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Sustainable Chemistry and Green Catalysis – Catalysis
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category-green-catalysis tag-biomass-conversion tag-environmental-sustainability tag-green-catalysis tag-ionic-liquids tag-polyoxometalates tag-renewable-feedstocks tag-sustainable-chemistry" itemtype="https://schema.org/CreativeWork" itemscope> <div class="inside-article"> <div class="featured-image page-header-image-single "> <img width="1200" height="628" src="https://catalysis.blog/archive/wp-content/uploads/2024/09/Green-Catalysis-28-min-scaled-e1725645791835.jpg" class="attachment-full size-full" alt="" itemprop="image" decoding="async" fetchpriority="high" /> </div> <header class="entry-header"> <h1 class="entry-title" itemprop="headline">Sustainable Chemistry and Green Catalysis</h1> <div class="entry-meta"> <span class="posted-on"><time class="updated" datetime="2024-09-06T23:33:17+05:30" itemprop="dateModified">September 6, 2024</time><time class="entry-date published" datetime="2024-09-03T15:10:11+05:30" itemprop="datePublished">September 3, 2024</time></span> <span class="byline">by <span class="author vcard" itemprop="author" itemtype="https://schema.org/Person" itemscope><a class="url fn n" href="https://catalysis.blog/archive/author/catalysis/" title="View all posts by catalysis" rel="author" itemprop="url"><span class="author-name" itemprop="name">catalysis</span></a></span></span> </div> </header> <div class="entry-content" itemprop="text"> <p><span style="font-weight: 400;">The growing awareness for environmental sustainability has been the thrust behind enormous developments in the area of chemistry. Sustainable or green chemistry is a type of enterprise that is implicated in the design of products as well as processes that minimize or do not generate and use hazardous materials. Green catalysis, on the other hand, forms a vital component of the green chemistry field and is an area employed in the design of active, non-toxic, and cost-effective catalysts. The present paper reports on new trends in the fields of sustainable chemistry and green catalysis. Emphasis is given to innovative approaches and technologies that decrease the environmental footprint of the chemical industry and enable it to proceed toward the present and future of sustainability.</span></p> <h3><b>Principles of Green Chemistry</b></h3> <p><span style="font-weight: 400;">Green chemistry is based on a set of 12 principles developed to guide chemists in their endeavor to develop processes and products that will be more sustainable. These principles dwell on waste prevention, using renewable feedstocks, energy efficiency, and reduction of toxicity. Following such courses enables chemists to plan processes that are environmental friendly and, at the same time, not only cost-effective but also safe for human health.</span></p> <p><span style="font-weight: 400;">One of the key basic principles underpinning green chemistry is catalysis. A catalyst is a substance that increases the rate of a chemical reaction but is left unchanged in quantity and kind at the end of the reaction. Green catalysis is involved in the development of effective, non-toxic, and renewable catalysts ready to work in mild conditions. Such an approach reduces the environmental impact of chemical processes and raises their efficiency.</span></p> <h3><b>Advances in Green Catalysis</b></h3> <p><span style="font-weight: 400;">Subsequently, in the new horizons developed, there are now green and improved catalysis methods, among other novel catalysts. A good example is the polyoxometalates in catalysis. These have been a topic of great interest. Polyoxometalates are a class of metal-oxygen clusters that show unprecedented properties, rendering them useful in nearly all kinds of catalytic systems. They can fit into the oxidative processes of organic compounds, ester hydrolysis, and the degradation of biomass into value-added chemicals.