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class="user-links-collapsible-item mw-list-item"><a href="https://donate.wikimedia.org/?wmf_source=donate&wmf_medium=sidebar&wmf_campaign=zh.wikipedia.org&uselang=zh"><span>资助维基百科</span></a></li><li id="pt-createaccount" class="user-links-collapsible-item mw-list-item"><a href="/w/index.php?title=Special:%E5%88%9B%E5%BB%BA%E8%B4%A6%E6%88%B7&returnto=%E6%BA%B4%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF" title="我们推荐您创建账号并登录，但这不是强制性的"><span class="vector-icon mw-ui-icon-userAdd mw-ui-icon-wikimedia-userAdd"></span> <span>创建账号</span></a></li><li id="pt-login" class="user-links-collapsible-item mw-list-item"><a href="/w/index.php?title=Special:%E7%94%A8%E6%88%B7%E7%99%BB%E5%BD%95&returnto=%E6%BA%B4%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF" title="建议你登录，尽管并非必须。[o]" accesskey="o"><span class="vector-icon mw-ui-icon-logIn mw-ui-icon-wikimedia-logIn"></span> <span>登录</span></a></li> </ul> </div> </div> <div id="p-user-menu-anon-editor" class="vector-menu mw-portlet mw-portlet-user-menu-anon-editor" > <div 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class="vector-pinned-container"> </div> </nav> </div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="目录" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">目录</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">隐藏</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">序言</div> </a> </li> <li id="toc-合成" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#合成"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>合成</span> </div> </a> <ul id="toc-合成-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-参考文献" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考文献"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>参考文献</span> </div> </a> <ul id="toc-参考文献-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-拓展链接" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#拓展链接"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>拓展链接</span> </div> </a> <ul id="toc-拓展链接-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" title="目录" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">溴乙酸乙酯</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。14种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-14" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">14种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D8%A7%D8%AA%DB%8C%D9%84_%D8%A8%D8%B1%D9%85%D9%88%D8%A7%D8%B3%D8%AA%D8%A7%D8%AA" title="اتیل برمواستات – South Azerbaijani" lang="azb" hreflang="azb" data-title="اتیل برمواستات" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Bromessigs%C3%A4ureethylester" title="Bromessigsäureethylester – 德语" lang="de" hreflang="de" data-title="Bromessigsäureethylester" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Ethyl_bromoacetate" title="Ethyl bromoacetate – 英语" lang="en" hreflang="en" data-title="Ethyl bromoacetate" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-eo mw-list-item"><a href="https://eo.wikipedia.org/wiki/Etila_bromoacetato" title="Etila bromoacetato – 世界语" lang="eo" hreflang="eo" data-title="Etila bromoacetato" data-language-autonym="Esperanto" data-language-local-name="世界语" class="interlanguage-link-target"><span>Esperanto</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%A7%D8%AA%DB%8C%D9%84_%D8%A8%D8%B1%D9%85%D9%88%D8%A7%D8%B3%D8%AA%D8%A7%D8%AA" title="اتیل برمواستات – 波斯语" lang="fa" hreflang="fa" data-title="اتیل برمواستات" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Etyylibromiasetaatti" title="Etyylibromiasetaatti – 