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name="order"><option selected value="-announced_date_first">Announcement date (newest first)</option><option value="announced_date_first">Announcement date (oldest first)</option><option value="-submitted_date">Submission date (newest first)</option><option value="submitted_date">Submission date (oldest first)</option><option value="">Relevance</option></select> </span> </div> <div class="control"> <button class="button is-small is-link">Go</button> </div> </div> </form> </div> </div> <ol class="breathe-horizontal" start="1"> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/2411.15052">arXiv:2411.15052</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/2411.15052">pdf</a>, <a href="https://arxiv.org/ps/2411.15052">ps</a>, <a href="https://arxiv.org/format/2411.15052">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Materials Science">cond-mat.mtrl-sci</span> </div> </div> <p class="title is-5 mathjax"> Thermal expansion in rare-earth cage systems: examples from the RB6 and RPt4Ge12 series </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mehdi Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Opagiste%2C+C">Christine Opagiste</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Shitsevalova%2C+N+Y">Natalya Yu. Shitsevalova</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="2411.15052v1-abstract-short" style="display: inline;"> In some intermetallic compounds, the crystallographic structure allows for an unusual latitude of movement of lanthanide ions inside so-called cages. Examples of such magnetic cage systems include the rare-earth hexaborides RB6 and filled skutterudites RPt4Ge12 series. In both instances, the rare-earth site, at the center of the cage, is of high symmetry, which may preserve some degree of orbital&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2411.15052v1-abstract-full').style.display = 'inline'; document.getElementById('2411.15052v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="2411.15052v1-abstract-full" style="display: none;"> In some intermetallic compounds, the crystallographic structure allows for an unusual latitude of movement of lanthanide ions inside so-called cages. Examples of such magnetic cage systems include the rare-earth hexaborides RB6 and filled skutterudites RPt4Ge12 series. In both instances, the rare-earth site, at the center of the cage, is of high symmetry, which may preserve some degree of orbital degeneracy. A deviation from the cage center lifts this degeneracy, yielding an interplay between the rare-earth movement and the system properties in the paramagnetic range. In particular, the low temperature thermal expansion should reflect this cage-specific crystal field contribution. This study presents an experimental investigation of the thermal expansion in the paramagnetic range of some elements in the aforementioned series. From a simple model for the vibrations in cage systems, a description of the phononic thermal expansion is proposed, within the quasi-harmonic approximation. Accounting for this non-magnetic contributions helps discern the influence of the orbital degeneracy at low temperature. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2411.15052v1-abstract-full').style.display = 'none'; document.getElementById('2411.15052v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 22 November, 2024; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> November 2024. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/2403.04540">arXiv:2403.04540</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/2403.04540">pdf</a>, <a href="https://arxiv.org/format/2403.04540">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Mesoscale and Nanoscale Physics">cond-mat.mes-hall</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1021/acs.nanolett.4c00605">10.1021/acs.nanolett.4c00605 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Impact of bright-dark exciton thermal population mixing on the brightness of CsPbBr$_3$ nanocrystals </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mohamed-Raouf Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Huo%2C+C">Caixia Huo</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Voisin%2C+C">Christophe Voisin</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Xiong%2C+Q">Qihua Xiong</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Diederichs%2C+C">Carole Diederichs</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="2403.04540v2-abstract-short" style="display: inline;"> Understanding the interplay between bright and dark exciton states is crucial for deciphering the luminescence properties of low-dimensional materials. The origin of the outstanding brightness of lead halide perovskites remains elusive. Here, we analyse temperature-dependent time-resolved photoluminescence to investigate the population mixing between bright and dark exciton sublevels in individual&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2403.04540v2-abstract-full').style.display = 'inline'; document.getElementById('2403.04540v2-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="2403.04540v2-abstract-full" style="display: none;"> Understanding the interplay between bright and dark exciton states is crucial for deciphering the luminescence properties of low-dimensional materials. The origin of the outstanding brightness of lead halide perovskites remains elusive. Here, we analyse temperature-dependent time-resolved photoluminescence to investigate the population mixing between bright and dark exciton sublevels in individual CsPbBr$_3$ nanocrystals in the intermediate confinement regime. We extract bright and dark exciton decay rates, and show quantitatively that the decay dynamics can only be reproduced with second-order phonon transitions. Furthermore, we find that any exciton sublevel ordering is compatible with the most likely population transfer mechanism. The remarkable brightness of lead halide perovskite nanocrystals rather stems from a reduced asymmetry between bright-to-dark and dark-to-bright conversion originating from the peculiar second-order phonon-assisted transitions that freeze bright-dark conversion at low temperature together with the very fast radiative recombination and favourable degeneracy of the bright exciton state. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2403.04540v2-abstract-full').style.display = 'none'; document.getElementById('2403.04540v2-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 15 April, 2024; <span class="has-text-black-bis has-text-weight-semibold">v1</span> submitted 7 March, 2024; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> March 2024. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/2301.09571">arXiv:2301.09571</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/2301.09571">pdf</a>, <a href="https://arxiv.org/format/2301.09571">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Mesoscale and Nanoscale Physics">cond-mat.mes-hall</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1021/acs.nanolett.3c00793">10.1021/acs.nanolett.3c00793 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Spectral fingerprint of quantum confinement in single CsPbBr$_3$ nanocrystals </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mohamed-Raouf Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Said%2C+Z">Zakaria Said</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Huo%2C+C">Caixia Huo</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Pierret%2C+A">Aur茅lie Pierret</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Voisin%2C+C">Christophe Voisin</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Gao%2C+W">Weibo Gao</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Xiong%2C+Q">Qihua Xiong</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Diederichs%2C+C">Carole Diederichs</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="2301.09571v2-abstract-short" style="display: inline;"> Lead halide perovskite nanocrystals are promising materials for classical and quantum light emission. To understand these outstanding properties, a thorough analysis of the band-edge exciton emission is needed which is not reachable in ensemble and room temperature studies because of broadening effects. Here, we report on a cryogenic-temperature study of the photoluminescence of single CsPbBr$_3$&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2301.09571v2-abstract-full').style.display = 'inline'; document.getElementById('2301.09571v2-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="2301.09571v2-abstract-full" style="display: none;"> Lead halide perovskite nanocrystals are promising materials for classical and quantum light emission. To understand these outstanding properties, a thorough analysis of the band-edge exciton emission is needed which is not reachable in ensemble and room temperature studies because of broadening effects. Here, we report on a cryogenic-temperature study of the photoluminescence of single CsPbBr$_3$ NCs in the intermediate quantum confinement regime. We reveal the size-dependence of the spectral features observed: the bright-triplet exciton energy splittings, the trion and biexciton binding energies as well as the optical phonon replica spectrum. In addition, we show that bright triplet energy splittings are consistent with a pure exchange model and that the variety of polarisation properties and spectra recorded can be rationalised simply by considering the orientation of the emitting dipoles and the populations of the emitting states. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2301.09571v2-abstract-full').style.display = 'none'; document.getElementById('2301.09571v2-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 31 March, 2023; <span class="has-text-black-bis has-text-weight-semibold">v1</span> submitted 23 January, 2023; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> January 2023. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/2203.13891">arXiv:2203.13891</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/2203.13891">pdf</a>, <a href="https://arxiv.org/format/2203.13891">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Optics">physics.optics</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Materials Science">cond-mat.mtrl-sci</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Applied Physics">physics.app-ph</span> </div> </div> <p class="title is-5 mathjax"> Light Management in Perovskite Photovoltaic Solar Cells: a perspective </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Berry%2C+F">Florian Berry</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Mermet-Lyaudoz%2C+R">Rapha毛l Mermet-Lyaudoz</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Davila%2C+J+M+C">Jose Maria Cuevas Davila</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Djemmah%2C+D+A">Djihad Amina Djemmah</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Nguyen%2C+H+S">Hai Son Nguyen</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Seassal%2C+C">Christian Seassal</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Fourmond%2C+E">Erwann Fourmond</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Chevalier%2C+C">C茅line Chevalier</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mohamed Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Drouard%2C+E">Emmanuel Drouard</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="2203.13891v1-abstract-short" style="display: inline;"> Light Management (LM) is essential for metal-halide perovskite solar cells in their race for record performance. In this review, criteria on materials, processes and photonic engineering are established