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Selenidostannate - Wikipedia
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data-event-name="pinnable-header.vector-appearance.unpin">hide</button> </div> </div> </div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">From Wikipedia, the free encyclopedia</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="en" dir="ltr"><p><b>Selenidostannates</b> are chemical compounds which contain anionic units of selenium connected to <a href="/wiki/Tin" title="Tin">tin</a>. They can be considered as <a href="/w/index.php?title=Stannates&action=edit&redlink=1" class="new" title="Stannates (page does not exist)">stannates</a> where selenium substitutes for oxygen. Similar compounds include the <a href="/wiki/Selenogermanates" class="mw-redirect" title="Selenogermanates">selenogermanates</a> and <a href="/wiki/Thiostannate" title="Thiostannate">thiostannates</a>. They are in the category of chalcogenidotetrelates or more broadly chalcogenometallates. </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Formation">Formation</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Selenidostannate&action=edit&section=1" title="Edit section: Formation"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Some selenidostannates can be made by treating <a href="/w/index.php?title=Tin_diselenide&action=edit&redlink=1" class="new" title="Tin diselenide (page does not exist)">tin diselenide</a> (SnSe<sub>2</sub>) with an alkali selenide dissolved in water.<sup id="cite_ref-:3_1-0" class="reference"><a href="#cite_note-:3-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> Other possible solvents include <a href="/wiki/Choline_chloride" title="Choline chloride">choline chloride</a> with <a href="/w/index.php?title=1,8-diaminooctane&action=edit&redlink=1" class="new" title="1,8-diaminooctane (page does not exist)">1,8-diaminooctane</a>,<sup id="cite_ref-:4_2-0" class="reference"><a href="#cite_note-:4-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Properties">Properties</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Selenidostannate&action=edit&section=2" title="Edit section: Properties"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Most selenidostannates are semiconductors. Their resistance drops on exposure to light. Also selenidostannates are often coloured, most often orange, red or yellow. </p><p>Many are unstable in humid air, as the water reacts with the selenidostannate to form <a href="/wiki/Hydrogen_selenide" title="Hydrogen selenide">hydrogen selenide</a> (H<sub>2</sub>Se). </p> <div class="mw-heading mw-heading2"><h2 id="Use">Use</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Selenidostannate&action=edit&section=3" title="Edit section: Use"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Selenidostannates are primarily of research interest. They are under investigation as photoelectric materials. </p> <div class="mw-heading mw-heading2"><h2 id="List">List</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Selenidostannate&action=edit&section=4" title="Edit section: List"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <table class="wikitable"> <tbody><tr> <th>name </th> <th>chem </th> <th>mw </th> <th>crystal system </th> <th>space group </th> <th>unit cell Å </th> <th>volume </th> <th>density </th> <th>comment </th> <th>references </th></tr> <tr> <td>tris(μ<sub>2</sub>-1,2-Diaminoethane)-1,2-diaminoethane-di-lithium triselenido-tin(iv) </td> <td>Li<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub> · 8<i>en</i> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=22.660 <i>b</i>=9.449 <i>c</i>=20.336 <i>β</i>=101.24° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>diammonium </td> <td>[NH<sub>4</sub>]<sub>2</sub>Sn<sub>4</sub>Se<sub>9</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pnma</i> </td> <td><i>a</i> =13.2274 <i>b</i>=12.4270 <i>c</i>=12.6102 </td> <td> </td> <td> </td> <td>supertetrahedra Sn<sub>4</sub>Se<sub>10</sub> arranged in layers </td> <td><sup id="cite_ref-:1_4-0" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(dimethylammonium) heptakis(μ-selenido)-tri-tin dimethylamine solvate </td> <td>[NH<sub>2</sub>(CH<sub>3</sub>)<sub>2</sub>]<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub>·0.5NH(CH<sub>3</sub>)<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=23.5939 <i>b=</i>13.6409 <i>c</i>=15.0372, <i>β</i>=102.177° </td> <td> </td> <td> </td> <td>chains of Sn<sub>3</sub>Se<sub>8</sub> </td> <td><sup id="cite_ref-:1_4-1" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(ethylammonium) tetradecakis(μ-selenido)-hexa-tin </td> <td>[NH<sub>3</sub>C<sub>2</sub>H<sub>5</sub>]<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Cmca</i> </td> <td><i>a</i>=13.5561 <i>b</i>=24.0194 <i>c</i>=27.0184 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-2" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(Ethylenediammonium) ethylenediamine bis((μ<sub>2</sub>-selenido)-diseleno-tin(iv)) </td> <td>[enH<sub>2</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>] · en </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> =8.636 <i>b</i> =11.044 <i>c</i> =6.613, <i>α</i> =104.48° <i>β</i> =110.76° <i>γ</i> =79.43° </td> <td> </td> <td> </td> <td>twin edge-bridged SnSe<sub>4</sub> tetrahedra </td> <td><sup id="cite_ref-:6_5-0" class="reference"><a href="#cite_note-:6-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(2-Aminoethylammonium) bis(μ<sub>2</sub>-selenido)-tetraselenido-di-tin(iv) 1,2-diaminoethane </td> <td>[<i>en</i>H]<sub>4</sub>[Sn<sup>IV</sup><sub>2</sub>Se<sub>6</sub>] · <i>en</i> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=11.212 <i>b</i>=11.631 <i>c</i>=13.097, <i>α</i>=79.40° <i>β</i>=76.82° <i>γ</i>=64.82° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:10_6-0" class="reference"><a href="#cite_note-:10-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena(Ethylenediammonium hemiethylenediamine (μ<sub>3</sub>-selenido)-hexakis(μ<sub>2</sub>-selenido)-tri-tin(iv)) </td> <td>[enH<sub>2</sub>][Sn<sub>3</sub>Se<sub>7</sub>]·0.5en </td> <td> </td> <td>orthorhombic </td> <td><i>Fdd</i>2 </td> <td><i>a</i>=23.597 <i>b</i>=27.563 <i>c</i>=13.877 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-3" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:6_5-1" class="reference"><a href="#cite_note-:6-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(tetrakis(μ<sub>2</sub>-Seleno)-ethylenediamine-di-tin(iv)) </td> <td>[2 SnSe<sub>2</sub>·en] </td> <td> </td> <td>orthorhombic </td> <td><i>Pca</i>2<sub>1</sub> </td> <td><i>a</i> 1=3.724 <i>b</i> =11.866 <i>c</i> =13.647 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:6_5-2" class="reference"><a href="#cite_note-:6-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>NH]<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td> </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td> </td> <td> </td> <td> </td> <td>2.12 eV </td> <td><sup id="cite_ref-:1_4-4" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>NH]<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub>·0.25H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td> </td> <td> </td> <td> </td> <td>2.1 eV </td> <td><sup id="cite_ref-:1_4-5" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(Et<sub>4</sub>N)<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>m</i> </td> <td><i>a</i>=10.140 <i>b</i>=13.858 <i>c</i>=12.071, <i>β</i>=100.649° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:8_7-0" class="reference"><a href="#cite_note-:8-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[NEt<sub>4</sub>]<sub>4</sub>[Sn<sub>4</sub>Se<sub>10</sub>] </td> <td> </td> <td>cubic </td> <td><i>P</i><span style="text-decoration:overline;">4</span>3<i>n</i> </td> <td><i>a</i> = 22.170 </td> <td>10897 </td> <td> </td> <td> </td> <td><sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(tetrapropylammonium) nonaselenidotetrastannate(IV) </td> <td>([C<sub>3</sub>H<sub>7</sub>]<sub>4</sub>N)<sub>2</sub>[Sn<sub>4</sub>Se<sub>9</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> = 15.328, <i>b</i> = 19.058, <i>c</i> = 15.398, <i>β</i> = 97.947°, <i>Z</i> = 4 </td> <td>4454.7 </td> <td> </td> <td>orange </td> <td><sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(C<sub>7</sub>N<sub>4</sub>OH<sub>16</sub>)<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub>·H<sub>2</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-6" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(NH<sub>3</sub>(CH<sub>2</sub>)<sub>8</sub>NH<sub>3</sub>)Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-7" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Octane-1,8-diammonium (μ<sub>3</sub>-selena)-hexakis(μ<sub>2</sub>-selena)-tri-tin </td> <td>(NH<sub>3</sub>(CH<sub>2</sub>)<sub>8</sub>NH<sub>3</sub>)Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=8.4419 <i>b</i>=11.6441 <i>c</i>=13.1857 <i>α</i>=66.636° <i>β</i>=77.989° <i>γ</i>=83.919° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:71_10-0" class="reference"><a href="#cite_note-:71-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Decane-1,10-diammonium (μ<sub>3</sub>-selena)-hexakis(μ<sub>2</sub>-selena)-tri-tin </td> <td>(NH<sub>3</sub>(CH<sub>2</sub>)<sub>10</sub>NH<sub>3</sub>)Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=23.726 <i>b</i>=13.910 <i>c</i>=15.954 <i>β</i>=111.915° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:71_10-1" class="reference"><a href="#cite_note-:71-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(NH<sub>3</sub>(CH<sub>2</sub>)<sub>10</sub>NH<sub>3</sub>)Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-8" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ<sub>3</sub>-selenido)-octadecakis(μ<sub>2</sub>-selenido)-nona-tin </td> <td> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> =18.652 <i>b</i>=20.353 <i>c</i>=20.196 <i>β</i>=105.244° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:74_11-0" class="reference"><a href="#cite_note-:74-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) dodecakis(μ<sub>2</sub>-selenido)-diselenido-hexa-tin </td> <td>[Mmpmim]<sub>4</sub>Sn<sub>6</sub>Se<sub>14</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=14.270 <i>b</i>=15.549 <i>c</i>=14.377 <i>β</i>=92.749° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:74_11-1" class="reference"><a href="#cite_note-:74-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) (μ<sub>3</sub>-selenido)-hexakis(μ<sub>2</sub>-selenido)-tri-tin </td> <td>[Mmpmim]<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>trigonal </td> <td><i>P</i>3<sub>2</sub>21 </td> <td><i>a</i>=13.9470 <i>b</i>=13.9470 <i>c</i>=27.8553 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:74_11-2" class="reference"><a href="#cite_note-:74-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>octakis(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) tetrakis(μ<sub>3</sub>-selenido)-docosakis(μ<sub>2</sub>-selenido)-diselenido-dodeca-tin </td> <td>[Mmpmim]<sub>8</sub>Sn12Se26 </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=24.538 <i>b</i>=13.961 <i>c</i>=19.434 <i>β</i>=94.539° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:74_11-3" class="reference"><a href="#cite_note-:74-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetra(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) bis(μ<sub>3</sub>-selenido)-dodecakis(μ<sub>2</sub>-selenido)-hexa-tin </td> <td>[Mmbmim]<sub>4</sub>Sn<sub>6</sub>Se<sub>14</sub> </td> <td> </td> <td>trigonal </td> <td><i>P</i>3<sub>2</sub>21 </td> <td><i>a</i>=13.9381 <i>c</i>=27.774 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:74_11-4" class="reference"><a href="#cite_note-:74-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[prmmim]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td> </td> <td><i>P</i>322<sub>1</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-9" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Bmmim=1-butyl-2,3-dimethylimidazolium </td> <td>[bmmim]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td> </td> <td><i>P</i>322<sub>1</sub> </td> <td> </td> <td> </td> <td> </td> <td>band gap 2.2 eV </td> <td><sup id="cite_ref-:1_4-10" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Bzmim = 1-benzyl-3-methylimidazolium <p>bis(1-benzyl-3-methylimidazolium) heptakis(μ-selenido)-tri-tin </p> </td> <td>[Bzmim]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=14.297 <i>b</i>=13.8808 <i>c</i>=16.8855 <i>β</i>=99.817° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:15_12-0" class="reference"><a href="#cite_note-:15-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Emim = 1-ethyl-3-methylimidazolium <p>pentakis(1-ethyl-3-methylimidazolium) bis(heptakis(μ-selenido)-tri-tin) chloride unknown solvate </p> </td> <td>[Emim]<sub>5</sub>[Sn<sub>3</sub>Se<sub>7</sub>]<sub>2</sub>Cl </td> <td> </td> <td>hexagonal </td> <td><i>P</i>6<sub>3</sub>/<i>mmc</i> </td> <td><i>a</i>=13.8331 <i>c</i>=18.4649 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:15_12-1" class="reference"><a href="#cite_note-:15-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[DBNH]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>]·PEG </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td> </td> <td> </td> <td> </td> <td>band gap 2.13 eV </td> <td><sup id="cite_ref-:1_4-11" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[DBNH]<sub>3</sub>[NH<sub>4</sub>][Sn<sub>6</sub>Se<sub>14</sub>] </td> <td> </td> <td>trigonal </td> <td><i>R</i><span style="text-decoration:overline;">3</span> </td> <td> </td> <td> </td> <td> </td> <td>band gap 2.02 eV </td> <td><sup id="cite_ref-:1_4-12" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(H<sup>+</sup>-DBN)<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td> </td> <td><i>Cmc</i>2<sub>1</sub> </td> <td> </td> <td> </td> <td> </td> <td>band gap 2.02 eV </td> <td><sup id="cite_ref-:1_4-13" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(CH<sub>3</sub>)<sub>3</sub>N(CH<sub>2</sub>)<sub>2</sub>OH]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td> </td> <td> </td> <td> </td> <td>band gap 2.35 eV </td> <td><sup id="cite_ref-:1_4-14" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate] </td> <td>(CH<sub>3</sub>)<sub>3</sub>N(CH<sub>2</sub>)<sub>2</sub>OH]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>]∙H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=9.8365 <i>b</i>=13.5796 <i>c</i>=20.7384 <i>β</i>=92.727° Z=4 </td> <td>2893.0 </td> <td>2.606 </td> <td>orange; </td> <td><sup id="cite_ref-:1_4-15" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin] </td> <td>(CH<sub>3</sub>)<sub>3</sub>N(CH<sub>2</sub>)<sub>2</sub>CH<sub>3</sub>]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i> =17.534 <i>b</i> =13.7273 <i>c</i> =24.1221 Z=8 </td> <td>5806.2 </td> <td>2.547 </td> <td>orange </td> <td><sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(<i>N,N,N</i>-trimethylbutanaminium) poly[heptaselenidotristannate(IV)] </td> <td>(Bu(CH<sub>3</sub>)<sub>3</sub>N)<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i> = 23.950, <i>b</i> = 13.760, <i>c</i> = 20.011, <i>β</i> = 114.565°, <i>Z</i> = 8 </td> <td>5998 </td> <td> </td> <td>orange </td> <td><sup id="cite_ref-:1_4-16" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-15" class="reference"><a href="#cite_note-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>AEPP = <i>N</i>-aminoethylpiperazine </td> <td>[AEPPH<sub>2</sub>]<sub>2</sub>[Sn<sub>5</sub>Se<sub>12</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> = 10.6351, <i>b</i> = 10.6850, <i>c</i> = 10.7771, <i>α</i> = 61.344°, <i>β</i> = 62.442°, <i>γ</i> = 67.468 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-16" class="reference"><a href="#cite_note-16"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>phen=1,10-Phenanthroline </td> <td>(CH<sub>3</sub>NH<sub>3</sub>)<sub>4</sub>(Sn<sub>2</sub>Se<sub>6</sub>)·6phen </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.594 <i>b</i> 12.225 <i>c</i> 14.945 <i>α</i> 83.589° <i>β</i> 83.133° <i>γ</i> 86.604° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:16_17-0" class="reference"><a href="#cite_note-:16-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Im=imidazolium <p>catena-(pentakis(3-n-butyl-1-methylimidazolium) dodecakis(μ-selenido)-nona-tin tetrafluoroborate) </p> </td> <td>(C<sub>4</sub>C<sub>1</sub>C<sub>1</sub>Im)<sub>5</sub>[Sn<sub>9</sub>Se<sub>20</sub>][BF<sub>4</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=13.878 <i>b</i>=20.365 <i>c</i>=31.026 <i>β</i> =91.326° Z=4 </td> <td>8766 </td> <td>2.652 </td> <td>orange </td> <td><sup id="cite_ref-:21_18-0" class="reference"><a href="#cite_note-:21-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>DMMP=2,6-dimethylmorpholine </td> <td>(DMMPH)<sub>4</sub>[Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=6.158 <i>b</i>=22.381 <i>c</i>=14.642 <i>β</i>=93.57° Z=2 </td> <td>2014.1 </td> <td>1.926 </td> <td>yellow </td> <td><sup id="cite_ref-:21_18-1" class="reference"><a href="#cite_note-:21-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(bis(1-ethyl-3-methylimidazolium) bis(2,6-dimethylmorpholin-4-ium) tetradecakis(μ-selenido)-hexa-tin) </td> <td>(C<sub>2</sub>C<sub>1</sub>Im)<sub>2</sub>(DMMPH)<sub>2</sub>[Sn<sub>6</sub>Se<sub>14</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=20.616 <i>b</i>=13.857 <i>c</i>=19.629 <i>β</i>=107.40° Z=4 </td> <td>5351 </td> <td>2.821 </td> <td>orange </td> <td><sup id="cite_ref-:21_18-2" class="reference"><a href="#cite_note-:21-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tetrakis(3-n-Butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(μ<sub>3</sub>-selenido)-undecakis(μ<sub>2</sub>-selenido)-selenido-hexa-tin(iv)] </td> <td>[BMMIm]<sub>4</sub>[Sn<sub>6</sub>Se<sub>14</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 24.2744 <i>b</i> 13.8901 <i>c</i> 19.1763 <i>β</i> 94.083° Z=4 </td> <td>6449.3 </td> <td>2.503 </td> <td>orange </td> <td><sup id="cite_ref-:30_19-0" class="reference"><a href="#cite_note-:30-19"><span class="cite-bracket">[</span>19<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(hexadecakis(1-butyl-2,3-dimethylimidazolium) octakis(μ<sub>3</sub>-selenido)-octatetracontakis(μ<sub>2</sub>-selenido)-tetracosa-tin) </td> <td>[BMMIm]<sub>16</sub>[Sn<sub>24</sub>Se<sub>56</sub>] </td> <td> </td> <td>trigonal </td> <td><i>P</i>3<sub>2</sub> </td> <td>a=27.8622 <i>c</i>=28.0566 Z=3 </td> <td>18862.4 </td> <td>2.568 </td> <td>red </td> <td><sup id="cite_ref-:30_19-1" class="reference"><a href="#cite_note-:30-19"><span class="cite-bracket">[</span>19<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(tris(3-Butyl-1,2-dimethylimidazolium) 2,6-dimethylmorpholin-4-ium (μ<sub>3</sub>-selenido)-dodecakis(μ<sub>2</sub>-selenido)-selenido-hexa-tin) </td> <td>[BMMIm]<sub>3</sub>[DMMPH][Sn<sub>6</sub>Se<sub>14</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 