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title="建议你登录，尽管并非必须。[o]" accesskey="o"><span class="vector-icon mw-ui-icon-logIn mw-ui-icon-wikimedia-logIn"></span> <span>登录</span></a></li> </ul> </div> </div> <div id="p-user-menu-anon-editor" class="vector-menu mw-portlet mw-portlet-user-menu-anon-editor" > <div class="vector-menu-heading"> 未登录编辑者的页面 <a href="/wiki/Help:%E6%96%B0%E6%89%8B%E5%85%A5%E9%97%A8" aria-label="了解有关编辑的更多信息"><span>了解详情</span></a> </div> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="pt-anoncontribs" class="mw-list-item"><a href="/wiki/Special:%E6%88%91%E7%9A%84%E8%B4%A1%E7%8C%AE" title="来自此IP地址的编辑列表[y]" accesskey="y"><span>贡献</span></a></li><li id="pt-anontalk" class="mw-list-item"><a href="/wiki/Special:%E6%88%91%E7%9A%84%E8%AE%A8%E8%AE%BA%E9%A1%B5" title="对于来自此IP地址编辑的讨论[n]" accesskey="n"><span>讨论</span></a></li> </ul> </div> </div> </div> </div> </nav> </div> </header> </div> <div class="mw-page-container"> <div class="mw-page-container-inner"> <div class="vector-sitenotice-container"> <div id="siteNotice"></div> </div> <div class="vector-column-start"> <div class="vector-main-menu-container"> <div id="mw-navigation"> <nav id="mw-panel" class="vector-main-menu-landmark" aria-label="站点"> <div id="vector-main-menu-pinned-container" class="vector-pinned-container"> </div> </nav> </div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="目录" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">目录</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">隐藏</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">序言</div> </a> </li> <li id="toc-制备" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#制备"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>制备</span> </div> </a> <button aria-controls="toc-制备-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>开关制备子章节</span> </button> <ul id="toc-制备-sublist" class="vector-toc-list"> <li id="toc-过臭氧过程" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#过臭氧过程"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.1</span> <span>过臭氧过程</span> </div> </a> <ul id="toc-过臭氧过程-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-结构" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#结构"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>结构</span> </div> </a> <ul id="toc-结构-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-酸性" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#酸性"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>酸性</span> </div> </a> <ul id="toc-酸性-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-反应" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#反应"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>反应</span> </div> </a> <ul id="toc-反应-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-存在与存在形式" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#存在与存在形式"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>存在与存在形式</span> </div> </a> <ul id="toc-存在与存在形式-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-参考文献" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考文献"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>参考文献</span> </div> </a> <ul id="toc-参考文献-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">过三氧化氢</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。21种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-21" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">21种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%AB%D9%84%D8%A7%D8%AB%D9%8A_%D8%A3%D9%83%D8%B3%D9%8A%D8%AF_%D8%AB%D9%86%D8%A7%D8%A6%D9%8A_%D8%A7%D9%84%D9%87%D9%8A%D8%AF%D8%B1%D9%88%D8%AC%D9%8A%D9%86" title="ثلاثي أكسيد ثنائي الهيدروجين – 阿拉伯语" lang="ar" hreflang="ar" data-title="ثلاثي أكسيد ثنائي الهيدروجين" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D8%AA%D8%B1%DB%8C%D8%A7%D9%88%DA%A9%D8%B3%DB%8C%D8%AF%D8%A7%D9%86" title="تریاوکسیدان – South Azerbaijani" lang="azb" hreflang="azb" data-title="تریاوکسیدان" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Trioxidan" title="Trioxidan – 捷克语" lang="cs" hreflang="cs" data-title="Trioxidan" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Dihydrogentrioxid" title="Dihydrogentrioxid – 德语" lang="de" hreflang="de" data-title="Dihydrogentrioxid" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%A4%CF%81%CE%B9%CE%BF%CE%BE%CE%B5%CE%B9%CE%B4%CE%AC%CE%BD%CE%B9%CE%BF" title="Τριοξειδάνιο – 希腊语" lang="el" hreflang="el" data-title="Τριοξειδάνιο" data-language-autonym="Ελληνικά" data-language-local-name="希腊语" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Trioxidane" title="Trioxidane – 英语" lang="en" hreflang="en" data-title="Trioxidane" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Trioxidano" title="Trioxidano – 西班牙语" lang="es" hreflang="es" data-title="Trioxidano" data-language-autonym="Español" data-language-local-name="西班牙语" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%AA%D8%B1%DB%8C%E2%80%8C%D8%A7%DA%A9%D8%B3%DB%8C%D8%AF%D8%A7%D9%86" title="تری‌اکسیدان – 波斯语" lang="fa" hreflang="fa" data-title="تری‌اکسیدان" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Trioxyde_d%27hydrog%C3%A8ne" title="Trioxyde d'hydrogène – 法语" lang="fr" hreflang="fr" data-title="Trioxyde d'hydrogène" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Dihidrog%C3%A9n-trioxid" title="Dihidrogén-trioxid – 匈牙利语" lang="hu" hreflang="hu" data-title="Dihidrogén-trioxid" data-language-autonym="Magyar" data-language-local-name="匈牙利语" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%83%88%E3%83%AA%E3%82%AA%E3%82%AD%E3%82%B7%E3%83%80%E3%83%B3" title="トリオキシダン – 日语" lang="ja" hreflang="ja" data-title="トリオキシダン" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%EC%82%BC%EC%82%B0%ED%99%94_%EC%88%98%EC%86%8C" title="삼산화 수소 – 韩语" lang="ko" hreflang="ko" data-title="삼산화 수소" data-language-autonym="한국어" data-language-local-name="韩语" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-ms mw-list-item"><a href="https://ms.wikipedia.org/wiki/Trioksidana" title="Trioksidana – 马来语" lang="ms" hreflang="ms" data-title="Trioksidana" data-language-autonym="Bahasa Melayu" data-language-local-name="马来语" class="interlanguage-link-target"><span>Bahasa Melayu</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Tritlenek_diwodoru" title="Tritlenek diwodoru – 波兰语" lang="pl" hreflang="pl" data-title="Tritlenek diwodoru" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Trioxidano" title="Trioxidano – 葡萄牙语" lang="pt" hreflang="pt" data-title="Trioxidano" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%A2%D1%80%D0%B8%D0%BE%D0%BA%D1%81%D0%B8%D0%B4_%D0%B4%D0%B8%D0%B2%D0%BE%D0%B4%D0%BE%D1%80%D0%BE%D0%B4%D0%B0" title="Триоксид диводорода – 俄语" lang="ru" hreflang="ru" data-title="Триоксид диводорода" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Trioksidan" title="Trioksidan – 塞尔维亚-克罗地亚语" lang="sh" hreflang="sh" data-title="Trioksidan" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="塞尔维亚-克罗地亚语" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sl mw-list-item"><a href="https://sl.wikipedia.org/wiki/Divodikov_trioksid" title="Divodikov trioksid – 斯洛文尼亚语" lang="sl" hreflang="sl" data-title="Divodikov trioksid" data-language-autonym="Slovenščina" data-language-local-name="斯洛文尼亚语" class="interlanguage-link-target"><span>Slovenščina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Trioksidan" title="Trioksidan – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Trioksidan" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Trioksidan" title="Trioksidan – 土耳其语" lang="tr" hreflang="tr" data-title="Trioksidan" data-language-autonym="Türkçe" data-language-local-name="土耳其语" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%93%D1%96%D0%B4%D1%80%D0%BE%D0%B3%D0%B5%D0%BD_%D1%82%D1%80%D0%B8%D0%BE%D0%BA%D1%81%D0%B8%D0%B4" title="Гідроген триоксид – 乌克兰语" lang="uk" hreflang="uk" data-title="Гідроген триоксид" data-language-autonym="Українська" data-language-local-name="乌克兰语" class="interlanguage-link-target"><span>Українська</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q417642#sitelinks-wikipedia" title="编辑跨语言链接" class="wbc-editpage">编辑链接</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav aria-label="命名空间"> <div id="p-associated-pages" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-associated-pages" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-nstab-main" class="selected vector-tab-noicon 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.mbox-text-span{margin-left:23px!important}@media(min-width:720px){.mw-parser-output .ambox{margin:0 10%}}@media screen{html.skin-theme-clientpref-night .mw-parser-output .ambox{border-left-color:#36c!