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The journal targets excellence in the international chemistry community and includes topics such as synthetic methodology, product property studies, and applications in catalysis, energy conversion, biomedical, pharmaceuticals, environmental protection, and more. It is suitable for publishing research in areas including inorganic, organic, polymer, and bio-synthesis. The journal accepts rapid short communications, research articles, reviews, feature articles, and commentaries."><meta data-n-head="ssr" name="keywords" content=""><meta data-n-head="ssr" name="twitter:title" content="Chemical Synthesis - OAE Publishing Inc."><meta data-n-head="ssr" name="twitter:type" content="OAE Publishing Inc."><meta data-n-head="ssr" name="twitter:description" content="Chemical Synthesis is an international journal with Bao-Lian Su as Editor-in-Chief, operating as a golden open-access publication. It covers various fields in the realm of chemical science and aims to be a preferred resource for groundbreaking research, providing a platform for future developments in chemistry for both academic and industrial research. The journal targets excellence in the international chemistry community and includes topics such as synthetic methodology, product property studies, and applications in catalysis, energy conversion, biomedical, pharmaceuticals, environmental protection, and more. It is suitable for publishing research in areas including inorganic, organic, polymer, and bio-synthesis. The journal accepts rapid short communications, research articles, reviews, feature articles, and commentaries."><meta data-n-head="ssr" property="og:url" content="/cs"><meta data-n-head="ssr" property="og:type" content="OAE Publishing Inc."><meta data-n-head="ssr" property="og:site_name" content="Chemical Synthesis"><meta data-n-head="ssr" property="og:title" content="Chemical Synthesis"><title>Chemical Synthesis - OAE Publishing Inc.</title><link data-n-head="ssr" rel="icon" type="image/x-icon" href="/favicon.ico"><link data-n-head="ssr" rel="canonical" href="https://www.oaepublish.com/cs"><script data-n-head="ssr" src="https://accounts.google.com/gsi/client" async></script><script data-n-head="ssr" src="https://g.oaes.cc/oae/dist/relijs.js" async></script><link rel="preload" href="https://g.oaes.cc/oae/nuxt/47b9fdf.js" as="script"><link rel="preload" href="https://g.oaes.cc/oae/nuxt/800bc65.js" as="script"><link rel="preload" href="https://g.oaes.cc/oae/nuxt/css/8176b15.css" 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data-v-1c35eca8><div class="ipad_bg" style="display:none;" data-v-1c35eca8></div> <div class="head_top" data-v-1c35eca8><div class="wrapper head_box" data-v-1c35eca8><span class="qk_jx" data-v-1c35eca8><img src="https://i.oaes.cc/upload/journal_logo/cs.jpg" alt data-v-1c35eca8></span> <a href="/cs" aria-current="page" class="qk_a_name nuxt-link-exact-active nuxt-link-active" data-v-1c35eca8><span class="title font20" data-v-1c35eca8>Chemical Synthesis</span></a> <div class="top_img" data-v-1c35eca8><a href="https://www.scopus.com/sourceid/21101189036" target="_blank" data-v-1c35eca8><img src="https://i.oaes.cc/uploads/20240813/6d91bea2ff474cb9b7ec10017b26ec2a.png" alt data-v-1c35eca8></a></div> <div class="oae_menu_box" data-v-1c35eca8><a href="/alljournals" data-v-1c35eca8><span data-v-1c35eca8>All Journals</span></a></div> <span class="search" data-v-1c35eca8><i class="icon-search icon_right font24" data-v-1c35eca8></i> <span data-v-1c35eca8>Search</span></span> <span class="go_oae" data-v-1c35eca8><a href="https://www.oaecenter.com/login" target="_blank" data-v-1c35eca8><i class="icon-login-line icon_right font24" data-v-1c35eca8></i> <span data-v-1c35eca8>Log In</span></a></span></div></div> <div class="cg" style="height: 41px" data-v-1c35eca8></div>  <div class="head_text" style="border-bottom:3px solid rgb(0,165,179);" data-v-1c35eca8><div class="head_search wrapper" data-v-1c35eca8><div class="box_btn" data-v-1c35eca8><div class="qk_miss" data-v-1c35eca8><img src="https://i.oaes.cc/uploads/20250113/4f8e516f15b649849086341d06b850f5.jpg" alt class="qk_fm" data-v-1c35eca8> <div class="miss_right" data-v-1c35eca8><div class="miss_btn" data-v-1c35eca8><span data-v-1c35eca8><span class="font_b" data-v-1c35eca8>Editor-in-Chief:</span> Bao-Lian Su</span></div> <div class="miss_btn" data-v-1c35eca8><div class="text_index" data-v-1c35eca8><span class="font_b" data-v-1c35eca8>Indexing: </span> <span data-v-1c35eca8><a href="https://suggestor.step.scopus.com/progressTracker/?trackingID=5EE267A0809C4A8A" target="_blank" data-v-1c35eca8>Scopus</a><span class="xing_d" data-v-1c35eca8>, </span></span><span data-v-1c35eca8><a href="https://cassi.cas.org/publication.jsp?P=eCQtRPJo9AQyz133K_ll3zLPXfcr-WXfTpYONFIPqYFOrPRP7aX3_zLPXfcr-WXfRPMVF6-WKMHLbuop5XpQjDLPXfcr-WXfT0oatUp63Y1EcnilAK1wWw" target="_blank" data-v-1c35eca8>CAS</a><span class="xing_d" data-v-1c35eca8>, </span></span><span data-v-1c35eca8><a href="https://app.dimensions.ai/discover/publication?and_facet_source_title=jour.1404582" target="_blank" data-v-1c35eca8>Dimensions</a><span class="xing_d" data-v-1c35eca8>, </span></span><span data-v-1c35eca8><a href="https://www.lens.org/lens/search/scholar/list?p=0&n=10&s=date_published&d=%2B&f=false&e=false&l=en&authorField=author&dateFilterField=publishedYear&orderBy=%2Bdate_published&presentation=false&preview=true&stemmed=true&useAuthorId=false&publicationType.must=journal%20article&sourceTitle.must=Chemical%20Synthesis&publisher.must=OAE%20Publishing%20Inc." target="_blank" data-v-1c35eca8>Lens</a><span class="xing_d" data-v-1c35eca8>, </span></span><span data-v-1c35eca8><a href=" https://enscholar.cnki.net/journal/index/3afe9fe8-0a1c-4977-adb8-269c05fba236" target="_blank" data-v-1c35eca8>CNKI</a><span class="xing_d" data-v-1c35eca8>, </span></span></div> <div class="text_jour" data-v-1c35eca8><span class="font_b" data-v-1c35eca8>Submission to first decision: </span><span data-v-1c35eca8>42 days</span></div></div> <div class="btn_box_t" data-v-1c35eca8><button type="button" class="el-button el-button--text " data-v-1c35eca8><span><a href="0" target="_blank" data-v-1c35eca8><i 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data-v-3e280d43></i>Menu</span></button></div></div>  </div> <main><div data-v-9d35a14e><div class="PcComment" data-v-9d35a14e><h1 class="hidden_h1" data-v-9d35a14e>Chemical Synthesis</h1> <div class="wrapper" data-v-9d35a14e><div aria-label="Breadcrumb" role="navigation" class="el-breadcrumb" data-v-9d35a14e><span class="el-breadcrumb__item" data-v-9d35a14e><span role="link" class="el-breadcrumb__inner