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(PDF) Laser ablation ICPMS study of trace element chemistry in molybdenite coupled with scanning electron microscopy (SEM) — An important tool for identification of different types of mineralization | Jan Pašava - Academia.edu
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"https://www.academia.edu/login?post_login_redirect_url=https%3A%2F%2Fwww.academia.edu%2F93590074%2FLaser_ablation_ICPMS_study_of_trace_element_chemistry_in_molybdenite_coupled_with_scanning_electron_microscopy_SEM_An_important_tool_for_identification_of_different_types_of_mineralization%3Fshow_translation%3Dtrue"; window.loswp.previewableAttachments = [{"id":96286231,"identifier":"Attachment_96286231","shouldShowBulkDownload":false}]; window.loswp.shouldDetectTimezone = true; window.loswp.shouldShowBulkDownload = true; window.loswp.showSignupCaptcha = false window.loswp.willEdgeCache = false; window.loswp.work = {"work":{"id":93590074,"created_at":"2022-12-24T02:13:30.491-08:00","from_world_paper_id":223641815,"updated_at":"2024-11-26T20:21:34.592-08:00","_data":{"publisher":"Elsevier BV","grobid_abstract":"Scanning electron microscopy Nano-to micro-inclusions Bohemian Massif Uzbekistan Using the example of four different types of associations from the Bohemian Massif (greisen-, gold-, base metal-, and \"barren granite\"-related) and of one porphyry-Cu-Mo(Au) deposit from Uzbekistan, it is shown that molybdenite from a specific type of mineralization possesses a distinct trace-element geochemical composition, which is locally influenced by the presence of relevant mineral phases occurring in the form of sub-nano-, nanoto micron-scale impurities/inclusions. It is documented that, besides typically lattice-bound elements (Re, and W) and isostructural concentrations of Se and Te (substituting for S), molybdenite can concentrate other metals (e.g., Ag, As, Au, Bi, Cu, Nb, Pb, Zn, Zr) which mostly form inclusions or impurities. Typical lattice-bound elements (W, Se, Te) can locally occur as impurities or micro-inclusions. The distribution of Re in molybdenite indicates crustal sources for the group of greisen-, base-metal-, and a few of the granite-related deposits, compared to a mixed mantle/crustal source for the Au-related and majority of granite-related deposits. Greisen-related molybdenites show the highest mean values of As (40 ppm), Cu (58 ppm), and Zn (45 ppm), but the lowest mean Re value (0.4 ppm). They contain abundant inclusions of native bismuth, which are accompanied, depending on the individual deposit, by variable quantities of Bi(Se)-, Bi(Pb)-, Pb(Bi)-and Pb-Bi-Cu-bearing phases and also bismuthinite (Bi 2 S 3), wolframite and scheelite. Gold-related molybdenite typically has the highest mean values of Ag (464 ppm), Au (24 ppm), Bi (1188 ppm), Sb (39 ppm), and Te (112 ppm) and also the highest median values of these elements. Gold mostly occurs as inclusions of native Au or in association with Bi (maldonite) and/or as Bi-Au-Te phases whereas silver is commonly present in the form of Au(Ag), and less commonly as BiTe -Ag, Ag-Se and Ag-Te phases. Selenium and Te are either isomorphously bound in the molybdenite structure (similarly to Re and W) and/or form micro-inclusions of different tellurides and selenides. Molybdenite from base metal associations is characterized by the highest mean Pb (3223 ppm) and the highest median Ag (12 ppm). These metals are present in the form of abundant micro-inclusions of galena locally accompanied by an Ag-S phase and anglesite [PbSO 4 ] with indications of other chalcophile element sub-micro-inclusions. \"Barren granite\"-related molybdenites, dispersed in the rock matrix, in quartz and/or pegmatite veins and/or located in fractures, have the highest mean and median Ni values (16 ppm). These molybdenites are either inclusion-free or contain micro-inclusions and also indications of sub-nano-impurities depending on the locality and a type of mineralization processes reported from the region. For example, inclusions of native bismuth, galena and anglesite occur in molybdenite from Harrachov and Bohutín where base-metal mineralization was exploited in the past. Molybdenite from the Kalmakyr porphyry-Cu-Mo(Au) deposit in Uzbekistan is characterized by the highest mean Re value (236 ppm). Rhenium, Se and W have a homogeneous distribution in molybdenite from this deposit. Only galena and anglesite inclusions were identified visually in molybdenite from this type of deposit, while the presence of most likely sub-nano impurities of Cu, Zn and Ag is indicated by LA-ICPMS time-resolved depth profiles.","publication_date":"2016,,","publication_name":"Ore Geology