</span></p> <p><span style="font-weight: 400;">One of the interesting applications of POMs is in the area of nanocatalysis of nerve agent-simulant hydrolysis. Thus, scientists synthesized zirconium-containing POMs, which are good catalysts in the hydrolysis of these toxic compounds, so that the way to their environmentally friendly disposal is opened with an ecologically desired profile. These POMs show very good stability, are easily reusable a number of times without losing activity, and thus reveal the realistic perspectives of their use in practice in processes of decontamination.</span></p> <p><span style="font-weight: 400;">Another important innovation in green catalysis is the use of ionic liquids as solvents and catalysts. ILs are salts that are liquid at room temperature and possess unique properties, including non-volatility, high thermal stability, and tunable solubility. In fact, these very properties make ILs most suitable for use in green catalysis, which could replace conventional organic solvents, which are usually very volatile and often highly toxic. In addition, ILs can be designed to have specific catalytic functions, which further increases their versatility.</span></p> <p><span style="font-weight: 400;">The application of ILs in combination with POMs to form a hybrid catalyst system has also been reported. Based on the proton density of POM and the type of cations in the employed ILs, the resulting hybrid catalysts could be successfully shown to be applied in the conversion of renewable feedstocks, such as biomass, into valuable chemicals. For example, fructose can be efficiently catalyzed to 5-hydroxymethylfurfural (HMF), which is a key bio-based chemical intermediate, using IL-modified POMs. The whole process is useful both as far as renewable resources are concerned and also under mild conditions, and thus saves the overall burden that is put on the environment.</span></p> <p></div></div> <div style="background: #f7f7f7;border: 1px solid rgba(0, 0, 0, 0.07);"> <div style="padding: 30px;"><div class="Adblock-main"> <div class="Adblock-head"> <h2>Yearwise Publication Trend on <b>“<a href="https://catalysis.blog/publication-trends/index/green catalysis" target="_blank" title="green catalysis - yearwise publication trends">green catalysis</a>”</b></h2> </div> </div><div class="results-container"><div class="chart-block" style="padding:15px;"> <div class="left"> <div id="results" class="results"></div> </div> <div class="right"> <div class="chart-container"><canvas id="publicationChart"></canvas></div> </div> <div class="keywordsdiv"> <div style="text-align:center;"><b>Find publication trends on relevant topics</b> </div> <span class="gp-icon icon-tags"><svg viewBox="0 0 512 512" aria-hidden="true" xmlns="http://www.w3.org/2000/svg" width="1em" height="1em"><path d="M20 39.5c-8.836 0-16 7.163-16 16v176c0 4.243 1.686 8.313 4.687 11.314l224 224c6.248 6.248 16.378 6.248 22.626 0l176-176c6.244-6.244 6.25-16.364.013-22.615l-223.5-224A15.999 15.999 0 00196.5 39.5H20zm56 96c0-13.255 10.745-24 24-24s24 10.745 24 24-10.745 24-24 24-24-10.745-24-24z"></path><path d="M259.515 43.015c4.686-4.687 12.284-4.687 16.97 0l228 228c4.686 4.686 4.686 12.284 0 16.97l-180 180c-4.686 4.687-12.284 4.687-16.97 0-4.686-4.686-4.686-12.284 0-16.97L479.029 279.5 259.515 59.985c-4.686-4.686-4.686-12.284 0-16.97z"></path></svg></span> <span id="keyword-stats"></span> </div> </div></div></div><div class="inside-article"><style> table { margin: 0 0 1.5em; 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'NA' : count; tableHTML += ` <tr> <td>${year}</td> <td>${displayCount}</td> </tr> `; }); tableHTML += '</table></div>'; resultsContainer.innerHTML = tableHTML; } function displayLineChart(statistics) { var years = Object.keys(statistics); var counts = Object.values(statistics); var ctx = document.getElementById('publicationChart').getContext('2d'); // Destroy existing chart instance if it exists if (chart !