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Hydroxyl radical - Wikipedia
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vector-toc-level-2"> <a class="vector-toc-link" href="#First_detection_of_interstellar_•HO"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.1</span> <span>First detection of interstellar <sup>•</sup>HO</span> </div> </a> <ul id="toc-First_detection_of_interstellar_•HO-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Important_subsequent_reports_of_•HO_astronomical_detections" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Important_subsequent_reports_of_•HO_astronomical_detections"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.2</span> <span>Important subsequent reports of <sup>•</sup>HO astronomical detections</span> </div> </a> <ul id="toc-Important_subsequent_reports_of_•HO_astronomical_detections-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Energy_levels" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Energy_levels"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.3</span> <span>Energy levels</span> </div> </a> <ul id="toc-Energy_levels-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Chemistry_of_the_molecule_•HO" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Chemistry_of_the_molecule_•HO"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.4</span> <span>Chemistry of the molecule <sup>•</sup>HO</span> </div> </a> <ul id="toc-Chemistry_of_the_molecule_•HO-sublist" class="vector-toc-list"> <li id="toc-•HO_production_pathways" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#•HO_production_pathways"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.4.1</span> <span><i><sup>•</sup>HO production pathways</i></span> </div> </a> <ul id="toc-•HO_production_pathways-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-•HO_destruction_pathways" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#•HO_destruction_pathways"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.4.2</span> <span><i><sup>•</sup>HO destruction pathways</i></span> </div> </a> <ul id="toc-•HO_destruction_pathways-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Rate_constants_and_relative_rates_for_important_formation_and_destruction_mechanisms" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#Rate_constants_and_relative_rates_for_important_formation_and_destruction_mechanisms"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.4.3</span> <span><i>Rate constants and relative rates for important formation and destruction mechanisms</i></span> </div> </a> <ul id="toc-Rate_constants_and_relative_rates_for_important_formation_and_destruction_mechanisms-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-Importance_of_interstellar_•HO_observations" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Importance_of_interstellar_•HO_observations"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.5</span> <span>Importance of interstellar <sup>•</sup>HO observations</span> </div> </a> <ul id="toc-Importance_of_interstellar_•HO_observations-sublist" class="vector-toc-list"> <li id="toc-•HO_as_a_tracer_of_shock_conditions" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#•HO_as_a_tracer_of_shock_conditions"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.5.1</span> <span><sup>•</sup>HO as a tracer of shock conditions</span> </div> </a> <ul id="toc-•HO_as_a_tracer_of_shock_conditions-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-In_diffuse_clouds" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#In_diffuse_clouds"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.5.2</span> <span>In diffuse clouds</span> </div> </a> <ul id="toc-In_diffuse_clouds-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-•HO_masers" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#•HO_masers"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.5.3</span> <span><sup>•</sup>HO masers</span> </div> </a> <ul id="toc-•HO_masers-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> </ul> </li> <li id="toc-See_also" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#See_also"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>See also</span> </div> </a> <ul id="toc-See_also-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-References" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#References"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>References</span> </div> </a> <ul id="toc-References-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-External_links" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#External_links"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>External links</span> </div> </a> <ul id="toc-External_links-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Contents" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" title="Table of Contents" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="Toggle the table of contents" > <label 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Available in 22 languages" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-22" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">22 languages</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%AC%D8%B0%D8%B1_%D8%A7%D9%84%D9%87%D9%8A%D8%AF%D8%B1%D9%88%D9%83%D8%B3%D9%8A%D9%84" title="جذر الهيدروكسيل – Arabic" lang="ar" hreflang="ar" data-title="جذر الهيدروكسيل" data-language-autonym="العربية" data-language-local-name="Arabic" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D8%B1%D8%A7%D8%AF%DB%8C%DA%A9%D8%A7%D9%84_%D9%87%DB%8C%D8%AF%D8%B1%D9%88%DA%A9%D8%B3%DB%8C%D9%84" title="رادیکال هیدروکسیل – South Azerbaijani" lang="azb" hreflang="azb" data-title="رادیکال هیدروکسیل" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-bs mw-list-item"><a href="https://bs.wikipedia.org/wiki/Hidroksil_radikal" title="Hidroksil radikal – Bosnian" lang="bs" hreflang="bs" data-title="Hidroksil radikal" data-language-autonym="Bosanski" data-language-local-name="Bosnian" class="interlanguage-link-target"><span>Bosanski</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Radical_hidroxil" title="Radical hidroxil – Catalan" lang="ca" hreflang="ca" data-title="Radical hidroxil" data-language-autonym="Català" data-language-local-name="Catalan" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Hydroxyl-Radikal" title="Hydroxyl-Radikal – German" lang="de" hreflang="de" data-title="Hydroxyl-Radikal" data-language-autonym="Deutsch" data-language-local-name="German" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Radical_hidroxilo" title="Radical hidroxilo – Spanish" lang="es" hreflang="es" data-title="Radical hidroxilo" data-language-autonym="Español" data-language-local-name="Spanish" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%B1%D8%A7%D8%AF%DB%8C%DA%A9%D8%A7%D9%84_%D9%87%DB%8C%D8%AF%D8%B1%D9%88%DA%A9%D8%B3%DB%8C%D9%84" title="رادیکال هیدروکسیل – Persian" lang="fa" hreflang="fa" data-title="رادیکال هیدروکسیل" data-language-autonym="فارسی" data-language-local-name="Persian" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Radical_hydroxyle" title="Radical hydroxyle – French" lang="fr" hreflang="fr" data-title="Radical hydroxyle" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%ED%95%98%EC%9D%B4%EB%93%9C%EB%A1%9D%EC%8B%A4_%EB%9D%BC%EB%94%94%EC%B9%BC" title="하이드록실 라디칼 – Korean" lang="ko" hreflang="ko" data-title="하이드록실 라디칼" data-language-autonym="한국어" data-language-local-name="Korean" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Radikal_hidroksil" title="Radikal hidroksil – Indonesian" lang="id" hreflang="id" data-title="Radikal hidroksil" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesian" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Radicale_ossidrile" title="Radicale ossidrile – Italian" lang="it" hreflang="it" data-title="Radicale ossidrile" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-lv mw-list-item"><a href="https://lv.wikipedia.org/wiki/Hidroksilradik%C4%81lis" title="Hidroksilradikālis – Latvian" lang="lv" hreflang="lv" data-title="Hidroksilradikālis" data-language-autonym="Latviešu" data-language-local-name="Latvian" class="interlanguage-link-target"><span>Latviešu</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Hidroxilgy%C3%B6k" title="Hidroxilgyök – Hungarian" lang="hu" hreflang="hu" data-title="Hidroxilgyök" data-language-autonym="Magyar" data-language-local-name="Hungarian" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Hydroxylradicaal" title="Hydroxylradicaal – Dutch" lang="nl" hreflang="nl" data-title="Hydroxylradicaal" data-language-autonym="Nederlands" data-language-local-name="Dutch" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%83%92%E3%83%89%E3%83%AD%E3%82%AD%E3%82%B7%E3%83%AB%E3%83%A9%E3%82%B8%E3%82%AB%E3%83%AB" title="ヒドロキシルラジカル – Japanese" lang="ja" hreflang="ja" data-title="ヒドロキシルラジカル" data-language-autonym="日本語" data-language-local-name="Japanese" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-nds mw-list-item"><a href="https://nds.wikipedia.org/wiki/Hydroxyl-Radikal" title="Hydroxyl-Radikal – Low German" lang="nds" hreflang="nds" data-title="Hydroxyl-Radikal" data-language-autonym="Plattdüütsch" data-language-local-name="Low German" class="interlanguage-link-target"><span>Plattdüütsch</span></a></li><li class="interlanguage-link interwiki-sk mw-list-item"><a href="https://sk.wikipedia.org/wiki/Hydroxylov%C3%BD_radik%C3%A1l" title="Hydroxylový radikál – Slovak" lang="sk" hreflang="sk" data-title="Hydroxylový radikál" data-language-autonym="Slovenčina" data-language-local-name="Slovak" class="interlanguage-link-target"><span>Slovenčina</span></a></li><li class="interlanguage-link interwiki-sl mw-list-item"><a href="https://sl.wikipedia.org/wiki/Hidroksilni_radikal" title="Hidroksilni radikal – Slovenian" lang="sl" hreflang="sl" data-title="Hidroksilni radikal" data-language-autonym="Slovenščina" data-language-local-name="Slovenian" class="interlanguage-link-target"><span>Slovenščina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Hidroksil_radikal" title="Hidroksil radikal – Serbian" lang="sr" hreflang="sr" data-title="Hidroksil radikal" data-language-autonym="Српски / srpski" data-language-local-name="Serbian" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Hidroksil_radikal" title="Hidroksil radikal – Serbo-Croatian" lang="sh" hreflang="sh" data-title="Hidroksil radikal" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="Serbo-Croatian" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sv mw-list-item"><a href="https://sv.wikipedia.org/wiki/Hydroxylradikal" title="Hydroxylradikal – Swedish" lang="sv" hreflang="sv" 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Unsourced material may be challenged and removed.