11.1358 <i>b</i> 12.6745 <i>c</i> 23.362, <i>α</i> 89.690° <i>β</i> 88.473° <i>γ</i> 72.098° Z=2 </td> <td>3136.6 </td> <td>2.534 </td> <td>orange or yellow (low temp) </td> <td><sup id="cite_ref-:30_19-2" class="reference"><a href="#cite_note-:30-19"><span class="cite-bracket">[</span>19<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1-butyl-3-methyl-inidazolinium </td> <td>[BMIm]<sub>4</sub>[Sn<sub>9</sub>Se<sub>20</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>Cc</i> </td> <td>a=19.901 b=26.494 c=14.447 <i>β</i>=105.34 Z=4 </td> <td>7361 </td> <td>2.892 </td> <td>red </td> <td><sup id="cite_ref-20" class="reference"><a href="#cite_note-20"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate] </td> <td>[HOCH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)<sub>3</sub>]<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub>·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 9.8365 <i>b</i> 13.5796 <i>c</i> 20.7384 <i>β</i> 92.727° </td> <td> </td> <td> </td> <td>orange (high temp) or yellow </td> <td><sup id="cite_ref-:37_21-0" class="reference"><a href="#cite_note-:37-21"><span class="cite-bracket">[</span>21<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin] </td> <td>[CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)<sub>3</sub>]<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i> 17.403 <i>b</i> 13.7025 <i>c</i> 23.9113 </td> <td> </td> <td>2.852 </td> <td>yellow </td> <td><sup id="cite_ref-:37_21-1" class="reference"><a href="#cite_note-:37-21"><span class="cite-bracket">[</span>21<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(piperidinium) bis(μ-selenido)-tetraselenido-di-tin </td> <td>{[Sn<sub>2</sub>Se<sub>6</sub>]·4(C<sub>5</sub>NH<sub>12</sub>)} </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 10.3277 <i>b</i> 10.2808 <i>c</i> 15.7823 <i>β</i> 96.725° </td> <td> </td> <td>2.0110 </td> <td>red </td> <td><sup id="cite_ref-:38_22-0" class="reference"><a href="#cite_note-:38-22"><span class="cite-bracket">[</span>22<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(3,6,7,8-tetrahydro-2H-pyrrolo[1,2-a]pyrimidin-5-ium) tetrakis(μ-selenido)-hexa-tin] </td> <td>{[Sn<sub>3</sub>Se<sub>7</sub>]·2(HDBN)} DBN = 1,5-diazabicyclo[4.3.0]non-5-ene </td> <td> </td> <td>orthorhombic </td> <td><i>Cmc</i>2<sub>1</sub> </td> <td><i>a</i> 13.4435 <i>b</i> 24.4817 <i>c</i> 14.4494 </td> <td> </td> <td> </td> <td>red </td> <td><sup id="cite_ref-:38_22-1" class="reference"><a href="#cite_note-:38-22"><span class="cite-bracket">[</span>22<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[dabcoH]<sub>2</sub>[(CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>m</i> </td> <td>a=20.172 b=11.674 c=6.476 <i>β</i>=103.15 Z=2 </td> <td>1485.2 </td> <td>2.303 </td> <td>yellow </td> <td><sup id="cite_ref-23" class="reference"><a href="#cite_note-23"><span class="cite-bracket">[</span>23<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(N<sub>2</sub>H<sub>4</sub>)<sub>3</sub>(N<sub>2</sub>H<sub>5</sub>)<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> = 6.6475, <i>b</i> = 9.5474, <i>c</i> = 9.883, α = 94.110°, β = 99.429°, γ = 104.141°, <i>Z</i> = 1 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-24" class="reference"><a href="#cite_note-24"><span class="cite-bracket">[</span>24<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(1-Aminoethylammonium) bis(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane-potassium) bis(μ<sub>2</sub>-seleno)-tetraseleno-di-tin(iv) </td> <td>(enH)<sub>2</sub>(2,2,2-crypt-K)<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=8.442 <i>b</i>=25.877 <i>c</i>=14.821 <i>β</i>=104.19° </td> <td> </td> <td> </td> <td> </td> <td> </td></tr> <tr> <td> </td> <td>(MeSn)<sub>4</sub>Se<sub>6</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td>a = 9.147, b =10.495 c =10.508, <i>α</i> = 85.60, <i>β</i> = 89.83 <i>γ</i> =65.71° Z=2 </td> <td>916 </td> <td> </td> <td>adamantane structure </td> <td><sup id="cite_ref-25" class="reference"><a href="#cite_note-25"><span class="cite-bracket">[</span>25<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>SnS<sub>4</sub> </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub><i>acd</i> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:43_26-0" class="reference"><a href="#cite_note-:43-26"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>SnS<sub>4</sub> </td> <td> </td> <td>tetragonal </td> <td><i>P</i><span style="text-decoration:overline;">4</span>2<sub>1</sub><i>c</i> </td> <td><i>a</i>=7.84679 <i>c</i>=6.95798, Z=2 </td> <td>428.42 </td> <td> </td> <td>yellow </td> <td><sup id="cite_ref-:43_26-1" class="reference"><a href="#cite_note-:43-26"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>SnSe<sub>4</sub>·14H<sub>2</sub>O </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:43_26-2" class="reference"><a href="#cite_note-:43-26"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>SnSe<sub>4</sub>·16H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>m</i> </td> <td>a = 8.673, b = 16.563, c = 8.647, β = 92.10°, Z = 2 </td> <td> </td> <td> </td> <td>tetrahedra; Sn-Se bond length 2.504−2.527 Å </td> <td><sup id="cite_ref-:2_27-0" class="reference"><a href="#cite_note-:2-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:3_1-1" class="reference"><a href="#cite_note-:3-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>Sn<sub>2</sub>S<sub>6</sub><b>·</b>5H<sub>2</sub>O </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:49_28-0" class="reference"><a href="#cite_note-:49-28"><span class="cite-bracket">[</span>28<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub>·13H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td>a = 7.106, b = 10.330, c = 19.009, α = 78.60, β = 85.66, γ = 72.85° Z = 2 (at −130 °C) </td> <td> </td> <td> </td> <td>orange-red; tetrahedral edge-shared pairs </td> <td><sup id="cite_ref-:2_27-1" class="reference"><a href="#cite_note-:2-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:5_29-0" class="reference"><a href="#cite_note-:5-29"><span class="cite-bracket">[</span>29<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>Ge<sub>2</sub>Se<sub>6</sub> · 16 H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td>a = 9.894, b = 11.781, c = 12.225, β = 92.90°, Z = 2 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-30" class="reference"><a href="#cite_note-30"><span class="cite-bracket">[</span>30<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>4</sub>Sn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td>trigonal bipyramid + tetrahedron </td> <td><sup id="cite_ref-:2_27-2" class="reference"><a href="#cite_note-:2-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>6</sub>Sn<sub>4</sub>Se<sub>11</sub> · 22 H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i> 15.325 <i>b</i> 11.634 <i>c</i> 26.739 <i>β</i> 95.81° </td> <td> </td> <td> </td> <td>yellow-orange </td> <td><sup id="cite_ref-31" class="reference"><a href="#cite_note-31"><span class="cite-bracket">[</span>31<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>6</sub>Sn<sub>2</sub>Se<sub>7</sub>·16H<sub>2</sub>O </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td>red </td> <td><sup id="cite_ref-:5_29-1" class="reference"><a href="#cite_note-:5-29"><span class="cite-bracket">[</span>29<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(tris(1-Amino-2-ammonioethane) octakis(μ<sub>3</sub>-selenido)-hexakis(μ<sub>2</sub>-selenido)-sodium-hexa-tin sesquikis(dimethylamine) sesquihydrate) </td> <td>(enH)<sub>3</sub>Na[Sn<sub>3</sub>Se<sub>7</sub>]<sub>2</sub>·1.5Me<sub>2</sub>NH·1.5H<sub>2</sub>O </td> <td> </td> <td> </td> <td><i>R</i>32 </td> <td>a=13.8647 <i>c</i>=18.962 </td> <td> </td> <td> </td> <td>Na<sup>+</sup> ion conductor </td> <td><sup id="cite_ref-32" class="reference"><a href="#cite_note-32"><span class="cite-bracket">[</span>32<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((μ<sub>4</sub>-Selenido)-(μ<sub>3</sub>-selenido)-bis(μ<sub>2</sub>-ethylene-1,2-diamine))-tetra-sodium-tin </td> <td>[Na<sub>4</sub>(<i>en</i>)<sub>4</sub>][SnSe<sub>4</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>4<sub>1</sub>2<sub>1</sub>2 </td> <td><i>a</i>=13.090 <i>b</i>=13.090 <i>c</i>=14.548 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-33" class="reference"><a href="#cite_note-33"><span class="cite-bracket">[</span>33<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Li<sub>2</sub>MgNaSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pmn</i>2<sub>1</sub> </td> <td>a = 8.40 b = 7.18 c = 6.73 Z=2 </td> <td>405.9 </td> <td>3.867 </td> <td>yellow; moisture absorbing </td> <td><sup id="cite_ref-34" class="reference"><a href="#cite_note-34"><span class="cite-bracket">[</span>34<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>SnPSe<sub>3</sub> </td> <td> </td> <td>monoclinic </td> <td><i>Pn</i> </td> <td><i>a</i>=6.8161 <i>b</i>=7.7264 <i>c</i>=9.6437 <i>β</i>=91.073° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-35" class="reference"><a href="#cite_note-35"><span class="cite-bracket">[</span>35<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>4</sub>SnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pnma</i> </td> <td>a=14.714 b=10.323 c=8.248 Z=4 </td> <td> </td> <td> </td> <td>yellow </td> <td><sup id="cite_ref-36" class="reference"><a href="#cite_note-36"><span class="cite-bracket">[</span>36<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>2D-K<sub>2</sub>Sn<sub>2</sub>Se<sub>5</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=13.0246 <i>b</i>=12.186 <i>c</i>=14.135 Z=8 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-37" class="reference"><a href="#cite_note-37"><span class="cite-bracket">[</span>37<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td>tetrahedral edge-shared pairs </td> <td><sup id="cite_ref-:2_27-3" class="reference"><a href="#cite_note-:2-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>4</sub>Sn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Ccca</i> </td> <td><i>a</i> 8.214 <i>b</i> 27.795 <i>c</i> 8.2136 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-38" class="reference"><a href="#cite_note-38"><span class="cite-bracket">[</span>38<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>0.5</sub>[Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>hexagonal </td> <td><i>P</i>6<sub>5</sub>22 </td> <td>a=13.8325 <i>c</i> 43.295 Z=12 </td> <td>7174.1 </td> <td>2.579 </td> <td>red </td> <td><sup id="cite_ref-:21_18-3" class="reference"><a href="#cite_note-:21-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>6</sub>Sn<sub>4</sub>Se<sub>11</sub> . 8H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i> =28.004 <i>b</i> =9 <i>c</i> =15.192, <i>β</i> 113.8° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:8_7-1" class="reference"><a href="#cite_note-:8-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>6</sub>[Sn<sup>III</sup><sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:10_6-1" class="reference"><a href="#cite_note-:10-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>4</sub>Sn<sub>4</sub>Se<sub>10</sub>·4.5H<sub>2</sub>O </td> <td> </td> <td>trigonal </td> <td><i>R</i><span style="text-decoration:overline;">3</span> </td> <td><i>a</i>=15.32 <i>c</i>=21.019 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:69_39-0" class="reference"><a href="#cite_note-:69-39"><span class="cite-bracket">[</span>39<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(Tetramethylammonium) (hexakis(μ<sub>2</sub>-seleno)-di-tin(iv)-potassium) </td> <td>K(N(CH<sub>3</sub>)<sub>4</sub>)<sub>3</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 9.587 <i>b</i> 10.005 <i>c</i> 15.996 <i>α</i> 95.15° <i>β</i> 92.81° <i>γ</i> 106.96° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-40" class="reference"><a href="#cite_note-40"><span class="cite-bracket">[</span>40<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>(μ<sub>2</sub>-Ethylene-1,2-diamine-N,N')-bis(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium (μ<sub>2</sub>-ethylene-1,2-diamine-N,N')-(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium hexakis(μ<sub>2</sub>-selenido)-(tetraselenoxy)-tetra-tin(iv) </td> <td>[18-crown-6-K]<sub>4</sub>[Sn<sub>4</sub>Se<sub>10</sub>]·5en </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=22.003 <i>b</i>=18.966 <i>c</i>=24.392 <i>β</i>=97.548° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-41" class="reference"><a href="#cite_note-41"><span class="cite-bracket">[</span>41<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>dipotassium(+) bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)potassium(+)] hexaselenodistannate(4-) tetrakis(ethylenediamine) solvate (18-crown-6) </td> <td>K<sub>2</sub>[K(C<sub>12</sub>H<sub>24</sub>O<sub>6</sub>)]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>].4C<sub>2</sub>H<sub>8</sub>N<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=15.634 <i>b</i>=8.479 <i>c</i>=23.404 <i>β</i>=108.60° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-42" class="reference"><a href="#cite_note-42"><span class="cite-bracket">[</span>42<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium) tris(tetraselenido)-tin(iv) </td> <td>[K-(2,2,2-crypt)]<sub>2</sub>Sn(Se<sub>4</sub>)<sub>3</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=10.7088 <i>b</i>=12.9986 <i>c</i>=21.7865 <i>α</i>=86.299° <i>β</i>=81.598° <i>γ</i>=87.258° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:76_43-0" class="reference"><a href="#cite_note-:76-43"><span class="cite-bracket">[</span>43<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Ca(en)<sub>4</sub>Ca(en)<sub>3</sub>[Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> = 10.2708, <i>b</i> = 12.2739, <i>c</i> = 16.3103, <i>α</i> = 93.576°, <i>β</i> = 90.609°, <i>γ</i> = 109.269°, <i>Z</i> = 1 </td> <td>1936.09 </td> <td> </td> <td> </td> <td><sup id="cite_ref-44" class="reference"><a href="#cite_note-44"><span class="cite-bracket">[</span>44<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[V<sup>II</sup>(dien)<sub>2</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 9.7686 <i>b</i> 15.094 <i>c</i> 12.517 <i>β</i> 91.007° </td> <td> </td> <td> </td> <td>band gap 2.11 eV </td> <td><sup id="cite_ref-45" class="reference"><a href="#cite_note-45"><span class="cite-bracket">[</span>45<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(tetraethylenepentaminedi-ium octakis(μ-selenido)-bis(tetraethylenepentamine)-tetraselenolato-tetra-tin(iv)-di-vanadium(iii)) </td> <td>[H<sub>2</sub>tepa]<sub>0.5</sub>[V<sup>III</sup>(tepa)(μ-Sn<sub>2</sub>Se<sub>6</sub>)] </td> <td> </td> <td>orthorhombic </td> <td><i>Abm</i>2 </td> <td><i>a</i>=7.808 <i>b</i>=41.97 <i>c</i>=16.982 Z=8 </td> <td>5565 </td> <td>2.496 </td> <td> </td> <td><sup id="cite_ref-:28_46-0" class="reference"><a href="#cite_note-:28-46"><span class="cite-bracket">[</span>46<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tepa = tetraethylenepentamine <p>bis(Hydroxy-tetraethylenepentamine-chromium) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) monohydrate </p> </td> <td>[Cr(tepa)(OH)]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>·H<sub>2</sub>O </td> <td> </td> <td>orthorhombic </td> <td><i>Pbcn</i> </td> <td><i>a</i>=16.767 <i>b</i>=14.552 <i>c</i>=14.859 </td> <td> </td> <td> </td> <td>2.08 eV </td> <td><sup id="cite_ref-:26_47-0" class="reference"><a href="#cite_note-:26-47"><span class="cite-bracket">[</span>47<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>peha = pentaethylenehexamide <p>bis(Pentaethylenehexamine-chromium) dichloride 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) </p> </td> <td>[Cr(peha)]<sub>2</sub>(Sn<sub>2</sub>Se<sub>6</sub>)Cl<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=9.636 <i>b</i>=14.361 <i>c</i>=15.357 <i>β</i>=106.50° </td> <td> </td> <td> </td> <td>2.19 eV </td> <td><sup id="cite_ref-:26_47-1" class="reference"><a href="#cite_note-:26-47"><span class="cite-bracket">[</span>47<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>en = ethylenediamine, pip = piperazine <p>pentakis(tris(ethylenediamine)-chromium(iii)) bis(tetrakis(selenyl)-tin(iv)) heptakis(chloride) piperazine solvate </p> </td> <td>[Cr(en)<sub>3</sub>]<sub>2.5</sub>[SnSe<sub>4</sub>]·Cl<sub>3.5</sub>·(pip)<sub>0.5</sub>·1.5H<sub>2</sub>O </td> <td> </td> <td>trigonal </td> <td><i>R</i><span style="text-decoration:overline;">3</span><i>c</i> </td> <td>a=15.4035 <i>c</i> =61.487 </td> <td> </td> <td> </td> <td>band gap 2.23 eV;SnSe<sub>4</sub> tetrahedron </td> <td><sup id="cite_ref-:4_2-1" class="reference"><a href="#cite_note-:4-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[(μ<sub>3</sub>-Selenido)-(μ<sub>2</sub>-selenido)-bis(1,2-diaminoethane)-selenido-manganese-tin] </td> <td>SnSe<sub>3</sub>Mn(en)<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> =9.4565 <i>b</i> =11.2896 <i>c</i> =12.7937 <i>β</i> =103.765° Z=4 </td> <td> </td> <td>2.657 </td> <td>red </td> <td><sup id="cite_ref-:27_48-0" class="reference"><a href="#cite_note-:27-48"><span class="cite-bracket">[</span>48<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[(μ<sub>3</sub>-Selenido)-bis(μ<sub>2</sub>-selenido)-(1,2-diaminoethane)-manganese-tin] </td> <td>SnSe<sub>3</sub>Mn(en) </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=13.9290 <i>b</i>=7.5261 <i>c</i>=19.2572 Z=8 </td> <td>2018.7 </td> <td>3.097 </td> <td>red </td> <td><sup id="cite_ref-:27_48-1" class="reference"><a href="#cite_note-:27-48"><span class="cite-bracket">[</span>48<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(μ<sub>3</sub>-Selenido)-bis(μ<sub>2</sub>-selenido)-bis(1,2-diaminoethane)-di-manganese-tin] </td> <td>MnSnSe<sub>4</sub>Mn(en)<sub>2</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pnma</i> </td> <td><i>a</i>=13.1101 <i>b</i>=14.8267 <i>c</i>=7.9466 Z=4 </td> <td>1544.66 </td> <td>2.858 </td> <td>yellow </td> <td><sup id="cite_ref-:27_48-2" class="reference"><a href="#cite_note-:27-48"><span class="cite-bracket">[</span>48<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>pentaehtylenehexaamine </td> <td>[Mn(peha)][Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-17" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Mn(dien)<sub>2</sub>]Sn<sub>3</sub>Se<sub>7</sub>·0.5H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td> </td> <td> </td> <td> </td> <td>band gap 1.89 eV </td> <td><sup id="cite_ref-:1_4-18" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Mn(en)<sub>2.5</sub>(en-Me)<sub>0.5</sub>][Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-19" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin] </td> <td>[Mn(en)<sub>3</sub>][Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=12.2277 <i>b</i>=13.1904 <i>c</i>=15.9272 <i>β</i>=100.174° </td> <td> </td> <td> </td> <td>red </td> <td><sup id="cite_ref-:1_4-20" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:23_49-0" class="reference"><a