== null) { chart.destroy(); } // Create a new chart instance chart = new Chart(ctx, { type: 'line', data: { labels: years, datasets: [{ label: 'Publication Counts', data: counts, fill: false, borderColor: 'rgba(75, 192, 192, 1)', tension: 0.1 }] }, options: { scales: { y: { beginAtZero: true } }, plugins: { legend: { display: true, position: 'top' } } } }); } function displayKeywordStats(keywords) { var resultsContainer = document.getElementById('keyword-stats'); resultsContainer.innerHTML = ''; if (!keywords || keywords.length === 0) { resultsContainer.innerHTML = '<p>No data found.</p>'; return; } var keywordHTML = ''; keywords.forEach((key, index) => { let key_replace = key.replace(/ /g, '-'); key_replace = key_replace.toLowerCase(); keywordHTML += `<a href="https://catalysis.blog/publication-trends/index/${key_replace}" target="_blank" title="${key} - yearwise publication trends">${key}</a>`; if (index < keywords.length - 1) { keywordHTML += ', '; } }); resultsContainer.innerHTML = keywordHTML; } // Call the function with the PHP data var statistics = { "2014": 35, "2015": 46, "2016": 38, "2017": 60, "2018": 59, "2019": 93, "2020": 124, "2021": 140, "2022": 174, "2023": 393, "2024": 138 }; var keywordsArray = ; displayResults(statistics); displayLineChart(statistics); displayKeywordStats(keywordsArray); </script></p> <h3><b>Renewable Feedstocks and Biomass Conversion</b></h3> <p><span style="font-weight: 400;">Renewable feedstock is all about green chemistry. They are derived from nature and can be well replenished. Biomass is just one good example of it. Sustainable chemistry, transforming valuable chemicals from biomass and fuels, gives this renewable alternative to fossil fuels and consequently decreases the effects of climate change.</span></p> <p><span style="font-weight: 400;">Probably quite a promising approach in biomass conversion is using heteropolyacid-based catalysts that combine this action and convert cellulose, the major biopolymers of biomass, into valuable chemicals, among which are levulinate esters and HMF. These processes include cellulose hydrolysis to glucose and further dehydration of glucose to HMF. In addition, the use of heteropolyacid-based catalysts enhances efficiency in the reaction thus, it will be much more sustainable and economically affordable.</span></p> <p><span style="font-weight: 400;">Second, research has been carried out into bifunctional catalysts linking acid and base sites. These bring possibilities for biomass processing into various forms of products, including fuels, chemicals, and materials. For example, ionic hybrid bifunctional catalysts have been found to be efficient in the selective transformation of glucose to HMF. Using the catalyst, both the acidic and basic sites present can increase the rate of reaction and selectivity of the reaction in hand, thus resulting in a high yield of the desired products.</span></p> <h3><b>Challenges and Future Directions</b></h3> <p><span style="font-weight: 400;">Despite these amazing advances in sustainable chemistry and green catalysis, there are several challenges to be met. The principal one is how to scale the developed processes in the laboratory to industry practice. The bulk of the highly advanced catalysts and techniques developed in the laboratory need to be scaled up for industrial applications. This requires overcoming technical and economic barriers to ensure not only sustainable but also economically feasible new processes.</span></p> <p><span style="font-weight: 400;">Another challenge concerns the development of stable and long-lasting catalysts under industrial conditions. Catalysts that have to obey industrially applied techniques have to face a number of other rigorous conditions high temperatures, for example, above p, that come into play during an industrial process without a loss of activity. Thus, researchers are on their way to design catalysts of improved stability and robustness.</span></p> <p><span style="font-weight: 400;">The implementation of the newly developed materials and processes will, therefore, be strategic in the future development of sustainable chemistry and green catalysis. More applied research can be expected in the fields of computational chemistry and materials science. In this sense, these technologies make the design and optimization of catalysts possible with absolute precision and, therefore, will lead to improved efficiency in the utilization of chemicals and sustainability.