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hydroxymethylfurfural</title> <meta name="description" content="Search results for: hydroxymethylfurfural"> <meta name="keywords" content="hydroxymethylfurfural"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="hydroxymethylfurfural"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 11</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: hydroxymethylfurfural</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">11</span> Bio-Furan Based Poly (β-Thioether Ester) Synthesized via Thiol-Michael Addition Polymerization with Tunable Structure and Properties</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Daihui%20Zhang">Daihui Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Marie%20J.%20Dumont"> Marie J. Dumont</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A derivative of 5-hydroxymethylfurfural (HMF) was synthesized for the thiol-Michael addition reaction. The efficiency of the catalysts (base and nucleophiles) and side reactions during the thiol-Michael addition were investigated. Dimethylphenylphosphine efficiently initiated the thiol-Michael addition polymerization for synthesizing a series of bio-based furan polymers with different structure and properties. The benzene rings or hydroxyl groups present in the polymer chains increased the glass transition temperature (Tg) of poly (β-thioether ester). Additionally, copolymers with various compositions were obtained via adding different ratio of 1,6-hexanedithiols to 1,4-benzenedithiols. 1H NMR analysis revealed that experimental ratios of two dithiols monomers matched well with theoretical ratios. The occurrence of a reversible Diels-Alder reaction between furan rings and maleimide groups allowed poly (β-thioether ester) to be dynamically crosslinked. These polymers offer the potentials to produce materials from biomass that have both practical mechanical properties and reprocessing ability. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=copolymers" title="copolymers">copolymers</a>, <a href="https://publications.waset.org/abstracts/search?q=Diels-Alder%20reaction" title=" Diels-Alder reaction"> Diels-Alder reaction</a>, <a href="https://publications.waset.org/abstracts/search?q=hydroxymethylfurfural" title=" hydroxymethylfurfural"> hydroxymethylfurfural</a>, <a href="https://publications.waset.org/abstracts/search?q=Thiol-Michael%20addition" title=" Thiol-Michael addition"> Thiol-Michael addition</a> </p> <a href="https://publications.waset.org/abstracts/68860/bio-furan-based-poly-v-thioether-ester-synthesized-via-thiol-michael-addition-polymerization-with-tunable-structure-and-properties" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/68860.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">330</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">10</span> Integrated Two Stage Processing of Biomass Conversion to Hydroxymethylfurfural Esters Using Ionic Liquid as Green Solvent and Catalyst: Synthesis of Mono Esters</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Komal%20Kumar">Komal Kumar</a>, <a href="https://publications.waset.org/abstracts/search?q=Sreedevi%20Upadhyayula"> Sreedevi Upadhyayula</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, a two-stage process was established for the synthesis of HMF esters using ionic liquid acid catalyst. Ionic liquid catalyst with different strength of the Bronsted acidity was prepared in the laboratory and characterized using 1H NMR, FT-IR, and 13C NMR spectroscopy. Solid acid catalyst from the ionic liquid catalyst was prepared using the immobilization method. The acidity of the synthesized acid catalyst was measured using Hammett function and titration method. Catalytic performance was evaluated for the biomass conversion to 5-hydroxymethylfurfural (5-HMF) and levulinic acid (LA) in methyl isobutyl ketone (MIBK)-water biphasic system. A good yield of 5-HMF and LA was found at the different composition of MIBK: Water. In the case of MIBK: Water ratio 10:1, good yield of 5-HMF was observed at ambient temperature 150˚C. Upgrading of 5-HMF into monoesters from the reaction of 5-HMF and reactants using biomass-derived monoacid were performed. Ionic liquid catalyst with -SO₃H functional group was found to be best efficient in comparative of a solid acid catalyst for the esterification reaction and biomass conversion. A good yield of 5-HMF esters with high 5-HMF conversion was found to be at 105˚C using the best active catalyst. In this process, process A was the hydrothermal conversion of cellulose and monomer into 5-HMF and LA using acid catalyst. And the process B was the esterification followed by using similar acid catalyst. All monoesters of 5-HMF synthesized here can be used in chemical, cross linker for adhesive or coatings and pharmaceutical industry. A theoretical density functional theory (DFT) study for the optimization of the ionic liquid structure was performed using the Gaussian 09 program to find out the minimum energy configuration of ionic liquid catalyst. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biomass%20conversion" title="biomass conversion">biomass conversion</a>, <a href="https://publications.waset.org/abstracts/search?q=5-HMF" title=" 5-HMF"> 5-HMF</a>, <a href="https://publications.waset.org/abstracts/search?q=Ionic%20liquid" title=" Ionic liquid"> Ionic liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=HMF%20ester" title=" HMF ester"> HMF ester</a> </p> <a href="https://publications.waset.org/abstracts/103568/integrated-two-stage-processing-of-biomass-conversion-to-hydroxymethylfurfural-esters-using-ionic-liquid-as-green-solvent-and-catalyst-synthesis-of-mono-esters" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/103568.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">251</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">9</span> One-Pot Synthesis of 5-Hydroxymethylfurfural from Hexose Sugar over Chromium Impregnated Zeolite Based Catalyst, Cr/H-ZSM-5</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Samuel%20K.%20Degife">Samuel K. Degife</a>, <a href="https://publications.waset.org/abstracts/search?q=Kamal%20K.%20Pant"> Kamal K. Pant</a>, <a href="https://publications.waset.org/abstracts/search?q=Sapna%20Jain"> Sapna Jain</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The world´s population and industrialization of countries continued to grow in an alarming rate irrespective of the security for food, energy supply, and pure water availability. As a result, the global energy consumption is observed to increase significantly. Fossil energy resources that mainly comprised of crude oil, coal, and natural gas have been used by mankind as the main energy source for almost two centuries. However, sufficient evidences are revealing that the consumption of fossil resource as transportation fuel emits environmental pollutants such as CO2, NOx, and SOx. These resources are dwindling rapidly besides enormous amount of problems associated such as fluctuation of oil price and instability of oil-rich regions. Biomass is a promising renewable energy candidate to replace fossil-based transportation fuel and chemical production. The present study aims at valorization of hexose sugars (glucose and fructose) using zeolite based catalysts in imidazolium based ionic liquid (1-butyl-3-methylimidazolium chloride, [BMIM] Cl) reaction media. The catalytic effect chromium impregnated H-ZSM-5 (Cr/H-ZSM-5) was studied for dehydration of hexose sugars. The wet impregnation method was used to prepare Cr/H-ZSM-5 catalyst. The characterization of the prepared catalyst was performed using techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction analysis (XRD), Temperature-programmed desorption of ammonia (NH3-TPD) and BET-surface area analysis. The dehydration product, 5-hydroxymethylfurfural (5-HMF), was analyzed using high-performance liquid chromatography (HPLC). Cr/H-ZSM-5 was effective in dehydrating fructose with 87% conversion and 55% yield 5-HMF at 180 oC for 30 min of reaction time compared with H-ZSM-5 catalyst which yielded only 31% of 5-HMF at identical reaction condition. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=chromium" title="chromium">chromium</a>, <a href="https://publications.waset.org/abstracts/search?q=hexose" title=" hexose"> hexose</a>, <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquid" title=" ionic liquid"> ionic liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=" title=""></a>, <a href="https://publications.waset.org/abstracts/search?q=zeolite" title=" zeolite"> zeolite</a> </p> <a href="https://publications.waset.org/abstracts/86044/one-pot-synthesis-of-5-hydroxymethylfurfural-from-hexose-sugar-over-chromium-impregnated-zeolite-based-catalyst-crh-zsm-5" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/86044.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">176</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">8</span> Application of Thermoplastic Microbioreactor to the Single Cell Study of Budding Yeast to Decipher the Effect of 5-Hydroxymethylfurfural on Growth</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Elif%20Gencturk">Elif Gencturk</a>, <a href="https://publications.waset.org/abstracts/search?q=Ekin%20Yurdakul"> Ekin Yurdakul</a>, <a href="https://publications.waset.org/abstracts/search?q=Ahmet%20Y.%20Celik"> Ahmet Y. Celik</a>, <a href="https://publications.waset.org/abstracts/search?q=Senol%20Mutlu"> Senol Mutlu</a>, <a href="https://publications.waset.org/abstracts/search?q=Kutlu%20O.