CINXE.COM

<!DOCTYPE html><html><head><title>Advances in Inorganic Chemistry: Homogeneous Biomimetic Oxidation Catalysis - Rudi van Eldik, Jan Reedijk - Google Books</title><link rel="stylesheet" href="/books/css/_ff77d0f0508c7e0bad470e7d6b7f28fa/kl_viewport_kennedy_full_bundle.css" type="text/css" /><link rel="stylesheet"href="https://fonts.googleapis.com/css2?family=Product+Sans:wght@400"><script src="/books/javascript/v2_ff77d0f0508c7e0bad470e7d6b7f28fa__en.js"></script><script>_OC_Hooks = ["_OC_Page", "_OC_SearchReload", "_OC_TocReload", "_OC_EmptyFunc", "_OC_SearchPage", "_OC_QuotePage" ];for (var _OC_i = 0; _OC_i < _OC_Hooks.length; _OC_i++) {eval("var " + _OC_Hooks[_OC_i] + ";");}function _OC_InitHooks () {for (var i = 0; i < _OC_Hooks.length; i++) {var func = arguments[i];eval( _OC_Hooks[i] + " = func;");}}</script><link rel="canonical" href="https://books.google.com/books/about/Advances_in_Inorganic_Chemistry.html?id=UgNp8-wq-aAC"/><meta property="og:url" content="https://books.google.com/books/about/Advances_in_Inorganic_Chemistry.html?id=UgNp8-wq-aAC"/><meta name="title" content="Advances in Inorganic Chemistry"/><meta name="description" content="Advances in Inorganic Chemistry Volume 58 focuses on homogeneous biomimetic oxidation catalysis. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. Contributions include diversity-based approaches to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by copper and manganese complexes; influences of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations by dinuclear and trinuclear copper complexes. In the final contribution the authors focus on green oxidation of alcohols using biomimetic copper complexes and enzymes as catalysts. Volume 58 provides another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry.* Includes new information on the important advances in inorganic and bioinorganic chemistry * Each chapter is fully referenced * Contains comprehensive reviews written by leading experts in the field"/><meta property="og:title" content="Advances in Inorganic Chemistry"/><meta property="og:type" content="book"/><meta property="og:site_name" content="Google Books"/><meta property="og:image" content="https://books.google.com.sg/books/content?id=UgNp8-wq-aAC&printsec=frontcover&img=1&zoom=1&edge=curl&imgtk=AFLRE71sC_exH1Benu-ailaNWnew5z5UgOI1RgbR4sjV89HdXE721g7PetcoZgvb_YiBIdc4rlWatLwrS4Qfjp5xa7mPwLRJFQODKZlCwmSnZnoLG8CgtL3fYvqjayU-db2XMXzJvCeC"/><link rel="image_src" href="https://books.google.com.sg/books/content?id=UgNp8-wq-aAC&printsec=frontcover&img=1&zoom=1&edge=curl&imgtk=AFLRE71sC_exH1Benu-ailaNWnew5z5UgOI1RgbR4sjV89HdXE721g7PetcoZgvb_YiBIdc4rlWatLwrS4Qfjp5xa7mPwLRJFQODKZlCwmSnZnoLG8CgtL3fYvqjayU-db2XMXzJvCeC"/><script></script><style>#gbar,#guser{font-size:13px;padding-top:1px !important;}#gbar{height:22px}#guser{padding-bottom:7px !important;text-align:right}.gbh,.gbd{border-top:1px solid #c9d7f1;font-size:1px}.gbh{height:0;position:absolute;top:24px;width:100%}@media all{.gb1{height:22px;margin-right:.5em;vertical-align:top}#gbar{float:left}}a.gb1,a.gb4{text-decoration:underline !important}a.gb1,a.gb4{color:#00c !important}.gbi .gb4{color:#dd8e27 !important}.gbf .gb4{color:#900 !important} #gbar { padding:.3em .6em !important;}</style></head><body class=""><div id=gbar><nobr><a target=_blank class=gb1 href="https://www.google.com.sg/search?tab=pw">Search</a> <a target=_blank class=gb1 href="https://www.google.com.sg/imghp?hl=en&tab=pi">Images</a> <a target=_blank class=gb1 href="https://maps.google.com.sg/maps?hl=en&tab=pl">Maps</a> <a target=_blank class=gb1 href="https://play.google.com/?hl=en&tab=p8">Play</a> <a target=_blank class=gb1 href="https://www.youtube.com/?tab=p1">YouTube</a> <a target=_blank class=gb1 href="https://news.google.com/?tab=pn">News</a> <a target=_blank class=gb1 href="https://mail.google.com/mail/?tab=pm">Gmail</a> <a target=_blank class=gb1 href="https://drive.google.com/?tab=po">Drive</a> <a target=_blank class=gb1 style="text-decoration:none" href="https://www.google.com.sg/intl/en/about/products?tab=ph"><u>More</u> »</a></nobr></div><div id=guser width=100%><nobr><span id=gbn class=gbi></span><span id=gbf class=gbf></span><span id=gbe></span><a target=_top id=gb_70 href="https://www.google.com/accounts/Login?service=print&continue=https://books.google.com.sg/books%3Fid%3DUgNp8-wq-aAC%26q%3Delectron%2Btransfer%26dq%3Dsubject:%2522Science%2BChemistry%2522%26source%3Dgbs_word_cloud_r%26hl%3Den&hl=en&ec=GAZACg" class=gb4>Sign in</a></nobr></div><div class=gbh style=left:0></div><div class=gbh style=right:0></div><div role="alert" style="position: absolute; left: 0; right: 0;"><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&q=electron+transfer&dq=subject:%22Science+Chemistry%22&source=gbs_word_cloud_r&hl=en&output=html_text" title="Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader."><img border="0" src="//www.google.com/images/cleardot.gif"alt="Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader."