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What are Organic Semiconductors? Examples, Advantages and more | Ossila
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Examples, Advantages and more | Ossila </title><meta name="description" content="Organic semiconductors are materials, ranging from small molecules to polymers, that can transport charge. Find out more." /><link rel="apple-touch-icon" sizes="180x180" href="//www.ossila.com/cdn/shop/t/303/assets/apple-touch-icon.png?v=47689890648139992551729065668"> <link rel="icon" type="image/png" sizes="32x32" href="//www.ossila.com/cdn/shop/t/303/assets/favicon-32x32.png?v=170914528706734454101729065668"> <link rel="icon" type="image/png" sizes="16x16" href="//www.ossila.com/cdn/shop/t/303/assets/favicon-16x16.png?v=162550173345868048431729065668"> <link rel="manifest" href="//www.ossila.com/cdn/shop/t/303/assets/site.webmanifest?v=100969836723433583841729065669"> <link rel="mask-icon" href="//www.ossila.com/cdn/shop/t/303/assets/safari-pinned-tab.svg?v=95647162979764929801729065669" color="#39499c"> <meta name="msapplication-TileColor" content="#418fde"> <meta name="theme-color" content="#ffffff"> <link rel="canonical" href="https://www.ossila.com/pages/what-are-organic-semiconductors" /> <!-- CSS --> <link rel="stylesheet" href="//www.ossila.com/cdn/shop/t/303/assets/main-style.css?v=129786468726129743101731684242"> <!-- JS --> <script>var shopifyMoneyFormat = '${{amount}}';</script> <script defer src="//www.ossila.com/cdn/shop/t/303/assets/main.js?v=120109391065215852831729088283"></script> <!--[template]-[shortcode-reference]--> <meta property="og:type" content="website" /> <meta property="og:title" content="What are Organic Semiconductors? Examples, Advantages and more" /> <meta property="og:description" content="Organic semiconductors are materials, ranging from small molecules to polymers, that can transport charge. Find out more." /> <meta property="og:url" content="https://www.ossila.com/pages/what-are-organic-semiconductors" /> <meta property="og:site_name" content="Ossila" /> <meta name="twitter:site" content="@ossilascience"> <meta name="twitter:card" content="summary"> <meta name="twitter:title" content="What are Organic Semiconductors?"> <meta name="twitter:description" content="Organic semiconductors are materials, ranging from small molecules to polymers, that can transport charge. Unlike conducting materials, where electrons move freely across the material, organic semiconductors rely on a structure primarily composed of carbon and hydrogen atoms. These atoms are arranged to enable overlap of π-orbitals, allowing electron delocalization within each molecule. This delocalization facilitates electron movement, or conductivity, along the molecule. Additionally, the π-orbitals can overlap with those of neighboring molecules, creating intermolecular electronic coupling. As a result, delocalized electrons can "hop" between molecules in the organic semiconductor, enabling charge transport. These unique properties make organic semiconductors useful in applications like organic light-emitting diodes (OLEDs) and organic photovoltaics. 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Supplies <b class="caret"></b> </a> <ul class="mega-menu-dropdown-menu mega-menu-quarter-col" id="menu-supplies"> <div class="mega-menu-row"> <div class="mega-menu-full-col"> <p class="mega-menu-section-header">Supplies and Accessories</p> <a href="/collections/substrates-and-fabrication"> <svg class="icon icon-navigate_next"><use xlink:href="#icon-navigate_next"></use></svg> Substrates & Fabrication</a> <a href="/collections/electrochemistry"> <svg class="icon icon-navigate_next"><use xlink:href="#icon-navigate_next"></use></svg> Electrochemistry Supplies</a> <a href="/collections/spectroscopy"> <svg class="icon icon-navigate_next"><use xlink:href="#icon-navigate_next"></use></svg> Spectroscopy Equipment</a> <a href="/collections/solution-making"> <svg class="icon icon-navigate_next"><use xlink:href="#icon-navigate_next"></use></svg> Solution Making Supplies</a> <a href="/collections/equipment-accessories"> <svg class="icon icon-navigate_next"><use 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You can still place orders by emailing us on <a href="mailto:info@ossila.com">info@ossila.com</a>, but you may experience issues browsing our website. Please consider upgrading to a modern browser for better security and an improved browsing experience.</p> </div> </div> <!