<br /><small><span class="plainlinks"><i>Find sources:</i> <a rel="nofollow" class="external text" href="https://www.google.com/search?as_eq=wikipedia&q=%22Hydroxyl+radical%22">"Hydroxyl radical"</a> – <a rel="nofollow" class="external text" href="https://www.google.com/search?tbm=nws&q=%22Hydroxyl+radical%22+-wikipedia&tbs=ar:1">news</a> <b>·</b> <a rel="nofollow" class="external text" href="https://www.google.com/search?&q=%22Hydroxyl+radical%22&tbs=bkt:s&tbm=bks">newspapers</a> <b>·</b> <a rel="nofollow" class="external text" href="https://www.google.com/search?tbs=bks:1&q=%22Hydroxyl+radical%22+-wikipedia">books</a> <b>·</b> <a rel="nofollow" class="external text" href="https://scholar.google.com/scholar?q=%22Hydroxyl+radical%22">scholar</a> <b>·</b> <a rel="nofollow" class="external text" href="https://www.jstor.org/action/doBasicSearch?Query=%22Hydroxyl+radical%22&acc=on&wc=on">JSTOR</a></span></small></span> <span class="date-container"><i>(<span class="date">May 2010</span>)</i></span><span class="hide-when-compact"><i> (<small><a href="/wiki/Help:Maintenance_template_removal" title="Help:Maintenance template removal">Learn how and when to remove this message</a></small>)</i></span></div></td></tr></tbody></table> <style data-mw-deduplicate="TemplateStyles:r1268415487">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}@media screen{html.skin-theme-clientpref-night .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}</style> <table class="infobox ib-chembox"> <caption>Hydroxyl radical </caption> <tbody><tr> <td colspan="2" style="text-align:center; padding:2px;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Hydroxyl_radical.svg" class="mw-file-description" title="Stick model of the hydroxyl radical with molecular orbitals"><img alt="Stick model of the hydroxyl radical with molecular orbitals" src="//upload.wikimedia.org/wikipedia/commons/thumb/d/db/Hydroxyl_radical.svg/180px-Hydroxyl_radical.svg.png" decoding="async" width="180" height="124" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/d/db/Hydroxyl_radical.svg/270px-Hydroxyl_radical.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/d/db/Hydroxyl_radical.svg/360px-Hydroxyl_radical.svg.png 2x" data-file-width="42" data-file-height="29" /></a><figcaption>Stick model of the hydroxyl radical with molecular orbitals</figcaption></figure> </td></tr> <tr> <td colspan="2" style="text-align:center; padding:2px;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:OH_orb5.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/8/8d/OH_orb5.jpg/180px-OH_orb5.jpg" decoding="async" width="180" height="151" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/8/8d/OH_orb5.jpg/270px-OH_orb5.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/8/8d/OH_orb5.jpg/360px-OH_orb5.jpg 2x" data-file-width="914" data-file-height="765" /></a><figcaption></figcaption></figure> </td></tr> <tr> <td colspan="2" class="borderless" style="text-align:center"> <table border="0" style="width:100%;display:inline-table;"> <tbody><tr> <td style="border-right:1px solid #aaa; width:50%;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Hydroxide_anion_or_hydroxyl_radical_spacefill.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6d/Hydroxide_anion_or_hydroxyl_radical_spacefill.png/110px-Hydroxide_anion_or_hydroxyl_radical_spacefill.png" decoding="async" width="110" height="104" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6d/Hydroxide_anion_or_hydroxyl_radical_spacefill.png/165px-Hydroxide_anion_or_hydroxyl_radical_spacefill.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6d/Hydroxide_anion_or_hydroxyl_radical_spacefill.png/220px-Hydroxide_anion_or_hydroxyl_radical_spacefill.png 2x" data-file-width="2000" data-file-height="1887" /></a><figcaption></figcaption></figure> </td> <td style="width:50%;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Hydroxide_anion_or_hydroxyl_radical_ball.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/Hydroxide_anion_or_hydroxyl_radical_ball.png/110px-Hydroxide_anion_or_hydroxyl_radical_ball.png" decoding="async" width="110" height="95" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/Hydroxide_anion_or_hydroxyl_radical_ball.png/165px-Hydroxide_anion_or_hydroxyl_radical_ball.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/Hydroxide_anion_or_hydroxyl_radical_ball.png/220px-Hydroxide_anion_or_hydroxyl_radical_ball.png 2x" data-file-width="2000" data-file-height="1725" /></a><figcaption></figcaption></figure> </td></tr></tbody></table> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Names </th></tr> <tr> <td colspan="2" style="text-align:left;"><a href="/wiki/Chemical_nomenclature" title="Chemical nomenclature">IUPAC name</a> <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;">Hydroxyl radical</div> </td></tr> <tr> <td colspan="2" style="text-align:left;"><a href="/wiki/Chemical_nomenclature#Systematic_name" title="Chemical nomenclature">Systematic IUPAC name</a> <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0; max-width:22em;"><style data-mw-deduplicate="TemplateStyles:r1126788409">.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}</style><div class="plainlist"><ul><li>Oxidanyl<sup id="cite_ref-Hydroxyl_(CHEBI:29191)_1-0" class="reference"><a href="#cite_note-Hydroxyl_(CHEBI:29191)-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> (substitutive)</li><li>Hydridooxygen(•)<sup id="cite_ref-Hydroxyl_(CHEBI:29191)_1-1" class="reference"><a href="#cite_note-Hydroxyl_(CHEBI:29191)-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> (additive)</li></ul></div></div></div> </td></tr> <tr> <td colspan="2" style="text-align:left;">Other names <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li>Hydroxy</li><li>Hydroxyl</li><li>λ<sup>1</sup>-Oxidanyl</li></ul></div></div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Identifiers </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CAS_Registry_Number" title="CAS Registry Number">CAS Number</a></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=3352-57-6">3352-57-6</a></span></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">3D model (<a href="/wiki/JSmol" class="mw-redirect" title="JSmol">JSmol</a>)</div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="chemapps.stolaf.edu (3D interactive model)"><a rel="nofollow" class="external text" href="https://chemapps.stolaf.edu/jmol/jmol.php?model=%5BOH%5D">Interactive image</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChEBI" title="ChEBI">ChEBI</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.ebi.ac.uk"><a rel="nofollow" class="external text" href="https://www.ebi.ac.uk/chebi/searchId.do?chebiId=29191">CHEBI:29191</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.chemspider.com"><a rel="nofollow" class="external text" href="https://www.chemspider.com/Chemical-Structure.138477.html">138477</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Gmelin_database" title="Gmelin database">Gmelin Reference</a></div> </td> <td>105 </td></tr> <tr> <td><a href="/wiki/KEGG" title="KEGG">KEGG</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.kegg.jp"><a rel="nofollow" class="external text" href="https://www.kegg.jp/entry/C16844">C16844</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/PubChem" title="PubChem">PubChem</a> <abbr title="Compound ID">CID</abbr></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="pubchem.ncbi.nlm.nih.gov"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/157350">157350</a></span></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CompTox_Chemicals_Dashboard" title="CompTox Chemicals Dashboard">CompTox Dashboard</a> <span style="font-weight:normal">(<abbr title="U.S. Environmental Protection Agency">EPA</abbr>)</span></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="comptox.epa.gov"><a rel="nofollow" class="external text" href="https://comptox.epa.gov/dashboard/chemical/details/DTXSID901318744">DTXSID901318744</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q427071#P3117" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span></span></li></ul></div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1S/HO/h1H<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: TUJKJAMUKRIRHC-UHFFFAOYSA-N<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></div></div></li></ul> </div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/Simplified_molecular-input_line-entry_system" class="mw-redirect" title="Simplified molecular-input line-entry system">SMILES</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.6em; word-wrap:break-word; text-indent:-1.5em; text-align:left; font-size:97%; line-height:120%;">[OH]</div></li></ul> </div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Properties </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></div> </td> <td><span