alloy. However, the mechanical strength of the as cast A356-Ag, A356-Sc, and A356+Ag+Sc additions has increased by 5, 30, and 35 MPa, respectively. The outcome is a tribute to the refining of the eutectic Si that takes place which it is strong in the A356-Sc alloy and more profound when silver and scandium has been combined. Moreover after SHT the Al alloy with the highest mechanical strength, is the one with Ag additions, in contrast to the as-cast condition where the Sc and Sc+Ag alloy was the strongest. The increase of strength is mainly attributed to the dissolution of grain boundary precipitates the increase of the solute content into the matrix, the spherodisation, and coarsening of the eutectic Si. Therefore, we could safely conclude for an A356 hypoeutectic alloy additions of: Ag exhibits a refining effect on the Si eutectic which is improved when is combined with Sc. In addition Ag enhance, the ageing kinetics increases the hardness and retains its strength at prolonged artificial ageing in a Al-7Si 0.3Mg hypoeutectic alloy. Finally the addition of Sc is beneficial due to the refinement of the α-Al grain and modification-refinement of the eutectic Si increasing the strength of the as-cast product. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ageing" title="ageing">ageing</a>, <a href="https://publications.waset.org/abstracts/search?q=casting" title=" casting"> casting</a>, <a href="https://publications.waset.org/abstracts/search?q=mechanical%20strength" title=" mechanical strength"> mechanical strength</a>, <a href="https://publications.waset.org/abstracts/search?q=precipitates" title=" precipitates"> precipitates</a> </p> <a href="https://publications.waset.org/abstracts/34561/microstructural-interactions-of-ag-and-sc-alloying-additions-during-casting-and-artificial-ageing-to-a-t6-temper-in-a-a356-aluminium-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/34561.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">498</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">60</span> Carbide Structure and Fracture Toughness of High Speed Tool Steels</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jung-Ho%20Moon">Jung-Ho Moon</a>, <a href="https://publications.waset.org/abstracts/search?q=Tae%20Kwon%20Ha"> Tae Kwon Ha</a> </p> <p class="card-text"><strong>Abstract:</strong></p> M2 steels, the typical Co-free high speed steel (HSS) possessing hardness level of 63~65 HRc, are most widely used for cutting tools. On the other hand, Co-containing HSS’s, such as M35 and M42, show a higher hardness level of 65~67 HRc and used for high quality cutting tools. In the fabrication of HSS’s, it is very important to control cleanliness and eutectic carbide structure of the ingot and it is required to increase productivity at the same time. Production of HSS ingots includes a variety of processes such as casting, electro-slag remelting (ESR), forging, blooming, and wire rod rolling processes. In the present study, electro-slag rapid remelting (ESRR) process, an advanced ESR process combined by continuous casting, was successfully employed to fabricate HSS billets of M2, M35, and M42 steels. Distribution and structure of eutectic carbides of the billets were analysed and cleanliness, hardness, and composition profile of the billets were also evaluated. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=high%20speed%20tool%20steel" title="high speed tool steel">high speed tool steel</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic%20carbide" title=" eutectic carbide"> eutectic carbide</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=hardness" title=" hardness"> hardness</a>, <a href="https://publications.waset.org/abstracts/search?q=fracture%20toughness" title=" fracture toughness"> fracture toughness</a> </p> <a href="https://publications.waset.org/abstracts/15803/carbide-structure-and-fracture-toughness-of-high-speed-tool-steels" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/15803.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">445</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">59</span> Chitin Crystalline Phase Transition Promoted by Deep Eutectic Solvent</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Diana%20G.%20Ramirez-Wong">Diana G. Ramirez-Wong</a>, <a href="https://publications.waset.org/abstracts/search?q=Marius%20Ramirez"> Marius Ramirez</a>, <a href="https://publications.waset.org/abstracts/search?q=Regina%20Sanchez-Leija"> Regina Sanchez-Leija</a>, <a href="https://publications.waset.org/abstracts/search?q=Adriana%20Rugerio"> Adriana Rugerio</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Araceli%20Mauricio-Sanchez"> R. Araceli Mauricio-Sanchez</a>, <a href="https://publications.waset.org/abstracts/search?q=Martin%20A.%20Hernandez-Landaverde"> Martin A. Hernandez-Landaverde</a>, <a href="https://publications.waset.org/abstracts/search?q=Arturo%20Carranza"> Arturo Carranza</a>, <a href="https://publications.waset.org/abstracts/search?q=John%20A.%20Pojman"> John A. Pojman</a>, <a href="https://publications.waset.org/abstracts/search?q=Josue%20D.