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-speedy,html.skin-theme-clientpref-night .mw-parser-output .ambox-delete{border-left-color:#b32424!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-speedy{background-color:#300!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-content{border-left-color:#f28500!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-style{border-left-color:#fc3!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-move{border-left-color:#9932cc!important}html.skin-theme-clientpref-night .mw-parser-output .ambox-protection{border-left-color:#a2a9b1!important}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ambox{border-left-color:#36c!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-speedy,html.skin-theme-clientpref-os .mw-parser-output .ambox-delete{border-left-color:#b32424!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-speedy{background-color:#300!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-content{border-left-color:#f28500!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-style{border-left-color:#fc3!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-move{border-left-color:#9932cc!important}html.skin-theme-clientpref-os .mw-parser-output .ambox-protection{border-left-color:#a2a9b1!important}}</style><table class="box-Expert_needed plainlinks metadata ambox ambox-content" role="presentation"><tbody><tr><td class="mbox-image"><div style="width:52px"><span typeof="mw:File"><span><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/b/b4/Ambox_important.svg/40px-Ambox_important.svg.png" decoding="async" width="40" height="40" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/b4/Ambox_important.svg/60px-Ambox_important.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/b4/Ambox_important.svg/80px-Ambox_important.svg.png 2x" data-file-width="40" data-file-height="40" /></span></span></div></td><td class="mbox-text"><div class="mbox-text-span">此條目需要<b>精通或熟悉<a href="/wiki/%E5%8C%96%E5%AD%A6" class="mw-redirect" title="化学">化学</a>的编者</b>参与及协助编辑。<span class="hide-when-compact"></span> <small class="date-container"><i>(<span class="date">2011年9月26日</span>)</i></small><span class="hide-when-compact"><br /><small>請<a href="/wiki/Wikipedia:%E5%B0%88%E5%AE%B6%E9%82%80%E8%AB%8B%E5%B7%A5%E4%BD%9C%E5%B0%8F%E7%B5%84" title="Wikipedia:專家邀請工作小組">邀請</a>適合的人士<a class="external text" href="https://zh.wikipedia.org/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit">改善本条目</a>。更多的細節與詳情請參见<a href="/wiki/Talk:%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2" title="Talk:过三氧化氢">討論頁</a>。</small></span><span class="hide-when-compact"></span></div></td></tr></tbody></table> <style data-mw-deduplicate="TemplateStyles:r84001320">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox nounderlines" cellspacing="0" cellpadding="3" rules="all" style="background-color:#f0f0f0; float:right; margin: 0 0 1em 1em; border-color: #aaaaaa; border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">过三氧化氢 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Trioxidan.svg" class="mw-file-description" title="过三氧化氢的结构式"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Trioxidan.svg/121px-Trioxidan.svg.png" decoding="async" width="121" height="30" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Trioxidan.svg/182px-Trioxidan.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Trioxidan.svg/242px-Trioxidan.svg.png 2x" data-file-width="151" data-file-height="38" /></a></span> </td></tr> <tr> <td colspan="2" style="max-width:305px; word-wrap: break-word; text-align: center;"><a href="/wiki/IUPAC%E5%91%BD%E5%90%8D%E6%B3%95" title="IUPAC命名法">IUPAC名</a><br />Trioxidane<br />三氧烷 </td></tr> <tr> <td>别名 </td> <td>三氧化二氢 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=14699-99-1">14699-99-1</a></span> <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/PubChem" title="PubChem">PubChem</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/166717">166717</a></span> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.chemspider.com/145859">145859</a></span> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">[H]OOO[H]</span></li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChI</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0">1/H2O3/c1-3-2/h1-2H</li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChIKey</a> </td> <td><small>JSPLKZUTYZBBKA-UHFFFAOYAV</small> </td></tr> <tr> <td><a