title="Hydrogen">H</span><span title="Oxygen">O</span> </td></tr> <tr> <td><a href="/wiki/Molar_mass" title="Molar mass">Molar mass</a> </td> <td><span class="nowrap"><span data-sort-value="7001170070000000000♠"></span>17.007</span> g·mol<sup>−1</sup>   </td></tr> <tr> <td><a href="/wiki/Acid_dissociation_constant" title="Acid dissociation constant">Acidity</a> (p<i>K</i><sub>a</sub>) </td> <td>11.8 to 11.9<sup id="cite_ref-P82db_2-0" class="reference"><a href="#cite_note-P82db-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Thermochemistry </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Standard_molar_entropy" title="Standard molar entropy">Std molar<br />entropy</a> <span style="font-size:112%;">(<i>S</i><sup>⦵</sup><sub>298</sub>)</span></div> </td> <td>183.71 J K<sup>−1</sup> mol<sup>−1</sup> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Standard_enthalpy_change_of_formation" class="mw-redirect" title="Standard enthalpy change of formation">Std enthalpy of<br />formation</a> <span style="font-size:112%;">(Δ<sub>f</sub><i>H</i><sup>⦵</sup><sub>298</sub>)</span></div> </td> <td>38.99 kJ mol<sup>−1</sup> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Related compounds </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Related compounds</div> </td> <td><a href="/wiki/Dioxidanylium" title="Dioxidanylium">O<sub>2</sub>H<sup>+</sup></a><br /><a href="/wiki/Hydroxide" title="Hydroxide">OH<sup>−</sup></a><br /><a href="/wiki/Peroxide" title="Peroxide">O<sub>2</sub><sup>2−</sup></a> </td></tr> <tr> <td colspan="2" style="text-align:left; background:#f8eaba; color:inherit; border:1px solid #a2a9b1;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Except where otherwise noted, data are given for materials in their <a href="/wiki/Standard_state" title="Standard state">standard state</a> (at 25 °C [77 °F], 100 kPa).</div> <div style="margin-top: 0.3em;"></div> <div style="margin-top: 0.3em; text-align: center;"><a href="/wiki/Wikipedia:Chemical_infobox#References" title="Wikipedia:Chemical infobox">Infobox references</a></div> </td></tr> </tbody></table><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Chemical compound</div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Pyrithione-tautomerism-2D-skeletal.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/3/3e/Pyrithione-tautomerism-2D-skeletal.png/220px-Pyrithione-tautomerism-2D-skeletal.png" decoding="async" width="220" height="92" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/3/3e/Pyrithione-tautomerism-2D-skeletal.png/330px-Pyrithione-tautomerism-2D-skeletal.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/3/3e/Pyrithione-tautomerism-2D-skeletal.png/440px-Pyrithione-tautomerism-2D-skeletal.png 2x" data-file-width="1100" data-file-height="460" /></a><figcaption><a href="/wiki/Skeletal_formula" title="Skeletal formula">Skeletal formulae</a> of <a href="/wiki/Pyrithione" title="Pyrithione">1-hydroxy-2(<i>1H</i>)-pyridinethione</a> and its <a href="/wiki/Tautomer" title="Tautomer">tautomer</a></figcaption></figure> <p>The <b>hydroxyl radical</b>, <b><sup>•</sup>HO</b>, is the neutral form of the <a href="/wiki/Hydroxide_ion" class="mw-redirect" title="Hydroxide ion">hydroxide ion</a> (HO<sup>–</sup>). Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of <a href="/wiki/Radical_(chemistry)" title="Radical (chemistry)">radical chemistry</a>. Most notably hydroxyl radicals are produced from the decomposition of <a href="/wiki/Organic_peroxide" class="mw-redirect" title="Organic peroxide">hydroperoxides</a> (ROOH) or, in <a href="/wiki/Atmospheric_chemistry" title="Atmospheric chemistry">atmospheric chemistry</a>, by the reaction of <a href="/wiki/Excited_state" title="Excited state">excited</a> <a href="/wiki/Atomic_oxygen" class="mw-redirect" title="Atomic oxygen">atomic oxygen</a> with water. It is also an important radical formed in radiation chemistry, since it leads to the formation of <a href="/wiki/Hydrogen_peroxide" title="Hydrogen peroxide">hydrogen peroxide</a> and <a href="/wiki/Oxygen" title="Oxygen">oxygen</a>, which can enhance <a href="/wiki/Corrosion" title="Corrosion">corrosion</a> and <a href="/wiki/Stress_corrosion_cracking" title="Stress corrosion cracking">stress corrosion cracking</a> in coolant systems subjected to radioactive environments. Hydroxyl radicals are also produced during UV-light dissociation of H<sub>2</sub>O<sub>2</sub> (suggested in 1879) and likely in <a href="/wiki/Fenton%27s_reagent" title="Fenton's reagent">Fenton chemistry</a>, where trace amounts of reduced transition metals catalyze peroxide-mediated oxidations of organic compounds. </p><p>In <a href="/wiki/Organic_synthesis" title="Organic synthesis">organic synthesis</a> hydroxyl radicals are most commonly generated by <a href="/wiki/Photolysis" class="mw-redirect" title="Photolysis">photolysis</a> of <i><a href="/wiki/1-Hydroxy-2(1H)-pyridinethione" class="mw-redirect" title="1-Hydroxy-2(1H)-pyridinethione">1-Hydroxy-2(1H)-pyridinethione</a></i>. </p><p>The hydroxyl radical is often referred to as the "detergent" of the <a href="/wiki/Troposphere" title="Troposphere">troposphere</a> because it reacts with many pollutants, often acting as the first step to their removal. It also has an important role in eliminating some <a href="/wiki/Greenhouse_gas" title="Greenhouse gas">greenhouse gases</a> like <a href="/wiki/Methane" title="Methane">methane</a> and <a href="/wiki/Ozone" title="Ozone">ozone</a>.<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> The rate of reaction with the hydroxyl radical often determines how long many pollutants last in the atmosphere, if they do not undergo <a href="/wiki/Photolysis" class="mw-redirect" title="Photolysis">photolysis</a> or are <a href="/wiki/Precipitation" title="Precipitation">rained out</a>. For instance, methane, which reacts relatively slowly with hydroxyl radicals, has an average lifetime of >5 years and many <a href="/wiki/Chlorofluorocarbon" title="Chlorofluorocarbon">CFCs</a> have lifetimes of 50+ years. Pollutants, such as larger <a href="/wiki/Hydrocarbons" class="mw-redirect" title="Hydrocarbons">hydrocarbons</a>, can have very short average lifetimes of less than a few hours. </p><p>The first reaction with many <a href="/wiki/Volatile_organic_compounds" class="mw-redirect" title="Volatile organic compounds">volatile organic compounds</a> (VOCs) is the removal of a hydrogen atom, forming water and an <a href="/wiki/Alkyl" class="mw-redirect" title="Alkyl">alkyl</a> radical (R<sup>•</sup>): </p> <dl><dd><sup>•</sup>HO + RH → H<sub>2</sub>O + R<sup>•</sup></dd></dl> <p>The alkyl radical will typically react rapidly with <a href="/wiki/Oxygen" title="Oxygen">oxygen</a> forming a <a href="/wiki/Peroxy" class="mw-redirect" title="Peroxy">peroxy</a> radical: </p> <dl><dd>R<sup>•</sup> + O<sub>2</sub> → RO<sub>2</sub></dd></dl> <p>The fate of this radical in the <a href="/wiki/Troposphere" title="Troposphere">troposphere</a> is dependent on factors such as the amount of sunlight, pollution in the atmosphere and the nature of the <a href="/wiki/Alkyl" class="mw-redirect" title="Alkyl">alkyl</a> radical that formed it (See chapters 12 & 13 in External Links "University Lecture notes on Atmospheric chemistry) </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Biological_significance">Biological significance</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=1" title="Edit section: Biological significance"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Hydroxyl radicals can occasionally be produced as a byproduct of <a href="/wiki/Immune_system" title="Immune system">immune action</a>. <a href="/wiki/Macrophage" title="Macrophage">Macrophages</a> and <a href="/wiki/Microglia" title="Microglia">microglia</a> most frequently generate this compound when exposed to very specific <a href="/wiki/Pathogen" title="Pathogen">pathogens</a>, such as certain bacteria. The destructive action of hydroxyl radicals has been implicated in several <a href="/wiki/Neurological" class="mw-redirect" title="Neurological">neurological</a> <a href="/wiki/Autoimmune_disorder" class="mw-redirect" title="Autoimmune disorder">autoimmune diseases</a> such as <a href="/wiki/HIV-associated_dementia" class="mw-redirect" title="HIV-associated dementia">HIV-associated dementia</a>, when immune cells become over-activated and toxic to neighboring healthy cells.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p><p>The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids (<a href="/wiki/Mutation" title="Mutation">mutations</a>), lipids (<a href="/wiki/Lipid_peroxidation" title="Lipid peroxidation">lipid peroxidation</a>) and amino acids (e.g. conversion of <a href="/wiki/Phenylalanine" title="Phenylalanine">Phe</a> to m-<a href="/wiki/Tyrosine" title="Tyrosine">Tyrosine</a> and o-<a href="/wiki/Tyrosine" title="Tyrosine">Tyrosine</a>). The hydroxyl radical has a very short <i><a href="/wiki/In_vivo" title="In vivo">in vivo</a></i> <a href="/wiki/Half-life" title="Half-life">half-life</a> of approximately 10<sup>−9</sup> seconds and a high reactivity.<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> This makes it a very dangerous compound to the organism.