NaK alloy: underrated liquid metal - Journal of Materials Chemistry A (RSC Publishing)

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Sci.; citation_volume=6; citation_pages=1355-1366;citation_publication_date=2020; " /> <meta content=" Liquid metals are poised to become a vital material for numerous challenges in science. The unique combination of metallicity and fluidity allows these materials to be used in inorganic synthesis, catalysis, electronics, photonics, robotics, and medicine. Among liquid metals, the sodium–potassium liquid alloy (NaK) is severely underutilised, mainly because of its high reactivity. However, in some cases, it is an essential tool for the synthesis and functionalisation of materials, and, in other cases, it can be reduced by stabilising NaK in inert matrices. Despite its disadvantages, NaK is characterised by some exceptional physical and chemical properties and combines not only metallicity and fluidity, but also the strongest reduction potential, which makes it useful for many scientific and industrial applications. This review aims to present and summarise the physical and chemical properties of NaK as well as current and potential applications of this alloy. We attempt to answer what new effects can be found on NaK systems and how the landscape of their application can be changed in case of its widespread introduction. This review shows why this is becoming possible today. We strongly believe that the study and use of this advanced material has the potential to transform entire branches of science and industry, such as materials synthesis, biomedicine, microelectronics, catalysis, and sustainable chemistry. 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Click to view all articles in this issue." title="Issue 43, 2022">Issue 43, 2022</a> </div> <nav aria-label="Article"> <ul class="article-nav__bar"> <li> <a href="/en/Content/ArticleLanding/2022/TA/D2TA07696A"> Previous <span class="v-mobile-hide--inline">Article</span> </a> </li> <li> <a href="/en/Content/ArticleLanding/2022/TA/D2TA05294F"> Next <span class="v-mobile-hide--inline">Article</span> </a> </li> </ul> </nav> <div class="list-control"> <div class="list__collection--image"> <div class="list__item"> <a href="/en/journals/journal/ta" class="list__item-link"> <div class="list__image-col"> <img src="/en/Image/Get?imageInfo.ImageType=CoverIssue&imageInfo.ImageIdentifier.SerCode=TA&imageInfo.ImageIdentifier.IssueId=TA010043" id="imgLoader" alt="" class="list__item-img" height="88"> </div> <div class="list__text-col"> <div class="list__item-label"> <span class="page-head__context">From the journal:</span> <h3 class="h--heading3 no-heading">Journal of Materials Chemistry A</h3> </div> </div> </a> </div> </div> </div> <br> </div> <article class="article-control"> <div class="article__title"> <h2 class="capsule__title fixpadv--m"> NaK alloy: underrated liquid metal </h2> <div class="fixpadv--m crossmark-button"> <button type="button" data-target="crossmark"><img width="150" height="32" src="https://crossmark-cdn.crossref.org/widget/v2.0/logos/CROSSMARK_Color_horizontal.svg" alt="Check for updates" /></button> </div> </div> <div class="article__authors"> <span class="article__author-link"> <a href="/en/results?searchtext=Author%3ASergei%20S.%20Leonchuk">Sergei S. Leonchuk</a>, <span class="orcid ver-b"><a target="_blank" title="Select to open ORCID record for Sergei S. Leonchuk (orcid.org/0000-0001-9733-862X) in a new window" href="https://orcid.org/0000-0001-9733-862X"><img src="https://www.rsc-cdn.org/pubs-core/2022.0.159/content/NewImages/orcid_16x16.png" alt="ORCID logo"></a></span> <span><sup><i>a</i></sup></span>   </span> <span class="article__author-link"> <a href="/en/results?searchtext=Author%3AAleksandra%20S.