href="/wiki/%E7%9B%96%E5%A2%A8%E6%9E%97%E6%95%B0%E6%8D%AE%E5%BA%93" title="盖墨林数据库">Gmelin</a> </td> <td>200290 </td></tr> <tr> <td><a href="/wiki/ChEBI" title="ChEBI">ChEBI</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:46736">46736</a></span> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td>H<sub>2</sub>O<sub>3</sub> </td></tr> <tr> <td><a href="/wiki/%E6%91%A9%E5%B0%94%E8%B4%A8%E9%87%8F" title="摩尔质量">摩尔质量</a> </td> <td>50.01 g·mol<sup>−1</sup> </td></tr> <tr> <td>外观 </td> <td><style data-mw-deduplicate="TemplateStyles:r83946278">.mw-parser-output .template-facttext{background-color:var(--background-color-neutral,#eaecf0);color:inherit;margin:-.3em 0;padding:.3em 0}</style><mark class="template-facttext" title="需要提供文献来源">无色至微紫色<a href="/wiki/%E6%B6%B2%E4%BD%93" title="液体">液体</a></mark><sup class="noprint Template-Fact"><a href="/wiki/Wikipedia:%E5%88%97%E6%98%8E%E6%9D%A5%E6%BA%90" title="Wikipedia:列明来源"><span style="white-space: nowrap;" title="来源请求。">[來源請求]</span></a></sup> </td></tr> <tr> <td><a href="/wiki/%E5%AF%86%E5%BA%A6" title="密度">密度</a> </td> <td>1.672 g/cm<sup>3</sup> </td></tr> <tr> <td><a href="/wiki/%E6%BA%B6%E8%A7%A3%E6%80%A7" class="mw-redirect" title="溶解性">溶解性</a>（<a href="/wiki/%E6%B0%B4" title="水">水</a>） </td> <td>与<a href="/wiki/%E6%B0%B4" title="水">水</a><a href="/wiki/%E6%B7%B7%E6%BA%B6" title="混溶">混溶</a> </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明，所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态（25 ℃，100 kPa）</a>下。 </td></tr></tbody></table> <p><b>过三氧化氢</b>也称为“<b>三氧化氢</b>”或“<b>三氧化二氢</b>”，其<a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a>为“H<sub>2</sub>O<sub>3</sub>”或“HOOOH”，是<a href="/wiki/%E6%B0%A2" title="氢">氢</a><a href="/wiki/%E5%85%83%E7%B4%A0" class="mw-redirect" title="元素">元素</a>的<a href="/wiki/%E6%B0%A7%E5%8C%96%E7%89%A9" title="氧化物">氧化物</a>。他是一种不稳定的<a href="/wiki/%E5%8C%96%E5%90%88%E7%89%A9" title="化合物">化合物</a>，在<a href="/wiki/%E6%B0%B4" title="水">水</a><a href="/wiki/%E6%BA%B6%E6%B6%B2" title="溶液">溶液</a>中会分解为水和<a href="/wiki/%E5%96%AE%E7%B7%9A%E6%85%8B%E6%B0%A7" title="單線態氧">单线态氧</a>： </p> <dl><dd><span typeof="mw:File"><a href="/wiki/File:Trioxidane_decomposition.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/92/Trioxidane_decomposition.png/400px-Trioxidane_decomposition.png" decoding="async" width="400" height="105" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/92/Trioxidane_decomposition.png/600px-Trioxidane_decomposition.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/92/Trioxidane_decomposition.png/800px-Trioxidane_decomposition.png 2x" data-file-width="3855" data-file-height="1015" /></a></span></dd></dl> <p>上述反应的<a href="/wiki/%E9%80%86%E5%8F%8D%E5%BA%94" class="mw-redirect" title="逆反应">逆反应</a>（向水分子中插入单线态氧原子）一般情况下由于单线态氧原子不足而速率小于正反应速率。 </p><p>理论研究表明，过三氧化氢有顺式和反式共两种<a href="/wiki/%E5%BC%82%E6%9E%84%E4%BD%93" class="mw-redirect" title="异构体">异构体</a>，其中反式异构体比顺式异构体更稳定。二阶全活化空间微扰理论（complete active space perturbation theory of second order，CASPT2）预测结果显示，在单激发态中，顺式过三氧化氢寿命最长的激发态为21A"，<a href="/w/index.php?title=%E8%B7%83%E8%BF%81%E8%83%BD&action=edit&redlink=1" class="new" title="跃迁能（页面不存在）">跃迁能</a>为167.43<a href="/wiki/%E7%BA%B3%E7%B1%B3" title="纳米">nm</a>，寿命为1.44×10<sup>-5</sup><a href="/wiki/%E7%A7%92" title="秒">s</a>；而反式过三氧化氢寿命最长的激发态为21A，其跃迁能为165.52nm，寿命为2.07×10<sup>-5</sup>s。<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p><p>在<a href="/wiki/%E7%94%9F%E5%91%BD%E7%B3%BB%E7%BB%9F" class="mw-redirect" title="生命系统">生命系统</a>中，<a href="/wiki/%E8%87%AD%E6%B0%A7" title="臭氧">臭氧</a>是由单线态氧形成的，现在推测其原理是：臭氧是单线态氧与水产生的H<sub>2</sub>O<sub>3</sub>的抗体<a href="/wiki/%E5%82%AC%E5%8C%96" title="催化">催化</a><a href="/wiki/%E4%BA%A7%E7%89%A9_(%E5%8C%96%E5%AD%A6)" title="产物 (化学)">产物</a>。