</span></p> <p><span style="font-weight: 400;">This further requires integrating the principles of green chemistry into the practice and teaching of the foundations of industry. That is to say, only proper education and the provision of tools and knowledge on sustainability to the future chemist and engineer generation will be able to drive civil society toward a sustainable future in the chemical industry.</span></p> <p></div></div> <div style="background: #f7f7f7;border: 1px solid rgba(0, 0, 0, 0.07);"> <div style="padding: 30px;"><div class="Adblock-main"> <div class="Adblock-head"> <h2>Recent Publications on <b>“<a href="https://catalysis.blog/recent-publications/index/green catalysis" target="_blank" rel="noopener" title="green catalysis - yearwise publication list">green catalysis</a>”</b></h2> </div> </div> <div class="pb-main"><div class="article-scroll"><div id="results_recent" class="results"></div></div><div class="keywordsdiv" style="margin: 0px 15px;margin-top:20px;"> <div style="text-align:center;"><b>Find publications on relevant topics</b> </div> <span class="gp-icon icon-tags"><svg viewBox="0 0 512 512" aria-hidden="true" xmlns="http://www.w3.org/2000/svg" width="1em" height="1em"><path d="M20 39.5c-8.836 0-16 7.163-16 16v176c0 4.243 1.686 8.313 4.687 11.314l224 224c6.248 6.248 16.378 6.248 22.626 0l176-176c6.244-6.244 6.25-16.364.013-22.615l-223.5-224A15.999 15.999 0 00196.5 39.5H20zm56 96c0-13.255 10.745-24 24-24s24 10.745 24 24-10.745 24-24 24-24-10.745-24-24z"></path><path d="M259.515 43.015c4.686-4.687 12.284-4.687 16.97 0l228 228c4.686 4.686 4.686 12.284 0 16.97l-180 180c-4.686 4.687-12.284 4.687-16.97 0-4.686-4.686-4.686-12.284 0-16.97L479.029 279.5 259.515 59.985c-4.686-4.686-4.686-12.284 0-16.97z"></path></svg></span> <span id="keyword-papers"></span> </div></div></div><div class="inside-article"> <style> .pb-main{ border: solid 1px #ccc; border-top: none; margin-bottom: 20px; padding-bottom: 25px; background:#fff; } .author-main { border: solid 1px #ccc; border-top: none; margin-bottom: 20px; padding-bottom: 25px; background:#fff; } .publication-block { padding: 10px; margin-bottom: 10px; background-color: #f9f9f9; text-align: left; background: #FFF; border-bottom: solid 1px #ccc; margin-left: 15px; margin-right: 15px; } .publication-block h3 { margin: 0 0 10px; color: #000!important; } .publication-block a { font-size: 16px !important; line-height: 1em; font-weight: 600; text-transform: none; color: #000; padding: 0px; } .publication-block a:hover{ color: #227cdc; text-decoration:underline; } .article-scroll { max-height: 445px; overflow-y: auto; overflow-x: hidden; } ::-webkit-scrollbar-track { -webkit-box-shadow: inset 0 0 6px rgba(0,0,0,0.3); background-color: #efefef; border-radius:30px; } ::-webkit-scrollbar { width: 6px; background-color: #efefef; border-radius:30px; } ::-webkit-scrollbar-thumb { background-color: #ababab; border-radius:30px; } .publication-block p { margin-bottom: .5em; font-size: 15px; color: #000; } h3 { font-size: 18px !important; margin-bottom: 20px; line-height: 1.2em; font-weight: 600; text-transform: none; } a { padding: 5px; color: #a71c49; } #keyword-papers{ margin-top: 20px; text-align: center; } </style> <script> function decodeString(str) { str = str.replace(/\\'/g, "'"); str = str.replace(/\\'/g, "'"); str = str.replace(/\\'/g, "'"); return str; } function displayResults_recent(papers) { var resultsContainer = document.getElementById('results_recent'); if (!papers || papers.length === 0) { resultsContainer.innerHTML = '<p>No recent publications found.