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metal extraction</title> <meta name="description" content="Search results for: rare-earth metal extraction"> <meta name="keywords" content="rare-earth metal extraction"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="rare-earth metal extraction"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 4316</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: rare-earth metal extraction</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4316</span> An Automatic Feature Extraction Technique for 2D Punch Shapes</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Awais%20Ahmad%20Khan">Awais Ahmad Khan</a>, <a href="https://publications.waset.org/abstracts/search?q=Emad%20Abouel%20Nasr"> Emad Abouel Nasr</a>, <a href="https://publications.waset.org/abstracts/search?q=H.%20M.%20A.%20Hussein"> H. M. A. Hussein</a>, <a href="https://publications.waset.org/abstracts/search?q=Abdulrahman%20Al-Ahmari"> Abdulrahman Al-Ahmari</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Sheet-metal parts have been widely applied in electronics, communication and mechanical industries in recent decades; but the advancement in sheet-metal part design and manufacturing is still behind in comparison with the increasing importance of sheet-metal parts in modern industry. This paper presents a methodology for automatic extraction of some common 2D internal sheet metal features. The features used in this study are taken from Unipunch ™ catalogue. The extraction process starts with the data extraction from STEP file using an object oriented approach and with the application of suitable algorithms and rules, all features contained in the catalogue are automatically extracted. Since the extracted features include geometry and engineering information, they will be effective for downstream application such as feature rebuilding and process planning. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=feature%20extraction" title="feature extraction">feature extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=internal%20features" title=" internal features"> internal features</a>, <a href="https://publications.waset.org/abstracts/search?q=punch%20shapes" title=" punch shapes"> punch shapes</a>, <a href="https://publications.waset.org/abstracts/search?q=sheet%20metal" title=" sheet metal"> sheet metal</a> </p> <a href="https://publications.waset.org/abstracts/45001/an-automatic-feature-extraction-technique-for-2d-punch-shapes" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/45001.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">616</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4315</span> Optimization of Synergism Extraction of Toxic Metals (Lead, Copper) from Chlorides Solutions with Mixture of Cationic and Solvating Extractants</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=F.%20Hassaine-Sadi">F. Hassaine-Sadi</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Chelouaou"> S. Chelouaou</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In recent years, environmental contamination by toxic metals such as Pb, Cu, Ni, Zn ... has become a worldwide crucial problem, particularly in some areas where the population depends on groundwater for drinking daily consumption. Thus, the sources of metal ions come from the metal manufacturing industry, fertilizers, batteries, paints, pigments and so on. Solvent extraction of metal ions has given an important role in the development of metal purification processes such as the synergistic extraction of some divalent cations metals ( M²⁺), the ions metals from various sources. This work consists of a water purification technique that involves the lead and copper systems: Pb²⁺, H₃O+, Cl⁻ and Cu²⁺, H₃O⁺, Cl⁻ for diluted solutions by a mixture of tri-n-octylphosphine oxide (TOPO) or Tri-n-butylphosphate(TBP) and di (2-ethyl hexyl) phosphoric acid (HDEHP) dissolved in kerosene. The study of the fundamental parameters influencing the extraction synergism: cation exchange/extraction solvent have been examined. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=synergistic%20extraction" title="synergistic extraction">synergistic extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=lead" title=" lead"> lead</a>, <a href="https://publications.waset.org/abstracts/search?q=copper" title=" copper"> copper</a>, <a href="https://publications.waset.org/abstracts/search?q=environment" title=" environment"> environment</a> </p> <a href="https://publications.waset.org/abstracts/80847/optimization-of-synergism-extraction-of-toxic-metals-lead-copper-from-chlorides-solutions-with-mixture-of-cationic-and-solvating-extractants" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/80847.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">445</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4314</span> Analytical Study of Cobalt(II) and Nickel(II) Extraction with Salicylidene O-, M-, and P-Toluidine in Chloroform</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sana%20Almi">Sana Almi</a>, <a href="https://publications.waset.org/abstracts/search?q=Djamel%20Barkat"> Djamel Barkat </a> </p> <p class="card-text"><strong>Abstract:</strong></p> The solvent extraction of cobalt (II) and nickel (II) from aqueous sulfate solutions were investigated with the analytical methods of slope analysis using salicylidene aniline and the three isomeric o-, m- and p-salicylidene toluidine diluted with chloroform at 25°C. By a statistical analysis of the extraction data, it was concluded that the extracted species are CoL2 with CoL2(HL) and NiL2 (HL denotes HSA, HSOT, HSMT, and HSPT). The extraction efficiency of Co(II) was higher than Ni(II). This tendency is confirmed from numerical extraction constants for each metal cations. The best extraction was according to the following order: HSMT > HSPT > HSOT > HSA for Co2+ and Ni2+. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=solvent%20extraction" title="solvent extraction">solvent extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel%28II%29" title=" nickel(II)"> nickel(II)</a>, <a href="https://publications.waset.org/abstracts/search?q=cobalt%28II%29" title=" cobalt(II)"> cobalt(II)</a>, <a href="https://publications.waset.org/abstracts/search?q=salicylidene%20aniline" title=" salicylidene aniline"> salicylidene aniline</a>, <a href="https://publications.waset.org/abstracts/search?q=o-" title=" o-"> o-</a>, <a href="https://publications.waset.org/abstracts/search?q=m-" title=" m-"> m-</a>, <a href="https://publications.waset.org/abstracts/search?q=and%20p-salicylidene%20toluidine" title=" and p-salicylidene toluidine"> and p-salicylidene toluidine</a> </p> <a href="https://publications.waset.org/abstracts/21677/analytical-study-of-cobaltii-and-nickelii-extraction-with-salicylidene-o-m-and-p-toluidine-in-chloroform" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/21677.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">484</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4313</span> Gas Phase Extraction: An Environmentally Sustainable and Effective Method for The Extraction and Recovery of Metal from Ores</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kolela%20J%20Nyembwe">Kolela J Nyembwe</a>, <a href="https://publications.waset.org/abstracts/search?q=Darlington%20C.%20Ashiegbu"> Darlington C. Ashiegbu</a>, <a href="https://publications.waset.org/abstracts/search?q=Herman%20J.%20Potgieter"> Herman J. Potgieter</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Over the past few decades, the demand for metals has increased significantly. This has led to a decrease and decline of high-grade ore over time and an increase in mineral complexity and matrix heterogeneity. In addition to that, there are rising concerns about greener processes and a sustainable environment. Due to these challenges, the mining and metal industry has been forced to develop new technologies that are able to economically process and recover metallic values from low-grade ores, materials having a metal content locked up in industrially processed residues (tailings and slag), and complex matrix mineral deposits. Several methods to address these issues have been developed, among which are ionic liquids (IL), heap leaching, and bioleaching. Recently, the gas phase extraction technique has been gaining interest because it eliminates many of the problems encountered in conventional mineral processing methods. The technique relies on the formation of volatile metal complexes, which can be removed from the residual solids by a carrier gas. The complexes can then be reduced using the appropriate method to obtain the metal and regenerate-recover the organic extractant. Laboratory work on the gas phase have been conducted for the extraction and recovery of aluminium (Al), iron (Fe), copper (Cu), chrome (Cr), nickel (Ni), lead (Pb), and vanadium V. In all cases the extraction revealed to depend of temperature and mineral surface area. The process technology appears very promising, offers the feasibility of recirculation, organic reagent regeneration, and has the potential to deliver on all promises of a “greener” process. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=gas-phase%20extraction" title="gas-phase extraction">gas-phase extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrometallurgy" title=" hydrometallurgy"> hydrometallurgy</a>, <a href="https://publications.waset.org/abstracts/search?q=low-grade%20ore" title=" low-grade ore"> low-grade ore</a>, <a href="https://publications.waset.org/abstracts/search?q=sustainable%20environment" title=" sustainable environment"> sustainable environment</a> </p> <a href="https://publications.waset.org/abstracts/157981/gas-phase-extraction-an-environmentally-sustainable-and-effective-method-for-the-extraction-and-recovery-of-metal-from-ores" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/157981.