<sup id="cite_ref-Reiter_RJ,_Melchiorri_D,_Sewerynek_E,_et_al._1995_1–11_6-0" class="reference"><a href="#cite_note-Reiter_RJ,_Melchiorri_D,_Sewerynek_E,_et_al._1995_1–11-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </p><p>Unlike <a href="/wiki/Superoxide" title="Superoxide">superoxide</a>, which can be detoxified by <a href="/wiki/Superoxide_dismutase" title="Superoxide dismutase">superoxide dismutase</a>, the hydroxyl radical cannot be eliminated by an <a href="/wiki/Enzyme" title="Enzyme">enzymatic</a> reaction. Mechanisms for scavenging peroxyl radicals for the protection of <a href="/wiki/Cell_(biology)" title="Cell (biology)">cellular</a> structures include endogenous <a href="/wiki/Antioxidants" class="mw-redirect" title="Antioxidants">antioxidants</a> such as <a href="/wiki/Melatonin" title="Melatonin">melatonin</a> and <a href="/wiki/Glutathione" title="Glutathione">glutathione</a>, and dietary <a href="/wiki/Antioxidants" class="mw-redirect" title="Antioxidants">antioxidants</a> such as <a href="/wiki/Mannitol" title="Mannitol">mannitol</a> and <a href="/wiki/Vitamin_E" title="Vitamin E">vitamin E</a>.<sup id="cite_ref-Reiter_RJ,_Melchiorri_D,_Sewerynek_E,_et_al._1995_1–11_6-1" class="reference"><a href="#cite_note-Reiter_RJ,_Melchiorri_D,_Sewerynek_E,_et_al._1995_1–11-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Importance_in_the_Earth's_atmosphere"><span id="Importance_in_the_Earth.27s_atmosphere"></span>Importance in the Earth's atmosphere</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=2" title="Edit section: Importance in the Earth's atmosphere"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The hydroxyl <sup>•</sup>HO radicals is one of the main chemical species controlling the oxidizing capacity of the Earth's atmosphere, having a major impact on the concentrations and distribution of greenhouse gases and pollutants. It is the most widespread oxidizer in the <a href="/wiki/Troposphere" title="Troposphere">troposphere</a>, the lowest part of the atmosphere. Understanding <sup>•</sup>HO variability is important to evaluating human impacts on the atmosphere and climate. The <sup>•</sup>HO species has a lifetime in the Earth atmosphere of less than one second.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> Understanding the role of <sup>•</sup>HO in the oxidation process of methane (CH<sub>4</sub>) present in the atmosphere to first carbon monoxide (CO) and then carbon dioxide (CO<sub>2</sub>) is important for assessing the residence time of this greenhouse gas, the overall carbon budget of the troposphere, and its influence on the process of global warming. The lifetime of <sup>•</sup>HO radicals in the Earth atmosphere is very short, therefore <sup>•</sup>HO concentrations in the air are very low and very sensitive techniques are required for its direct detection.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup> Global average hydroxyl radical concentrations have been measured indirectly by analyzing <a href="/wiki/Methyl_chloroform" class="mw-redirect" title="Methyl chloroform">methyl chloroform</a> (CH<sub>3</sub>CCl<sub>3</sub>) present in the air. The results obtained by Montzka <i>et al.</i> (2011)<sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> shows that the interannual variability in <sup>•</sup>HO estimated from CH<sub>3</sub>CCl<sub>3</sub> measurements is small, indicating that global <sup>•</sup>HO is generally well buffered against perturbations. This small variability is consistent with measurements of <a href="/wiki/Methane" title="Methane">methane</a> and other trace gases primarily oxidized by <sup>•</sup>HO, as well as global photochemical model calculations. </p> <div class="mw-heading mw-heading2"><h2 id="Astronomical_importance">Astronomical importance</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=3" title="Edit section: Astronomical importance"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="First_detection_of_interstellar_•HO"><span id="First_detection_of_interstellar_.E2.80.A2HO"></span>First detection of interstellar <sup>•</sup>HO</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=4" title="Edit section: First detection of interstellar •HO"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The first experimental evidence for the presence of 18 cm absorption lines of the hydroxyl (<sup>•</sup>HO) radical in the radio absorption spectrum of <a href="/wiki/Cassiopeia_A" title="Cassiopeia A">Cassiopeia A</a> was obtained by Weinreb et al. (Nature, Vol. 200, pp. 829, 1963) based on observations made during the period October 15–29, 1963.<sup id="cite_ref-DieterEwen1964_11-0" class="reference"><a href="#cite_note-DieterEwen1964-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Important_subsequent_reports_of_•HO_astronomical_detections"><span id="Important_subsequent_reports_of_.E2.80.A2HO_astronomical_detections"></span>Important subsequent reports of <sup>•</sup>HO astronomical detections</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=5" title="Edit section: Important subsequent reports of •HO astronomical detections"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <table class="wikitable" border="1"> <tbody><tr> <th><b>Year</b> </th> <th><b>Description</b> </th></tr> <tr> <td>1967 </td> <td><i><sup>•</sup>HO Molecules in the Interstellar Medium</i>. Robinson and McGee. One of the first observational reviews of <sup>•</sup>HO observations. <sup>•</sup>HO had been observed in absorption and emission, but at this time the processes which populate the energy levels are not yet known with certainty, so the article does not give good estimates of <sup>•</sup>HO densities.<sup id="cite_ref-RobinsonMcGee1967_12-0" class="reference"><a href="#cite_note-RobinsonMcGee1967-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1967 </td> <td><i>Normal <sup>•</sup>HO Emission and Interstellar Dust Clouds</i>. Heiles. First detection of normal emission from <sup>•</sup>HO in interstellar dust clouds.<sup id="cite_ref-Heiles1968_13-0" class="reference"><a href="#cite_note-Heiles1968-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1971 </td> <td><i>Interstellar molecules and dense clouds</i>.D. M. Rank, C. H. Townes, and W. J. Welch. Review of the epoch about molecular line emission of molecules through dense clouds.<sup id="cite_ref-RankTownes1971_14-0" class="reference"><a href="#cite_note-RankTownes1971-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1980 </td> <td><i><sup>•</sup>HO observations of molecular complexes in Orion and Taurus</i>. Baud and Wouterloot. Map of <sup>•</sup>HO emission in molecular complexes Orion and Taurus. Derived column densities are in good agreement with previous CO results.<sup id="cite_ref-BaudWouterloot1980_15-0" class="reference"><a href="#cite_note-BaudWouterloot1980-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1981 </td> <td><i>Emission-absorption observations of HO in diffuse interstellar clouds</i>. Dickey, Crovisier and Kazès. Observations of fifty eight regions which show HI absorption were studied. Typical densities and excitation temperature for diffuse clouds are determined in this article.<sup id="cite_ref-DickeyCrovisier1981_16-0" class="reference"><a href="#cite_note-DickeyCrovisier1981-16"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1981 </td> <td><i>Magnetic fields in molecular clouds — <sup>•</sup>HO Zeeman observations</i>. Crutcher, Troland and Heiles. <sup>•</sup>HO Zeeman observations of the absorption lines produced in interstellar dust clouds toward 3C 133, 3C 123, and W51.<sup id="cite_ref-CrutcherTroland1981_17-0" class="reference"><a href="#cite_note-CrutcherTroland1981-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1981 </td> <td><i>Detection of interstellar HO in the Far-Infrared</i>. J. Storey, D. Watson, C. Townes. Strong absorption lines of <sup>•</sup>HO were detected at wavelengths of 119.23 and 119.44 microns in the direction of Sgr B2.<sup id="cite_ref-StoreyWatson1981_18-0" class="reference"><a href="#cite_note-StoreyWatson1981-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td>1989 </td> <td><i>Molecular outflows in powerful HO megamasers</i>. Baan, Haschick and Henkel. Observations of <sup>•</sup>H and <sup>•</sup>HO molecular emission through <sup>•</sup>HO megamasers galaxies, in order to get a FIR luminosity and maser activity relation.<sup id="cite_ref-BaanHaschick1989_19-0" class="reference"><a href="#cite_note-BaanHaschick1989-19"><span class="cite-bracket">[</span>19<span class="cite-bracket">]</span></a></sup> </td></tr></tbody></table> <div class="mw-heading mw-heading3"><h3 id="Energy_levels">Energy levels</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=6" title="Edit section: Energy levels"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><sup>•</sup>HO is a diatomic molecule. The electronic angular momentum along the molecular axis is +1 or -1, and the electronic spin angular momentum S=1/2. Because of the orbit-spin coupling, the spin angular momentum can be oriented in parallel or anti parallel directions to the orbital angular momentum, producing the splitting into Π<sub>1/2</sub> and Π<sub>3/2</sub> states. The <sup>2</sup>Π<sub>3/2</sub> ground state of <sup>•</sup>HO is split by lambda doubling interaction (an interaction between the nuclei rotation and the unpaired electron motion around its orbit). Hyperfine interaction with the unpaired spin of the proton further splits the levels. </p> <ul class="gallery mw-gallery-traditional"> </ul> <div class="mw-heading mw-heading3"><h3 id="Chemistry_of_the_molecule_•HO"><span id="Chemistry_of_the_molecule_.E2.80.A2HO"></span>Chemistry of the molecule <sup>•</sup>HO</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=7" title="Edit section: Chemistry of the molecule •HO"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>In order to study gas phase interstellar chemistry, it is convenient to distinguish two types of interstellar clouds: diffuse clouds, with T=30-100 K, and n=10–1000 cm<sup>−3</sup>, and dense clouds with T=10-30K and density n=<span class="nowrap"><span data-sort-value="7004100000000000000♠"></span>10<sup>4</sup></span>-<span class="nowrap"><span data-sort-value="7003100000000000000♠"></span>10<sup>3</sup> cm<sup>−3</sup></span>. Ion