Fabrication and Characterization of CeO2-NiO/SiC Membranes for Hydrogen Permeation

<!DOCTYPE html> <html lang="en" dir="ltr"> <head> <meta name="format-detection" content="telephone=no"> <meta name="viewport" content="width=device-width, initial-scale=1.0" /> <meta charset="utf-8"> <meta http-equiv="X-UA-Compatible" content="IE=edge"> <link rel="canonical" href="https://www.scientific.net/DDF.353.143" /> <meta property="og:title" content="Fabrication and Characterization of CeO2-NiO/SiC Membranes for Hydrogen Permeation | Scientific.Net" /> <meta property="og:type" content="website" /> <meta property="og:url" content="https://www.scientific.net/DDF.353.143" /> <meta property="og:image" content="/Content/app/scinet5/images/metadata_logo.png" /> <meta property="og:image:type" content="image/png" /> <meta property="og:image:width" content="261" /> <meta property="og:image:height" content="260" /> <meta property="og:image:alt" content="Scientific.Net Logo" /> <meta name="citation_language" content="en" /> <meta name="citation_publisher" content="Trans Tech Publications Ltd" /> <meta name="citation_title" content="Fabrication and Characterization of CeO2-NiO/SiC Membranes for Hydrogen Permeation" /> <meta name="citation_publication_date" content="2014" /> <meta name="citation_online_date" content="2014/05/21" /> <meta name="citation_journal_title" content="Defect and Diffusion Forum" /> <meta name="citation_issn" content="1662-9507" /> <meta name="citation_volume" content="353" /> <meta name="citation_firstpage" content="143" /> <meta name="citation_lastpage" content="147" /> <meta name="citation_pdf_url" content="https://www.scientific.net/DDF.353.143.pdf" /> <meta name="citation_abstract_html_url" content="https://www.scientific.net/DDF.353.143" /> <meta name="citation_keywords" content="CeO<sub>2</sub>-NiO;Hot-Press Sintering;Hydrogen Permeation;Silicon Carbide (SiC);Sol-Gel Process" /> <meta name="citation_doi" content="10.4028/www.scientific.net/DDF.353.143" /> <meta name="citation_author" content="Ji Hye Park" /> <meta name="citation_author" content="Mie Won Jung" /> <meta name="citation_reference" content="B. 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Barbaux, Langmuir Vol. 17 (2001) 1511-1517." /> <meta name="person" content="Ji Hye Park, Mie Won Jung" /> <meta name="description" content="In order to enhance the hydrogen permeation, Silicon carbide (SiC) was prepared with CeO2-NiO mixed oxides via sol-gel process and the SiC membranes with various contents of 蠂 wt% mixed oxides (蠂 = 20, 40, 60 and 80) were fabricated by hot-press sintering (HPS) at 1173 K under vacuum condition. The effect of the CeO2-NiO mixed oxides was studied in terms of properties on hydrogen permeation. All the membranes were characterized by XRD, FE-SEM and BET instrument. The hydrogen permeation test was carried out at various temperatures under 0.1 MPa. Hydrogen permeation flux of the 80 wt% CeO2-NiO/SiC membrane, which has the highest value, was obtained at 2.92×10-6 mol/m2sPa, 323 K. The reaction enthalpy (螖H°) was calculated as - 4.95 J/mol by Arrhenius鈥檚 plot." /> <meta name="keywords" content="CeO<sub>2</sub>-NiO, Hot-Press Sintering, Hydrogen Permeation, Silicon Carbide (SiC), Sol-Gel Process" /> <meta name="copyright" content="2014 Trans Tech Publications Ltd. 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class="paper-statistics"> <div class="loading"> <i class="inline-icon download-and-visitor-statistics-icon"></i> <span class="normal-text" id="paperDownloadsAndVisitorsCount"></span> </div> </div> <div class="clearfix"></div> <div class="page-paper-title"> <div class="preview-block"> <img alt="Article Preview" width="128" height="180" src="/DDF.353.143/thumbnail.gif"> <div id="preview-button" data-url-preview-log="/Paper/PreviewImageLog?paperId=395619"> <i class="inline-icon preview-icon"></i> </div>  <div id="paper-preview-modal" class="modal fade"> <div class="modal-dialog" role="document"> <div class="popup-page-name underline-begin"> <div class="page-name-block-text">Article Preview</div> </div> <img alt="Article Preview" class="preview-image lazyload" data-src="/DDF.353.143/preview.gif"> <a data-dismiss="modal" title="Close" class="inline-icon close-icon"></a> </div> </div>  </div> <div class="abstract-block-description"> <h3 class="page-paper-first-header">Abstract:</h3> <p class="normal-text"> In order to enhance the hydrogen permeation, Silicon carbide (SiC) was prepared with CeO<sub>2</sub>-NiO mixed oxides via sol-gel process and the SiC membranes with various contents of 蠂 wt% mixed oxides (蠂 = 20, 40, 60 and 80) were fabricated by hot-press sintering (HPS) at 1173 K under vacuum condition. The effect of the CeO<sub>2</sub>-NiO mixed oxides was studied in terms of properties on hydrogen permeation. All the membranes were characterized by XRD, FE-SEM and BET instrument. The hydrogen permeation test was carried out at various temperatures under 0.1 MPa. Hydrogen permeation flux of the 80 wt% CeO<sub>2</sub>-NiO/SiC membrane, which has the highest value, was obtained at 2.92脳10<sup>-6 </sup>mol/m<sup>2</sup>sPa, 323 K. The reaction enthalpy (螖H掳) was calculated as - 4.95 J/mol by Arrhenius鈥檚 plot. </p> </div> <div class="paper-access-buttons col-xs-12"> <div class="row"> <div class="sa-button-wrap"> <a id="sa-button" class="wayfinder-login d-flex sa-button" href="javascript:;"> <div class="sa-button-logo-wrap"> <i class="inline-icon sa-white"></i> </div> <div class="d-flex justify-content-center align-items-center sa-button-text text-truncate"> <div class="sa-button-text-primary text-truncate">Access through your institution</div> </div> </a> </div> <div class="title-button-pdf"> <button id="readPaperButton" data-url-read-paper-log="/Paper/ReadThePaperLog?paperId=395619" class="button button-160"> <span class="inline-element">Read The Paper</span> </button> </div> </div> <div class="row"> </div> </div> <div class="clearfix"></div> <div class="connected-title-container"> <div class="connected-title-text semibold-middle-text">You might also be interested in these eBooks</div> <div 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Corresponding Author"> </a> <a href="/author-papers/ji-hye-park">Ji Hye Park</a>*, <a href="/author-papers/mie-won-jung">Mie Won Jung</a> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Keywords:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <a href="/paper-keyword/ceo2-nio">CeO<sub>2</sub>-NiO</a>, <a href="/paper-keyword/hot-press-sintering-1">Hot-Press Sintering</a>, <a href="/paper-keyword/hydrogen-permeation">Hydrogen Permeation</a>, <a href="/paper-keyword/silicon-carbide-sic">Silicon Carbide (SiC)</a>, <a href="/paper-keyword/sol-gel-process">Sol-Gel Process</a> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Export:</p> </div> </div> <div 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