></a></div><div class="kd-appbar"><h2 class="kd-appname"><a href="/books">Books</a></h2><div class="kd-buttonbar left" id="left-toolbar-buttons"><a id="appbar-view-print-sample-link" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&printsec=frontcover&vq=electron+transfer&source=gbs_vpt_read"></a><a id="appbar-view-ebook-sample-link" href="https://play.google.com/books/reader?id=UgNp8-wq-aAC&source=gbs_vpt_read"></a><a id="appbar-patents-prior-art-finder-link" href=""></a><a id="appbar-patents-discuss-this-link" href="" data-is-grant=""></a><a id="appbar-read-patent-link" href=""></a><a id="appbar-download-pdf-link" href=""></a></div><div class="kd-buttonbar right" id="right-toolbar-buttons"></div></div><div style="display: none"><ol id="ofe-gear-menu-contents" class="gbmcc"><li class="gbe gbmtc"><a class="gbmt goog-menuitem-content" id="" href="https://www.google.com/accounts/Login?service=print&continue=https://books.google.com.sg/books%3Fop%3Dlibrary&hl=en">My library</a></li><li class="gbe gbmtc"><a class="gbmt goog-menuitem-content" id="" href="http://books.google.com.sg/support/topic/4359341?hl=en-SG">Help</a></li><li class="gbe gbmtc"><a class="gbmt goog-menuitem-content" id="" href="https://books.google.com.sg/advanced_book_search?q=subject:%22Science+Chemistry%22">Advanced Book Search</a></li></ol></div><div id="volume-main"><div id="volume-left"><div id=menu_container ><div id="menu_scroll_wrapper"><div id="menu_scroll" role="navigation"><div id="gb-get-book-container"><a href="https://play.google.com/store/books/details?id=UgNp8-wq-aAC&rdid=book-UgNp8-wq-aAC&rdot=1&source=gbs_vpt_read&pcampaignid=books_booksearch_viewport" id="gb-get-book-content">Buy eBook - SGD 326.69</a></div><p id="gb-buy-options-trigger" class="gb-buy-options-link">Get this book in print</p><h3 class=about_title><a name="buy_anchor"></a></h3><div id=buy class=about_content><div id=buy_v><ul style="list-style-type: none; padding-left: 0; margin: 0;"><li><a style="white-space:normal" href="https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9" dir=ltr onMouseOver="this.href='https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttps://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9\x26usg\x3dAOvVaw3t0n6E_aFSl4BwFIeW_SC9\x26source\x3dgbs_buy_r';return true"><span dir=ltr>Buy Direct from Elsevier</span></a></li><li><a style="white-space:normal" href="http://www.amazon.com/gp/search?index=books&linkCode=qs&keywords=9780080462172" dir=ltr onMouseOver="this.href='http://www.amazon.com/gp/search?index\x3dbooks\x26linkCode\x3dqs\x26keywords\x3d9780080462172';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttp://www.amazon.com/gp/search%3Findex%3Dbooks%26linkCode%3Dqs%26keywords%3D9780080462172\x26usg\x3dAOvVaw1zDPXY4buAsPqNIqWJvHq8\x26source\x3dgbs_buy_r';return true"><span dir=ltr>Amazon.com</span></a></li><li><a style="white-space:normal" href="http://www.mphonline.com/books/nsearch.aspx?do=detail&pcode=9780080462172" dir=ltr onMouseOver="this.href='http://www.mphonline.com/books/nsearch.aspx?do\x3ddetail\x26pcode\x3d9780080462172';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttp://www.mphonline.com/books/nsearch.aspx%3Fdo%3Ddetail%26pcode%3D9780080462172\x26usg\x3dAOvVaw2ex_OvBz-jZwZdrNm3b5Z6\x26source\x3dgbs_buy_r';return true"><span dir=ltr>MPH</span></a></li><li><a style="white-space:normal" href="https://www.popular.com.sg/catalogsearch/result/?q=9780080462172" dir=ltr onMouseOver="this.href='https://www.popular.com.sg/catalogsearch/result/?q\x3d9780080462172';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttps://www.popular.com.sg/catalogsearch/result/%3Fq%3D9780080462172\x26usg\x3dAOvVaw31RPIQA7d8S3dmU-l_v8sC\x26source\x3dgbs_buy_r';return true"><span dir=ltr>Popular</span></a></li><li><hr style="margin-right: 20%; color: #666;"></li><li><a style="white-space:normal" href="https://books.google.com.sg/url?id=UgNp8-wq-aAC&pg=PA122&q=http://www.worldcat.org/oclc/1113213446&clientid=librarylink&usg=AOvVaw2QZSU5523uKSBMxI0WVSG-&source=gbs_buy_r"><span dir=ltr>Find in a library</span></a></li><li><a class="secondary" style="white-space:normal" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&sitesec=buy&source=gbs_buy_r" id="get-all-sellers-link"><span dir=ltr>All sellers</span> »</a></li></ul></div></div><div class=menu id=menu><div class="menu_content" style="margin-bottom:6px"><div style="margin-bottom:4px"><div class="sidebarnav"><table border="0" cellpadding="0" cellspacing="0"><tr><td><div class="sidebarcover"><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&printsec=frontcover&vq=electron+transfer" onclick="_OC_Page('PP1',this.href); return false;"><img src="https://books.google.com.sg/books/content?id=UgNp8-wq-aAC&printsec=frontcover&img=1&zoom=5&edge=curl&imgtk=AFLRE71Dhq5wIlqpCUwAwzP9e6sc-ekfc6newuGlFrgfo9kGHZTwpkXiYamHq8G_rnOoexVK1m8ZY25Ps2Y12SdQ9NbQfVQvkBT0Hcogb_MsPvzbkiZkG1F39SubH-Uz8994s1VIvLdU" alt="Front Cover" title="Front Cover" height=80 border=1 id=summary-frontcover ></a></div></td><td></td></tr></table></div><div style="clear:both"></div></div><div id="volume-info-sidebar"><h1 class="gb-volume-title" dir=ltr>Advances in Inorganic Chemistry: Homogeneous Biomimetic Oxidation Catalysis</h1><span class="addmd">By Rudi van Eldik, Jan Reedijk</span></div><div style="margin-bottom:3px"><form action=/books id=search_form style="margin:0px;padding:0px;" method=get> <input type=hidden name="id" value="UgNp8-wq-aAC"><input type=hidden name="dq" value="subject:"Science Chemistry""><table cellpadding=0 cellspacing=0 class="swv-table"><tr><td class="swv-td-search"><span><input id=search_form_input type=text maxlength=1024 class="text_flat swv-input-search" aria-label="Search in this book" name=q value="" title="Go" accesskey=i></span></td><td class="swv-td-space"><div> </div></td><td><input type=submit value="Go"></td></tr></table><script type="text/javascript">if (window['_OC_autoDir']) {_OC_autoDir('search_form_input');}</script></form></div><div><p><a id="sidebar-atb-link" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&vq=electron+transfer&dq=subject:%22Science+Chemistry%22&source=gbs_navlinks_s"><span