芬兰语" lang="fi" hreflang="fi" data-title="Etyylibromiasetaatti" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Bromoac%C3%A9tate_d%27%C3%A9thyle" title="Bromoacétate d'éthyle – 法语" lang="fr" hreflang="fr" data-title="Bromoacétate d'éthyle" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Etil_bromoasetat" title="Etil bromoasetat – 印度尼西亚语" lang="id" hreflang="id" data-title="Etil bromoasetat" data-language-autonym="Bahasa Indonesia" data-language-local-name="印度尼西亚语" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%83%96%E3%83%AD%E3%83%A2%E9%85%A2%E9%85%B8%E3%82%A8%E3%83%81%E3%83%AB" title="ブロモ酢酸エチル – 日语" lang="ja" hreflang="ja" data-title="ブロモ酢酸エチル" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Bromooctan_etylu" title="Bromooctan etylu – 波兰语" lang="pl" hreflang="pl" data-title="Bromooctan etylu" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Bromoacetato_de_etila" title="Bromoacetato de etila – 葡萄牙语" lang="pt" hreflang="pt" data-title="Bromoacetato de etila" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Etil_bromoacetat" title="Etil bromoacetat – 塞尔维亚-克罗地亚语" lang="sh" hreflang="sh" data-title="Etil bromoacetat" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="塞尔维亚-克罗地亚语" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Etil_bromoacetat" title="Etil bromoacetat – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Etil bromoacetat" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%8E%E0%AE%A4%E0%AF%8D%E0%AE%A4%E0%AE%BF%E0%AE%B2%E0%AF%8D_%E0%AE%AA%E0%AF%81%E0%AE%B0%E0%AF%8B%E0%AE%AE%E0%AF%8B_%E0%AE%85%E0%AE%9A%E0%AE%BF%E0%AE%9F%E0%AF%8D%E0%AE%9F%E0%AF%87%E0%AE%9F%E0%AF%8D%E0%AE%9F%E0%AF%81" title="எத்தில் புரோமோ அசிட்டேட்டு – 泰米尔语" lang="ta" hreflang="ta" data-title="எத்தில் புரோமோ அசிட்டேட்டு" data-language-autonym="தமிழ்" data-language-local-name="泰米尔语" class="interlanguage-link-target"><span>தமிழ்</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q413962#sitelinks-wikipedia" title="编辑跨语言链接" class="wbc-editpage">编辑链接</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav aria-label="命名空间"> <div id="p-associated-pages" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-associated-pages" > 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</div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">维基百科，自由的百科全书</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="zh" dir="ltr"><style data-mw-deduplicate="TemplateStyles:r84001320">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox nounderlines" cellspacing="0" cellpadding="3" rules="all" style="background-color:#f0f0f0; float:right; margin: 0 0 1em 1em; border-color: #aaaaaa; border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">溴乙酸乙酯 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Ethyl-bromoacetate-2D-skeletal.png" class="mw-file-description" title="Skeletal formula of ethyl bromoacetate"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/c/c3/Ethyl-bromoacetate-2D-skeletal.png/200px-Ethyl-bromoacetate-2D-skeletal.png" decoding="async" width="200" height="93" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/c3/Ethyl-bromoacetate-2D-skeletal.png/300px-Ethyl-bromoacetate-2D-skeletal.