is-link">Journals</span><span role="presentation" class="el-breadcrumb__separator"></span></span> <span class="el-breadcrumb__item" style="text-transform:uppercase;" data-v-9d35a14e><span role="link" class="el-breadcrumb__inner">cs</span><span role="presentation" class="el-breadcrumb__separator"></span></span></div> <div class="el-row" style="margin-left:-10px;margin-right:-10px;" data-v-9d35a14e><div class="el-col el-col-24 el-col-xs-24 el-col-sm-16 el-col-md-18" style="padding-left:10px;padding-right:10px;" data-v-9d35a14e><div data-v-c1f41ab4 data-v-9d35a14e><div class="banner_box" data-v-c1f41ab4><div class="grid-content banner_cont pad_r_10" data-v-c1f41ab4><div class="banner_box_b" data-v-c1f41ab4> <div class="swiper-container" data-v-5c8e3c6d data-v-c1f41ab4><div class="swiper-wrapper" data-v-5c8e3c6d><div class="swiper-slide" data-v-5c8e3c6d><a href="https://www.oaepublish.com/news/cs.1042" data-v-5c8e3c6d><div class="tit" data-v-5c8e3c6d><div class="title" data-v-5c8e3c6d><a href="https://www.oaepublish.com/news/cs.1042" data-v-5c8e3c6d><span data-v-5c8e3c6d>Congratulations to <i>Chemical Synthesis</i> Author Professor Vivian W.W. Yam on Receiving the 2025 IUPAC Award for Distinguished Women in Chemistry</span></a></div> <div class="title_sm" data-v-5c8e3c6d><span data-v-5c8e3c6d>Professor Vivian W.W. Yam </span></div></div> <img src="https://i.oaes.cc/uploads/20250219/b35e4c50a4854a63a57a0b1597ccffea.jpg" alt data-v-5c8e3c6d></a></div><div class="swiper-slide" data-v-5c8e3c6d><a href="https://www.oaepublish.com/articles/cs.2024.30" data-v-5c8e3c6d><div class="tit" data-v-5c8e3c6d><div class="title" data-v-5c8e3c6d><a href="https://www.oaepublish.com/articles/cs.2024.30" data-v-5c8e3c6d><span data-v-5c8e3c6d>The transfer hydrogenation of levulinic acid to γ-valerolactone over CuNiAl catalyst</span></a></div> <div class="title_sm" data-v-5c8e3c6d><span data-v-5c8e3c6d>Keywords: CuNiAl catalyst, levulinic acid, CuNi alloy, γ-valerolactone, transfer hydrogenation, formic acid</span></div></div> <img src="https://i.oaes.cc/uploads/20250109/82eed824dfc64d868a1f19ede7a186f8.png" alt data-v-5c8e3c6d></a></div><div class="swiper-slide" data-v-5c8e3c6d><a href="https://www.oaepublish.com/news/cs.981" data-v-5c8e3c6d><div class="tit" data-v-5c8e3c6d><div class="title" data-v-5c8e3c6d><a href="https://www.oaepublish.com/news/cs.981" data-v-5c8e3c6d><span data-v-5c8e3c6d>Congratulations to Associate Editor Professor Aicheng Chen Elected to the Royal Society of Canada as Fellow of the Academy of Science </span></a></div> <div class="title_sm" data-v-5c8e3c6d><span data-v-5c8e3c6d>University of Guelph，Canada</span></div></div> <img src="https://i.oaes.cc/uploads/20250103/e73a9b5a98334cba82a172fe3c432732.jpg" alt data-v-5c8e3c6d></a></div><div class="swiper-slide" data-v-5c8e3c6d><a href="https://www.oaepublish.com/specials/cs.2232" data-v-5c8e3c6d><div class="tit" data-v-5c8e3c6d><div class="title" data-v-5c8e3c6d><a href="https://www.oaepublish.com/specials/cs.2232" data-v-5c8e3c6d><span data-v-5c8e3c6d>Call For Papers!</span></a></div> <div class="title_sm" data-v-5c8e3c6d><span data-v-5c8e3c6d>Hot Topic: Catalysis for CO<sub>2</sub> Utilization</span></div></div> <img src="https://i.oaes.cc/uploads/20241217/533367ba549a49f3857590cdde06e5f9.png" alt 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Yam on Receiving the 2025 IUPAC Award for Distinguished Women in Chemistry",sub_title:"Professor Vivian W.W. Yam\r\n",href:"https:\u002F\u002Fwww.oaepublish.com\u002Fnews\u002Fcs.1042",target:g,img:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20250219\u002Fb35e4c50a4854a63a57a0b1597ccffea.jpg",mobile_img:a},{id:1143,type:r,title:"The transfer hydrogenation of levulinic acid to γ-valerolactone over CuNiAl catalyst",sub_title:"Keywords: CuNiAl catalyst, levulinic acid, CuNi alloy, γ-valerolactone, transfer hydrogenation, formic acid",href:"https:\u002F\u002Fwww.oaepublish.com\u002Farticles\u002Fcs.2024.30",target:i,img:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20250109\u002F82eed824dfc64d868a1f19ede7a186f8.png",mobile_img:a},{id:1137,type:r,title:"Congratulations to Associate Editor Professor Aicheng Chen Elected to the Royal Society of Canada as Fellow of the Academy of Science\r\n",sub_title:"University of Guelph，Canada",href:"https:\u002F\u002Fwww.oaepublish.com\u002Fnews\u002Fcs.981",target:i,img:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20250103\u002Fe73a9b5a98334cba82a172fe3c432732.jpg",mobile_img:a},{id:1115,type:r,title:"Call For Papers!",sub_title:"Hot Topic: Catalysis for CO\u003Csub\u003E2\u003C\u002Fsub\u003E Utilization",href:"https:\u002F\u002Fwww.oaepublish.com\u002Fspecials\u002Fcs.2232",target:i,img:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20241217\u002F533367ba549a49f3857590cdde06e5f9.png",mobile_img:a},{id:1113,type:r,title:"Porous frameworks for uranium extraction from seawater",sub_title:"Authors: Doudou Cao, Suming Zhang, Cheng Zhang, Yajie Yang, Ying-Bo Song, Yue Zheng, Jiarui Cao, Shusen Chen, Yan Song, Fengju Wang, Ye Yuan*\r\n",href:"https:\u002F\u002Fwww.oaepublish.com\u002Farticles\u002Fcs.2024.47",target:i,img:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20241216\u002F0d8f0833ccda44389adb35f5114e10a8.png",mobile_img:a}],articles:[{url_doi:"cs.2024.11",title:"Selective electroreduction of CO\u003Csub\u003E2\u003C\u002Fsub\u003E to C\u003Csub\u003E2+\u003C\u002Fsub\u003E products on cobalt decorated copper catalysts",id:387},{url_doi:"cs.2024.03",title:"Research progress of photoelectrochemical conversion of CO\u003Csub\u003E2\u003C\u002Fsub\u003E to C\u003Csub\u003E2+\u003C\u002Fsub\u003E products",id:386},{url_doi:"cs.2024.26",title:"Metal-organic framework-based self-supported electrodes for oxygen evolution reaction",id:N}],video:{id:460,title:"Interview with Prof. Shixue Dou\u003Cbr\u003EUniversity of Shanghai for Science and Technology, Shanghai, China",video_url:O,img_url:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20241105\u002Ff28687f927b640bf86475e8e044a61a3.png",link:O,journal_id:e,type:"academic",videos_home_url:"\u002Facademic_talks"}},indexMid:{articles:{recent:[{article_id:"7613",title:"Synergistic promotion of ultra-small Pt nanoparticles and oxygen vacancy in MOF catalyst for ethyl levulinate to valerolactone at room temperature",image:P,tag:"26",doi:"10.20517\u002Fcs.2024.35",date_published:"1739721600",section:m,authors:"Wei Yan, ... Xiaoqin Zou",journal_id:n,volume:d,year:s,section_id:"1411",special_name:Q,url_doi:"cs.2024.35",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002Ff4094f41-d480-4c33-9ab7-2a3f9462954a\u002Fcs4035.