chemical routes in both dense and diffuse clouds have been established for some works (Hartquist 1990). </p> <div class="mw-heading mw-heading4"><h4 id="•HO_production_pathways"><span id=".E2.80.A2HO_production_pathways"></span><i><sup>•</sup>HO production pathways</i></h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=8" title="Edit section: •HO production pathways"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The <sup>•</sup>HO radical is linked with the production of H<sub>2</sub>O in molecular clouds. Studies of <sup>•</sup>HO distribution in Taurus Molecular Cloud-1 (TMC-1)<sup id="cite_ref-HarjuWinnberg2000_20-0" class="reference"><a href="#cite_note-HarjuWinnberg2000-20"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup> suggest that in dense gas, <sup>•</sup>HO is mainly formed by dissociative recombination of H<sub>3</sub>O<sup>+</sup>. Dissociative recombination is the reaction in which a molecular ion recombines with an electron and dissociates into neutral fragments. Important formation mechanisms for <sup>•</sup>HO are: </p><p>H<sub>3</sub>O<sup>+</sup> + e<sup>−</sup> → <sup>•</sup>HO + H<sub>2</sub> (1a) Dissociative recombination </p><p>H<sub>3</sub>O<sup>+</sup> + e<sup>−</sup> → <sup>•</sup>HO + <sup>•</sup>H + <sup>•</sup>H (1b) Dissociative recombination </p><p>HCO<sub>2</sub><sup>+</sup> + e<sup>−</sup> → <sup>•</sup>HO + CO (2a) Dissociative recombination </p><p><sup>•</sup>O + HCO → <sup>•</sup>HO + CO (3a) Neutral-neutral </p><p>H<sup>−</sup> + H<sub>3</sub>O<sup>+</sup> → <sup>•</sup>HO + H<sub>2</sub> + <sup>•</sup>H (4a) Ion-molecular ion neutralization </p> <div class="mw-heading mw-heading4"><h4 id="•HO_destruction_pathways"><span id=".E2.80.A2HO_destruction_pathways"></span><i><sup>•</sup>HO destruction pathways</i></h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=9" title="Edit section: •HO destruction pathways"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Experimental data on association reactions of <sup>•</sup>H and <sup>•</sup>HO suggest that radiative association involving atomic and diatomic neutral radicals may be considered as an effective mechanism for the production of small neutral molecules in the interstellar clouds.<sup id="cite_ref-FieldAdams1980_21-0" class="reference"><a href="#cite_note-FieldAdams1980-21"><span class="cite-bracket">[</span>21<span class="cite-bracket">]</span></a></sup> The formation of O<sub>2</sub> occurs in the gas phase via the neutral exchange reaction between <sup>•</sup>O and <sup>•</sup>HO, which is also the main sink for <sup>•</sup>HO in dense regions.<sup id="cite_ref-HarjuWinnberg2000_20-1" class="reference"><a href="#cite_note-HarjuWinnberg2000-20"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup> </p><p>We can see that atomic oxygen takes part both in the production and destruction of <sup>•</sup>HO, so the abundance of <sup>•</sup>HO depends mainly on the <style data-mw-deduplicate="TemplateStyles:r1123817410">.mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}</style><span class="chemf nowrap"><a href="/wiki/Trihydrogen_cation#Destruction" title="Trihydrogen cation">H<span class="template-chem2-su"><span>+</span><span>3</span></span></a></span> abundance. Then, important chemical pathways leading from <sup>•</sup>HO radicals are: </p><p><sup>•</sup>HO + <sup>•</sup>O → O<sub>2</sub> + <sup>•</sup>H (1A) Neutral-neutral </p><p><sup>•</sup>HO + C<sup>+</sup> → CO<sup>+</sup> + <sup>•</sup>H (2A) Ion-neutral </p><p><sup>•</sup>HO + <sup>•</sup>N → NO + <sup>•</sup>H (3A) Neutral-neutral </p><p><sup>•</sup>HO + C → CO + <sup>•</sup>H (4A) Neutral-neutral </p><p><sup>•</sup>HO + <sup>•</sup>H → H<sub>2</sub>O + photon (5A) Neutral-neutral </p> <div class="mw-heading mw-heading4"><h4 id="Rate_constants_and_relative_rates_for_important_formation_and_destruction_mechanisms"><i>Rate constants and relative rates for important formation and destruction mechanisms</i></h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=10" title="Edit section: Rate constants and relative rates for important formation and destruction mechanisms"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Rate constants can be derived from the dataset published on the website <a rel="nofollow" class="external autonumber" href="http://udfa.net">[1]</a>. Rate constants have the form: </p><p>k(T) = alpha*(T/300)<sup>beta</sup>*exp(-gamma/T)cm<sup>3</sup>s<sup>−1</sup> </p><p>The following table has the rate constants calculated for a typical temperature in a dense cloud T=10 K. </p> <table class="wikitable" border="1"> <tbody><tr> <th>Reaction </th> <th>k (T=10 K) cm<sup>3</sup>s<sup>−1</sup> </th></tr> <tr> <td>1a </td> <td>3.29 10<sup>−6</sup> </td></tr> <tr> <td>1b </td> <td>1.41 10<sup>−7</sup> </td></tr> <tr> <td>2a </td> <td>4.71 10<sup>−7</sup> </td></tr> <tr> <td>3a </td> <td>5.0 10<sup>−11</sup> </td></tr> <tr> <td>4a </td> <td>1.26 10<sup>−6</sup> </td></tr> <tr> <td>5a </td> <td>2.82 10<sup>−6</sup> </td></tr> <tr> <td>1A </td> <td>7.7 10<sup>−10</sup> </td></tr> <tr> <td>2A </td> <td>3.5 10<sup>−11</sup> </td></tr> <tr> <td>3A </td> <td>1.38 10<sup>−10</sup> </td></tr> <tr> <td>4A </td> <td>1.0 10<sup>−10</sup> </td></tr> <tr> <td>5A </td> <td>3.33 10<sup>−14</sup> </td></tr></tbody></table> <p>Formation rates r<sub>ix</sub> can be obtained using the rate constants k(T) and the abundances of the reactants species C and D: </p><p>r<sub>ix</sub>=k(T)<sub>ix</sub>[C][D] </p><p>where [Y] represents the abundance of the specie Y. In this approach, abundances were taken from <i>The UMIST database for astrochemistry 2006</i>, and the values are relatives to the H<sub>2</sub> density. Following table shows the ratio r<sub>ix</sub>/r<sub>1a</sub> in order to get a view of the most important reactions. </p> <table class="wikitable" border="1"> <tbody><tr> <th> </th> <th>r<sub>1a</sub> </th> <th>r<sub>1b</sub> </th> <th>r<sub>2a</sub> </th> <th>r<sub>3a</sub> </th> <th>r<sub>4a</sub> </th> <th>r<sub>5a</sub> </th></tr> <tr> <td>r<sub>1a</sub> </td> <td>1.0 </td> <td>0.043 </td> <td>0.013 </td> <td>0.035 </td> <td>3.6 10<sup>−5</sup> </td> <td>0.679 </td></tr></tbody></table> <p>The results suggest that (1a) reaction is the most prominent reaction in dense clouds. It is in concordance with Harju et al. 2000. </p><p>Next table shows the results by doing the same procedure for destruction reaction: </p> <table class="wikitable" border="1"> <tbody><tr> <th> </th> <th>r<sub>1A</sub> </th> <th>r<sub>2A</sub> </th> <th>r<sub>3A</sub> </th> <th>r<sub>4A</sub> </th> <th>r<sub>5A</sub> </th></tr> <tr> <td>r<sub>1A</sub> </td> <td>1.0 </td> <td>6.14 10<sup>−3</sup> </td> <td>0.152 </td> <td>3.6 10<sup>−5</sup> </td> <td>4.29 10<sup>−3</sup> </td></tr></tbody></table> <p>Results shows that, 1A reaction is the main sink for HO in dense clouds. </p> <div class="mw-heading mw-heading3"><h3 id="Importance_of_interstellar_•HO_observations"><span id="Importance_of_interstellar_.E2.80.A2HO_observations"></span>Importance of interstellar <sup>•</sup>HO observations</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=11" title="Edit section: Importance of interstellar •HO observations"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Discoveries of the microwave spectra of a considerable number of molecules prove the existence of rather complex molecules in the interstellar clouds, and provides the possibility to study dense clouds, which are obscured by the dust they contain.<sup id="cite_ref-22" class="reference"><a href="#cite_note-22"><span class="cite-bracket">[</span>22<span class="cite-bracket">]</span></a></sup> The <sup>•</sup>HO molecule has been observed in the interstellar medium since 1963 through its 18-cm transitions.<sup id="cite_ref-23" class="reference"><a href="#cite_note-23"><span class="cite-bracket">[</span>23<span class="cite-bracket">]</span></a></sup> In the subsequent years <sup>•</sup>HO was observed by its rotational transitions at far infrared wavelengths, mainly in the Orion region. Because each rotational level of <sup>•</sup>HO is split in by lambda doubling, astronomers can observe a wide variety of energy states from the ground state. </p> <div class="mw-heading mw-heading4"><h4 id="•HO_as_a_tracer_of_shock_conditions"><span id=".E2.80.A2HO_as_a_tracer_of_shock_conditions"></span><sup>•</sup>HO as a tracer of shock conditions</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=12" title="Edit section: •HO as a tracer of shock conditions"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Very high densities are required to thermalize the rotational transitions of <sup>•</sup>HO,<sup id="cite_ref-24" class="reference"><a href="#cite_note-24"><span class="cite-bracket">[</span>24<span class="cite-bracket">]</span></a></sup> so it is difficult to detect far-infrared emission lines from a quiescent molecular cloud. Even at H<sub>2</sub> densities of 10<sup>6</sup> cm<sup>−3</sup>, dust must be optically thick at infrared wavelengths. But the passage of a shock wave through a molecular cloud is precisely the process which can bring the molecular gas out of equilibrium with the dust, making observations of far-infrared emission lines possible. A moderately fast shock may produce a transient raise in the <sup>•</sup>HO abundance relative to hydrogen. So, it is possible that far-infrared emission lines of <sup>•</sup>HO can be a good diagnostic of shock conditions. </p> <div class="mw-heading mw-heading4"><h4 id="In_diffuse_clouds">In diffuse clouds</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=13" title="Edit section: In diffuse clouds"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Diffuse clouds are of astronomical interest because they play a primary role in the evolution and thermodynamics of ISM. Observation of the abundant atomic hydrogen in 21 cm has shown good signal-to-noise ratio in both emission and absorption. Nevertheless, HI observations have a fundamental difficulty when are directed to low mass regions of the hydrogen nucleus, as the center part of a diffuse cloud: Thermal width of hydrogen lines are the same order as the internal velocities' structures of interest, so clouds components of various temperatures and central velocities are indistinguishable in the spectrum. Molecular lines observations in principle doesn't suffer from these problems. Unlike HI, molecules generally have <a href="/wiki/Excitation_temperature" title="Excitation temperature">excitation temperature</a> T<sub>ex</sub> << T<sub>kin</sub>, so that emission is very weak even from abundant species. CO and <sup>•</sup>HO are considered to be the most easily studied candidate molecules. CO has transitions in a region of the spectrum (wavelength < 3 mm) where there are not strong background continuum sources, but <sup>•</sup>HO has the 18 cm emission, line convenient for absorption observations.