-- no sidebars --> <main> <div id="informational-page"> <h1>What are Organic Semiconductors?</h1> <div class="container"> <img loading="lazy" width="1340" height="280" src="https://www.ossila.com/cdn/shop/files/semiconductor_wafer.jpg?v=1728388349&width=1340&height=280&crop=center" alt="semiconductor" class="featured-image"> <p>Organic semiconductors are materials, ranging from small molecules to polymers, that can transport charge. Unlike conducting materials, where electrons move freely across the material, organic semiconductors rely on a structure primarily composed of carbon and hydrogen atoms. These atoms are arranged to enable overlap of π-orbitals, allowing electron delocalization within each molecule. This delocalization facilitates electron movement, or conductivity, along the molecule. Additionally, the π-orbitals can overlap with those of neighboring molecules, creating intermolecular electronic coupling. As a result, delocalized electrons can "hop" between molecules in the organic semiconductor, enabling charge transport. These unique properties make organic semiconductors useful in applications like organic light-emitting diodes (OLEDs) and organic photovoltaics.</p> <div class="panel panel-default"> <div class="panel-body"> <p class="h3" style="margin-top: 10px;" data-mce-style="margin-top: 10px;">On This Page</p> <hr> <ul> <li><a href="#classes">Main Classes of Organic Semiconductors</a></li> <li><a href="#advantages">Advantages of Organic Semiconductors</a></li> <li><a href="#chemistry">Chemistry of Organic Semiconductors</a></li> <li><a href="#charge-transport">Charge Transport in Organic Semiconductors</a></li> <li><a href="#organic-vs-inorganic-semiconductors">Difference between Organic Semiconductors and Inorganic Semiconductors</a></li> <li><a href="#applications">Applications of Organic Semiconductors</a></li> <li><a href="#limitations">Limitations of Organic Semiconductors</a></li> </ul> </div> </div> <h2 id="classes">Main Classes of Organic Semiconductors</h2> <hr> <p>There are three main classes or types of organic semiconductor; small molecules, polymers and 2D materials. Within these broad categories there are families of organic semiconductor materials that are being explored within different areas of research from organic electronic devices to medical sensors. See the table below for the main classes of organic semiconductors and some example materials:</p> <table width="100%"> <tbody> <tr> <th>Small Molecule Semiconductors</th> <th>Polymeric Semiconductors</th> <th>2D Organic Semiconductors</th> </tr> <tr> <td> <li>Fullerenes</li> <li><a title="Non-fullerene acceptors, nfas" href="https://www.ossila.com/collections/non-fullerene-acceptors">Non-Fullerene Acceptors</a></li> <li>Polycyclic aromatic hydrocarbons (PAHs)</li> </td> <td> <li>Classic conjugated polymers</li> <li>Donor-Acceptor (D-A) copolymers</li> <li>Polymeric blends</li> </td> <td> <li>2D Covalent Organic Frameworks</li> <li>Graphene Oxide / Reduced Graphene Oxide</li> <li>Self-Assembled Monolayers</li> </td> </tr> </tbody> </table> <figure><img src="https://cdn.shopify.com/s/files/1/0823/0287/files/conjugated-organic-semiconductors.svg?v=1731056960" width="828" alt="examples of conjugation in organic semiconductors" loading="lazy"> <figcaption>Examples of Conjugation in Organic Semiconductors</figcaption> </figure> <h3>Examples of Organic Semiconductor Materials</h3> <p>For specific examples of organic semiconductor material families—such as fullerenes, non-fullerene acceptors, semiconducting polymers, and semiconducting molecules—explore the collections below:</p> <div class="collection-container"> <div class="collection-tile"> <a href="https://www.ossila.com/collections/fullerene-acceptors"> <div class="collection-button background-ossila-blue"> <img alt="Fullerenes" height="109" loading="lazy" src="https://www.ossila.com/cdn/shop/files/collection-link-fullerene-acceptors.png?width=150" width="150"> <p>Fullerenes</p> </div> </a> <p><a href="https://www.ossila.com/collections/fullerene-acceptors">Fullerenes</a></p> <p>Fullerenes and fullerene derivatives with unique properties suitable for electronics.</p> </div> <div class="collection-tile"> <a href="https://www.ossila.com/collections/non-fullerene-acceptors"> <div class="collection-button background-ossila-blue"> <img alt="Non-Fullerene Acceptors" height="109" loading="lazy" src="https://www.ossila.com/cdn/shop/files/collection-link-non-fullerene-acceptors.png?width=150" width="150"> <p>Non-Fullerene Acceptors</p> </div> </a> <p><a href="https://www.ossila.com/collections/non-fullerene-acceptors">Non-Fullerene Acceptors</a></p> <p>A promising range of alternatives to fullerene-based electron acceptors.