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Wei Yan'\u003E Wei Yan, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ying Wang'\u003E Ying Wang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Xu Zhao'\u003E Xu Zhao, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Siyi Pu'\u003E Siyi Pu, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Chunyan Yang'\u003E Chunyan Yang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Zirui Dao'\u003E Zirui Dao, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Changfu Zhuang'\u003E Changfu Zhuang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Chungang Min'\u003E Chungang Min, ... \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Xiaoqin Zou'\u003E Xiaoqin Zou",journal_path:b,video_img:a,image_list:P,abstract:"\u003Cp\u003ECurrently, designing highly efficient catalysts for biomass hydrogenation at low temperatures remains a significant challenge. This paper proposes a straightforward solvent-treatment strategy to create rich oxygen vacancies (O\u003Csub\u003EV\u003C\u002Fsub\u003E), facilitating the loading of ultra-small (1.6 nm) Pt nanoparticles (NPs) onto a metal-organic framework (MOF) (LaQS) with rich O\u003Csub\u003EV\u003C\u002Fsub\u003E (LaO\u003Csub\u003EV\u003C\u002Fsub\u003E-r). Consequently, a bifunctional Pt\u003Csub\u003E2\u003C\u002Fsub\u003E\u002FLaO\u003Csub\u003EV\u003C\u002Fsub\u003E-r catalyst, featuring Lewis acid and metal hydrogenation sites, was synthesized. Under mild conditions (80 °C), the Pt\u003Csub\u003E2\u003C\u002Fsub\u003E\u002FLaO\u003Csub\u003EV\u003C\u002Fsub\u003E-r catalyst exhibited a catalytic yield of \u003E99% in converting biobased ethyl acetylpropionate [ethyl levulinate (EL)] to valerolactone [γ-valerolactone (GVL)]. This yield was 3.2 and 13.3 times higher than those measured by Pt\u003Csub\u003E2\u003C\u002Fsub\u003E\u002FLaQS and commercial Pt\u002FC catalysts, respectively. Specifically, Pt\u003Csub\u003E2\u003C\u002Fsub\u003E\u002FLaO\u003Csub\u003EV\u003C\u002Fsub\u003E-r catalyzed the full conversion of EL to GVL even at room temperature. The results revealed that the synergistic effect between ultra-small Pt NPs and O\u003Csub\u003EV\u003C\u002Fsub\u003E in the MOF catalyst is important for the efficient conversion of EL into GVL. Especially, the abundant O\u003Csub\u003EV\u003C\u002Fsub\u003E defects in LaO\u003Csub\u003EV\u003C\u002Fsub\u003E-r not only enhanced the electron cloud density of Pt NPs at active sites of hydrogenation, but also elevated the content of moderately-strong acidic sites. This enhances the ability to activate H\u003Csub\u003E2\u003C\u002Fsub\u003E and EL, and promotes the intra-molecular dehydration of intermediates to GVL. The synergistic catalytic mechanism of O\u003Csub\u003EV\u003C\u002Fsub\u003E and ultra-small Pt NPs in MOFs is proposed. This study presents an effective strategy for defect engineering aimed at enhancing catalytic biomass conversion using MOFs-loaded metal NPs.\u003C\u002Fp\u003E"},{article_id:"7472",title:"Selective photooxidation of 5-hydroxymethylfurfural in water enabled by highly dispersed gold nanoparticles on graphitic carbon nitride",image:R,tag:"25",doi:"10.20517\u002Fcs.2024.115",date_published:"1739462400",section:m,authors:"Qizhao Zhang, ... Wenhao Fang\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0002-2449-3749' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Wenhao Fang'\u003E\u003C\u002Fa\u003E",journal_id:n,volume:d,year:s,section_id:i,special_name:a,url_doi:"cs.2024.115",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F251da64a-c758-4b41-b370-092c2f516868\u002Fcs40115.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Qizhao Zhang'\u003E Qizhao Zhang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Botao Fan'\u003E Botao Fan, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yuxi Wang'\u003E Yuxi Wang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Bang Gu'\u003E Bang Gu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-5178-021X' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Bang Gu'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Qinghu Tang'\u003E Qinghu Tang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Feng Qiu'\u003E Feng Qiu, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Qiue Cao'\u003E Qiue Cao, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Wenhao Fang'\u003E Wenhao Fang\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0002-2449-3749' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Wenhao Fang'\u003E\u003C\u002Fa\u003E",journal_path:b,video_img:a,image_list:R,abstract:"\u003Cp\u003EPhotocatalytic synthesis of chemicals is highly recognized for its eco-friendliness and mild reaction conditions, yet it faces considerable challenges regarding catalytic efficiency, stability and cost. The selective photooxidation of \u003CInlineParagraph\u003E5-hydroxymethylfurfural\u003C\u002FInlineParagraph\u003E to 2,5-diformylfuran in water is a cost-effective and sustainable route for biomass valorization. The capability of a photocatalyst to capture visible light is paramount for efficiently harnessing solar energy and is the most critical initial step. Therefore, metal nanocatalysts with visible-light response and localized surface plasmon resonance have received widespread attention. In this work, graphitic carbon nitride (\u003Ci\u003Eg\u003C\u002Fi\u003E-C\u003Csub\u003E3\u003C\u002Fsub\u003EN\u003Csub\u003E4\u003C\u002Fsub\u003E) with different morphologies was synthesized through high-temperature calcination of various organic precursors. Following that, the photodeposition of Au nanoparticles was used to construct a Schottky junction photocatalyst endowed with the localized surface plasmon resonance effect. The optimal Au\u002FCN(I) catalyst achieved a 26% yield of 2,5-diformylfuran and productivity of \u003CInlineParagraph\u003E72.7 mg\u003Csub\u003EDFF\u003C\u002Fsub\u003E g\u003Csub\u003Ecatal.\u003C\u002Fsub\u003E\u003Csup\u003E-1\u003C\u002Fsup\u003E h\u003Csup\u003E-1\u003C\u002Fsup\u003E\u003C\u002FInlineParagraph\u003E under simulated sunlight in oxygen and water without any additives. This outstanding result outperformed most \u003Ci\u003Eg\u003C\u002Fi\u003E-C\u003Csub\u003E3\u003C\u002Fsub\u003EN\u003Csub\u003E4\u003C\u002Fsub\u003E and metal oxide photocatalysts ever reported in the literature. The interfacial electronic interactions between Au nanoparticles and \u003Ci\u003Eg\u003C\u002Fi\u003E-C\u003Csub\u003E3\u003C\u002Fsub\u003EN\u003Csub\u003E4\u003C\u002Fsub\u003E semiconductors were meticulously elucidated using comprehensive characterizations and computational calculations. The roles of different reactive oxygen species were clarified by a series of controlled experiments. A plausible mechanism explaining the origin of visible-light response and photocatalytic performance was discussed.