</p>'; return; } papers.forEach(paper => { var publicationBlock = document.createElement('div'); publicationBlock.className = 'publication-block'; var title_de = decodeString(paper.title); var publicationHTML = ` <div style="margin-bottom: 10px;line-height: 24px;"><a href="${paper.url}" target="_blank" title="${title_de}">${title_de}</a></div> <p><strong>Issue Release:</strong> ${paper.publishedDate}</p> `; publicationBlock.innerHTML = publicationHTML; resultsContainer.appendChild(publicationBlock); }); } function displayKeywordPapers(keywords) { var resultsContainer = document.getElementById('keyword-papers'); resultsContainer.innerHTML = ''; if (!keywords || keywords.length === 0) { resultsContainer.innerHTML = '<p>No data found.</p>'; return; } var keywordHTML = ''; keywords.forEach((key, index) => { let key_replace = key.replace(/ /g, '-'); key_replace = key_replace.toLowerCase(); keywordHTML += `<a href="https://catalysis.blog/recent-publications/index/${key_replace}" target="_blank" title="${key} - publication list">${key}</a>`; if (index < keywords.length - 1) { keywordHTML += ', '; } }); resultsContainer.innerHTML = keywordHTML; } // Call the function with the PHP data var recent_papers = [ { "title": "Niobic acid as a support for microheterogeneous nanocatalysis of sodium borohydride hydrolysis under mild conditions.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38887643", "publishedDate": "2024" }, { "title": "Enzyme-mediated green synthesis of glycosaminoglycans and catalytic process intensification.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38857660", "publishedDate": "2024" }, { "title": "Nanotechnology for the enhancement of algal cultivation and bioprocessing: Bridging gaps and unlocking potential.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38914236", "publishedDate": "2024" }, { "title": "Green-synthesized CuO and ZnO nanoparticles derived from Calotropis gigantea (Apple of Sodom): enhancing plant growth, efficient dye removal, and potent antibacterial applications.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38958855", "publishedDate": "2024" }, { "title": "Electronic Structure and Functions of Carbon Nitride in Frontier Green Catalysis.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/39107898", "publishedDate": "2024" }, { "title": "Green Synthesis of Carbon Quantum Dots and Carbon Quantum Dot-Gold Nanoparticles for Applications in Bacterial Imaging and Catalytic Reduction of Aromatic Nitro Compounds.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38854549", "publishedDate": "2024" }, { "title": "Green synthesis for diverse bioactive benzo-fused spiroindolines through DBU-catalysed post-Ugi double cyclization.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38689553", "publishedDate": "2024" }, { "title": "Engineering cascade biocatalysis in whole cells for syringic acid bioproduction.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38824548", "publishedDate": "2024" }, { "title": "Photoredox Catalysis by 21-Thiaporphyrins: A green and Efficient Approach for C-N Borylation and C-H Arylation.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38825798", "publishedDate": "2024" }, { "title": "Progress on metabolites of Astragalus medicinal plants and a new factor affecting their formation: Biotransformation of endophytic fungi.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38838334", "publishedDate": "2024" }, { "title": "Cu-chelated polydopamine nanozymes with laccase-like activity for photothermal catalytic degradation of dyes.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38735253", "publishedDate": "2024" }, { "title": "Classification and functional origins of stereocomplementary alcohol dehydrogenases for asymmetric synthesis of chiral secondary alcohols: A review.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38729463", "publishedDate": "2024" }, { "title": "Isomerization Engineering of Oxygen-Enriched Carbon Quantum Dots for Efficient Electrochemical Hydrogen Peroxide Production.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38713154", "publishedDate": "2024" }, { "title": "Progress and Perspective for \\\\\\\"Green\\\\\\\" Strategies of Catalytic Plastics Conversion into Fuels by Regulating Half-Reactions.