%20Falchevskaya">Aleksandra S. Falchevskaya</a>, <span class="orcid ver-b"><a target="_blank" title="Select to open ORCID record for Aleksandra S. Falchevskaya (orcid.org/0000-0003-1713-7313) in a new window" href="https://orcid.org/0000-0003-1713-7313"><img src="https://www.rsc-cdn.org/pubs-core/2022.0.159/content/NewImages/orcid_16x16.png" alt="ORCID logo"></a></span> <span><sup><i>a</i></sup></span>   </span> <span class="article__author-link"> <a href="/en/results?searchtext=Author%3AVitaly%20Nikolaev">Vitaly Nikolaev</a> <span class="orcid ver-b"><a target="_blank" title="Select to open ORCID record for Vitaly Nikolaev (orcid.org/0000-0001-7054-2655) in a new window" href="https://orcid.org/0000-0001-7054-2655"><img src="https://www.rsc-cdn.org/pubs-core/2022.0.159/content/NewImages/orcid_16x16.png" alt="ORCID logo"></a></span> <span><sup><i>a</i></sup></span>  and  </span> <span class="article__author-link"> <a href="/en/results?searchtext=Author%3AVladimir%20V.%20Vinogradov">Vladimir V. Vinogradov</a> <span class="orcid ver-b"><a target="_blank" title="Select to open ORCID record for Vladimir V. Vinogradov (orcid.org/0000-0002-5081-4876) in a new window" href="https://orcid.org/0000-0002-5081-4876"><img src="https://www.rsc-cdn.org/pubs-core/2022.0.159/content/NewImages/orcid_16x16.png" alt="ORCID logo"></a></span> *<span><sup><i>a</i></sup></span>   </span> </div> <div class="drawer-control fixpadv--m"> <a href="#" role="button" id="btnAuthorAffiliations" aria-expanded="false" aria-controls="pnlAuthorAffiliations" class="drawer__handle"> <span class="drawer__icon"></span> Author affiliations </a> <div class="drawer__content" id="pnlAuthorAffiliations" aria-labelledby="btnAuthorAffiliations"> <div> <p class="article__author-affiliation"> <span> * </span> <span> Corresponding authors </span> </p> <p class="article__author-affiliation"> <span> <sup>a</sup> </span> <span> ITMO University, International Institute “Solution Chemistry of Advanced Materials and Technologies” (SCAMT), Saint Petersburg 191002, Russia <br /> <b>E-mail:</b> <a href="mailto:vinogradov@scamt-itmo.ru" title="vinogradov@scamt-itmo.ru">vinogradov@scamt-itmo.ru</a> </span> </p> </div> </div> </div> <h3 class="h--heading3 article-abstract__heading">Abstract</h3> <div class="capsule__column-wrapper"> <div class="capsule__text"> <p xmlns="http://www.rsc.org/schema/rscart38">Liquid metals are poised to become a vital material for numerous challenges in science. The unique combination of metallicity and fluidity allows these materials to be used in inorganic synthesis, catalysis, electronics, photonics, robotics, and medicine. Among liquid metals, the sodium–potassium liquid alloy (NaK) is severely underutilised, mainly because of its high reactivity. However, in some cases, it is an essential tool for the synthesis and functionalisation of materials, and, in other cases, it can be reduced by stabilising NaK in inert matrices. Despite its disadvantages, NaK is characterised by some exceptional physical and chemical properties and combines not only metallicity and fluidity, but also the strongest reduction potential, which makes it useful for many scientific and industrial applications. This review aims to present and summarise the physical and chemical properties of NaK as well as current and potential applications of this alloy. We attempt to answer what new effects can be found on NaK systems and how the landscape of their application can be changed in case of its widespread introduction. This review shows why this is becoming possible today. We strongly believe that the study and use of this advanced material has the potential to transform entire branches of science and industry, such as materials synthesis, biomedicine, microelectronics, catalysis, and sustainable chemistry.