</p> </div> <div class="collection-tile"> <a href="https://www.ossila.com/collections/semiconducting-polymers"> <div class="collection-button background-ossila-blue"> <img alt="Semiconducting Polymers" height="109" loading="lazy" src="https://www.ossila.com/cdn/shop/files/collection-link-semiconducting-polymers.png?width=150" width="150"> <p>Semiconducting Polymers</p> </div> </a> <p><a href="https://www.ossila.com/collections/semiconducting-polymers">Semiconducting Polymers</a></p> <p>Ideal for bulk heterojunction, OPV, OLED, OFET, and perovskite interfaces.</p> </div> <div class="collection-tile"> <a href="https://www.ossila.com/collections/semiconducting-molecules"> <div class="collection-button background-light-blue"> <img alt="Semiconducting Molecules" height="109" loading="lazy" src="https://www.ossila.com/cdn/shop/files/collection-link-Semiconducting-Molecules.png?width=150" width="150"> <p>Semiconducting Molecules</p> </div> </a> <p><a href="https://www.ossila.com/collections/semiconducting-molecules">Semiconducting Molecules</a></p> <p>Organic <span data-mce-fragment="1">small-molecule semiconductors as emmitters, active materials, and more.</span></p> </div> </div> <h2 id="advantages">Advantages of Organic Semiconductors</h2> <hr> <p>Organic semiconductors offer several advantages, especially for applications in flexible and lightweight electronics. Here are some key benefits:</p> <br> <div class="row"> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30" data-mce-style="float: left; padding-right: 10px;">Low-cost Preparation</div> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30" data-mce-style="float: left; padding-right: 10px;">Light Weight</div> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30" data-mce-style="float: left; padding-right: 10px;">Mechanical Flexibility</div> </div> <br> <div class="row"> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30" data-mce-style="float: left; padding-right: 10px;">Easy Processing</div> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30" data-mce-style="float: left; padding-right: 10px;">Tunable Function Through Molecular Design</div> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30" data-mce-style="float: left; padding-right: 10px;">Rich Availability</div> </div> <br> <div class="row"> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30">Wide Range of Optical Properties</div> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30">Thin Film Formation</div> <div class="col-xs-4"> <img alt="Check Mark" height="30" loading="lazy" src="https://www.ossila.com/cdn/shop/files/tick.svg?v=1613513177" style="float: left; padding-right: 10px;" width="30">Low Energy Consumption</div> </div> <br> <p>These advantages make organic semiconductors stand out from traditional inorganic semiconductors like silicon, positioning them as attractive materials for various applications but especially lightweight and flexible electronic devices.</p> <h2 id="chemistry">Chemistry of Organic Semiconductors</h2> <hr> <p>Organic semiconducting materials are versatile and can have many components. One of the most crucial components to organic semiconductors is conjugated units. This is where there is an area of sp<sup>2</sup>-hybridised carbons. This kind of bonding means only three of the four valence electrons within carbon atoms hybridise. The fourth electron occupies the perpendicular p<sub>z</sub> orbital.</p> <figure><img alt="Delocalisation of electrons in conjugated organic molecules" class="featured-image" loading="lazy" width="848" src="https://www.ossila.com/cdn/shop/files/delocalisation-in-conjugated-molecules.svg?&width=848"> <figcaption>Delocalisation of electrons in conjugated organic molecules</figcaption> </figure> <p>Interactions between these p<sub>z</sub> orbitals form weaker π (bonding) and π* (anti-bonding) orbitals, which flatten the molecule. This planarity facilitates the delocalization of π and π* states across multiple carbon atoms and is known as conjugation. The more conjugation a material possesses the closer the HOMO and LUMO levels are as the difference between the bonding and antibonding molecular orbitals reduces.