dir=ltr>About this book</span></a></p></div></div></div><div><div id="navbarContainer" class="gb-navbar"></div><script>_OC_InitNavbar({"child_node":[{"title":"My library","url":"https://books.google.com.sg/books?uid=114584440181414684107\u0026source=gbs_lp_bookshelf_list","id":"my_library","collapsed":true},{"title":"My History","url":"","id":"my_history","collapsed":true}],"highlighted_node_id":""});</script><a href="/intl/en/googlebooks/tos.html" target="_blank">Terms of Service</a><h3 class=about_title><a name="pub_info_anchor"></a></h3><div id=pub_info class=about_content><div id=pub_info_v><table cellspacing=0><tr><td><a href="https://books.google.com.sg/url?id=UgNp8-wq-aAC&pg=PA122&q=https://www.elsevier.com/books-and-journals&clientid=ca-print-elsevier-academic_press&linkid=1&usg=AOvVaw0gzjgx6fEefU16_Ns97Irz&source=gbs_pub_info_r" style="text-decoration:none"><img width=25 height=35 border=0 src="https://pagead2.googlesyndication.com/pagead/imgad?id=CMSjweqOm5D25gEQJRgyMgj-lPFy73claA" alt="Elsevier"></a><tr><td style="font-size:84.6%;color:#666666">Pages displayed by permission of <a class=link_aux href="https://books.google.com.sg/url?id=UgNp8-wq-aAC&pg=PA122&q=https://www.elsevier.com/books-and-journals&clientid=ca-print-elsevier-academic_press&linkid=1&usg=AOvVaw0gzjgx6fEefU16_Ns97Irz&source=gbs_pub_info_r">Elsevier</a>. <a style="color:#7777cc;white-space:normal" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&printsec=copyright&vq=electron+transfer&source=gbs_pub_info_r">Copyright</a>. </table></div></div></div></div></div></div></div><div id="volume-center"><div id="scroll_atb" role="main"><div id="toolbar_container"><div style="float:left;white-space:nowrap"><table cellpadding=0 cellspacing=0><tr><td id="l_toolbar"></td><td class=toolbar-pc-cell><table cellpadding=0 cellspacing=0><tr><td class=no-jump-cell align=right><span id=page_label style="margin-right:.5em">Page 122</span></td><td class=arrow style="padding-right:2px"><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&pg=PA121&lpg=PA122&focus=viewport&vq=electron+transfer&dq=subject:%22Science+Chemistry%22" onclick="_OC_EmptyFunc(this.href); return false;"><div class=pagination><div id=prev_btn alt="Previous Page" title="Previous Page" class="SPRITE_pagination_v2_left"></div></div></a></td><td class=arrow><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&pg=PA123&lpg=PA122&focus=viewport&vq=electron+transfer&dq=subject:%22Science+Chemistry%22" onclick="_OC_EmptyFunc(this.href); return false;"><div class=pagination><div id=next_btn alt="Next Page" title="Next Page" class="SPRITE_pagination_v2_right"></div></div></a></td></tr></table></td><td>  </td><td id=view_toolbar></td><td id=view_new></td></tr></table></div><div style="float:right"><table cellpadding=0 cellspacing=0><tr><td></td><td id="r_toolbar" style="white-space:nowrap"></td></tr></table></div><div style="clear:both"></div></div><div id="search_bar"></div><div class="gback"><div id="viewport" class="viewport" tabindex="0"><a name="page" accesskey="c"></a><table class="viewport-table" id="container" align="center" cellpadding="0" cellspacing="0"><tr><td valign="top" align="center"><noscript><style type=text/css>.imgg { width:575px;height:835px;background:#eee;padding-bottom:25px}</style><div class=imgg><div align=center><table border=0 cellpadding=0 cellspacing=0 width=500 align=center style="margin-top:2em"><tr><td rowspan=2 valign=top style="width:9px;background:#fff url('/googlebooks/bbl_l.gif') top left repeat-y"><img src="/googlebooks/bbl_tl.gif" width=9 height=7 alt=""></td><td style="background:url('/googlebooks/bbl_t.gif') top left repeat-x"><img width=1 height=7 alt=""></td><td rowspan=2 valign=top style="width:10px;background:#fff url('/googlebooks/bbl_r.gif') top right repeat-y"><img src="/googlebooks/bbl_tr.gif" width=10 height=7 alt=""></td></tr><tr><td align=center style="background:#ff9;text-align:center;line-height:1.2em"><div style="margin:1em"><img width=60 height=60 align=absmiddle src="/googlebooks/restricted_logo.gif" alt=""> <span style="font-weight:bold;font-size:1.2em"><br>Restricted Page</span></div><div style="margin:1em" align=left>You have reached your viewing limit for this book (<a href=https://books.google.com.sg/support/answer/43729?topic=9259&hl=en>why?</a>).</div></td></tr><tr><td><img src="/googlebooks/bbl_bl.gif" width=9 height=9 alt=""></td><td style="background:url('/googlebooks/bbl_b.gif') bottom left repeat-x"><img width=1 height=9 alt=""></td><td><img src="/googlebooks/bbl_br.gif" width=10 height=9 alt=""></td></tr></table></div></div></noscript></td></tr></table></div></div><script>_OC_addFlags({Host:"https://books.google.com.sg/", IsZipitFolderCollectionEnabled:1, IsBooksUnifiedLeftNavEnabled:1, IsBooksRentalEnabled:1, IsBrowsingHistoryEnabled:1});_OC_Run({"page":[{"pid":"PP1","flags":32,"order":0},{"pid":"PR3","order":3,"title":"iii"},{"pid":"PR4","order":4,"title":"iv"},{"pid":"PR5","order":5,"title":"v"},{"pid":"PR6","order":6,"title":"vi"},{"pid":"PR7","order":7,"title":"vii"},{"pid":"PR8","order":8,"title":"viii"},{"pid":"PA1","order":9,"title":"1"},{"pid":"PA2","order":10,"title":"2"},{"pid":"PA3","order":11,"title":"3"},{"pid":"PA4","order":12,"title":"4"},{"pid":"PA5","order":13,"title":"5"},{"pid":"PA6","order":14,"title":"6"},{"pid":"PA7","order":15,"title":"7"},{"pid":"PA8","order":16,"title":"8"},{"pid":"PA9","order":17,"title":"9"},{"pid":"PA10","order":18,"title":"10"},{"pid":"PA11","order":19,"title":"11"},{"pid":"PA12","order":20,"title":"12"},{"pid":"PA13","order":21,"title":"13