<sup id="cite_ref-DickeyCrovisier1981_16-1" class="reference"><a href="#cite_note-DickeyCrovisier1981-16"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup> Observation studies provide the most sensitive means of detections of molecules with sub thermal excitation, and can give the opacity of the spectral line, which is a central issue to model the molecular region. </p><p>Studies based in the kinematic comparison of <sup>•</sup>HO and HI absorption lines from diffuse clouds are useful in determining their physical conditions, especially because heavier elements provide higher velocity resolution. </p> <div class="mw-heading mw-heading4"><h4 id="•HO_masers"><span id=".E2.80.A2HO_masers"></span><sup>•</sup>HO masers</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=14" title="Edit section: •HO masers"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><sup>•</sup>HO <a href="/wiki/Maser" title="Maser">masers</a>, a type of <a href="/wiki/Astrophysical_maser" title="Astrophysical maser">astrophysical maser</a>, were the first masers to be discovered in space and have been observed in more environments than any other type of maser. </p><p>In the <a href="/wiki/Milky_Way" title="Milky Way">Milky Way</a>, <sup>•</sup>HO masers are found in stellar masers (evolved stars), interstellar masers (regions of massive star formation), or in the interface between supernova remnants and molecular material. Interstellar HO masers are often observed from molecular material surrounding ultracompact <a href="/wiki/H_II_region" title="H II region">H II regions</a> (UC H II). But there are masers associated with very young stars that have yet to create UC H II regions.<sup id="cite_ref-25" class="reference"><a href="#cite_note-25"><span class="cite-bracket">[</span>25<span class="cite-bracket">]</span></a></sup> This class of <sup>•</sup>HO masers appears to form near the edges of very dense material, places where H<sub>2</sub>O masers form, and where total densities drop rapidly, and UV radiation from young stars can dissociate the H<sub>2</sub>O molecules. So, observations of <sup>•</sup>HO masers in these regions, can be an important way to probe the distribution of the important H<sub>2</sub>O molecule in interstellar shocks at high <a href="/wiki/Spatial_resolution" title="Spatial resolution">spatial resolutions</a>. </p><p><b>Application in <a href="/wiki/Water_purification" title="Water purification">water purification</a></b> </p><p>Hydroxyl radicals also play a key role in the <a href="/wiki/Oxidative" class="mw-redirect" title="Oxidative">oxidative</a> destruction of <a href="/wiki/Persistent_organic_pollutant" title="Persistent organic pollutant">organic pollutants</a>.<sup id="cite_ref-26" class="reference"><a href="#cite_note-26"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="See_also">See also</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=15" title="Edit section: See also"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Hydroxyl_ion_absorption" title="Hydroxyl ion absorption">Hydroxyl ion absorption</a></li> <li><a href="/wiki/Hydrogen_darkening" title="Hydrogen darkening">Hydrogen darkening</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyl_radical&action=edit&section=16" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist reflist-columns references-column-width reflist-columns-2"> <ol class="references"> <li id="cite_note-Hydroxyl_(CHEBI:29191)-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-Hydroxyl_(CHEBI:29191)_1-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-Hydroxyl_(CHEBI:29191)_1-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite class="citation web cs1"><a rel="nofollow" class="external text" href="http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:29191">"Hydroxyl (CHEBI:29191)"</a>. <i>Chemical Entities of Biological Interest (ChEBI)</i>. 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href="/wiki/Template:Molecules_detected_in_outer_space" title="Template:Molecules detected in outer space"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Molecules_detected_in_outer_space" title="Template talk:Molecules detected in outer space"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Molecules_detected_in_outer_space" title="Special:EditPage/Template:Molecules detected in outer space"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Molecules_detected_in_outer_space800" style="font-size:114%;margin:0 4em"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules" title="List of interstellar and circumstellar molecules">Molecules detected in outer space</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Molecule" title="Molecule">Molecules</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Diatomic_molecule" title="Diatomic molecule">Diatomic</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Aluminium_monochloride" title="Aluminium monochloride">Aluminium monochloride</a></li> <li><a href="/wiki/Aluminium_monofluoride" title="Aluminium monofluoride">Aluminium monofluoride</a></li> <li><a href="/wiki/Aluminium(II)_oxide" title="Aluminium(II) oxide">Aluminium(II) oxide</a></li> <li><a href="/wiki/Argonium" title="Argonium">Argonium</a></li> <li><a href="/wiki/Carbon_cation" class="mw-redirect" title="Carbon cation">Carbon cation</a></li> <li><a href="/wiki/Carbon_monophosphide" title="Carbon monophosphide">Carbon monophosphide</a></li> <li><a href="/wiki/Carbon_monosulfide" title="Carbon monosulfide">Carbon monosulfide</a></li> <li><a href="/wiki/Carbon_monoxide" title="Carbon monoxide">Carbon monoxide</a></li> <li><a href="/wiki/Cyano_radical" title="Cyano radical">Cyano radical</a></li> <li><a href="/wiki/Diatomic_carbon" title="Diatomic carbon">Diatomic carbon</a></li> <li><a href="/w/index.php?title=Fluoromethylidynium&action=edit&redlink=1" class="new" title="Fluoromethylidynium (page does not exist)">Fluoromethylidynium</a></li> <li><a href="/wiki/Helium_hydride_ion" title="Helium hydride ion">Helium hydride ion</a></li> <li><a href="/wiki/Hydrogen_chloride" title="Hydrogen chloride">Hydrogen chloride</a></li> <li><a href="/wiki/Hydrogen_fluoride" title="Hydrogen fluoride">Hydrogen fluoride</a></li> <li><a href="/wiki/Hydrogen" title="Hydrogen">Hydrogen</a> (molecular)</li> <li><a class="mw-selflink selflink">Hydroxyl radical</a></li> <li><a href="/wiki/Imidogen" title="Imidogen">Imidogen</a></li> <li><a href="/wiki/Iron(II)_oxide" title="Iron(II) oxide">Iron(II) oxide</a></li> <li><a href="/wiki/Magnesium_monohydride" title="Magnesium monohydride">Magnesium monohydride</a></li> <li><a href="/wiki/Methylidyne_radical" title="Methylidyne radical">Methylidyne radical</a></li> <li><a href="/wiki/Nitric_oxide" title="Nitric oxide">Nitric oxide</a></li> <li><a href="/wiki/Nitrogen" title="Nitrogen">Nitrogen</a> (molecular)</li> <li><a href="/wiki/Oxygen" title="Oxygen">Oxygen</a> (molecular)</li> <li><a href="/wiki/Phosphorus_monoxide" title="Phosphorus monoxide">Phosphorus monoxide</a></li> <li><a href="/wiki/Phosphorus_mononitride" title="Phosphorus mononitride">Phosphorus mononitride</a></li> <li><a href="/wiki/Potassium_chloride" title="Potassium chloride">Potassium chloride</a></li> <li><a href="/wiki/Silicon_carbide" title="Silicon carbide">Silicon carbide</a></li> <li><a href="/wiki/Silicon_monoxide" title="Silicon monoxide">Silicon monoxide</a></li> <li><a href="/wiki/Silicon_monosulfide" title="Silicon monosulfide">Silicon monosulfide</a></li> <li><a href="/wiki/Sodium_chloride" title="Sodium chloride">Sodium chloride</a></li> <li><a href="/wiki/Sodium_iodide" title="Sodium iodide">Sodium iodide</a></li> <li><a href="/wiki/Sulfanyl" title="Sulfanyl">Sulfanyl</a></li> <li><a href="/wiki/Sulfur_mononitride" title="Sulfur mononitride">Sulfur mononitride</a></li> <li><a href="/wiki/Sulfur_monoxide" title="Sulfur monoxide">Sulfur monoxide</a></li> <li><a href="/wiki/Titanium(II)_oxide" title="Titanium(II) oxide">Titanium(II) oxide</a></li></ul> </div></td><td class="noviewer navbox-image" rowspan="9" style="width:1px;padding:0 0 0 2px"><div><span typeof="mw:File"><a href="/wiki/Nitrous_oxide" title="Nitrous oxide"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/93/Nitrous-oxide-3D-balls.png/60px-Nitrous-oxide-3D-balls.png" decoding="async" width="60" height="24" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/93/Nitrous-oxide-3D-balls.png/90px-Nitrous-oxide-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/93/Nitrous-oxide-3D-balls.png/120px-Nitrous-oxide-3D-balls.png 2x" data-file-width="1100" data-file-height="441" /></a></span> <br /><br /><br /><br /> <span