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">132</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4312</span> Removal Cobalt (II) and Copper (II) by Solvent Extraction from Sulfate Solutions by Capric Acid in Chloroform</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=A.%20Bara">A. Bara</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Barkat"> D. Barkat</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Liquid-liquid extraction is one of the most useful techniques for selective removal and recovery of metal ions from aqueous solutions, applied in purification processes in numerous chemical and metallurgical industries. In this work, The liquid-liquid extraction of cobalt (II) and copper (II) from aqueous solution by capric acid (HL) in chloroform at 25°C has been studied. Our interest in this paper is to study the effect of concentration of capric acid on the extraction of Co(II) and Cu(II) to see the complexes could be formed in the organic phase using various concentration of capric acid. The extraction of cobalt (II) and copper (II) is extracted as the complex CoL2 (HL )2, CuL2 (HL)2. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=capric%20acid" title="capric acid">capric acid</a>, <a href="https://publications.waset.org/abstracts/search?q=Cobalt%28II%29" title=" Cobalt(II)"> Cobalt(II)</a>, <a href="https://publications.waset.org/abstracts/search?q=copper%28II%29" title=" copper(II)"> copper(II)</a>, <a href="https://publications.waset.org/abstracts/search?q=liquid-liquid%20extraction" title=" liquid-liquid extraction "> liquid-liquid extraction </a> </p> <a href="https://publications.waset.org/abstracts/27656/removal-cobalt-ii-and-copper-ii-by-solvent-extraction-from-sulfate-solutions-by-capric-acid-in-chloroform" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/27656.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">441</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4311</span> Metal Extraction into Ionic Liquids and Hydrophobic Deep Eutectic Mixtures</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=E.%20E.%20Tereshatov">E. E. Tereshatov</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Yu.%20Boltoeva"> M. Yu. Boltoeva</a>, <a href="https://publications.waset.org/abstracts/search?q=V.%20Mazan"> V. Mazan</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20F.%20Volia"> M. F. Volia</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20M.%20Folden%20III"> C. M. Folden III</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Room temperature ionic liquids (RTILs) are a class of liquid organic salts with melting points below 20 °C that are considered to be environmentally friendly ‘designers’ solvents. Pure hydrophobic ILs are known to extract metallic species from aqueous solutions. The closest analogues of ionic liquids are deep eutectic solvents (DESs), which are a eutectic mixture of at least two compounds with a melting point lower than that of each individual component. DESs are acknowledged to be attractive for organic synthesis and metal processing. Thus, these non-volatile and less toxic compounds are of interest for critical metal extraction. The US Department of Energy and the European Commission consider indium as a key metal. Its chemical homologue, thallium, is also an important material for some applications and environmental safety. The aim of this work is to systematically investigate In and Tl extraction from aqueous solutions into pure fluorinated ILs and hydrophobic DESs. The dependence of the Tl extraction efficiency on the structure and composition of the ionic liquid ions, metal oxidation state, and initial metal and aqueous acid concentrations have been studied. The extraction efficiency of the TlXz3–z anionic species (where X = Cl– and/or Br–) is greater for ionic liquids with more hydrophobic cations. Unexpectedly high distribution ratios (> 103) of Tl(III) were determined even by applying a pure ionic liquid as receiving phase. An improved mathematical model based on ion exchange and ion pair formation mechanisms has been developed to describe the co-extraction of two different anionic species, and the relative contributions of each mechanism have been determined. The first evidence of indium extraction into new quaternary ammonium- and menthol-based hydrophobic DESs from hydrochloric and oxalic acid solutions with distribution ratios up to 103 will be provided. Data obtained allow us to interpret the mechanism of thallium and indium extraction into ILs and DESs media. The understanding of Tl and In chemical behavior in these new media is imperative for the further improvement of separation and purification of these elements. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=deep%20eutectic%20solvents" title="deep eutectic solvents">deep eutectic solvents</a>, <a href="https://publications.waset.org/abstracts/search?q=indium" title=" indium"> indium</a>, <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquids" title=" ionic liquids"> ionic liquids</a>, <a href="https://publications.waset.org/abstracts/search?q=thallium" title=" thallium"> thallium</a> </p> <a href="https://publications.waset.org/abstracts/44043/metal-extraction-into-ionic-liquids-and-hydrophobic-deep-eutectic-mixtures" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/44043.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">241</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4310</span> The Effect of Supercritical Fluid on the Extraction Efficiency of Heavy Metal from Soil</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Haifa%20El-Sadi">Haifa El-Sadi</a>, <a href="https://publications.waset.org/abstracts/search?q=Maria%20Elektorowicz"> Maria Elektorowicz</a>, <a href="https://publications.waset.org/abstracts/search?q=Reed%20Rushing"> Reed Rushing</a>, <a href="https://publications.waset.org/abstracts/search?q=Ammar%20Badawieh"> Ammar Badawieh</a>, <a href="https://publications.waset.org/abstracts/search?q=Asif%20Chaudry"> Asif Chaudry </a> </p> <p class="card-text"><strong>Abstract:</strong></p> Clay soils have particular properties that affect the assessment and remediation of contaminated sites. In clay soils, electro-kinetic transport of heavy metals has been carried out. The transport of these metals is predicated on maintaining a low pH throughout the cell, which, in turn, keeps the metals in the pore water phase where they are accessible to electro-kinetic transport. Supercritical fluid extraction and acid digestion were used for the analysis of heavy metals concentrations after the completion of electro-kinetic experimentation. Supercritical fluid (carbon dioxide) extraction is a new technique used to extract the heavy metal (lead, nickel, calcium and potassium) from clayey soil. The comparison between supercritical extraction and acid digestion of different metals was carried out. Supercritical fluid extraction, using ethylenediaminetetraacetic acid (EDTA) as a modifier, proved to be efficient and a safer technique than acid digestion technique in extracting metals from clayey soil. Mixing time of soil with EDTA before extracting heavy metals from clayey soil was investigated. The optimum and most practical shaking time for the extraction of lead, nickel, calcium and potassium was two hours. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=clay%20soil" title="clay soil">clay soil</a>, <a href="https://publications.waset.org/abstracts/search?q=heavy%20metals" title=" heavy metals"> heavy metals</a>, <a href="https://publications.waset.org/abstracts/search?q=supercritical%20fluid%20extraction" title=" supercritical fluid extraction"> supercritical fluid extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=acid%20digestion" title=" acid digestion"> acid digestion</a> </p> <a href="https://publications.waset.org/abstracts/8297/the-effect-of-supercritical-fluid-on-the-extraction-efficiency-of-heavy-metal-from-soil" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/8297.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">466</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4309</span> The Solvent Extraction of Uranium, Plutonium and Thorium from Aqueous Solution by 1-Hydroxyhexadecylidene-1,1-Diphosphonic Acid </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Bouhoun%20Ali">M. Bouhoun Ali</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Y.%20Badjah%20Hadj%20Ahmed"> A. Y. Badjah Hadj Ahmed</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Attou"> M. Attou</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Elias"> A. Elias</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20A.%20Didi"> M. A. Didi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this paper, the solvent extraction of uranium(VI), plutonium(IV) and thorium(IV) from aqueous solutions using 1-hydroxyhexadecylidene-1,1-diphosphonic acid (HHDPA) in treated kerosene has been investigated. The HHDPA was previously synthesized and characterized by FT-IR, 1H NMR, 31P NMR spectroscopy and elemental analysis. The effects contact time, initial pH, initial metal concentration, aqueous/organic phase ratio, extractant concentration and temperature on the extraction process have been studied. An empirical modelling was performed by using a 25 full factorial design, and regression equation for extraction metals was determined from the data. The conventional log-log analysis of the extraction data reveals that ratios of extractant to extracted U(VI), Pu(IV) and Th(IV) are 1:1, 1:2 and 1:2, respectively. Thermodynamic parameters showed that the extraction process was exothermic heat and spontaneous. The obtained optimal parameters were applied to real efﬂuents containing uranium(VI), plutonium(IV) and thorium(IV) ions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=solvent%20extraction" title="solvent extraction">solvent extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=uranium" title=" uranium"> uranium</a>, <a href="https://publications.waset.org/abstracts/search?q=plutonium" title=" plutonium"> plutonium</a>, <a href="https://publications.waset.org/abstracts/search?q=thorium" title=" thorium"> thorium</a>, <a href="https://publications.waset.org/abstracts/search?q=1-hydroxyhexadecylidene-1-1-diphosphonic%20acid" title=" 1-hydroxyhexadecylidene-1-1-diphosphonic acid"> 1-hydroxyhexadecylidene-1-1-diphosphonic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=aqueous%20solution" title=" aqueous solution"> aqueous solution</a> </p> <a href="https://publications.waset.org/abstracts/37851/the-solvent-extraction-of-uranium-plutonium-and-thorium-from-aqueous-solution-by-1-hydroxyhexadecylidene-11-diphosphonic-acid" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/37851.