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violet</title> <meta name="description" content="Search results for: methyl violet"> <meta name="keywords" content="methyl violet"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none navbar-toggler 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id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="methyl violet"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 555</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: methyl violet</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">555</span> Adsorption of Methyl Violet Dye from Aqueous Solution onto Modified Kapok Sawdust : Characteristics and Equilibrium Studies</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Widi%20Astuti">Widi Astuti</a>, <a href="https://publications.waset.org/abstracts/search?q=Triastuti%20Sulistyaningsih"> Triastuti Sulistyaningsih</a>, <a href="https://publications.waset.org/abstracts/search?q=Masni%20Maksiola"> Masni Maksiola</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Kapok sawdust, an inexpensive material, has been utilized as an adsorbent for the removal of methyl violet in aqueous solution. To increase the adsorption capacity, kapok sawdust was reacted with sodium hydroxide (NaOH) solution having various concentrations. Various physico-chemical parameters such as solution pH, contact time and initial dye concentration were studied. Langmuir, Freundlich and Redlich-Peterson isotherm model were used to analyze the equilibrium data. The research shows that the experimental data fitted well with the Redlich-Peterson model, with the value of constants are 41.001 for KR, 0.523 for aR and 0.799 for g. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=kapok%20sawdust" title="kapok sawdust">kapok sawdust</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20violet" title=" methyl violet"> methyl violet</a>, <a href="https://publications.waset.org/abstracts/search?q=dye" title=" dye"> dye</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a> </p> <a href="https://publications.waset.org/abstracts/31072/adsorption-of-methyl-violet-dye-from-aqueous-solution-onto-modified-kapok-sawdust-characteristics-and-equilibrium-studies" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/31072.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">312</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">554</span> The Effect of Calcining Temperature on Photocatalytic Activity of Porous ZnO Architecture</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Masar">M. Masar</a>, <a href="https://publications.waset.org/abstracts/search?q=P.%20Janota"> P. Janota</a>, <a href="https://publications.waset.org/abstracts/search?q=J.%20Sedlak"> J. Sedlak</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Machovsky"> M. Machovsky</a>, <a href="https://publications.waset.org/abstracts/search?q=I.%20Kuritka"> I. Kuritka</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Zinc oxide (ZnO) nano crystals assembled porous architecture was prepared by thermal decomposition of zinc oxalate precursor at various temperatures ranging from 400-900°C. The effect of calcining temperature on structure and morphology was examined by scanning electron microscopy (SEM), X-ray diffractometry, thermogravimetry, and BET adsorption analysis. The porous nano crystalline ZnO morphology was developed due to the release of volatile precursor products, while the overall shape of ZnO micro crystals was retained as a legacy of the precursor. The average crystallite size increased with increasing temperature of calcination from approximately 21 nm to 79 nm, while the specific surface area decreased from 30 to 1.7 m2g-1. The photo catalytic performance of prepared ZnO powders was evaluated by degradation of methyl violet 2B, a model compound. The significantly highest photo catalytic activity was achieved with powder calcined at 500°C. This may be attributed to the sufficiently well-developed crystalline arrangement, while the specific surface area is still high enough. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ZnO" title="ZnO">ZnO</a>, <a href="https://publications.waset.org/abstracts/search?q=porous%20structure" title=" porous structure"> porous structure</a>, <a href="https://publications.waset.org/abstracts/search?q=photodegradation" title=" photodegradation"> photodegradation</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20violet" title=" methyl violet"> methyl violet</a> </p> <a href="https://publications.waset.org/abstracts/10735/the-effect-of-calcining-temperature-on-photocatalytic-activity-of-porous-zno-architecture" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/10735.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">408</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">553</span> Sorption of Crystal Violet from Aqueous Solution Using Chitosan−Charcoal Composite</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kingsley%20Izuagbe%20Ikeke">Kingsley Izuagbe Ikeke</a>, <a href="https://publications.waset.org/abstracts/search?q=Abayomi%20O.%20Adetuyi"> Abayomi O. Adetuyi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The study investigated the removal efficiency of crystal violet from aqueous solution using chitosan-charcoal composite as adsorbent. Deproteination was carried out by placing 200g of powdered snail shell in 4% w/v NaOH for 2hours. The sample was then placed in 1% HCl for 24 hours to remove CaCO3. Deacetylation was done by boiling in 50% NaOH for 2hours. 10% Oxalic acid was used to dissolve the chitosan before mixing with charcoal at 55°C to form the composite. The composite was characterized by Fourier Transform Infra-Red and Scanning Electron Microscopy measurements. The efficiency of adsorption was evaluated by varying pH of the solution, contact time, initial concentration and adsorbent dose. Maximum removal of crystal violet by composite and activated charcoal was attained at pH10 while maximum removal of crystal violet by chitosan was achieved at pH 8. The results showed that adsorption of both dyes followed the pseudo-second-order rate equation and fit the Langmuir and Freundlich isotherms. The data showed that composite was best suited for crystal violet removal and also did relatively well in the removal of alizarin red. Thermodynamic parameters such as enthalpy change (ΔHº), free energy change (ΔGº) and entropy change (ΔSº) indicate that adsorption process of Crystal Violet was endothermic, spontaneous and feasible respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=crystal%20violet" title="crystal violet">crystal violet</a>, <a href="https://publications.waset.org/abstracts/search?q=chitosan%E2%88%92charcoal%20composite" title=" chitosan−charcoal composite"> chitosan−charcoal composite</a>, <a href="https://publications.waset.org/abstracts/search?q=extraction%20process" title=" extraction process"> extraction process</a>, <a href="https://publications.waset.org/abstracts/search?q=sorption" title=" sorption"> sorption</a> </p> <a href="https://publications.waset.org/abstracts/66114/sorption-of-crystal-violet-from-aqueous-solution-using-chitosancharcoal-composite" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/66114.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">439</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">552</span> A Study on Adsorption Ability of MnO2 Nanoparticles to Remove Methyl Violet Dye from Aqueous Solution</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Zh.%20Saffari">Zh. Saffari</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Naeimi"> A. Naeimi</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20S.%20Ekrami-Kakhki"> M. S. Ekrami-Kakhki</a>, <a href="https://publications.waset.org/abstracts/search?q=Kh.%20Khandan-Barani"> Kh. Khandan-Barani</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The textile industries are becoming a major source of environmental contamination because an alarming amount of dye pollutants are generated during the dyeing processes. Organic dyes are one of the largest pollutants released into wastewater from textile and other industrial processes, which have shown severe impacts on human physiology. Nano-structure compounds have gained importance in this category due their anticipated high surface area and improved reactive sites. In recent years several novel adsorbents have been reported to possess great adsorption potential due to their enhanced adsorptive capacity. Nano-MnO2 has great potential applications in environment protection field and has gained importance in this category because it has a wide variety of structure with large surface area. The diverse structures, chemical properties of manganese oxides are taken advantage of in potential applications such as adsorbents, sensor catalysis and it is also used for wide catalytic applications, such as degradation of dyes. In this study, adsorption of Methyl Violet (MV) dye from aqueous solutions onto MnO2 nanoparticles (MNP) has been investigated. The surface characterization of these nano particles was examined by Particle size analysis, Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FTIR) spectroscopy and X-Ray Diffraction (XRD). The effects of process parameters such as initial concentration, pH, temperature and contact duration on the adsorption capacities have been evaluated, in which pH has been found to be most effective parameter among all. The data were analyzed using the Langmuir and Freundlich for explaining the equilibrium characteristics of adsorption. And kinetic models like pseudo first- order, second-order model and Elovich equation were utilized to describe the kinetic data. The experimental data were well fitted with Langmuir adsorption isotherm model and pseudo second order kinetic model. The thermodynamic parameters, such as Free energy of adsorption (ΔG°), enthalpy change (ΔH°) and entropy change (ΔS°) were also determined and evaluated. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=MnO2%20nanoparticles" title="MnO2 nanoparticles">MnO2 nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20violet" title=" methyl violet"> methyl violet</a>, <a href="https://publications.waset.org/abstracts/search?q=isotherm%20models" title=" isotherm models"> isotherm models</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetic%20models" title=" kinetic models"> kinetic models</a>, <a href="https://publications.waset.org/abstracts/search?q=surface%20chemistry" title=" surface chemistry"> surface chemistry</a> </p> <a href="https://publications.waset.org/abstracts/35661/a-study-on-adsorption-ability-of-mno2-nanoparticles-to-remove-methyl-violet-dye-from-aqueous-solution" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/35661.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">258</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">551</span> Low-Temperature Luminescence Spectroscopy of Violet Sr-Al-O:Eu2+ Phosphor Particles </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Keiji%20Komatsu">Keiji Komatsu</a>, <a href="https://publications.waset.org/abstracts/search?q=Hayato%20Maruyama"> Hayato Maruyama</a>, <a href="https://publications.waset.org/abstracts/search?q=Ariyuki%20Kato"> Ariyuki Kato</a>, <a href="https://publications.waset.org/abstracts/search?q=Atsushi%20Nakamura"> Atsushi Nakamura</a>, <a href="https://publications.waset.org/abstracts/search?q=Shigeo%20Ohshio"> Shigeo Ohshio</a>, <a href="https://publications.waset.org/abstracts/search?q=Hiroki%20Akasaka"> Hiroki Akasaka</a>, <a href="https://publications.waset.org/abstracts/search?q=Hidetoshi%20Saitoh"> Hidetoshi Saitoh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Violet Sr–Al–O:Eu2+ phosphor particles were synthesized from a metal–ethylenediaminetetraacetic acid (EDTA) solution of Sr, Al, Eu, and particulate alumina via spray drying and sintering in a reducing atmosphere. The crystal structures and emission properties at 85–300 K were investigated. The composition of the violet Sr–Al–O:Eu2+ phosphor particles was determined from various Sr–Al–O:Eu2+ phosphors by their emission properties’ dependence on temperature. The highly crystalline SrAl12O19:Eu2+ emission phases were confirmed by their crystallite sizes and the activation energies for the 4f5d–8S7/2 transition of the Eu2+ ion. These results showed that the material identification for the violet Sr–Al–O:Eu2+ phosphor was accomplished by the low-temperature luminescence measurements. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=low%20temperature%20luminescence%20spectroscopy" title="low temperature luminescence spectroscopy">low temperature luminescence spectroscopy</a>, <a href="https://publications.waset.org/abstracts/search?q=material%20identification" title=" material identification"> material identification</a>, <a href="https://publications.waset.org/abstracts/search?q=strontium%20aluminates%20phosphor" title=" strontium aluminates phosphor"> strontium aluminates phosphor</a>, <a href="https://publications.waset.org/abstracts/search?q=emission%20properties" title=" emission properties "> emission properties </a> </p> <a href="https://publications.waset.org/abstracts/10329/low-temperature-luminescence-spectroscopy-of-violet-sr-al-oeu2-phosphor-particles" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/10329.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">448</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">550</span> Hybrid Method Development for the Removal of Crystal Violet Dye from Aqueous Medium</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=D.%20Nareshyadav">D. Nareshyadav</a>, <a href="https://publications.waset.org/abstracts/search?q=K.%20Anand%20Kishore"> K. Anand Kishore</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Bhagawan"> D. Bhagawan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Water scarcity is the much-identified issue all over the world. The available sources of water need to be reused to sustainable future. The present work explores the treatment of dye wastewater using combinative photocatalysis and ceramic nanofiltration membrane. Commercial ceramic membrane and TiO₂ catalyst were used in this study to investigate the removal of crystal violet dye from the aqueous solution. The effect of operating parameters such as inlet pressure, initial concentration of crystal violet dye, catalyst (TiO₂) loading, initial pH was investigated in the individual system as well as the combined system. In this study, 95 % of dye water was decolorized and 89 % of total organic carbon (TOC) was removed by the hybrid system for 500 ppm of dye and 0.75 g/l of TiO₂ concentrations at pH 9. The operation of the integrated photocatalytic reactor and ceramic membrane ﬁltration has shown the maximum removal of crystal violet dye compared to individual systems. Hence this proposed method may be effective for the removal of Crystal violet dye from effluents. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=advanced%20oxidation%20process" title="advanced oxidation process">advanced oxidation process</a>, <a href="https://publications.waset.org/abstracts/search?q=ceramic%20nanoporous%20membrane" title=" ceramic nanoporous membrane"> ceramic nanoporous membrane</a>, <a href="https://publications.waset.org/abstracts/search?q=dye%20degradation%2Fremoval" title=" dye degradation/removal"> dye degradation/removal</a>, <a href="https://publications.waset.org/abstracts/search?q=hybrid%20system" title=" hybrid system"> hybrid system</a>, <a href="https://publications.waset.org/abstracts/search?q=photocatalysis" title=" photocatalysis"> photocatalysis</a> </p> <a href="https://publications.waset.org/abstracts/97034/hybrid-method-development-for-the-removal-of-crystal-violet-dye-from-aqueous-medium" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/97034.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">177</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">549</span> The Catalytic Activity of CU2O Microparticles</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kanda%20Wongwailikhit">Kanda Wongwailikhit</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Copper (I) oxide microparticles with the morphology of cubic and hollow sphere were synthesized with the assistance of a surfactant as the shape controller. Both particles were then subjected to a study of the catalytic activity and the results of shape effects of catalysts on rate of catalytic reaction was observed. The decolorizing reaction of crystal violet and sodium hydroxide was chosen and the decrease of reactant with respect to time was measured using a spectrophotometer. The result revealed that morphology of the crystal had no effect on the catalytic activity for the crystal violet reaction but contributed to total surface area predominantly. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=copper%20%28I%29%20oxide" title="copper (I) oxide">copper (I) oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=catalytic%20activity" title=" catalytic activity"> catalytic activity</a>, <a href="https://publications.waset.org/abstracts/search?q=crystal%20violet" title=" crystal violet"> crystal violet</a> </p> <a href="https://publications.waset.org/abstracts/23861/the-catalytic-activity-of-cu2o-microparticles" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/23861.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">503</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">548</span> Investigation the Photocatalytic Properties of Fe3O4-TiO2 Nanocomposites Prepared by Sonochemical Method</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Zh.%20Saffari">Zh. Saffari</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Naeimi"> A. Naeimi</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20S.%20Ekrami-Kakhki"> M. S. Ekrami-Kakhki</a>, <a href="https://publications.waset.org/abstracts/search?q=F.%20Hamidi"> F. Hamidi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Fe3O4 is one of the important magnetic oxides with spinel structure; it has exhibited unique electric and magnetic properties based on the electron transfer between Fe2+ and Fe3+ in the octahedral sites. Fe3O4 has received considerable attention in various areas such as cancer therapy, drug targeting, enzyme immobilization catalysis, magnetic cell separation, magnetic refrigeration systems and super-paramagnetic materials Fe3O4–TiO2 nanostructures were synthesized by simple, effective and new co-precipitation method assisted by ultrasonic reaction at room temperatures with organic surfactant. The effect of various parameters such as temperature, time, and power on the size and morphology of the product was investigated. Alternating gradient force magnetometer shows that Fe3O4 nanoparticles exhibit super-paramagnetic behaviour at room temperature. For preparation of nanocomposite, 1 g of TiO2 nanostructures were dispersed in 100 mL of ethanol. 0.25 g of Fe(NO3)2 and 2 mL of octanoic acid was added to the solution as a surfactant. Then, NaOH solution (1.5 M) was slowly added into the solution until the pH of the mixture was 7–8. After complete precipitation, the solution placed under the ultrasonic irradiation for 30 min. The product was centrifuged, washed with distilled water and dried in an oven at 100 °C for 3 h. The resulting red powder was calcinated at 800 °C for 3 h to remove any organic residue. The photocatalytic behaviour of Fe3O4–TiO2 nanoparticles was evaluated using the degradation of a Methyl Violet (MV) aqueous solution under ultraviolet light irradiation. As time increased, more and more MV was adsorbed on the nanoparticles catalyst, until the absorption peak vanish. The MV concentration decreased rapidly with increasing UV-irradiation time <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=magnetic" title="magnetic">magnetic</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20violet" title=" methyl violet"> methyl violet</a>, <a href="https://publications.waset.org/abstracts/search?q=nanocomposite" title=" nanocomposite"> nanocomposite</a>, <a href="https://publications.waset.org/abstracts/search?q=photocatalytic" title=" photocatalytic"> photocatalytic</a> </p> <a href="https://publications.waset.org/abstracts/34337/investigation-the-photocatalytic-properties-of-fe3o4-tio2-nanocomposites-prepared-by-sonochemical-method" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/34337.