</p> <p>Every sp<sup>2</sup> hybridised carbon that is able to engage in π bonding introduces another variable into the molecular orbitals. The number of p-orbitals increases as the conjugated system grows, with each p-orbital containing both a positive and a negative lobe. This arrangement allows for variations in π-orbital interactions since each lobe can align with either a like-charged or an opposite-charged neighboring lobe. This variability contributes to the richness of the electronic states within the material, offering multiple pathways for electron delocalization across the π-system. As a result, the increased possibilities for orbital overlap enhance the overall stability and flexibility of the molecular orbitals, providing greater control over the material's electronic properties and its suitability for various organic electronic applications.</p> <figure><img src="https://cdn.shopify.com/s/files/1/0823/0287/files/extended-conjugation.svg?v=1730296957" loading="lazy" alt="extended conjugation"> <figcaption>The different lobes of some p<sub>z</sub> orbitals showing bonding (like-charge) and antibonding (opposite-charge) interactions</figcaption> </figure> <p>The π orbitals of neighboring molecules can also overlap, allowing electrons to spread across multiple layers of semiconducting molecules. This "π–π stacking" is important for helping with electron movement and also lowers the energy needed for light absorption. By combining the inter- and intramolecular electron delocalization with other methods to adjust the HOMO and LUMO energy level gap these organic molecules offer huge advantages. Such features means organic semiconductors have very strong absorption and emission in the visible spectral range making them advantageous for organic electronic applications like photovoltaics and LEDs.</p> <h2 id="charge-transport">Charge Transport in Organic Semiconductors</h2> <hr> <p>Charge transport in organic semiconductors is thought to be heavily dependent on the degree of crystallization of the material. The charge transport theories associated with degree of crystallinity is described in the table below:<span data-mce-fragment="1"> <span class="tooltip-icon quot" data-tooltip-content="Lui, C. et al. (2017). A unified understanding of charge transport in organic semiconductors: the..."></span> </span></p> <table> <tbody> <tr> <th>Degree of Crystallinity</th> <th>Charge Transport Mechanism</th> <th>Description</th> </tr> <tr> <td> <p>Highly Crystalline – disorder free</p> </td> <td> <p>Band-like transport: similar to inorganic semiconductor.</p> </td> <td> <p>Charge carriers move within energy bands formed by strong overlap between molecular orbitals.</p> <p>Fast transport.</p> </td> </tr> <tr> <td> <p>Polycrystalline – low disorder</p> </td> <td> <p>Mobility Edge Model</p> <p>Polaron Formation</p> </td> <td> <p>Areas of localized and delocalized states.</p> <p>Local distortion in the material leads to the formation of a "polaron"—a charge combined with its associated molecular distortion.</p> <p>Slower Transport.</p> </td> </tr> <tr> <td> <p>Amorphous – highly disordered</p> </td> <td> <p>Hopping</p> <p>Tunnelling</p> </td> <td> <p>Charge carriers hop between molecules via π-stacking.</p> <p>When the distance between molecules is very small, electrons may "tunnel" through the energy barrier separating them instead of hopping over it.</p> <p>Slower Transport.</p> </td> </tr> </tbody> </table> <p>The first important feature of organic semiconductors (OSCs) is the relatively weak bonding strength and electronic interactions between neighboring molecules, which result in the density of states (DOS) having a narrow Gaussian distribution <span class="tooltip-icon quot" data-tooltip-content="Lui, C. et al. (2017). A unified understanding of charge transport in organic semiconductors: the..."></span> Whether small or polymeric, OSCs are held together by weak van der Waals forces. OSCs have lots of structural defects and strong lattice vibrations as a result. <span class="tooltip-icon quot" data-tooltip-content="Lui, C. et al. (2017). A unified understanding of charge transport in organic semiconductors: the..."></span> This means there is some fluctuation in electronic coupling between molecules as they are more free to move. Electronic coupling is typically electron-phonon coupling. This makes determining electronic processes in organic semiconductors quite complicated. <span class="tooltip-icon quot" data-tooltip-content="Giannini, S. et al. (2019). Quantum localization and delocalization of charge carriers in organic semiconducting..."