\u003C\u002Fp\u003E"},{article_id:"7750",title:"The effect of accessibility to acid sites in Y zeolites on ring opening reaction in light cycle oil hydrocracking",image:S,tag:"24",doi:"10.20517\u002Fcs.2024.133",date_published:"1739376000",section:m,authors:"Ping Yang\u003Ca href='https:\u002F\u002Forcid.org\u002F0009-0004-0888-141X' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Ping Yang'\u003E\u003C\u002Fa\u003E, ... Mingfeng Li",journal_id:n,volume:d,year:s,section_id:T,special_name:U,url_doi:"cs.2024.133",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002Ffc7d5a5f-9863-4fb4-9a18-d5e374ab4d06\u002Fcs40133.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ping Yang'\u003E Ping Yang\u003Ca href='https:\u002F\u002Forcid.org\u002F0009-0004-0888-141X' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Ping Yang'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Siyang Yan'\u003E Siyang Yan\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0002-5171-990X' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Siyang Yan'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ning He'\u003E Ning He, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Hong Nie'\u003E Hong Nie, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Luyao Guo'\u003E Luyao Guo, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Guang Xiong'\u003E Guang Xiong, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Naixin Wang'\u003E Naixin Wang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Jiaxu Liu'\u003E Jiaxu Liu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0003-0815-3979' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Jiaxu Liu'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Mingfeng Li'\u003E Mingfeng Li",journal_path:b,video_img:a,image_list:S,abstract:"\u003Cp\u003EThe light cycle oil (LCO) hydrocracking process converts polycyclic aromatics into highly valuable light aromatics such as benzene, toluene, xylene (BTX), in accordance with the requirements of low-carbon development and high-quality transformation from oil refining to chemical industry. The accessibility of acid sites is a critical factor that impacts LCO conversion and BTX yield. Initially, the fine structure and molecular size of the typical polycyclic aromatics in LCO and their hydrogenation reaction intermediates were investigated through gas chromatography-mass spectrometry (GC-MS) analysis and density functional theory (DFT) calculations. Three porous Y zeolites with comparable Si\u002FAl molar atomic ratios and pyridine (Py)-measured Brønsted acid amounts were chosen as an acidic component to prepare NiMo\u002F(Al\u003Csub\u003E2\u003C\u002Fsub\u003EO\u003Csub\u003E3\u003C\u002Fsub\u003E + HY) catalysts. The acid accessibility of HY zeolite was characterized via dual-beam infrared spectroscopy using 2,4,6-tri-tert-butylpyridine (2,4,6-TTBPy) and trihexylamine (THA) as probe molecules, and the LCO hydrocracking performance was evaluated on a fixed-bed reactor. The results revealed that bicyclic aromatic hydrocarbons featuring multiple, short side chains such as dimethylnaphthalene and trimethylnaphthalene are the main components of LCO, with sizes larger than those of HY zeolite micropores. There is a strong positive correlation between LCO conversion and ring-opening rate of polycyclic aromatics and cycloalkanes in LCO. Among these three HY zeolite catalysts, the ring-opening rates of polycyclic aromatics and cycloalkanes, and the yields of C\u003Csub\u003E6\u003C\u002Fsub\u003E-C\u003Csub\u003E12\u003C\u002Fsub\u003E aromatics and BTX increased in the order of HY1 \u003C HY2 \u003C HY3, which is consistent with external surface acidity measured by THA as the probe molecule.\u003C\u002Fp\u003E"},{article_id:"7703",title:"Selective heterogeneous photocatalytic activation for toluene oxidation: recent advances, challenges and perspective",image:V,tag:"22",doi:"10.20517\u002Fcs.2024.96",date_published:W,section:j,authors:"Shiqin Gao, ... Bolun Wang",journal_id:n,volume:d,year:s,section_id:"1767",special_name:"Topic: Carbon in Catalysis",url_doi:"cs.2024.96",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002Fb26a012b-d7a2-4da9-b6f5-ee6b104489be\u002Fcs4096.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Shiqin Gao'\u003E Shiqin Gao, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Lisu Bai'\u003E Lisu Bai, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Tao Gan'\u003E Tao Gan, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Bolun Wang'\u003E Bolun Wang",journal_path:b,video_img:a,image_list:V,abstract:"\u003Cp\u003EThe conversion of toluene into high-value products without generating undesired CO\u003Csub\u003E2\u003C\u002Fsub\u003E remains a critical challenge. Selective oxidation of toluene under visible light irradiation has emerged as a promising solution. This review offers a comprehensive interpretation of photocatalytic transformations in heterogeneous toluene oxidation. We start by outlining the basic mechanism of C–H bond activation of toluene and provide an overview of reactive oxygen species (ROS) within photocatalytic systems. Subsequently, we provide a summary of strategies that have been developed to enhance the conversion and selectivity of the heterogeneous photocatalytic system. Following this, advanced characterization techniques and density functional theory (DFT) calculations are discussed for understanding the structure-performance relationship of photocatalysts and the mechanisms underlying photocatalytic processes. Finally, we put forward a detailed discussion of current challenges and potential directions for future research, with the aim of offering valuable insights for this emerging field. We believe that this review will not only spark greater creativity in optimizing photocatalysts but also offer valuable insights for designing other C–H bond activation systems.\u003C\u002Fp\u003E"},{article_id:"7632",title:"A focus on the observation of bridging SiOHAl Brønsted acid sites in amorphous silica-alumina",image:i,tag:"23",doi:"10.20517\u002Fcs.2024.141",date_published:W,section:X,authors:"Olivier Lafon",journal_id:n,volume:d,year:s,section_id:T,special_name:U,url_doi:"cs.2024.141",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002Ffd271c2d-9661-4e6e-8ebc-9b791bf9dd69\u002Fcs40141.