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">255</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">547</span> Methyl Red Dye Adsorption On PMMA/GO and PMMA/GO-Fe3O4 Nanocomposites: Equilibrium Isotherm Studies</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mostafa%20Rajabi">Mostafa Rajabi</a>, <a href="https://publications.waset.org/abstracts/search?q=Kazem%20Mahanpoor"> Kazem Mahanpoor</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Performances of the methyl red (MR) dye adsorption on poly(methyl methacrylate)/graphene oxide (PMMA/GO) and poly(methyl methacrylate)/graphene oxide-Fe3O4 (PMMA/GO-Fe3O4) nanocomposites as adsorbents were investigated. Our results showed that for adsorption of MR dye on PMMA/GO-Fe3O4 and PMMA/GO nanocomposites, 80 minutes, 298 K, and pH 2 were the best contact time, temperature and pH value for process, respectively, because the optimum adsorption of the MR dye with both nanocomposite adsorbents were observed in these values of the parameters. The equilibrium study results showed that PMMA/GO-Fe3O4 and PMMA/GO were suitable adsorbents for MR dye removing and were best in agreement with the Langmuir isotherm model. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=adsorption" title="adsorption">adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=isotherm" title=" isotherm"> isotherm</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20methacrylate" title=" methyl methacrylate"> methyl methacrylate</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20red" title=" methyl red"> methyl red</a>, <a href="https://publications.waset.org/abstracts/search?q=nanocomposite" title=" nanocomposite"> nanocomposite</a>, <a href="https://publications.waset.org/abstracts/search?q=nano%20magnetic%20Fe3O4" title=" nano magnetic Fe3O4"> nano magnetic Fe3O4</a> </p> <a href="https://publications.waset.org/abstracts/140772/methyl-red-dye-adsorption-on-pmmago-and-pmmago-fe3o4-nanocomposites-equilibrium-isotherm-studies" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/140772.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">187</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">546</span> Optimization of Temperature for Crystal Violet Dye Adsorption Using Castor Leaf Powder by Response Surface Methodology</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Vipan%20Kumar%20Sohpal">Vipan Kumar Sohpal</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Temperature effect on the adsorption of crystal violet dye (CVD) was investigated using a castor leaf powder (CLP) that was prepared from the mature leaves of castor trees, through chemical reaction. The optimum values of pH (8), adsorbent dose (10g/L), initial dye concentration (10g/L), time (2hrs), and stirrer speed (120 rpm) were fixed to investigate the influence of temperature on adsorption capacity, percentage of removal of dye and free energy. A central composite design (CCD) was successfully employed for experimental design and analysis of the results. The combined effect of temperature, absorbance, and concentration on the dye adsorption was studied and optimized using response surface methodology. The optimum values of adsorption capacity, percentage of removal of dye and free energy were found to be 0.965(mg/g), 93.38 %, -8202.7(J/mol) at temperature 55.97 °C having desirability > 90% for removal of crystal violet dye respectively. The experimental values were in good agreement with predicted values. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=crystal%20violet%20dye" title="crystal violet dye">crystal violet dye</a>, <a href="https://publications.waset.org/abstracts/search?q=CVD" title=" CVD"> CVD</a>, <a href="https://publications.waset.org/abstracts/search?q=castor%20leaf%20powder" title=" castor leaf powder"> castor leaf powder</a>, <a href="https://publications.waset.org/abstracts/search?q=CLP" title=" CLP"> CLP</a>, <a href="https://publications.waset.org/abstracts/search?q=response%20surface%20methodology" title=" response surface methodology"> response surface methodology</a>, <a href="https://publications.waset.org/abstracts/search?q=temperature" title=" temperature"> temperature</a>, <a href="https://publications.waset.org/abstracts/search?q=optimization" title=" optimization"> optimization</a> </p> <a href="https://publications.waset.org/abstracts/108698/optimization-of-temperature-for-crystal-violet-dye-adsorption-using-castor-leaf-powder-by-response-surface-methodology" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/108698.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">132</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">545</span> An Association Model to Correlate the Experimentally Determined Mixture Solubilities of Methyl 10-Undecenoate with Methyl Ricinoleate in Supercritical Carbon Dioxide</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=V.%20Mani%20Rathnam">V. Mani Rathnam</a>, <a href="https://publications.waset.org/abstracts/search?q=Giridhar%20Madras"> Giridhar Madras</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Fossil fuels are depleting rapidly as the demand for energy, and its allied chemicals are continuously increasing in the modern world. Therefore, sustainable renewable energy sources based on non-edible oils are being explored as a viable option as they do not compete with the food commodities. Oils such as castor oil are rich in fatty acids and thus can be used for the synthesis of biodiesel, bio-lubricants, and many other fine industrial chemicals. There are several processes available for the synthesis of different chemicals obtained from the castor oil. One such process is the transesterification of castor oil, which results in a mixture of fatty acid methyl esters. The main products in the above reaction are methyl ricinoleate and methyl 10-undecenoate. To separate these compounds, supercritical carbon dioxide (SCCO₂) was used as a green solvent. SCCO₂ was chosen as a solvent due to its easy availability, non-toxic, non-flammable, and low cost. In order to design any separation process, the preliminary requirement is the solubility or phase equilibrium data. Therefore, the solubility of a mixture of methyl ricinoleate with methyl 10-undecenoate in SCCO₂ was determined in the present study. The temperature and pressure range selected for the investigation were T = 313 K to 333 K and P = 10 MPa to 18 MPa. It was observed that the solubility (mol·mol⁻¹) of methyl 10-undecenoate varied from 2.44 x 10⁻³ to 8.42 x 10⁻³ whereas it varied from 0.203 x 10⁻³ to 6.28 x 10⁻³ for methyl ricinoleate within the chosen operating conditions. These solubilities followed a retrograde behavior (characterized by the decrease in the solubility values with the increase in temperature) throughout the range of investigated operating conditions. An association theory model, coupled with regular solution theory for activity coefficients, was developed in the present study. The deviation from the experimental data using this model can be quantified using the average absolute relative deviation (AARD). The AARD% for the present compounds is 4.69 and 8.08 for methyl 10-undecenoate and methyl ricinoleate, respectively in a mixture of methyl ricinoleate and methyl 10-undecenoate. The maximum solubility enhancement of 32% was observed for the methyl ricinoleate in a mixture of methyl ricinoleate and methyl 10-undecenoate. The highest selectivity of SCCO₂ was observed to be 12 for methyl 10-undecenoate in a mixture of methyl ricinoleate and methyl 10-undecenoate. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=association%20theory" title="association theory">association theory</a>, <a href="https://publications.waset.org/abstracts/search?q=liquid%20mixtures" title=" liquid mixtures"> liquid mixtures</a>, <a href="https://publications.waset.org/abstracts/search?q=solubilities" title=" solubilities"> solubilities</a>, <a href="https://publications.waset.org/abstracts/search?q=supercritical%20carbon%20dioxide" title=" supercritical carbon dioxide"> supercritical carbon dioxide</a> </p> <a href="https://publications.waset.org/abstracts/107534/an-association-model-to-correlate-the-experimentally-determined-mixture-solubilities-of-methyl-10-undecenoate-with-methyl-ricinoleate-in-supercritical-carbon-dioxide" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/107534.