></span> </p> <p>In OSCs, electron-phonon coupling occurs because electrons can’t move through the organic material without interacting with molecular vibrations. This interaction has several important effects:</p> <ul> <li> <p><strong>Polaron Formation:</strong> When an electron or hole moves through an OSC, it can locally distort the molecular structure, creating what’s known as a <strong>polaron</strong>—a combination of the charge carrier and the local distortion. This is considered a "self-trapped" charge andmoves more slowly than a free charge due to the energy cost of maintaining the molecular distortion as it moves. This reduces overall charge mobility.</p> </li> <li> <p><strong>Impact on Charge Mobility:</strong> Strong electron-phonon coupling in OSCs means that the energy needed for charge carriers to hop from one molecule to another is relatively high. The strength of electron-phonon coupling impacts how strongly a charge carrier is localized within this polaron.</p> </li> <li> <p><strong>Reorganization energy:</strong> energy cost of overcoming the molecular vibrations between each hop. In materials with high electron-phonon coupling, these vibrations can impede movement, making charge transport thermally activated—meaning that it improves with temperature as thermal energy helps overcome this barrier.</p> </li> <li> <p><strong>Temperature Dependence</strong>: Due to electron-phonon coupling, the temperature of the material significantly impacts charge transport. As temperature increases, molecular vibrations increase, which can assist charge carriers in hopping between molecules, improving mobility. In contrast, lower temperatures can decrease charge mobility as less thermal energy is available to aid hopping.</p> </li> <li> <p><strong>Broadening of Energy Levels</strong>: Electron-phonon coupling in OSCs also causes energy levels to fluctuate, particularly due to the organic material's structural flexibility. This can lead to a broadening of energy levels or a Gaussian distribution in the density of states (DOS). A narrow Gaussian distribution means there are only a few energy levels close together, making it more challenging for charge carriers to find states with the energy needed for transport. This broadening effect can increase disorder, further slowing charge mobility.</p> </li> <li> <p><strong>Hopping and Tunneling in Amorphous Regions</strong>: In highly disordered or amorphous OSCs, electron-phonon coupling influences the mechanisms of hopping and tunneling. For hopping transport, electron-phonon interactions mean that electrons must "jump" between energy states on different molecules. In cases where molecules are very close, tunneling may occur, where charges pass through energy barriers instead of hopping over them. This tunneling is also impacted by electron-phonon coupling, especially in terms of how well charge carriers maintain their path without scattering off of vibrations.</p> </li> </ul> <h2 id="organic-vs-inorganic-semiconductors">Difference between Organic Semiconductors and Inorganic Semiconductors</h2> <hr> <p>There are a few key differences between organic semiconductors and their inorganic counterparts due to the difference in chemical structure and composition. Here is a summary of some of the key differences:</p> <ul> <li> <strong>Organic semiconductors have low dielectric constants (e):</strong> They don't shield charges from each other as much as inorganic semiconductors. This makes it harder to separate electron-hole pairs and as such they are described as "Frenkel excitons". Good for LEDs but not so good for photovoltaics.</li> </ul> <div class="info-tip-box"> <strong>Note:</strong> Molecular engineering has been used to increase the dielectric constant of organic semiconductors like non-fullerene acceptors. Methods such as asymmetric design and incorporating polar functional groups and side chains have provided an increase in dielectric constant to enhance charge dissociation efficiency.</div> <ul> <li> <p><strong>Organic semiconductors are considered electronically "soft":</strong> The delocalized electrons tend to stay close to a small number of atoms rather than spreading across the whole system. This localizations causes changes in the local electronic structure. Along with low dielectric constant this causes distortion in molecular structure in that area. Therefore the charge carrier is a quasiparticle known as a polaron. When polarons move between different parts of the material, like hopping from one polymer chain to another, it requires a lot of energy because the material has to rearrange itself each time. This reorganization energy slows down the movement of charges, reducing the material’s conductivity.