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38832898", "publishedDate": "2024" }, { "title": "Surface viscosity of liquid interfaces from Green-Kubo relations.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38775241", "publishedDate": "2024" }, { "title": "Spontaneous Formation of Ultrasmall Noble Metal Nanoparticles on Cobalt-Based Layered Double Hydroxide for Electrochemical and Environmental Catalysis.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38189520", "publishedDate": "2024" }, { "title": "The Synergistic Impact of Crystal Seed and Fluoride Ion in the Synthesis of Silicalite-1 Zeolite in Low-Template Systems.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38204118", "publishedDate": "2024" }, { "title": "Biosynthesis of Nicotinamide Mononucleotide: Synthesis Method, Enzyme, and Biocatalytic System.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38330904", "publishedDate": "2024" }, { "title": "Rare Earths-The Answer to Everything.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38338432", "publishedDate": "2024" }, { "title": "Structural characterization of lignin from the green pretreatments for co-producing xylo-oligosaccharides and glucose: Toward full biomass utilization.", "url": "https:\/\/pubmed.ncbi.nlm.nih.gov\/38211916", "publishedDate": "2024" } ]; var keywordsArray = ; displayResults_recent(recent_papers); displayKeywordPapers(keywordsArray); // function stripslashes(str) { // if (typeof str === 'string') { // return str.replace(/\/g, ''); // } // } </script></p> <h3><b>Conclusion</b></h3> <p><span style="font-weight: 400;">Green catalysis in the context of sustainable chemistry embodies the current wave for creating a future chemical industry that is both environmentally friendly and economically feasible. Recent advances in green catalysis, enforced thermally by the design of polyoxometalates, ionic liquids, and bifunctional catalysts, could change the picture of sustainable chemical processes. The most important aspects of such reorientation are represented by upstream renewable feedstocks and the conversion of biomass into chemicals of added value.</span></p> <p><span style="font-weight: 400;">While challenges remain, the progress made in recent years offers good grounds for an exciting future. Therefore, continued innovation and cooperation among researchers, industry, and policymakers are fundamental to realizing the translation and transformation needed to harness this field’s full potential as sustainable chemistry. The chemical industry can therefore help to shape cleaner and more sustainable living for everybody if it moves toward green catalysis and other sustainable practices.</span></p> <h3 class="citation-actions"><b>References</b></h3> <ol> <li> <div class="oxford-citation-text"><span class="contributors">Anastas, Paul T, and John C Warner, </span><a href="https://academic.oup.com/book/53104"><span class="mainTitle"><em class="inner">Green Chemistry: Theory and Practice</em></span></a> (<span class="publisher-location">Oxford, </span><span class="print-publication-date">2000; </span><span class="online-edition">online edn, </span><span class="containing-site">Oxford Academic</span><span class="online-publication-date">, 31 Oct. 2023</span>).</div> </li> <li>Sheldon, R.A., 2016. <a href="https://pubs.rsc.org/en/content/articlehtml/2016/gc/c6gc90040b">Green chemistry and resource efficiency: towards a green economy.</a> <i>Green Chemistry</i>, <i>18</i>(11), pp.3180-3183.</li> <li>Suib, S.L. ed., 2013. <a href="https://books.google.co.in/books?hl=en&lr=&id=2KEZL6i32MAC&oi=fnd&pg=PR1&dq=New+and+Future+Developments+in+Catalysis:+Catalysis+for+Remediation+and+Environmental+Concerns&ots=VPvm5SNYU0&sig=XssATvWlPVbxOmFN9ro4Q2ZfgWE#v=onepage&q=New%20and%20Future%20Developments%20in%20Catalysis%3A%20Catalysis%20for%20Remediation%20and%20Environmental%20Concerns&f=false">New and future developments in catalysis: Catalysis for remediation and environmental concerns</a>. Newnes.