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Olivier Lafon'\u003E Olivier Lafon",journal_path:b,video_img:a,image_list:i,abstract:a}],recent_ids:"7613,7472,7750,7703,7632",view:[{article_id:Y,title:Z,image:v,tag:p,doi:_,date_published:$,section:j,authors:aa,journal_id:n,volume:g,year:q,section_id:i,special_name:a,url_doi:ab,pdf:ac,video_url:a,allauthors:"Jie Liu, Han-Zhi Xiao, Qiang Fu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-9993-8776' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Qiang Fu'\u003E\u003C\u002Fa\u003E, Da-Gang Yu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-5888-1494' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Da-Gang Yu'\u003E\u003C\u002Fa\u003E",journal_path:b,video_img:a,image_list:v,abstract:ad},{article_id:"6197",title:"Energy-efficient anodic reactions for sustainable hydrogen production via water electrolysis",image:ae,tag:"44",doi:"10.20517\u002Fcs.2023.28",date_published:"1697126400",section:j,authors:"Wenxian Liu, ... Yingtang Zhou\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0002-8678-295X' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Yingtang Zhou'\u003E\u003C\u002Fa\u003E",journal_id:n,volume:k,year:t,section_id:i,special_name:a,url_doi:"cs.2023.28",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F28d3d9ed-cc45-4385-be56-bc8a423770a6\u002Fcs3028.pdf",video_url:a,allauthors:"Wenxian Liu, Xinxin Niu, Jiawei Tang, Qian Liu, Jun Luo, Xijun Liu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0002-2624-6901' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Xijun Liu'\u003E\u003C\u002Fa\u003E, Yingtang Zhou\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0002-8678-295X' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Yingtang Zhou'\u003E\u003C\u002Fa\u003E",journal_path:b,video_img:a,image_list:ae,abstract:"\u003Cp\u003EOverall water splitting is considered as an effective technique for hydrogen (H\u003Csub\u003E2\u003C\u002Fsub\u003E) production; however, it usually requires large operating voltage mainly due to the high equilibrium potential of the anodic oxygen evolution reaction (OER). Replacing OER with energy-saving anode reactions not only reduces the operating voltage for H\u003Csub\u003E2\u003C\u002Fsub\u003E production but also generates high-value-added chemicals or purifies wastewater. This review article provides an overview of the fundamental reaction principles of overall water splitting and typical energy-saving alternative anode reactions, including methanol oxidation, hydrazine oxidation, and urea oxidation reactions. Then, the preparation methods, regulation strategies, and composition\u002Fstructure-performance relations of advanced catalysts for these energy-efficient H\u003Csub\u003E2\u003C\u002Fsub\u003E generation technologies are discussed. Finally, we propose the underlying challenges and perspectives for this promising field.\u003C\u002Fp\u003E"},{article_id:af,title:ag,image:w,tag:p,doi:ah,date_published:ai,section:j,authors:aj,journal_id:n,volume:h,year:x,section_id:i,special_name:a,url_doi:ak,pdf:al,video_url:a,allauthors:"Yaru Li, Dongsheng Zhang, Wei Qiao, Hongwei Xiang, Flemming Besenbacher, Yongwang Li, Ren Su",journal_path:b,video_img:a,image_list:w,abstract:am},{article_id:an,title:ao,image:y,tag:h,doi:ap,date_published:aq,section:j,authors:ar,journal_id:n,volume:g,year:q,section_id:i,special_name:a,url_doi:as,pdf:at,video_url:a,allauthors:"Yi Qin, Yu-Te Wang, Hai-Bo Yang\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0003-4926-1618' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Hai-Bo Yang'\u003E\u003C\u002Fa\u003E, Weihong Zhu",journal_path:b,video_img:a,image_list:y,abstract:au},{article_id:av,title:aw,image:z,tag:F,doi:ax,date_published:ay,section:az,authors:G,journal_id:n,volume:g,year:q,section_id:i,special_name:a,url_doi:aA,pdf:aB,video_url:a,allauthors:G,journal_path:b,video_img:a,image_list:z,abstract:aC}],view_ids:"4282,6197,4831,4183,4330",download:[{article_id:Y,title:Z,image:v,tag:p,doi:_,date_published:$,section:j,authors:aa,journal_id:n,volume:g,year:q,section_id:i,special_name:a,url_doi:ab,pdf:ac,video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Jie Liu'\u003E Jie Liu, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Han-Zhi Xiao'\u003E Han-Zhi Xiao, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Qiang Fu'\u003E Qiang Fu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-9993-8776' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Qiang Fu'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Da-Gang Yu'\u003E Da-Gang Yu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-5888-1494' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Da-Gang Yu'\u003E\u003C\u002Fa\u003E",journal_path:b,video_img:a,image_list:v,abstract:ad},{article_id:af,title:ag,image:w,tag:p,doi:ah,date_published:ai,section:j,authors:aj,journal_id:n,volume:h,year:x,section_id:i,special_name:a,url_doi:ak,pdf:al,video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yaru Li'\u003E Yaru Li, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Dongsheng Zhang'\u003E Dongsheng Zhang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Wei Qiao'\u003E Wei Qiao, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Hongwei Xiang'\u003E Hongwei Xiang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Flemming Besenbacher'\u003E Flemming Besenbacher, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yongwang Li'\u003E Yongwang Li, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ren Su'\u003E Ren Su",journal_path:b,video_img:a,image_list:w,abstract:am},{article_id:"4810",title:"Selenium confined in ZIF-8 derived porous carbon@MWCNTs 3D networks: tailoring reaction kinetics for high performance lithium-selenium batteries",image:aD,tag:A,doi:"10.20517\u002Fcs.2022.04",date_published:"1651075200",section:m,authors:"Hong-Yan Li, ... Bao-Lian Su\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-8474-0652' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Bao-Lian Su'\u003E\u003C\u002Fa\u003E",journal_id:n,volume:h,year:x,section_id:i,special_name:a,url_doi:"cs.2022.04",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002Ff1e1803d-b9e2-4b34-a222-71aaba905fae\u002F4810.