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window.loswp.shouldDetectTimezone = true; window.loswp.shouldShowBulkDownload = true; window.loswp.showSignupCaptcha = false window.loswp.willEdgeCache = false; window.loswp.work = {"work":{"id":6684668,"created_at":"2014-04-07T04:48:54.176-07:00","from_world_paper_id":123920044,"updated_at":"2024-11-18T15:27:11.436-08:00","_data":{"grobid_abstract":"Activated carbons were prepared from waste tyres by gasification with steam and carbon dioxide and their characteristics were investigated. A two-stage activation procedure (pyrolysis at 800 8C in N 2 atmosphere, followed by steam or carbon dioxide activation) was used for the production of activated samples. The effect of the activation temperature (750-900 8C) and the activation time (1-3 h) on the surface characteristics of the prepared carbon was investigated. Carbons produced to different degrees of burn-off were characterized by means of their nitrogen adsorption isotherms at 77 K. In both sets of experiments, the mesopore, micropore volume, and BET surface area increased almost linearly with the degree of activation. For burn-off values lower than 53%, the steam activation produced carbons with a narrower and more extensive microporosity and higher BET and external surface area than the carbon dioxide activation. As the activation proceeds (burn-off \u003e 53%), a strong development of the mesoporosity in the carbons was observed and the micropores size distribution revealed broader micropores, that is, a more heterogeneous distribution. #","publication_date":"2006,,","publication_name":"Applied Surface Science","grobid_abstract_attachment_id":"48755226"},"document_type":"paper","pre_hit_view_count_baseline":null,"quality":"high","language":"en","title":"Preparation of activated carbons from used tyres by gasification with steam and carbon dioxide","broadcastable":true,"draft":null,"has_indexable_attachment":true,"indexable":true}}["work"]; window.loswp.workCoauthors = [10889774]; window.loswp.locale = "en"; window.loswp.countryCode = "SG"; window.loswp.cwvAbTestBucket = ""; window.loswp.designVariant = "ds_vanilla"; window.loswp.fullPageMobileSutdModalVariant = "control"; window.loswp.useOptimizedScribd4genScript = false; window.loswp.appleClientId = 'edu.academia.applesignon';</script><script 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href="https://www.academia.edu/25419277/On_the_Carbon_Dioxide_and_Benzene_Adsorption_on_Activated_Carbons_To_Study_Their_Micropore_Structure">On the Carbon Dioxide and Benzene Adsorption on Activated Carbons To Study Their Micropore Structure</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="32505871" href="https://granada.academia.edu/Jos%C3%A9Riverautrilla">José Rivera-utrilla</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Langmuir, 1997</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"On the Carbon Dioxide and Benzene Adsorption on Activated Carbons To Study Their Micropore Structure","attachmentId":45735632,"attachmentType":"pdf","work_url":"https://www.academia.edu/25419277/On_the_Carbon_Dioxide_and_Benzene_Adsorption_on_Activated_Carbons_To_Study_Their_Micropore_Structure","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/25419277/On_the_Carbon_Dioxide_and_Benzene_Adsorption_on_Activated_Carbons_To_Study_Their_Micropore_Structure"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="5" data-entity-id="9496124" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/9496124/Conversion_of_waste_tires_into_activated_carbon_through_pyrolysis_and_physical_activation_with_CO2">Conversion of waste tires into activated carbon through pyrolysis and physical activation with CO2</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="22246066" href="https://epn.academia.edu/ErnestodelaTorre">Ernesto de la Torre</a></div><p class="ds-related-work--abstract ds2-5-body-sm">A particular environmental problem is the growing generation and the difficulties in the disposal of waste tires. The European Union, USA, and Japan produce around 6 million tons of scrap tires per year; while in the entire world generate 1 billion of waste tires. Commonly, landfill zones are the primary destiny of tires, where they represents hazards such diseases and accidental fires. Tires are bulky, recalcitrant to natural degradation and difficult to compact. Actual treatments such as energy recovery in cement kilns and recycling process do not offer an integral way to benefit the end life tires (ELT). However, pyrolysis has shown to be an alternative treatment, and an attractive way to