typeof="mw:File"><a href="/wiki/Ethanol" title="Ethanol"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Ethanol-3D-balls.png/60px-Ethanol-3D-balls.png" decoding="async" width="60" height="41" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Ethanol-3D-balls.png/90px-Ethanol-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Ethanol-3D-balls.png/120px-Ethanol-3D-balls.png 2x" data-file-width="1100" data-file-height="754" /></a></span> <br /><br /><br /><br /> <span typeof="mw:File"><a href="/wiki/Buckminsterfullerene" title="Buckminsterfullerene"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/0/0f/Buckminsterfullerene-perspective-3D-balls.png/60px-Buckminsterfullerene-perspective-3D-balls.png" decoding="async" width="60" height="63" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/0/0f/Buckminsterfullerene-perspective-3D-balls.png/90px-Buckminsterfullerene-perspective-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/0/0f/Buckminsterfullerene-perspective-3D-balls.png/120px-Buckminsterfullerene-perspective-3D-balls.png 2x" data-file-width="1056" data-file-height="1100" /></a></span></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Triatomic_molecule" title="Triatomic molecule">Triatomic</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Aluminium(I)_hydroxide" class="mw-redirect" title="Aluminium(I) hydroxide">Aluminium(I) hydroxide</a></li> <li><a href="/w/index.php?title=Aluminium_isocyanide&action=edit&redlink=1" class="new" title="Aluminium isocyanide (page does not exist)">Aluminium isocyanide</a></li> <li><a href="/wiki/Amino_radical" title="Amino radical">Amino radical</a></li> <li><a href="/wiki/Carbon_dioxide" title="Carbon dioxide">Carbon dioxide</a></li> <li><a href="/wiki/Carbonyl_sulfide" title="Carbonyl sulfide">Carbonyl sulfide</a></li> <li><a href="/w/index.php?title=CCP_radical&action=edit&redlink=1" class="new" title="CCP radical (page does not exist)">CCP radical</a></li> <li><a href="/wiki/Halonium_ion" title="Halonium ion">Chloronium</a></li> <li><a href="/wiki/Diazenylium" title="Diazenylium">Diazenylium</a></li> <li><a href="/wiki/Dicarbon_monoxide" title="Dicarbon monoxide">Dicarbon monoxide</a></li> <li><a href="/w/index.php?title=Disilicon_carbide&action=edit&redlink=1" class="new" title="Disilicon carbide (page does not exist)">Disilicon carbide</a></li> <li><a href="/wiki/Ethynyl_radical" title="Ethynyl radical">Ethynyl radical</a></li> <li><a href="/w/index.php?title=Formyl_radical&action=edit&redlink=1" class="new" title="Formyl radical (page does not exist)">Formyl radical</a></li> <li><a href="/wiki/Hydrogen_cyanide" title="Hydrogen cyanide">Hydrogen cyanide</a> (HCN)</li> <li><a href="/wiki/Hydrogen_isocyanide" title="Hydrogen isocyanide">Hydrogen isocyanide</a> (HNC)</li> <li><a href="/wiki/Hydrogen_sulfide" title="Hydrogen sulfide">Hydrogen sulfide</a></li> <li><a href="/wiki/Hydroperoxyl" title="Hydroperoxyl">Hydroperoxyl</a></li> <li><a href="/wiki/Iron(II)_cyanide" title="Iron(II) cyanide">Iron cyanide</a></li> <li><a href="/w/index.php?title=Isoformyl&action=edit&redlink=1" class="new" title="Isoformyl (page does not exist)">Isoformyl</a></li> <li><a href="/wiki/Magnesium_cyanide" title="Magnesium cyanide">Magnesium cyanide</a></li> <li><a href="/w/index.php?title=Magnesium_isocyanide&action=edit&redlink=1" class="new" title="Magnesium isocyanide (page does not exist)">Magnesium isocyanide</a></li> <li><a href="/wiki/Methylene_(compound)" title="Methylene (compound)">Methylene</a></li> <li><a href="/wiki/Methylidynephosphane" title="Methylidynephosphane">Methylidynephosphane</a></li> <li><a href="/wiki/Diazenylium" title="Diazenylium">N<sub>2</sub>H<sup>+</sup></a></li> <li><a href="/wiki/Nitrous_oxide" title="Nitrous oxide">Nitrous oxide</a></li> <li><a href="/wiki/Nitroxyl" title="Nitroxyl">Nitroxyl</a></li> <li><a href="/wiki/Ozone" title="Ozone">Ozone</a></li> <li><a href="/wiki/Potassium_cyanide" title="Potassium cyanide">Potassium cyanide</a></li> <li><a href="/wiki/Sodium_cyanide" title="Sodium cyanide">Sodium cyanide</a></li> <li><a href="/wiki/Sodium_hydroxide" title="Sodium hydroxide">Sodium hydroxide</a></li> <li><a href="/w/index.php?title=Silicon_carbonitride&action=edit&redlink=1" class="new" title="Silicon carbonitride (page does not exist)">Silicon carbonitride</a></li> <li><a href="/w/index.php?title=C-Silicon_dicarbide&action=edit&redlink=1" class="new" title="C-Silicon dicarbide (page does not exist)">c-Silicon dicarbide</a></li> <li><a href="/w/index.php?title=SiNC&action=edit&redlink=1" class="new" title="SiNC (page does not exist)">SiNC</a></li> <li><a href="/wiki/Sulfur_dioxide" title="Sulfur dioxide">Sulfur dioxide</a></li> <li><a href="/w/index.php?title=Thioformyl&action=edit&redlink=1" class="new" title="Thioformyl (page does not exist)">Thioformyl</a></li> <li><a href="/wiki/Thioxoethenylidene" title="Thioxoethenylidene">Thioxoethenylidene</a></li> <li><a href="/wiki/Titanium_dioxide" title="Titanium dioxide">Titanium dioxide</a></li> <li><a href="/wiki/Tricarbon" title="Tricarbon">Tricarbon</a></li> <li><a href="/wiki/Trihydrogen_cation" title="Trihydrogen cation">Trihydrogen cation</a></li> <li><a href="/wiki/Water" title="Water">Water</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Four<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetylene" title="Acetylene">Acetylene</a></li> <li><a href="/wiki/Ammonia" title="Ammonia">Ammonia</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Cyanoethynyl</a></li> <li><a href="/wiki/Interstellar_formaldehyde" title="Interstellar formaldehyde">Formaldehyde</a></li> <li><a href="/wiki/Fulminic_acid" title="Fulminic acid">Fulminic acid</a></li> <li><a href="/w/index.php?title=HCCN&action=edit&redlink=1" class="new" title="HCCN (page does not exist)">HCCN</a></li> <li><a href="/wiki/Hydrogen_peroxide" title="Hydrogen peroxide">Hydrogen peroxide</a></li> <li><a href="/w/index.php?title=Hydromagnesium_isocyanide&action=edit&redlink=1" class="new" title="Hydromagnesium isocyanide (page does not exist)">Hydromagnesium isocyanide</a></li> <li><a href="/wiki/Isocyanic_acid" title="Isocyanic acid">Isocyanic acid</a></li> <li><a href="/wiki/Thiocyanic_acid" title="Thiocyanic acid">Isothiocyanic acid</a></li> <li><a href="/w/index.php?title=Ketenyl&action=edit&redlink=1" class="new" title="Ketenyl (page does not exist)">Ketenyl</a></li> <li><a href="/wiki/Methyl_cation" class="mw-redirect" title="Methyl cation">Methyl cation</a></li> <li><a href="/wiki/Methyl_radical" title="Methyl radical">Methyl radical</a></li> <li><a href="/w/index.php?title=Methylene_amidogen&action=edit&redlink=1" class="new" title="Methylene amidogen (page does not exist)">Methylene amidogen</a></li> <li><a href="/wiki/Propynylidyne" title="Propynylidyne">Propynylidyne</a></li> <li><a href="/w/index.php?title=Protonated_carbon_dioxide&action=edit&redlink=1" class="new" title="Protonated carbon dioxide (page does not exist)">Protonated carbon dioxide</a></li> <li><a href="/wiki/Protonated_hydrogen_cyanide" title="Protonated hydrogen cyanide">Protonated hydrogen cyanide</a></li> <li><a href="/w/index.php?title=Silicon_tricarbide&action=edit&redlink=1" class="new" title="Silicon tricarbide (page does not exist)">Silicon tricarbide</a></li> <li><a href="/wiki/Thiocyanic_acid" title="Thiocyanic acid">Thiocyanic acid</a></li> <li><a href="/wiki/Thioformaldehyde" title="Thioformaldehyde">Thioformaldehyde</a></li> <li><a href="/wiki/Tricarbon_monosulfide" title="Tricarbon monosulfide">Tricarbon monosulfide</a></li> <li><a href="/wiki/Tricarbon_monoxide" title="Tricarbon monoxide">Tricarbon monoxide</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Five<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Ammonium" title="Ammonium">Ammonium</a> ion</li> <li><a href="/wiki/Polyyne" title="Polyyne">Butadiynyl</a></li> <li><a href="/wiki/Carbodiimide" title="Carbodiimide">Carbodiimide</a></li> <li><a href="/wiki/Cyanamide" title="Cyanamide">Cyanamide</a></li> <li><a href="/wiki/Cyanoacetylene" title="Cyanoacetylene">Cyanoacetylene</a></li> <li><a href="/w/index.php?title=Cyanoformaldehyde&action=edit&redlink=1" class="new" title="Cyanoformaldehyde (page does not exist)">Cyanoformaldehyde</a></li> <li><a href="/wiki/Cyanomethyl" title="Cyanomethyl">Cyanomethyl</a></li> <li><a href="/wiki/Cyclopropenylidene" title="Cyclopropenylidene">Cyclopropenylidene</a></li> <li><a href="/wiki/Formic_acid" title="Formic acid">Formic acid</a></li> <li><a href="/w/index.php?title=Isocyanoacetylene&action=edit&redlink=1" class="new" title="Isocyanoacetylene (page does not exist)">Isocyanoacetylene</a></li> <li><a href="/wiki/Ketene" title="Ketene">Ketene</a></li> <li><a href="/wiki/Methane" title="Methane">Methane</a></li> <li><a href="/wiki/Methoxy" class="mw-redirect" title="Methoxy">Methoxy radical</a></li> <li><a href="/w/index.php?title=Methylenimine&action=edit&redlink=1" class="new" title="Methylenimine (page does not exist)">Methylenimine</a></li> <li><a href="/w/index.php?title=Propadienylidene&action=edit&redlink=1" class="new" title="Propadienylidene (page does not exist)">Propadienylidene</a></li> <li><a href="/w/index.php?title=Protonated_formaldehyde&action=edit&redlink=1" class="new" title="Protonated formaldehyde (page does not exist)">Protonated formaldehyde</a></li> <li><a href="/wiki/Silane" title="Silane">Silane</a></li> <li><a href="/w/index.php?title=Silicon-carbide_cluster&action=edit&redlink=1" class="new" title="Silicon-carbide cluster (page does not exist)">Silicon-carbide cluster</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Six<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetonitrile" title="Acetonitrile">Acetonitrile</a></li> <li><a