</p> </div> <div class="capsule__article-image fixpadv--s"> <img src="/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D2TA06882F&imageInfo.ImageIdentifier.Year=2022" alt="Graphical abstract: NaK alloy: underrated liquid metal" /> </div> </div> <p></p> <div class="pnl pnl--border pnl--drop"> <div class="list-control"> <ul class="list__collection"> <li class="list__item"> This article is part of the themed collection: <a href="/en/journals/articlecollectionlanding?sercode=ta&themeid=a9e70e12-8fd2-49fe-9ee6-ce45faf3d996">Journal of Materials Chemistry A Recent Review Articles</a> </li> </ul> </div> </div> <div id="pnlArticleAccess" class="article-access fixpadt--xxl" style="display: none; border: 0;"> <div class="article-access__inner" style="background-color: #F1F1F3;"> <div class="article-access__head fixpad--s"> You have access to this article </div> <div class="fixpad--xl"> <div id="pnlViewFullArticleButton" class="paywall__body text--centered"> <div id="pnlArticleLoading"> <span id="thtmlLoadingMessage"> <img src="https://www.rsc-cdn.org/pubs-core/2022.0.159/content/NewImages/Ajax-GA-Loader.gif" alt="" class="ver-m" /> Please wait while we load your content... </span> <span id="thtmlErrorMessage" style="display: none;"> Something went wrong. <a href="#" id="btnTryAgain">Try again?</a> </span> </div> </div> </div> </div> </div> <div id="pnlArticleContent" class="t-html"> <div id="pnlArticleContentLoaded"> </div> </div> </article> </section> </div> <div class="layout__panel layout__panel--secondary layout__panel--40 layout__panel--filled"> <section class="layout__content"> <input id="contentType" name="contentType" type="hidden" value="" /> <div class="tab-control"> <div class="tab__nav" role="tablist" aria-label="Article"> <div class="tab__item" role="none"> <a href="#pnlAbstract" class="tab__btn selected" role="tab" id="btnAbstract" aria-selected="true" aria-controls="pnlAbstract">About</a> </div> <div class="tab__item" role="none"> <a href="#pnlCitation" class="tab__btn" role="tab" id="btnCitation" aria-selected="false" aria-controls="pnlCitation">Cited by</a> </div> <div class="tab__item" role="none"> <a href="#pnlRelatedContent" class="tab__btn" role="tab" id="btnRelatedContent" aria-selected="false" aria-controls="pnlRelatedContent">Related</a> </div> </div> <div class="tab__panel open" role="tabpanel" id="pnlAbstract" aria-hidden="false" aria-labelledby="btnAbstract" data-loaded="true"> <div class="fixpadv--m"> <div id="divAbout"> <div id="DownloadOption" class="autopad--h fixpadv--l" style="min-height: 150px;"> <div class="text--centered"> <a href="#" class="btn btn--cta btn--disabled btn--block btn--stack btn-icon btn-icon--loading"> Download options <span class="btn-info">Please wait...</span> </a> </div> </div> <div class="autopad--h"> <h2 class="h--heading3">Article information</h2> <dl class="definition-list"> <div class="c doi-link"> <dt class="sr-only">DOI</dt> <dd class="c__24"><a class="text--small" title="Link to landing page via DOI" href="https://doi.org/10.1039/D2TA06882F">https://doi.org/10.1039/D2TA06882F</a></dd> </div> <div class="c fixpadt--l line-separator"> <dt class="c__10"><strong>Article type</strong></dt> <dd class="c__14">Review Article</dd> </div> <div class="c fixpadt--l"> <dt class="c__10">Submitted</dt> <dd class="c__14">30 Aug 2022</dd> </div> <div class="c fixpadt--l"> <dt class="c__10">Accepted</dt> <dd class="c__14">14 Oct 2022</dd> </div> <div class="c fixpadt--l"> <dt class="c__10">First published</dt> <dd class="c__14">17 Oct 2022</dd> </div> </dl> <div class="c fixpadt--l line-separator"> <div class="c__10"> <h3 class="definition-label"> <label for="ResultAbstractFormat"><span class="sr-only">Download</span> Citation</label> </h3> </div> <div class="c__14"> <i><strong>J. 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NaK alloy: underrated liquid metal - Journal of Materials Chemistry A (RSC Publishing)