%20Mota-Morales"> Josue D. Mota-Morales</a>, <a href="https://publications.waset.org/abstracts/search?q=Gabriel%20Luna-Barcenas"> Gabriel Luna-Barcenas</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chitin films were prepared using alpha-chitin from shrimp shells as raw material and a simple method of precipitation-evaporation. Choline chloride: urea Deep Eutectic Solvent (DES) was used to disperse chitin and compared against hexafluoroisopropanol (HFIP). A careful analysis of the chemical and crystalline structure was followed along the synthesis of the films, revealing crystalline-phase transitions. The full conversion of alpha- to beta-, or alpha- to gamma-chitin structure were detected by XRD and NMR on the films. The synthesis of highly crystalline monophasic gamma-chitin films was achieved using a DES; whereas HFIP helps to promote the beta-phase. These results are encouraging to continue in the study of DES as good processing media to control the final properties of chitin based materials. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=chitin" title="chitin">chitin</a>, <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvent" title=" deep eutectic solvent"> deep eutectic solvent</a>, <a href="https://publications.waset.org/abstracts/search?q=polymorph" title=" polymorph"> polymorph</a>, <a href="https://publications.waset.org/abstracts/search?q=phase%20transformation" title=" phase transformation"> phase transformation</a> </p> <a href="https://publications.waset.org/abstracts/48813/chitin-crystalline-phase-transition-promoted-by-deep-eutectic-solvent" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/48813.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">539</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">58</span> Working Fluids in Absorption Chillers: Investigation of the Use of Deep Eutectic Solvents </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=L.%20Cesari">L. Cesari</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Alonso"> D. Alonso</a>, <a href="https://publications.waset.org/abstracts/search?q=F.%20Mutelet"> F. Mutelet</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The interest in cold production has been on the increase in absorption chillers for many years. In fact, the absorption cycles replace the compressor and thus reduce electrical consumption. The devices also allow waste heat generated through industrial activities to be recovered and cooled to a moderate temperature in accordance with regulatory guidelines. Many working fluids were investigated but could not compete with the commonly used {H2O + LiBr} and {H2O + NH3} to author’s best knowledge. Yet, the corrosion, toxicity and crystallization phenomena of these mixtures prevent the development of the absorption technology. This work investigates the possible use of a glyceline deep eutectic solvent (DES) and CO2 as working fluid in an absorption chiller. To do so, good knowledge of the mixtures is required. Experimental measurements (vapor-liquid equilibria, density, and heat capacity) were performed to complete the data lacking in the literature. The performance of the mixtures was quantified by the calculation of the coefficient of performance (COP). The results show that working fluids containing DES + CO2 are an interesting alternative and lead to different trails of working mixtures for absorption and chiller. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=absorption%20devices" title="absorption devices">absorption devices</a>, <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvent" title=" deep eutectic solvent"> deep eutectic solvent</a>, <a href="https://publications.waset.org/abstracts/search?q=energy%20valorization" title=" energy valorization"> energy valorization</a>, <a href="https://publications.waset.org/abstracts/search?q=experimental%20data" title=" experimental data"> experimental data</a>, <a href="https://publications.waset.org/abstracts/search?q=simulation" title=" simulation"> simulation</a> </p> <a href="https://publications.waset.org/abstracts/106222/working-fluids-in-absorption-chillers-investigation-of-the-use-of-deep-eutectic-solvents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/106222.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">110</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">57</span> Mechanical Properties and Microstructures of the Directional Solidified Zn-Al-Cu Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mehmet%20Izzettin%20Yilmazer">Mehmet Izzettin Yilmazer</a>, <a href="https://publications.waset.org/abstracts/search?q=Emin%20Cadirli"> Emin Cadirli</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Zn-7wt.%Al-2.96wt.%Cu eutectic alloy was directionally solidified upwards with different temperature gradients (from 6.70 K/mm to 10.67 K/mm) at a constant growth rate (16.4 Km/s) and also different growth rate (from 8.3 micron/s to 166 micron/s) at a constant temperature gradient (10.67 K/mm) using a Bridgman–type growth apparatus.The values of eutectic spacing were measured from longitudinal and transverse sections of the samples. The dependency of microstructures on the G and V were determined with linear regression analysis and experimental equations were found as λl=8.953xVexp-0.49, λt=5.942xVexp-0.42 and λl=0.008xGexp-1.23, λt=0.024xGexp-0.93. The measurements of microhardness of directionally solidified samples were obtained by using a microhardness test device. The dependence of microhardness HV on temperature gradient and growth rate were analyzed. The dependency of microhardness on the G and V were also determined with linear regression analysis as HVl=110.66xVexp0.02, HVt=111.94xVexp0.02 and HVl=69.66xGexp0.17, HVt=68.86xGexp0.18. The experimental results show that the microhardness of the directionally solidified Zn-Al-Cu alloy increases with increasing the growth rate. The results obtained in this work were compared with the previous similar experimental results. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=directional%20solidification" title="directional solidification">directional solidification</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic%20alloys" title=" eutectic alloys"> eutectic alloys</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title="microstructure">microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=microhardness" title=" microhardness "> microhardness </a> </p> <a href="https://publications.waset.org/abstracts/27066/mechanical-properties-and-microstructures-of-the-directional-solidified-zn-al-cu-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/27066.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">451</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">56</span> Breakthrough Highly-Effective Extraction of Perfluoroctanoic Acid Using Natural Deep Eutectic Solvents</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sana%20Eid">Sana Eid</a>, <a href="https://publications.waset.org/abstracts/search?q=Ahmad%20S.%20Darwish"> Ahmad S. Darwish</a>, <a href="https://publications.waset.org/abstracts/search?q=Tarek%20Lemaoui"> Tarek Lemaoui</a>, <a href="https://publications.waset.org/abstracts/search?q=Maguy%20Abi%20Jaoude"> Maguy Abi Jaoude</a>, <a href="https://publications.waset.org/abstracts/search?q=Fawzi%20Banat"> Fawzi Banat</a>, <a href="https://publications.waset.org/abstracts/search?q=Shadi%20W.%20Hasan"> Shadi W. Hasan</a>, <a href="https://publications.waset.org/abstracts/search?q=Inas%20M.%20AlNashef"> Inas M. AlNashef</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Addressing the growing challenge of per- and polyfluoroalkyl substances (PFAS) pollution in water bodies, this study introduces natural deep eutectic solvents (NADESs) as a pioneering solution for the efficient extraction of perfluorooctanoic acid (PFOA), one of the most persistent and concerning PFAS pollutants. Among the tested NADESs, trioctylphosphine oxide: lauric acid (TOPO:LauA) in a 1:1 molar ratio was distinguished as the most effective, achieving an extraction efficiency of approximately 99.52% at a solvent-to-feed (S:F) ratio of 1:2, room temperature, and neutral pH. This efficiency is achieved within a notably short mixing time of only one min, which is significantly less than the time required by conventional methods, underscoring the potential of TOPO:LauA for rapid and effective PFAS remediation. TOPO:LauA maintained consistent performance across various operational parameters, including a range of initial PFOA concentrations (0.1 ppm to 1000 ppm), temperatures (15 °C to 100 °C), pH values (3 to 9), and S:F ratios (2:3 to 1:7), demonstrating its versatility and robustness. Furthermore, its effectiveness was consistently high over seven consecutive extraction cycles, highlighting TOPO:LauA as a sustainable, environmentally friendly alternative to hazardous organic solvents, with promising applications for reliable, repeatable use in combating persistent water pollutants such as PFOA. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvents" title="deep eutectic solvents">deep eutectic solvents</a>, <a href="https://publications.waset.org/abstracts/search?q=natural%20deep%20eutectic%20solvents" title=" natural deep eutectic solvents"> natural deep eutectic solvents</a>, <a href="https://publications.waset.org/abstracts/search?q=perfluorooctanoic%20acid" title=" perfluorooctanoic acid"> perfluorooctanoic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=water%20remediation" title=" water remediation"> water remediation</a> </p> <a href="https://publications.waset.org/abstracts/177812/breakthrough-highly-effective-extraction-of-perfluoroctanoic-acid-using-natural-deep-eutectic-solvents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/177812.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">63</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">55</span> Extractive Desulfurization of Fuels Using Choline Chloride-Based Deep Eutectic Solvents</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=T.%20Zaki">T. Zaki</a>, <a href="https://publications.waset.org/abstracts/search?q=Fathi%20S.