recover valuable products such as combustible gases, fuel and carbon. The last one is of interest in this research because it is the precursor in the production of activated carbon. The main purpose of the present work was to prepare activated carbon from waste tires, which is suitable as an adsorbent of relatively large molecules. Small pieces of rubber (2-3 cm) from the sidewall of tires were used into the experimentation. The pyrolysis tests were developed into laboratory and pilot scales under temperatures between 450-550 °C. The physical activation of the char was carried under CO2 atmosphere and temperatures between 850-900 °C. The methods of iodine index, blue-methylene adsorption, and sugar index were used to determinate the specific area, and the adsorption capacity of activated carbon. Pyrolysis results demonstrated that residence times superior to 45 min were necessary to get a char with a high content of fixed carbon with an overall weight loss constant of 67%. Activated carbon with specific area over 800 m2/g has been produced under certain conditions. The activation with CO2 shown a linear relation between time residence and specific surface for burnoff less to 70%.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Conversion of waste tires into activated carbon through pyrolysis and physical activation with CO2","attachmentId":35726190,"attachmentType":"docx","work_url":"https://www.academia.edu/9496124/Conversion_of_waste_tires_into_activated_carbon_through_pyrolysis_and_physical_activation_with_CO2","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/9496124/Conversion_of_waste_tires_into_activated_carbon_through_pyrolysis_and_physical_activation_with_CO2"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="6" data-entity-id="84114000" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/84114000/Micropore_Size_Analysis_of_Activated_Carbons_Using_Nitrogen_Carbon_Dioxide_and_Methane_Adsorption_Isotherms_Experimental_and_Theoretical_Studies">Micropore Size Analysis of Activated Carbons Using Nitrogen, Carbon Dioxide and Methane Adsorption Isotherms: Experimental and Theoretical Studies</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="67404383" href="https://independent.academia.edu/MohsenMohsennia">Mohsen Mohsennia</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Adsorption Science & Technology, 2012</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Micropore Size Analysis of Activated Carbons Using Nitrogen, Carbon Dioxide and Methane Adsorption Isotherms: Experimental and Theoretical Studies","attachmentId":89247403,"attachmentType":"pdf","work_url":"https://www.academia.edu/84114000/Micropore_Size_Analysis_of_Activated_Carbons_Using_Nitrogen_Carbon_Dioxide_and_Methane_Adsorption_Isotherms_Experimental_and_Theoretical_Studies","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/84114000/Micropore_Size_Analysis_of_Activated_Carbons_Using_Nitrogen_Carbon_Dioxide_and_Methane_Adsorption_Isotherms_Experimental_and_Theoretical_Studies"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="7" data-entity-id="24093779" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/24093779/Production_of_Activated_Carbons_from_Pyrolysis_of_Waste_Tires_Impregnated_with_Potassium_Hydroxide">Production of Activated Carbons from Pyrolysis of Waste Tires Impregnated with Potassium Hydroxide</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="46491355" href="https://utmachala.academia.edu/JonathanalexanderRuizcarrillo">Jonathan alexander Ruiz carrillo</a></div><p class="ds-related-work--abstract ds2-5-body-sm">Activated carbons were produced from waste tires using a chemical activation method. The carbon production process consisted of potassium hydroxide (KOH) impregnation followed by pyrolysis in N2 at 600-900 degrees C for 0-2 hr. The activation method can produce carbons with a surface area (SA) and total pore volume as high as 470 m2/g and 0.57 cm3/g, respectively. The influence of different parameters during chemical activation, such as pyrolysis temperature, holding time, and KOH/tire ratio, on the carbon yield and the surface characteristics was explored, and the optimum preparation conditions were recommended. The pore volume of the resulting carbons generally increases with the extent of carbon gasified by KOH and its derivatives, whereas the SA increases with degree of gasification to reach a maximum value, and then decreases upon further gasification.