href="#cite_note-:23-49"><span class="cite-bracket">[</span>49<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin monohydrate] </td> <td>[Mn(dien)<sub>2</sub>][Sn<sub>3</sub>Se<sub>7</sub>]∙H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=12.3987 <i>b</i>=13.3150 <i>c</i>=16.6672 <i>β</i>=96.378° </td> <td> </td> <td> </td> <td>red; band gap 2.04 eV </td> <td><sup id="cite_ref-:1_4-21" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:23_49-1" class="reference"><a href="#cite_note-:23-49"><span class="cite-bracket">[</span>49<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Mn(dien)<sub>2</sub>]Sn<sub>3</sub>Se<sub>7</sub><b>·</b>0.5H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 12.322 <i>b</i> 13.300 <i>c</i> 16.706 <i>β</i> 96.331° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:13_50-0" class="reference"><a href="#cite_note-:13-50"><span class="cite-bracket">[</span>50<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) bis(μ-selenido)-tetrakis(selenido)-di-tin </td> <td>[Mn(dien)<sub>2</sub>]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 12.677 <i>b</i> 9.585 <i>c</i> 15.595 <i>β</i> 102.49(3)° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:13_50-1" class="reference"><a href="#cite_note-:13-50"><span class="cite-bracket">[</span>50<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Mn(dien)<sub>2</sub>]MnSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>C</i>222<sub>1</sub> </td> <td><i>a</i>=9.002 <i>b</i>=17.761 <i>c</i>=12.967 </td> <td> </td> <td> </td> <td>band gap 2.25 eV </td> <td><sup id="cite_ref-:9_51-0" class="reference"><a href="#cite_note-:9-51"><span class="cite-bracket">[</span>51<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(ethane-1,2-diamine)-manganese(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] </td> <td>[Mn(en)<sub>3</sub>]Sn<sub>3</sub>Se<sub>6</sub>(Se<sub>2</sub>) </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 11.974 <i>b</i> 14.046 <i>c</i> 15.893, <i>β</i> 99.78° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-0" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-((bis(diethylenetriamine)-manganese(ii)) bis(μ-selenido)-manganese) </td> <td>[Mn(en)<sub>3</sub>][Sn(Se<sub>4</sub>)<sub>3</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.222 <i>b</i> 12.175 <i>c</i> 12.394, <i>α</i> 89.37° <i>β</i> 74.97° <i>γ</i> 75.66° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-1" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>en = ethylenediamine, hda = <i>N</i>-(2-hydroxyethyl)ethylenediamine) <p>bis(bis(ethylenediamine)-(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii)) bis(μ-selenido)-tetrakis(selenido)-di-tin </p> </td> <td>[Mn(en)<sub>2</sub>(hda)]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 9.1189 <i>b</i> 12.3968 <i>c</i> 17.515 <i>β</i> 97.010° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:12_53-0" class="reference"><a href="#cite_note-:12-53"><span class="cite-bracket">[</span>53<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin] </td> <td>[Mn(hda)<sub>2</sub>][SnMnSe<sub>4</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i> 9.4497 <i>b</i> 17.6025 <i>c</i> 13.1121 <i>β</i> 103.617° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:12_53-1" class="reference"><a href="#cite_note-:12-53"><span class="cite-bracket">[</span>53<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>dien = diethylenetriamine <p>catena-[bis(diethylenetriamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin] </p> </td> <td>[Mn(dien)<sub>2</sub>][SnMnSe<sub>4</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>C</i>222<sub>1</sub> </td> <td><i>a</i> 9.0169 <i>b</i> 17.740 <i>c</i> 12.9543 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:12_53-2" class="reference"><a href="#cite_note-:12-53"><span class="cite-bracket">[</span>53<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>heptakis(μ<sub>2</sub>-selenido)-(tetraethylenepentamine)-manganese(ii)-tri-tin(iv) </td> <td>Mn(tepa)·Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i>=12.533 <i>b</i>=13.709 <i>c</i>=13.989 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:73_54-0" class="reference"><a href="#cite_note-:73-54"><span class="cite-bracket">[</span>54<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(μ<sub>2</sub>-selenido)-bis(seleno)-bis(tetraethylenepentamine)-di-manganese(ii)-di-tin(iv) </td> <td>[Mn(tepa)]<sub>2</sub>(μ<sub>2</sub>-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td><i>a</i>=26.483 <i>b</i>=26.483 <i>c</i>=10.1423 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:73_54-1" class="reference"><a href="#cite_note-:73-54"><span class="cite-bracket">[</span>54<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>hexakis(μ<sub>2</sub>-selenido)-tetrakis(1,10-phenanthroline)-di-manganese-di-tin dihydrate </td> <td>{[Mn(phen)<sub>2</sub>]<sub>2</sub>(μ<sub>2</sub>-Sn<sub>2</sub>Se<sub>6</sub>)}·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 11.061 <i>b</i> 10.061 <i>c</i> 25.21 <i>β</i> 90.081° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:16_17-1" class="reference"><a href="#cite_note-:16-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-((μ<sub>3</sub>-selenido)-bis(μ<sub>2</sub>-selenido)-(1,10-phenanthroline)-manganese-tin) </td> <td>[Mn(phen)]<sub>2</sub>(μ<sub>4</sub>-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 9.721 <i>b</i> 10.257 <i>c</i> 10.346, <i>α</i> 118.24° <i>β</i> 112.53° <i>γ</i> 95.75° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:16_17-2" class="reference"><a href="#cite_note-:16-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>hexakis(μ-2-aminoethan-1-olato)-octakis(μ-selenido)-hepta-manganese-di-tin </td> <td>Mn<sub>7</sub>(ea)<sub>6</sub>(SnSe<sub>4</sub>)<sub>2</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pccn</i> </td> <td><i>a</i>=14.886 <i>b</i>=19.354 <i>c</i>=12.4314 Z=4 </td> <td>3581.5 </td> <td>2.993 </td> <td>orange </td> <td><sup id="cite_ref-55" class="reference"><a href="#cite_note-55"><span class="cite-bracket">[</span>55<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(pentakis(μ<sub>2</sub>-selenido)-bis(1,10-phenanthroline)-manganese-di-tin) </td> <td>[Mn(phen)<sub>2</sub>](Sn<sub>2</sub>Se<sub>5</sub>) </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i> 16.639 <i>b</i> 12.961 <i>c</i> 14.088<i>β</i> 117.91° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:16_17-3" class="reference"><a href="#cite_note-:16-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(tris(ethane-1,2-diamine)-manganese) icosakis(μ-selenido)-selenido-nona-tin chloride] </td> <td>(Bmmim)<sub>3</sub>[Mn(en)<sub>3</sub>]<sub>2</sub>[Sn<sub>9</sub>Se<sub>21</sub>]Cl </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=19.4488 <i>b</i>=19.5108 <i>c</i>=26.6148 <i>β</i>=109.587° </td> <td> </td> <td> </td> <td>red </td> <td><sup id="cite_ref-:23_49-2" class="reference"><a href="#cite_note-:23-49"><span class="cite-bracket">[</span>49<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[hexakis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) bis((N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) tetratriacontakis(selenido)-selenido-pentadeca-tin] </td> <td>(Bmmim)<sub>6</sub>[Mn(dien)<sub>2</sub>]<sub>2</sub>Sn<sub>15</sub>Se<sub>35</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=13.4256 <i>b</i>=29.904 <i>c</i>=19.5845 <i>β</i>=106.643° </td> <td> </td> <td> </td> <td>red </td> <td><sup id="cite_ref-:23_49-3" class="reference"><a href="#cite_note-:23-49"><span class="cite-bracket">[</span>49<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[hemikis(tris(ethane-1,2-diamine)-manganese) hemikis((N-methylethane-1,2-diamine)-bis(ethane-1,2-diamine)-mangnaese) heptakis(μ-selenido)-tri-tin] </td> <td>[Mn(en)<sub>2.5</sub>(en-Me)<sub>0.5</sub>][Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=12.1058 <i>b</i>=13.2204 <i>c</i>=18.2504 <i>β</i>=120.839° Z=4 </td> <td>2507.9 </td> <td>3.049 </td> <td>orange </td> <td><sup id="cite_ref-:36_56-0" class="reference"><a href="#cite_note-:36-56"><span class="cite-bracket">[</span>56<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(bis(4-Aminobutan-1-aminium) tetrakis(μ<sub>2</sub>-selenido)-manganese-tin) </td> <td>(1,4-dabH)<sub>2</sub>MnSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Fdd</i>2 </td> <td><i>a</i> =23.287 <i>b</i>=25.410 <i>c</i>=6.6053 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:51_57-0" class="reference"><a href="#cite_note-:51-57"><span class="cite-bracket">[</span>57<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(2,2'-bipyridine)-hexakis(μ-selenido)-di-tin-di-manganese </td> <td>{Mn(2,2′-bipy)<sub>2</sub>}<sub>2</sub>(<i>μ</i><sub>2</sub>-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>monoclinic </td> <td>P 2<sub>1</sub>/n </td> <td><i>a</i>=8.756 <i>b</i>=20.960 <i>c</i>=12.484 <i>β</i>=95.66° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:66_58-0" class="reference"><a href="#cite_note-:66-58"><span class="cite-bracket">[</span>58<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>hexakis(μ<sub>2</sub>-Selenido)-bis(1,4,8,11-tetraazacyclotetradecane)-di-manganese(ii)-di-tin </td> <td>{Mn(cyclam)}<sub>2</sub>(μ-Sn<sub>2</sub>Se<sub>6.15</sub>) </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=9.949 <i>b</i>=16.783 <i>c</i>=11.649 <i>β</i>=105.208° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:67_59-0" class="reference"><a href="#cite_note-:67-59"><span class="cite-bracket">[</span>59<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>hexakis(μ<sub>2</sub>-Selenido)-bis(2,2';6',2''-terpyridine)-di-manganese(ii)-di-tin </td> <td>{Mn(terpy)}<sub>2</sub>(μ-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=9.430 <i>b</i>=10.872 <i>c</i>=11.090 <i>α</i>=117.86° <i>β</i>=102.83° <i>γ</i>=103.22° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:67_59-1" class="reference"><a href="#cite_note-:67-59"><span class="cite-bracket">[</span>59<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tris(μ<sub>2</sub>-Selenido)-(2,2';6',2''-terpyridine)-manganese(ii)-tin </td> <td>{Mn(terpy)}<sub>2</sub>(μ-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=9.923 <i>b</i>=10.027 <i>c</i>=10.959 <i>α</i>=107.29° <i>β</i>=97.57° <i>γ</i>=115.10° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:67_59-2" class="reference"><a href="#cite_note-:67-59"><span class="cite-bracket">[</span>59<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(NMe<sub>4</sub>)<sub>2</sub>[MnSn<sub>4</sub>Se<sub>10</sub>] </td> <td> </td> <td>tetragonal </td> <td><i>I</i><span style="text-decoration:overline;">4</span> </td> <td>a=9.865 <i>c</i> =15.317 </td> <td> </td> <td> </td> <td>red </td> <td><sup id="cite_ref-:64_60-0" class="reference"><a href="#cite_note-:64-60"><span class="cite-bracket">[</span>60<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Li<sub>4</sub>MnSn<sub>2</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>Cc</i> </td> <td>a=18.126 b=7.221 c=10.470 <i>β</i>=93.43° Z=4 </td> <td>1403.2 </td> <td>4.132 </td> <td>orange </td> <td><sup id="cite_ref-61" class="reference"><a href="#cite_note-61"><span class="cite-bracket">[</span>61<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>DBN=1,5-diazabicyclo[4.3.0]non-5-ene </td> <td>[DBNH]<sub>2</sub>[MnSnSe<sub>4</sub>] </td> <td> </td> <td>tetragonal </td> <td><i>P</i>4<sub>2</sub>/<i>ncm</i> </td> <td>a=13.0305 <i>c</i> =6.6220 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:65_62-0" class="reference"><a href="#cite_note-:65-62"><span class="cite-bracket">[</span>62<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Fe(tatda)]Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td> </td> <td> </td> <td> </td> <td>1.93 eV </td> <td><sup id="cite_ref-:1_4-22" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-((bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-iron) </td> <td>[Fe(dien)<sub>2</sub>]FeSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>C</i>222<sub>1</sub> </td> <td><i>a</i> =8.974 <i>b</i> =17.755 <i>c</i> =12.967 </td> <td> </td> <td> </td> <td>band gap 2.21 eV </td> <td><sup id="cite_ref-:9_51-1" class="reference"><a href="#cite_note-:9-51"><span class="cite-bracket">[</span>51<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-tetraselenido-di-tin </td> <td>[Fe(dien)<sub>2</sub>]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=12.563 <i>b</i>=9.655 <i>c</i>=15.566 <i>β</i>=102.76° </td> <td> </td> <td> </td> <td>band gap 2.60 eV </td> <td><sup id="cite_ref-:9_51-2" class="reference"><a href="#cite_note-:9-51"><span class="cite-bracket">[</span>51<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(diethylenetriamine)-iron(ii)) ethane-1,2-diammonium bis(2-ammonioethyl)amine bis(bis(μ-selenido)-tetraselenido-di-tin) </td> <td>[H<sub>2</sub>en][H<sub>2</sub>dien][Fe(dien)<sub>2</sub>]<sub>2</sub>(Sn<sub>2</sub>Se<sub>6</sub>)<sub>2</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=8.727 <i>b</i>=12.794 <i>c</i>=14.918, <i>α</i>=66.09° <i>β</i>=84.06° <i>γ</i>=75.33° </td> <td> </td> <td> </td> <td>band gap 2.58 eV </td> <td><sup id="cite_ref-:9_51-3" class="reference"><a href="#cite_note-:9-51"><span class="cite-bracket">[</span>51<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(ethane-1,2-diamine)-iron(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] </td> <td>[Fe(en)<sub>3</sub>]Sn<sub>3</sub>Se<sub>6</sub>(Se<sub>2</sub>) </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> =11.950 <i>b</i> =14.083 <i>c</i> =17.995 <i>β</i> =120.25° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-2" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tris(ethane-1,2-diamine)-iron(ii) tris[tetraselanato]-tin </td> <td>[Fe(en)<sub>3</sub>][Sn(Se<sub>4</sub>)<sub>3</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.223 <i>b</i> 12.106 <i>c</i> 12.263, <i>α</i> 89.40° <i>β</i> 89.40° <i>γ</i> 75.45° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-3" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tatda = 3,6,9,12-tetraazatetradecane-1,14-diamine <p>catena-[(3,6,9,12-tetraazatetradecane-1,14-diamine)-iron heptakis(μ-selenido)-tri-tin] </p> </td> <td>[Fe(tatda)]Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 12.1067 <i>b</i> 13.3225 <i>c</i> 17.0827 <i>β</i> 96.978° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:13_50-2" class="reference"><a href="#cite_note-:13-50"><span class="cite-bracket">[</span>50<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>hexakis(μ<sub>2</sub>-selenido)-tetrakis(1,10-phenanthroline)-di-iron-di-tin </td> <td>[Fe(phen)<sub>2</sub>]<sub>2</sub>(μ<sub>2</sub>-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i> 26.192 <i>b</i> 11.248 <i>c</i> 17.843 <i>β</i> 98.816° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:16_17-4" class="reference"><a href="#cite_note-:16-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(bis(tris(1,10-phenanthroline)-iron) bis(μ<sub>3</sub>-selenido)-dodecakis(μ<sub>2</sub>-selenido)-hexa-tin hydrate) </td> <td>[Fe(phen)<sub>3</sub>](Sn<sub>3</sub>Se<sub>7</sub>)·1.25H<sub>2</sub>O </td> <td> </td> <td>trigonal </td> <td><i>R</i><span style="text-decoration:overline;">3</span><i>c</i> </td> <td>a=13.9483 <i>c</i> 75.476 </td> <td> </td> <td> </td> <td>band gap 1.97 eV </td> <td><sup id="cite_ref-:16_17-5" class="reference"><a href="#cite_note-:16-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bipy = bipyridine <p>catena-[nonakis(μ-selenido)-tetra-tin tris(2,2'-bipyridine)-iron dihydrate] </p> </td> <td>[Fe(bipy)<sub>3</sub>]Sn<sub>4</sub>Se<sub>9</sub>·2H<sub>2</sub>O </td> <td> </td> <td>trigonal </td> <td><i>R</i><span style="text-decoration:overline;">3</span><i>c</i> </td> <td>a=26.902 <i>c</i> 30.673 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:17_63-0" class="reference"><a href="#cite_note-:17-63"><span class="cite-bracket">[</span>63<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Fe(bipy)<sub>3</sub>]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>]<sub>2</sub>·bipy·2H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 27.055 <i>b</i> 13.391 <i>c</i> 24.756, <i>β</i> 103.88° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:17_63-1" class="reference"><a href="#cite_note-:17-63"><span class="cite-bracket">[</span>63<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>heptakis(μ-selenido)-(tetra-ethylenepentamine)-iron-tri-tin </td> <td>Sn<sub>3</sub>Se<sub>7</sub>Fe(tepa) </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i> 12.4958 <i>b</i> 13.7745 <i>c</i> 14.0233 </td> <td> </td> <td>3.112 </td> <td>black </td> <td><sup id="cite_ref-:38_22-2" class="reference"><a href="#cite_note-:38-22"><span class="cite-bracket">[</span>22<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis[tris(ethane-1,2-diamine)-iron] 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) </td> <td>[Fe(en)<sub>3</sub>]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i> =15.5062(9)Å <i>b</i>=11.8662 <i>c</i>=19.0966 </td> <td> </td> <td>2.146 </td> <td>red </td> <td><sup id="cite_ref-:38_22-3" class="reference"><a href="#cite_note-:38-22"><span class="cite-bracket">[</span>22<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>{CpFe(CO)<sub>2</sub>}<sub>3</sub>{CpFe(CO)}Sn<sub>3</sub>Se<sub>4</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 12.2066 <i>b</i> 12.584 <i>c</i> 13.0007, <i>α</i> 90.632° <i>β</i> 90.068° <i>γ</i> 120.836° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-64" class="reference"><a href="#cite_note-64"><span class="cite-bracket">[</span>64<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(NMe<sub>4</sub>)<sub>2</sub>[FeSn<sub>4</sub>Se<sub>10</sub>] </td> <td> </td> <td>tetragonal </td> <td><i>I</i><span style="text-decoration:overline;">4</span> </td> <td>a=9.878 <i>c</i>=15.345 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:64_60-1" class="reference"><a href="#cite_note-:64-60"><span class="cite-bracket">[</span>60<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Co(en)<sub>3</sub>]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td>a=15.640 b=11.564 c=18.742 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:28_46-1" class="reference"><a href="#cite_note-:28-46"><span class="cite-bracket">[</span>46<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Co(dien)<sub>2</sub>]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td>a=10.2224 b=14.5788 c=12.3921 <i>β</i>=91.237° </td> <td>1846.4 </td> <td> </td> <td>yellow; black with water, ultrasound turns yellow </td> <td><sup id="cite_ref-:7_65-0" class="reference"><a href="#cite_note-:7-65"><span class="cite-bracket">[</span>65<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:28_46-2" class="reference"><a href="#cite_note-:28-46"><span class="cite-bracket">[</span>46<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-66" class="reference"><a href="#cite_note-66"><span