</p> </li> </ul> <div class="info-tip-box"> <strong>Note:</strong> How easily the material can bend or change shape (its "stiffness") affects how much the structure relaxes around the charge. This relaxation can create a noticeable difference between the light absorbed and the light emitted by the material, known as a "Stokes shift." A large Stokes shift is helpful in organic LEDs because it reduces the amount of emitted light that gets reabsorbed by the material, improving efficiency.</div> <ul> <li> <p><strong>For organic semiconductors the limiting factor in charge transport is the "hopping" of charge carriers between molecules:</strong> Due to the asymmetry of organic semiconductors, charge transport can vary significantly throughout the system (anisotropic). For a given molecule, intrachain transport through the conjugated plane will be much faster than intermolecular transport via π–π stacking. Inter-molecular "hopping" requires significant molecular reorganization and is therefore dependent on temperature and electronic disorder. The same disorder impacts how easily excitons diffuse through the system by limiting the energetic accessibility of nearby sites.</p> </li> <li> <p><strong>Organic semiconductors are easily processed:</strong> Small molecule organic semiconductors can be easily processed into well-defined high quality films and layered devices without the need for intense heat or ultra-clean conditions. Additionally, the solubility of the molecules can be tuned depending on the desired processing solvent through flexible side chain groups. This tunable solubility means organic semiconductors are solution processed making flexible and highly fracture resistant films.</p> </li> </ul> <h2 id="applications">Applications of Organic Semiconductors</h2> <hr> <p>OSCs are attractive across science disciplines including chemistry, physics, materials science, medicine, and biology. Crucially, OSCs are becoming key elements in the preparation of flexible, printable, and scalable electronics such as: <span class="tooltip-icon quot" data-tooltip-content="Ahmad, S. (2014). Organic semiconductors for device applications: current trends and future prospects"></span> </p> <ul> <li>Light-emitting diodes</li> <li>Solar cells</li> <li>Transistors</li> <li>Thermoelectrics</li> <li>Sensors</li> <li>Bioelectronics</li> <li>Biomimetics</li> </ul> <p>Various synthetic and processing technologies offer flexible platforms for developing different functional materials. <span class="tooltip-icon quot" data-tooltip-content="Zhang, Q. et al. (2022). Recent Progress in Emerging Organic Semiconductors"></span> Molecular engineering allows organic semiconducting materials to be directly tuned and modified for a given application. Specific optical and electronic properties can be accessed via chemical modifications which make these organic materials particularly exciting candidates for the future of electronic device research.</p> <h2 id="limitations">Limitations of Organic Semiconductors</h2> <hr> <p>Organic semiconductors (OSCs) offer flexibility, tunability, and potential for low-cost production, but they also have limitations that impact their performance and broader application including:</p> <ul> <li> <strong>Low Charge Carrier Mobility:</strong> Charge carrier mobilities in OSCs rarely exceed 10 cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup>, a value which is orders of magnitude lower than in c-Si or graphene, where mobilities in the order of 10<sup>3</sup> cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup> and 10<sup>6</sup> cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup>. <span class="tooltip-icon quot" data-tooltip-content="Haneef, H. (2019). Charge carrier traps in organic semiconductors: a review on the..."></span> </li> <li> <strong>Stability:</strong> Some organic materials are sensitive to environmental factors like oxygen, moisture, and UV light. They may need to be processed in a <a title="glove box" href="https://www.ossila.com/products/glove-box">glove box</a> to ensure inert conditions and encapsulated to preserve properties. This adds complexity and costs to device production.