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">288</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4308</span> Separation of Copper(II) and Iron(III) by Solvent Extraction and Membrane Processes with Ionic Liquids as Carriers</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Beata%20Pospiech">Beata Pospiech</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Separation of metal ions from aqueous solutions is important as well as difficult process in hydrometallurgical technology. This process is necessary for obtaining of clean metals. Solvent extraction and membrane processes are well known as separation methods. Recently, ionic liquids (ILs) are very often applied and studied as extractants and carriers of metal ions from aqueous solutions due to their good extractability properties for various metals. This work discusses a method to separate copper(II) and iron(III) from hydrochloric acid solutions by solvent extraction and transport across polymer inclusion membranes (PIM) with the selected ionic liquids as extractants/ion carriers. Cyphos IL 101 (trihexyl(tetradecyl)phosphonium chloride), Cyphos IL 104 (trihexyl(tetradecyl)phosphonium bis(2,4,4 trimethylpentyl)phosphi-nate), trioctylmethylammonium thiosalicylate [A336][TS] and trihexyl(tetradecyl)phosphonium thiosalicylate [PR4][TS] were used for the investigations. Effect of different parameters such as hydrochloric acid concentration in aqueous phase on iron(III) and copper(II) extraction has been investigated. Cellulose triacetate membranes with the selected ionic liquids as carriers have been prepared and applied for transport of iron(IIII) and copper(II) from hydrochloric acid solutions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=copper" title="copper">copper</a>, <a href="https://publications.waset.org/abstracts/search?q=iron" title=" iron"> iron</a>, <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquids" title=" ionic liquids"> ionic liquids</a>, <a href="https://publications.waset.org/abstracts/search?q=solvent%20extraction" title=" solvent extraction"> solvent extraction</a> </p> <a href="https://publications.waset.org/abstracts/58770/separation-of-copperii-and-ironiii-by-solvent-extraction-and-membrane-processes-with-ionic-liquids-as-carriers" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/58770.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">279</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4307</span> Lead in The Soil-Plant System Following Aged Contamination from Ceramic Wastes</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=F.%20Pedron">F. Pedron</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Grifoni"> M. Grifoni</a>, <a href="https://publications.waset.org/abstracts/search?q=G.%20Petruzzelli"> G. Petruzzelli</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Barbafieri"> M. Barbafieri</a>, <a href="https://publications.waset.org/abstracts/search?q=I.%20Rosellini"> I. Rosellini</a>, <a href="https://publications.waset.org/abstracts/search?q=B.%20Pezzarossa"> B. Pezzarossa</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Lead contamination of agricultural land mainly vegetated with perennial ryegrass (<em>Lolium perenne</em>) has been investigated. The metal derived from the discharge of sludge from a ceramic industry in the past had used lead paints. The results showed very high values of lead concentration in many soil samples. In order to assess the lead soil contamination, a sequential extraction with H<sub>2</sub>O, KNO<sub>3</sub>, EDTA was performed, and the chemical forms of lead in the soil were evaluated. More than 70% of lead was in a potentially bioavailable form. Analysis of <em>Lolium perenne</em> showed elevated lead concentration. A Freundlich-like model was used to describe the transferability of the metal from the soil to the plant. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bioavailability" title="bioavailability">bioavailability</a>, <a href="https://publications.waset.org/abstracts/search?q=Freundlich-like%20equation" title=" Freundlich-like equation"> Freundlich-like equation</a>, <a href="https://publications.waset.org/abstracts/search?q=sequential%20extraction" title=" sequential extraction"> sequential extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=soil%20lead%20contamination" title=" soil lead contamination"> soil lead contamination</a> </p> <a href="https://publications.waset.org/abstracts/90618/lead-in-the-soil-plant-system-following-aged-contamination-from-ceramic-wastes" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/90618.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">310</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4306</span> Mechanisms of Ginger Bioactive Compounds Extract Using Soxhlet and Accelerated Water Extraction</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20N.%20Azian">M. N. Azian</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20N.%20Ilia%20Anisa"> A. N. Ilia Anisa</a>, <a href="https://publications.waset.org/abstracts/search?q=Y.%20Iwai"> Y. Iwai</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The mechanism for extraction bioactive compounds from plant matrix is essential for optimizing the extraction process. As a benchmark technique, a soxhlet extraction has been utilized for discussing the mechanism and compared with an accelerated water extraction. The trends of both techniques show that the process involves extraction and degradation. The highest yields of 6-, 8-, 10-gingerols and 6-shogaol in soxhlet extraction were 13.948, 7.12, 10.312 and 2.306 mg/g, respectively. The optimum 6-, 8-, 10-gingerols and 6-shogaol extracted by the accelerated water extraction at 140oC were 68.97±3.95 mg/g at 3min, 18.98±3.04 mg/g at 5min, 5.167±2.35 mg/g at 3min and 14.57±6.27 mg/g at 3min, respectively. The effect of temperature at 3mins shows that the concentration of 6-shogaol increased rapidly as decreasing the recovery of 6-gingerol. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=mechanism" title="mechanism">mechanism</a>, <a href="https://publications.waset.org/abstracts/search?q=ginger%20bioactive%20compounds" title=" ginger bioactive compounds"> ginger bioactive compounds</a>, <a href="https://publications.waset.org/abstracts/search?q=soxhlet%20extraction" title=" soxhlet extraction"> soxhlet extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=accelerated%20water%20extraction" title=" accelerated water extraction"> accelerated water extraction</a> </p> <a href="https://publications.waset.org/abstracts/9278/mechanisms-of-ginger-bioactive-compounds-extract-using-soxhlet-and-accelerated-water-extraction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/9278.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">434</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4305</span> Study of the Adsorption of Metal Ions Ag+ Mg2+, Ni2+ by the Chemical and Electrochemical Polydibenzoether Crown</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dalila%20Chouder">Dalila Chouder</a>, <a href="https://publications.waset.org/abstracts/search?q=Djaafer%20Benachour"> Djaafer Benachour</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This work concerns the study of the adsorption of metal ions Ag +, Mg +, and Ni2+ in aqueous medium by polydibenzoether-ROWN based on three factors: Temperature, time and concentration. The polydibenzoether crown was synthesized by two means: Chemical and electrochemical. The behavior of the two polymers has been different, and turns out very interesting for chemical polydibenzoether crown has identified conditions. Chemical and électronique polydibenzoether crown have different extraction screw vi property of adsoption of ions fifférents, this study also shows that plyméres doped may have an advantageous electrical conductivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=polymerization" title="polymerization">polymerization</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical" title=" electrochemical"> electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=conductivity" title=" conductivity"> conductivity</a>, <a href="https://publications.waset.org/abstracts/search?q=complexing%20metal%20ions" title=" complexing metal ions"> complexing metal ions</a> </p> <a href="https://publications.waset.org/abstracts/26255/study-of-the-adsorption-of-metal-ions-ag-mg2-ni2-by-the-chemical-and-electrochemical-polydibenzoether-crown" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/26255.