Reviews","grobid_abstract_attachment_id":"96286231"},"document_type":"paper","pre_hit_view_count_baseline":null,"quality":"high","language":"en","title":"Laser ablation ICPMS study of trace element chemistry in molybdenite coupled with scanning electron microscopy (SEM) — An important tool for identification of different types of mineralization","broadcastable":false,"draft":null,"has_indexable_attachment":true,"indexable":true}}["work"]; window.loswp.workCoauthors = [32318794]; window.loswp.locale = "en"; window.loswp.countryCode = "SG"; window.loswp.cwvAbTestBucket = ""; window.loswp.designVariant = "ds_vanilla"; window.loswp.fullPageMobileSutdModalVariant = "control"; window.loswp.useOptimizedScribd4genScript = false; 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Kelson</a><span>, </span><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="33102417" href="https://adelaide1.academia.edu/NigelCook">Nigel Cook</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Chemical Geology, 2013</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Trace element heterogeneity in molybdenite fingerprints stages of mineralization","attachmentId":43710472,"attachmentType":"pdf","work_url":"https://www.academia.edu/14949783/Trace_element_heterogeneity_in_molybdenite_fingerprints_stages_of_mineralization","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/14949783/Trace_element_heterogeneity_in_molybdenite_fingerprints_stages_of_mineralization"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="1" data-entity-id="36826637" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/36826637/Trace_element_geochemistry_of_molybdenite_from_porphyry_Cu_deposits_of_the_Birgilda_Tomino_ore_cluster_South_Urals_Russia">Trace-element geochemistry of molybdenite from porphyry Cu deposits of the Birgilda-Tomino ore cluster (South Urals, Russia</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="32329724" href="https://igem.academia.edu/OlgaPlotinskaya">Olga Y Plotinskaya</a><span>, </span><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="34210023" href="https://nhm.academia.edu/JohnSpratt">John Spratt</a><span>, </span><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="23017749" href="https://nhm.academia.edu/ReimarSeltmann">Reimar Seltmann</a></div><p class="ds-related-work--abstract ds2-5-body-sm">Mineralogical, electron microprobe analysis and laser ablation-inductively coupled plasma-mass spectrometry data from molybdenite within two porphyry copper deposits (Kalinovskoe and Birgilda) of the Birgilda-Tomino ore cluster (South Urals) are presented. † The results provide evidence that molybdenites from these two sites have similar trace-element chemistry. Most trace elements (Si, Fe, Co, Cu, Zn, Ag, Sb, Te, Pb, Bi, Au, As and Se) form mineral inclusions within molybdenite. The Re contents in molybdenite vary from 8.7 ppm to 1.13 wt.%. The Re distribution within single molybdenite flakes is always extremely heterogeneous. It is argued that a temperature decrease favours the formation of Re-rich molybdenite. The high Re content of molybdenite observed points to a mantle-derived source.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Trace-element geochemistry of molybdenite from porphyry Cu deposits of the Birgilda-Tomino ore cluster (South Urals, Russia","attachmentId":56778445,"attachmentType":"pdf","work_url":"https://www.academia.edu/36826637/Trace_element_geochemistry_of_molybdenite_from_porphyry_Cu_deposits_of_the_Birgilda_Tomino_ore_cluster_South_Urals_Russia","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/36826637/Trace_element_geochemistry_of_molybdenite_from_porphyry_Cu_deposits_of_the_Birgilda_Tomino_ore_cluster_South_Urals_Russia"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="2" data-entity-id="29374610" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/29374610/Molybdenite_Mineral_Evolution_A_Study_Of_Trace_Elements_Through_Time">Molybdenite Mineral Evolution: A Study Of Trace Elements Through Time</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="55394597" href="https://independent.academia.edu/SteinHolly">Holly Stein</a></div><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Molybdenite Mineral Evolution: A Study Of Trace Elements Through Time","attachmentId":49815876,"attachmentType":"pdf","work_url":"https://www.academia.edu/29374610/Molybdenite_Mineral_Evolution_A_Study_Of_Trace_Elements_Through_Time","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/29374610/Molybdenite_Mineral_Evolution_A_Study_Of_Trace_Elements_Through_Time"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="3" data-entity-id="59741073" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/59741073/Distribution_of_rhenium_in_molybdenite_from_porphyry_Cu_Mo_and_Mo_Cu_deposits_of_Russia_Siberia_and_Mongolia">Distribution