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">134</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">544</span> Phytobeds with Fimbristylis dichotoma and Ammannia baccifera for Treatment of Real Textile Effluent: An in situ Treatment, Anatomical Studies and Toxicity Evaluation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Suhas%20Kadam">Suhas Kadam</a>, <a href="https://publications.waset.org/abstracts/search?q=Vishal%20Chandanshive"> Vishal Chandanshive</a>, <a href="https://publications.waset.org/abstracts/search?q=Niraj%20Rane"> Niraj Rane</a>, <a href="https://publications.waset.org/abstracts/search?q=Sanjay%20Govindwar"> Sanjay Govindwar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Fimbristylis dichotoma, Ammannia baccifera, and their co-plantation consortium FA were found to degrade methyl orange, simulated dye mixture, and real textile effluent. Wild plants of Fimbristylis dichotoma and Ammannia baccifera with equal biomass showed 91 and 89% decolorization of methyl orange within 60 h at a concentration of 50 ppm, while 95% dye removal was achieved by consortium FA within 48 h. Floating phyto-beds with co-plantation (Fimbristylis dichotoma and Ammannia baccifera) for the treatment of real textile effluent in a constructed wetland was observed to be more efficient and achieved 79, 72, 77, 66 and 56% reductions in ADMI color value, chemical oxygen demand, biological oxygen demand, total dissolve solid and total suspended solid of textile effluent, respectively. High performance thin layer chromatography, gas chromatography-mass spectroscopy, Fourier transform infrared spectroscopy, Ultra violet-Visible spectroscopy and enzymatic assays confirmed the phytotransformation of parent dye in the new metabolites. T-RFLP analysis of rhizospheric bacteria of Fimbristylis dichotoma, Ammannia baccifera, and consortium FA revealed the presence of 88, 98 and 223 genera which could have been involved in dye removal. Toxicity evaluation of products formed after phytotransformation of methyl orange by consortium FA on bivalves Lamellidens marginalis revealed less damage in the gills architecture when analyzed histologically. Toxicity measurement by Random Amplification of Polymorphic DNA (RAPD) technique revealed normal banding pattern in treated methyl orange sample suggesting less toxic nature of phytotransformed dye products. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=constructed%20wetland" title="constructed wetland">constructed wetland</a>, <a href="https://publications.waset.org/abstracts/search?q=phyto-bed" title=" phyto-bed"> phyto-bed</a>, <a href="https://publications.waset.org/abstracts/search?q=textile%20effluent" title=" textile effluent"> textile effluent</a>, <a href="https://publications.waset.org/abstracts/search?q=phytoremediation" title=" phytoremediation"> phytoremediation</a> </p> <a href="https://publications.waset.org/abstracts/78943/phytobeds-with-fimbristylis-dichotoma-and-ammannia-baccifera-for-treatment-of-real-textile-effluent-an-in-situ-treatment-anatomical-studies-and-toxicity-evaluation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/78943.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">483</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">543</span> Optimization of the Culture Medium, Incubation Period, pH and Temperatures for Maximal Dye Bioremoval Using A. Fumigates</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Wafaa%20M.%20Abd%20El-Rahim">Wafaa M. Abd El-Rahim</a>, <a href="https://publications.waset.org/abstracts/search?q=Magda%20A.%20El-Meleigy"> Magda A. El-Meleigy</a>, <a href="https://publications.waset.org/abstracts/search?q=Eman%20Refaat"> Eman Refaat</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This study dealing with optimization the conditions affecting the formation of extracellular lignin- degrading enzymes to achieve maximal decolorization activity of Direct Violet dye by one fungal strain. In this study Aspergillus fumigates fungal strain used for production extracellular ligninolytic enzymes for removing Direct Violet dye under different conditions: culture medium, incubation period, pH and temperatures. The results indicted that the removal efficiency of A. fumigatus was enhanced by addition glucose and peptone to the culture medium. The addition of peptone and glucose was found to increase the decolorization activity of the fungal isolate from 51.38% to 93.74% after 4 days of incubation. The highest production of extracellular lignin degrading enzymes also recorded in Direct Violet dye medium supplemented with peptone and glucose. It was also found the decolorization activity of A. fumigatus was decreased gradually by increasing the incubation period up to 4 days. Also it was found that the fungal strain can grow and produce extracellular ligninolytic enzymes which accompanied by efficient removal of Direct Violet dye in a wide pH range of 4-8. The results also found that the maximal biosynthesis of ligninolytic enzymes which accompanied with maximal removal of Direct Violet dye was obtained at a temperature of 28C. This indicates that the different conditions of culture medium, incubation period, pH and temperatures are effective on dye decolorization on the fungal biomass and played a role in Direct Violet dye removal along with enzymatic activity of A. fumigatus. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=A.%20fumigates" title="A. fumigates">A. fumigates</a>, <a href="https://publications.waset.org/abstracts/search?q=extracellular%20lignin-%20degrading%20enzymes" title=" extracellular lignin- degrading enzymes"> extracellular lignin- degrading enzymes</a>, <a href="https://publications.waset.org/abstracts/search?q=textile%20dye" title=" textile dye"> textile dye</a>, <a href="https://publications.waset.org/abstracts/search?q=dye%20removing" title=" dye removing"> dye removing</a> </p> <a href="https://publications.waset.org/abstracts/17335/optimization-of-the-culture-medium-incubation-period-ph-and-temperatures-for-maximal-dye-bioremoval-using-a-fumigates" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/17335.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">278</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">542</span> Effect of Asymmetric Amphiphilic Dicationic Ionic Liquids as Oil Spill Dispersants in Red Sea</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Raghda%20El-Nagara">Raghda El-Nagara</a>, <a href="https://publications.waset.org/abstracts/search?q=Maher%20I.%20Nessim"> Maher I. Nessim</a>, <a href="https://publications.waset.org/abstracts/search?q=Carmen%20E.%20Elshafee"> Carmen E. Elshafee</a>, <a href="https://publications.waset.org/abstracts/search?q=Renee%20I.%20Abdallah"> Renee I. Abdallah</a>, <a href="https://publications.waset.org/abstracts/search?q=Yasser%20M.%20Moustafa"> Yasser M. Moustafa</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Three asymmetric dicationic ionic liquids (ADILs), 1-(2-(1-dodecyl-2-methyl-1H-imidazolium-3-yl)ethyl)-3-methyl pyridinium bromide (IL₁), 1-(6-(1-dodecyl-2-methyl-1H-imidazolium-3-yl)hexyl)-3-methyl pyridinium bromide (IL₂) and 1-(10-(1-dodecyl-2-methyl-1H-imidazolium-3-yl)decyl)-3-methyl pyridinium bromide (IL₃) were synthesized with yield of 83.54, 84.12 & 83.05% respectively. They were elucidated via conventional tools of analysis (elemental analysis, FT-IR, and 1H-NMR). The thermogravimetric analysis confirmed that the three ADILs possessed high thermal stability (up to 500ᵒC). Their critical micelle concentration (CMC) was investigated and exhibited values of 5.5-1*10⁻³ Mol./L. They were evaluated as oil spill dispersants were at different temperatures (10, 30 & 50ᵒC) with different concentrations (750, 1500, 2000, 3000 ppm). Data reveals that the efficiency is ranked as follows: IL₂ > IL₁ > IL₃, which showed high dispersion efficiency reached to 63% with the concentration of 1500 ppm. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquids" title="ionic liquids">ionic liquids</a>, <a href="https://publications.waset.org/abstracts/search?q=amphiphilic" title=" amphiphilic"> amphiphilic</a>, <a href="https://publications.waset.org/abstracts/search?q=oil%20spill%20dispersants" title=" oil spill dispersants"> oil spill dispersants</a>, <a href="https://publications.waset.org/abstracts/search?q=dicationic" title=" dicationic"> dicationic</a>, <a href="https://publications.waset.org/abstracts/search?q=efficiency%20test" title=" efficiency test"> efficiency test</a> </p> <a href="https://publications.waset.org/abstracts/135621/effect-of-asymmetric-amphiphilic-dicationic-ionic-liquids-as-oil-spill-dispersants-in-red-sea" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/135621.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">151</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">541</span> Solar Photocatalysis of Methyl Orange Using Multi-Ion Doped TiO2 Catalysts</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Victor%20R.%20Thulari">Victor R. Thulari</a>, <a href="https://publications.waset.org/abstracts/search?q=John%20Akach"> John Akach</a>, <a href="https://publications.waset.org/abstracts/search?q=Haleden%20Chiririwa"> Haleden Chiririwa</a>, <a href="https://publications.waset.org/abstracts/search?q=Aoyi%20Ochieng"> Aoyi Ochieng</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Solar-light activated titanium dioxide photocatalysts were prepared by hydrolysis of titanium (IV) isopropoxide with thiourea, followed by calcinations at 450 °C. The experiments demonstrated that methyl orange in aqueous solutions were successfully degraded under solar light using doped TiO<sub>2</sub>. The photocatalytic oxidation of a mono azo methyl-orange dye has been investigated in multi ion doped TiO<sub>2</sub> and solar light. Solutions were irradiated by solar-light until high removal was achieved. It was found that there was no degradation of methyl orange in the dark and in the absence of TiO<sub>2</sub>. Varieties of laboratory prepared TiO<sub>2</sub> catalysts both un-doped and doped using titanium (IV) isopropoxide and thiourea as a dopant were tested in order to compare their photoreactivity. As a result, it was found that the efficiency of the process strongly depends on the working conditions. The highest degradation rate of methyl orange was obtained at optimum dosage using commercially produced TiO<sub>2</sub>. Our work focused on laboratory synthesized catalyst and the maximum methyl orange removal was achieved at 81% with catalyst loading of 0.04 g/L, initial pH of 3 and methyl orange concentration of 0.005 g/L using multi-ion doped catalyst. The kinetics of photocatalytic methyl orange dye stuff degradation was found to follow a pseudo-first-order rate law. The presence of the multi-ion dopant (thiourea) enhanced the photoefficiency of the titanium dioxide catalyst. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=degradation" title="degradation">degradation</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetics" title=" kinetics"> kinetics</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20orange" title=" methyl orange"> methyl orange</a>, <a href="https://publications.waset.org/abstracts/search?q=photocatalysis" title=" photocatalysis"> photocatalysis</a> </p> <a href="https://publications.waset.org/abstracts/59808/solar-photocatalysis-of-methyl-orange-using-multi-ion-doped-tio2-catalysts" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/59808.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">336</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">540</span> Glycerol-Free Biodiesel Synthesis from Crude Mahua (Madhuca indica) Oil under Supercritical Methyl Acetate Using CO2 as a Co-Solvent</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Antaram%20Sarve">Antaram Sarve</a>, <a href="https://publications.waset.org/abstracts/search?q=Mahesh%20Varma"> Mahesh Varma</a>, <a href="https://publications.waset.org/abstracts/search?q=Shriram%20Sonawane"> Shriram Sonawane</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Conventional route of producing biodiesel with alcohol produces glycerol as side product which leads to oversupply and devaluation in the world market. Supercritical methyl acetate (SCMA) has been proven to convert triglycerides into fatty acid methyl esters (FAMEs) and triacetin, which is a valuable biodiesel additive as side product rather than glycerol. However, due to the low reactivity of supercritical methyl acetate on triglycerides, high reaction conditions are required to obtained maximum yields. The present study describes the renewable approach for the production of biodiesel from low-cost, high acid value mahua oil under supercritical methyl acetate condition using carbon dioxide (CO2) as a co-solvent. CO2 was employed to decrease high reaction conditions required for supercritical methyl acetate transesterification. The inﬂuence of process parameters such as temperature, oil to methyl acetate molar ratio, reaction time, and the CO2 pressure was evaluated. The properties of biodiesel produced were found to be superior compared to conventional biodiesel method. Furthermore, SCMA has a high tolerance towards free fatty acids (FFAs) which is crucial to allow the utilization of inexpensive waste oils as a biodiesel feedstock. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=supercritical%20methyl%20acetate" title="supercritical methyl acetate">supercritical methyl acetate</a>, <a href="https://publications.waset.org/abstracts/search?q=CO2" title=" CO2"> CO2</a>, <a href="https://publications.waset.org/abstracts/search?q=biodiesel" title=" biodiesel"> biodiesel</a>, <a href="https://publications.waset.org/abstracts/search?q=fuel%20properties" title=" fuel properties"> fuel properties</a> </p> <a href="https://publications.waset.org/abstracts/34550/glycerol-free-biodiesel-synthesis-from-crude-mahua-madhuca-indica-oil-under-supercritical-methyl-acetate-using-co2-as-a-co-solvent" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/34550.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">563</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">539</span> Study of Intermolecular Interactions in Binary Mixtures of 1-Butyl-3-Methyl Imidazolium Bis (Trifluoro Methyl Sulfonyl) Imide and 1-Ethyl-3-Methyl Imidazolium Ethyl Sulphate at Different Temperature from 293.18 to 342.15 K</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=V.%20Lokesh">V. Lokesh</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Manjunathan"> M. Manjunathan</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Sairam"> S. Sairam</a>, <a href="https://publications.waset.org/abstracts/search?q=K.%20Saithsh%20Kumar"> K. Saithsh Kumar</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Anantharaj"> R. Anantharaj</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The densities of pure and its binary mixtures of 1-Butyl-3-methyl imidazolium bis (trifluoro methyl sulfonyl) imide and 1–Ethyl-3-methyl imidazolium ethyl sulphate at different temperature, over the entire composition range were measured at 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, 33.15, 338.15, 343.15 K. In this study, the liquid-liquid extraction procedure was used. From this experimental data, the excess molar volumes, apparent molar volume, partial molar volumes and the excess partial molar volumes have been calculated for over the whole composition range. Hence, the effect of temperature and composition on all derived thermodynamic properties of this binary mixture will be discussed in terms of intermolecular interactions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquid" title="ionic liquid">ionic liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=interaction%20energy" title=" interaction energy"> interaction energy</a>, <a href="https://publications.waset.org/abstracts/search?q=effect%20of%20temperature" title=" effect of temperature"> effect of temperature</a>, <a href="https://publications.waset.org/abstracts/search?q=effect%20of%20composition" title=" effect of composition"> effect of composition</a> </p> <a href="https://publications.waset.org/abstracts/81348/study-of-intermolecular-interactions-in-binary-mixtures-of-1-butyl-3-methyl-imidazolium-bis-trifluoro-methyl-sulfonyl-imide-and-1-ethyl-3-methyl-imidazolium-ethyl-sulphate-at-different-temperature-from-29318-to-34215-k" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/81348.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">172</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">538</span> Effect of Acid-Basic Treatments of Lingocellulosic Material Forest Wastes Wild Carob on Ethyl Violet Dye Adsorption</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Abdallah%20Bouguettoucha">Abdallah Bouguettoucha</a>, <a href="https://publications.waset.org/abstracts/search?q=Derradji%20Chebli"> Derradji Chebli</a>, <a href="https://publications.waset.org/abstracts/search?q=Tariq%20Yahyaoui"> Tariq Yahyaoui</a>, <a href="https://publications.waset.org/abstracts/search?q=Hichem%20Attout"> Hichem Attout</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The effect of acid -basic treatment of lingocellulosic material (forest wastes wild carob) on Ethyl violet adsorption was investigated. It was found that surface chemistry plays an important role in Ethyl violet (EV) adsorption. HCl treatment produces more active acidic surface groups such as carboxylic and lactone, resulting in an increase in the adsorption of EV dye. The adsorption efficiency was higher for treated of lingocellulosic material with HCl than for treated with KOH. Maximum biosorption capacity was 170 and 130 mg/g, for treated of lingocellulosic material with HCl than for treated with KOH at pH 6 respectively. It was also found that the time to reach equilibrium takes less than 25 min for both treated materials. The adsorption of basic dye (i.e., ethyl violet or basic violet 4) was carried out by varying some process parameters, such as initial concentration, pH and temperature. The adsorption process can be well described by means of a pseudo-second-order reaction model showing that boundary layer resistance was not the rate-limiting step, as confirmed by intraparticle diffusion since the linear plot of Qt versus t^0.5 did not pass through the origin. In addition, experimental data were accurately expressed by the Sips equation if compared with the Langmuir and Freundlich isotherms. The values of ΔG° and ΔH° confirmed that the adsorption of EV on acid-basic treated forest wast wild carob was spontaneous and endothermic in nature. The positive values of ΔS° suggested an irregular increase of the randomness at the treated lingocellulosic material -solution interface during the adsorption process. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=adsorption" title="adsorption">adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=isotherm%20models" title=" isotherm models"> isotherm models</a>, <a href="https://publications.waset.org/abstracts/search?q=thermodynamic%20parameters" title=" thermodynamic parameters"> thermodynamic parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=wild%20carob" title=" wild carob"> wild carob</a> </p> <a href="https://publications.waset.org/abstracts/43718/effect-of-acid-basic-treatments-of-lingocellulosic-material-forest-wastes-wild-carob-on-ethyl-violet-dye-adsorption" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/43718.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">277</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">537</span> GAC Adsorption Modelling of Metsulfuron Methyl from Water</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nathaporn%20Areerachakul">Nathaporn Areerachakul</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, the adsorption capacity of GAC with metsulfuron methyl was evaluated by using adsorption equilibrium and a fixed bed. Mathematical modelling was also used to simulate the GAC adsorption behavior. Adsorption equilibrium experiment of GAC was conducted using a constant concentration of metsulfuron methyl of 10 mg/L. The purpose of this study was to find the single component equilibrium concentration of herbicide. The adsorption behavior was simulated using the Langmuir, Freundlich, and Sips isotherm. The Sips isotherm fitted the experimental data reasonably well with an error of 6.6 % compared with 15.72 % and 7.07% for the Langmuir isotherm and Freudrich isotherm. Modelling using GAC adsorption theory could not replicate the experimental results in fixed bed column of 10 and 15 cm bed depths after a period more than 10 days of operation. This phenomenon is attributed to the formation of micro-organism (BAC) on the surface of GAC in addition to GAC alone. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=isotherm" title="isotherm">isotherm</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption%20equilibrium" title=" adsorption equilibrium"> adsorption equilibrium</a>, <a href="https://publications.waset.org/abstracts/search?q=GAC" title=" GAC"> GAC</a>, <a href="https://publications.waset.org/abstracts/search?q=metsulfuron%20methyl" title=" metsulfuron methyl"> metsulfuron methyl</a> </p> <a href="https://publications.waset.org/abstracts/8935/gac-adsorption-modelling-of-metsulfuron-methyl-from-water" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/8935.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">307</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">536</span> Isothermal Crystallization Kinetics of Lauric Acid Methyl Ester from DSC Measurements</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Charine%20Faith%20H.%20Lagrimas">Charine Faith H. Lagrimas</a>, <a href="https://publications.waset.org/abstracts/search?q=Rommel%20N.%20Galvan"> Rommel N. Galvan</a>, <a href="https://publications.waset.org/abstracts/search?q=Rizalinda%20L.%20de%20Leon"> Rizalinda L. de Leon</a> </p> <p class="card-text"><strong>Abstract:</strong></p> An ongoing study, methyl laurate to be used as a refrigerant in an HVAC system, requires the crystallization kinetics of the said substance. Step-wise and normal forms of Avrami model parameters were used to describe the isothermal crystallization kinetics of methyl laurate at different temperatures from Differential Scanning Calorimetry (DSC) measurements. At 3 °C, parameters showed that methyl laurate exhibits a secondary crystallization. The primary crystallization occurred with instantaneous nuclei and spherulitic growth; followed by a secondary instantaneous nucleation with a lower growth of dimensionality, rod-like. At 4 °C to 6 °C, the exotherms from DSC implied that the system was under the isokinetic range. The kinetics behavior is the same which is instantaneous nucleation with one-dimensional growth. The differences for the isokinetic range temperatures are the activation energies (directly proportional to T) and nucleation rates (inversely proportional to T). From the images obtained during the crystallization of methyl laurate using an optical microscope, it is confirmed that the nucleation and crystal growth modes obtained from the optical microscope are consistent with the parameters from Avrami model. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Avrami%20model" title="Avrami model">Avrami model</a>, <a href="https://publications.waset.org/abstracts/search?q=isothermal%20crystallization" title=" isothermal crystallization"> isothermal crystallization</a>, <a href="https://publications.waset.org/abstracts/search?q=lipids%20kinetics" title=" lipids kinetics"> lipids kinetics</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20laurate" title=" methyl laurate"> methyl laurate</a> </p> <a href="https://publications.waset.org/abstracts/27068/isothermal-crystallization-kinetics-of-lauric-acid-methyl-ester-from-dsc-measurements" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/27068.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">342</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">535</span> Synthesis and Characterization of New Polyesters Based on Diarylidene-1-Methyl-4-Piperidone</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Tareg%20M.%20Elsunaki">Tareg M. Elsunaki</a>, <a href="https://publications.waset.org/abstracts/search?q=Suleiman%20A.%20Arafa"> Suleiman A. Arafa</a>, <a href="https://publications.waset.org/abstracts/search?q=Mohamed%20A.%20Abd-Alla"> Mohamed A. Abd-Alla</a> </p> <p class="card-text"><strong>Abstract:</strong></p> New interesting thermal stable polyesters containing 1-methyl-4-piperidone moiety in the main chain have been synthesized. These polyesters were synthesized by interfacial polycondensation technique of 3,5-bis(4-hydroxybenzylidene)-1-methyl-4-piperidone (I) and 3,5-bis(4-hydroxy-3-methoxy benzyli-dene)-1-methyl-4-piperidone (II) with terphthaloyl, isophthaloyl, 4,4'-diphenic, adipoyl and sebacoyl dichlorides. The yield and the values of the reduced viscosity of the produced polyesters were found to be affected by the type of an organic phase. In order to characterize these polymers, the necessary model compounds (A), (B) were prepared from (I), (II) respectively and benzoyl chloride. The structure of monomers (I), (II), model compounds and resulting polyesters were confirmed by IR, elemental analysis and 1HNMR spectroscopy. The various characteristic of the resulting polymers including solubility, thermal properties, viscosity and X-ray analysis were also studied. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=synthesis" title="synthesis">synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=characterization" title=" characterization"> characterization</a>, <a href="https://publications.waset.org/abstracts/search?q=new%20polyesters" title=" new polyesters"> new polyesters</a>, <a href="https://publications.waset.org/abstracts/search?q=chemistry" title=" chemistry"> chemistry</a> </p> <a href="https://publications.waset.org/abstracts/5559/synthesis-and-characterization-of-new-polyesters-based-on-diarylidene-1-methyl-4-piperidone" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/5559.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">458</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">534</span> Synthesis and Antimicrobial Profile of Newer Schiff Bases and Thiazolidinone Derivatives</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=N.%20K.%20Fuloria">N. K. Fuloria</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Fuloria"> S. Fuloria</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Gupta"> R. Gupta</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Esterification of p-bromo-m-cresol offered 2-(4-bromo-3-methyl phenoxy)acetate (1), which was hydrazinated to yield 2-(4-bromo-3-methyl phenoxy)aceto hydrazide (2). Compound (2) was reacted with different aromatic aldehydes to yield N-(substituted benzylidiene)-2-(4-bromo-3-methyl phenoxy)acetamide(3a-c). Cyclization of compound (3a-c) with thioglycolic acid yielded 2-(4-bromo-3-methylphenoxy)-N-(4-oxo-2-arylthiazolidin-3-yl) acetamide (4a-c). The newly synthesized compounds were characterized on the basis of spectral studies and evaluated for antibacterial and antifungal activities. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=imines" title="imines">imines</a>, <a href="https://publications.waset.org/abstracts/search?q=thiazolidinone" title=" thiazolidinone"> thiazolidinone</a>, <a href="https://publications.waset.org/abstracts/search?q=schiff%20base" title=" schiff base"> schiff base</a>, <a href="https://publications.waset.org/abstracts/search?q=antimicrobial" title=" antimicrobial"> antimicrobial</a> </p> <a href="https://publications.waset.org/abstracts/17411/synthesis-and-antimicrobial-profile-of-newer-schiff-bases-and-thiazolidinone-derivatives" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/17411.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">445</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">533</span> Improvement of Thermal Stability in Ethylene Methyl Acrylate Composites for Gasket Application</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Pemika%20Ketsuwan">Pemika Ketsuwan</a>, <a href="https://publications.waset.org/abstracts/search?q=Pitt%20Supaphol"> Pitt Supaphol</a>, <a href="https://publications.waset.org/abstracts/search?q=Manit%20Nithitanakul"> Manit Nithitanakul</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A typical used of ethylene methyl acrylate (EMA) gasket is in the manufacture of optical lens, and often, they are deteriorated rapidly due to high temperature during the process. The objective of this project is to improve the thermal stability of the EMA copolymer gasket by preparing EMA with cellulose and silica composites. Hydroxy propyl methyl cellulose (HPMC) and Carboxy methyl cellulose (CMC) were used in preparing of EMA/cellulose composites and fumed silica (SiO2) was used in preparing EMA/silica composites with different amounts of filler (3, 5, 7, 10, 15 wt.%), using a twin screw extruder at 160 °C and the test specimens were prepared by the injection molding machine. The morphology and dispersion of fillers in the EMA matrix were investigated by field emission scanning electron microscopy (FESEM). The thermal stability of the composite was determined by thermal gravimetric analysis (TGA), and differential scanning calorimeter (DSC). Mechanical properties were evaluated by tensile testing. The developed composites were found to enhance thermal and mechanical properties when compared to that of the EMA copolymer alone. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ethylene%20methyl%20acrylate" title="ethylene methyl acrylate">ethylene methyl acrylate</a>, <a href="https://publications.waset.org/abstracts/search?q=HPMC" title=" HPMC"> HPMC</a>, <a href="https://publications.waset.org/abstracts/search?q=Silica" title=" Silica"> Silica</a>, <a href="https://publications.waset.org/abstracts/search?q=Thermal%20stability" title=" Thermal stability"> Thermal stability</a> </p> <a href="https://publications.waset.org/abstracts/124859/improvement-of-thermal-stability-in-ethylene-methyl-acrylate-composites-for-gasket-application" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/124859.