such as to enhance mainly the short circuit current density, towards high energy yields. These criteria are used to analyse a large panel of solutions envisaged in the literature for single junctio&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2203.13891v1-abstract-full').style.display = 'inline'; document.getElementById('2203.13891v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="2203.13891v1-abstract-full" style="display: none;"> Light Management (LM) is essential for metal-halide perovskite solar cells in their race for record performance. In this review, criteria on materials, processes and photonic engineering are established such as to enhance mainly the short circuit current density, towards high energy yields. These criteria are used to analyse a large panel of solutions envisaged in the literature for single junction cells. Moreover, a perspective based on rigorous electromagnetic simulations performed on various comparable structures is proposed in order to clarify the conclusions, and to pave the way to further performance enhancement in the case of all-perovskite, two-terminal tandem cells. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2203.13891v1-abstract-full').style.display = 'none'; document.getElementById('2203.13891v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 25 March, 2022; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> March 2022. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1908.11758">arXiv:1908.11758</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1908.11758">pdf</a>, <a href="https://arxiv.org/ps/1908.11758">ps</a>, <a href="https://arxiv.org/format/1908.11758">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> </div> <p class="title is-5 mathjax"> Cage multipoles in rare-earth hexaborides </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mehdi Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Galera%2C+R">Rose-Marie Galera</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1908.11758v1-abstract-short" style="display: inline;"> In rare-earth cage compounds, the guest 4f ion cannot be considered as fixed at the centre of its cage. As result of the electronic degeneracy of the 4f shell, single-ion or collective mechanisms can redistribute the ion inside the cage, which can be described in terms of multipolar components. These mechanisms and their influence are here discussed and illustrated in relation with the rare-earth&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1908.11758v1-abstract-full').style.display = 'inline'; document.getElementById('1908.11758v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1908.11758v1-abstract-full" style="display: none;"> In rare-earth cage compounds, the guest 4f ion cannot be considered as fixed at the centre of its cage. As result of the electronic degeneracy of the 4f shell, single-ion or collective mechanisms can redistribute the ion inside the cage, which can be described in terms of multipolar components. These mechanisms and their influence are here discussed and illustrated in relation with the rare-earth hexaboride series. Warning: Following our oral presentation, this manuscript should have appeared in the Proceedings of SCES 2014 (SCES 2014, International Conference on Strongly Correlated Electron Systems, held 7 - 11 July 2014 in Grenoble). An infuriated referee decided otherwise stating, in substance, that &#34;... it could corrupt the youth ... &#34; (the very few interested in this particular the subject). The casual reader is here free to appreciate how far this corruption goes... <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1908.11758v1-abstract-full').style.display = 'none'; document.getElementById('1908.11758v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 30 August, 2019; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> August 2019. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1907.07530">arXiv:1907.07530</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1907.07530">pdf</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Mesoscale and Nanoscale Physics">cond-mat.mes-hall</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Optics">physics.optics</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1021/acs.nanolett.9b02816">10.1021/acs.nanolett.9b02816 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Super-localization of excitons in carbon nanotubes at cryogenic temperature </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Raynaud%2C+C">Christophe Raynaud</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Claude%2C+T">Th茅o Claude</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Borel%2C+A">Antoine Borel</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mohamed-Raouf Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Graf%2C+A">Arko Graf</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Zaumseil%2C+J">Jana Zaumseil</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Lauret%2C+J">Jean-S茅bastien Lauret</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Chassagneux%2C+Y">Yannick Chassagneux</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Voisin%2C+C">Christophe Voisin</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1907.07530v1-abstract-short" style="display: inline;"> At cryogenic temperature and at the single emitter level, the optical properties of single-wall carbon nanotubes depart drastically from that of a one-dimensional (1D) object. In fact, the (usually unintentional) localization of excitons in local potential wells leads to nearly 0D behaviors such as photon antibunching, spectral diffusion, inhomogeneous broadening, etc. Here, we present an hyperspe&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1907.07530v1-abstract-full').style.display = 