%20Soliman"> Fathi S. Soliman</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Desulfurization process is required by most, if not all refineries, to achieve ultra-low sulfur fuel, that contains less than 10 ppm sulfur. A lot of research works and many effective technologies have been studied to achieve deep desulfurization process in moderate reaction environment, such as adsorption desulfurization (ADS), oxidative desulfurization (ODS), biodesulfurization and extraction desulfurization (EDS). Extraction desulfurization using deep eutectic solvents (DESs) is considered as simple, cheap, highly efficient and environmentally friend process. In this work, four DESs were designed and synthesized. Choline chloride (ChCl) was selected as typical hydrogen bond acceptors (HBA), and ethylene glycol (EG), glycerol (Gl), urea (Ur) and thiourea (Tu) were selected as hydrogen bond donors (HBD), from which a series of deep eutectic solvents were synthesized. The experimental data showed that the synthesized DESs showed desulfurization affinities towards the thiophene species in cyclohexane solvent. Ethylene glycol molecules showed more affinity to create hydrogen bond with thiophene instead of choline chloride. Accordingly, ethylene glycol choline chloride DES has the highest extraction efficiency. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=DES" title="DES">DES</a>, <a href="https://publications.waset.org/abstracts/search?q=desulfurization" title=" desulfurization"> desulfurization</a>, <a href="https://publications.waset.org/abstracts/search?q=green%20solvent" title=" green solvent"> green solvent</a>, <a href="https://publications.waset.org/abstracts/search?q=extraction" title=" extraction"> extraction</a> </p> <a href="https://publications.waset.org/abstracts/73326/extractive-desulfurization-of-fuels-using-choline-chloride-based-deep-eutectic-solvents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/73326.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">289</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">54</span> Devulcanization of Waste Rubber Tyre Utilizing Deep Eutectic Solvents and Ultrasonic Energy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ricky%20Saputra">Ricky Saputra</a>, <a href="https://publications.waset.org/abstracts/search?q=Rashmi%20Walvekar"> Rashmi Walvekar</a>, <a href="https://publications.waset.org/abstracts/search?q=Mohammad%20Khalid"> Mohammad Khalid</a>, <a href="https://publications.waset.org/abstracts/search?q=Kaveh%20Shahbaz"> Kaveh Shahbaz</a>, <a href="https://publications.waset.org/abstracts/search?q=Suganti%20Ramarad"> Suganti Ramarad</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This particular study of interest aims to study the effect of coupling ultrasonic treatment with eutectic solvents in devulcanization process of waste rubber tyre. Specifically, three different types of Deep Eutectic Solvents (DES) were utilized, namely ChCl:Urea (1:2), ChCl:ZnCl₂ (1:2) and ZnCl₂:urea (2:7) in which their physicochemical properties were analysed and proven to have permissible water content that is less than 3.0 wt%, degradation temperature below 200ᵒC and freezing point below 60ᵒC. The mass ratio of rubber to DES was varied from 1:20-1:40, sonicated for 1 hour at 37 kHz and heated at variable time of 5-30 min at 180ᵒC. Energy dispersive x-rays (EDX) results revealed that the first two DESs give the highest degree of sulphur removal at 74.44 and 76.69% respectively with optimum heating time at 15 minutes whereby if prolonged, reformation of crosslink network would be experienced. Such is supported by the evidence shown by both FTIR and FESEM results where di-sulfide peak reappears at 30 minutes and morphological structures from 15 to 30 minutes change from smooth with high voidage to rigid with low voidage respectively. Furthermore, TGA curve reveals similar phenomena whereby at 15 minutes thermal decomposition temperature is at the lowest due to the decrease of molecular weight as a result of sulphur removal but increases back at 30 minutes. Type of bond change was also analysed whereby it was found that only di-sulphide bond was cleaved and which indicates partial-devulcanization. Overall, the results show that DES has a great potential to be used as devulcanizing solvent. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=crosslink%20network" title="crosslink network">crosslink network</a>, <a href="https://publications.waset.org/abstracts/search?q=devulcanization" title=" devulcanization"> devulcanization</a>, <a href="https://publications.waset.org/abstracts/search?q=eutectic%20solvents" title=" eutectic solvents"> eutectic solvents</a>, <a href="https://publications.waset.org/abstracts/search?q=reformation" title=" reformation"> reformation</a>, <a href="https://publications.waset.org/abstracts/search?q=ultrasonic" title=" ultrasonic"> ultrasonic</a> </p> <a href="https://publications.waset.org/abstracts/80273/devulcanization-of-waste-rubber-tyre-utilizing-deep-eutectic-solvents-and-ultrasonic-energy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/80273.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">173</span> </span> </div> </div> <ul class="pagination"> <li class="page-item disabled"><span class="page-link">&lsaquo;</span></li> <li class="page-item active"><span class="page-link">1</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=eutectic&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=eutectic&page=3">3</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=eutectic&page=2" rel="next">&rsaquo;</a></li> </ul> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div 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