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Hong-Yan Li'\u003E Hong-Yan Li, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Chao Li'\u003E Chao Li, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ying-Ying Wang'\u003E Ying-Ying Wang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ming-Hui Sun'\u003E Ming-Hui Sun, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Wenda Dong'\u003E Wenda Dong, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yu Li'\u003E Yu Li\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0002-1282-5312' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Yu Li'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Bao-Lian Su'\u003E Bao-Lian Su\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-8474-0652' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Bao-Lian Su'\u003E\u003C\u002Fa\u003E",journal_path:b,video_img:a,image_list:aD,abstract:"\u003Cp\u003ELithium-selenium battery is nowadays a highly competing technology to the commercial Li-ion battery because it has a high volumetric capacity of 3253 mAh cm\u003Csup\u003E-3\u003C\u002Fsup\u003E and gravimetric capacity of 675 mAh g\u003Csup\u003E-1\u003C\u002Fsup\u003E. However, the practical application of lithium-selenium (Li-Se) batteries is impeded by the shuttle effect of the soluble polyselenides during the cycling process. Herein, we report the in situ growth and pyrolysis of the metal-organic framework zeolitic imidazolate framework-8 (ZIF-8) on three-dimensional (3D) interconnected highly conductive multiwalled carbon nanotubes (MWCNTs). The obtained composites are used to anchor Se for advanced Li-Se batteries. Compared with the isolated ZIF-8 derived microporous carbon, our synthesized ZIF-8 derived porous carbon@MWCNTs (ZIF-8-C@MWCNTs) 3D highly conductive networks facilitate lithium ion diffusion and electron transportation. The particle size of ZIF-8 crystals has an important impact on the battery performance. By adjusting the particle size of ZIF-8, the electrochemical reaction kinetics in ZIF-8-C@MWCNTs 3D networks can be tuned. The optimized particle size of ZIF-8 around 300-500 nm coated on MWCNTs composite achieves an excellent initial discharge capacity of 756 mAh g\u003Csup\u003E-1\u003C\u002Fsup\u003E and a stabilized capacity of 468 mAh g\u003Csup\u003E-1 \u003C\u002Fsup\u003Eat 0.2 C after 200 cycles. Combining the 3D MWCNTs with the appropriate size of ZIF-8 derived microporous carbon particles could highly improve the performance of the Li-Se battery. This work provides significant guidance for further structural design and host particle size selection for high-performance Li-Se batteries.\u003C\u002Fp\u003E"},{article_id:an,title:ao,image:y,tag:h,doi:ap,date_published:aq,section:j,authors:ar,journal_id:n,volume:g,year:q,section_id:i,special_name:a,url_doi:as,pdf:at,video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yi Qin'\u003E Yi Qin, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yu-Te Wang'\u003E Yu-Te Wang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Hai-Bo Yang'\u003E Hai-Bo Yang\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0003-4926-1618' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Hai-Bo Yang'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Weihong Zhu'\u003E Weihong Zhu",journal_path:b,video_img:a,image_list:y,abstract:au},{article_id:av,title:aw,image:z,tag:F,doi:ax,date_published:ay,section:az,authors:G,journal_id:n,volume:g,year:q,section_id:i,special_name:a,url_doi:aA,pdf:aB,video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Guillaume Berionni'\u003E Guillaume Berionni",journal_path:b,video_img:a,image_list:z,abstract:aC}],download_ids:"4282,4831,4810,4183,4330"},cited:[{article_id:"5666",title:"Nanostructured intermetallics: from rational synthesis to energy electrocatalysis",image:aE,tag:"28",doi:"10.20517\u002Fcs.2023.17",date_published:"1685894400",section:j,authors:"Mingcheng Zhang, ... Xiaoxin Zou\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0003-4143-9274' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Xiaoxin Zou'\u003E\u003C\u002Fa\u003E",journal_id:n,volume:k,year:t,section_id:i,special_name:a,url_doi:"cs.2023.17",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F3d9463d3-4395-4626-9fdb-59a3b6661f94\u002F5666.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Mingcheng Zhang'\u003E Mingcheng Zhang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Qianqian Liu'\u003E Qianqian Liu, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Weipei Sun'\u003E Weipei Sun, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ke Sun'\u003E Ke Sun, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yucheng Shen'\u003E Yucheng Shen, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Wei An'\u003E Wei An, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Lu Zhang'\u003E Lu Zhang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Hui Chen'\u003E Hui Chen\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-7113-0206' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Hui Chen'\u003E\u003C\u002Fa\u003E, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Xiaoxin Zou'\u003E Xiaoxin Zou\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0003-4143-9274' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Xiaoxin Zou'\u003E\u003C\u002Fa\u003E",journal_path:b,video_img:a,image_list:aE,abstract:"\u003Cp\u003EIntermetallics are a large family of structurally ordered alloys that combines a metal element with other metal\u002Fmetalloid elements with a clearly defined stoichiometric ratio. Intermetallics possess abundant crystal structures and atomic packing motifs, giving rise to a great variety of electronic configurations and surface adsorption properties. The wide electronic and geometric diversity makes intermetallics a highly promising population for discovering advanced materials for various catalytic applications. This review presents recent advances in the reaction synthesis of intermetallic materials at the nanoscale and their energy-related electrocatalytic applications. Initially, we introduce general principles for the formation of stable intermetallic structures. Subsequently, we elaborate on common synthetic strategies of nanostructured intermetallics, such as thermal annealing, wet-chemical methods, metallothermic reduction, and template-directed synthesis. Furthermore, we discuss the wide employment of these intermetallic nanocatalysts in many different kinds of electrocatalytic applications, as well as highlight the theoretical and experimental evidence for establishing a reasonable relationship between atomic arrangement and catalytic activity. Finally, we propose some perspectives for future developments of intermetallic preparation and catalytic applications.\u003C\u002Fp\u003E"},{article_id:"5446",title:"Enantioselective synthesis of 3-arylindole atropisomers via organocatalytic indolization of iminoquinones",image:aF,tag:aG,doi:"10.20517\u002Fcs.2022.46",date_published:"1677427200",section:m,authors:"Yu-Wei Liu, ... Bin Tan",journal_id:n,volume:k,year:t,section_id:aH,special_name:H,url_doi:"cs.2022.46",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F83372d5a-3f62-4f3f-bdfd-7c5ebbd5bfae\u002F5446.