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/c3/Ethyl-bromoacetate-2D-skeletal.png/400px-Ethyl-bromoacetate-2D-skeletal.png 2x" data-file-width="1100" data-file-height="512" /></a></span> </td></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Ethyl-bromoacetate-3D-balls.png" class="mw-file-description" title="Ball-and-stick model of ethyl bromoacetate"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/1/18/Ethyl-bromoacetate-3D-balls.png/200px-Ethyl-bromoacetate-3D-balls.png" decoding="async" width="200" height="101" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/18/Ethyl-bromoacetate-3D-balls.png/300px-Ethyl-bromoacetate-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/18/Ethyl-bromoacetate-3D-balls.png/400px-Ethyl-bromoacetate-3D-balls.png 2x" data-file-width="1100" data-file-height="557" /></a></span> </td></tr> <tr> <td colspan="2" style="max-width:305px; word-wrap: break-word; text-align: center;"><a href="/wiki/IUPAC%E5%91%BD%E5%90%8D%E6%B3%95" title="IUPAC命名法">IUPAC名</a><br />Ethyl bromoacetate </td></tr> <tr> <td>英文名 </td> <td><span lang="en">Ethyl bromoacetate</span> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=105-36-2">105-36-2</a></span> <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/PubChem" title="PubChem">PubChem</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/7748">7748</a></span> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.chemspider.com/7462">7462</a></span> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">BrCC(=O)OCC</span></li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChI</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0">1/C4H7BrO2/c1-2-7-4(6)3-5/h2-3H2,1H3</li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChIKey</a> </td> <td><small>PQJJJMRNHATNKG-UHFFFAOYAE</small> </td></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E7%89%A9%E8%B4%A8%E6%AF%92%E6%80%A7%E6%95%B0%E6%8D%AE%E5%BA%93" title="化学物质毒性数据库">RTECS</a> </td> <td>AF6000000 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td>C<sub>4</sub>H<sub>7</sub>BrO<sub>2</sub> </td></tr> <tr> <td><a href="/wiki/%E6%91%A9%E5%B0%94%E8%B4%A8%E9%87%8F" title="摩尔质量">摩尔质量</a> </td> <td>167 g·mol<sup>−1</sup> </td></tr> <tr> <td>外观 </td> <td>无色至黄色液体<sup id="cite_ref-chemicalland21_1-0" class="reference"><a href="#cite_note-chemicalland21-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td><a href="/wiki/%E5%AF%86%E5%BA%A6" title="密度">密度</a> </td> <td>1.51 g/cm<sup>3</sup> </td></tr> <tr> <td><a href="/wiki/%E7%86%94%E7%82%B9" title="熔点">熔点</a> </td> <td>−38 °C（235 K） </td></tr> <tr> <td><a href="/wiki/%E6%B2%B8%E7%82%B9" title="沸点">沸点</a> </td> <td>158 °C（431 K） </td></tr> <tr> <td><a href="/wiki/%E6%BA%B6%E8%A7%A3%E6%80%A7" class="mw-redirect" title="溶解性">溶解性</a>（<a href="/wiki/%E6%B0%B4" title="水">水</a>） </td> <td>难溶 </td></tr> <tr> <td><a href="/wiki/%E7%A3%81%E5%8C%96%E7%8E%87" title="磁化率">磁化率</a> </td> <td>-82.8·10<sup>−6</sup> cm<sup>3</sup>/mol </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">危险性 </th></tr> <tr> <td><a href="/wiki/%E8%AD%A6%E7%A4%BA%E6%80%A7%E8%B3%AA%E6%A8%99%E6%BA%96%E8%A9%9E%E5%88%97%E8%A1%A8" title="警示性質標準詞列表">警示术语</a> </td> <td>R：<a href="/wiki/%E8%AD%A6%E7%A4%BA%E6%80%A7%E8%B3%AA%E6%A8%99%E6%BA%96%E8%A9%9E%E5%88%97%E8%A1%A8#R26/27/28" title="警示性質標準詞列表"><abbr class="abbr" title="R26/27/28: 吸入、触摸及吞食有剧毒">R26/27/28</abbr></a> </td></tr> <tr> <td><a href="/wiki/%E5%AE%89%E5%85%A8%E5%BB%BA%E8%AD%B0%E6%A8%99%E6%BA%96%E8%A9%9E%E5%88%97%E8%A1%A8" title="安全建議標準詞列表">安全术语</a> </td> <td>S：<a href="/wiki/%E5%AE%89%E5%85%A8%E5%BB%BA%E8%AD%B0%E6%A8%99%E6%BA%96%E8%A9%9E%E5%88%97%E8%A1%A8#S1/2" title="安全建議標準詞列表"><abbr class="abbr" title="S1/2: 上锁储存并防止儿童触及">S1/2</abbr></a>, <a href="/wiki/%E5%AE%89%E5%85%A8%E5%BB%BA%E8%AD%B0%E6%A8%99%E6%BA%96%E8%A9%9E%E5%88%97%E8%A1%A8#S7/9" title="安全建議標準詞列表"><abbr class="abbr" title="S7/9: 严格密闭，保持通风">S7/9</abbr></a>, <a href="/wiki/%E5%AE%89%E5%85%A8%E5%BB%BA%E8%AD%B0%E6%A8%99%E6%BA%96%E8%A9%9E%E5%88%97%E8%A1%A8#S26" title="安全建議標準詞列表"><abbr