<sup id="cite_ref-nyffeler_2-0" class="reference"><a href="#cite_note-nyffeler-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="制备"><span id=".E5.88.B6.E5.A4.87"></span>制备</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&section=1" title="编辑章节：制备"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>过三氧化氢可由<a href="/wiki/%E8%87%AD%E6%B0%A7" title="臭氧">O<sub>3</sub></a>和<a href="/wiki/%E8%BF%87%E6%B0%A7%E5%8C%96%E6%B0%A2" title="过氧化氢">H<sub>2</sub>O<sub>2</sub></a>的反应或<a href="/w/index.php?title=%E6%B0%B4%E7%9A%84%E7%94%B5%E8%A7%A3&action=edit&redlink=1" class="new" title="水的电解（页面不存在）">水的电解</a>少量制备。用以上两种反应制得的过H<sub>2</sub>O<sub>3</sub>的量虽然较少，但已可检测出其存在。 </p><p>若需获得大量H<sub>2</sub>O<sub>3</sub>，则要利用<a href="/w/index.php?title=%E6%9C%89%E6%9C%BA%E8%BF%98%E5%8E%9F%E5%89%82&action=edit&redlink=1" class="new" title="有机还原剂（页面不存在）">有机还原剂</a>（例如<a href="/wiki/%E6%B0%AB%E5%8C%96%E5%81%B6%E6%B0%AE%E8%8B%AF" class="mw-redirect" title="氫化偶氮苯">氢化偶氮苯</a>）在<a href="/wiki/%E6%9C%89%E6%9C%BA%E6%BA%B6%E5%89%82" title="有机溶剂">有机溶剂</a>中低温<a href="/wiki/%E8%BF%98%E5%8E%9F%E5%8F%8D%E5%BA%94" class="mw-redirect" title="还原反应">还原</a>O<sub>3</sub>，H<sub>2</sub>O<sub>3</sub>也能在<a href="/w/index.php?title=%E6%9C%89%E6%9C%BA%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&redlink=1" class="new" title="有机过三氧化氢（页面不存在）">有机过三氧化氢</a>分解时产生（ROOOH）。<sup id="cite_ref-Bozo_3-0" class="reference"><a href="#cite_note-Bozo-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="过臭氧过程"><span id=".E8.BF.87.E8.87.AD.E6.B0.A7.E8.BF.87.E7.A8.8B"></span>过臭氧过程</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&section=2" title="编辑章节：过臭氧过程"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>O<sub>3</sub>与H<sub>2</sub>O<sub>2</sub>反应（<a href="/w/index.php?title=%E8%BF%87%E8%87%AD%E6%B0%A7%E5%8C%96&action=edit&redlink=1" class="new" title="过臭氧化（页面不存在）">过臭氧化</a>）的过程也被称为“<a href="/w/index.php?title=%E8%BF%87%E8%87%AD%E6%B0%A7%E8%BF%87%E7%A8%8B&action=edit&redlink=1" class="new" title="过臭氧过程（页面不存在）">过臭氧过程</a>”（Peroxone process）。而O<sub>3</sub>与H<sub>2</sub>O<sub>2</sub>的<a href="/wiki/%E6%B7%B7%E5%90%88%E7%89%A9" title="混合物">混合物</a>曾被用作含有各种<a href="/wiki/%E6%9C%89%E6%9C%BA%E5%8C%96%E5%90%88%E7%89%A9" title="有机化合物">有机化合物</a>的<a href="/wiki/%E5%9C%B0%E4%B8%8B%E6%B0%B4" title="地下水">地下水</a>的处理剂。上述反应也能产生H<sub>2</sub>O<sub>5</sub>及一些<a href="/wiki/%E7%8E%AF%E7%8A%B6%E5%8C%96%E5%90%88%E7%89%A9" title="环状化合物">环状化合物</a>。<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="结构"><span id=".E7.BB.93.E6.9E.84"></span>结构</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&section=3" title="编辑章节：结构"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/%E5%85%89%E8%B0%B1%E5%AD%A6" title="光谱学">光谱学</a>分析已指出H<sub>2</sub>O<sub>3</sub><a href="/wiki/%E5%88%86%E5%AD%90" title="分子">分子</a>具有曲折的结构（H-O-O-O-H），具有C<sub>2</sub>对称性，其中，H<sub>2</sub>O<sub>3</sub>O-O键的<a href="/wiki/%E9%94%AE%E9%95%BF" title="键长">键长</a>约为142.8<a href="/wiki/%E7%9A%AE%E7%B1%B3" title="皮米">pm</a>，略短于H<sub>2</sub>O<sub>3</sub>中的146.4pm。O-H键的键长为96.6pm，H-O-O键角为101.9°，O-O-O键角为106.8°，H-O-O-O二面角为81.2°。<sup id="cite_ref-Bozo_3-1" class="reference"><a href="#cite_note-Bozo-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p><p>H<sub>2</sub>O<sub>3</sub>还可能以多种<a href="/wiki/%E4%BA%8C%E8%81%9A%E4%BD%93" class="mw-redirect" title="二聚体">二聚体</a>及<a href="/wiki/%E4%B8%89%E8%81%9A%E4%BD%93" title="三聚体">三聚体</a>的形式存在。 </p> <div class="mw-heading mw-heading2"><h2 id="酸性"><span id=".E9.85.B8.E6.80.A7"></span>酸性</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&section=4" title="编辑章节：酸性"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>H<sub>2</sub>O<sub>3</sub>是一种弱电解质，其酸性比<a href="/wiki/%E8%BF%87%E6%B0%A7%E5%8C%96%E6%B0%A2" title="过氧化氢">H<sub>2</sub>O<sub>2</sub></a>略强，在溶液中可电离产生<a href="/wiki/%E6%B0%A2%E6%AD%A3%E7%A6%BB%E5%AD%90" title="氢正离子">H<sup>+</sup></a>和OOOH<sup>-</sup>。<sup id="cite_ref-Roto_5-0" class="reference"><a href="#cite_note-Roto-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="反应"><span id=".E5.8F.8D.E5.BA.94"></span>反应</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&section=5" title="编辑章节：反应"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>其能自发地分解为水与单线态氧。室温下有机溶剂中的H<sub>2</sub>O<sub>3</sub>的<a href="/wiki/%E5%8D%8A%E8%A1%B0%E6%9C%9F" title="半衰期">半衰期</a>约为16<a href="/wiki/%E5%88%86%E9%92%9F" title="分钟">min</a>，而H<sub>2</sub>O<sub>3</sub>在水中的半衰期只有几<a href="/wiki/%E6%AF%AB%E7%A7%92" class="mw-redirect" title="毫秒">毫秒</a>。 </p><p>H<sub>2</sub>O<sub>3</sub>能与<a href="/wiki/%E6%9C%89%E6%9C%BA%E7%A1%AB%E5%8C%96%E7%89%A9" class="mw-redirect" title="有机硫化物">有机硫化物</a>反应生成<a href="/wiki/%E4%BA%9A%E7%A0%9C" title="亚砜">亚砜</a>，但现在对这类反应的了解仍不多。 </p> <div class="mw-heading mw-heading2"><h2 id="存在与存在形式"><span id=".E5.AD.98.E5.9C.A8.E4.B8.8E.E5.AD.98.E5.9C.A8.E5.BD.A2.E5.BC.8F"></span>存在与存在形式</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&section=6" title="编辑章节：存在与存在形式"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>由于在<a href="/wiki/%E7%94%9F%E5%91%BD%E7%B3%BB%E7%BB%9F" class="mw-redirect" title="生命系统">生命系统</a>中H<sub>2</sub>O<sub>3</sub>像臭氧/过氧化氢混合物一样，也能由人体内的抗体能产生，并利用其强氧化性对抗入侵的细菌等病原体。所以新近的研究认为H<sub>2</sub>O<sub>3</sub>是上述混合物中起抗菌作用的活性物质。<sup id="cite_ref-nyffeler_2-1" class="reference"><a href="#cite_note-nyffeler-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup>生命系统中H<sub>2</sub>O<sub>3</sub>由<a href="/wiki/%E5%85%8D%E7%96%AB%E7%B4%B0%E8%83%9E" title="免疫細胞">免疫细胞</a>产生的单线态氧和水反应获得（该化学反应的方向视各物质的浓度而定）。<sup id="cite_ref-Bozo_3-2" class="reference"><a href="#cite_note-Bozo-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </p><p>2005年，H<sub>2</sub>O<sub>3</sub>被利用<a href="/w/index.php?title=%E5%BE%AE%E6%B3%A2%E5%85%89%E8%B0%B1%E5%AD%A6&action=edit&redlink=1" class="new" title="微波光谱学（页面不存在）">微波光谱学</a>在<a href="/wiki/%E8%B6%85%E9%9F%B3%E9%80%9F%E5%AE%A2%E6%9C%BA" class="mw-redirect" title="超音速客机">超音速客机</a>中发现，其分子呈现反式构象（trans conformation），其中的O-O键短于H<sub>2</sub>O<sub>2</sub>中的O-O键。 </p><p><a href="/wiki/%E8%AE%A1%E7%AE%97%E5%8C%96%E5%AD%A6" title="计算化学">计算化学</a>方面的预测表明还可能有包含更多氧原子的<a href="/w/index.php?title=%E9%93%BE%E7%8A%B6%E5%88%86%E5%AD%90&action=edit&redlink=1" class="new" title="链状分子（页面不存在）">链状分子</a>（或多氧化氢）存在，在低温气体中，甚至连具有无数个氧原子的链也可能存在。 </p><p>在该证据支持下，一项对<a href="/wiki/%E6%98%9F%E9%99%85%E7%89%A9%E8%B4%A8" title="星际物质">星际物质</a>中的这类物质的寻找可能将会展开。<sup id="cite_ref-Roto_5-1" class="reference"><a href="#cite_note-Roto-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="参考文献"><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span>参考文献</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&action=edit&section=7" title="编辑章节：参考文献"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><cite class="citation journal">王连宾、吴文鹏、张敬来. <a rel="nofollow" class="external text" href="http://f.wanfangdata.com.cn/view/反式和顺式HOOOH的电子光谱的理论研究.aspx?ID=Periodical_wlhxxb200609009">反式和顺式HOOOH的电子光谱的理论研究</a>. 物理化学学报. 2006, <b>22</b> (8): 1079–1084.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&rft.atitle=%E5%8F%8D%E5%BC%8F%E5%92%8C%E9%A1%BA%E5%BC%8FHOOOH%E7%9A%84%E7%94%B5%E5%AD%90%E5%85%89%E8%B0%B1%E7%9A%84%E7%90%86%E8%AE%BA%E7%A0%94%E7%A9%B6&rft.au=%E7%8E%8B%E8%BF%9E%E5%AE%BE%E3%80%81%E5%90%B4%E6%96%87%E9%B9%8F%E3%80%81%E5%BC%A0%E6%95%AC%E6%9D%A5&rft.date=2006&rft.genre=article&rft.issue=8&rft.jtitle=%E7%89%A9%E7%90%86%E5%8C%96%E5%AD%A6%E5%AD%A6%E6%8A%A5&rft.pages=1079-1084&rft.volume=22&rft_id=http%3A%2F%2Ff.wanfangdata.com.cn%2Fview%2F%E5%8F%8D%E5%BC%8F%E5%92%8C%E9%A1%BA%E5%BC%8FHOOOH%E7%9A%84%E7%94%B5%E5%AD%90%E5%85%89%E8%B0%B1%E7%9A%84%E7%90%86%E8%AE%BA%E7%A0%94%E7%A9%B6.aspx%3FID%3DPeriodical_wlhxxb200609009&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-nyffeler-2"><span class="mw-cite-backlink">^ <a href="#cite_ref-nyffeler_2-0"><sup><b>2.0</b></sup></a> <a href="#cite_ref-nyffeler_2-1"><sup><b>2.1</b></sup></a></span> <span class="reference-text"><cite class="citation journal">Paul T. Nyffeler, Nicholas A. Boyle, Laxman Eltepu, Chi-Huey Wong, Albert Eschenmoser, Richard A. Lerner, Paul Wentworth Jr. Dihydrogen Trioxide (HOOOH) Is Generated during the Thermal Reaction between Hydrogen Peroxide and Ozone. <a href="/wiki/Angewandte_Chemie_International_Edition" class="mw-redirect" title="Angewandte Chemie International Edition">Angewandte Chemie International Edition</a>. 2004, <b>43</b> (35): 4656–4659. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/15317003"><span title="公共医学识别码">PMID 15317003</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1002%2Fanie.200460457"><span title="數位物件識別號">doi:10.1002/anie.200460457</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&rft.atitle=Dihydrogen+Trioxide+%28HOOOH%29+Is+Generated+during+the+Thermal+Reaction+between+Hydrogen+Peroxide+and+Ozone&rft.au=Paul+T.+Nyffeler%2C+Nicholas+A.