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Search results for: Sumeya Bedrane
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text-center" style="font-size:1.6rem;">Search results for: Sumeya Bedrane</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3</span> Hydrodeoxygenation of Furfural over RU Sub-Nano Particles Supported on Al₂O₃-SIO₂ Mixed Oxides</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Chaima%20Zoulikha%20Tabet%20Zatla">Chaima Zoulikha Tabet Zatla</a>, <a href="https://publications.waset.org/abstracts/search?q=Nihel%20Dib"> Nihel Dib</a>, <a href="https://publications.waset.org/abstracts/search?q=Sumeya%20Bedrane"> Sumeya Bedrane</a>, <a href="https://publications.waset.org/abstracts/search?q=Juan%20Carlos%20Hernandez%20Garrido"> Juan Carlos Hernandez Garrido</a>, <a href="https://publications.waset.org/abstracts/search?q=Redouane%20Bachir"> Redouane Bachir</a>, <a href="https://publications.waset.org/abstracts/search?q=Miguel%20Angel%20Cauqui"> Miguel Angel Cauqui</a>, <a href="https://publications.waset.org/abstracts/search?q=Jose%20Juan%20Calvino%20Gamez"> Jose Juan Calvino Gamez</a> </p> <p class="card-text"><strong>Abstract:</strong></p> These last year's our planet has witnessed global warming, which is a serious threat to our lives; it has many causes, such as the CO₂ excess in the atmosphere that results from our activity, for the purpose of living in a neater and better environment, working and improving an eco-responsible energy system is a must. Valorization of biomass to produce biofuels is among the most compelling routes to decrease air pollution without considerable modification in current vehicle technology. Effective transformation of lignocellulosic biomass-derived compounds into liquid fuels and value-added chemicals is an economically viable solution. Presently, very competitive technics for the conversion of lignocellulosic biomass into platform chemicals, such as furfural and Hydroxymethylfurfural (HMF), are used. Furfural (C₅H₄O₂) is a major hemi cellulosic biomass-derived platform molecule. In our work, we focus on the valorization of lignocellulosic biomass derivative furfural that is transformed into biofuel through a hydrodeoxygenation reaction in general and involving a catalytic process. In order to get to this point, we are synthesizing and characterizing a series of catalysts with different amounts of Ru (0.5%, 1% and 2%) supported on alumina-silica mixed oxides with various molar ratios (Si/Al = 2.5; 5; 7; 10; 15). These catalysts will be characterized by numerous technics such as N₂ adsorption/desorption, Pyridine adsorption (acidity measure), FTIR, X-rays diffraction, AAS, TEM and SEM. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=furfural" title="furfural">furfural</a>, <a href="https://publications.waset.org/abstracts/search?q=ruthenium" title=" ruthenium"> ruthenium</a>, <a href="https://publications.waset.org/abstracts/search?q=silica-alumina" title=" silica-alumina"> silica-alumina</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass" title=" biomass"> biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=biofuel" title=" biofuel"> biofuel</a> </p> <a href="https://publications.waset.org/abstracts/163321/hydrodeoxygenation-of-furfural-over-ru-sub-nano-particles-supported-on-al2o3-sio2-mixed-oxides" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/163321.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">84</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">2</span> Synthesis of Highly Efficient Bio-Octane Number Booster Using Nano Au-NiAlZr-Layered Double Hydroxides Catalyst</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Bachir%20Redouane">Bachir Redouane</a>, <a href="https://publications.waset.org/abstracts/search?q=Dib%20Nihel"> Dib Nihel</a>, <a href="https://publications.waset.org/abstracts/search?q=Bedrane%20Sumeya"> Bedrane Sumeya</a>, <a href="https://publications.waset.org/abstracts/search?q=Blanco%20Ginesa"> Blanco Ginesa</a>, <a href="https://publications.waset.org/abstracts/search?q=Calvino%20Jos%C3%A9%20Juan"> Calvino José Juan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Furfural, a key biomass-derived platform compound, holds significant potential for biofuel production and the synthesis of high-value intermediates. This study investigates the hydrogenation-condensation reaction of furfural issued from lignocellulosique biomass with isopropyl alcohol to produce isopropylfurfuryl ether (iPFE), a next-generation synfuel with a high-octane number. iPFE’s water stability and resistance to methanol absorption make it a sustainable alternative to conventional gasoline additives, offering comparable performance. The catalyst used in this reaction is based on NiAl layered double hydroxides (LDH), with zirconium incorporated to enhance the distribution and structure of active sites. Gold (Au) was deposited on the NiAlZr-LDH support to improve selectivity and yield. The addition of Zr improved the thermal and mechanical stability of the catalyst, while the Au modification further increased selectivity toward iPFE. Extensive catalytic experiments were conducted to optimize reaction conditions, including temperature, hydrogen