class="cite-bracket">[</span>66<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Co(en)(trien)]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 7.929 <i>b</i> 15.855 <i>c</i> 14.262 <i>β</i> 93.436° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:57_67-0" class="reference"><a href="#cite_note-:57-67"><span class="cite-bracket">[</span>67<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(tris(2,2'-bipyridine)-cobalt(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate </td> <td>[Co(2,2′-bipy)<sub>3</sub>]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>]<sub>2</sub>·(2,2′-bipy)·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=27.032 <i>b</i>=13.392 <i>c</i>=24.763 <i>β</i>=103.85° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:66_58-1" class="reference"><a href="#cite_note-:66-58"><span class="cite-bracket">[</span>58<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(ethylenediamine)-nickel hemikis(heptakis(μ-selenato)-selenato-tri-tin) hemikis(hexakis(μ-selenato)-selenato-tri-tin)] </td> <td>[Ni(en)<sub>3</sub>][Sn<sub>3</sub>Se<sub>6.5</sub>(Se<sub>2</sub>)<sub>0.5</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pca</i>2<sub>1</sub> </td> <td><i>a</i> =14.88 <i>b</i> =1.8872Å <i>c</i> =13.859 </td> <td> </td> <td> </td> <td>1.95 eV;chains of [Sn<sub>3</sub>Se<sub>7</sub>]<i><sub>n</sub></i><sup>2<i>n</i>–</sup> and [Sn<sub>3</sub>Se<sub>6</sub>(Se)<sub>2</sub>]<i><sub>n</sub></i><sup>2<i>n</i>–</sup> </td> <td><sup id="cite_ref-:4_2-2" class="reference"><a href="#cite_note-:4-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tris(ethylenediamine)-nickel(ii) tetrakis(μ-selanyl)-selanyl-di-tin </td> <td>[Ni(en)<sub>3</sub>][Sn<sub>2</sub>Se<sub>5</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=8.7998 <i>b</i>=10.0736 <i>c</i>=22.655 <i>β</i>=90.763° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-68" class="reference"><a href="#cite_note-68"><span class="cite-bracket">[</span>68<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Ni(en)<sub>3</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>orthorhombic </td> <td> </td> <td>a=15.288 b=11.937 c=19.239 </td> <td>3511.0 </td> <td> </td> <td> </td> <td><sup id="cite_ref-:28_46-3" class="reference"><a href="#cite_note-:28-46"><span class="cite-bracket">[</span>46<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(ethylenediamine)-nickel heptakis(μ-selenato)-tri-tin] </td> <td>[Ni(en)<sub>3</sub>][Sn<sub>3</sub>Se<sub>7</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=12.32 <i>b</i>=13.19 <i>c</i>=15.73 <i>β</i>=101.07° </td> <td> </td> <td> </td> <td>band gap 2.01 eV </td> <td><sup id="cite_ref-:4_2-3" class="reference"><a href="#cite_note-:4-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(1,2-diaminoethane)-nickel(ii) pentakis(μ-selenido)-bis(selenido)-tri-tin(iv)] </td> <td>[Ni(en)<sub>3</sub>]Sn<sub>3</sub>Se<sub>7.5</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pca</i>2<sub>1</sub> </td> <td><i>a</i> 14.869 <i>b</i> 11.888 <i>c</i> 13.860 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-4" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tris(ethane-1,2-diamine)-nickel tris[tetraselanato]-tin </td> <td>[Ni(en)<sub>3</sub>][Sn(Se<sub>4</sub>)<sub>3</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.104 <i>b</i> 12.048 <i>c</i> 12.107, <i>α</i> 89.52° <i>β</i> 75.44° <i>γ</i> 75.78° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-5" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>phen = 1,10-phenanthroline <p>tris(1,10-phenanthroline)-nickel(ii) heptakis(μ-selenato)-tri-tin(iv) sesquihydrate </p> </td> <td>[Ni(phen)<sub>3</sub>]Sn<sub>3</sub>Se<sub>7</sub>·1.5H<sub>2</sub>O </td> <td> </td> <td>trigonal </td> <td><i>R</i><span style="text-decoration:overline;">3</span> </td> <td>a=13.971 <i>c</i>=38.281 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-69" class="reference"><a href="#cite_note-69"><span class="cite-bracket">[</span>69<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[(Ni<sub>0.4</sub>Zn<sub>0.6</sub>)(en)<sub>6</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:7_65-1" class="reference"><a href="#cite_note-:7-65"><span class="cite-bracket">[</span>65<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) hemikis((μ<sub>2</sub>-triethylenetetramine)-bis(triethylenetetramine)-di-nickel) tris(μ<sub>3</sub>-selenido)-heptadecakis(μ<sub>2</sub>-selenido)-selenido-nona-tin) </td> <td>2D-(Bmmim)<sub>8</sub>[Ni<sub>2</sub>(teta)<sub>2</sub>(μ-teta)]Sn<sub>18</sub>Se<sub>42</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> =18.9764 <i>b</i>= 25.1081 <i>c</i> =20.5731 <i>β</i> =100.870° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:19_70-0" class="reference"><a href="#cite_note-:19-70"><span class="cite-bracket">[</span>70<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>teta = triethylenetetramine <p>(ethylenediamine)-(triethylenetetramine)-nickel(ii) (triethylenetetramine)-(N-(2-hydroxyethyl)ethylenediamine)-nickel(ii) hexakis(μ-selenido)-tetrakis(selenido)-tetra-tin </p> </td> <td>[Ni(teta)(en)][Ni(teta)(hda)][Sn<sub>4</sub>Se<sub>10</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 12.3191 <i>b</i> 17.7104 <i>c</i> 22.643 <i>β</i> 95.278° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:19_70-1" class="reference"><a href="#cite_note-:19-70"><span class="cite-bracket">[</span>70<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tepa=tetraethylenepentamine <p>catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) bis(chloro-(tetraethylenepentamine)-nickel) pentakis(μ<sub>3</sub>-selenido)-tricosakis(μ<sub>2</sub>-selenido)-(tetraethylenepentamine)-nickel-dodeca-tin) </p> </td> <td>2D-(Bmmim)<sub>4</sub>[Ni(tepa)Cl]<sub>2</sub>[Ni(tepa)Sn<sub>12</sub>Se<sub>28</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>Pn</i> </td> <td><i>a</i>=21.2230 <i>b</i>=13.4993 <i>c</i>=23.8715 <i>β</i> =112.461° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:19_70-2" class="reference"><a href="#cite_note-:19-70"><span class="cite-bracket">[</span>70<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Bmmim=1-butyl-2,3-dimethylimidazolium </td> <td>2D-(Bmmim)<sub>3</sub>[Ni(en)<sub>3</sub>]<sub>2</sub>[Sn<sub>9</sub>Se<sub>21</sub>]Cl </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 19.488 <i>b</i> 19.626 <i>c</i> 26.793 <i>β</i> 109.930° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:12_53-3" class="reference"><a href="#cite_note-:12-53"><span class="cite-bracket">[</span>53<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(bis(1-n-Butyl-2,3-dimethylimidazolium) bis(tris(propane-1,2-diamine)-nickel) bis(bis(μ<sub>3</sub>-selenido)-heptakis(μ<sub>2</sub>-selenido)-tetra-tin)) </td> <td>3D-(Bmmim)<sub>2</sub>[Ni(1,2-pda)<sub>3</sub>]Sn<sub>8</sub>Se<sub>18</sub> </td> <td> </td> <td>trigonal </td> <td><i>R</i><span style="text-decoration:overline;">3</span><i>c</i> </td> <td>a=27.7913 <i>c</i> 47.4281 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:19_70-3" class="reference"><a href="#cite_note-:19-70"><span class="cite-bracket">[</span>70<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-nickel sesquikis(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) hemikis(2-amino-N-(2-aminoethyl)ethylammonium) octadecakis(μ-selenido)-octa-tin] </td> <td>2D-(Bmmim)<sub>2</sub>[Ni(teta)(en)][Sn<sub>3</sub>Se<sub>7</sub>]<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=31.088 <i>b</i>=10.5393 <i>c</i>=19.9712 <i>β</i>=99.966° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:22_71-0" class="reference"><a href="#cite_note-:22-71"><span class="cite-bracket">[</span>71<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-(ethane-1,2-diamine)-nickel bis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) tridecakis(μ-selenido)-selenido-hexa-tin] </td> <td>3D-(Bmmim)<sub>1.5</sub>(dienH)<sub>0.5</sub>Ni(dien)<sub>2</sub>[Sn<sub>4</sub>Se<sub>9</sub>]<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=24.3753 <i>b</i>=13.3778 <i>c</i>=17.7885 <i>β</i>=93.949° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:22_71-1" class="reference"><a href="#cite_note-:22-71"><span class="cite-bracket">[</span>71<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Ni(tren)(en)]SnSe<sub>3</sub>∙H<sub>2</sub>O </td> <td>638.64 </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td>a=12.8150 b=10.0094 <p>c=15.6626 <i>β</i>=???? Z=4 </p> </td> <td>1885.8 </td> <td> </td> <td>band gap </td> <td><sup id="cite_ref-72" class="reference"><a href="#cite_note-72"><span class="cite-bracket">[</span>72<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin dihydrate </td> <td>[Ni(tren)(en)]<sub>2</sub>[Sn<sub>2</sub>S<sub>6</sub>]·2H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 12.7041 <i>b</i> 9.8000 <i>c</i> 15.3989 <i>β</i> 108.843° </td> <td> </td> <td> </td> <td>3.23 eV </td> <td><sup id="cite_ref-:44_73-0" class="reference"><a href="#cite_note-:44-73"><span class="cite-bracket">[</span>73<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin hexahydrate </td> <td>[Ni(tren)(en)]<sub>2</sub>[Sn<sub>2</sub>S<sub>6</sub>]·6H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 12.5580 <i>b</i> 9.7089 <i>c</i> 16.0359 <i>β</i> 91.827° </td> <td> </td> <td> </td> <td>3.16 eV </td> <td><sup id="cite_ref-:44_73-1" class="reference"><a href="#cite_note-:44-73"><span class="cite-bracket">[</span>73<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin trihydrate </td> <td>[Ni(tren)(1,2-dach)]<sub>2</sub>[Sn<sub>2</sub>S<sub>6</sub>]·3H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 9.8121 <i>b</i> 10.0080 <i>c</i> 12.422, <i>α</i> 86.38° <i>β</i> 79.65° <i>γ</i> 65.71° </td> <td> </td> <td> </td> <td>3.43 eV </td> <td><sup id="cite_ref-:44_73-2" class="reference"><a href="#cite_note-:44-73"><span class="cite-bracket">[</span>73<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate </td> <td>[Ni(tren)(1,2-dach)]<sub>2</sub>[Sn<sub>2</sub>S<sub>6</sub>]·4H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 10.7119 <i>b</i> 19.0797 <i>c</i> 11.1005 <i>β</i> 104.803° </td> <td> </td> <td> </td> <td>3.29 eV </td> <td><sup id="cite_ref-:44_73-3" class="reference"><a href="#cite_note-:44-73"><span class="cite-bracket">[</span>73<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((tris(2-aminoethyl)amine)-(propane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate </td> <td>[Ni(tren)(1,2-dap)]<sub>2</sub>[Sn<sub>2</sub>S<sub>6</sub>]·4H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/c </td> <td><i>a</i> 14.3925 <i>b</i> 15.1550 <i>c</i> 18.9307 <i>β</i> 99.108° </td> <td> </td> <td> </td> <td>3.32 eV </td> <td><sup id="cite_ref-:44_73-4" class="reference"><a href="#cite_note-:44-73"><span class="cite-bracket">[</span>73<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis((tris(2-aminoethyl)amine)-(2-(aminomethyl)pyridine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin decahydrate </td> <td>[Ni(tren)(2amp)]<sub>2</sub>[Sn<sub>2</sub>S<sub>6</sub>]·10H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 12.1933 <i>b</i> 13.4025 <i>c</i> 14.8920 <i>β</i> 103.090° </td> <td> </td> <td> </td> <td>3.28 eV </td> <td><sup id="cite_ref-:44_73-5" class="reference"><a href="#cite_note-:44-73"><span class="cite-bracket">[</span>73<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>L<sub>1</sub> = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane </td> <td>[Ni(L<sub>1</sub>)][Ni(L<sub>1</sub>)Sn<sub>2</sub>S<sub>6</sub>]<i><sub>n</sub></i><b>·</b>2H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 11.6481 <i>b</i> 14.4268 <i>c</i> 10.8450 <i>β</i> 95.449° </td> <td> </td> <td> </td> <td>brown </td> <td><sup id="cite_ref-:46_74-0" class="reference"><a href="#cite_note-:46-74"><span class="cite-bracket">[</span>74<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>L<sub>2</sub> = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane </td> <td>[Ni(L<sub>2</sub>)]<sub>2</sub>[Sn<sub>2</sub>S<sub>6</sub>]<b>·</b>4H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 9.1562 <i>b</i> 10.3705 <i>c</i> 12.2897 <i>α</i> 66.761° <i>β</i> 85.350° <i>γ</i> 81.308° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:46_74-1" class="reference"><a href="#cite_note-:46-74"><span class="cite-bracket">[</span>74<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>(μ<sub>2</sub>-triethylenetetramine)-bis(triethylenetetramine)-di-nickel(ii) tetrachloride dihydrate </td> <td>[Ni<sub>2</sub>(trien)<sub>2</sub>(μ-trien)]Cl<sub>4</sub><b>·</b>2H<sub>2</sub>O </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i> 13.737 <i>b</i> 13.089 <i>c</i> 18.193 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:57_67-1" class="reference"><a href="#cite_note-:57-67"><span class="cite-bracket">[</span>67<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(tris(2,2'-bipyridine)-nickel(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate </td> <td>[Ni(2,2′-bipy)<sub>3</sub>]<sub>2</sub>[Sn<sub>3</sub>Se<sub>7</sub>]<sub>2</sub>·(2,2′-bipy)·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td>P 2<sub>1</sub>/c </td> <td><i>a</i>=26.999 <i>b</i>=13.383 <i>c</i>=24.714 <i>β</i>=103.89° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:66_58-2" class="reference"><a href="#cite_note-:66-58"><span class="cite-bracket">[</span>58<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cu<sub>2</sub>SnSe<sub>4</sub> </td> <td> </td> <td> </td> <td><i>F</i>3<i>m</i> </td> <td> </td> <td> </td> <td> </td> <td>thermoelectric </td> <td><sup id="cite_ref-:52_75-0" class="reference"><a href="#cite_note-:52-75"><span class="cite-bracket">[</span>75<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(1,4-dabH<sub>2</sub>)Cu<sub>2</sub>SnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>4<sub>2</sub>/n </td> <td><i>a</i>=14.956 <i>b</i>=14.956 <i>c</i>=12.017 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:51_57-1" class="reference"><a href="#cite_note-:51-57"><span class="cite-bracket">[</span>57<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>6</sub>Cu<sub>8</sub>Sn<sub>3</sub>Se<sub>13</sub> </td> <td> </td> <td>cubic </td> <td><i>Fm</i><span style="text-decoration:overline;">3</span><i>c</i> </td> <td><i>a</i> =18.4754 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-xlink.rsc.org_76-0" class="reference"><a href="#cite_note-xlink.rsc.org-76"><span class="cite-bracket">[</span>76<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Cu<sub>2</sub>SnSe<sub>5</sub>][Mn(Hen)<sub>2</sub>(en)] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 9.640 <i>b</i> 21.04 <i>c</i> 10.611 <i>β</i> 100.72° </td> <td> </td> <td> </td> <td>1.49 eV </td> <td><sup id="cite_ref-77" class="reference"><a href="#cite_note-77"><span class="cite-bracket">[</span>77<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[(Mn<sub>1.67</sub>Zn<sub>0.33</sub>)(en)<sub>6</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:7_65-2" class="reference"><a href="#cite_note-:7-65"><span class="cite-bracket">[</span>65<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>2</sub>Cu<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td>C2/c </td> <td>Z=8 </td> <td> </td> <td> </td> <td>black; band gap 1.04 eV </td> <td><sup id="cite_ref-:50_78-0" class="reference"><a href="#cite_note-:50-78"><span class="cite-bracket">[</span>78<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>Copper zinc tin selenide </td> <td>Cu<sub>2</sub>ZnSnSe<sub>4</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td>black; photovoltaic 11.6% efficient </td> <td><sup id="cite_ref-:5_29-2" class="reference"><a href="#cite_note-:5-29"><span class="cite-bracket">[</span>29<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[tris(ethane-1,2-diamine)-zinc(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] </td> <td>[Zn(en)<sub>3</sub>]Sn<sub>3</sub>Se<sub>6</sub>(Se<sub>2</sub>) </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 11.949 <i>b</i> 14.060 <i>c</i> 15.794 <i>β</i> 100.39° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-6" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tris(ethane-1,2-diamine)-zinc(ii) tris[tetraselanato]-tin </td> <td>[Zn(en)<sub>3</sub>][Sn(Se<sub>4</sub>)<sub>3</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.156 <i>b</i> 12.096 <i>c</i> 12.109, <i>α</i> 89.64° <i>β</i> 75.49° <i>γ</i> 75.87° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:11_52-7" class="reference"><a href="#cite_note-:11-52"><span class="cite-bracket">[</span>52<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Zn<sub>2</sub>(en)<sub>2</sub>(μ<sub>4</sub>-SnSe<sub>4</sub>) </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td><i>a</i> =7.8032 <i>c</i> =31.528 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:12_53-4" class="reference"><a href="#cite_note-:12-53"><span class="cite-bracket">[</span>53<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(μ-selenido)-bis(selenido)-bis(N,N-bis(2-aminoethyl)ethane-1,2-diamine)-di-tin(iv)-di-zinc(ii) </td> <td>{Zn(tren)}<sub>2</sub>(<i>μ</i>-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/c </td> <td><i>a</i> 12.414 <i>b</i> 9.846 <i>c</i> 23.970° <i>β</i> 102.395° </td> <td>2861.5 </td> <td> </td> <td>band gap 2.38 eV </td> <td><sup id="cite_ref-:14_79-0" class="reference"><a href="#cite_note-:14-79"><span class="cite-bracket">[</span>79<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(μ-selenido)-bis(selenido)-bis(bis(2-(2-aminoethyl)aminoethyl)amine)-di-tin(iv)-di-zinc(ii) </td> <td>{Zn(tepa)}<sub>2</sub>(<i>μ</i>-Sn<sub>2</sub>Se<sub>6</sub>) </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td>a=26.6205 <i>c</i> =10.0533 </td> <td>7124.3 </td> <td> </td> <td>band gap 2.31 eV </td> <td><sup id="cite_ref-:14_79-1" class="reference"><a href="#cite_note-:14-79"><span class="cite-bracket">[</span>79<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(dimethylammonium) octakis(μ-selenido)-tri-tin(iv)-zinc(ii)] </td> <td>[(Me)<sub>2</sub>NH<sub>2</sub>]<sub>2</sub>ZnSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2 </td> <td><i>a</i>=10.961 <i>b</i>=11.056 <i>c</i>=9.683 <i>β</i>=105.17° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:54_80-0" class="reference"><a href="#cite_note-:54-80"><span class="cite-bracket">[</span>80<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(Me<sub>4</sub>N)<sub>2</sub>Zn[Sn<sub>4</sub>Se<sub>10</sub>] </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-81" class="reference"><a href="#cite_note-81"><span class="cite-bracket">[</span>81<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>DBN=1,5-diazabicyclo[4.3.0]non-5-ene </td> <td>[DBNH]<sub>2</sub>[ZnSnSe<sub>4</sub>] </td> <td> </td> <td>tetragonal </td> <td><i>P</i>4<sub>2</sub>/<i>ncm</i> </td> <td>a=13.033 <i>c</i> 6.548 </td> <td> </td> <td> </td> <td>band gap 2.42 eV </td> <td><sup id="cite_ref-:65_62-1" class="reference"><a href="#cite_note-:65-62"><span class="cite-bracket">[</span>62<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>2</sub>ZnSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub> </td> <td><i>a</i> 