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Production of Activated Carbons from Pyrolysis of Waste Tires Impregnated with Potassium Hydroxide","attachmentId":44460244,"attachmentType":"pdf","work_url":"https://www.academia.edu/24093779/Production_of_Activated_Carbons_from_Pyrolysis_of_Waste_Tires_Impregnated_with_Potassium_Hydroxide","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/24093779/Production_of_Activated_Carbons_from_Pyrolysis_of_Waste_Tires_Impregnated_with_Potassium_Hydroxide"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="8" data-entity-id="82165308" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/82165308/Activated_Carbons_from_Waste_Tyre_Pyrolysis_Application">Activated Carbons from Waste Tyre Pyrolysis: Application</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="223011189" href="https://independent.academia.edu/delforddovorogwa">delford dovorogwa</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Recent Perspectives in Pyrolysis Research</p><p class="ds-related-work--abstract ds2-5-body-sm">The development of better and efficient methods of consuming less and/or wasting little resource materials is becoming more important. In this study, pyrolytic waste tyre carbon black residue and commercial grade activated carbon were characterized and evaluated against adsorption of mercury vapor. The performance of the raw carbon black residue and the activated carbon against mercury vapor generated in the laboratory was determined using a designed reactor system. The adsorption of Hg+ was investigated at temperatures ranging from 200 to 280°C for 6 hours. Batch experiments were conducted for the different carbon residue samples and characterization analysis were done before and after adsorption using the spectroscopic, microscopic, and structural techniques to elucidate the structural arrangements and properties of the carbonaceous materials. Spectroscopic analysis of these carbonaceous residues showed a C=C stretching vibration attributed to the lignocellulose aromatic ring at 1...</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Activated Carbons from Waste Tyre Pyrolysis: Application","attachmentId":87959103,"attachmentType":"pdf","work_url":"https://www.academia.edu/82165308/Activated_Carbons_from_Waste_Tyre_Pyrolysis_Application","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/82165308/Activated_Carbons_from_Waste_Tyre_Pyrolysis_Application"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="9" data-entity-id="24093782" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/24093782/Production_of_activated_carbons_from_waste_tyres_for_low_temperature_NOx_control">Production of activated carbons from waste tyres for low temperature NOx control</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="46491355" href="https://utmachala.academia.edu/JonathanalexanderRuizcarrillo">Jonathan alexander Ruiz carrillo</a></div><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Production of activated carbons from waste tyres for low temperature NOx control","attachmentId":44460284,"attachmentType":"pdf","work_url":"https://www.academia.edu/24093782/Production_of_activated_carbons_from_waste_tyres_for_low_temperature_NOx_control","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/24093782/Production_of_activated_carbons_from_waste_tyres_for_low_temperature_NOx_control"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div></div></div><div class="ds-sticky-ctas--wrapper js-loswp-sticky-ctas hidden"><div class="ds-sticky-ctas--grid-container"><div class="ds-sticky-ctas--container"><button class="ds2-5-button js-swp-download-button" data-signup-modal="{"location":"continue-reading-button--sticky-ctas","attachmentId":48755226,"attachmentType":"pdf","workUrl":null}">See full PDF</button><button class="ds2-5-button ds2-5-button--secondary js-swp-download-button" data-signup-modal="{"location":"download-pdf-button--sticky-ctas","attachmentId":48755226,"attachmentType":"pdf","workUrl":null}"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">download</span>Download PDF</button></div></div></div><div class="ds-below-fold--grid-container"><div class="ds-work--container js-loswp-embedded-document"><div class="attachment_preview" data-attachment="Attachment_48755226" style="display: none"><div class="js-scribd-document-container"><div class="scribd--document-loading js-scribd-document-loader" style="display: block;"><img alt="Loading..." src="//a.academia-assets.com/images/loaders/paper-load.gif" /><p>Loading Preview</p></div></div><div style="text-align: center;"><div class="scribd--no-preview-alert js-preview-unavailable"><p>Sorry, preview is currently unavailable. 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