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yu-Wei Liu'\u003E Yu-Wei Liu, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ye-Hui Chen'\u003E Ye-Hui Chen, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Jun Kee Cheng'\u003E Jun Kee Cheng, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Shao-Hua Xiang'\u003E Shao-Hua Xiang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Bin Tan'\u003E Bin Tan",journal_path:b,video_img:a,image_list:aF,abstract:"\u003Cp\u003EThe direct enantioselective construction of axially chiral 3-arylindole frameworks via nucleophilic addition of 2-substituted indoles to iminoquinones has been achieved with high efficiencies under mild chiral phosphoric acid (CPA) catalytic conditions. The utility of this method was demonstrated in successful scale-up syntheses without compromising the product yields and enantioselectivities. The oxidation of products yields axially chiral heteroaryl-\u003Ci\u003Ep\u003C\u002Fi\u003E-quinone monoimine, which could be subjected to structural diversification\u003Ci\u003E via\u003C\u002Fi\u003E addition of nucleophiles.\u003C\u002Fp\u003E"},{article_id:"5400",title:"Organocatalytic Nazarov-type cyclization of 3-alkynyl-2-indolylmethanols: construction of axially chiral cyclopenta[\u003Ci\u003Eb\u003C\u002Fi\u003E]indole scaffolds",image:aI,tag:o,doi:"10.20517\u002Fcs.2022.42",date_published:"1675353600",section:m,authors:"Ping Wu, ... Feng Shi\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0003-3922-0708' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Feng Shi'\u003E\u003C\u002Fa\u003E",journal_id:n,volume:k,year:t,section_id:aH,special_name:H,url_doi:"cs.2022.42",pdf:"https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F1eaf238f-bf8c-47d6-8ee0-a65d921a9bc6\u002F5400.pdf",video_url:a,allauthors:"\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Ping Wu'\u003E Ping Wu, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Xin-Yu Yan'\u003E Xin-Yu Yan, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Song Jiang'\u003E Song Jiang, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Yi-Nan Lu'\u003E Yi-Nan Lu, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Wei Tan'\u003E Wei Tan, \u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Fdefault_photo.png' class='author_photo' alt='Feng Shi'\u003E Feng Shi\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0003-3922-0708' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Feng Shi'\u003E\u003C\u002Fa\u003E",journal_path:b,video_img:a,image_list:aI,abstract:"\u003Cp\u003EIn recent years, it has become an urgent task to design new types of indole-based platform molecules for Nazarov-type cyclizations and develop organocatalytic Nazarov-type cyclizations for synthesizing indole derivatives. To fulfill this task, in this work, by changing the alkynyl terminal substituent from \u003Ci\u003Et\u003C\u002Fi\u003E-Bu to an aryl group, the reactivity of 3-alkynyl-2-indolylmethanols is modulated and the new platform molecules serve as competent substrates for Brønsted acid-catalyzed Nazarov-type cyclization. Based on this new reactivity, the first organocatalytic Nazarov-type cyclization of aryl-substituted 3-alkynyl-2-indolylmethanols with 2-naphthols is accomplished, leading to the efficient construction of a new class of axially chiral 3, 4-dihydrocyclopenta[\u003Ci\u003Eb\u003C\u002Fi\u003E]indole scaffolds. This preliminary investigation of organocatalytic asymmetric Nazarov-type cyclization provides an optional strategy for the atroposelective construction of this new class of axially chiral cyclopenta[\u003Ci\u003Eb\u003C\u002Fi\u003E]indole scaffolds. In addition, the first preparation of axially chiral 3, 4-dihydrocyclopenta[\u003Ci\u003Eb\u003C\u002Fi\u003E]indole with optical purity is established through chiral resolution, which could serve as a complementary method to catalytic asymmetric approaches.\u003C\u002Fp\u003E"}],cited_ids:"5666,5446,5400"},indexFot:{webinars:[],osi:{url:"https:\u002F\u002Foaemesas.com\u002Flogin?JournalId=cs",img:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20240228\u002Ff65c034ec5ae4d3982ec3daab121afbb.jpg",list:[{section_id:2395,journal_id:e,deadline:aJ,image:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20250208\u002F506b58ef394b4ad9a1fba0bff6e530e0.jpg",sub_link:"https:\u002F\u002Fwww.oaecenter.com\u002Flogin?JournalId=cs&IssueId=cs250208",email:aK,issue_flyer:a,title:"Topic: Design and Advanced Characterization of Catalysts",count:c,author:["Prof. Anmin Zheng","Prof. Shutao Xu","Prof. Pu 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https:\u002F\u002Fenscholar.cnki.net\u002Fjournal\u002Findex\u002F3afe9fe8-0a1c-4977-adb8-269c05fba236"},editor:aL,journal_rank:a,journal_flyer:i,qksearch:["Catalysis","Supramolecular assembly","Synthesis","Inorganic materials","Phosphorylation","Biosynthesis","Gas therapy"],sitetag:"Chem Synth",ad:[],colour_tag:"#00a5b3",score:a,mobile_top_img:a,impact_factor:[{factor:"https:\u002F\u002Fi.oaes.cc\u002Fuploads\u002F20240813\u002F6d91bea2ff474cb9b7ec10017b26ec2a.png",url:"https:\u002F\u002Fwww.scopus.com\u002Fsourceid\u002F21101189036"}],rgba:"rgb(0,165,179)",log_image:"https:\u002F\u002Fi.oaes.cc\u002Fupload\u002Fjournal_logo\u002Fcs.jpg"},webinfo:{},searchKey:a,loading:aZ,appid:a,videoPlay:{show:E,href:a}},editer:{editList:{list:{}}},userdata:{showLogin:E,logined:E}},serverRendered:aZ,routePath:L,config:{_app:{basePath:a_,assetsPath:a_,cdnURL:"https:\u002F\u002Fg.oaes.cc\u002Foae\u002Fnuxt\u002F"}}}}("","cs",0,"5",20,null,"1","2","0","Review","3","4","Research Article","20","6","9","2021","image","2025","2023",449,"https:\u002F\u002Fimage.oaes.cc\u002F122b6d9d-9281-4d06-a896-31ba743bcac0\u002F4282-coverimg.jpg","https:\u002F\u002Fimage.oaes.cc\u002F56840e6d-7e99-4cba-95e8-d2b2c95681e1\u002F4831-coverimg.jpg","2022","https:\u002F\u002Fimage.oaes.cc\u002F5aca738e-1c59-461a-be61-43c7da541a1f\u002F4183-coverimg.jpg","https:\u002F\u002Fimage.oaes.cc\u002F9890435f-527b-49e9-a3c7-e774c1203901\u002F4330-coverimg.jpg","8","assistant_editor@chesynjournal.com",275,"Mini Review",false,"10","Guillaume Berionni","Topic: Celebrating the 45th Anniversary of Changzhou University - Applications and Future Prospects of Asymmetric Organocatalysis","editorialoffice@chesynjournal.com","Contact Us","Chemical Synthesis","\u002Fcs","7",385,"https:\u002F\u002Fv.oaes.cc\u002Fuploads\u002F20241105\u002F5da58112be0746208ca117e5e75395a4.mp4","https:\u002F\u002Fimage.oaes.cc\u002Ff4094f41-d480-4c33-9ab7-2a3f9462954a\u002Fcs4035-coverimg.jpg","Topic: Innovations in Functional Porous