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">122</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">532</span> The Electrical Properties of Polyester Materials as Outdoor Insulators</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=R.%20M.%20EL-Sharkawy">R. M. EL-Sharkawy</a>, <a href="https://publications.waset.org/abstracts/search?q=L.%20S.%20Nasrat"> L. S. Nasrat</a>, <a href="https://publications.waset.org/abstracts/search?q=K.%20B.%20Ewiss"> K. B. Ewiss</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This work presents a study of flashover voltage for outdoor polyester and composite insulators under dry, ultra-violet and contaminated conditions. Cylindrical of polyester composite samples (with different lengths) have been prepared after incorporated with different concentration of inorganic filler e.g. Magnesium Hydroxide [Mg(OH)2] to improve the electrical and thermal properties in addition to maximize surface flashover voltage and decrease tracking phenomena. Results showed that flashover voltage reaches to 46 kV for samples without filler and 52.6 kV for samples containing 40% of [Mg(OH)2] filler in dry condition. A comparison between different concentrations of filler under various environmental conditions (dry and contaminated conditions) showed higher flashover voltage values for samples containing filler with ratio 40% [Mg(OH)2] and length 3cm than that of samples containing filler [Mg(OH)2] with ratios 20%, 30% and lengths 0.5cm, 1cm, 2cm and 2.5cm. Flashover voltage decreases by adding [Mg(OH)2] filler for polyester samples under ultra-violet condition; as the ratio of filler increases, the value of flashover voltage decreases Also, in this study, the effect of thermal performance with respect to surface of the sample under test have been investigated in details. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=flashover%20voltage" title="flashover voltage">flashover voltage</a>, <a href="https://publications.waset.org/abstracts/search?q=filler" title=" filler"> filler</a>, <a href="https://publications.waset.org/abstracts/search?q=polymers" title=" polymers"> polymers</a>, <a href="https://publications.waset.org/abstracts/search?q=ultra-violet%20radiation" title=" ultra-violet radiation"> ultra-violet radiation</a> </p> <a href="https://publications.waset.org/abstracts/40599/the-electrical-properties-of-polyester-materials-as-outdoor-insulators" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/40599.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">315</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">531</span> Synthesis of Biolubricant Base Stock from Palm Methyl Ester</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nur%20Sulihatimarsyila%20Abd%20Wafti">Nur Sulihatimarsyila Abd Wafti</a>, <a href="https://publications.waset.org/abstracts/search?q=Harrison%20Lik%20Nang%20Lau"> Harrison Lik Nang Lau</a>, <a href="https://publications.waset.org/abstracts/search?q=Nabilah%20Kamaliah%20Mustaffa"> Nabilah Kamaliah Mustaffa</a>, <a href="https://publications.waset.org/abstracts/search?q=Nur%20Azreena%20Idris"> Nur Azreena Idris</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The use of biolubricant has gained its popularity over the last decade. Base stock produced using methyl ester and trimethylolethane (TME) can be potentially used for biolubricant production due to its biodegradability, non-toxicity and good thermal stability. The synthesis of biolubricant base stock e.g. triester (TE) via transesterification of palm methyl ester and TME in the presence of sodium methoxide as the catalyst was conducted. Factors influencing the reaction conditions were investigated including reaction time, temperature and pressure. The palm-based biolubricant base stock produced was analysed for its monoester (ME), diester (DE) and TE contents using gas chromatography as well as its lubricating properties such as viscosity, viscosity index, oxidation stability, and density. The resulting base stock containing 90 wt% TE was successfully synthesized. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biolubricant" title="biolubricant">biolubricant</a>, <a href="https://publications.waset.org/abstracts/search?q=methyl%20ester" title=" methyl ester"> methyl ester</a>, <a href="https://publications.waset.org/abstracts/search?q=triester%20transesterification" title=" triester transesterification"> triester transesterification</a>, <a href="https://publications.waset.org/abstracts/search?q=lubricating%20properties" title=" lubricating properties"> lubricating properties</a> </p> <a href="https://publications.waset.org/abstracts/52775/synthesis-of-biolubricant-base-stock-from-palm-methyl-ester" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/52775.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">445</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">530</span> Control Effect of Flowering Chrysanthemum, the Trap Plant to the Western Flower Thrips, Frankliniella occidentalis (Thysanoptera: Thripidae) in Greenhouse</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=YongSeok%20Choi">YongSeok Choi</a>, <a href="https://publications.waset.org/abstracts/search?q=HwaYoung%20Seo"> HwaYoung Seo</a>, <a href="https://publications.waset.org/abstracts/search?q=InSu%20Whang"> InSu Whang</a>, <a href="https://publications.waset.org/abstracts/search?q=GeogKee%20Park"> GeogKee Park</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Frankliniella. occidentalis is major pest in chrysanthemum in worldwide. The density of F. occidentalis increased continuously in spite of the periodical chemical control after planting in this study. F. occidentalis began to increase mid-May. The numbers of F. occidentalis collected on a tray with wet paper by heating the flowers of pink, white, and yellow Chrysanthemum standard mums were 18.4, 56.6, and 52.6 in the flowering season. Also, the numbers were 15.2, 45.8, and 41.6 in bud season, but in the case of the leaves, the numbers were 2, 8.8 and 3.4. In the Y-tube olfactometer test, the frequency of F. occidentalis’ visits to one side arm of the Y-tube olfactometer was higher in the odor cue of the white flower than of the yellow, red, and violet flowers, but the frequency was higher in the odor cue of the violet and red flowers than of the yellow without white. In the case of the four-choice olfactometer test, in the same visual cues as the odor cues of the pot mum flowers, the frequency of F. occidentalis was higher in the yellow flower than in the other flowers (white, red, and violet) in all the observation times (10, 15, and 20 minutes). <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Frankliniella%20occidentalis" title="Frankliniella occidentalis">Frankliniella occidentalis</a>, <a href="https://publications.waset.org/abstracts/search?q=Chrysanthemum" title=" Chrysanthemum"> Chrysanthemum</a>, <a href="https://publications.waset.org/abstracts/search?q=trap%20plant" title=" trap plant"> trap plant</a>, <a href="https://publications.waset.org/abstracts/search?q=control%20effect" title=" control effect"> control effect</a> </p> <a href="https://publications.waset.org/abstracts/85755/control-effect-of-flowering-chrysanthemum-the-trap-plant-to-the-western-flower-thrips-frankliniella-occidentalis-thysanoptera-thripidae-in-greenhouse" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/85755.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">188</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">529</span> Effect of Doping Ag and N on the Photo-Catalytic Activity of ZnO/CuO Nanocomposite for Degradation of Methyl Orange under UV and Visible Radiation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=O.%20P.%20Yadav">O. P. Yadav</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Nano-size Ag-N co-doped ZnO/CuO composite photo-catalyst has been synthesized by chemical method and characterized using XRD, TEM, FTIR, AAS and UV-Vis spectroscopic techniques. Photo-catalytic activity of as-synthesized nanomaterial has been studied using degradation of methyl orange as a probe under UV as well as visible radiations. Ag-N co-doped ZnO/CuO composite showed higher photo-catalytic activity than Ag- or N-doped ZnO and undoped ZnO-CuO composite photo-catalysts. The observed highest activity of Ag-N co-doped ZnO-CuO among the studied photo-catalysts is attributed to the cumulative effects of lowering of band-gap energy and decrease of recombination rate of photo-generated electrons and holes owing to doped N and Ag, respectively. Effects of photo-catalyst load, pH and substrate initial concentration on degradation of methyl orange have also been studied. Photo-catalytic degradation of methyl orange follows pseudo first order kinetics. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=degradation" title="degradation">degradation</a>, <a href="https://publications.waset.org/abstracts/search?q=nanocomposite" title=" nanocomposite"> nanocomposite</a>, <a href="https://publications.waset.org/abstracts/search?q=photocatalyst" title=" photocatalyst"> photocatalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=spectroscopy" title=" spectroscopy"> spectroscopy</a>, <a href="https://publications.waset.org/abstracts/search?q=XRD" title=" XRD"> XRD</a> </p> <a href="https://publications.waset.org/abstracts/18641/effect-of-doping-ag-and-n-on-the-photo-catalytic-activity-of-znocuo-nanocomposite-for-degradation-of-methyl-orange-under-uv-and-visible-radiation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/18641.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">497</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">528</span> Semiconductor Properties of Natural Phosphate Application to Photodegradation of Basic Dyes in Single and Binary Systems</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Y.