7.639 <i>b</i> 12.400 <i>c</i> 18.384 <i>β</i> 98.13° </td> <td> </td> <td> </td> <td>band gap 2.10 eV </td> <td><sup id="cite_ref-82" class="reference"><a href="#cite_note-82"><span class="cite-bracket">[</span>82<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cu<sub>2</sub>ZnSnSe<sub>4</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:52_75-1" class="reference"><a href="#cite_note-:52-75"><span class="cite-bracket">[</span>75<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[NH<sub>4</sub>]<sub>2</sub>Ga<sub>4</sub>Se<sub>8</sub>Sn<sub>4</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 7.582 <i>b</i> 12.501 <i>c</i> 18.377 <i>β</i> 96.43° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-83" class="reference"><a href="#cite_note-83"><span class="cite-bracket">[</span>83<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(1-ethylpyridinium hexakis(μ-selenido)-gallium-di-tin hydrate) </td> <td>H<sub>3</sub>CCH<sub>2</sub>NC<sub>5</sub>H<sub>5</sub>GaSn<sub>2</sub>Se<sub>6</sub> ∙ 0.25H<sub>2</sub>O </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td><i>a</i>=26.401 <i>c</i> =10.464 </td> <td> </td> <td> </td> <td>orange </td> <td><sup id="cite_ref-:20_84-0" class="reference"><a href="#cite_note-:20-84"><span class="cite-bracket">[</span>84<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>x~0.25 </td> <td>Na<sub>2−<i>x</i></sub>Ga<sub>2−<i>x</i></sub>Sn<sub>1+<i>x</i></sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2 </td> <td><i>a</i>=13.308 <i>b</i>=7.594 <i>c</i>=13.842 <i>β</i>=118.730° </td> <td>1226.7 </td> <td> </td> <td> </td> <td><sup id="cite_ref-:70_85-0" class="reference"><a href="#cite_note-:70-85"><span class="cite-bracket">[</span>85<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>3</sub>Ga<sub>6</sub>Sn<sub>6</sub>Se<sub>12</sub> </td> <td> </td> <td>cubic </td> <td><i>Pa</i><span style="text-decoration:overline;">3</span> </td> <td><i>a</i>=13.5555 Z=12 </td> <td>2490.8 </td> <td>4.347 </td> <td>colourless </td> <td><sup id="cite_ref-:42_86-0" class="reference"><a href="#cite_note-:42-86"><span class="cite-bracket">[</span>86<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>KGaSnSe<sub>4</sub> </td> <td> </td> <td>cubic </td> <td><i>Pa</i><span style="text-decoration:overline;">3</span> </td> <td>a=13.5555 Z=12 </td> <td>2490.8 </td> <td>4.347 </td> <td>orange </td> <td><sup id="cite_ref-:42_86-1" class="reference"><a href="#cite_note-:42-86"><span class="cite-bracket">[</span>86<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[(TEPA)Mn]<sup>2+</sup><sub>4</sub>[Sn<sub>4</sub>Ga<sub>4</sub>Zn<sub>2</sub>Se<sub>20</sub>]<sup>8−</sup> </td> <td> </td> <td>tetragonal </td> <td><i>P</i><span style="text-decoration:overline;">4</span><i>b</i>2 </td> <td>a=17.4951 <i>c</i> 13.5849 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-87" class="reference"><a href="#cite_note-87"><span class="cite-bracket">[</span>87<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(Et<sub>4</sub>N)<sub>2</sub>[Sn<sub>6</sub>Se<sub>10</sub>Br<sub>6</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> = 14.0826 <i>b</i> = 14.1904 <i>c</i> = 24.277 <i>β</i> = 92.809° Z = 4 </td> <td>4845.6 </td> <td> </td> <td> </td> <td><sup id="cite_ref-88" class="reference"><a href="#cite_note-88"><span class="cite-bracket">[</span>88<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>2</sub>Sn<sub>2</sub>Se<sub>5</sub> </td> <td> </td> <td>monoclinic </td> <td>C2/c </td> <td>a=11.555 b=8.478 c=12.030 <i>β</i>=108.60 Z=4 </td> <td>1117 </td> <td>4.78 </td> <td>black; oxygen sensitive </td> <td><sup id="cite_ref-89" class="reference"><a href="#cite_note-89"><span class="cite-bracket">[</span>89<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>4</sub>Sn<sub>4</sub>Se<sub>10</sub>·1.5H<sub>2</sub>O </td> <td> </td> <td> </td> <td><i>R</i><span style="text-decoration:overline;">3</span> </td> <td><i>a</i> 15.539 <i>c</i> 21.373 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:69_39-1" class="reference"><a href="#cite_note-:69-39"><span class="cite-bracket">[</span>39<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>2</sub>Cu<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td>C2/c </td> <td>Z=8 </td> <td> </td> <td> </td> <td>black; band gap 1.04 eV </td> <td><sup id="cite_ref-:50_78-1" class="reference"><a href="#cite_note-:50-78"><span class="cite-bracket">[</span>78<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>RbGaSnSe<sub>4</sub> </td> <td> </td> <td>cubic </td> <td><i>Pa</i><span style="text-decoration:overline;">3</span> </td> <td>a=13.7200 </td> <td>2582.63 </td> <td>4.550 </td> <td>orange </td> <td><sup id="cite_ref-:42_86-2" class="reference"><a href="#cite_note-:42-86"><span class="cite-bracket">[</span>86<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>2</sub>Sn<sub>4</sub>Se<sub>9</sub>-H<sub>2</sub>O </td> <td> </td> <td>orthorhombic </td> <td><i>Pnma</i> </td> <td><i>a</i>=13.298 <i>b</i>=12.418 <i>c</i>=12.563 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:18_90-0" class="reference"><a href="#cite_note-:18-90"><span class="cite-bracket">[</span>90<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>2</sub>MnSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub> </td> <td><i>a</i> 7.7864 <i>b</i> 12.6343 <i>c</i> 18.4878 <i>β</i> 95.810° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:58_91-0" class="reference"><a href="#cite_note-:58-91"><span class="cite-bracket">[</span>91<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>2</sub>MnSnSe<sub>4</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=8.6015 <i>b</i>=10.956 <i>c</i>=10.675 <i>β</i>=90° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:68_92-0" class="reference"><a href="#cite_note-:68-92"><span class="cite-bracket">[</span>92<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>4</sub>Cu<sub>8</sub>Sn<sub>3</sub>S<sub>12</sub> </td> <td> </td> <td>cubic </td> <td><i>Fm</i><span style="text-decoration:overline;">3</span><i>c</i> </td> <td><i>a</i>=18.0851 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:45_93-0" class="reference"><a href="#cite_note-:45-93"><span class="cite-bracket">[</span>93<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(H<sub>3</sub>O)RbCu<sub>6</sub>Sn<sub>2</sub>S<sub>8</sub> </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4/<i>m</i> </td> <td>a=14.8834 <i>c</i>=7.6466 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:45_93-1" class="reference"><a href="#cite_note-:45-93"><span class="cite-bracket">[</span>93<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>SrZnSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Fdd2</i> </td> <td><i>a</i> 21.6984 <i>b</i> 21.873 <i>c</i> 13.1140 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-94" class="reference"><a href="#cite_note-94"><span class="cite-bracket">[</span>94<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-yttrium] </td> <td>[Y<sub>2</sub>(tepa)<sub>2</sub>(μ-OH)<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=12.4190 <i>b</i>=13.6062 <i>c</i>=20.6569 Z=8 </td> <td> </td> <td>2.467 </td> <td>orange </td> <td><sup id="cite_ref-:33_95-0" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(μ<sub>2</sub>-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-yttrium) hexakis(μ<sub>2</sub>-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate </td> <td>[Y<sub>2</sub>(tepa)<sub>2</sub>(μ<sub>2</sub>-OH)<sub>2</sub>Cl<sub>2</sub>]<sub>2</sub>[Sn<sub>4</sub>Se<sub>10</sub>]·4H<sub>2</sub>O </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td><i>a</i>=28.24 <i>c</i>=10.940 </td> <td> </td> <td>2.025 </td> <td>yellow </td> <td><sup id="cite_ref-:33_95-1" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Ru(bpy)<sub>3</sub>[Sn<sub>4</sub>Se<sub>9</sub>] </td> <td>1755.02 </td> <td>trigonal </td> <td><i>R</i>3<i>c</i> </td> <td>a=27.240 <i>c</i>=31.01 Z=18 </td> <td>19927 </td> <td>2.632 </td> <td>dark red </td> <td><sup id="cite_ref-96" class="reference"><a href="#cite_note-96"><span class="cite-bracket">[</span>96<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td><i>β-</i>Ag<sub>8</sub>SnSe<sub>6</sub> </td> <td> </td> <td> </td> <td><i>Pmn</i>2<sub>1</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-23" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[NH<sub>4</sub>]<sub>3</sub>AgSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>tetragonal </td> <td><i>P</i>4/<i>nbm</i> </td> <td>a=8.2155 <i>c</i>=13.413 </td> <td> </td> <td> </td> <td>thermochromic: gold-darkred-gold </td> <td><sup id="cite_ref-:1_4-24" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:54_80-1" class="reference"><a href="#cite_note-:54-80"><span class="cite-bracket">[</span>80<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[NH<sub>4</sub>]<sub>4</sub>Ag<sub>12</sub>Sn<sub>7</sub>Se<sub>22</sub> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td>a=52.634 b=6.8175 c=13.5176 β=99.955 Z=4 </td> <td>4959.1 </td> <td>5.270 </td> <td>black; band gap 1.21 eV </td> <td><sup id="cite_ref-:1_4-25" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-97" class="reference"><a href="#cite_note-97"><span class="cite-bracket">[</span>97<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[(Me)<sub>2</sub>NH<sub>2</sub>]<sub>0.75</sub>[Ag<sub>1.25</sub>SnSe<sub>3</sub>] </td> <td> </td> <td>tetragonal </td> <td><i>P</i><span style="text-decoration:overline;">4</span>2<sub>1</sub>m </td> <td>a=13.998 c=8.685 Z=8 </td> <td>1701.9 </td> <td>4.403 </td> <td>dark red; band gap 1.85 eV </td> <td><sup id="cite_ref-:1_4-26" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-98" class="reference"><a href="#cite_note-98"><span class="cite-bracket">[</span>98<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[CH<sub>3</sub>NH<sub>3</sub>]<sub>2</sub>[H<sub>3</sub>O]Ag<sub>5</sub>Sn<sub>4</sub>Se<sub>12</sub>·C<sub>2</sub>H<sub>5</sub>OH </td> <td> </td> <td>tetragonal </td> <td><i>P</i><span style="text-decoration:overline;">4</span>2<sub>1</sub>m </td> <td>a=13.6350 <i>c</i> 9.1491 Z=8 </td> <td> </td> <td> </td> <td>band gap 1.80 eV </td> <td><sup id="cite_ref-:1_4-27" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:54_80-2" class="reference"><a href="#cite_note-:54-80"><span class="cite-bracket">[</span>80<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(methylammonium) dimethylammonium dodecakis(μ-selenido)-penta-silver-tetra-tin] </td> <td>[NH<sub>3</sub>CH<sub>3</sub>]<sub>0.5</sub>[NH<sub>2</sub>(CH<sub>3</sub>)<sub>2</sub>]<sub>0.25</sub>Ag<sub>1.25</sub>SnSe<sub>3</sub> </td> <td> </td> <td>tetragonal </td> <td><i>P</i><span style="text-decoration:overline;">4</span>2<sub>1</sub>m </td> <td><i>b</i> =13.7193 <i>c</i> 9.0964 </td> <td> </td> <td>4.019 </td> <td> </td> <td><sup id="cite_ref-99" class="reference"><a href="#cite_note-99"><span class="cite-bracket">[</span>99<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[bmmim]<sub>7</sub>[AgSn<sub>12</sub>Se<sub>28</sub>] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td> </td> <td> </td> <td> </td> <td>band gap 2.2 eV </td> <td><sup id="cite_ref-:1_4-28" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>heptakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ<sub>3</sub>-selenido)-hexacosakis(μ<sub>2</sub>-selenido)-dodeca-tin-silver </td> <td>[Mmpmim]<sub>7</sub>Ag<sub>5</sub>Sn<sub>4</sub>Se<sub>12</sub>∙3H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.8983 <i>b</i> 13.5554 <i>c</i> 23.091 <i>α</i> 88.904° <i>β</i> 86.700° <i>γ</i> 68.230° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:74_11-5" class="reference"><a href="#cite_note-:74-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[N<sup>1</sup>-(2-azaniumylethyl)ethane-1,2-bis(aminium) dodeca-selenium-tetra-tin-penta-silver trihydrate] </td> <td>[H<sub>3</sub>dien][Ag<sub>5</sub>Sn<sub>4</sub>Se<sub>12</sub>]∙3H<sub>2</sub>O </td> <td> </td> <td> </td> <td><i>P</i><span style="text-decoration:overline;">4</span>2<sub>1</sub> </td> <td><i>a</i> =14.2623 <i>b</i> =14.2623 <i>c</i> =9.3022 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-100" class="reference"><a href="#cite_note-100"><span class="cite-bracket">[</span>100<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>2</sub>Ag<sub>2</sub>SnSe<sub>4</sub> </td> <td> </td> <td> </td> <td><i>P</i>2/<i>c</i> </td> <td> </td> <td> </td> <td> </td> <td>band gap 1.8 eV </td> <td><sup id="cite_ref-:1_4-29" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>2</sub>Ag<sub>2</sub>Sn<sub>2</sub>Se6 </td> <td> </td> <td> </td> <td><i>P</i>4/<i>mmc</i> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-30" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>3</sub>AgSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td> </td> <td><i>P</i>4/<i>nbm</i> </td> <td> </td> <td> </td> <td> </td> <td>band gap 1.8 eV </td> <td><sup id="cite_ref-:1_4-31" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Mn(NH<sub>3</sub>)<sub>6</sub>][Ag<sub>4</sub>Mn<sub>4</sub>Sn<sub>3</sub>Se<sub>13</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>F</i><span style="text-decoration:overline;">4</span>3<i>c</i> </td> <td><i>a</i> 19.1263Å <i>b</i> 19.1263Å <i>c</i> 19.1263 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:39_101-0" class="reference"><a href="#cite_note-:39-101"><span class="cite-bracket">[</span>101<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(2-aminoethylammonium bis(μ<sub>4</sub>-sulfido)-bis(μ<sub>3</sub>-sulfido)-tin-di-copper-silver) </td> <td>[enH][Cu<sub>2</sub>AgSnS<sub>4</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pnma</i> </td> <td><i>a</i>=19.726 <i>b</i>=7.8544 <i>c</i>=6.5083 Z=4 </td> <td>1008.35 </td> <td>3.577 </td> <td>red </td> <td><sup id="cite_ref-102" class="reference"><a href="#cite_note-102"><span class="cite-bracket">[</span>102<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Zn(NH<sub>3</sub>)<sub>6</sub>][Ag<sub>4</sub>Zn<sub>4</sub>Sn<sub>3</sub>Se<sub>13</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>F</i><span style="text-decoration:overline;">4</span>3<i>c</i> </td> <td><i>a</i>=18.9679 <i>b</i>=18.9679 <i>c</i>=18.9679 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:39_101-1" class="reference"><a href="#cite_note-:39-101"><span class="cite-bracket">[</span>101<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>(1,4-dabH<sub>2</sub>)Cu<sub>1.72</sub>Ag<sub>0.28</sub>SnSe<sub>4</sub> </td> <td> </td> <td>tetragonal </td> <td><i>P</i>4<sub>2</sub>/<i>n</i> </td> <td><i>a</i>=14.990 <i>c</i>=12.059 </td> <td> </td> <td> </td> <td>band gap 2.43 eV </td> <td><sup id="cite_ref-103" class="reference"><a href="#cite_note-103"><span class="cite-bracket">[</span>103<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Rb<sub>3</sub>AgSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td> </td> <td><i>P</i>4/<i>nbm</i> </td> <td> </td> <td> </td> <td> </td> <td>band gap 1.8 eV </td> <td><sup id="cite_ref-:1_4-32" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Li<sub>6.4</sub>Cd<sub>4.8</sub>Sn<sub>4</sub>Se<sub>16</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pna</i>2<sub>1</sub> </td> <td><i>a</i>=14.400 <i>b</i>=8.399 <i>c</i>=6.787 </td> <td> </td> <td> </td> <td>band gap 1.95 eV </td> <td><sup id="cite_ref-104" class="reference"><a href="#cite_note-104"><span class="cite-bracket">[</span>104<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ<sub>3</sub>-diselenido)-undecakis(μ<sub>2</sub>-selenido)-tri-cadmium-tetra-tin </td> <td>[DBNH]<sub>4</sub>[Cd<sub>3</sub>Sn<sub>4</sub>Se<sub>11</sub>(Se<sub>2</sub>)<sub>2</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=22.236 <i>b</i>=12.623 <i>c</i>=21.756 <i>β</i>=109.91° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:40_105-0" class="reference"><a href="#cite_note-:40-105"><span class="cite-bracket">[</span>105<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cd(tren)SnSe<sub>3</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td>a=7.752 b=8.128 c=12.467, α=97.299° β=103.639° γ=107.325° Z=2 </td> <td>712.1 </td> <td>2.865 </td> <td> </td> <td><sup id="cite_ref-106" class="reference"><a href="#cite_note-106"><span class="cite-bracket">[</span>106<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>2</sub>CdSnSe<sub>4</sub> </td> <td>625.16 </td> <td>tetragonal </td> <td><i>I</i><span style="text-decoration:overline;">4</span>2<i>m</i> </td> <td>a=8.084 c=6.920 </td> <td>452.24 </td> <td> </td> <td>photocatalyst </td> <td><sup id="cite_ref-107" class="reference"><a href="#cite_note-107"><span class="cite-bracket">[</span>107<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cu<sub>2</sub>CdSnSe<sub>4</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:52_75-2" class="reference"><a href="#cite_note-:52-75"><span class="cite-bracket">[</span>75<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(1-ethylpyridinium hexakis(μ-selenido)-indium-di-tin hydrate) </td> <td>CH<sub>3</sub>CH<sub>2</sub>NC<sub>5</sub>H<sub>5</sub>InSn<sub>2</sub>Se<sub>6</sub> ∙ 0.25H<sub>2</sub>O </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td>a=26.946 <i>c</i> =10.283 </td> <td> </td> <td> </td> <td>orange </td> <td><sup id="cite_ref-:20_84-1" class="reference"><a href="#cite_note-:20-84"><span class="cite-bracket">[</span>84<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[NH<sub>4</sub>]<sub>2</sub>[In<sub>2</sub>Sn<sub>2</sub>Se<sub>8</sub>] </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4/<i>mcm</i> </td> <td>a=<i>b</i> 8.3731 <i>c</i> 6.719 </td> <td> </td> <td> </td> <td> </td> <td> </td></tr> <tr> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td></tr> <tr> <td>catena-[tris(1,10-phenanthroline)-cobalt octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrate] </td> <td>Co(phen)<sub>3</sub>In<sub>2</sub>Sn<sub>2</sub>Se<sub>8</sub> ∙ C<sub>6</sub>H<sub>11</sub>NH<sub>2</sub> ∙ 4H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=15.610 <i>b</i>=24.238 <i>c</i>=15.828 <i>β</i>=107.04° Z=4 </td> <td>5726 </td> <td>2.169 </td> <td>orange </td> <td><sup id="cite_ref-:25_108-0" class="reference"><a href="#cite_note-:25-108"><span class="cite-bracket">[</span>108<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tris(1,10-phenanthroline)-nickel octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrate </td> <td>Ni(phen)<sub>3</sub>In<sub>2</sub>Sn<sub>2</sub>Se<sub>8</sub> ∙ C<sub>6</sub>H<sub>11</sub>NH<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=15.574 <i>b</i>=24.083 <i>c</i>=15.804 <i>β</i>=107.11° Z=4 </td> <td>5665 </td> <td>2.192 </td> <td>orange </td> <td><sup id="cite_ref-:25_108-1" class="reference"><a href="#cite_note-:25-108"><span class="cite-bracket">[</span>108<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>RbInSnSe<sub>4</sub> </td> <td> </td> <td>cubic </td> <td><i>Pa</i><span style="text-decoration:overline;">3</span> </td> <td>a=13.9728 