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">264</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4304</span> N-Type GaN Thinning for Enhancing Light Extraction Efficiency in GaN-Based Thin-Film Flip-Chip Ultraviolet (UV) Light Emitting Diodes (LED)</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Anil%20Kawan">Anil Kawan</a>, <a href="https://publications.waset.org/abstracts/search?q=Soon%20Jae%20Yu"> Soon Jae Yu</a>, <a href="https://publications.waset.org/abstracts/search?q=Jong%20Min%20Park"> Jong Min Park</a> </p> <p class="card-text"><strong>Abstract:</strong></p> GaN-based 365 nm wavelength ultraviolet (UV) light emitting diodes (LED) have various applications: curing, molding, purification, deodorization, and disinfection etc. However, their usage is limited by very low output power, because of the light absorption in the GaN layers. In this study, we demonstrate a method utilizing removal of 365 nm absorption layer buffer GaN and thinning the n-type GaN so as to improve the light extraction efficiency of the GaN-based 365 nm UV LED. The UV flip chip LEDs of chip size 1.3 mm x 1.3 mm were fabricated using GaN epilayers on a sapphire substrate. Via-hole n-type contacts and highly reflective Ag metal were used for efficient light extraction. LED wafer was aligned and bonded to AlN carrier wafer. To improve the extraction efficiency of the flip chip LED, sapphire substrate and absorption layer buffer GaN were removed by using laser lift-off and dry etching, respectively. To further increase the extraction efficiency of the LED, exposed n-type GaN thickness was reduced by using inductively coupled plasma etching. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=extraction%20efficiency" title="extraction efficiency">extraction efficiency</a>, <a href="https://publications.waset.org/abstracts/search?q=light%20emitting%20diodes" title=" light emitting diodes"> light emitting diodes</a>, <a href="https://publications.waset.org/abstracts/search?q=n-GaN%20thinning" title=" n-GaN thinning"> n-GaN thinning</a>, <a href="https://publications.waset.org/abstracts/search?q=ultraviolet" title=" ultraviolet"> ultraviolet</a> </p> <a href="https://publications.waset.org/abstracts/61185/n-type-gan-thinning-for-enhancing-light-extraction-efficiency-in-gan-based-thin-film-flip-chip-ultraviolet-uv-light-emitting-diodes-led" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/61185.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">426</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4303</span> Chemical Partitioning of Trace Metals in Sub-Surface Sediments of Lake Acigol, Denizli, Turkey</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Budakoglu">M. Budakoglu</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Karaman"> M. Karaman</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Kiran"> D. Kiran</a>, <a href="https://publications.waset.org/abstracts/search?q=Z.%20Doner"> Z. Doner</a>, <a href="https://publications.waset.org/abstracts/search?q=B.%20Zeytuncu"> B. Zeytuncu</a>, <a href="https://publications.waset.org/abstracts/search?q=B.%20Tan%C3%A7"> B. Tanç</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Kumral"> M. Kumral</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Lake Acıgöl is one of the large saline lacustrine environment in Turkey. Eleven trace metals (Cr, Mn, Fe, Al, Co, Ni, Cu, Zn, Cd, Pb and As) in 9 surface and subsurface sediment samples from the Lake Acıgöl were analyzed with the bulk and sequential extraction analysis methods by ICP-MS to obtain the metal distribution patterns in this extreme environment. Five stepped sequential extraction technique (1- exchangeable, 2- bond to carbonates, 3- bond to iron and manganese oxides/hydroxides, 4- bond to organic matter and sulphides, and 5- residual fraction incorporated into clay and silicate mineral lattices) was used to characterize the various forms of metals in the <63μ size sediments. The metal contents (ppm) and their percentages for each extraction step were reported and compared with the results obtained from the total digestion. Results indicate that sum of the four fraction are in good agreement with the total digestion results of Ni, Cd, As, Zn, Cu and Fe with the satisfactory recoveries (94.04–109.0%) and the method used is reliable and repeatable for these elements. It was found that there were high correlations between Fe vs. Ni loads in the fraction of F2 and F4 with R2= 0,91 and 0,81, respectively. Comparison of totally 135 chemical analysis results in three sampling location and for 5 fraction between Fe-Co, Co-Ni and Fe-Ni element couples were presented elevated correlations with R2=0,98, 0,92 and 0,91, respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Lake%20Acigol" title="Lake Acigol">Lake Acigol</a>, <a href="https://publications.waset.org/abstracts/search?q=sequancial%20extraction" title=" sequancial extraction"> sequancial extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=recent%20lake%20sediment" title=" recent lake sediment"> recent lake sediment</a>, <a href="https://publications.waset.org/abstracts/search?q=geochemical%20speciation%20of%20heavy%20metals" title=" geochemical speciation of heavy metals "> geochemical speciation of heavy metals </a> </p> <a href="https://publications.waset.org/abstracts/10637/chemical-partitioning-of-trace-metals-in-sub-surface-sediments-of-lake-acigol-denizli-turkey" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/10637.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">412</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4302</span> Optimization of Process Parameters using Response Surface Methodology for the Removal of Zinc(II) by Solvent Extraction </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=B.%20Guezzen">B. Guezzen</a>, <a href="https://publications.waset.org/abstracts/search?q=M.A.%20Didi"> M.A. Didi</a>, <a href="https://publications.waset.org/abstracts/search?q=B.%20Medjahed"> B. Medjahed</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A factorial design of experiments and a response surface methodology were implemented to investigate the liquid-liquid extraction process of zinc (II) from acetate medium using the 1-Butyl-imidazolium di(2-ethylhexyl) phosphate [BIm<sup>+</sup>][D2EHP<sup>-</sup>]. The optimization process of extraction parameters such as the initial pH effect (2.5, 4.5, and 6.6), ionic liquid concentration (1, 5.5, and 10 mM) and salt effect (0.01, 5, and 10 mM) was carried out using a three-level full factorial design (3<sup>3</sup>). The results of the factorial design demonstrate that all these factors are statistically significant, including the square effects of pH and ionic liquid concentration. The results showed that the order of significance: IL concentration > salt effect > initial pH. Analysis of variance (ANOVA) showing high coefficient of determination (R<sup>2</sup> = 0.91) and low probability values (P < 0.05) signifies the validity of the predicted second-order quadratic model for Zn (II) extraction. The optimum conditions for the extraction of zinc (II) at the constant temperature (20 °C), initial Zn (II) concentration (1mM) and A/O ratio of unity were: initial pH (4.8), extractant concentration (9.9 mM), and NaCl concentration (8.2 mM). At the optimized condition, the metal ion could be quantitatively extracted. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquid" title="ionic liquid">ionic liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=response%20surface%20methodology" title=" response surface methodology"> response surface methodology</a>, <a href="https://publications.waset.org/abstracts/search?q=solvent%20extraction" title=" solvent extraction"> solvent extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=zinc%20acetate" title=" zinc acetate"> zinc acetate</a> </p> <a href="https://publications.waset.org/abstracts/57289/optimization-of-process-parameters-using-response-surface-methodology-for-the-removal-of-zincii-by-solvent-extraction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/57289.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">374</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4301</span> Development of Metal-Organic Frameworks-Type Hybrid Functionalized Materials for Selective Uranium Extraction</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Damien%20Rinsant">Damien Rinsant</a>, <a href="https://publications.waset.org/abstracts/search?q=Eugen%20Andreiadis"> Eugen Andreiadis</a>, <a href="https://publications.waset.org/abstracts/search?q=Michael%20Carboni"> Michael Carboni</a>, <a href="https://publications.waset.org/abstracts/search?q=Daniel%20Meyer"> Daniel Meyer</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Different types of materials have been developed for the solid/liquid uranium extraction processes, such as functionalized organic polymers, hybrid silica or inorganic adsorbents. In general, these materials exhibit a moderate affinity for uranyl ions and poor selectivity against impurities like iron, vanadium or molybdenum. Moreover, the structural organization deficiency of these materials generates ion diffusion issues inside the material. Therefore, the aim of our study is to developed efficient and organized materials, stable in the acid media encountered in uranium extraction processes. Metal organic frameworks (MOFs) are hybrid crystalline materials consisting of an inorganic part (cluster or metal ions) and tailored organic linkers connected via coordination bonds. These hierarchical materials have exceptional surface area, thermal stability and a large variety of tunable structures. However, due to the reversibility of constitutive coordination bonds, MOFs have moderate stability in strongly complexing or acidic media. Only few of them are known to be stable in aqueous media and only one example is described in strong acidic media. However, these conditions are very often encountered in the environmental pollution remediation of mine wastewaters. To tackle the challenge of developing MOFs adapted for uranium extraction from acid mine waters, we have investigated the stability of several materials. To ensure a good stability we have synthetized and characterized different materials based on highly coordinated metal clusters, such as LnOFs and Zirconium based materials. Among the latter, the UiO family shows a great stability in sulfuric acid media even in the presence of 1.4 M sodium sulfate at pH 2. However, the stability in phosphoric media is reduced due to the high affinity between zirconium and phosphate ligand. Based on these results, we have developed a tertiary amine functionalized MOF denoted UiO-68-NMe2 particularly adapted for the extraction of anionic uranyl (VI) sulfate complexes mainly present in the acid mine solutions. The adsorption capacity of the material has been determined upon varying total sulfate concentration, contact time and uranium concentration. The extraction tests put in evidence different phenomena due to the complexity of the extraction media and the interaction between the MOF and sulfate anion. Finally, the extraction mechanisms and the interaction between uranyl and the MOF structure have been investigated. The functionalized material UiO-68-NMe2 has been characterized in the presence and absence of uranium by FT-IR, UV and Raman techniques. Moreover, the stability of the protonated amino functionalized MOF has been evaluated. The synthesis, characterization and evaluation of this type of hybrid material, particularly adapted for uranium extraction in sulfuric acid media by an anionic exchange mechanism, paved the way for the development of metal organic frameworks functionalized by different other chelating motifs, such as bifunctional ligands showing an enhanced affinity and selectivity for uranium in acid and complexing media. Work in this direction is currently in progress. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=extraction" title="extraction">extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=MOF" title=" MOF"> MOF</a>, <a href="https://publications.waset.org/abstracts/search?q=ligand" title=" ligand"> ligand</a>, <a href="https://publications.waset.org/abstracts/search?q=uranium" title=" uranium"> uranium</a> </p> <a href="https://publications.waset.org/abstracts/97172/development-of-metal-organic-frameworks-type-hybrid-functionalized-materials-for-selective-uranium-extraction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/97172.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">160</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4300</span> Removal of Nickel and Vanadium from Crude Oil by Using Solvent Extraction and Electrochemical Process</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Aliya%20Kurbanova">Aliya Kurbanova</a>, <a href="https://publications.waset.org/abstracts/search?q=Nurlan%20Akhmetov"> Nurlan Akhmetov</a>, <a href="https://publications.waset.org/abstracts/search?q=Abilmansur%20Yeshmuratov"> Abilmansur Yeshmuratov</a>, <a href="https://publications.waset.org/abstracts/search?q=Yerzhigit%20Sugurbekov"> Yerzhigit Sugurbekov</a>, <a href="https://publications.waset.org/abstracts/search?q=Ramiz%20Zulkharnay"> Ramiz Zulkharnay</a>, <a href="https://publications.waset.org/abstracts/search?q=Gulzat%20Demeuova"> Gulzat Demeuova</a>, <a href="https://publications.waset.org/abstracts/search?q=Murat%20Baisariyev"> Murat Baisariyev</a>, <a href="https://publications.waset.org/abstracts/search?q=Gulnar%20Sugurbekova"> Gulnar Sugurbekova</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Last decades crude oils have tended to become more challenge to process due to increasing amounts of sour and heavy crude oils. Some crude oils contain high vanadium and nickel content, for example Pavlodar LLP crude oil, which contains more than 23.09 g/t nickel and 58.59 g/t vanadium. In this study, we used two types of metal removing methods such as solvent extraction and electrochemical. The present research is conducted for comparative analysis of the deasphalting with organic solvents (cyclohexane, carbon tetrachloride, chloroform) and electrochemical method. Applying the cyclic voltametric analysis (CVA) and Inductively coupled plasma mass spectrometry (ICP MS), these mentioned types of metal extraction methods were compared in this paper. Maximum efficiency of deasphalting, with cyclohexane as the solvent, in Soxhlet extractor was 66.4% for nickel and 51.2% for vanadium content from crude oil. Percentage of Ni extraction reached maximum of approximately 55% by using the electrochemical method in electrolysis cell, which was developed for this research and consists of three sections: oil and protonating agent (EtOH) solution between two conducting membranes which divides it from two capsules of 10% sulfuric acid and two graphite electrodes which cover all three parts in electrical circuit. Ions of metals pass through membranes and remain in acid solutions. The best result was obtained in 60 minutes with ethanol to oil ratio 25% to 75% respectively, current fits into the range from 0.3A to 0.4A, voltage changed from 12.8V to 17.3V. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=demetallization" title="demetallization">demetallization</a>, <a href="https://publications.waset.org/abstracts/search?q=deasphalting" title=" deasphalting"> deasphalting</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemical%20removal" title=" electrochemical removal"> electrochemical removal</a>, <a href="https://publications.waset.org/abstracts/search?q=heavy%20metals" title=" heavy metals"> heavy metals</a>, <a href="https://publications.waset.org/abstracts/search?q=petroleum%20engineering" title=" petroleum engineering"> petroleum engineering</a>, <a href="https://publications.waset.org/abstracts/search?q=solvent%20extraction" title=" solvent extraction"> solvent extraction</a> </p> <a href="https://publications.waset.org/abstracts/80594/removal-of-nickel-and-vanadium-from-crude-oil-by-using-solvent-extraction-and-electrochemical-process" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/80594.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">324</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4299</span> Study Mercapto-Nanoscavenger as a Promising Analytical Tool</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mohammed%20M.%20Algaradah">Mohammed M. Algaradah</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A chelating mercapto- nanoscavenger has been developed exploiting the high surface area of monodisperse nano-sized mesoporous silica. The nanoscavenger acts as a solid phase trace metal extractant whilst suspended as a quasi-stable sol in aqueous samples. This mode of extraction requires no external agitation as the particles move naturally through the sample by Brownian motion, convection and slow sedimentation. Careful size selection enables the nanoscavenger to be easily recovered together with the extracted analyte by conventional filtration or centrifugation. The research describes the successful attachment of chelator mercapto to ca. 136 ± 15 nm high surface area (BET surface area = 1006 m2 g-1) mesoporous silica particles. The resulting material had a copper capacity of ca. 1.34 ± 0.10 mmol g-1 and was successfully applied to the collection of a trace element from water. Essentially complete recovery of Cu (II) has been achieved from freshwater samples giving typical preconcentration factors of 100 from 50 µg/l samples. Data obtained from a nanoscavenger-based extraction of copper from samples were not significantly different from those obtained by using a conventional colorimetric procedure employing complexation/solvent extraction. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nano%20scavenger" title="nano scavenger">nano scavenger</a>, <a href="https://publications.waset.org/abstracts/search?q=mesoporous%20silica" title=" mesoporous silica"> mesoporous silica</a>, <a href="https://publications.waset.org/abstracts/search?q=trace%20metal" title=" trace metal"> trace metal</a>, <a href="https://publications.waset.org/abstracts/search?q=preconcentration" title=" preconcentration"> preconcentration</a> </p> <a href="https://publications.waset.org/abstracts/147914/study-mercapto-nanoscavenger-as-a-promising-analytical-tool" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/147914.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">83</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4298</span> Selective Extraction of Couple Nickel(II) / Cobalt(II) by a Series of Schiff Bases in Sulfate Medium, in the Chloroforme-Water</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=N.%20Belhadj">N. Belhadj</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Hadj%20Youcef"> M. Hadj Youcef</a>, <a href="https://publications.waset.org/abstracts/search?q=T.%20Benabdallah"> T. Benabdallah</a>, <a href="https://publications.waset.org/abstracts/search?q=Belbachir%20Ibtissem"> Belbachir Ibtissem</a>, <a href="https://publications.waset.org/abstracts/search?q=N.%20Boceiri"> N. Boceiri</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This work deals with the synthesis, the structural elucidation and the exploration the extracting properties of a series of ortho-hydroxy Schiff base in sulfate medium. After the synthesis and characterization of their structures, the study of their behavior in solution was carried out by pH-metric titration in different media homogeneous and heterogeneous solution. This allowed to explore and to quantify in each of these media, some of their properties in solution such as, their acid-base behavior (determination and comparison of pKa), their distribution powers (determination and comparison of logKd), and their thermodynamic constants (determining ∆H°, ΔS° and ∆G°moy) by optimizing both the temperature and ionic strength. Study of the extraction of nickel (II) and cobalt(II) separately was undertaken in the aqueous-organic system, chloroform-water. Different extraction parameters have been thus optimized such, the pH, the concentration of extractant and the ionic strength, and the extraction constants established in each case. The extracted metal complexes have been isolated and their spatial configurations elucidated. The selective extraction of the couple cobalt (II)/nickel (II) was finally performed by our series of Schiff base in the chloroforme/water. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=selective%20extraction" title="selective extraction">selective extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=Schiff%20base" title=" Schiff base"> Schiff base</a>, <a href="https://publications.waset.org/abstracts/search?q=distribution" title=" distribution"> distribution</a>, <a href="https://publications.waset.org/abstracts/search?q=cobalt%28II%29" title=" cobalt(II)"> cobalt(II)</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel%28II%29" title=" nickel(II)"> nickel(II)</a> </p> <a href="https://publications.waset.org/abstracts/43695/selective-extraction-of-couple-nickelii-cobaltii-by-a-series-of-schiff-bases-in-sulfate-medium-in-the-chloroforme-water" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/43695.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">459</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4297</span> Facile Synthesis of Metal Nanoparticles on Graphene via Galvanic Displacement Reaction for Sensing Application</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Juree%20Hong">Juree Hong</a>, <a href="https://publications.waset.org/abstracts/search?q=Sanggeun%20Lee"> Sanggeun Lee</a>, <a href="https://publications.waset.org/abstracts/search?q=Jungmok%20Seo"> Jungmok Seo</a>, <a href="https://publications.waset.org/abstracts/search?q=Taeyoon%20Lee"> Taeyoon Lee</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We report a facile synthesis of metal nano particles (NPs) on graphene layer via galvanic displacement reaction between graphene-buffered copper (Cu) and metal ion-containing salts. Diverse metal NPs can be formed on graphene surface and their morphologies can be tailored by controlling the concentration of metal ion-containing salt and immersion time. The obtained metal NP-decorated single-layer graphene (SLG) has been used as hydrogen gas (H2) sensing material and exhibited highly sensitive response upon exposure to 2% of H2. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20nanoparticle" title="metal nanoparticle">metal nanoparticle</a>, <a href="https://publications.waset.org/abstracts/search?q=galvanic%20displacement%20reaction" title=" galvanic displacement reaction"> galvanic displacement reaction</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene" title=" graphene"> graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogen%20sensor" title=" hydrogen sensor"> hydrogen sensor</a> </p> <a href="https://publications.waset.org/abstracts/18400/facile-synthesis-of-metal-nanoparticles-on-graphene-via-galvanic-displacement-reaction-for-sensing-application" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/18400.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">424</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4296</span> Functionalized Magnetic Iron Oxide Nanoparticles for Extraction of Protein and Metal Nanoparticles from Complex Fluids</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Meenakshi%20Verma">Meenakshi Verma</a>, <a href="https://publications.waset.org/abstracts/search?q=Mandeep%20Singh%20Bakshi"> Mandeep Singh Bakshi</a>, <a href="https://publications.waset.org/abstracts/search?q=Kultar%20Singh"> Kultar Singh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Magnetic nanoparticles have received incredible importance in view of their diverse applications, which arise primarily due to their response to the external magnetic field. The magnetic behaviour of magnetic nanoparticles (NPs) helps them in numerous different ways. The most important amongst them is the ease with which they can be purified and also can be separated from the media in which they are present merely by applying an external magnetic field. This exceptional ease of separation of the magnetic NPs from an aqueous media enables them to use for extracting/removing metal pollutants from complex aqueous medium. Functionalized magnetic NPs can be subjected for the metallic impurities extraction if are favourably adsorbed on the NPs surfaces. We have successfully used the magnetic NPs as vehicles for gold and silver NPs removal from the complex fluids. The NPs loaded with gold and silver NPs pollutant fractions has been easily removed from the aqueous media by using external magnetic field. Similarly, we have used the magnetic NPs for extraction of protein from complex media and then constantly washed with pure water to eliminate the unwanted surface adsorbed components for quantitative estimation. The purified and protein loaded magnetic NPs are best analyzed with SDS Page to not only for characterization but also for separating the protein fractions. A collective review of the results indicates that we have synthesized surfactant coated iron oxide NPs and then functionalized these with selected materials. These surface active magnetic NPs work very well for the extraction of metallic NPs from the aqueous bulk and make the whole process environmentally sustainable. Also, magnetic NPs-Au/Ag/Pd hybrids have excellent protein extracting properties. They are much easier to use in order to extract the magnetic impurities as well as protein fractions under the effect of external magnetic field without any complex conventional purification methods. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=magnetic%20nanoparticles" title="magnetic nanoparticles">magnetic nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=protein" title=" protein"> protein</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalized" title=" functionalized"> functionalized</a>, <a href="https://publications.waset.org/abstracts/search?q=extraction" title=" extraction"> extraction</a> </p> <a href="https://publications.waset.org/abstracts/122882/functionalized-magnetic-iron-oxide-nanoparticles-for-extraction-of-protein-and-metal-nanoparticles-from-complex-fluids" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/122882.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">99</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4295</span> Prediction of Metals Available to Maize Seedlings in Crude Oil Contaminated Soil</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Stella%20O.%20Olubodun">Stella O. Olubodun</a>, <a href="https://publications.waset.org/abstracts/search?q=George%20E.%20Eriyamremu"> George E. Eriyamremu</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The study assessed the effect of crude oil applied at rates, 0, 2, 5, and 10% on the fractional chemical forms and availability of some metals in soils from Usen, Edo State, with no known crude oil contamination and soil from a crude oil spill site in Ubeji, Delta State, Nigeria. Three methods were used to determine the bioavailability of metals in the soils: maize (<em>Zea mays</em>) plant, EDTA and BCR sequential extraction. The sequential extract acid soluble fraction of the BCR extraction (most labile fraction of the soils, normally associated with bioavailability) were compared with total metal concentration in maize seedlings as a means to compare the chemical and biological measures of bioavailability. Total Fe was higher in comparison to other metals for the crude oil contaminated soils. The metal concentrations were below the limits of 4.7% Fe, 190mg/kg Cu and 720mg/kg Zn intervention values and 36mg/kg Cu and 140mg/kg Zn target values for soils provided by the Department of Petroleum Resources (DPR) guidelines. The concentration of the metals in maize seedlings increased with increasing rates of crude oil contamination. Comparison of the metal concentrations in maize seedlings with EDTA extractable concentrations showed that EDTA extracted more metals than maize plant. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=availability" title="availability">availability</a>, <a href="https://publications.waset.org/abstracts/search?q=crude%20oil%20contamination" title=" crude oil contamination"> crude oil contamination</a>, <a href="https://publications.waset.org/abstracts/search?q=EDTA" title=" EDTA"> EDTA</a>, <a href="https://publications.waset.org/abstracts/search?q=maize" title=" maize"> maize</a>, <a href="https://publications.waset.org/abstracts/search?q=metals" title=" metals"> metals</a> </p> <a href="https://publications.waset.org/abstracts/38382/prediction-of-metals-available-to-maize-seedlings-in-crude-oil-contaminated-soil" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/38382.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">228</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4294</span> Interaction of Metals with Non-Conventional Solvents</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Evgeny%20E.%20Tereshatov">Evgeny E. Tereshatov</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20M.%20Folden"> C. M. Folden</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Ionic liquids and deep eutectic mixtures represent so-called non-conventional solvents. The former, composed of discrete ions, is a salt with a melting temperature below 100°С. The latter, consisting of hydrogen bond donors and acceptors, is a mixture of at least two compounds, resulting in a melting temperature depression in comparison with that of the individual moiety. These systems also can be water-immiscible, which makes them applicable for metal extraction. This work will cover interactions of In, Tl, Ir, and Rh in hydrochloric acid media with eutectic mixtures and Er, Ir, and At in a gas phase with chemically modified α-detectors. The purpose is to study chemical systems based on non-conventional solvents in terms of their interaction with metals. Once promising systems are found, the next step is to modify the surface of α-detectors used in the online element production at cyclotrons to get the detector chemical selectivity. Initially, the metal interactions are studied by means of the liquid-liquid extraction technique. Then appropriate molecules are chemisorbed on the surrogate surface first to understand the coating quality. Finally, a detector is covered with the same molecule, and the metal sorption on such detectors is studied in the online regime. It was found that chemical treatment of the surface can result in 99% coverage with a monolayer formation. This surface is chemically active and can adsorb metals from hydrochloric acid solutions. Similarly, a detector surface was modified and tested during cyclotron-based experiments. Thus, a procedure of detectors functionalization has been developed, and this opens an interesting opportunity of studying chemisorption of elements which do not have stable isotopes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=mechanism" title="mechanism">mechanism</a>, <a href="https://publications.waset.org/abstracts/search?q=radioisotopes" title=" radioisotopes"> radioisotopes</a>, <a href="https://publications.waset.org/abstracts/search?q=solvent%20extraction" title=" solvent extraction"> solvent extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=gas%20phase%20sorption" title=" gas phase sorption"> gas phase sorption</a> </p> <a href="https://publications.waset.org/abstracts/152945/interaction-of-metals-with-non-conventional-solvents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/152945.