</li> <li>Tong, X. and Li, Y., 2010. <a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cssc.200900224">Efficient and selective dehydration of fructose to 5‐hydroxymethylfurfural catalyzed by brønsted‐acidic ionic liquids</a>. <i>ChemSusChem: Chemistry & Sustainability Energy & Materials</i>, <i>3</i>(3), pp.350-355.</li> <li>Polshettiwar, V. and Varma, R.S., 2010. <a href="https://pubs.rsc.org/en/content/articlelanding/2010/gc/b921171c/unauth">Green chemistry by nano-catalysis.</a> <i>Green Chemistry</i>, <i>12</i>(5), pp.743-754.</li> <li>Tong, X. and Li, Y., 2010. <a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cssc.200900224">Efficient and selective dehydration of fructose to 5‐hydroxymethylfurfural catalyzed by brønsted‐acidic ionic liquids.</a> <i>ChemSusChem: Chemistry & Sustainability Energy & Materials</i>, <i>3</i>(3), pp.350-355.</li> <li><span style="font-weight: 400;">Biomass Conversion: Catalytic Conversion of Biomass to Renewable Chemicals and Fuels.</span></li> </ol> <p></div></div> <div style="background: #f7f7f7;border: 1px solid rgba(0, 0, 0, 0.07);"> <div style="padding: 30px;"><div class="Adblock-main"> <div class="Adblock-head"> <h2>Top Experts on “<b style="color:#000;font-size:22px;">green catalysis</b>“</h2> </div> </div><div class="author-main"><div id="results_author"></div><div style="text-align: center;"><a class="register-button" href="https://catalysis.blog/expert-search" target="_blank" rel="noopener">Find experts on any field</a></div></div><div class="inside-article" style="background: none;border: none;box-shadow: none;margin-top: -70px;"> <style> .author-block { padding: 15px; margin-bottom: 10px; text-align: left; font-size: 15px; line-height: 1.2; background: #FFF; border-bottom: solid 1px #ccc; margin-left: 15px; margin-right: 15px; } .author-block h3 { margin: 0 0 10px; color: #227cdc; } .author-block p { margin: 5px 0; } .author-b { display: flex; justify-content: space-between; flex-wrap: wrap; margin-bottom:10px; } .author-b .ainfo { flex: 1 1 30%; box-sizing: border-box; text-align: left; background: #dcdcdc; padding: 7px 14px; border-radius: 5px; margin-top: 3px; margin-right: 10px; } @media (max-width: 768px) { .author-b .ainfo { flex: 1 1 100%; margin: 10px 0; } } </style> <script> function displayResults_author(authors) { var resultsContainer = document.getElementById('results_author'); resultsContainer.innerHTML = ''; if (!authors || Object.keys(authors).length === 0) { resultsContainer.innerHTML = '<p>No authors found.</p>'; return; } Object.values(authors).slice(0, 10).forEach(author => { if (author.affiliation.length > 400) { return; } var authorBlock = document.createElement('div'); authorBlock.className = 'author-block'; var author_name=author.name; let key_replace = author_name.replace(/ /g, '-'); key_replace = key_replace.toLowerCase(); var authorHTML = ` <h3><a href="https://catalysis.blog/author/index/${key_replace}\/${author.aid}" target="_blank" title="${author.name}">${author.name}</a></h3> <div class="author-b"> <div class="ainfo"><strong>H-Index:</strong> ${author.hindex}</div> <div class="ainfo"><strong>Publication Count:</strong> ${author.paper_count}</div> <div class="ainfo"><strong>Citation Count:</strong> ${author.citation_count}</div> </div> <p><strong>Affiliation:</strong> ${author.affiliation}</p> `; authorBlock.innerHTML = authorHTML; resultsContainer.appendChild(authorBlock); }); } function displayKeywordAuthors(keywords) { var resultsContainer = document.getElementById('keyword-authors'); resultsContainer.innerHTML = ''; if (!keywords || keywords.length === 0) { resultsContainer.innerHTML = '<p>No data found.</p>'; return; } var keywordHTML = ''; keywords.forEach(key => { let key_replace = key.replace(/ /g, '-'); key_replace = key_replace.toLowerCase(); keywordHTML += `<a href="https://catalysis.blog/expert-search/index/${key_replace}" target="_blank" title="${key}">${key}</a>`; }); resultsContainer.innerHTML = keywordHTML; } // Call the function with the PHP data var authors_data = { "lrrYK4wBWBy50K-rs_qL": { "aid": "lrrYK4wBWBy50K-rs_qL", "name": "C. 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