Z=12 </td> <td>2728.04 </td> <td>4.637 </td> <td>red; air sensitive </td> <td><sup id="cite_ref-:48_109-0" class="reference"><a href="#cite_note-:48-109"><span class="cite-bracket">[</span>109<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>RbInSnSe<sub>4</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td>a= 7.8104 b= 12.6533 c= 18.7062 <p>β= 96.297 </p> </td> <td>1837.52 </td> <td>4.589 </td> <td>orange </td> <td><sup id="cite_ref-:48_109-1" class="reference"><a href="#cite_note-:48-109"><span class="cite-bracket">[</span>109<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>Sn<sub>2</sub>Se<sub>5</sub> . H<sub>2</sub>O </td> <td> </td> <td>orthorhombic </td> <td><i>Ama</i>2 </td> <td><i>a</i> =12.05 <i>b</i> =12.405 <i>c</i> =9.426 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:8_7-2" class="reference"><a href="#cite_note-:8-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>Sn<sub>2</sub>Se<sub>5</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> =7.129 <i>b</i> =7.285 <i>c</i> =7.965, <i>α</i> =95.8° <i>β</i> =115.38° <i>γ</i> =108.46° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:18_90-1" class="reference"><a href="#cite_note-:18-90"><span class="cite-bracket">[</span>90<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>Sn<sub>3</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td>a = 23.214, b = 13.679, c =14,657, <i>β</i>= 111.92°, Z = 8, </td> <td>4317 </td> <td> </td> <td>red; SnSe<sub>5</sub> trigonal bipyramids connected in sheets </td> <td><sup id="cite_ref-:1_4-33" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-:2_27-4" class="reference"><a href="#cite_note-:2-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td>yellow; tetrahedral edge-shared pairs </td> <td><sup id="cite_ref-:2_27-5" class="reference"><a href="#cite_note-:2-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>4</sub>Sn<sub>4</sub>Se<sub>10</sub>·3.2H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=7.235 <i>b</i>=9.468 <i>c</i>=11.235 <i>α</i>=68.77° <i>β</i>=83.25° <i>γ</i>=84.53° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:69_39-2" class="reference"><a href="#cite_note-:69-39"><span class="cite-bracket">[</span>39<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>Sn<sub>4</sub>Se<sub>9</sub>-H<sub>2</sub>O </td> <td> </td> <td>orthorhombic </td> <td><i>Pnma</i> </td> <td><i>a</i> =13.514 <i>b</i> =12.54 <i>c</i> =12.679 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:18_90-2" class="reference"><a href="#cite_note-:18-90"><span class="cite-bracket">[</span>90<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>(4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium tris(μ<sub>3</sub>-selenido)-tris(μ<sub>2</sub>-selenido)-bis(1,2-ethylenediamine-N)-(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-di-cesium-potassium-di-tin(iv) </td> <td>[K-(2,2,2-crypt)]<sub>2</sub>Cs<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>·2en </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=10.0019 <i>b=</i>13.8929 <i>c=</i>24.478 <i>α</i>=100.204° <i>β</i>=95.701° <i>γ=</i>90.147° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:76_43-1" class="reference"><a href="#cite_note-:76-43"><span class="cite-bracket">[</span>43<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs[Cr(en)<sub>2</sub>SnSe<sub>4</sub>] </td> <td>739.67 </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td>a=7.6800 b=13.1483 c=15.7069 <i>β=</i>91.176° Z=4 </td> <td>1585.7 </td> <td>3.098 </td> <td>black </td> <td><sup id="cite_ref-110" class="reference"><a href="#cite_note-110"><span class="cite-bracket">[</span>110<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>MnSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Fddd</i> </td> <td><i>a</i>=6.4075 <i>b</i>=14.416 <i>c</i>=24.820 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:68_92-1" class="reference"><a href="#cite_note-:68-92"><span class="cite-bracket">[</span>92<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>MgSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i> 7.9055 <i>b</i> 12.7661 <i>c</i> 18.474 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:47_111-0" class="reference"><a href="#cite_note-:47-111"><span class="cite-bracket">[</span>111<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>MnSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i> 7.8798 <i>b</i> 12.7040 <i>c</i> 18.4556 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:58_91-1" class="reference"><a href="#cite_note-:58-91"><span class="cite-bracket">[</span>91<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Mn<sub>4</sub>Cs<sub>10</sub>Se<sub>17</sub>Sn<sub>4</sub> ∙ 15.5H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 13.717 <i>b</i> 15.502 <i>c</i> 18.481 <i>α</i> 77.02° <i>β</i> 74.35° <i>γ</i> 69.71° Z=2 </td> <td>3512 </td> <td>3.418 </td> <td>red </td> <td><sup id="cite_ref-:36_56-1" class="reference"><a href="#cite_note-:36-56"><span class="cite-bracket">[</span>56<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Zn<sub>4</sub>Cs<sub>10</sub>Se<sub>17</sub>Sn<sub>4</sub> ∙ 17H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 13.537 <i>b</i> 15.256 <i>c</i> 18.41, <i>α</i> 76.98° <i>β</i> 73.78° <i>γ</i> 69.57° Z=2 </td> <td>3386 </td> <td>3.577 </td> <td>yellow </td> <td><sup id="cite_ref-:36_56-2" class="reference"><a href="#cite_note-:36-56"><span class="cite-bracket">[</span>56<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>ZnSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i> 7.8146 <i>b</i> 12.6534 <i>c</i> 18.3747 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:47_111-1" class="reference"><a href="#cite_note-:47-111"><span class="cite-bracket">[</span>111<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>CsGaSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pmcn</i> </td> <td><i>a</i> 7.6785Å <i>b</i> 12.655Å <i>c</i> 18.278 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:70_85-1" class="reference"><a href="#cite_note-:70-85"><span class="cite-bracket">[</span>85<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cd<sub>4</sub>Cs<sub>10</sub>Se<sub>17</sub>Sn<sub>4</sub> ∙ 17H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 17.8678 <i>b</i> 17.7949 <i>c</i> 23.5518 <i>α</i> 98.682° <i>β</i> 105.75° <i>γ</i> 90.307° Z=4 </td> <td>7116 </td> <td>3.617 </td> <td>yellow </td> <td><sup id="cite_ref-:36_56-3" class="reference"><a href="#cite_note-:36-56"><span class="cite-bracket">[</span>56<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>CdSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i> 7.9335 <i>b</i> 12.7336 <i>c</i> 18.5387 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:47_111-2" class="reference"><a href="#cite_note-:47-111"><span class="cite-bracket">[</span>111<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>CsInSnSe<sub>4</sub> </td> <td> </td> <td>cubic </td> <td><i>Pa</i><span style="text-decoration:overline;">3</span> </td> <td>a=14.1932 Z=12 </td> <td>2959.2 </td> <td>4.755 </td> <td>red; air sensitive </td> <td><sup id="cite_ref-:48_109-2" class="reference"><a href="#cite_note-:48-109"><span class="cite-bracket">[</span>109<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Ba<sub>2</sub>SnSe<sub>4</sub> </td> <td>709.21 </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 8.582 <i>b</i> 9.255 <i>c</i> 12.460 <i>β</i> 114.28° Z=4 </td> <td>902.2 </td> <td>5.221 </td> <td>orange </td> <td><sup id="cite_ref-:59_112-0" class="reference"><a href="#cite_note-:59-112"><span class="cite-bracket">[</span>112<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>α-Ba<sub>2</sub>SnSe<sub>5</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td> </td> <td> </td> <td> </td> <td>dark brown </td> <td><sup id="cite_ref-:72_113-0" class="reference"><a href="#cite_note-:72-113"><span class="cite-bracket">[</span>113<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>β-Ba<sub>2</sub>SnSe<sub>5</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> = 9.3949 <i>b</i> = 8.8656 <i>c</i> = 12.5745 β = 113.299° <i>Z</i> = 4 </td> <td>961.9 </td> <td> </td> <td>high temperature; red </td> <td><sup id="cite_ref-:72_113-1" class="reference"><a href="#cite_note-:72-113"><span class="cite-bracket">[</span>113<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>m-Ba<sub>2</sub>SnSe<sub>5</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>12<sub>1</sub>/<i>c</i>1 </td> <td><i>a</i> = 21.17189 <i>b</i> = 9.0915 <i>c</i> = 24.7141 <i>β</i> = 125.621° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-114" class="reference"><a href="#cite_note-114"><span class="cite-bracket">[</span>114<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Ba<sub>6</sub>Sn<sub>6</sub>Se<sub>13</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i> 9.2998 <i>b</i> 12.384 <i>c</i> 26.896 Z=4 </td> <td>3097.8 </td> <td>5.495 </td> <td>black; 1.52 eV </td> <td><sup id="cite_ref-115" class="reference"><a href="#cite_note-115"><span class="cite-bracket">[</span>115<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Li<sub>2</sub>Ba<sub>7</sub>Sn<sub>4</sub>Se<sub>16</sub> </td> <td> </td> <td>cubic </td> <td><i>I</i><span style="text-decoration:overline;">4</span>3<i>d</i> </td> <td>a=15.1628 Z=4 </td> <td>3486.1 </td> <td>5.170 ? </td> <td>red </td> <td><sup id="cite_ref-:55_116-0" class="reference"><a href="#cite_note-:55-116"><span class="cite-bracket">[</span>116<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>2</sub>Ba<sub>7</sub>Sn<sub>4</sub>Se<sub>16</sub> </td> <td> </td> <td>cubic </td> <td><i>I</i><span style="text-decoration:overline;">4</span>3<i>d</i> </td> <td>a=14.807 Z=4 </td> <td>3246 </td> <td>4.082 </td> <td>red </td> <td><sup id="cite_ref-:55_116-1" class="reference"><a href="#cite_note-:55-116"><span class="cite-bracket">[</span>116<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>BaZnSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Fdd</i>2 </td> <td><i>a</i> 22.2402 <i>b</i> 22.7047 <i>c</i> 13.1972 </td> <td>6664.0 </td> <td>5.081 </td> <td>red; band gap 1.95 eV </td> <td><sup id="cite_ref-117" class="reference"><a href="#cite_note-117"><span class="cite-bracket">[</span>117<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>BaGa<sub>2</sub>SnSe<sub>6</sub> </td> <td> </td> <td>trigonal </td> <td><i>R</i>3 </td> <td><i>a</i> = 10.145 <i>c</i> = 9.249 <i>Z</i> = 3 </td> <td>824.4 </td> <td>5.253 </td> <td>red <p>NLO 5.2 × AgGaS<sub>2</sub> at 2.09 μm birefringence 0.1649 at 1.064 μm </p> </td> <td><sup id="cite_ref-118" class="reference"><a href="#cite_note-118"><span class="cite-bracket">[</span>118<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Ba<sub>4</sub>Ga<sub>4</sub>SnSe<sub>12</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td>band gap 2.14 </td> <td><sup id="cite_ref-119" class="reference"><a href="#cite_note-119"><span class="cite-bracket">[</span>119<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>BaAg<sub>2</sub>SnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>I</i>222 </td> <td><i>a</i>=7.10 <i>b</i>=7.47 <i>c</i>=8.30 </td> <td> </td> <td> </td> <td>band gap 0.2 eV </td> <td><sup id="cite_ref-:1_4-34" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-120" class="reference"><a href="#cite_note-120"><span class="cite-bracket">[</span>120<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>BaCdSnSe<sub>4</sub> </td> <td>684.27 </td> <td>orthorhombic </td> <td><i>Fdd</i>2 </td> <td><i>a</i> 22.38 <i>b</i> 22.71 <i>c</i> 13.588 Z=32 </td> <td>6907 </td> <td>5.265 </td> <td>orange </td> <td><sup id="cite_ref-:59_112-1" class="reference"><a href="#cite_note-:59-112"><span class="cite-bracket">[</span>112<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(hexakis(μ<sub>2</sub>-selenido)-(N-(2-(amino)ethyl)-N'-(2-((2-(amino)ethyl)amino)ethyl)ethane-1,2-diaminato)-di-tin-lanthanum hemihydrate) </td> <td>(H<sub>3</sub>O)[La(tepa)(μ-1κ<sup>2</sup>:2κ<sup>2</sup>-Sn<sub>2</sub>Se<sub>6</sub>)] </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=13.845 <i>b</i>=9.805 <i>c</i>=22.010 <i>β</i>=105.949° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:32_121-0" class="reference"><a href="#cite_note-:32-121"><span class="cite-bracket">[</span>121<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(μ-selenido)-bis(3,6,9,12-tetraazatetradecane-1,14-diamine)-nitrato-chloro-di-lanthanum(iii)-tin </td> <td>{La(peha)(Cl)}{La(peha)(NO<sub>3</sub>)}(μ-1κ<sup>2</sup>:2κ<sup>2</sup>-SnSe<sub>4</sub>)] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 8.411 <i>b</i> 14.760 <i>c</i> 16.244 <i>α</i> 92.57° <i>β</i> 91.95° <i>γ</i> 102.18° Z=2 </td> <td>1967.3 </td> <td>2.15 </td> <td>light yellow </td> <td><sup id="cite_ref-:34_122-0" class="reference"><a href="#cite_note-:34-122"><span class="cite-bracket">[</span>122<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>2,2'-(ethane-1,2-diyldiimino)diethanaminium tetrakis(μ-selenido)-tetrakis(triethylenetetramine )-diselenido-di-tin-di-lanthanum(iii) bis(μ-selenido)-tetraselenido-di-tin monohydrate </td> <td>[H<sub>2</sub>trien][{La(trien)<sub>2</sub>}<sub>2</sub>(μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)][Sn<sub>2</sub>Se<sub>6</sub>]·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=14.903 <i>b</i>=16.763 <i>c</i>=16.552 <i>β</i>=101.231° Z=2 </td> <td>4056 </td> <td>2.01 </td> <td>orange </td> <td><sup id="cite_ref-:34_122-1" class="reference"><a href="#cite_note-:34-122"><span class="cite-bracket">[</span>122<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{La(dien)<sub>2</sub>}<sub>4</sub>(μ<sub>4</sub>-Sn<sub>2</sub>Se<sub>9</sub>)(μ-Sn<sub>2</sub>Se<sub>6</sub>)]<sub>∞</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.253 <i>b</i> 13.061 <i>c</i> 15.847 <i>α</i> 80.62° <i>β</i> 73.59° <i>γ</i> 88.60° Z=1 </td> <td>2007.9 </td> <td>2.514 </td> <td>red </td> <td><sup id="cite_ref-:61_123-0" class="reference"><a href="#cite_note-:61-123"><span class="cite-bracket">[</span>123<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[La<sub>2</sub>(en)<sub>8</sub>(μ-Se<sub>2</sub>)]Sn<sub>2</sub>Se </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 10.079 <i>b</i> 14.843 <i>c</i> 14.918 <i>β</i> 90.599° Z=2 </td> <td>2231.7 </td> <td>2.422 </td> <td>yellow </td> <td><sup id="cite_ref-:61_123-1" class="reference"><a href="#cite_note-:61-123"><span class="cite-bracket">[</span>123<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>La<sub>3</sub>AgSnSe<sub>7</sub> </td> <td> </td> <td> </td> <td><i>P</i>6<sub>3</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:1_4-35" class="reference"><a href="#cite_note-:1-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(hexakis(μ<sub>2</sub>-Selenido)-(tetraethylenepentamine)-cerium-di-tin monohydrate) </td> <td>(H<sub>3</sub>O)[Ce(tepa)(μ-1κ<sup>2</sup>:2κ<sup>2</sup>-Sn<sub>2</sub>Se<sub>6</sub>)] </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=13.852 <i>b</i>=9.802 <i>c</i>=22.035 <i>β</i>=105.98° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:31_124-0" class="reference"><a href="#cite_note-:31-124"><span class="cite-bracket">[</span>124<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(μ<sub>2</sub>-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-cerium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ<sub>2</sub>-selenido)-tetraselenido-di-tin </td> <td>[Htrien]<sub>2</sub>[{Ce(trien)(tren)}<sub>2</sub>(μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 9.832 <i>b</i> 10.584 <i>c</i> 18.091, <i>α</i> 90.097° <i>β</i> 92.448° <i>γ</i> 94.500° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:31_124-1" class="reference"><a href="#cite_note-:31-124"><span class="cite-bracket">[</span>124<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Ce(dien)<sub>2</sub>}<sub>4</sub>(μ<sub>4</sub>-Sn<sub>2</sub>Se<sub>9</sub>)(μ-Sn<sub>2</sub>Se<sub>6</sub>)]<sub>∞</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.2333 <i>b</i> 13.0790 <i>c</i> 15.7663, <i>α</i> 80.422° <i>β</i> 73.738° <i>γ</i> 88.376° Z=1 </td> <td>1997.1 </td> <td>2.532 </td> <td>orange </td> <td><sup id="cite_ref-:60_125-0" class="reference"><a href="#cite_note-:60-125"><span class="cite-bracket">[</span>125<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Ce(en)<sub>4</sub>}<sub>2</sub>(μ-Se<sub>2</sub>)]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 10.094 <i>b</i> 16.616 <i>c</i> 13.397 <i>β</i> 101.878° Z=2 </td> <td>2198.9 </td> <td>2.462 </td> <td>light yellow </td> <td><sup id="cite_ref-:60_125-1" class="reference"><a href="#cite_note-:60-125"><span class="cite-bracket">[</span>125<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>BaCeSn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pmc</i>2<sub>1</sub> </td> <td><i>a</i>=4.1908 <i>b</i>=20.749 <i>c</i>=12.406 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-126" class="reference"><a href="#cite_note-126"><span class="cite-bracket">[</span>126<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>tetrakis(μ<sub>2</sub>-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-neodymium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ<sub>2</sub>-selenido)-tetraselenido-di-tin </td> <td>[Htrien]<sub>2</sub>[{Pr(trien)(tren)}<sub>2</sub>(μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 9.842 <i>b</i> 10.578 <i>c</i> 18.080, <i>α</i> 90.065° <i>β</i> 92.532° <i>γ</i> 94.511° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:31_124-2" class="reference"><a href="#cite_note-:31-124"><span class="cite-bracket">[</span>124<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-praseodymium] </td> <td>[Pr<sub>2</sub>(tepa)<sub>2</sub>(μ-OH)<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=12.450 <i>b</i>=13.617 <i>c</i>=21.005 Z=8 </td> <td> </td> <td>2.622 </td> <td>orange </td> <td><sup id="cite_ref-:33_95-2" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Pr(en)<sub>3</sub>}<sub>2</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 10.197 <i>b</i> 11.7622 <i>c</i> 15.497 <i>β</i> 98.967° Z=2 </td> <td>1835.9 </td> <td>2.510 </td> <td>yellow </td> <td><sup id="cite_ref-:60_125-2" class="reference"><a href="#cite_note-:60-125"><span class="cite-bracket">[</span>125<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(bis(μ<sub>2</sub>-hydroxo)-tetrakis(μ<sub>2</sub>-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-neodymium-di-tin) </td> <td>[{Nd(tepa)(μ-OH)}<sub>2</sub>(μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=12.485 <i>b</i>=13.601 <i>c</i>=20.917 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:32_121-1" class="reference"><a href="#cite_note-:32-121"><span class="cite-bracket">[</span>121<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Nd(en)<sub>3</sub>}<sub>2</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 10.176 <i>b</i> 11.772 <i>c</i> 15.470 <i>β</i> 99.128° Z=2 </td> <td>1829.8 </td> <td>2.531 </td> <td>yellow </td> <td><sup id="cite_ref-:60_125-3" class="reference"><a