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">103</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4293</span> Speciation and Bioavailability of Heavy Metals in Greenhouse Soils</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Bulent%20Topcuoglu">Bulent Topcuoglu</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Repeated amendments of organic matter and intensive use of fertilizers, metal-enriched chemicals and biocides may cause soil and environmental pollution in greenhouses. Specially, the impact of heavy metal pollution of soils on food metal content and underground water quality has become a public concern. Due to potential toxicity of heavy metals to human life and environment, determining the chemical form of heavy metals in greenhouse soils is an important approach of chemical characterization and can provide useful information on its mobility and bioavailability. A sequential extraction procedure was used to estimate the availability of heavy metals (Zn, Cd, Ni, Pb and Cr) in greenhouse soils of Antalya Aksu. Zn was predominantly associated with Fe-Mn oxide fraction, major portion of Cd associated with carbonate and organic matter fraction, a major portion of (>65 %) Ni and Cr were largely associated with Fe-Mn oxide and residual fractions and Pb was largely associated with organic matter and Fe-Mn oxide fractions. Results of the present study suggest that the mobility and bioavailability of metals probably increase in the following order: Cr < Pb < Ni < Cd < Zn. Among the elements studied, Zn and Cd appeared to be the most readily soluble and potentially bioavailable metals and these metals may carry a potential risk for metal transfer in food chain and contamination to ground water. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20speciation" title="metal speciation">metal speciation</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20mobility" title=" metal mobility"> metal mobility</a>, <a href="https://publications.waset.org/abstracts/search?q=greenhouse%20soils" title=" greenhouse soils"> greenhouse soils</a>, <a href="https://publications.waset.org/abstracts/search?q=biosystems%20engineering" title=" biosystems engineering"> biosystems engineering</a> </p> <a href="https://publications.waset.org/abstracts/5068/speciation-and-bioavailability-of-heavy-metals-in-greenhouse-soils" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/5068.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">416</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4292</span> Propane Dehydrogenation with Better Stability by a Modified Pt-Based Catalyst</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Napat%20Hataivichian">Napat Hataivichian</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The effect of transition metal doping on Pt/Al2O3 catalyst used in propane dehydrogenation reaction at 500˚C was studied. The preparation methods investigated were sequential impregnation (Pt followed by the 2nd metal or the 2nd metal followed by Pt) and co-impregnation. The metal contents of these catalysts were fixed as the weight ratio of Pt per the 2nd metal of around 0.075. These catalysts were characterized by N2-physisorption, TPR, CO-chemisorption and NH3-TPD. It was found that the impregnated 2nd metal had an effect upon reducibility of Pt due to its interaction with transition metal-containing structure. This was in agreement with the CO-chemisorption result that the presence of Pt metal, which is a result from Pt species reduction, was decreased. The total acidity of bimetallic catalysts is decreased but the strong acidity is slightly increased. It was found that the stability of bimetallic catalysts prepared by co-impregnation and sequential impregnation where the 2nd metal was impregnated before Pt were better than that of monometallic catalyst (undoped Pt one) due to the forming of Pt sites located on the transition metal-oxide modified surface. Among all preparation methods, the sequential impregnation method- having Pt impregnated before the 2nd metal gave the worst stability because this catalyst lacked the modified Pt sites and some fraction of Pt sites was covered by the 2nd metal. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=alumina" title="alumina">alumina</a>, <a href="https://publications.waset.org/abstracts/search?q=dehydrogenation" title=" dehydrogenation"> dehydrogenation</a>, <a href="https://publications.waset.org/abstracts/search?q=platinum" title=" platinum"> platinum</a>, <a href="https://publications.waset.org/abstracts/search?q=transition%20metal" title=" transition metal"> transition metal</a> </p> <a href="https://publications.waset.org/abstracts/25499/propane-dehydrogenation-with-better-stability-by-a-modified-pt-based-catalyst" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/25499.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">310</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4291</span> Preparation of Porous Metal Membrane by Thermal Annealing for Thin Film Encapsulation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jaibir%20Sharma">Jaibir Sharma</a>, <a href="https://publications.waset.org/abstracts/search?q=Lee%20JaeWung"> Lee JaeWung</a>, <a href="https://publications.waset.org/abstracts/search?q=Merugu%20Srinivas"> Merugu Srinivas</a>, <a href="https://publications.waset.org/abstracts/search?q=Navab%20Singh"> Navab Singh </a> </p> <p class="card-text"><strong>Abstract:</strong></p> This paper presents thermal annealing dewetting technique for the preparation of porous metal membrane for thin film encapsulation application. Thermal annealing dewetting experimental results reveal that pore size in porous metal membrane depend upon i.e. 1. The substrate on which metal is deposited for formation of porous metal cap membrane, 2. Melting point of metal used for porous metal cap layer membrane formation, 3. Thickness of metal used for cap layer, 4. Temperature used for porous metal membrane formation. Silver (Ag) was used as a metal for preparation of porous metal membrane by annealing the film at different temperature. Pores in porous silver film were analyzed using Scanning Electron Microscope (SEM). In order to check the usefulness of porous metal film for thin film encapsulation application, the porous silver film prepared on amorphous silicon (a-Si) was release using XeF2. Finally, guide line and structures are suggested to use this porous membrane for thin film encapsulation (TFE) application. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=dewetting" title="dewetting">dewetting</a>, <a href="https://publications.waset.org/abstracts/search?q=themal%20annealing" title=" themal annealing"> themal annealing</a>, <a href="https://publications.waset.org/abstracts/search?q=metal" title=" metal"> metal</a>, <a href="https://publications.waset.org/abstracts/search?q=melting%20point" title=" melting point"> melting point</a>, <a href="https://publications.waset.org/abstracts/search?q=porous" title=" porous"> porous</a> </p> <a href="https://publications.waset.org/abstracts/31602/preparation-of-porous-metal-membrane-by-thermal-annealing-for-thin-film-encapsulation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/31602.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">657</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4290</span> Magnetic Solid-Phase Separation of Uranium from Aqueous Solution Using High Capacity Diethylenetriamine Tethered Magnetic Adsorbents </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Amesh%20P">Amesh P</a>, <a href="https://publications.waset.org/abstracts/search?q=Suneesh%20A%20S"> Suneesh A S</a>, <a href="https://publications.waset.org/abstracts/search?q=Venkatesan%20K%20A"> Venkatesan K A</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The magnetic solid-phase extraction is a relatively new method among the other solid-phase extraction techniques for the separating of metal ions from aqueous solutions, such as mine water and groundwater, contaminated wastes, etc. However, the bare magnetic particles (Fe3O4) exhibit poor selectivity due to the absence of target-specific functional groups for sequestering the metal ions. The selectivity of these magnetic particles can be remarkably improved by covalently tethering the task-specific ligands on magnetic surfaces. The magnetic particles offer a number of advantages such as quick phase separation aided by the external magnetic field. As a result, the solid adsorbent can be prepared with the particle size ranging from a few micrometers to the nanometer, which again offers the advantages such as enhanced kinetics of extraction, higher extraction capacity, etc. Conventionally, the magnetite (Fe3O4) particles were prepared by the hydrolysis and co-precipitation of ferrous and ferric salts in aqueous ammonia solution. Since the covalent linking of task-specific functionalities on Fe3O4 was difficult, and it is also susceptible to redox reaction in the presence of acid or alkali, it is necessary to modify