'inline'; document.getElementById('1907.07530v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1907.07530v1-abstract-full" style="display: none;"> At cryogenic temperature and at the single emitter level, the optical properties of single-wall carbon nanotubes depart drastically from that of a one-dimensional (1D) object. In fact, the (usually unintentional) localization of excitons in local potential wells leads to nearly 0D behaviors such as photon antibunching, spectral diffusion, inhomogeneous broadening, etc. Here, we present an hyperspectral imaging of this exciton self-localization effect at the single nanotube level using a super-resolved optical microscopy approach. We report on the statistical distribution of the traps localization, depth and width. We use a quasi-resonant photoluminescence excitation approach to probe the confined quantum states. Numerical simulations of the quantum states and exciton diffusion show that the excitonic states are deeply modified by the interface disorder inducing a remarkable discretization of the excitonic absorption spectrum and a quenching of the free 1D exciton absorption. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1907.07530v1-abstract-full').style.display = 'none'; document.getElementById('1907.07530v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 17 July, 2019; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> July 2019. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Journal ref:</span> Nano Letters 19, 7210 (2019) </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1907.05775">arXiv:1907.05775</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1907.05775">pdf</a>, <a href="https://arxiv.org/ps/1907.05775">ps</a>, <a href="https://arxiv.org/format/1907.05775">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1103/PhysRevB.101.094411">10.1103/PhysRevB.101.094411 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Retrieving CeB$_6$&#39;s lost magnetic entropy </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mehdi Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Opagiste%2C+C">Christine Opagiste</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Galera%2C+R">Rose-Marie Galera</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1907.05775v1-abstract-short" style="display: inline;"> The reported temperature variations of CeB6 s magnetic entropy are inconsistent with the fourfold degeneracy of the crystal field ground state. This old question is here addressed through new specific heat measurements and an improved description, in the cage context, of both the phonons and crystal field contributions to the specific heat. The antiferromagnetic transition is characterized as firs&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1907.05775v1-abstract-full').style.display = 'inline'; document.getElementById('1907.05775v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1907.05775v1-abstract-full" style="display: none;"> The reported temperature variations of CeB6 s magnetic entropy are inconsistent with the fourfold degeneracy of the crystal field ground state. This old question is here addressed through new specific heat measurements and an improved description, in the cage context, of both the phonons and crystal field contributions to the specific heat. The antiferromagnetic transition is characterized as first-order and its latent heat determined. From the phonons dispersion for a cage compound, the lattice specific heat contribution is derived from the LaB6 data. Once corrected for the first-order transition and lattice contributions, the magnetic entropy displays the characteristic plateau of the quadruplet crystal field ground state, but at temperatures in excess of 30 K. Below 30 K, as the ordering temperature is approached, the magnetic entropy is substantially reduced. This anomalous temperature dependence is consistent with a crystal field ground state split by the rare-earth movement, a phenomenon specific to rare-earth cage compounds. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1907.05775v1-abstract-full').style.display = 'none'; document.getElementById('1907.05775v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 12 July, 2019; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> July 2019. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">11 double column pages, 9 figures, latex for PRB</span> </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Journal ref:</span> Phys. Rev. B 101, 094411 (2020) </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1812.08722">arXiv:1812.08722</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1812.08722">pdf</a>, <a href="https://arxiv.org/ps/1812.08722">ps</a>, <a href="https://arxiv.org/format/1812.08722">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1103/PhysRevB.99.174405">10.1103/PhysRevB.99.174405 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Dynamical splitting of cubic crystal field levels in rare-earth cage compounds </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mehdi Amara</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1812.08722v3-abstract-short" style="display: inline;"> The Crystalline Electric Field (CEF) influence is usually described by considering an ideally symmetrical rare-earth site. In the case of cage compounds, ample excursions of the rare-earth inside the cage require an adapted CEF description. A corrective, position dependent, CEF term accounts for the deviation from the perfect symmetry. In the paramagnetic range, a CEF level with orbital degeneracy&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1812.08722v3-abstract-full').style.display = 'inline'; document.getElementById('1812.08722v3-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1812.08722v3-abstract-full" style="display: none;"> The Crystalline Electric Field (CEF) influence is usually described by considering an ideally