href="#cite_note-:60-125"><span class="cite-bracket">[</span>125<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Nd(dien)<sub>2</sub>}<sub>4</sub>(μ<sub>4</sub>-Sn<sub>2</sub>Se<sub>9</sub>)(μ-Sn<sub>2</sub>Se<sub>6</sub>)]<sub>∞</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.184 <i>b</i> 12.979 <i>c</i> 15.751, <i>α</i> 80.448° <i>β</i> 73.991° <i>γ</i> 88.552° Z=1 </td> <td>1973.1 </td> <td>2.576 </td> <td>red </td> <td><sup id="cite_ref-:60_125-4" class="reference"><a href="#cite_note-:60-125"><span class="cite-bracket">[</span>125<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>ethane-1,2-diaminium tris(N-(2-(amino)ethyl)ethane-1,2-diamine)-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) </td> <td>[Hen][Sm(dien)<sub>3</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=10.044 <i>b</i>=12.803 <i>c</i>=15.811 <i>α</i>=66.32° <i>β</i>=72.86° <i>γ</i>=68.35° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:24_127-0" class="reference"><a href="#cite_note-:24-127"><span class="cite-bracket">[</span>127<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(N,N-bis(2-(amino)ethyl)ethane-1,2-diamine)-chloro-samarium) hemikis(N,N-bis(2-aminoethyl)ethane-1,2-diamine) bis(μ-selenido)-tetrakis(selenido)-di-tin </td> <td>[Sm(trien)(tren)(Cl)]<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>·0.5en </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=10.348 <i>b</i>=10.575 <i>c</i>=14.043 <i>α</i>=77.26° <i>β</i>=87.78° <i>γ</i>=61.410° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:24_127-1" class="reference"><a href="#cite_note-:24-127"><span class="cite-bracket">[</span>127<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-bis(ethane-1,2-diamine)-bis(μ-hydroxy)di-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) </td> <td>[{Sm(en)(trien)}<sub>2</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i>=10.044 <i>b</i>=12.803 <i>c</i>=15.811, <i>α</i>=66.32° <i>β</i>=72.86° <i>γ</i>=68.35° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:24_127-2" class="reference"><a href="#cite_note-:24-127"><span class="cite-bracket">[</span>127<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-samarium-tin hemihydrate] </td> <td>[{Sm(tepa)(μ-OH)}<sub>2</sub> (μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)]<sub>n</sub>·nH<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=22.944 <i>b</i>=11.946 <i>c</i>=18.907 <i>β</i>=125.53° Z=4 </td> <td>4217 </td> <td>2.27 </td> <td>yellow </td> <td><sup id="cite_ref-:34_122-2" class="reference"><a href="#cite_note-:34-122"><span class="cite-bracket">[</span>122<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Hdien][Sm(dien)<sub>2</sub>(μ-SnSe<sub>4</sub>)] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2/<i>c</i> </td> <td><i>a</i> 10.185 <i>b</i> 9.471 <i>c</i> 13.808 <i>β</i> 102.256° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:62_128-0" class="reference"><a href="#cite_note-:62-128"><span class="cite-bracket">[</span>128<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Eu<sub>8</sub>(Sn<sub>4</sub>Se<sub>14</sub>)(Se<sub>3</sub>)<sub>2</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2 </td> <td>a = 11.990 b = 16.425 c = 8.543 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-129" class="reference"><a href="#cite_note-129"><span class="cite-bracket">[</span>129<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-europium-tin hemihydrate] </td> <td>[{Eu(tepa)(μ-OH)}<sub>2</sub> (μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)]<sub>n</sub>·nH<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=22.904 <i>b</i>=11.981 <i>c</i>=18.894 <i>β</i>=125.52° Z=4 </td> <td>4220 </td> <td>2.28 </td> <td>yellow </td> <td><sup id="cite_ref-:34_122-3" class="reference"><a href="#cite_note-:34-122"><span class="cite-bracket">[</span>122<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Hdien][Eu(dien)<sub>2</sub>(μ-SnSe<sub>4</sub>)] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2/<i>c</i> </td> <td><i>a</i> 10.185 <i>b</i> 9.453 <i>c</i> 13.791 <i>β</i> 102.165° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:62_128-1" class="reference"><a href="#cite_note-:62-128"><span class="cite-bracket">[</span>128<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Eu<sub>2</sub>(dien)<sub>4</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 12.027 <i>b</i> 11.802 <i>c</i> 13.827 <i>β</i> 99.179° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:62_128-2" class="reference"><a href="#cite_note-:62-128"><span class="cite-bracket">[</span>128<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Eu(en)<sub>3</sub>}<sub>2</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> = 10.136 <i>b</i> = 11.771 <i>c</i> = 15.423 <i>β</i> = 99.322° <i>Z</i> = 2 </td> <td>1815.8 </td> <td> </td> <td> </td> <td><sup id="cite_ref-130" class="reference"><a href="#cite_note-130"><span class="cite-bracket">[</span>130<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(bis(μ<sub>2</sub>-hydroxo)-tetrakis(μ<sub>2</sub>-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-gadolinium-di-tin monohydrate) </td> <td>[{Gd(tepa)(μ-OH)}<sub>2</sub>(μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)]<b>·</b>H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=22.82 <i>b</i>=11.975 <i>c</i>=18.918 <i>β</i>=125.975° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:32_121-2" class="reference"><a href="#cite_note-:32-121"><span class="cite-bracket">[</span>121<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Gd(en)<sub>3</sub>}<sub>2</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 9.993 <i>b</i> 11.842 <i>c</i> 15.313° <i>β</i> 99.979° Z=2 </td> <td>1784.6 </td> <td>2.643 </td> <td>yellow </td> <td><sup id="cite_ref-:60_125-5" class="reference"><a href="#cite_note-:60-125"><span class="cite-bracket">[</span>125<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Hdien][Gd(dien)<sub>2</sub>(μ-SnSe<sub>4</sub>)] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i> 10.300 <i>b</i> 9.426 <i>c</i> 13.875 <i>β</i> 101.678° Z=2 </td> <td>1319.3 </td> <td>2.271 </td> <td>red </td> <td><sup id="cite_ref-:60_125-6" class="reference"><a href="#cite_note-:60-125"><span class="cite-bracket">[</span>125<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Gd(dap)<sub>4</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>]Cl<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=10.2385 <i>b</i>=14.1276 <i>c</i>=18.068 <i>β</i> =102.745° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:75_131-0" class="reference"><a href="#cite_note-:75-131"><span class="cite-bracket">[</span>131<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[{Tb(en)<sub>3</sub>}<sub>2</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td>1423.62 </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td>a=10.120 b=11.781 c=15.403 β=99.534° Z=2 </td> <td>1811.1 </td> <td>2.611 </td> <td> </td> <td><sup id="cite_ref-132" class="reference"><a href="#cite_note-132"><span class="cite-bracket">[</span>132<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(tetrakis(propane-1,2-diamine)-terbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate </td> <td>[Tb(dap)<sub>4</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>]Cl<sub>2</sub>·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=10.240 <i>b</i>=14.116 <i>c</i>=18.030 <i>β</i>=102.808° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:75_131-1" class="reference"><a href="#cite_note-:75-131"><span class="cite-bracket">[</span>131<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(μ<sub>2</sub>-selenido)-(μ<sub>2</sub>-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-dysprosium-tin] </td> <td>[Dy<sub>2</sub>(tepa)<sub>2</sub>(μ-OH)<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=12.4132 <i>b</i>=13.5901 <i>c</i>=20.6722 Z=8 </td> <td> </td> <td>2.759 </td> <td>orange </td> <td><sup id="cite_ref-:33_95-3" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(μ<sub>2</sub>-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-dysprosium) hexakis(μ<sub>2</sub>-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate </td> <td>[Dy<sub>2</sub>(tepa)<sub>2</sub>(μ<sub>2</sub>-OH)<sub>2</sub>Cl<sub>2</sub>]<sub>2</sub>[Sn<sub>4</sub>Se<sub>10</sub>]·4H<sub>2</sub>O </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td>a=28.2390 <i>c</i>=11.0380 </td> <td> </td> <td>2.229 </td> <td>yellow </td> <td><sup id="cite_ref-:33_95-4" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Dy<sub>2</sub>(en)<sub>6</sub>(<i>μ</i><sub>2</sub>-OH)<sub>2</sub>][Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:63_133-0" class="reference"><a href="#cite_note-:63-133"><span class="cite-bracket">[</span>133<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(tetrakis(propane-1,2-diamine)-dysprosium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate </td> <td>[Dy(dap)<sub>4</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>]Cl<sub>2</sub>·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=10.214 <i>b</i>=14.118 <i>c</i>=18.000 <i>β</i>=102.798° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:75_131-2" class="reference"><a href="#cite_note-:75-131"><span class="cite-bracket">[</span>131<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(tetrakis(Propane-1,2-diamine)-holmium chloride) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) </td> <td>[Ho(dap)<sub>4</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>]Cl<sub>2</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=10.1839 <i>b</i>=14.1303 <i>c</i>=18.0100 <i>β</i>=102.571° Z=4 </td> <td>2529.5 </td> <td> </td> <td>yellow </td> <td><sup id="cite_ref-:29_134-0" class="reference"><a href="#cite_note-:29-134"><span class="cite-bracket">[</span>134<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(μ<sub>2</sub>-Hydroxo)-tetrakis(diethylenetriamine)-di-holmium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) </td> <td>{[Ho(dien)<sub>2</sub>]<sub>2</sub>(μ<sub>2</sub>-OH)<sub>2</sub>}[Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=12.0096 <i>b</i>=11.7181 <i>c</i>=13.7717 <i>β</i>=99.138° Z=2 </td> <td>1913.5 </td> <td>2.586 </td> <td>yellow </td> <td><sup id="cite_ref-:29_134-1" class="reference"><a href="#cite_note-:29-134"><span class="cite-bracket">[</span>134<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-bis(μ-hydroxo)-di-holmium) tricyclo[3.3.1.1<sup>3,7</sup>]tetrastannaselenane-1,3,5,7-tetrakis(selenolate) tetrahydrate </td> <td>[Ho<sub>2</sub>(tepa)<sub>2</sub>(μ<sub>2</sub>-OH)<sub>2</sub>Cl<sub>2</sub>]<sub>2</sub>[Sn<sub>4</sub>Se<sub>10</sub>]·4H<sub>2</sub>O </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td>a=28.076 <i>c</i> 10.948 </td> <td>8629.6 </td> <td>2.281 </td> <td>yellow; supertetrahedron </td> <td><sup id="cite_ref-:29_134-2" class="reference"><a href="#cite_note-:29-134"><span class="cite-bracket">[</span>134<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[bis(μ<sub>2</sub>-selenido)-(μ<sub>2</sub>-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-erbium-tin] </td> <td>[Er<sub>2</sub>(tepa)<sub>2</sub>(μ-OH)<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=12.418 <i>b</i>=13.605 <i>c</i>=20.636 Z=8 </td> <td> </td> <td>2.778 </td> <td>orange </td> <td><sup id="cite_ref-:33_95-5" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(μ<sub>2</sub>-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-erbium) hexakis(μ<sub>2</sub>-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate </td> <td>[Er<sub>2</sub>(tepa)<sub>2</sub>(μ<sub>2</sub>-OH)<sub>2</sub>Cl<sub>2</sub>]<sub>2</sub>[Sn<sub>4</sub>Se<sub>10</sub>]·4H<sub>2</sub>O </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td>a=28.1622 <i>c</i>=11.0089 </td> <td> </td> <td>2.261 </td> <td>yellow </td> <td><sup id="cite_ref-:33_95-6" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Er<sub>2</sub>(en)<sub>6</sub>(<i>μ</i><sub>2</sub>-OH)<sub>2</sub>][Sn<sub>2</sub>S<sub>6</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i> 9.951 <i>b</i> 11.860 <i>c</i> 15.278 <i>β</i> 100.239° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:63_133-1" class="reference"><a href="#cite_note-:63-133"><span class="cite-bracket">[</span>133<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(tetrakis(propane-1,2-diamine)-erbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate </td> <td>[Er(dap)<sub>4</sub>]<sub>2</sub>[Sn<sub>2</sub>Se<sub>6</sub>]Cl<sub>2</sub>·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=10.204 <i>b</i>=14.176 <i>c</i>=18.041 <i>β</i>=102.530° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:75_131-3" class="reference"><a href="#cite_note-:75-131"><span class="cite-bracket">[</span>131<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-thulium </td> <td>[Tm<sub>2</sub>(tepa)<sub>2</sub>(μ-OH)<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>] </td> <td> </td> <td>orthorhombic </td> <td><i>Pbca</i> </td> <td><i>a</i>=12.399 <i>b</i>=13.518 <i>c</i>=20.504 Z=8 </td> <td> </td> <td>2.820 </td> <td>orange </td> <td><sup id="cite_ref-:33_95-7" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(bis(μ<sub>2</sub>-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-thulium) hexakis(μ<sub>2</sub>-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate </td> <td>[Tm<sub>2</sub>(tepa)<sub>2</sub>(μ<sub>2</sub>-OH)<sub>2</sub>Cl<sub>2</sub>]<sub>2</sub>[Sn<sub>4</sub>Se<sub>10</sub>]·4H<sub>2</sub>O </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4<sub>1</sub>/<i>a</i> </td> <td>a=28.2080 <i>c</i>=11.0142 </td> <td> </td> <td>2.258 </td> <td>yellow </td> <td><sup id="cite_ref-:33_95-8" class="reference"><a href="#cite_note-:33-95"><span class="cite-bracket">[</span>95<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>[Hen]<sub>4</sub>[Tm(en)<sub>4</sub>]<sub>2</sub>[Ag<sub>6</sub>Sn<sub>6</sub>S<sub>20</sub>]·3en </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>m</i> </td> <td><i>a</i> 14.517 <i>b</i> 24.380 <i>c</i> 13.422 <i>β</i> 94.46° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:41_135-0" class="reference"><a href="#cite_note-:41-135"><span class="cite-bracket">[</span>135<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-((μ<sub>2</sub>-Hydroxo)-bis(μ<sub>2</sub>-selenido)-selenide-(tetraethylenepentamine)-tin-ytterbium hemihydrate) </td> <td>[{Yb(tepa)(μ-OH)}<sub>2</sub>(μ-1κ:2κ-Sn<sub>2</sub>Se<sub>6</sub>)]·H<sub>2</sub>O </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i>=21.255 <i>b</i>=12.835 <i>c</i>=17.633 <i>β</i>=125.41° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:31_124-3" class="reference"><a href="#cite_note-:31-124"><span class="cite-bracket">[</span>124<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>bis(μ<sub>2</sub>-Hydroxo)-tetrakis(diethylenetriamine)-di-ytterbium bis(μ<sub>2</sub>-selenido)-tetraselenido-di-tin </td> <td>[{Yb(dien)<sub>2</sub>}<sub>2</sub>(μ-OH)<sub>2</sub>]Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>n</i> </td> <td><i>a</i>=12.026 <i>b</i>=11.666 <i>c</i>=13.819 <i>β</i>=98.971° Z=4 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:31_124-4" class="reference"><a href="#cite_note-:31-124"><span class="cite-bracket">[</span>124<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>DBU=1,8-diazabicyclo[5.4.0]undec-7-ene <p>catena-(bis(2,3,4,6,7,8,9,10-Octahydropyrimido(1,2-a)azepin-1-ium) bis(μ<sub>3</sub>-selenido)-pentakis(μ<sub>2</sub>-selenido)-di-mercury) </p> </td> <td>[DBUH]<sub>2</sub>[Hg<sub>2</sub>Sn<sub>2</sub>Se<sub>6</sub>(Se<sub>2</sub>)] </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 10.390 <i>b</i> 12.244 <i>c</i> 13.977 <i>α</i> 86.58° <i>β</i> 79.51° <i>γ</i> 70.14° Z=2 </td> <td>1644.3 </td> <td>3.025 </td> <td>yellow </td> <td><sup id="cite_ref-:35_136-0" class="reference"><a href="#cite_note-:35-136"><span class="cite-bracket">[</span>136<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>catena-(bis(2,3,4,6,7,8,9,10-Octahydro-1H-pyrimido(1,2-a)azepin-5-ium) (μ<sub>3</sub>-diselenido)-(μ<sub>3</sub>-selenido)-pentakis(μ<sub>2</sub>-selenido)-di-mercury-di-tin) </td> <td>[DBUH]<sub>2</sub>[Hg<sub>2</sub>Sn<sub>2</sub>Se5(Se<sub>2</sub>)] </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td><i>a</i>=14.7289 <i>b</i>=18.6045 <i>c</i>=13.5200 <i>β</i>=111.571 </td> <td>3445.33 </td> <td>3.040 </td> <td>red </td> <td><sup id="cite_ref-:35_136-1" class="reference"><a href="#cite_note-:35-136"><span class="cite-bracket">[</span>136<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>(tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ<sub>3</sub>-diselenido)-undecakis(μ<sub>2</sub>-selenido)-tri-mercury-tetra-tin </td> <td>[DBNH]<sub>4</sub>[Hg<sub>3</sub>Sn<sub>4</sub>Se<sub>11</sub>(Se<sub>2</sub>)<sub>2</sub>] </td> <td> </td> <td>monoclinic </td> <td><i>C</i>2/<i>c</i> </td> <td><i>a</i> 22.137 <i>b</i> 12.663 <i>c</i> 21.780° <i>β</i> 109.48° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:40_105-1" class="reference"><a href="#cite_note-:40-105"><span class="cite-bracket">[</span>105<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>DBN=1,5-diazabicyclo[4.3.0]non-5-ene </td> <td>[DBNH]<sub>2</sub>[HgSnSe<sub>4</sub>] </td> <td> </td> <td>tetragonal </td> <td><i>P</i>4<sub>2</sub>/<i>ncm</i> </td> <td>a=12.8605 <i>c</i> 6.85560 </td> <td> </td> <td> </td> <td>band gap 2.46 eV </td> <td><sup id="cite_ref-:65_62-2" class="reference"><a href="#cite_note-:65-62"><span class="cite-bracket">[</span>62<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Li<sub>4</sub>HgSn<sub>2</sub>Se<sub>7</sub> </td> <td> </td> <td>monoclinic </td> <td><i>Cc</i> </td> <td><i>a</i> 18.286<i>b</i> 7.197 <i>c</i> 10.809 <i>β</i> 93.44° </td> <td> </td> <td> </td> <td>red </td> <td><sup id="cite_ref-137" class="reference"><a href="#cite_note-137"><span class="cite-bracket">[</span>137<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Li<sub>2</sub>HgSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pna</i>2<sub>1</sub> </td> <td>a=14.458 b=8.378 c=6.8215 Z=4 </td> <td>826.3 </td> <td>5.217 </td> <td>red; SHG 6.0 × AgGaS<sub>2</sub> </td> <td><sup id="cite_ref-:0_138-0" class="reference"><a href="#cite_note-:0-138"><span class="cite-bracket">[</span>138<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>2</sub>HgSn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4/<i>mcm</i> </td> <td>a=7.8571 <i>c</i>=20.214 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-139" class="reference"><a href="#cite_note-139"><span class="cite-bracket">[</span>139<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Na<sub>2</sub>Hg<sub>3</sub>Sn<sub>2</sub>Se<sub>8</sub> </td> <td>1516.81 </td> <td>tetragonal </td> <td><i>P</i><span style="text-decoration:overline;">4</span><i>c</i>2 </td> <td>a=9.3749 c=9.790 Z=2 </td> <td>860.5 </td> <td>5.854 </td> <td>red </td> <td><sup id="cite_ref-:0_138-1" class="reference"><a href="#cite_note-:0-138"><span