</li> <li> <strong>Complex Charge Transport Pathways:</strong> As described above, charges can transport via numerous routes with different levels of efficiency. Issues of reorganization energy, slow hopping and tunnelling and strong electron-phonon coupling make pathways complex.</li> <li> <strong>High Exciton Binding Energy:</strong> The low dielectric constants of organic semiconductor materials means that electron-hole pairs are more tightly bound due to less shielding.</li> </ul> <p>Research is ongoing to improve these limitations of organic semiconducting materials. The modifiable nature of organic molecules has lead to significant advancements in tailoring specific properties required for various applications. In particular, non-fullerene acceptors have seen a huge amount of development and expansion within the field of photovoltaics.</p> <a href="https://www.ossila.com/collections/non-fullerene-acceptors" class="green-banner" data-track-content=""> <p data-content-piece="cta-non-fullerene-acceptors" data-content-name="/pages/what-are-organic-semiconductors">Non-fullerene acceptors</p> <img loading="lazy" alt="NFAs" src="https://www.ossila.com/cdn/shop/files/nfas.jpg?v=1730192510&width=600&height=120&crop=left" height="120" width="600"><button>Browse now</button></a> <h2>Learn More</h2> <hr> <div class="row button-row"> <div class="col-xs-12 col-sm-6 button-col"> <div class="card-box card-truncate"> <a href="/pages/what-are-non-fullerene-acceptors"><img alt="ITIC features" loading="lazy" src="//www.ossila.com/cdn/shop/files/L8-BO-chemical-structure.png?v=1718725075&width=160&height=160&crop=left" width="160" height="160"></a> <a href="/pages/what-are-non-fullerene-acceptors">What are Non-Fullerene Acceptors?</a> <p>Non-fullerene acceptors (NFAs) are organic molecules that, like fullerenes, act as electron acceptors in organic solar cells and other organic electronic devices. However, unlike fullerenes, NFAs lack the hollow cage structure and offer greater flexibility in molecular design, allowing for tunable electronic and optical properties.</p> <a href="/pages/what-are-non-fullerene-acceptors">Read more...</a> </div> </div> <div class="col-xs-12 col-sm-6 button-col"> <div class="card-box card-truncate"> <a href="/pages/organic-photovoltaics-introduction"><img alt="Organic photovoltaics (OPV)" height="160" loading="lazy" src="https://www.ossila.com/cdn/shop/files/OLED-fabrication.jpg?width=160&height=160&crop=center" width="160"></a> <a href="/pages/organic-photovoltaics-introduction">Organic Solar Cells: An Introduction to Organic Photovoltaics</a> <p>Organic solar cells, also known as photovoltaics (OPVs), have become widely recognized for their many promising qualities. This page introduces the topic of OPVs, how they work and their development.</p> <a href="/pages/organic-photovoltaics-introduction">Read more...</a> </div> </div> </div> <div class="panel panel-default"> <div class="panel-body"> <h3>References</h3> <hr> <ul> <li> <a target="_blank" rel="nofollow" href="https://doi.org/10.1039/c7mh00091j" title="A unified understanding of charge transport in organic semiconductors: the importance of attenuated delocalization for the carriers">A unified understanding of charge transport in organic...</a>, Lui, C. et al., Mater. Horiz. (2017) </li> <li> <a target="_blank" rel="nofollow" href="https://doi.org/10.1038/s41467-019-11775-9" title="Quantum localization and delocalization of charge carriers in organic semiconducting crystals">Quantum localization and delocalization of charge carriers in...</a>, Giannini, S. et al., Nat Commun (2019) </li> <li> <a target="_blank" rel="nofollow" href="https://doi.org/10.1515/polyeng-2013-0267" title="Organic semiconductors for device applications: current trends and future prospects">Organic semiconductors for device applications: current trends and...</a>, Ahmad, S., J Polym Eng (2014) </li> <li> <a target="_blank" rel="nofollow" href="https://doi.org/10.1002/adma.202108701" title="Recent Progress in Emerging Organic Semiconductors">Recent Progress in Emerging Organic Semiconductors</a>, Zhang, Q. et al., Advanced Materials (2022) </li> <li> <a target="_blank" rel="nofollow" href="https://doi.org/10.1039/C9TC05695E" title="Charge carrier traps in organic semiconductors: a review on the underlying physics and impact on electronic devices">Charge carrier traps in organic semiconductors: a review...</a>, Haneef, H., J. Mater. Chem. 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