symmetrical rare-earth site. In the case of cage compounds, ample excursions of the rare-earth inside the cage require an adapted CEF description. A corrective, position dependent, CEF term accounts for the deviation from the perfect symmetry. In the paramagnetic range, a CEF level with orbital degeneracy thus acquires a width reflecting the rare-earth spatial distribution. In the case, frequent in cubic systems, of an orbitally degenerate CEF ground state at the center, this width introduces an additional energy scale, influential at low temperature. A spherical simplification allows to identify the major consequences of a cage-split ground multiplet: a Schottky-like anomaly appears in the specific heat with associated reduction of the magnetic entropy and alteration of the magnetic properties. Concomitantly, a centrifugal Jahn-Teller effect develops that expands the distribution of the magnetic ion and softens the rattling phonons. These effects are confronted with anomalous paramagnetic properties of rare-earth cage compounds, notably rare-earth filled skutterudites and hexaborides. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1812.08722v3-abstract-full').style.display = 'none'; document.getElementById('1812.08722v3-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 2 January, 2019; <span class="has-text-black-bis has-text-weight-semibold">v1</span> submitted 20 December, 2018; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> December 2018. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Journal ref:</span> Phys. Rev. B 99, 174405 (2019) </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1612.03681">arXiv:1612.03681</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1612.03681">pdf</a>, <a href="https://arxiv.org/ps/1612.03681">ps</a>, <a href="https://arxiv.org/format/1612.03681">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Materials Science">cond-mat.mtrl-sci</span> </div> </div> <p class="title is-5 mathjax"> Crystal field investigation in the light rare earth R$_3$Pt$_{23}$Si$_{11}$ compounds </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Gal%C3%A9ra%2C+R+M">R. M. Gal茅ra</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Opagiste%2C+C">C. Opagiste</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">M. Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Toussaint%2C+J+C">J. C. Toussaint</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Lepetit%2C+M+B">M. B. Lepetit</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Rols%2C+S">S. Rols</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1612.03681v1-abstract-short" style="display: inline;"> The crystalline electric field (CEF) is investigated in Pr$_3$Pt$_{23}$Si$_{11}$ and Nd$_3$Pt$_{23}$Si$_{11}$ by neutron spectroscopy (NS). At low temperature, the number of observed CEF excitations is consistent with the orthorhombic symmetry at the rare earth site. This agrees with previous results on Ce$_3$Pt$_{23}$Si$_{11}$. For Pr- and Nd$_3$Pt$_{23}$Si$_{11}$, the number of CEF parameters is&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1612.03681v1-abstract-full').style.display = 'inline'; document.getElementById('1612.03681v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1612.03681v1-abstract-full" style="display: none;"> The crystalline electric field (CEF) is investigated in Pr$_3$Pt$_{23}$Si$_{11}$ and Nd$_3$Pt$_{23}$Si$_{11}$ by neutron spectroscopy (NS). At low temperature, the number of observed CEF excitations is consistent with the orthorhombic symmetry at the rare earth site. This agrees with previous results on Ce$_3$Pt$_{23}$Si$_{11}$. For Pr- and Nd$_3$Pt$_{23}$Si$_{11}$, the number of CEF parameters is too large to allow for an unambiguous determination. This determination is possible for Ce$_3$Pt$_{23}$Si$_{11}$, due to a reduced number of parameters and to the availability of extensive experimental data. A specific procedure is developed for this purpose that combines genetic algorithmics and optimization methods. An unique set of CEF parameters is found for Ce$_3$Pt$_{23}$Si$_{11}$. It reveals a strong anisotropy at the orthorhombic site, responsible for an easy threefold magnetization axis in the cubic system. Using a microscopic, mean-field, description, the magnetization processes in the paramagnetic and ferromagnetic phases of Ce$_3$Pt$_{23}$Si$_{11}$ are well reproduced. Ce$_3$Pt$_{23}$Si$_{11}$ is shown to realize a model for systems where conflicting anisotropies are forced to cooperate. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1612.03681v1-abstract-full').style.display = 'none'; document.getElementById('1612.03681v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 12 December, 2016; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> December 2016. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">8 pages, 11 figures</span> </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1609.08805">arXiv:1609.08805</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1609.08805">pdf</a>, <a href="https://arxiv.org/format/1609.08805">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1103/PhysRevB.95.014428">10.1103/PhysRevB.95.014428 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Field driven magnetostructural transitions in GeCo$_2$O$_4$ </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Fabr%C3%A8ges%2C+X">X. Fabr猫ges</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Ressouche%2C+E">E. Ressouche</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Duc%2C+F">F. Duc</a>, <a href="/search/cond-mat?searchtype=author&amp;query=de+Brion%2C+S">S. de Brion</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">M. Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Detlefs%2C+C">C. Detlefs</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Paolasini%2C+L">L. Paolasini</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Suard%2C+E">E. Suard</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Regnault%2C+L+-">L. -P. Regnault</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Canals%2C+B">B. Canals</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Strobel%2C+P">P. Strobel</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Simonet%2C+V">V. Simonet</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1609.08805v2-abstract-short" style="display: inline;"> In the spinel compound GeCo$_2$O$_4$, the Co$^{2+}$ pyrochlore sublattice presents remarkable magnetic field-induced behaviors that we unveil through neutron and X-ray single-crystal diffraction. The N茅el ordered magnetic phase is entered through a structural lowering of the cubic symmetry. In this phase, when a magnetic field is applied along a 2-fold cubic direction, a spin-flop transition of on&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1609.08805v2-abstract-full').style.display = 'inline'; document.getElementById('1609.08805v2-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1609.08805v2-abstract-full" style="display: none;"> In the spinel compound GeCo$_2$O$_4$, the Co$^{2+}$ pyrochlore sublattice presents remarkable magnetic field-induced behaviors that we unveil through neutron and X-ray single-crystal diffraction. The N茅el ordered magnetic phase is entered through a structural lowering of the cubic symmetry. In this phase, when a magnetic field is applied along a 2-fold cubic direction, a spin-flop transition of one fourth of the magnetic moments releases the magnetic frustration and triggers magnetostructural effects. At high field, these ultimately lead to an unusual spin reorientation associated to structural changes. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1609.08805v2-abstract-full').style.display = 'none'; document.getElementById('1609.08805v2-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 25 January, 2017; <span class="has-text-black-bis has-text-weight-semibold">v1</span> submitted 28 September, 2016; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> September 2016. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Journal ref:</span> Phys. Rev. B 95, 014428 (2017) </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1507.04918">arXiv:1507.04918</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1507.04918">pdf</a>, <a href="https://arxiv.org/ps/1507.04918">ps</a>, <a href="https://arxiv.org/format/1507.04918">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> </div> <p class="title is-5 mathjax"> The centrifugal Jahn-Teller effect in rare-earth cage systems </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mehdi Amara</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1507.04918v1-abstract-short" style="display: inline;"> The analysis of the properties of rare-earth based materials relies on the Crystalline Electric Field theory. This theory has to be reconsidered in case of cage-type compounds, where the rare-earth ion can substantially depart from its, high symmetry, average position. It is shown that, in case of an orbital degeneracy at the cage center, a specific Jahn-Teller effect develops in the paramagnetic&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1507.04918v1-abstract-full').style.display = 'inline'; document.getElementById('1507.04918v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1507.04918v1-abstract-full" style="display: none;"> The analysis of the properties of rare-earth based materials relies on the Crystalline Electric Field theory. This theory has to be reconsidered in case of cage-type compounds, where the rare-earth ion can substantially depart from its, high symmetry, average position. It is shown that, in case of an orbital degeneracy at the cage center, a specific Jahn-Teller effect develops in the paramagnetic range: at low temperature, the distribution of the magnetic ion spreads inside the cage, the magnetic entropy is reduced, whereas the cage multipolar susceptibilities are increased. These consequences are put in relation with the properties of some metallic rare-earth cage compounds. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1507.04918v1-abstract-full').style.display = 'none'; document.getElementById('1507.04918v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 17 July, 2015; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> July 2015. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1306.5723">arXiv:1306.5723</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1306.5723">pdf</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Materials Science">cond-mat.mtrl-sci</span> </div> </div> <p class="title is-5 mathjax"> TASC-1D-cSi: a simulation tool to scrutinize the thermal impacts on the performances of crystalline silicon solar cells </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Dupr%C3%A9%2C+O">Olivier Dupr茅</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">Mohamed Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Vaillon%2C+R">Rodolphe Vaillon</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1306.5723v1-abstract-short" style="display: inline;"> The capabilities of a simulation tool for the in-depth analysis of the thermal impacts on the performances of solar cells are described. TASC-1D (Thermal Analysis of Solar Cells - 1D, version cSi) solves the coupled electrical, radiative and thermal transport problems for a crystalline silicon cell, as a function of irradiation and thermal conditions. In addition to the electrical outputs that are&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1306.5723v1-abstract-full').style.display = 'inline'; document.getElementById('1306.5723v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1306.5723v1-abstract-full" style="display: none;"> The capabilities of a simulation