"},{"pid":"PA14","order":22,"title":"14"},{"pid":"PA15","order":23,"title":"15"},{"pid":"PA16","order":24,"title":"16"},{"pid":"PA17","order":25,"title":"17"},{"pid":"PA18","order":26,"title":"18"},{"pid":"PA19","order":27,"title":"19"},{"pid":"PA20","order":28,"title":"20"},{"pid":"PA21","order":29,"title":"21"},{"pid":"PA22","order":30,"title":"22"},{"pid":"PA23","order":31,"title":"23"},{"pid":"PA24","order":32,"title":"24"},{"pid":"PA25","order":33,"title":"25"},{"pid":"PA26","order":34,"title":"26"},{"pid":"PA27","order":35,"title":"27"},{"pid":"PA28","order":36,"title":"28"},{"pid":"PA29","order":37,"title":"29"},{"pid":"PA30","order":38,"title":"30"},{"pid":"PA31","order":39,"title":"31"},{"pid":"PA32","order":40,"title":"32"},{"pid":"PA33","order":41,"title":"33"},{"pid":"PA34","order":42,"title":"34"},{"pid":"PA35","order":43,"title":"35"},{"pid":"PA36","order":44,"title":"36"},{"pid":"PA37","order":45,"title":"37"},{"pid":"PA38","order":46,"title":"38"},{"pid":"PA39","order":47,"title":"39"},{"pid":"PA40","order":48,"title":"40"},{"pid":"PA41","order":49,"title":"41"},{"pid":"PA42","order":50,"title":"42"},{"pid":"PA43","order":51,"title":"43"},{"pid":"PA44","order":52,"title":"44"},{"pid":"PA45","order":53,"title":"45"},{"pid":"PA46","order":54,"title":"46"},{"pid":"PA47","order":55,"title":"47"},{"pid":"PA48","order":56,"title":"48"},{"pid":"PA49","order":57,"title":"49"},{"pid":"PA50","order":58,"title":"50"},{"pid":"PA51","order":59,"title":"51"},{"pid":"PA52","order":60,"title":"52"},{"pid":"PA53","order":61,"title":"53"},{"pid":"PA54","order":62,"title":"54"},{"pid":"PA55","order":63,"title":"55"},{"pid":"PA56","order":64,"title":"56"},{"pid":"PA57","order":65,"title":"57"},{"pid":"PA58","order":66,"title":"58"},{"pid":"PA59","order":67,"title":"59"},{"pid":"PA60","order":68,"title":"60"},{"pid":"PA61","order":69,"title":"61"},{"pid":"PA62","order":70,"title":"62"},{"pid":"PA63","order":71,"title":"63"},{"pid":"PA64","order":72,"title":"64"},{"pid":"PA65","order":73,"title":"65"},{"pid":"PA66","order":74,"title":"66"},{"pid":"PA67","order":75,"title":"67"},{"pid":"PA68","order":76,"title":"68"},{"pid":"PA69","order":77,"title":"69"},{"pid":"PA70","order":78,"title":"70"},{"pid":"PA71","order":79,"title":"71"},{"pid":"PA72","order":80,"title":"72"},{"pid":"PA73","order":81,"title":"73"},{"pid":"PA74","order":82,"title":"74"},{"pid":"PA75","order":83,"title":"75"},{"pid":"PA76","order":84,"title":"76"},{"pid":"PA77","order":85,"title":"77"},{"pid":"PA78","order":86,"title":"78"},{"pid":"PA79","order":87,"title":"79"},{"pid":"PA80","order":88,"title":"80"},{"pid":"PA81","order":89,"title":"81"},{"pid":"PA82","order":90,"title":"82"},{"pid":"PA83","order":91,"title":"83"},{"pid":"PA84","order":92,"title":"84"},{"pid":"PA85","order":93,"title":"85"},{"pid":"PA86","order":94,"title":"86"},{"pid":"PA87","order":95,"title":"87"},{"pid":"PA88","order":96,"title":"88"},{"pid":"PA89","order":97,"title":"89"},{"pid":"PA90","order":98,"title":"90"},{"pid":"PA91","order":99,"title":"91"},{"pid":"PA92","order":100,"title":"92"},{"pid":"PA93","order":101,"title":"93"},{"pid":"PA94","order":102,"title":"94"},{"pid":"PA95","order":103,"title":"95"},{"pid":"PA96","order":104,"title":"96"},{"pid":"PA97","order":105,"title":"97"},{"pid":"PA98","order":106,"title":"98"},{"pid":"PA99","order":107,"title":"99"},{"pid":"PA100","order":108,"title":"100"},{"pid":"PA101","order":109,"title":"101"},{"pid":"PA102","order":110,"title":"102"},{"pid":"PA103","order":111,"title":"103"},{"pid":"PA104","order":112,"title":"104"},{"pid":"PA105","order":113,"title":"105"},{"pid":"PA106","order":114,"title":"106"},{"pid":"PA107","order":115,"title":"107"},{"pid":"PA108","order":116,"title":"108"},{"pid":"PA109","order":117,"title":"109"},{"pid":"PA110","order":118,"title":"110"},{"pid":"PA111","order":119,"title":"111"},{"pid":"PA112","order":120,"title":"112"},{"pid":"PA113","order":121,"title":"113"},{"pid":"PA114","order":122,"title":"114"},{"pid":"PA115","order":123,"title":"115"},{"pid":"PA116","order":124,"title":"116"},{"pid":"PA117","order":125,"title":"117"},{"pid":"PA118","order":126,"title":"118"},{"pid":"PA119","order":127,"title":"119"},{"pid":"PA120","order":128,"title":"120"},{"pid":"PA121","flags":8,"order":129,"title":"121"},{"pid":"PA122","flags":8,"order":130,"title":"122"},{"pid":"PA123","flags":8,"order":131,"title":"123"},{"pid":"PA124","flags":8,"order":132,"title":"124"},{"pid":"PA125","flags":8,"order":133,"title":"125"},{"pid":"PA126","order":134,"title":"126"},{"pid":"PA127","order":135,"title":"127"},{"pid":"PA128","order":136,"title":"128"},{"pid":"PA129","order":137,"title":"129"},{"pid":"PA130","order":138,"title":"130"},{"pid":"PA131","order":139,"title":"131"},{"pid":"PA132","order":140,"title":"132"},{"pid":"PA133","order":141,"title":"133"},{"pid":"PA134","order":142,"title":"134"},{"pid":"PA135","order":143,"title":"135"},{"pid":"PA136","order":144,"title":"136"},{"pid":"PA137","order":145,"title":"137"},{"pid":"PA138","order":146,"title":"138"},{"pid":"PA139","order":147,"title":"139"},{"pid":"PA140","order":148,"title":"140"},{"pid":"PA141","order":149,"title":"141"},{"pid":"PA142","order":150,"title":"142"},{"pid":"PA143","order":151,"title":"143"},{"pid":"PA145","order":153,"title":"145"},{"pid":"PA146","order":154,"title":"146"},{"pid":"PA148","order":156,"title":"148"},{"pid":"PA149","order":157,"title":"149"},{"pid":"PA150","order":158,"title":"150"},{"pid":"PA151","order":159,"title":"151"},{"pid":"PA152","order":160,"title":"152"},{"pid":"PA155","order":163,