Frameworks","https:\u002F\u002Fimage.oaes.cc\u002F251da64a-c758-4b41-b370-092c2f516868\u002Fcs40115-coverimg.jpg","https:\u002F\u002Fimage.oaes.cc\u002Ffc7d5a5f-9863-4fb4-9a18-d5e374ab4d06\u002Fcs40133-coverimg.jpg","1448","Topic: Advanced Characterization Techniques and Applications for Catalytic Materials","https:\u002F\u002Fimage.oaes.cc\u002Fb26a012b-d7a2-4da9-b6f5-ee6b104489be\u002Fcs4096-coverimg.jpg","1738944000","Research Highlight","4282","Advances in radical phosphorylation from 2016 to 2021","10.20517\u002Fcs.2021.07","1629907200","Jie Liu, ... Da-Gang Yu\u003Ca href='https:\u002F\u002Forcid.org\u002F0000-0001-5888-1494' target='_blank'\u003E\u003Cimg src='https:\u002F\u002Fi.oaes.cc\u002Fimages\u002Forcid.png' class='author_id' alt='Da-Gang Yu'\u003E\u003C\u002Fa\u003E","cs.2021.07","https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F122b6d9d-9281-4d06-a896-31ba743bcac0\u002F4282.pdf","\u003Cp\u003EOrganophosphorus compounds are of great significance in organic chemistry. Therefore, the construction of phosphorus-containing compounds has attracted significant attention from organic chemists. Radical phosphorylation has become a powerful strategy for building organophosphorus compounds and numerous achievements have been realized in recent years. In this review, we summarize the development of the generation and application of phosphorus radicals in organic chemistry since 2016. Special emphasis is given to various new transformations involving the generation of P-centered radicals via transition metal catalytic, photochemical and electrochemical means. Recent advances in the development of metal-free catalytic phosphorylations involving P-centered radicals are also reviewed.\u003C\u002Fp\u003E","https:\u002F\u002Fimage.oaes.cc\u002F28d3d9ed-cc45-4385-be56-bc8a423770a6\u002Fcs3028-coverimg.jpg","4831","Nanostructured heterogeneous photocatalyst materials for green synthesis of valuable chemicals","10.20517\u002Fcs.2022.05","1650988800","Yaru Li, ... Ren Su","cs.2022.05","https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F56840e6d-7e99-4cba-95e8-d2b2c95681e1\u002F4831.pdf","\u003Cp\u003EThe photocatalytic process employing nanostructured semiconductor materials has attracted great attention in energy production, CO\u003Csub\u003E2\u003C\u002Fsub\u003E reduction, and water\u002Fair purification for decades. Recently, applying heterogeneous photocatalyst for the synthesis of valuable chemicals is gradually emerging and considered as a promising process for the conversion of cheap resources (i.e., biomass derivatives, polyols, and aromatic hydrocarbons). Compared with traditional thermal catalytic approaches, the photocatalytic process provides a mild reaction condition and flexible platform (photocatalyst) that allows precise tweaking of reaction intermediates and reaction pathways, thus resulting in fine control of the selective synthesis of specialized chemicals that are challenging for thermal catalysis. In this review, we summarize recent achievements in photocatalytic synthesis of various industrial important chemicals via photo-oxidative and photo-reductive processes. The selective oxidation of alcohols and aromatics, epoxidation of alkenes, hydrogenation of gaseous molecules and hydrocarbons, and coupling reactions by means of various photocatalysts including metal oxides, supported plasmonic metal nanostructures, conjugated organic polymers, anchored homogeneous catalysts, and dye-sensitized heterostructures are discussed from a material perspective. In addition, fundamental understandings of reaction mechanisms and rational design of nanostructured photocatalysts for enhancing efficiency, selectivity, and stability are discussed in detail.\u003C\u002Fp\u003E","4183","Recent advances on the construction of diarylethene-based supramolecular metallacycles and metallacages via coordination-driven self-assembly","10.20517\u002Fcs.2021.05","1625673600","Yi Qin, ... Weihong Zhu","cs.2021.05","https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F5aca738e-1c59-461a-be61-43c7da541a1f\u002F4183.pdf","\u003Cp\u003EDuring the past few years, the construction of diarylethene (DAE)-based supramolecular metallacycles and metallacages has gained increasing attention due to their distinctive photophysical and photochemical properties and potential applications in magnetic switching, smart soft materials, photodynamic therapy, \u003Ci\u003Eetc\u003C\u002Fi\u003E. Surprisingly, no review on the construction of discrete DAE-based supramolecular metallacycles and metallacages via coordination-driven self-assembly has been summarized to the best of our knowledge. Considering the rapid development of this field, it is time to summarize the recent development of the construction of discrete DAE-containing polygons and polyhedra. In this review, the construction of diarylethene-based metallacycles and metallacages via coordination-driven self-assembly is briefly introduced. In addition, the properties and applications of these metallacycles and metallacages are also discussed.\u003C\u002Fp\u003E","4330","Future prospects in boron chemistry: new boron compounds and Lewis acids for catalysis and materials science","10.20517\u002Fcs.2021.11","1632326400","Perspective","cs.2021.11","https:\u002F\u002Ff.oaes.cc\u002Fxmlpdf\u002F9890435f-527b-49e9-a3c7-e774c1203901\u002F4330.pdf","\u003Cp\u003EBoron-containing compounds have a wide range of structures and rich and multifaceted reactivity patterns. As a result, these compounds are being increasingly used in organometallic, supramolecular, organic and inorganic chemistry, as well as in catalysis and materials science. This perspective describes recent ground-breaking studies and their implications for the future development of new catalysts and materials containing one or several trivalent boron atoms.\u003C\u002Fp\u003E","https:\u002F\u002Fimage.oaes.cc\u002Ff1e1803d-b9e2-4b34-a222-71aaba905fae\u002F4810-coverimg.jpg","https:\u002F\u002Fimage.oaes.cc\u002F3d9463d3-4395-4626-9fdb-59a3b6661f94\u002F5666-coverimg.jpg","https:\u002F\u002Fimage.oaes.cc\u002F83372d5a-3f62-4f3f-bdfd-7c5ebbd5bfae\u002F5446-coverimg.jpg","11","1227","https:\u002F\u002Fimage.oaes.cc\u002F1eaf238f-bf8c-47d6-8ee0-a65d921a9bc6\u002F5400-coverimg.jpg",1767153903,"CS_editor@oae-publish.com","Bao-Lian Su",1025,620,"Carbon Footprints","About","Editorial Policies","Journals","Academic Talks","5555","\u002Fcs\u002Fcontact_us","For Authors","For Reviewers","2769-5247 (Online)","https:\u002F\u002Ftwitter.com\u002FChem_Synth",true,"\u002F"));</script><script src="https://g.oaes.cc/oae/nuxt/47b9fdf.js" defer></script><script 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