href="/w/index.php?title=Cyanobutadiynyl_radical&action=edit&redlink=1" class="new" title="Cyanobutadiynyl radical (page does not exist)">Cyanobutadiynyl radical</a></li> <li><a href="/wiki/Cyclopropenone" title="Cyclopropenone">Cyclopropenone</a></li> <li><a href="/wiki/Diacetylene" title="Diacetylene">Diacetylene</a></li> <li><a href="/w/index.php?title=E-Cyanomethanimine&action=edit&redlink=1" class="new" title="E-Cyanomethanimine (page does not exist)">E-Cyanomethanimine</a></li> <li><a href="/wiki/Ethylene" title="Ethylene">Ethylene</a></li> <li><a href="/wiki/Formamide" title="Formamide">Formamide</a></li> <li><a href="/w/index.php?title=HC4N&action=edit&redlink=1" class="new" title="HC4N (page does not exist)">HC<sub>4</sub>N</a></li> <li><a href="/wiki/Ketenimine" class="mw-redirect" title="Ketenimine">Ketenimine</a></li> <li><a href="/wiki/Methanethiol" title="Methanethiol">Methanethiol</a></li> <li><a href="/wiki/Methanol" title="Methanol">Methanol</a></li> <li><a href="/wiki/Methyl_isocyanide" title="Methyl isocyanide">Methyl isocyanide</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Pentynylidyne</a></li> <li><a href="/wiki/Propynal" class="mw-redirect" title="Propynal">Propynal</a></li> <li><a href="/w/index.php?title=Protonated_cyanoacetylene&action=edit&redlink=1" class="new" title="Protonated cyanoacetylene (page does not exist)">Protonated cyanoacetylene</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Seven<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetaldehyde" title="Acetaldehyde">Acetaldehyde</a></li> <li><a href="/wiki/Acrylonitrile" title="Acrylonitrile">Acrylonitrile</a> <ul><li><a href="/wiki/Vinyl_cyanide" class="mw-redirect" title="Vinyl cyanide">Vinyl cyanide</a></li></ul></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Cyanodiacetylene</a></li> <li><a href="/wiki/Ethylene_oxide" title="Ethylene oxide">Ethylene oxide</a></li> <li><a href="/wiki/Glycolonitrile" title="Glycolonitrile">Glycolonitrile</a></li> <li><a href="/wiki/Hexatriynyl_radical" title="Hexatriynyl radical">Hexatriynyl radical</a></li> <li><a href="/wiki/Methyl_isocyanate" title="Methyl isocyanate">Methyl isocyanate</a></li> <li><a href="/wiki/Methylamine" title="Methylamine">Methylamine</a></li> <li><a href="/wiki/Propyne" title="Propyne">Propyne</a></li> <li><a href="/wiki/Vinyl_alcohol" title="Vinyl alcohol">Vinyl alcohol</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Eight<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetic_acid" title="Acetic acid">Acetic acid</a></li> <li><a href="/wiki/Acrolein" title="Acrolein">Acrolein</a></li> <li><a href="/wiki/Aminoacetonitrile" title="Aminoacetonitrile">Aminoacetonitrile</a></li> <li><a href="/w/index.php?title=Cyanoallene&action=edit&redlink=1" class="new" title="Cyanoallene (page does not exist)">Cyanoallene</a></li> <li><a href="/wiki/Ethanimine" title="Ethanimine">Ethanimine</a></li> <li><a href="/wiki/Glycolaldehyde" title="Glycolaldehyde">Glycolaldehyde</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Hexapentaenylidene</a></li> <li><a href="/wiki/Methyl_formate" title="Methyl formate">Methyl formate</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Methylcyanoacetylene</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Nine<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetamide" title="Acetamide">Acetamide</a></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Cyanohexatriyne</a></li> <li><a href="/wiki/Dimethyl_ether" title="Dimethyl ether">Dimethyl ether</a></li> <li><a href="/wiki/Ethanethiol" title="Ethanethiol">Ethanethiol</a></li> <li><a href="/wiki/Ethanol" title="Ethanol">Ethanol</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Methyldiacetylene</a></li> <li><a href="/wiki/N-Methylformamide" title="N-Methylformamide">N-Methylformamide</a></li> <li><a href="/wiki/Octatetraynyl_radical" title="Octatetraynyl radical">Octatetraynyl radical</a></li> <li><a href="/wiki/Propene" class="mw-redirect" title="Propene">Propene</a></li> <li><a href="/wiki/Propionitrile" title="Propionitrile">Propionitrile</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Ten<br />atoms<br />or more</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetone" title="Acetone">Acetone</a></li> <li><a href="/wiki/Benzene" title="Benzene">Benzene</a></li> <li><a href="/wiki/Benzonitrile" title="Benzonitrile">Benzonitrile</a></li> <li><a href="/wiki/Buckminsterfullerene" title="Buckminsterfullerene">Buckminsterfullerene</a> (C<sub>60</sub>, C<sub>60</sub><sup>+</sup>, fullerene, buckyball)</li> <li><a href="/wiki/Butyronitrile" title="Butyronitrile">Butyronitrile</a></li> <li><a href="/wiki/C70_fullerene" title="C70 fullerene">C<sub>70</sub> fullerene</a></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Cyanodecapentayne</a></li> <li><a href="/wiki/Ethyl_formate" title="Ethyl formate">Ethyl formate</a></li> <li><a href="/wiki/Ethylene_glycol" title="Ethylene glycol">Ethylene glycol</a></li> <li><a href="/w/index.php?title=Heptatrienyl_radical&action=edit&redlink=1" class="new" title="Heptatrienyl radical (page does not exist)">Heptatrienyl radical</a></li> <li><a href="/wiki/Methyl_acetate" title="Methyl acetate">Methyl acetate</a></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Methyl-cyano-diacetylene</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Methyltriacetylene</a></li> <li><a href="/wiki/Propionaldehyde" title="Propionaldehyde">Propionaldehyde</a></li> <li><a href="/wiki/Pyrimidine" title="Pyrimidine">Pyrimidine</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Deuterium" title="Deuterium">Deuterated</a><br />molecules</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Ammonia" title="Ammonia">Ammonia</a></li> <li><a href="/wiki/Ammonium" title="Ammonium">Ammonium</a> ion</li> <li><a href="/wiki/Formaldehyde" title="Formaldehyde">Formaldehyde</a></li> <li><a href="/wiki/Interstellar_formaldehyde#Interstellar_reactions" title="Interstellar formaldehyde">Formyl radical</a></li> <li><a href="/wiki/Heavy_water" title="Heavy water">Heavy water</a></li> <li><a href="/wiki/Hydrogen_cyanide" title="Hydrogen cyanide">Hydrogen cyanide</a></li> <li><a href="/wiki/Hydrogen_deuteride" title="Hydrogen deuteride">Hydrogen deuteride</a></li> <li><a href="/wiki/Hydrogen_isocyanide" title="Hydrogen isocyanide">Hydrogen isocyanide</a></li> <li><a href="/wiki/Diazenylium" title="Diazenylium">N<sub>2</sub>D<sup>+</sup></a></li> <li><a href="/wiki/Propyne" title="Propyne">Propyne</a></li> <li><a href="/wiki/Trihydrogen_cation" title="Trihydrogen cation">Trihydrogen cation</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Unconfirmed</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Anthracene" title="Anthracene">Anthracene</a></li> <li><a href="/wiki/Dihydroxyacetone" title="Dihydroxyacetone">Dihydroxyacetone</a></li> <li><a href="/wiki/Glycine" title="Glycine">Glycine</a></li> <li><a href="/wiki/Graphene" title="Graphene">Graphene</a></li> <li><a href="/w/index.php?title=H2NCO%2B&action=edit&redlink=1" class="new" title="H2NCO+ (page does not exist)">H<sub>2</sub>NCO<sup>+</sup></a></li> <li><a href="/wiki/Hemolithin" title="Hemolithin">Hemolithin</a></li> <li><a href="/wiki/Carbon" title="Carbon">Linear C<sub>5</sub></a></li> <li><a href="/wiki/Methoxyethane" title="Methoxyethane">Methoxyethane</a></li> <li><a href="/wiki/Naphthalene" title="Naphthalene">Naphthalene cation</a></li> <li><a href="/wiki/Phosphine" title="Phosphine">Phosphine</a></li> <li><a href="/wiki/Pyrene" title="Pyrene">Pyrene</a></li> <li><a href="/wiki/Silylidyne" title="Silylidyne">Silylidyne</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#See_also" title="List of interstellar and circumstellar molecules">Related</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Abiogenesis" title="Abiogenesis">Abiogenesis</a></li> <li><a href="/wiki/Astrobiology" title="Astrobiology">Astrobiology</a></li> <li><a href="/wiki/Astrochemistry" title="Astrochemistry">Astrochemistry</a></li> <li><a href="/wiki/Atomic_and_molecular_astrophysics" title="Atomic and molecular astrophysics">Atomic and molecular astrophysics</a></li> <li><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></li> <li><a href="/wiki/Circumstellar_dust" title="Circumstellar dust">Circumstellar dust</a></li> <li><a href="/wiki/Circumstellar_envelope" title="Circumstellar envelope">Circumstellar envelope</a></li> <li><a href="/wiki/Cosmic_dust" title="Cosmic dust">Cosmic dust</a></li> <li><a href="/wiki/Cosmic_ray" title="Cosmic ray">Cosmic ray</a></li> <li><a href="/wiki/Cosmochemistry" title="Cosmochemistry">Cosmochemistry</a></li> <li><a href="/wiki/Diffuse_interstellar_band" class="mw-redirect" title="Diffuse 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theory</a></li> <li><a href="/wiki/Kerogen" title="Kerogen">Kerogen</a></li> <li><a href="/wiki/Molecules_in_stars" title="Molecules in stars">Molecules in stars</a></li> <li><a href="/wiki/Nexus_for_Exoplanet_System_Science" title="Nexus for Exoplanet System Science">Nexus for Exoplanet System Science</a></li> <li><a href="/wiki/Organic_compound" title="Organic compound">Organic compound</a></li> <li><a href="/wiki/Outer_space" title="Outer space">Outer space</a></li> <li><a href="/wiki/PAH_world_hypothesis" title="PAH world hypothesis">PAH world hypothesis</a></li> <li><a href="/wiki/Photodissociation_region" title="Photodissociation region">Photodissociation region</a></li> <li><a href="/wiki/Polycyclic_aromatic_hydrocarbon" title="Polycyclic aromatic hydrocarbon">Polycyclic aromatic hydrocarbon</a> (PAH)</li> <li><a href="/wiki/Pseudo-panspermia" title="Pseudo-panspermia">Pseudo-panspermia</a></li> <li><a href="/wiki/RNA_world_hypothesis" class="mw-redirect" title="RNA world 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