"title":"155"},{"pid":"PA156","order":164,"title":"156"},{"pid":"PA160","order":168,"title":"160"},{"pid":"PA162","order":170,"title":"162"},{"pid":"PA164","order":172,"title":"164"},{"pid":"PA167","order":175,"title":"167"},{"pid":"PA171","order":179,"title":"171"},{"pid":"PA172","order":180,"title":"172"},{"pid":"PA175","order":183,"title":"175"},{"pid":"PA176","order":184,"title":"176"},{"pid":"PA177","order":185,"title":"177"},{"pid":"PA178","order":186,"title":"178"},{"pid":"PA181","order":189,"title":"181"},{"pid":"PA182","order":190,"title":"182"},{"pid":"PA183","order":191,"title":"183"},{"pid":"PA184","order":192,"title":"184"},{"pid":"PA185","order":193,"title":"185"},{"pid":"PA186","order":194,"title":"186"},{"pid":"PA187","order":195,"title":"187"},{"pid":"PA188","order":196,"title":"188"},{"pid":"PA189","order":197,"title":"189"},{"pid":"PA191","order":199,"title":"191"},{"pid":"PA192","order":200,"title":"192"},{"pid":"PA193","order":201,"title":"193"},{"pid":"PA195","order":203,"title":"195"},{"pid":"PA196","order":204,"title":"196"},{"pid":"PA198","order":206,"title":"198"},{"pid":"PA199","order":207,"title":"199"},{"pid":"PA201","order":209,"title":"201"},{"pid":"PA202","order":210,"title":"202"},{"pid":"PA203","order":211,"title":"203"},{"pid":"PA204","order":212,"title":"204"},{"pid":"PA205","order":213,"title":"205"},{"pid":"PA206","order":214,"title":"206"},{"pid":"PA207","order":215,"title":"207"},{"pid":"PA208","order":216,"title":"208"},{"pid":"PA210","order":218,"title":"210"},{"pid":"PA211","order":219,"title":"211"},{"pid":"PA212","order":220,"title":"212"},{"pid":"PA215","order":223,"title":"215","h":396},{"pid":"PA216","order":224,"title":"216"},{"pid":"PA218","order":226,"title":"218"},{"pid":"PA219","order":227,"title":"219"},{"pid":"PA220","order":228,"title":"220"},{"pid":"PA221","order":229,"title":"221"},{"pid":"PA222","order":230,"title":"222"},{"pid":"PA224","order":232,"title":"224"},{"pid":"PA225","order":233,"title":"225"},{"pid":"PA227","order":235,"title":"227"},{"pid":"PA228","order":236,"title":"228"},{"pid":"PA229","order":237,"title":"229"},{"pid":"PA230","order":238,"title":"230"},{"pid":"PA231","order":239,"title":"231"},{"pid":"PA233","order":241,"title":"233"},{"pid":"PA234","order":242,"title":"234"},{"pid":"PA235","order":243,"title":"235"},{"pid":"PA236","order":244,"title":"236"},{"pid":"PA237","order":245,"title":"237"},{"pid":"PA238","order":246,"title":"238"},{"pid":"PA240","order":248,"title":"240"},{"pid":"PA241","order":249,"title":"241"},{"pid":"PA243","order":251,"title":"243"},{"pid":"PA244","order":252,"title":"244"},{"pid":"PA245","order":253,"title":"245"},{"pid":"PA248","order":256,"title":"248"},{"pid":"PA250","order":258,"title":"250"},{"pid":"PA252","order":260,"title":"252"},{"pid":"PA253","order":261,"title":"253","h":396},{"pid":"PA255","order":263,"title":"255"},{"pid":"PA257","order":265,"title":"257"},{"pid":"PA258","order":266,"title":"258"},{"pid":"PA260","order":268,"title":"260","h":396},{"pid":"PA262","order":270,"title":"262"},{"pid":"PA265","order":273,"title":"265"},{"pid":"PA266","order":274,"title":"266"},{"pid":"PA267","order":275,"title":"267","h":396},{"pid":"PA268","order":276,"title":"268"},{"pid":"PA270","order":278,"title":"270"},{"pid":"PA271","order":279,"title":"271"},{"pid":"PA272","order":280,"title":"272"},{"pid":"PA273","order":281,"title":"273"},{"pid":"PA274","order":282,"title":"274"},{"pid":"PA275","order":283,"title":"275","h":396},{"pid":"PA280","order":288,"title":"280"},{"pid":"PA281","order":289,"title":"281"},{"pid":"PA282","order":290,"title":"282"},{"pid":"PA283","order":291,"title":"283"},{"pid":"PA284","order":292,"title":"284"},{"pid":"PA285","order":293,"title":"285"},{"pid":"PA286","order":294,"title":"286"},{"pid":"PA287","order":295,"title":"287"},{"pid":"PA288","order":296,"title":"288"},{"pid":"PA289","order":297,"title":"289"}],"prefix":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026lpg=PA122\u0026vq=electron+transfer\u0026dq=subject:%22Science+Chemistry%22"},{"fullview":false,"page_width":575,"page_height":835,"font_height":12,"first_content_page":9,"disable_twopage":true,"initial_zoom_width_override":685,"show_print_pages_button":false,"title":"Advances in Inorganic Chemistry","subtitle":"Homogeneous Biomimetic Oxidation Catalysis","attribution":"By Rudi van Eldik, Jan Reedijk","additional_info":{"[JsonBookInfo]":{"BuyLinks":[{"Seller":"Buy Direct from Elsevier","Url":"https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9\u0026usg=AOvVaw3t0n6E_aFSl4BwFIeW_SC9","IsPublisher":true},{"Seller":"Amazon.com","Url":"http://www.amazon.com/gp/search?index=books\u0026linkCode=qs\u0026keywords=9780080462172","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=http://www.amazon.com/gp/search%3Findex%3Dbooks%26linkCode%3Dqs%26keywords%3D9780080462172\u0026usg=AOvVaw1zDPXY4buAsPqNIqWJvHq8"},{"Seller":"MPH","Url":"http://www.mphonline.com/books/nsearch.aspx?do=detail\u0026pcode=9780080462172","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=http://www.mphonline.com/books/nsearch.aspx%3Fdo%3Ddetail%26pcode%3D9780080462172\u0026usg=AOvVaw2ex_OvBz-jZwZdrNm3b5Z6"},{"Seller":"Popular","Url":"https://www.popular.com.sg/catalogsearch/result/?q=9780080462172","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=https://www.popular.com.sg/catalogsearch/result/%3Fq%3D9780080462172\u0026usg=AOvVaw31RPIQA7d8S3dmU-l_v8sC"}],"AboutUrl":"https://books.google.com.sg/books?id=UgNp8-wq-aAC","PreviewUrl":"https://books.google.com.sg/books?id=UgNp8-wq-aAC","allowed_syndication_flags":{"allow_disabling_chrome":true},"online_access":{"url":"https://play.google.com/store/books/details?id=UgNp8-wq-aAC\u0026rdid=book-UgNp8-wq-aAC\u0026rdot=1","price":"SGD 