%20Roumila">Y. Roumila</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Meziani"> D. Meziani</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Bagtache"> R. Bagtache</a>, <a href="https://publications.waset.org/abstracts/search?q=K.%20Abdmeziem"> K. Abdmeziem</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Trari"> M. Trari</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Heterogeneous photocatalysis over semiconductors has proved its effectiveness in the treatment of wastewaters since it works under soft conditions. It has emerged as a promising technique, giving rise to less toxic effluents and offering the opportunity of using sunlight as a sustainable and renewable source of energy. Many compounds have been used as photocatalysts. Though synthesized ones are intensively used, they remain expensive, and their synthesis involves special conditions. We thus thought of implementing a natural material, a phosphate ore, due to its low cost and great availability. Our work is devoted to the removal of hazardous organic pollutants, which cause several environmental problems and health risks. Among them, dye pollutants occupy a large place. This work relates to the study of the photodegradation of methyl violet (MV) and rhodamine B (RhB), in single and binary systems, under UV light and sunlight irradiation. Methyl violet is a triarylmethane dye, while RhB is a heteropolyaromatic dye belonging to the Xanthene family. In the first part of this work, the natural compound was characterized using several physicochemical and photo-electrochemical (PEC) techniques: X-Ray diffraction, chemical, and thermal analyses scanning electron microscopy, UV-Vis diffuse reflectance measurements, and FTIR spectroscopy. The electrochemical and photoelectrochemical studies were performed with a Voltalab PGZ 301 potentiostat/galvanostat at room temperature. The structure of the phosphate material was well characterized. The photo-electrochemical (PEC) properties are crucial for drawing the energy band diagram, in order to suggest the formation of radicals and the reactions involved in the dyes photo-oxidation mechanism. The PEC characterization of the natural phosphate was investigated in neutral solution (Na₂SO₄, 0.5 M). The study revealed the semiconducting behavior of the phosphate rock. Indeed, the thermal evolution of the electrical conductivity was well fitted by an exponential type law, and the electrical conductivity increases with raising the temperature. The Mott–Schottky plot and current-potential J(V) curves recorded in the dark and under illumination clearly indicate n-type behavior. From the results of photocatalysis, in single solutions, the changes in MV and RhB absorbance in the function of time show that practically all of the MV was removed after 240 mn irradiation. For RhB, the complete degradation was achieved after 330 mn. This is due to its complex and resistant structure. In binary systems, it is only after 120 mn that RhB begins to be slowly removed, while about 60% of MV is already degraded. Once nearly all of the content of MV in the solution has disappeared (after about 250 mn), the remaining RhB is degraded rapidly. This behaviour is different from that observed in single solutions where both dyes are degraded since the first minutes of irradiation. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=environment" title="environment">environment</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20pollutant" title=" organic pollutant"> organic pollutant</a>, <a href="https://publications.waset.org/abstracts/search?q=phosphate%20ore" title=" phosphate ore"> phosphate ore</a>, <a href="https://publications.waset.org/abstracts/search?q=photodegradation" title=" photodegradation"> photodegradation</a> </p> <a href="https://publications.waset.org/abstracts/113573/semiconductor-properties-of-natural-phosphate-application-to-photodegradation-of-basic-dyes-in-single-and-binary-systems" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/113573.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">132</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">527</span> Prediction of Corrosion Inhibition Using Methyl Ester Sulfonate Anionic Surfactants</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=A.%20Asselah">A. Asselah</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Khalfi"> A. Khalfi</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20A.Toumi"> M. A.Toumi</a>, <a href="https://publications.waset.org/abstracts/search?q=A.Tazerouti"> A.Tazerouti</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The study of the corrosion inhibition of a standard carbon steel "API 5L grade X70" by two biodegradable anionic surfactants derived from fatty acids by photo sulfochlorination, called sodium lauryl methyl ester sulfonates and sodium palmityl methyl ester sulfonates was carried. A solution at 2.5 g/l NaCl saturated with carbon dioxide is used as a corrosive medium. The gravimetric and electrochemical technics (stationary and transient) were used in order to quantify the rate of corrosion and to evaluate the electrochemical inhibition efficiency, thus the nature of the mode of action of the inhibitor, in addition to a surface characterization by scanning electron microscopy (MEB) coupled to energy dispersive X-ray spectroscopy (EDX). The variation of the concentration and the temperature were examined, and the mode of adsorption of these inhibitors on the surface of the metal was established by assigning it the appropriate isotherm and determining the corresponding thermodynamic parameters. The MEB-EDX allowed the visualization of good adhesion of the protective film formed by the surfactants to the surface of the steel. The corrosion inhibition was evaluated at around 93% for sodium lauryl methyl ester sulfonate surfactant at 20 ppm and 87.2% at 50 ppm for sodium palmityl methyl ester sulfonate surfactant. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbon%20steel" title="carbon steel">carbon steel</a>, <a href="https://publications.waset.org/abstracts/search?q=oilfield" title=" oilfield"> oilfield</a>, <a href="https://publications.waset.org/abstracts/search?q=corrosion" title=" corrosion"> corrosion</a>, <a href="https://publications.waset.org/abstracts/search?q=anionic%20surfactants" title=" anionic surfactants"> anionic surfactants</a> </p> <a href="https://publications.waset.org/abstracts/158305/prediction-of-corrosion-inhibition-using-methyl-ester-sulfonate-anionic-surfactants" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/158305.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">94</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">526</span> Cytotoxic Activity Of Major Iridoids From Barleria Trispinosa (Forssk.) Vahl. Growing In Saudi Arabia</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hamza%20Assiry">Hamza Assiry</a>, <a href="https://publications.waset.org/abstracts/search?q=Gamal%20A.%20Mohamed"> Gamal A. Mohamed</a>, <a href="https://publications.waset.org/abstracts/search?q=Sabrin%20R.%20M.%20Ibrahim"> Sabrin R. M. Ibrahim</a>, <a href="https://publications.waset.org/abstracts/search?q=Hossam%20M.%20Abdallah"> Hossam M. Abdallah</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chemical investigation of the aerial parts of Barleria trispinosa(Forssk.) Vahl. resulted in isolation of four major iridoids that were identified as 6,8-O,O-diacetylshanhiside methyl ester (acetyl barlerin) (1), 8-O-acetylshanzhiside methyl ester (barlerin) (2), shanzhiside methyl ester (3), and 6- ⍺ -L-rhamnopyranosyl-8-O-acetylshanzihiside methyl ester (4). The isolated compounds were confirmed by detailed one and two-dimensional NMR. Isolated compounds were tested for their cytotoxic activity on breast cancer (MCF-7, MDA-MB-231) and colon cancer (LS174T) cell linesusing sulphorhodamine B (SRB) assay. It is noteworthy that compound 1 demonstrated a significant cytotoxic potential towards MDA-MB-231 cell line with IC5016.7 ± 2.7µg / mL compared to doxorubicin whereas compounds 2, showed moderate cytotoxic potential with IC5021.2 ± 1.9µg / mL on MCF-7. The other compounds showed moderate activity on the tested cell lines. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=acanthaceae" title="acanthaceae">acanthaceae</a>, <a href="https://publications.waset.org/abstracts/search?q=cytotoxicity" title=" cytotoxicity"> cytotoxicity</a>, <a href="https://publications.waset.org/abstracts/search?q=metabolites" title=" metabolites"> metabolites</a>, <a href="https://publications.waset.org/abstracts/search?q=barleria%20trispinosa" title=" barleria trispinosa"> barleria trispinosa</a> </p> <a href="https://publications.waset.org/abstracts/147131/cytotoxic-activity-of-major-iridoids-from-barleria-trispinosa-forssk-vahl-growing-in-saudi-arabia" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/147131.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">146</span> </span> </div> </div> <ul class="pagination"> <li class="page-item disabled"><span class="page-link">&lsaquo;</span></li> <li class="page-item active"><span class="page-link">1</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=3">3</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=4">4</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=5">5</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=6">6</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=7">7</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=8">8</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=9">9</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=10">10</a></li> <li class="page-item disabled"><span class="page-link">...</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=18">18</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=19">19</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=methyl%20violet&page=2" rel="next">&rsaquo;</a></li> </ul> 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