+Boyle%2C+Laxman+Eltepu%2C+Chi-Huey+Wong%2C+Albert+Eschenmoser%2C+Richard+A.+Lerner%2C+Paul+Wentworth+Jr.&rft.date=2004&rft.genre=article&rft.issue=35&rft.jtitle=Angewandte+Chemie+International+Edition&rft.pages=4656-4659&rft.volume=43&rft_id=info%3Adoi%2F10.1002%2Fanie.200460457&rft_id=info%3Apmid%2F15317003&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-Bozo-3"><span class="mw-cite-backlink">^ <a href="#cite_ref-Bozo_3-0"><sup><b>3.0</b></sup></a> <a href="#cite_ref-Bozo_3-1"><sup><b>3.1</b></sup></a> <a href="#cite_ref-Bozo_3-2"><sup><b>3.2</b></sup></a></span> <span class="reference-text"><cite class="citation journal">Božo Plesničar. Progress in the Chemistry of Dihydrogen Trioxide (HOOOH). Acta Chim. Slov. 2005, <b>52</b>: 1–12.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&rft.atitle=Progress+in+the+Chemistry+of+Dihydrogen+Trioxide+%28HOOOH%29&rft.au=Bo%C5%BEo+Plesni%C4%8Dar&rft.date=2005&rft.genre=article&rft.jtitle=Acta+Chim.+Slov&rft.pages=1-12&rft.volume=52&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-4">^</a></b></span> <span class="reference-text"><cite class="citation journal">Xin Xu and William A. Goddard III. Peroxonechemistry:Formation of H<sub>2</sub>O<sub>3</sub> and ring-(HO<sub>2</sub>)(<sub>HO3</sub>) from O<sub>3</sub>/H<sub>2</sub>O<sub>2</sub>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&rft.atitle=Peroxonechemistry%3AFormation+of+H%3Csub%3E2%3C%2Fsub%3EO%3Csub%3E3%3C%2Fsub%3E+and+ring-%28HO%3Csub%3E2%3C%2Fsub%3E%29%28%3Csub%3EHO3%3C%2Fsub%3E%29+from+O%3Csub%3E3%3C%2Fsub%3E%2FH%3Csub%3E2%3C%2Fsub%3EO%3Csub%3E2%3C%2Fsub%3E&rft.au=Xin+Xu+and+William+A.+Goddard+III&rft.genre=article&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-Roto-5"><span class="mw-cite-backlink">^ <a href="#cite_ref-Roto_5-0"><sup><b>5.0</b></sup></a> <a href="#cite_ref-Roto_5-1"><sup><b>5.1</b></sup></a></span> <span class="reference-text"><cite class="citation journal">Kohsuke Suma, Yoshihiro Sumiyoshi, and Yasuki Endo. <a rel="nofollow" class="external text" href="https://web.archive.org/web/20130523142705/http://pubs.acs.org/acs/journals/doilookup?in_doi=10.1021%2Fja0556530">The Rotational Spectrum and Structure of HOOOH</a>. <a href="/wiki/J._Am._Chem._Soc." class="mw-redirect" title="J. Am. Chem. Soc.">J. Am. Chem. Soc.</a> 2005, <b>127</b> (43): 14998–14999 <span class="reference-accessdate"> [<span class="nowrap">2020-09-19</span>]</span>. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/16248618"><span title="公共医学识别码">PMID 16248618</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fja0556530"><span title="數位物件識別號">doi:10.1021/ja0556530</span></a>. （<a rel="nofollow" class="external text" href="http://pubs3.acs.org/acs/journals/doilookup?in_doi=10.1021/ja0556530">原始内容</a>存档于2013-05-23）.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&rft.atitle=The+Rotational+Spectrum+and+Structure+of+HOOOH&rft.au=Kohsuke+Suma%2C+Yoshihiro+Sumiyoshi%2C+and+Yasuki+Endo&rft.date=2005&rft.genre=article&rft.issue=43&rft.jtitle=J.+Am.+Chem.+Soc.&rft.pages=14998-14999&rft.volume=127&rft_id=http%3A%2F%2Fpubs3.acs.org%2Facs%2Fjournals%2Fdoilookup%3Fin_doi%3D10.1021%2Fja0556530&rft_id=info%3Adoi%2F10.1021%2Fja0556530&rft_id=info%3Apmid%2F16248618&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-6"><span class="mw-cite-backlink"><b><a href="#cite_ref-6">^</a></b></span> <span class="reference-text"><a rel="nofollow" class="external text" href="http://www.scripps.edu/newsandviews/e_20040913/wentworth.html">A Time-Honored Chemical Reaction Generates an Unexpected Product</a> （<a rel="nofollow" class="external text" href="//web.archive.org/web/20191114163727/http://www.scripps.edu/newsandviews/e_20040913/wentworth.html">页面存档备份</a>，存于<a href="/wiki/%E4%BA%92%E8%81%94%E7%BD%91%E6%A1%A3%E6%A1%88%E9%A6%86" title="互联网档案馆">互联网档案馆</a>）, <i>News & Views</i>, September 13, 2004</span> </li> <li id="cite_note-7"><span class="mw-cite-backlink"><b><a href="#cite_ref-7">^</a></b></span> <span class="reference-text"><cite class="citation journal">Roald Hoffmann. <a rel="nofollow" class="external text" href="https://web.archive.org/web/20160303185831/http://www.americanscientist.org/issues/pub/the-story-of-o/5">The Story of O</a>. American Scientist. 