pressure, and Au loading, to maximize iPFE yield. The results demonstrate a high conversion rate of furfural, exceeding 90% under optimal conditions, with enhanced selectivity toward iPFE. Moreover, iPFE was shown to have a higher-octane number compared to traditional furfuryl ethers, making it a highly promising candidate for advanced fuel applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Au-NiAlZr-LDH" title="Au-NiAlZr-LDH">Au-NiAlZr-LDH</a>, <a href="https://publications.waset.org/abstracts/search?q=biofuels" title=" biofuels"> biofuels</a>, <a href="https://publications.waset.org/abstracts/search?q=furfural" title=" furfural"> furfural</a>, <a href="https://publications.waset.org/abstracts/search?q=green%20chemistry" title=" green chemistry"> green chemistry</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogenation" title=" hydrogenation"> hydrogenation</a>, <a href="https://publications.waset.org/abstracts/search?q=isopropylfurfuryl%20ether" title=" isopropylfurfuryl ether"> isopropylfurfuryl ether</a>, <a href="https://publications.waset.org/abstracts/search?q=octane%20number." title=" octane number."> octane number.</a> </p> <a href="https://publications.waset.org/abstracts/193484/synthesis-of-highly-efficient-bio-octane-number-booster-using-nano-au-nialzr-layered-double-hydroxides-catalyst" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/193484.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">10</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">1</span> Influence of Gold Nanoparticles on NiAlZr Type Layered Double Hydroxide for the Catalytic Transfer Oxidation of Biomass Derived Aldehydes</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nihel%20Dib">Nihel Dib</a>, <a href="https://publications.waset.org/abstracts/search?q=Redouane%20Bachir"> Redouane Bachir</a>, <a href="https://publications.waset.org/abstracts/search?q=Ghezlane%20Berrahou"> Ghezlane Berrahou</a>, <a href="https://publications.waset.org/abstracts/search?q=Chaima%20Zoulikha%20Tabet%20Zatla"> Chaima Zoulikha Tabet Zatla</a>, <a href="https://publications.waset.org/abstracts/search?q=Sumeya%20Bedrane"> Sumeya Bedrane</a>, <a href="https://publications.waset.org/abstracts/search?q=Ginessa%20Blanco%20Montilla"> Ginessa Blanco Montilla</a>, <a href="https://publications.waset.org/abstracts/search?q=Jose%20Juan%20Calvino%20Gamez"> Jose Juan Calvino Gamez</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In recent decades, the world’s population has rapidly increased annually, resulting in the consumption of huge amounts of conventional non-renewable petroleum-based resources at an alarming rate. The scarcity of such resources will shut down the corresponding industries and consequently have negative effects on the well-being of humanity. Accordingly, to combat the forthcoming crises and to serve the ever-growing demands, seeking potentially sustainable resources such as geothermal, wind, solar, and biomass has become an active field of study. Currently, lignocellulosic biomass, one of the world’s most plentiful resources, is acknowledged as a cost-effective material that has drawn great interest from many researchers since it has substantial energy potential as well as containing useful C5 and C6 sugars. These C5 and C6 sugars are the key reactants for the production of the valuable 16-platform chemicals such as 5-hydroxymethyl furfural, furfural, levulinic acid, succinic acid, and fumaric acid, all of which are crucial intermediates for synthesizing high-value bio-based chemicals and polymers. Succinic acid (SA) has been predicted to make a significant contribution to the global bio-based economy soon since it serves as a C4 building block that is used in a wide spectrum of industries, including biopolymers, solvents, and pharmaceuticals. In the present work, we modify the HDL MgAl with Zr to try to create acid sites on the supports and deposit gold by deposition precipitation with urea with a low gold content (0.25%). The catalyst was used to produce succinic acid by selective oxidation of furfuraldehyde with hydrogen peroxide under mild reaction conditions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=hydrotalcite" title="hydrotalcite">hydrotalcite</a>, <a href="https://publications.waset.org/abstracts/search?q=catalysis" title=" catalysis"> catalysis</a>, <a href="https://publications.waset.org/abstracts/search?q=gold" title=" gold"> gold</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass" title=" biomass"> biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=furfural" title=" furfural"> furfural</a>, <a href="https://publications.waset.org/abstracts/search?q=oxidation" title=" oxidation"> oxidation</a> </p> <a href="https://publications.waset.org/abstracts/162966/influence-of-gold-nanoparticles-on-nialzr-type-layered-double-hydroxide-for-the-catalytic-transfer-oxidation-of-biomass-derived-aldehydes" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/162966.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">69</span> </span> </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/WASET-16th-foundational-anniversary.pdf">WASET celebrates its 16th 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