class="cite-bracket">[</span>138<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>K<sub>2</sub>HgSnSe<sub>4</sub> </td> <td> </td> <td>tetragonal </td> <td><i>I</i>4/<i>mcm</i> </td> <td><i>a</i>=8.0531Å <i>c</i>=6.9501 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-xlink.rsc.org_76-1" class="reference"><a href="#cite_note-xlink.rsc.org-76"><span class="cite-bracket">[</span>76<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>phen = 1,10-phenanthroline; eta = ethanolamine </td> <td>[Fe(phen)<sub>3</sub>]Hg<sub>2</sub>Sn<sub>2</sub>Se<sub>7</sub>·1.5eta·0.25H<sub>2</sub>O </td> <td> </td> <td>triclinic </td> <td><i>P</i><span style="text-decoration:overline;">1</span> </td> <td><i>a</i> 13.0238 <i>b</i> 13.6275 <i>c</i> 14.4626 <i>α</i> 81.104° <i>β</i> 88.117° <i>γ</i> 82.840° </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:53_140-0" class="reference"><a href="#cite_note-:53-140"><span class="cite-bracket">[</span>140<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>teta = triethylenetetramine </td> <td>[Ni<sub>2</sub>(teta)<sub>2</sub>(<i>μ</i>-teta)]HgSn<sub>3</sub>Se<sub>9</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Pmc</i>2<sub>1</sub> </td> <td><i>a</i> 22.731 <i>b</i> 13.2151 <i>c</i> 14.6495 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:53_140-1" class="reference"><a href="#cite_note-:53-140"><span class="cite-bracket">[</span>140<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>SrHgSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Fdd</i>2 </td> <td><i>a</i> 21.9027 <i>b</i> 21.9059 <i>c</i> 13.5010 </td> <td> </td> <td> </td> <td>SHG 5 × AgGaS<sub>2</sub> </td> <td><sup id="cite_ref-:56_141-0" class="reference"><a href="#cite_note-:56-141"><span class="cite-bracket">[</span>141<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Cs<sub>2</sub>HgSn<sub>3</sub>Se<sub>8</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub> </td> <td><i>a</i> 7.9196 <i>b</i> 12.6657 <i>c</i> 18.5375 </td> <td> </td> <td> </td> <td> </td> <td><sup id="cite_ref-:47_111-3" class="reference"><a href="#cite_note-:47-111"><span class="cite-bracket">[</span>111<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>BaHgSnSe<sub>4</sub> </td> <td> </td> <td>orthorhombic </td> <td><i>Fdd</i>2 </td> <td><i>a</i> 22.441 <i>b</i> 22.760 <i>c</i> 13.579 </td> <td> </td> <td> </td> <td>SHG 5 × AgGaS<sub>2</sub> </td> <td><sup id="cite_ref-:56_141-1" class="reference"><a href="#cite_note-:56-141"><span class="cite-bracket">[</span>141<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>Tl<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td>tetrahedral edge-shared pairs </td> <td><sup id="cite_ref-:2_27-6" class="reference"><a href="#cite_note-:2-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>TlGaSnSe<sub>4</sub> </td> <td> </td> <td>monoclinic </td> <td><i>P</i>2<sub>1</sub>/<i>c</i> </td> <td>a=7.501 b= 12.175 c= 18.203 <p>β= 97.164 Z=8 </p> </td> <td>1649.4 </td> <td>5.646 </td> <td>red </td> <td><sup id="cite_ref-:42_86-3" class="reference"><a href="#cite_note-:42-86"><span class="cite-bracket">[</span>86<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td> </td> <td>TlGaSnSe<sub>4</sub> </td> <td> </td> <td>cubic </td> <td><i>Pa</i><span style="text-decoration:overline;">3</span> </td> <td>a=13.4755 Z=12 </td> <td>2447.0 </td> <td>5.770 </td> <td>red </td> <td><sup id="cite_ref-:42_86-4" class="reference"><a href="#cite_note-:42-86"><span class="cite-bracket">[</span>86<span class="cite-bracket">]</span></a></sup> </td></tr></tbody></table> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Selenidostannate&action=edit&section=5" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist"> <div class="mw-references-wrap mw-references-columns"><ol class="references"> <li id="cite_note-:3-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-:3_1-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-:3_1-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output 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href="https://doi.org/10.1021%2Facs.inorgchem.9b01572">10.1021/acs.inorgchem.9b01572</a>. <a href="/wiki/ISSN_(identifier)" class="mw-redirect" title="ISSN (identifier)">ISSN</a> <a rel="nofollow" class="external text" href="https://search.worldcat.org/issn/0020-1669">0020-1669</a>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/31342744">31342744</a>. <a href="/wiki/S2CID_(identifier)" class="mw-redirect" title="S2CID (identifier)">S2CID</a> <a rel="nofollow" class="external text" href="https://api.semanticscholar.org/CorpusID:198494837">198494837</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Inorganic+Chemistry&rft.atitle=AHgSnQ+4+%28A+%3D+Sr%2C+Ba%3B+Q+%3D+S%2C+Se%29%3A+A+Series+of+Hg-Based+Infrared+Nonlinear-Optical+Materials+with+Strong+Second-Harmonic-Generation+Response+and+Good+Phase+Matchability&rft.volume=58&rft.issue=15&rft.pages=%3Cspan+class%3D%22nowrap%22%3E10390-%3C%2Fspan%3E10398&rft.date=2019-08-05&rft.issn=0020-1669&rft_id=https%3A%2F%2Fapi.semanticscholar.org%2FCorpusID%3A198494837%23id-name%3DS2CID&rft_id=info%3Apmid%2F31342744&rft_id=info%3Adoi%2F10.1021%2Facs.inorgchem.9b01572&rft.aulast=Guo&rft.aufirst=Yangwu&rft.au=Liang%2C+Fei&rft.au=Li%2C+Zhuang&rft.au=Xing%2C+Wenhao&rft.au=Lin%2C+Zhe-shuai&rft.au=Yao%2C+Jiyong&rft.au=Mar%2C+Arthur&rft.au=Wu%2C+Yicheng&rft_id=https%3A%2F%2Fpubs.acs.org%2Fdoi%2F10.1021%2Facs.inorgchem.9b01572&rfr_id=info%3Asid%2Fen.wikipedia.org%3ASelenidostannate" class="Z3988"></span></span> </li> </ol></div></div> <div 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class="navbox-list navbox-odd" style="width:100%;padding:0;border-width:0;"><div style="padding:0"><div class="mw-collapsible-content" style="overflow-x:auto"> <table class="center"> <tbody><tr style="background-color:mistyrose"> <td><a href="/wiki/Hydrogen_selenide" title="Hydrogen selenide">H<sub>2</sub>Se</a><br /><a href="/wiki/Hydrogen_diselenide" title="Hydrogen diselenide">H<sub>2</sub>Se<sub>2</sub></a><br /><a href="/wiki/Hydride_selenide" title="Hydride selenide">+H</a><br /><a href="/wiki/Hydroselenide" title="Hydroselenide">-H</a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td style="background-color:white;color:inherit;border:none" colspan="11" rowspan="3"> </td> <td style="background-color:white;color:inherit;border:none" colspan="5"> </td> <td>He </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Lithium_selenide" title="Lithium selenide">Li<sub>2</sub>Se</a> </td> <td>Be </td> <td><a href="/wiki/Selenide_borate" title="Selenide borate">Se<sub><span class="texhtml mvar" style="font-style:italic;">x</span></sub>B<sub><span class="texhtml mvar" style="font-style:italic;">y</span></sub>O<sub><span class="texhtml mvar" style="font-style:italic;">z</span></sub></a> </td> <td><a href="/wiki/Carbon_diselenide" title="Carbon diselenide">CSe<sub>2</sub></a><br /><a href="/wiki/Carbonyl_selenide" title="Carbonyl selenide">OCSe</a><br /><a href="/wiki/Dimethyl_selenide" title="Dimethyl selenide">(CH<sub>3</sub>)<sub>2</sub>Se</a> </td> <td><a href="/wiki/Ammonium_selenide" title="Ammonium selenide">(NH<sub>4</sub>)<sub>2</sub>Se</a> </td> <td>O </td> <td>F </td> <td>Ne </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Sodium_selenide" title="Sodium selenide">Na<sub>2</sub>Se</a> </td> <td><a href="/wiki/Magnesium_selenide" title="Magnesium selenide">MgSe</a> </td> <td><a href="/wiki/Aluminium_selenide" title="Aluminium selenide">Al<sub>2</sub>Se<sub>3</sub></a> </td> <td>Si </td> <td><a href="/wiki/Phosphorus_selenide" title="Phosphorus selenide">P<sub><span class="texhtml mvar" style="font-style:italic;">x</span></sub>Se<sub><span class="texhtml mvar" style="font-style:italic;">y</span></sub></a><br /><a href="/wiki/Selenophosphate" title="Selenophosphate">-P</a> </td> <td><a href="/wiki/Sulfoselenide" class="mw-redirect" title="Sulfoselenide">+S</a> </td> <td>Cl </td> <td>Ar </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Potassium_selenide" title="Potassium selenide">K<sub>2</sub>Se</a> </td> <td><a href="/wiki/Calcium_selenide" title="Calcium selenide">CaSe</a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td><a href="/w/index.php?title=Scandium_selenide&action=edit&redlink=1" class="new" title="Scandium selenide (page does not exist)">Sc<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Titanium_diselenide" title="Titanium diselenide">TiSe<sub>2</sub></a> </td> <td>V </td> <td><a href="/wiki/Chromium(II)_selenide" title="Chromium(II) selenide">CrSe</a><br /><a href="/wiki/Chromium(III)_selenide" title="Chromium(III) selenide">Cr<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Manganese(II)_selenide" title="Manganese(II) selenide">MnSe</a><br /><a href="/wiki/Manganese_diselenide" title="Manganese diselenide">MnSe<sub>2</sub></a> </td> <td><a href="/wiki/Iron(II)_selenide" title="Iron(II) selenide">FeSe</a> </td> <td><a href="/wiki/Cobalt(II)_selenide" title="Cobalt(II) selenide">CoSe</a> </td> <td><a href="/wiki/Nickel_selenide" title="Nickel selenide">NiSe</a> </td> <td><a href="/wiki/Copper(I)_selenide" title="Copper(I) selenide">Cu<sub>2</sub>Se</a><br /><a href="/wiki/Copper(II)_selenide" title="Copper(II) selenide">CuSe</a> </td> <td><a href="/wiki/Zinc_selenide" title="Zinc selenide">ZnSe</a> </td> <td><a href="/wiki/Gallium(II)_selenide" title="Gallium(II) selenide">GaSe</a><br /><a href="/wiki/Gallium(III)_selenide" title="Gallium(III) selenide">Ga<sub>2</sub>Se<sub>3</sub></a><br /><a href="/wiki/Selenogallate" title="Selenogallate">-Ga</a> </td> <td><a href="/wiki/Germanium_monoselenide" title="Germanium monoselenide">GeSe</a><br /><a href="/wiki/Germanium_diselenide" title="Germanium diselenide">GeSe<sub>2</sub></a><br /><a href="/wiki/Selenidogermanate" title="Selenidogermanate">-Ge</a> </td> <td><a href="/wiki/Arsenic_triselenide" title="Arsenic triselenide">As<sub>2</sub>Se<sub>3</sub></a><br /><a href="/w/index.php?title=Tetraarsenic_triselenide&action=edit&redlink=1" class="new" title="Tetraarsenic triselenide (page does not exist)">As<sub>4</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Polyselenide" title="Polyselenide">Se<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1.2em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline">2−</sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline"><i>n</i></sub></span></span></a> </td> <td>Br </td> <td>Kr </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Rubidium_selenide" title="Rubidium selenide">Rb<sub>2</sub>Se<sub></sub></a> </td> <td><a href="/wiki/Strontium_selenide" title="Strontium selenide">SrSe</a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td><a href="/w/index.php?title=Yttrium_selenide&action=edit&redlink=1" class="new" title="Yttrium selenide (page does not exist)">Y<sub>2</sub>Se<sub>3</sub></a> </td> <td>Zr </td> <td><a href="/wiki/Niobium_diselenide" title="Niobium diselenide">NbSe<sub>2</sub></a><br /><a href="/wiki/Niobium_triselenide" title="Niobium triselenide">NbSe<sub>3</sub></a> </td> <td><a href="/wiki/Molybdenum_diselenide" title="Molybdenum diselenide">MoSe<sub>2</sub></a> </td> <td>Tc </td> <td>Ru </td> <td>Rh </td> <td>Pd </td> <td><a href="/wiki/Silver(I)_selenide" title="Silver(I) selenide">Ag<sub>2</sub>Se</a> </td> <td><a href="/wiki/Cadmium_selenide" title="Cadmium selenide">CdSe</a> </td> <td><a href="/wiki/Indium(II)_selenide" title="Indium(II) selenide">InSe</a><br /><a href="/wiki/Indium(III)_selenide" title="Indium(III) selenide">In<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Tin_selenide" title="Tin selenide">SnSe</a><br /><a href="/w/index.php?title=Tin(IV)_selenide&action=edit&redlink=1" class="new" title="Tin(IV) selenide (page does not exist)">SnSe<sub>2</sub></a><br /><a class="mw-selflink selflink">-Sn</a> </td> <td><a href="/wiki/Antimony_triselenide" title="Antimony triselenide">Sb<sub>2</sub>Se<sub>3</sub></a> </td> <td>Te </td> <td><a href="/wiki/Selenide_iodide" title="Selenide iodide">+I</a> </td> <td>Xe </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Caesium_selenide" title="Caesium selenide">Cs<sub>2</sub>Se</a> </td> <td><a href="/wiki/Barium_selenide" title="Barium selenide">BaSe</a> </td> <td style="background-color:white;color:inherit;border:none">* </td> <td><a href="/w/index.php?title=Lutetium_monoselenide&action=edit&redlink=1" class="new" title="Lutetium monoselenide (page does not exist)">LuSe</a><br /><a href="/wiki/Lutetium(III)_selenide" title="Lutetium(III) selenide">Lu<sub>2</sub>Se<sub>3</sub></a> </td> <td>Hf </td> <td><a href="/wiki/Tantalum_diselenide" title="Tantalum diselenide">TaSe<sub>2</sub></a> </td> <td><a href="/wiki/Tungsten_diselenide" title="Tungsten diselenide">WSe<sub>2</sub></a><br /><a href="/w/index.php?title=Tungsten_triselenide&action=edit&redlink=1" class="new" title="Tungsten triselenide (page does not exist)">WSe<sub>3</sub></a> </td> <td><a href="/wiki/Rhenium_diselenide" title="Rhenium diselenide">ReSe<sub>2</sub></a> </td> <td>Os </td> <td>Ir </td> <td><a href="/wiki/Platinum_diselenide" title="Platinum diselenide">PtSe<sub>2</sub></a> </td> <td>Au </td> <td><a href="/wiki/Mercury_selenide" title="Mercury selenide">HgSe</a> </td> <td><a href="/w/index.php?title=Thallium_selenide&action=edit&redlink=1" class="new" title="Thallium selenide (page does not exist)">Tl<sub>2</sub>Se</a> </td> <td><a href="/wiki/Lead_selenide" title="Lead selenide">PbSe</a> </td> <td><a href="/wiki/Bismuth_selenide" title="Bismuth selenide">Bi<sub>2</sub>Se<sub>3</sub></a> </td> <td>Po </td> <td>At </td> <td>Rn </td></tr> <tr style="background-color:mistyrose;color:black;"> <td>Fr </td> <td>Ra </td> <td style="background-color:white;color:inherit;border:none">** </td> <td>Lr </td> <td>Rf </td> <td>Db </td> <td>Sg </td> <td>Bh </td> <td>Hs </td> <td>Mt </td> <td>Ds </td> <td>Rg </td> <td><a href="/w/index.php?title=Copernicium_selenide&action=edit&redlink=1" class="new" title="Copernicium selenide (page does not exist)">CnSe</a> </td> <td>Nh </td> <td>Fl </td> <td>Mc </td> <td>Lv </td> <td>Ts </td> <td>Og </td></tr> <tr> <td style="background-color:white;color:inherit;border:none" colspan="2" rowspan="3"> </td> <td style="background-color:white;color:inherit;border:none" colspan="20">  </td></tr> <tr style="background-color:mistyrose;color:black;"> <td style="background-color:white;color:inherit;border:none">* </td> <td><a href="/w/index.php?title=Lanthanum_monoselenide&action=edit&redlink=1" class="new" title="Lanthanum monoselenide (page does not exist)">LaSe</a><br /><a href="/w/index.php?title=Lanthanum(III)_selenide&action=edit&redlink=1" class="new" title="Lanthanum(III) selenide (page does not exist)">La<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Cerium_monoselenide" title="Cerium monoselenide">CeSe</a><br /><a href="/w/index.php?title=Cerium(III)_selenide&action=edit&redlink=1" class="new" title="Cerium(III) selenide (page does not exist)">Ce<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Praseodymium_monoselenide" title="Praseodymium monoselenide">PrSe</a><br /><a href="/w/index.php?title=Praseodymium(III)_selenide&action=edit&redlink=1" class="new" title="Praseodymium(III) selenide (page does not exist)">Pr<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Neodymium_monoselenide&action=edit&redlink=1" class="new" title="Neodymium monoselenide (page does not exist)">NdSe</a><br /><a href="/w/index.php?title=Neodymium(III)_selenide&action=edit&redlink=1" class="new" title="Neodymium(III) selenide (page does not exist)">Nd<sub>2</sub>Se<sub>3</sub></a> </td> <td>Pm </td> <td><a href="/wiki/Samarium(II)_selenide" class="mw-redirect" title="Samarium(II) selenide">SmSe</a><br /><a href="/w/index.php?title=Samarium(III)_selenide&action=edit&redlink=1" class="new" title="Samarium(III) selenide (page does not exist)">Sm<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Europium_monoselenide" title="Europium monoselenide">EuSe</a><br /><a href="/wiki/Europium(III)_selenide" title="Europium(III) selenide">Eu<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Gadolinium_monoselenide&action=edit&redlink=1" class="new" title="Gadolinium monoselenide (page does not exist)">GdSe</a><br /><a href="/w/index.php?title=Gadolinium(III)_selenide&action=edit&redlink=1" class="new" title="Gadolinium(III) selenide (page does not exist)">Gd<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Terbium_monoselenide" title="Terbium monoselenide">TbSe</a><br /><a href="/w/index.php?title=Terbium(III)_selenide&action=edit&redlink=1" class="new" title="Terbium(III) selenide (page does not exist)">Tb<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Dysprosium_monoselenide&action=edit&redlink=1" class="new" title="Dysprosium monoselenide (page does not exist)">DySe</a><br /><a href="/wiki/Dysprosium(III)_selenide" title="Dysprosium(III) selenide">Dy<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Holmium_monoselenide&action=edit&redlink=1" class="new" title="Holmium monoselenide (page does not exist)">HoSe</a><br /><a href="/wiki/Holmium(III)_selenide" title="Holmium(III) selenide">Ho<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Erbium_monoselenide&action=edit&redlink=1" class="new" title="Erbium monoselenide (page does not exist)">ErSe</a><br /><a href="/wiki/Erbium(III)_selenide" title="Erbium(III) selenide">Er<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/wiki/Thulium_monoselenide" title="Thulium monoselenide">TmSe</a><br /><a href="/wiki/Thulium(III)_selenide" title="Thulium(III) selenide">Tm<sub>2</sub>Se<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Ytterbium_monoselenide&action=edit&redlink=1" class="new" title="Ytterbium monoselenide (page does not exist)">YbSe</a><br /><a href="/w/index.php?title=Ytterbium(III)_selenide&action=edit&redlink=1" class="new" title="Ytterbium(III) selenide (page does not exist)">Yb<sub>2</sub>Se<sub>3</sub></a> </td></tr> <tr style="background-color:mistyrose;color:black;"> <td style="background-color:white;color:inherit;border:none">** </td> <td>Ac </td> <td><a href="/wiki/Thorium_diselenide" title="Thorium diselenide">ThSe<sub>2</sub></a> </td> <td>Pa </td> <td><a href="/wiki/Uranium_diselenide" title="Uranium diselenide">USe<sub>2</sub></a> </td> <td>Np </td> <td><a href="/wiki/Plutonium_selenide" title="Plutonium selenide">PuSe</a> </td> <td>Am </td> <td>Cm </td> <td>Bk </td> <td>Cf </td> <td>Es </td> <td>Fm </td> <td>Md </td> <td>No </td></tr></tbody></table></div> </div></td></tr></tbody></table></div> <!-- NewPP limit report Parsed by mw‐api‐int.codfw.main‐54c7cf74fd‐pw226 Cached time: 20250316114137 Cache expiry: 2592000 Reduced expiry: false Complications: [vary‐revision‐sha1, show‐toc] CPU time usage: 1.696 seconds Real time usage: 1.788 seconds Preprocessor visited node count: 12202/1000000 Post‐expand include size: 449761/2097152 bytes Template argument size: 4773/2097152 bytes Highest expansion 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