of rhenium in molybdenite from porphyry Cu–Mo and Mo–Cu deposits of Russia (Siberia) and Mongolia</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="40794" href="https://uoa.academia.edu/MariaEconomou">Maria Economou-Eliopoulos</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Ore Geology Reviews, 2005</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Distribution of rhenium in molybdenite from porphyry Cu–Mo and Mo–Cu deposits of Russia (Siberia) and Mongolia","attachmentId":73507780,"attachmentType":"pdf","work_url":"https://www.academia.edu/59741073/Distribution_of_rhenium_in_molybdenite_from_porphyry_Cu_Mo_and_Mo_Cu_deposits_of_Russia_Siberia_and_Mongolia","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/59741073/Distribution_of_rhenium_in_molybdenite_from_porphyry_Cu_Mo_and_Mo_Cu_deposits_of_Russia_Siberia_and_Mongolia"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="4" data-entity-id="221579" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/221579/Distribution_of_rhenium_in_molybdenites_from_porphyry_Cu_Mo_deposits_of_Russia_Siberia_and_Mongolia">Distribution of rhenium in molybdenites from porphyry Cu-Mo deposits of Russia (Siberia) and Mongolia.</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="40794" href="https://uoa.academia.edu/MariaEconomou">Maria Economou-Eliopoulos</a></div><p class="ds-related-work--abstract ds2-5-body-sm">Rhenium was determined in representative molybdenite samples (concentrates) from the Aksug, Erdenetuin-Obo, Zhireken, Shakhtama and Sora porphyry Cu–Mo and Mo–Cu deposits of Russia (Siberia) and Mongolia. The Re contents in the majority of the concentrates are low, ranging from 6 to 460 ppm. The maximum Re contents were determined in molybdenite concentrates from the Aksug (460 ppm Re) and Erdenetuin-Obo (199 ppm Re) Co–Mo porphyry deposits and are significantly higher than those from the Zhireken, Shakhtama and Sora Mo–Cu porphyry deposits. The Re content of molybdenite concentrates from the studied Mo–Cu porphyry deposits (6 to 57 ppm) are, however, comparable to those from comparable deposits worldwide. The Aksug and Erdenetuin-Obo deposits, with relatively elevated Re content, differ from the Zhireken, Shakhtama and Sora deposits with lower Re contents in terms of (1) higher Cu/Mo ratio; (2) lower y34S and 87Sr/86Sr values; (3) silica and alkali contents of the host rocks; (4) the alteration type of the associated rocks; (5) the elevated Cl activity in the fluid; (6) the lower temperature of the molybdenite formation; and (7) the higher oxidized conditions. The Re contents of molybdenite from porphyry Cu–Mo deposits may therefore be related to the composition of parent magmas themselves and/or fractionation, sources of the material, and variations of physical and chemical conditions of crystallization ( fO2, Cl activity, P, T).</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Distribution of rhenium in molybdenites from porphyry Cu-Mo deposits of Russia (Siberia) and Mongolia.","attachmentId":782570,"attachmentType":"pdf","work_url":"https://www.academia.edu/221579/Distribution_of_rhenium_in_molybdenites_from_porphyry_Cu_Mo_deposits_of_Russia_Siberia_and_Mongolia","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/221579/Distribution_of_rhenium_in_molybdenites_from_porphyry_Cu_Mo_deposits_of_Russia_Siberia_and_Mongolia"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="5" data-entity-id="70118428" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/70118428/Article_The_Distribution_Character_and_Rhenium_Content_of_Molybdenite_in_the_Aitik_Cu_Au_Ag_Mo_Deposit_and_Its_Southern_Extension_in_the_Northern_Norrbotten_Ore_District">Article The Distribution, Character, and Rhenium Content of Molybdenite in the Aitik Cu-Au-Ag-(Mo) Deposit and Its Southern Extension in the Northern Norrbotten Ore District</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="63863537" href="https://independent.academia.edu/RogerNordin">Roger Nordin</a></div><p class="ds-related-work--metadata ds2-5-body-xs">2014</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Article The Distribution, Character, and Rhenium Content of Molybdenite in the Aitik Cu-Au-Ag-(Mo) Deposit and Its Southern Extension in the Northern Norrbotten Ore District","attachmentId":79981194,"attachmentType":"pdf","work_url":"https://www.academia.edu/70118428/Article_The_Distribution_Character_and_Rhenium_Content_of_Molybdenite_in_the_Aitik_Cu_Au_Ag_Mo_Deposit_and_Its_Southern_Extension_in_the_Northern_Norrbotten_Ore_District","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/70118428/Article_The_Distribution_Character_and_Rhenium_Content_of_Molybdenite_in_the_Aitik_Cu_Au_Ag_Mo_Deposit_and_Its_Southern_Extension_in_the_Northern_Norrbotten_Ore_District"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="6" data-entity-id="32111803" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/32111803/The_Distribution_Character_and_Rhenium_Content_of_Molybdenite_in_the_Aitik_Cu_Au_Ag_Mo_Deposit_and_Its_Southern_Extension_in_the_Northern_Norrbotten_Ore_District_Northern_Sweden">The