class="abbr" title="S26: 接触眼睛后立即用大量清水冲洗并求医">S26</abbr></a>, <a href="/wiki/%E5%AE%89%E5%85%A8%E5%BB%BA%E8%AD%B0%E6%A8%99%E6%BA%96%E8%A9%9E%E5%88%97%E8%A1%A8#S45" title="安全建議標準詞列表"><abbr class="abbr" title="S45: 发生事故或感到不适时立即求医，可能的话出示标签">S45</abbr></a> </td></tr> <tr> <td><a href="/wiki/%E5%8D%B1%E9%99%A9%E7%89%A9%E8%B4%A8%E7%9A%84%E5%88%86%E7%B1%BB%E3%80%81%E5%8C%85%E8%A3%85%E3%80%81%E6%A0%87%E7%A4%BA%E6%8C%87%E4%BB%A4" class="mw-redirect" title="危险物质的分类、包装、标示指令">欧盟分类</a> </td> <td>剧毒（<b>T+</b>）、催泪剂 </td></tr> <tr> <td><a href="/wiki/NFPA_704" title="NFPA 704">NFPA 704</a> </td> <td> <div style="position: relative; height: 85px; width: 75px;"> <div style="position: absolute; height: 75px; width: 75px;"><span typeof="mw:File"><a href="/wiki/File:NFPA_704.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/75px-NFPA_704.svg.png" decoding="async" width="75" height="75" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/113px-NFPA_704.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/150px-NFPA_704.svg.png 2x" data-file-width="512" data-file-height="512" /></a></span></div> <div title="可燃性" style="background: transparent; width: 75px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 3px; font-size: large;"><span class="abbr" style="color: black;" title="可燃性0級。不會燃燒（如水）。"><b>0</b></span></div> <div title="健康" style="background: transparent; width: 37.5px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 21px; font-size: large;"><span class="abbr" style="color: black;" title="健康危險4級。短時間的暴露可能會導致死亡或重大持續性傷害（如VX毒氣）"><b>4</b></span></div> <div title="反應性" style="background: transparent; width: 37.5px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 21px; left: 37.5px; font-size: large;"><span class="abbr" style="color: black;" title="反應性3級。可能爆炸分解，但需要一個強的引發源，必須在密閉性容器内加熱方可引發，與水爆炸性反應，或重擊下爆炸（如氟氣）。"><b>3</b></span></div> <div title="其它危險" style="background: transparent; width: 75px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 44px; font-size: small;"> </div> </div> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">相关物质 </th></tr> <tr> <td>其他<a href="/wiki/%E9%98%B4%E7%A6%BB%E5%AD%90" class="mw-redirect" title="阴离子">阴离子</a> </td> <td><a href="/wiki/%E4%B9%99%E9%85%B0%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF" title="乙酰乙酸乙酯">乙酰乙酸乙酯</a><br /><a href="/w/index.php?title=%E6%B0%9F%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF&action=edit&redlink=1" class="new" title="氟乙酸乙酯（页面不存在）">氟乙酸乙酯</a><br /><a href="/wiki/%E6%B0%AF%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF" title="氯乙酸乙酯">氯乙酸乙酯</a><br /><a href="/w/index.php?title=%E7%A2%98%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF&action=edit&redlink=1" class="new" title="碘乙酸乙酯（页面不存在）">碘乙酸乙酯</a> </td></tr> <tr> <td>相关化学品 </td> <td><a href="/wiki/%E6%BA%B4%E4%B9%99%E9%85%B8%E7%94%B2%E9%85%AF" title="溴乙酸甲酯">溴乙酸甲酯</a> </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明，所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态（25 ℃，100 kPa）</a>下。 </td></tr></tbody></table> <p><b>溴乙酸乙酯</b>是一种<a href="/wiki/%E6%9C%89%E6%9C%BA%E5%8C%96%E5%90%88%E7%89%A9" title="有机化合物">有机化合物</a>，化学式为CH<sub>2</sub>BrCO<sub>2</sub>C<sub>2</sub>H<sub>5</sub>。它可由<a href="/wiki/%E4%B9%99%E9%85%B8" title="乙酸">乙酸</a>为原料合成。<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>它是一种催泪剂，具有果味和刺激性气味。<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>它是毒性很高的烷基化试剂。吸入、吞咽或与皮肤接触可能致命。 </p> <div class="mw-heading mw-heading2"><h2 id="合成"><span id=".E5.90.88.E6.88.90"></span>合成</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E6%BA%B4%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF&action=edit&section=1" title="编辑章节：合成"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>乙酸和溴在<a href="/wiki/%E7%BA%A2%E7%A3%B7" title="红磷">红磷</a>的存在下进行溴代反应，制得<a href="/wiki/%E6%BA%B4%E4%B9%99%E9%85%B8" title="溴乙酸">溴乙酸</a>。溴乙酸和<a href="/wiki/%E4%B9%99%E9%86%87" title="乙醇">乙醇</a>进行酯化反应，得到溴乙酸乙酯。<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="参考文献"><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span>参考文献</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E6%BA%B4%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF&action=edit&section=2" title="编辑章节：参考文献"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-chemicalland21-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-chemicalland21_1-0">^</a></b></span> <span class="reference-text"><a rel="nofollow" class="external text" href="http://www.chemicalland21.com/arokorhi/specialtychem/finechem/ETHYL%202-BROMOACETATE.htm">Chemicalland properties database</a> <a href="/wiki/Archive.is" title="Archive.is">Archive.is</a>的<a rel="nofollow" class="external text" href="https://archive.today/20130119065954/http://www.chemicalland21.com/arokorhi/specialtychem/finechem/ETHYL%202-BROMOACETATE.htm">存檔</a>，存档日期2013年1月19日，</span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text"><cite style="font-style:normal">Natelson, S.; Gottfried, S. (1955). "<a rel="nofollow" class="external text" href="http://www.orgsyn.org/demo.aspx?prep=cv3p0381">Ethyl Bromoacetate</a>". <i><a href="/wiki/%E6%9C%89%E6%9C%BA%E5%90%88%E6%88%90_(%E6%9C%9F%E5%88%8A)" title="有机合成 (期刊)">Org. Synth.</a></i>; <i>Coll. Vol.</i> <b>3</b>: 381.</cite><span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Ethyl+Bromoacetate &rft.date=1955&rft.au=Natelson%2C+S.%3B+Gottfried%2C+S."> </span></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text"><cite class="citation journal">Criswell, DW; McClure, FL; Schaefer, R; Brower, KR. War gases as olfactory probes. Science. 1980, <b>210</b> (4468): 425–6. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/6968976"><span title="公共医学识别码">PMID 6968976</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.6968976"><span title="數位物件識別號">doi:10.1126/science.6968976</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E6%BA%B4%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF&rft.atitle=War+gases+as+olfactory+probes&rft.au=Brower%2C+KR&rft.au=McClure%2C+FL&rft.au=Schaefer%2C+R&rft.aufirst=DW&rft.aulast=Criswell&rft.date=1980&rft.genre=article&rft.issue=4468&rft.jtitle=Science&rft.pages=425-6&rft.volume=210&rft_id=info%3Adoi%2F10.1126%2Fscience.6968976&rft_id=info%3Apmid%2F6968976&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-4">^</a></b></span> <span class="reference-text">张序红. 一种溴代乙酸乙酯的合成方法: CN, CN101891615A[P]. 2010.</span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="拓展链接"><span id=".E6.8B.93.E5.B1.95.E9.93.BE.E6.8E.A5"></span>拓展链接</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E6%BA%B4%E4%B9%99%E9%85%B8%E4%B9%99%E9%85%AF&action=edit&section=3" title="编辑章节：拓展链接"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a rel="nofollow" class="external text" href="https://web.archive.org/web/20050830142944/http://www.ehs.neu.edu/hazardeg.htm">Environmental Health & Safety dept, Northeastern University</a></li></ul>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?useformat=desktop&type=1x1&usesul3=0" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">检索自“<a dir="ltr" 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