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Performances of Carbon Black-Titanium nitrate and Carbon Black-Titanium/Triton X-100 Composite Polymer Counter Electrodes for Dye-Sensitized Solar Cells | Scientific.Net
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Sudhagar; citation_author=S. Nagarajan; citation_author=Yong-Gun Lee; citation_author=Donghoon Song; citation_author=Taewook Son; citation_author=Woohyung Cho; citation_author=Miyoung Heo; citation_author=Kyoungjun Lee; citation_author=Jongok Won; citation_author=Yong Soo Kang; citation_volume=3; citation_issue=6; citation_publication_date=2011/6/2; citation_pages=1838-1843; citation_doi=10.1021/am2003735" /> <meta name="citation_reference" content="Z. Y. Zhang , X. Y. Zhang , H. X. Xu , Z. H. Liu , S. P. Pang , X. H. Zhou , S. M. Dong, X. Chen and G. L. Cui, ACS Appl. Mater. Interfaces, 2012, 4 , 6242. https://doi.org/10.1021/am3018338." /> <meta name="person" content="Fadzai Lesley Chawarambwa, Tika Erna Putri, Pankaj Attri, Kunihiro Kamataki, Naho Itagaki, Kazunori Koga, Masaharu Shiratani" /> <meta name="description" content="The development of platinum-free counter electrodes (CEs) is significant in the development of cost-effective dye-sensitized solar cells (DSSCs). In this study, Pt-free, low-cost carbon black-titanium nitrate (CB-TiN) nanocomposite counter electrodes CEs were prepared via simple heating and cooling process for application in DSSCs. Different weight concentrations of CB-TiN (15-200 mg) were uniformly blended with PEDOT:PSS at 350 rpm and 150°C for 10 mins. Thereafter, the solution mixtures were immediately cooled at 4°C overnight to produce PEDOT:PSS/CB-TiN CEs. Further, to investigate the effects of iso-octyphenoxy-polyethoxyethanol (TX100) on the performance of the PEDOT:PSS/CB-TIN CE, various concentrations of TX100 (1-10%) were blended with PEDOT:PSS/15mgCB-TiN CE mixture at room temperature to produce PEDOT:PSS/15mgCB-TiN/TX100 CEs. The results indicated a gradual increase in electrocatalytic activity coupled with a reduction in internal resistance in the DSSCs as the weight of CB-TiN nanoparticles was enhanced. Similar results were obtained when the concentration of TX100 was increased. The DSSCs with the PEDOT:PSS/200mgCB-TiN and PEDOT:PSS/15mgCB-TiN/10%TX100 CEs exhibited optimum performances of 4.42% and 4.32%, respectively. Their performance closely matches that of the Pt CE (4.43%)." /> <meta name="keywords" content="Catalytic Performance, Counter Electrode, Cyclic Voltammetry, Dye-Sensitised Solar Cells, Fill Factor" /> <meta name="copyright" content="2022 Trans Tech Publications Ltd. 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arrow-breadcrumbs"></i><span class="bread-crumbs-second">Performances of Carbon Black-Titanium nitrate and...</span></div> <div class="page-name-block underline-begin"> <h1 class="page-name-block-text">Performances of Carbon Black-Titanium nitrate and Carbon Black-Titanium/Triton X-100 Composite Polymer Counter Electrodes for Dye-Sensitized Solar Cells</h1> </div> <div class="paper-statistics"> <div class="loading"> <i class="inline-icon download-and-visitor-statistics-icon"></i> <span class="normal-text" id="paperDownloadsAndVisitorsCount"></span> </div> </div> <div class="clearfix"></div> <div class="page-paper-title"> <div class="preview-block"> <img alt="Article Preview" width="128" height="180" src="/AMR.1168.35/thumbnail.gif"> <div id="preview-button" data-url-preview-log="/Paper/PreviewImageLog?paperId=582455"> <i class="inline-icon preview-icon"></i> </div> <!--Modal window for article preview--> <div id="paper-preview-modal" class="modal fade"> <div class="modal-dialog" role="document"> <div class="popup-page-name underline-begin"> <div class="page-name-block-text">Article Preview</div> </div> <img alt="Article Preview" class="preview-image lazyload" data-src="/AMR.1168.35/preview.gif"> <a data-dismiss="modal" title="Close" class="inline-icon close-icon"></a> </div> </div> <!--End modal--> </div> <div class="abstract-block-description"> <h3 class="page-paper-first-header">Abstract:</h3> <p class="normal-text"> The development of platinum-free counter electrodes (CEs) is significant in the development of cost-effective dye-sensitized solar cells (DSSCs). In this study, Pt-free, low-cost carbon black-titanium nitrate (CB-TiN) nanocomposite counter electrodes CEs were prepared via simple heating and cooling process for application in DSSCs. Different weight concentrations of CB-TiN (15-200 mg) were uniformly blended with PEDOT:PSS at 350 rpm and 150掳C for 10 mins. Thereafter, the solution mixtures were immediately cooled at 4掳C overnight to produce PEDOT:PSS/CB-TiN CEs. Further, to investigate the effects of iso-octyphenoxy-polyethoxyethanol (TX100) on the performance of the PEDOT:PSS/CB-TIN CE, various concentrations of TX100 (1-10%) were blended with PEDOT:PSS/15mgCB-TiN CE mixture at room temperature to produce PEDOT:PSS/15mgCB-TiN/TX100 CEs. The results indicated a gradual increase in electrocatalytic activity coupled with a reduction in internal resistance in the DSSCs as the weight of CB-TiN nanoparticles was enhanced. Similar results were obtained when the concentration of TX100 was increased. The DSSCs with the PEDOT:PSS/200mgCB-TiN and PEDOT:PSS/15mgCB-TiN/10%TX100 CEs exhibited optimum performances of 4.42% and 4.32%, respectively. Their performance closely matches that of the Pt CE (4.43%). </p> </div> <div class="paper-access-buttons col-xs-12"> <div class="row"> <div class="sa-button-wrap"> <a id="sa-button" class="wayfinder-login d-flex sa-button" href="javascript:;"> <div class="sa-button-logo-wrap"> <i class="inline-icon sa-white"></i> </div> <div class="d-flex justify-content-center align-items-center sa-button-text text-truncate"> <div class="sa-button-text-primary text-truncate">Access through your institution</div> </div> </a> </div> <div class="title-button-pdf"> <button id="readPaperButton" data-url-read-paper-log="/Paper/ReadThePaperLog?paperId=582455" class="button button-160"> <span class="inline-element">Read The Paper</span> </button> </div> </div> <div class="row"> </div> </div> <div class="clearfix"></div> <div class="connected-title-container"> <div class="connected-title-text semibold-middle-text">You might also be interested in these eBooks</div> <div class="connected-title-list-container"> 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