the surface of Fe3O4 by silica coating. This silica coating is usually carried out by hydrolysis and condensation of tetraethyl orthosilicate over the surface of magnetite to yield a thin layer of silica-coated magnetite particles. Since the silica-coated magnetite particles amenable for further surface modification, it can be reacted with task-specific functional groups to obtain the functionalized magnetic particles. The surface area exhibited by such magnetic particles usually falls in the range of 50 to 150 m2.g-1, which offer advantage such as quick phase separation, as compared to the other solid-phase extraction systems. In addition, the magnetic (Fe3O4) particles covalently linked on mesoporous silica matrix (MCM-41) and task-specific ligands offer further advantages in terms of extraction kinetics, high stability, longer reusable cycles, and metal extraction capacity, due to the large surface area, ample porosity and enhanced number of functional groups per unit area on these adsorbents. In view of this, the present paper deals with the synthesis of uranium specific diethylenetriamine ligand (DETA) ligand anchored on silica-coated magnetite (Fe-DETA) as well as on magnetic mesoporous silica (MCM-Fe-DETA) and studies on the extraction of uranium from aqueous solution spiked with uranium to mimic the mine water or groundwater contaminated with uranium. The synthesized solid-phase adsorbents were characterized by FT-IR, Raman, TG-DTA, XRD, and SEM. The extraction behavior of uranium on the solid-phase was studied under several conditions like the effect of pH, initial concentration of uranium, rate of extraction and its variation with pH and initial concentration of uranium, effect of interference ions like CO32-, Na+, Fe+2, Ni+2, and Cr+3, etc. The maximum extraction capacity of 233 mg.g-1 was obtained for Fe-DETA, and a huge capacity of 1047 mg.g-1 was obtained for MCM-Fe-DETA. The mechanism of extraction, speciation of uranium, extraction studies, reusability, and the other results obtained in the present study suggests Fe-DETA and MCM-Fe-DETA are the potential candidates for the extraction of uranium from mine water, and groundwater. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=diethylenetriamine" title="diethylenetriamine">diethylenetriamine</a>, <a href="https://publications.waset.org/abstracts/search?q=magnetic%20mesoporous%20silica" title=" magnetic mesoporous silica"> magnetic mesoporous silica</a>, <a href="https://publications.waset.org/abstracts/search?q=magnetic%20solid-phase%20extraction" title=" magnetic solid-phase extraction"> magnetic solid-phase extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=uranium%20extraction" title=" uranium extraction"> uranium extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=wastewater%20treatment" title=" wastewater treatment"> wastewater treatment</a> </p> <a href="https://publications.waset.org/abstracts/124878/magnetic-solid-phase-separation-of-uranium-from-aqueous-solution-using-high-capacity-diethylenetriamine-tethered-magnetic-adsorbents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/124878.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">168</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4289</span> Extraction of Essential Oil From Orange Peels</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Aayush%20Bhisikar">Aayush Bhisikar</a>, <a href="https://publications.waset.org/abstracts/search?q=Neha%20Rajas"> Neha Rajas</a>, <a href="https://publications.waset.org/abstracts/search?q=Aditya%20Bhingare"> Aditya Bhingare</a>, <a href="https://publications.waset.org/abstracts/search?q=Samarth%20Bhandare"> Samarth Bhandare</a>, <a href="https://publications.waset.org/abstracts/search?q=Amruta%20Amrurkar"> Amruta Amrurkar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Orange peels are currently thrown away as garbage in India after orange fruits' edible components are consumed. However, the nation depends on important essential oils for usage in companies that produce goods, including food, beverages, cosmetics, and medicines. This study was conducted to show how to effectively use it. By using various extraction techniques, orange peel is used in the creation of essential oils. Stream distillation, water distillation, and solvent extraction were the techniques taken into consideration in this paper. Due to its relative prevalence among the extraction techniques, Design Expert 7.0 was used to plan an experimental run for solvent extraction. Oil was examined to ascertain its physical and chemical characteristics after extraction. It was determined from the outcomes that the orange peels. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=orange%20peels" title="orange peels">orange peels</a>, <a href="https://publications.waset.org/abstracts/search?q=extraction" title=" extraction"> extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=essential%20oil" title=" essential oil"> essential oil</a>, <a href="https://publications.waset.org/abstracts/search?q=distillation" title=" distillation"> distillation</a> </p> <a href="https://publications.waset.org/abstracts/173039/extraction-of-essential-oil-from-orange-peels" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/173039.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">87</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4288</span> Extraction of Essential Oil from Orange Peels</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Neha%20Rajas">Neha Rajas</a>, <a href="https://publications.waset.org/abstracts/search?q=Aayush%20Bhisikar"> Aayush Bhisikar</a>, <a href="https://publications.waset.org/abstracts/search?q=Samarth%20Bhandare"> Samarth Bhandare</a>, <a href="https://publications.waset.org/abstracts/search?q=Aditya%20Bhingare"> Aditya Bhingare</a>, <a href="https://publications.waset.org/abstracts/search?q=Amruta%20Amrutkar"> Amruta Amrutkar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Orange peels are currently thrown away as garbage in India after orange fruits' edible components are consumed. However, the nation depends on important essential oils for usage in companies that produce goods, including food, beverages, cosmetics, and medicines. This study was conducted to show how to effectively use it. By using various extraction techniques, orange peel is used in the creation of essential oils. Stream distillation, water distillation, and solvent extraction were the techniques taken into consideration in this paper. Due to its relative prevalence among the extraction techniques, Design Expert 7.0 was used to plan an experimental run for solvent extraction. Oil was examined to ascertain its physical and chemical characteristics after extraction. It was determined from the outcomes that the orange peels. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=orange%20peels" title="orange peels">orange peels</a>, <a href="https://publications.waset.org/abstracts/search?q=extraction" title=" extraction"> extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=distillation" title=" distillation"> distillation</a>, <a href="https://publications.waset.org/abstracts/search?q=essential%20oil" title=" essential oil"> essential oil</a> </p> <a href="https://publications.waset.org/abstracts/173321/extraction-of-essential-oil-from-orange-peels" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/173321.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">80</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4287</span> Electro-Winning of Dilute Solution of Copper Metal from Sepon Mine, Lao PDR</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20Vasailor">S. Vasailor</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20Rattanakawin"> C. Rattanakawin</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Electro-winning of copper metal from dilute sulfate solution (13.7 g/L) was performed in a lab electrolytic cell with stainless-steel cathode and lead-alloy anode. The effects of various parameters including cell voltage, electro-winning temperature and time were studied in order to acquire an appropriate current efficiency of copper deposition. The highest efficiency is about 95% obtaining from electro-winning condition of 3V, 55°C and 3,600 s correspondingly. The cathode copper with 95.5% Cu analyzed using atomic absorption spectrometry can be obtained from this single-winning condition. In order to increase the copper grade, solvent extraction should be used to increase the sulfate concentration, say 50 g/L, prior to winning the cathode copper effectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=copper%20metal" title="copper metal">copper metal</a>, <a href="https://publications.waset.org/abstracts/search?q=current%20efficiency" title=" current efficiency"> current efficiency</a>, <a href="https://publications.waset.org/abstracts/search?q=dilute%20sulfate%20solution" title=" dilute sulfate solution"> dilute sulfate solution</a>, <a href="https://publications.waset.org/abstracts/search?q=electro-winning" title=" electro-winning"> electro-winning</a> </p> <a href="https://publications.waset.org/abstracts/109027/electro-winning-of-dilute-solution-of-copper-metal-from-sepon-mine-lao-pdr" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/109027.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">138</span> </span> </div> </div> <ul class="pagination"> <li class="page-item disabled"><span class="page-link">&lsaquo;</span></li> <li class="page-item active"><span class="page-link">1</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=rare-earth%20metal%20extraction&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=rare-earth%20metal%20extraction&page=3">3</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=rare-earth%20metal%20extraction&page=4">4</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=rare-earth%20metal%20extraction&page=5">5</a></li> <li class="page-item"><a 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