2004 <span class="reference-accessdate"> [<span class="nowrap">2011-01-14</span>]</span>. （<a rel="nofollow" class="external text" href="http://www.americanscientist.org/issues/pub/the-story-of-o/5">原始内容</a>存档于2016-03-03）.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E8%BF%87%E4%B8%89%E6%B0%A7%E5%8C%96%E6%B0%A2&rft.atitle=The+Story+of+O&rft.au=Roald+Hoffmann&rft.date=2004&rft.genre=article&rft.jtitle=American+Scientist&rft_id=http%3A%2F%2Fwww.americanscientist.org%2Fissues%2Fpub%2Fthe-story-of-o%2F5&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> </ol></div> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r84265675">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist dt,.mw-parser-output .hlist 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href="/wiki/Template:%E6%B0%A2%E5%8C%96%E5%90%88%E7%89%A9" title="Template:氢化合物"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E6%B0%A2%E5%8C%96%E5%90%88%E7%89%A9" title="Template talk:氢化合物"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E6%B0%A2%E5%8C%96%E5%90%88%E7%89%A9" title="Special:编辑页面/Template:氢化合物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="氢化合物" style="font-size:110%;margin:0 5em"><a href="/wiki/%E6%B0%A2" title="氢">氢</a>化合物</div></th></tr><tr><td colspan="2" class="navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%97%A0%E6%9C%BA%E9%85%B8" title="无机酸">H<sub>x</sub>AO<sub>y</sub></a></li> <li><a href="/wiki/%E7%BE%A7%E9%85%B8" title="羧酸">RCOOH</a></li> <li><a href="/wiki/%E7%A3%BA%E9%85%B8" title="磺酸">RSO<sub>3</sub>H</a></li> <li><a href="/wiki/%E6%B0%A2%E5%8C%96%E7%89%A9" title="氢化物">MH<sub>x</sub></a></li> <li><a href="/wiki/Template:%E4%B8%89%E5%85%83%E6%B0%A2%E5%8C%96%E7%89%A9" title="Template:三元氢化物">M<sub>x</sub>M'<sub>y</sub>H<sub>z</sub></a></li> <li><a href="/wiki/%E6%B0%A2%E6%B0%A7%E5%8C%96%E7%89%A9" class="mw-redirect" title="氢氧化物">M(OH)<sub>x</sub></a></li> <li><a href="/wiki/%E7%83%83" title="烃">C<sub>x</sub>H<sub>y</sub></a></li> <li><a href="/wiki/%E4%B9%99%E7%A1%BC%E7%83%B7" title="乙硼烷">B<sub>2</sub>H<sub>6</sub></a></li> <li><a href="/wiki/%E7%BE%B0%E5%9F%BA%E7%94%B2%E7%A1%BC%E7%83%B7" title="羰基甲硼烷">BH<sub>3</sub>CO</a></li> <li><a href="/wiki/%E6%B0%A8%E7%A1%BC%E7%83%B7" class="mw-redirect" title="氨硼烷">BH<sub>3</sub>NH<sub>3</sub></a></li> <li><a href="/wiki/%E5%8F%94%E4%B8%81%E8%83%BA%E7%94%B2%E7%A1%BC%E7%83%B7" title="叔丁胺甲硼烷">BH<sub>3</sub>NH<sub>2</sub>C<sub>4</sub>H<sub>9</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%91%8B%E5%96%83%E7%A1%BC%E7%83%B7" title="四氢呋喃硼烷">BH<sub>3</sub>OC<sub>4</sub>H<sub>8</sub></a></li> <li><a href="/wiki/%E9%A2%91%E9%82%A3%E9%86%87%E7%A1%BC%E7%83%B7" title="频那醇硼烷">BH(O<sub>2</sub>C<sub>2</sub>(CH<sub>3</sub>)<sub>4</sub>)</a></li> <li><a href="/wiki/%E7%94%B2%E7%A1%AB%E9%86%9A%E7%A1%BC%E7%83%B7" title="甲硫醚硼烷">BH<sub>3</sub>S(CH<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/%E6%B0%A8" title="氨">NH<sub>3</sub></a></li> <li><a href="/wiki/%E9%93%B5%E7%9B%90" class="mw-redirect" title="铵盐">NH<sub>4</sub><sup>+</sup></a></li> <li><a href="/wiki/%E8%81%AF%E6%B0%A8" title="聯氨">N<sub>2</sub>H<sub>4</sub></a></li> <li><a href="/w/index.php?title=%F0%B0%BD%9F%E7%9B%90&action=edit&redlink=1" class="new" title="𰽟盐（页面不存在）">N<sub>2</sub>H<sub>5</sub><sup>+</sup></a></li> <li><a href="/wiki/%E8%83%BA" title="胺">NR<sub>3</sub></a></li> <li><a href="/wiki/%E7%A3%B7%E5%8C%96%E6%B0%A2" title="磷化氢">PH<sub>3</sub></a></li> <li><a href="/wiki/%E8%81%94%E8%86%A6" class="mw-redirect" title="联膦">P<sub>2</sub>H<sub>4</sub></a></li> <li><a href="/wiki/%E8%86%A6" title="膦">PR<sub>3</sub></a></li> <li><a href="/wiki/%E7%A0%B7%E5%8C%96%E6%B0%AB" title="砷化氫">AsH<sub>3</sub></a></li> <li><a href="/wiki/%E9%94%97%E7%83%B7%E5%9F%BA%E8%83%82" title="锗烷基胂">AsH<sub>3</sub>GeH<sub>3</sub></a></li> <li><a href="/wiki/%E9%94%97%E7%83%B7" title="锗烷">GeH<sub>4</sub></a></li></ul> </div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">检索自“<a dir="ltr" href="https://zh.wikipedia.org/w/index.php?title=过三氧化氢&oldid=80816288">https://zh.wikipedia.org/w/index.php?title=过三氧化氢&oldid=80816288</a>”</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Special:%E9%A1%B5%E9%9D%A2%E5%88%86%E7%B1%BB" title="Special:页面分类">分类</a>：<ul><li><a 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