326.69","list_price":"SGD 413.76"},"TocLine":[{"Title":"DiversityBased Approaches to Selective Biomimetic Oxidation Catalysis","Pid":"PA1","PgNum":"1","Order":9},{"Title":"Selective Conversion of Hydrocarbons with H2O2 Using Biomimetic Nonheme Iron and Manganese Oxidation Catalysts","Pid":"PA29","PgNum":"29","Order":37},{"Title":"DNA Oxidation by Copper and Manganese Complexes","Pid":"PA77","PgNum":"77","Order":85},{"Title":"Ligand Influences in CopperDioxygen ComplexFormation and Substrate Oxidations","Pid":"PA131","PgNum":"131","Order":139},{"Title":"Biomimetic Oxidations by Dinuclear and Trinuclear Copper Complexes","Pid":"PA185","PgNum":"185","Order":193},{"Title":"Green oxidation of alcohols using biomimetic Cu complexes and Cu enzymes as catalysts","Pid":"PA235","PgNum":"235","Order":243},{"Title":"Index","Pid":"PA281","PgNum":"281","Order":289},{"Title":"Contents of Previous Volumes","Pid":"PA285","PgNum":"285","Order":293}]}},"table_of_contents_page_id":"PR5","max_resolution_image_width":1280,"max_resolution_image_height":1858,"num_toc_pages":2,"quality_info":"We have no quality information about this book.","volume_id":"UgNp8-wq-aAC","permission_info":"Pages displayed by permission of \u003ca class=link_aux href=\"https://books.google.com.sg/url?id=UgNp8-wq-aAC\u0026pg=PA122\u0026q=https://www.elsevier.com/books-and-journals\u0026clientid=ca-print-elsevier-academic_press\u0026linkid=1\u0026usg=AOvVaw0gzjgx6fEefU16_Ns97Irz\u0026source=gbs_pub_info_r\"\u003eElsevier\u003c/a\u003e","is_ebook":true,"volumeresult":{"has_flowing_text":false,"has_scanned_text":true,"can_download_pdf":false,"can_download_epub":false,"is_pdf_drm_enabled":false,"is_epub_drm_enabled":false},"publisher":"Elsevier","publication_date":"2006.01.18","subject":"Science","num_pages":298,"sample_url":"https://play.google.com/books/reader?id=UgNp8-wq-aAC\u0026source=gbs_vpt_hover","synposis":"Advances in Inorganic Chemistry Volume 58 focuses on homogeneous biomimetic oxidation catalysis. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. Contributions include diversity-based approaches to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by copper and manganese complexes; influences of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations by dinuclear and trinuclear copper complexes. In the final contribution the authors focus on green oxidation of alcohols using biomimetic copper complexes and enzymes as catalysts. Volume 58 provides another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry.* Includes new information on the important advances in inorganic and bioinorganic chemistry * Each chapter is fully referenced * Contains comprehensive reviews written by leading experts in the field","my_library_url":"https://www.google.com/accounts/Login?service=print\u0026continue=https://books.google.com.sg/books%3Fop%3Dlibrary\u0026hl=en","is_magazine":false,"is_public_domain":false,"last_page":{"pid":"PA290","order":298,"title":"290"}},{"enableUserFeedbackUI":true,"pseudocontinuous":true,"is_cobrand":false,"sign_in_url":"https://www.google.com/accounts/Login?service=print\u0026continue=https://books.google.com.sg/books%3Fid%3DUgNp8-wq-aAC%26q%3Delectron%2Btransfer%26dq%3Dsubject:%2522Science%2BChemistry%2522%26source%3Dgbs_word_cloud_r%26hl%3Den\u0026hl=en","isEntityPageViewport":false,"showViewportOnboarding":false,"showViewportPlainTextOnboarding":false},{"page":[{"pid":"PA122","highlights":[{"X":290,"Y":153,"W":30,"H":7},{"X":128,"Y":210,"W":31,"H":7},{"X":290,"Y":247,"W":29,"H":7},{"X":179,"Y":318,"W":31,"H":8},{"X":338,"Y":317,"W":31,"H":8},{"X":247,"Y":356,"W":30,"H":8},{"X":319,"Y":374,"W":40,"H":11},{"X":452,"Y":374,"W":41,"H":11},{"X":313,"Y":460,"W":44,"H":12},{"X":346,"Y":475,"W":45,"H":12},{"X":395,"Y":475,"W":45,"H":12},{"X":184,"Y":504,"W":45,"H":12},{"X":291,"Y":622,"W":45,"H":12},{"X":285,"Y":651,"W":45,"H":12}],"flags":8,"order":130,"vq":"electron transfer"}]},null,{"number_of_results":35,"search_results":[{"page_id":"PA32","page_number":"32","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e with concomitant reduction of dioxygen to water , and oxygenases , which catalyze the reaction of dioxygen with organic or inorganic substrates . Mono - oxygenases catalyze the incorporation of one atom of dioxygen\u0026nbsp;..."},{"page_id":"PA54","page_number":"54","snippet_text":"... \u003cb\u003eelectron\u003c/b\u003e - rich phenyl ring , in agreement with the experiments carried out in the presence of 1802 , for which the ... \u003cb\u003etransfer\u003c/b\u003e of an oxygen atom from H2O2 into anisole substrate occurred ( 51 ) . Also , it has been observed that\u0026nbsp;..."},{"page_id":"PA58","page_number":"58","snippet_text":"... \u003cb\u003etransfer\u003c/b\u003e to a substrate and the oxidative degradation of the catalyst . An alternative approach for the epoxidation ... \u003cb\u003eElectron\u003c/b\u003e - donating substituents at the 5 and 5 \u0026#39; positions of the salicylide ligand in the catalyst I\u0026nbsp;..."},{"page_id":"PA93","page_number":"93","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e between O2 and Cu [ Eq . ( 8 ) ] . H2O2 is formed by reduction of O by the Cu1 complex [ Eq . ( 9 ) ] or by dismutation of O [ Eq . ( 10 ) ] . A Fenton 2 2 reaction Eq. (11), or a Haber^Weiss reaction [Eq. (12)]\u0026nbsp;..."