tool for the in-depth analysis of the thermal impacts on the performances of solar cells are described. TASC-1D (Thermal Analysis of Solar Cells - 1D, version cSi) solves the coupled electrical, radiative and thermal transport problems for a crystalline silicon cell, as a function of irradiation and thermal conditions. In addition to the electrical outputs that are obtained with the existing simulation tools, it provides the cell equilibrium temperature as well as the spatial and spectral distributions of many relevant quantities. The physical modeling and associated numerical solution techniques are summarized. Result cases with a prescribed cell temperature demonstrate that the code performs well, is able to provide valuable information on the quantum efficiency and power loss mechanisms, and is capable of handling diffuse irradiations. The intricate correlation between thermal sources and optical-electrical losses is discussed. The other cases include the solution of the heat transfer problem and analyses are conducted on the cell operating temperature and efficiency as a function of the thermal conditions. This simulation tool is likely to allow new optimizations of photovoltaic cells that include a thermal criterion in addition to the optical and electrical criteria. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1306.5723v1-abstract-full').style.display = 'none'; document.getElementById('1306.5723v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 30 May, 2013; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> June 2013. </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1110.2039">arXiv:1110.2039</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/1110.2039">pdf</a>, <a href="https://arxiv.org/ps/1110.2039">ps</a>, <a href="https://arxiv.org/format/1110.2039">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1103/PhysRevLett.108.026402">10.1103/PhysRevLett.108.026402 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> CeB6 macroscopically revisited </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">M. Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Gal%C3%A9ra%2C+R+-">R. -M. Gal茅ra</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1110.2039v1-abstract-short" style="display: inline;"> Magnetic susceptibility anisotropy and high sensitivity magnetostriction measurements are used to investigate the symmetry of CeB6 ordered states. The antiferromagnetic state is confirmed as tetragonal, but no deviation from the cubic symmetry is observed in the so-called antiferroquadrupolar phase, where only volume effects are detected. In this phase, the temperature dependence of the strain fie&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1110.2039v1-abstract-full').style.display = 'inline'; document.getElementById('1110.2039v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1110.2039v1-abstract-full" style="display: none;"> Magnetic susceptibility anisotropy and high sensitivity magnetostriction measurements are used to investigate the symmetry of CeB6 ordered states. The antiferromagnetic state is confirmed as tetragonal, but no deviation from the cubic symmetry is observed in the so-called antiferroquadrupolar phase, where only volume effects are detected. In this phase, the temperature dependence of the strain field-susceptibilities is typical of non-ordered quadrupoles. Moreover, while an antiferroquadruplar order should be cubic, this symmetry is incompatible with the &lt;1/2 1/2 1/2&gt; ordering wave-vector. The antiferroquadrupolar description of CeB6 phase II is clearly inconsistent and an alternative model, based on a unidimensional representation of the cube, has to be sought for. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1110.2039v1-abstract-full').style.display = 'none'; document.getElementById('1110.2039v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 10 October, 2011; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> October 2011. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">Submitted to PRL, the 7th of October 2011</span> </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/0812.4330">arXiv:0812.4330</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/0812.4330">pdf</a>, <a href="https://arxiv.org/ps/0812.4330">ps</a>, <a href="https://arxiv.org/format/0812.4330">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> </div> <p class="title is-5 mathjax"> On the ferromagnetic structure of the intermetallic borocarbide TbCo2B2C </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=ElMassalami%2C+M">M. ElMassalami</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Moreno%2C+R">R. Moreno</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Saeed%2C+R+M">R. M. Saeed</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Chaves%2C+F+A+B">F. A. B. Chaves</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Chaves%2C+C+M">C. M. Chaves</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Takeya%2C+H">H. Takeya</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Ouladdiaf%2C+B">B. Ouladdiaf</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">M. Amara</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="0812.4330v1-abstract-short" style="display: inline;"> Based on magnetization, specific heat, magnetostriction, and neutron diffraction studies on single-crystal TbCo2B2C, it is found out that the paramagnetic properties, down to liquid nitrogen temperatures, are well described by a Curie-Weiss behavior of the Tb+3 moments. Furthermore, below Tc= 6.3 K, the Tb-sublattice undergoes a ferromagnetic (FM) phase transition with the easy axis being along&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('0812.4330v1-abstract-full').style.display = 'inline'; document.getElementById('0812.4330v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="0812.4330v1-abstract-full" style="display: none;"> Based on magnetization, specific heat, magnetostriction, and neutron diffraction studies on single-crystal TbCo2B2C, it is found out that the paramagnetic properties, down to liquid nitrogen temperatures, are well described by a Curie-Weiss behavior of the Tb+3 moments. Furthermore, below Tc= 6.3 K, the Tb-sublattice undergoes a ferromagnetic (FM) phase transition with the easy axis being along the (100) direction and, concomitantly, the unit cell undergoes a tetragonal-to-orthorhhombic distortion. For fields up to 90 kOe, no field-induced splitting of the Co 3d orbitals was observed; as such the internal field must be well below the critical value needed to polarize the Co 3d subsystem. The manifestation of a FM state in TbCo2B2C is unique among all other isomorphous borocarbides, in particular TbNi2B2C (Tn=15 K, incommensurate modulated magnetic state) even though the Tb-ions in both isomorphs have almost the same crystalline electric field properties. The difference in the magnetic modes of these Tb-based isomorphs is attributed to a difference in their exchange couplings caused by a variation in their lattice parameters and in the position of their Fermi levels. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('0812.4330v1-abstract-full').style.display = 'none'; document.getElementById('0812.4330v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 22 December, 2008; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> December 2008. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">9 figures</span> </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/cond-mat/0302521">arXiv:cond-mat/0302521</a> <span>&nbsp;[<a href="https://arxiv.org/pdf/cond-mat/0302521">pdf</a>, <a href="https://arxiv.org/ps/cond-mat/0302521">ps</a>, <a href="https://arxiv.org/format/cond-mat/0302521">other</a>]&nbsp;</span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Materials Science">cond-mat.mtrl-sci</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Strongly Correlated Electrons">cond-mat.str-el</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1103/PhysRevB.67.144421">10.1103/PhysRevB.67.144421 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Magnetic Phase Diagram of GdNi2B2C: Two-ion Magnetoelasticity and Anisotropic Exchange Couplings </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/cond-mat?searchtype=author&amp;query=Massalami%2C+M+E">M. El Massalami</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Takeya%2C+H">H. Takeya</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Hirata%2C+K">K. Hirata</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Amara%2C+M">M. Amara</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Galera%2C+R+-">R. -M. Galera</a>, <a href="/search/cond-mat?searchtype=author&amp;query=Schmitt%2C+D">D. Schmitt</a> </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="cond-mat/0302521v1-abstract-short" style="display: inline;"> Extensive magnetization and magnetostriction measurements were carried out on a single crystal of GdNi2B2C along the main tetragonal axes. Within the paramagnetic phase, the magnetic and strain susceptibilities revealed a weak anisotropy in the exchange couplings and two-ion tetragonal-preserving alpha-strain modes. Within the ordered phase, magnetization and magnetostriction revealed a relative&hellip; <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('cond-mat/0302521v1-abstract-full').style.display = 'inline'; document.getElementById('cond-mat/0302521v1-abstract-short').style.display = 'none';">&#9661; More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="cond-mat/0302521v1-abstract-full" style="display: none;"> Extensive magnetization and magnetostriction measurements were carried out on a single crystal of GdNi2B2C along the main tetragonal axes. Within the paramagnetic phase, the magnetic and strain susceptibilities revealed a weak anisotropy in the exchange couplings and two-ion tetragonal-preserving alpha-strain modes. Within the ordered phase, magnetization and magnetostriction revealed a relatively strong orthorhombic distortion mode and rich field-temperature phase diagrams. For H//(100) phase diagram, three field-induced transformations were observed, namely, at: Hd(T), related to the domain alignment; Hr(T), associated with reorientation of the moment towards the c-axis; and Hs(T), defining the saturation process wherein the exchange field is completely counterbalanced. On the other hand, For H//(001) phase diagram, only two field-induced transformations were observed, namely at: Hr(T) and Hs(T). For both phase diagrams, Hs(T) follows the relation Hs[1-(T/Tn)^2]^(1/2)kOe with Hs(T--&gt;0)=128.5(5) kOe and Tn(H=0)=19.5 K. In contrast, the thermal evolution of Hr(T) along the c-axis (much simpler than along the a-axis) follows the relation Hr[1-T/Tr]^(1/3) kOe where Hr(T--&gt;0)=33.5(5) kOe and Tr(H=0)=13.5 K. It is emphasized that the magnetoelastic interaction and the anisotropic exchange coupling are important perturbations and therefore should be explicitly considered if a complete analysis of the magnetic properties of the borocarbides is desired. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('cond-mat/0302521v1-abstract-full').style.display = 'none'; document.getElementById('cond-mat/0302521v1-abstract-short').style.display = 'inline';">&#9651; Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 25 February, 2003; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> February 2003. </p> </li> </ol> <div class="is-hidden-tablet"> <!-- feedback for mobile only --> <span class="help" style="display: inline-block;"><a href="https://github.com/arXiv/arxiv-search/releases">Search v0.5.6 released 2020-02-24</a>&nbsp;&nbsp;</span> </div> </div> </main> <footer> 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