Distribution, Character, and Rhenium Content of Molybdenite in the Aitik Cu-Au-Ag-(Mo) Deposit and Its Southern Extension in the Northern Norrbotten Ore District, Northern Sweden</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="63863537" href="https://independent.academia.edu/RogerNordin">Roger Nordin</a><span>, </span><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="925935" href="https://independent.academia.edu/NilsJohanBolin">Nils Johan Bolin</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Minerals, 2014</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"The Distribution, Character, and Rhenium Content of Molybdenite in the Aitik Cu-Au-Ag-(Mo) Deposit and Its Southern Extension in the Northern Norrbotten Ore District, Northern Sweden","attachmentId":52359337,"attachmentType":"pdf","work_url":"https://www.academia.edu/32111803/The_Distribution_Character_and_Rhenium_Content_of_Molybdenite_in_the_Aitik_Cu_Au_Ag_Mo_Deposit_and_Its_Southern_Extension_in_the_Northern_Norrbotten_Ore_District_Northern_Sweden","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/32111803/The_Distribution_Character_and_Rhenium_Content_of_Molybdenite_in_the_Aitik_Cu_Au_Ag_Mo_Deposit_and_Its_Southern_Extension_in_the_Northern_Norrbotten_Ore_District_Northern_Sweden"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="7" data-entity-id="97866048" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/97866048/Trace_element_geochemistry_of_molybdenite_from_the_Shapinggou_super_large_porphyry_Mo_deposit_China">Trace element geochemistry of molybdenite from the Shapinggou super-large porphyry Mo deposit, China</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="23017749" href="https://nhm.academia.edu/ReimarSeltmann">Reimar Seltmann</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Ore Geology Reviews, 2018</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Trace element geochemistry of molybdenite from the Shapinggou super-large porphyry Mo deposit, China","attachmentId":99372817,"attachmentType":"pdf","work_url":"https://www.academia.edu/97866048/Trace_element_geochemistry_of_molybdenite_from_the_Shapinggou_super_large_porphyry_Mo_deposit_China","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/97866048/Trace_element_geochemistry_of_molybdenite_from_the_Shapinggou_super_large_porphyry_Mo_deposit_China"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="8" data-entity-id="53361592" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/53361592/Grain_scale_distribution_of_molybdenite_polytypes_versus_rhenium_contents_%CE%BCXRD_and_EBSD_data">Grain-scale distribution of molybdenite polytypes versus rhenium contents: μXRD and EBSD data</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="66175151" href="https://independent.academia.edu/OPlotinskaya">Olga Plotinskaya</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Mineralogical Magazine</p><p class="ds-related-work--abstract ds2-5-body-sm">Molybdenite from two porphyry copper mineralisation sites within the South Urals was studied by electron microprobe (EMPA), micro x-ray diffraction (μXRD) and electron backscattered diffraction (EBSD) methods. Elevated contents of rhenium (0.2 to 0.4, sometimes up to 1.1 wt.%) form linear zones from several to tens of micrometres wide and up to hundreds of micrometres long parallel to the elongation of molybdenite flakes. In most cases Re-rich zones are composed of the rhombohedral (3R) polytype of molybdenite, while the rest of the molybdenite flakes with ca. 0.1 wt.% of Re consist of hexagonal (2H) molybdenite. In rare cases Re-rich zones are confined to grain boundaries of molybdenite-2H. It is shown that both μXRD and EBSD are the most appropriate tools to distinguish different polytypes within a single grain of molybdenite.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Grain-scale distribution of molybdenite polytypes versus rhenium contents: μXRD and EBSD data","attachmentId":70242320,"attachmentType":"pdf","work_url":"https://www.academia.edu/53361592/Grain_scale_distribution_of_molybdenite_polytypes_versus_rhenium_contents_%CE%BCXRD_and_EBSD_data","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/53361592/Grain_scale_distribution_of_molybdenite_polytypes_versus_rhenium_contents_%CE%BCXRD_and_EBSD_data"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="9" data-entity-id="110324166" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/110324166/Molybdenite_occurrences_in_Greece_mineralogy_geochemistry_and_depositional_environment">Molybdenite occurrences in Greece : mineralogy, geochemistry and depositional environment</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="42421718" href="https://en-uoa-gr.academia.edu/PVoudouris">Panagiotis Voudouris</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Επιστημονική Επετηρίδα του Τμήματος Γεωλογίας (Α.