},{"page_id":"PA94","page_number":"94","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e to the CuII-hydroxo species [Eq. (16)] that regenerates the CuI species. These proposed non-di¡usible active species generated by CuI complex in the presence of H 2O2 can also be centered on the metal. It can be a CuI\u0026nbsp;..."},{"page_id":"PA95","page_number":"95","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e to form a DNA cation and a CuI species as in Eq. (19) (59,127,130^133). A putative CuIII-hydroxo species, generated as in Eq. (20) of Fig. 14, could also be able to oxidize DNA as in Eqs. (21,22), since this trivalent\u0026nbsp;..."},{"page_id":"PA96","page_number":"96","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e between them may allow the oxidation of the radical to a cation and the regeneration of the initial CuI complex. Other non-di¡usible active species centered on the metal and generated by CuI complexes in the presence\u0026nbsp;..."},{"page_id":"PA97","page_number":"97","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e [ Eq . ( 28 ) ] , this last reaction releasing a Cul complex . II Dinuclear Cu1 complexes can also generate Cu - O - O - Cu species in the presence of dioxygen . This peroxy - bridged complex can be able to perform\u0026nbsp;..."},{"page_id":"PA98","page_number":"98","snippet_text":"... \u003cb\u003eelectron transfers\u003c/b\u003e observed during the deoxyribose oxidation of double-stranded DNA (Figs 4, 5, 7, and 8). The ... transfer reaction oxidizing this radical to a carbocation. Some of these activated species like HOl, CuI-hydroperoxo\u0026nbsp;..."},{"page_id":"PA102","page_number":"102","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e R AH * + H + OH MnV 0 = IV Mn R AH oxygen transfer \u003cb\u003eelectron transfer\u003c/b\u003e ROH A OH2 Mn A Mn - B peroxidase mechanism cytochromome P450 mechanism FIG . 21. Mechanism of the oxidative chemistry mediated by high - valent\u0026nbsp;..."},{"page_id":"PA103","page_number":"103","snippet_text":"... (\u003cb\u003eelectron\u003c/b\u003e abstraction vs. oxygen atom \u003cb\u003etransfer\u003c/b\u003e) on DNA will follow the same rules as those known for heme enzymes. Oxygen atom \u003cb\u003etransfer\u003c/b\u003e is only possible when the substrate can approach the metal-oxo center (like in cytochromes P450). It\u0026nbsp;..."},{"page_id":"PA111","page_number":"111","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e mechanism and abstracts electrons from the most oxidizable base of DNA , guanine ( 214 ) . The redox potential of the guanine base of guanosine was measured at 1.29 V vs. NHE and is significantly lower ( 0.5V ) than\u0026nbsp;..."},{"page_id":"PA113","page_number":"113","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e had been previously characterized with a photosensitizer as oxidative reagent, benzophenone (249,250). The mechanism of its formation involved an inter- mediate guanine radical cation, G þ l, that deprotonated\u0026nbsp;..."},{"page_id":"PA119","page_number":"119","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e and oxygen atom transfer were observed on the same DNA target. The product of deoxyribose oxidation at C1 \u0026#39; , 5. DNA OXIDATION BY COPPER AND MANGANESE COMPLEXES 119."},{"page_id":"PA120","page_number":"120","snippet_text":"... \u003cb\u003etransfer\u003c/b\u003e ) and \u003cb\u003eelectron\u003c/b\u003e abstraction at guanine bases . With this powerful oxidant , free radical chemistry was not observed . Trapping of intermediate radicals on the guanine base or at the sugars by molecular oxygen did not occur\u0026nbsp;..."},{"page_id":"PA121","page_number":"121","snippet_text":"... \u003cb\u003eelectron\u003c/b\u003e oxidation of DNA) can be performed by HOl radicals or by activated species of oxidized metal complexes ... \u003cb\u003etransfer\u003c/b\u003e or an oxygen rebound mechanism (direct hydroxylation by MnIV^OH species). Alternatively, hydro- xyl\u0026nbsp;..."},{"page_id":"PA122","page_number":"122","snippet_text":"... \u003cb\u003etransfer\u003c/b\u003e - le- G G + e- \u003cb\u003etransfer\u003c/b\u003e - H + - le- ( G - H ) ( G - H ) * + e- \u003cb\u003etransfer\u003c/b\u003e G + hole migration G 02 H2O or Nu Iz Iz , 31-34 first \u0026quot; 1 - \u003cb\u003eelectron\u003c/b\u003e oxidation \u0026quot; second \u0026quot; 1 - \u003cb\u003eelectron\u003c/b\u003e oxidation \u0026quot; \u0026quot; 2 - \u003cb\u003eelectron\u003c/b\u003e oxidation \u0026quot; FIG . 35. DNA\u0026nbsp;..."},{"page_id":"PA123","page_number":"123","snippet_text":"Homogeneous Biomimetic Oxidation Catalysis Rudi van Eldik, Jan Reedijk. of \u003cb\u003eelectron transfer\u003c/b\u003e , but also in oxygen transfer reactions . No radical chem- istry is observed , the trapping of intermediate radical species by O2 on the\u0026nbsp;..."},{"page_id":"PA164","page_number":"164","snippet_text":"... transfer reactions to phosphanes and sulfides ( 108 ) , and benzylamine oxidation to benzonitrile has also been ... \u003cb\u003eelectron transfer\u003c/b\u003e mechanism (see Section IV.D), with the only di¡erence 164 L.Q. HATCHER and K.D. KARLIN."},{"page_id":"PA171","page_number":"171","snippet_text":"Homogeneous Biomimetic Oxidation Catalysis Rudi van Eldik, Jan Reedijk. \u003cb\u003eelectron transfer\u003c/b\u003e process . However , as the Cu2O2 compound becomes less oxidizing based on its electron donating ligand substituent , the results of the linear free\u0026nbsp;..."},{"page_id":"PA176","page_number":"176","snippet_text":"... \u003cb\u003etransfer\u003c/b\u003e -MePY2)} 2 (OH) 2 ]2þ indicating 4 that a proton coupled (PCET) reaction occurred. Curiously, addition of \u003cb\u003eelectron\u003c/b\u003e [FeII(phen) 2 (NO-phen)](ClO 4 ) 2 with a weaker acid such as acetic acid did not promote any PCET reaction\u0026nbsp;..."},{"page_id":"PA178","page_number":"178","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e ” oxidations . V. Summary and Outlook Significant advances have been made in the synthesis and characteriza- tion of discrete copper - dioxygen structures , with a deeper understanding of their spectroscopic origins\u0026nbsp;..."},{"page_id":"PA193","page_number":"193","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e proteins containing a single type 1 Cu center (54), by a cascade of domain duplication events (55) ... transfer the electrons to dioxygen. From spectroscopic studies and fast kinetic experiments carried out on\u0026nbsp;..."},{"page_id":"PA199","page_number":"199","snippet_text":"... \u003cb\u003eelectron\u003c/b\u003e withdrawing substituents , such as R = NO2 . In this case , Raman spectroscopic data unambiguously ... \u003cb\u003etransfer\u003c/b\u003e . The lack of kinetic isotope effect on the hydroxylation reaction suggests that the initial attack on the\u0026nbsp;..."},{"page_id":"PA210","page_number":"210","snippet_text":"... \u003cb\u003etransfer\u003c/b\u003e to the phenolic substrate . In addition , [ Cu2 ( DBED ) 202 ] 2 + reacts with catechol giving the quinone ... \u003cb\u003eelectron\u003c/b\u003e oxi- dant producing an equimolecular amount of phenoxy radical , which sponta- neously dimerizes to\u0026nbsp;..."},{"page_id":"PA211","page_number":"211","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e r.d.s. (^0.5) and for a pure proton transfer r.d.s. (^1.0). Kinetic deuterium isotope e¡ects measured for several substrates con¢rmed the involvement of the proton transfer in the r.d.s. and were comparable with the\u0026nbsp;..."},{"page_id":"PA212","page_number":"212","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e too . This is inconsistent with the previous data demonstrating that the oxygenation of phenolate by the μ - η2 : n2 - peroxodicopper ( II ) complex pro- ceeds by an electrophilic aromatic substitution mechanism\u0026nbsp;..."},{"page_id":"PA236","page_number":"236","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e , enzyme requires mediators to extend its catalytic action . Significant progress in its use has been made in the last five years and an overview thereof will be given as well . Finally , the class of dinuclear\u0026nbsp;..."},{"page_id":"PA240","page_number":"240","snippet_text":"... electron rich aromatic substrates , usually phenols or aromatic amines , via four single electron oxidation steps concomitant with the four electron reduction of O2 to H2O ( 15,37 ) . \u003cb\u003eElectron transfer\u003c/b\u003e takes place at the T1 site , which\u0026nbsp;..."},{"page_id":"PA243","page_number":"243","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e ( ET ) , e.g. , with ABTS , or via hydrogen atom transfer ( HAT ) , e.g. , with N - hydroxy com- pounds which form N - oxy radicals ( 55 ) . TEMPO and its derivatives form a unique case : one - electron oxidation of\u0026nbsp;..."},{"page_id":"PA244","page_number":"244","snippet_text":"... \u003cb\u003eelectron transfer\u003c/b\u003e from the intermediate. ketyl. radical. anion. with. reduction. of. Cul. to. Cu1 . The. copper. (. I. ) species. C. reacts with dioxygen to form the hydroperoxo copper ( II ) complex D with the liberation of the aldehyde ."},{"page_id":"PA271","page_number":"271","snippet_text":"... transferred to TEMPO resulting in a radical - TEMPOH copper species IV . Intramolecular one - \u003cb\u003eelectron transfer\u003c/b\u003e leads to the aldehyde , TEMPOH and Cu ( I ) species V. Finally , species I is regenerated by the TEMPO - mediated oxidation\u0026nbsp;..."},{"page_id":"PA285","page_number":"285","snippet_text":"... \u003cb\u003eElectron\u003c/b\u003e- , Energy- , and Atom - \u003cb\u003eTransfer\u003c/b\u003e Reactions between Metal Complexes and DNA H. Holden Thorp Magnetism of Heterobimetallics : Toward Molecular - Based Magnets Olivier Kahn VOLUME 45 Syntheses , Structures , and Reactions of\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA285\u0026vq=electron+transfer\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA286","page_number":"286","snippet_text":"... \u003cb\u003eElectron Transfer\u003c/b\u003e Chain C. Dennison , G. W. Canters , S. de Vries , E. Vijgenboom , and R. J. van Spanning INDEX VOLUME 46 The Octahedral M6Y6 and M6Y12 Clusters of Group 4 and 5 Transition Metals Nicholas Prokopuk and D. F. Shriver\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA286\u0026vq=electron+transfer\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA288","page_number":"288","snippet_text":"... \u003cb\u003eElectron\u003c/b\u003e - \u003cb\u003eTransfer\u003c/b\u003e Reactions David M. Stanbury Metal Ion Catalyzed Autoxidation Reactions : Kinetics and Mechanisms István Fábián and Viktor Csordás VOLUME 53 Wheel - Shaped Polyoxo and Polyoxothiometalates : From the Molecular Level\u0026nbsp;..."}],"search_query_escaped":"electron transfer"},{});</script></div></div></div><script>(function() {var href = window.location.href;if (href.indexOf('?') !== -1) {var parameters = href.split('?')[1].split('&');for (var i = 0; i < parameters.length; i++) {var param = parameters[i].split('=');if (param[0] == 'focus') {var elem = document.getElementById(param[1]);if (elem) {elem.focus();}}}}})();</script>