Π.Θ.), 2010</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Molybdenite occurrences in Greece : mineralogy, geochemistry and depositional environment","attachmentId":108176379,"attachmentType":"pdf","work_url":"https://www.academia.edu/110324166/Molybdenite_occurrences_in_Greece_mineralogy_geochemistry_and_depositional_environment","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/110324166/Molybdenite_occurrences_in_Greece_mineralogy_geochemistry_and_depositional_environment"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div></div></div><div class="ds-sticky-ctas--wrapper js-loswp-sticky-ctas hidden"><div class="ds-sticky-ctas--grid-container"><div class="ds-sticky-ctas--container"><button class="ds2-5-button js-swp-download-button" data-signup-modal="{"location":"continue-reading-button--sticky-ctas","attachmentId":96286231,"attachmentType":"pdf","workUrl":null}">See full PDF</button><button class="ds2-5-button ds2-5-button--secondary js-swp-download-button" data-signup-modal="{"location":"download-pdf-button--sticky-ctas","attachmentId":96286231,"attachmentType":"pdf","workUrl":null}"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">download</span>Download PDF</button></div></div></div><div class="ds-below-fold--grid-container"><div class="ds-work--container js-loswp-embedded-document"><div class="attachment_preview" data-attachment="Attachment_96286231" style="display: none"><div class="js-scribd-document-container"><div class="scribd--document-loading js-scribd-document-loader" style="display: block;"><img alt="Loading..." src="//a.academia-assets.com/images/loaders/paper-load.gif" /><p>Loading Preview</p></div></div><div style="text-align: center;"><div class="scribd--no-preview-alert js-preview-unavailable"><p>Sorry, preview is currently unavailable. You can download the paper by clicking the button above.</p></div></div></div></div><div class="ds-sidebar--container js-work-sidebar"><div class="ds-related-content--container"><h2 class="ds-related-content--heading">Related papers</h2><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="0" data-entity-id="117739970" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/117739970/Geochemistry_of_Hydrothermal_Molybdenite_Inclusions_Linking_Ore_Stage_Pyrite_with_Accessory_Minerals">Geochemistry of Hydrothermal Molybdenite Inclusions: Linking Ore-Stage Pyrite with Accessory Minerals</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="183979950" href="https://ualberta.academia.edu/AlexisBlanchetteArnold">Alexis Blanchette-Arnold</a></div><p class="ds-related-work--metadata ds2-5-body-xs">2018</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Geochemistry of Hydrothermal Molybdenite Inclusions: Linking Ore-Stage Pyrite with Accessory Minerals","attachmentId":113521534,"attachmentType":"pdf","work_url":"https://www.academia.edu/117739970/Geochemistry_of_Hydrothermal_Molybdenite_Inclusions_Linking_Ore_Stage_Pyrite_with_Accessory_Minerals","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-related-work-grid-card-view-pdf" href="https://www.academia.edu/117739970/Geochemistry_of_Hydrothermal_Molybdenite_Inclusions_Linking_Ore_Stage_Pyrite_with_Accessory_Minerals"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="1" data-entity-id="20553822" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/20553822/Classification_and_genesis_of_stockwork_molybdenum_deposits_discussion">Classification and genesis of stockwork molybdenum deposits; 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Moritz</a></div><p class="ds-related-work--metadata ds2-5-body-xs">The Canadian Mineralogist, 2009</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"RHENIUM-RICH MOLYBDENITE AND RHENIITE IN THE PAGONI RACHI Mo-Cu-Te-Ag-Au PROSPECT, NORTHERN GREECE: IMPLICATIONS FOR THE Re GEOCHEMISTRY OF PORPHYRY-STYLE Cu-Mo AND Mo MINERALIZATION","attachmentId":51337420,"attachmentType":"pdf","work_url":"https://www.academia.edu/30913432/RHENIUM_RICH_MOLYBDENITE_AND_RHENIITE_IN_THE_PAGONI_RACHI_Mo_Cu_Te_Ag_Au_PROSPECT_NORTHERN_GREECE_IMPLICATIONS_FOR_THE_Re_GEOCHEMISTRY_OF_PORPHYRY_STYLE_Cu_Mo_AND_Mo_MINERALIZATION","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline 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