%20Ulgen"> Kutlu O. Ulgen</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Yeast cells are generally used as a model system of eukaryotes due to their complex genetic structure, rapid growth ability in optimum conditions, easy replication and well-defined genetic system properties. Thus, yeast cells increased the knowledge of the principal pathways in humans. During fermentation, carbohydrates (hexoses and pentoses) degrade into some toxic by-products such as 5-hydroxymethylfurfural (5-HMF or HMF) and furfural. HMF influences the ethanol yield, and ethanol productivity; it interferes with microbial growth and is considered as a potent inhibitor of bioethanol production. In this study, yeast single cell behavior under HMF application was monitored by using a continuous flow single phase microfluidic platform. Microfluidic device in operation is fabricated by hot embossing and thermo-compression techniques from cyclo-olefin polymer (COP). COP is biocompatible, transparent and rigid material and it is suitable for observing fluorescence of cells considering its low auto-fluorescence characteristic. The response of yeast cells was recorded through Red Fluorescent Protein (RFP) tagged Nop56 gene product, which is an essential evolutionary-conserved nucleolar protein, and also a member of the box C/D snoRNP complexes. With the application of HMF, yeast cell proliferation continued but HMF slowed down the cell growth, and after HMF treatment the cell proliferation stopped. By the addition of fresh nutrient medium, the yeast cells recovered after 6 hours of HMF exposure. Thus, HMF application suppresses normal functioning of cell cycle but it does not cause cells to die. The monitoring of Nop56 expression phases of the individual cells shed light on the protein and ribosome synthesis cycles along with their link to growth. Further computational study revealed that the mechanisms underlying the inhibitory or inductive effects of HMF on growth are enriched in functional categories of protein degradation, protein processing, DNA repair and multidrug resistance. The present microfluidic device can successfully be used for studying the effects of inhibitory agents on growth by single cell tracking, thus capturing cell to cell variations. By metabolic engineering techniques, engineered strains can be developed, and the metabolic network of the microorganism can thus be manipulated such that chemical overproduction of target metabolite is achieved along with the maximum growth/biomass yield.   <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=COP" title="COP">COP</a>, <a href="https://publications.waset.org/abstracts/search?q=HMF" title=" HMF"> HMF</a>, <a href="https://publications.waset.org/abstracts/search?q=ribosome%20biogenesis" title=" ribosome biogenesis"> ribosome biogenesis</a>, <a href="https://publications.waset.org/abstracts/search?q=thermoplastic%20microbioreactor" title=" thermoplastic microbioreactor"> thermoplastic microbioreactor</a>, <a href="https://publications.waset.org/abstracts/search?q=yeast" title=" yeast"> yeast</a> </p> <a href="https://publications.waset.org/abstracts/102817/application-of-thermoplastic-microbioreactor-to-the-single-cell-study-of-budding-yeast-to-decipher-the-effect-of-5-hydroxymethylfurfural-on-growth" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/102817.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">171</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">7</span> Agro-Industrial Waste as a Source of Catalyst Production</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Brenda%20Cecilia%20Ledesma">Brenda Cecilia Ledesma</a>, <a href="https://publications.waset.org/abstracts/search?q=Andrea%20Beltramone"> Andrea Beltramone</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This work deals with the bio-waste valorization approach for catalyst development, the use of products derived from biomass as raw material and the obtaining of biofuels. In this research, activated carbons were synthesized from the orange peel using different synthesis conditions. With the activated carbons obtained with the best structure and texture, PtIr bimetallic catalysts were prepared. Carbon activation was carried out through a chemical process with phosphoric acid as an activating agent, varying the acid concentration, the ratio substrate/activating agent and time of contact between them. The best support was obtained using a carbonization time of 1 h, the temperature of carbonization of 470oC, the phosphoric acid concentration of 50 wt.% and a BET area of 1429 m2/g. Subsequently, the metallic nanoparticles were deposited in the activated carbon to use the solid as a catalytic material for the hydrogenation of HMF to 2,5-DMF. The catalyst presented an excellent performance for biofuels generation. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=orange%20peel" title="orange peel">orange peel</a>, <a href="https://publications.waset.org/abstracts/search?q=bio-waste%20valorization" title=" bio-waste valorization"> bio-waste valorization</a>, <a href="https://publications.waset.org/abstracts/search?q=platinum" title=" platinum"> platinum</a>, <a href="https://publications.waset.org/abstracts/search?q=iridium" title=" iridium"> iridium</a>, <a href="https://publications.waset.org/abstracts/search?q=5-hydroxymethylfurfural" title="5-hydroxymethylfurfural">5-hydroxymethylfurfural</a> </p> <a href="https://publications.waset.org/abstracts/142523/agro-industrial-waste-as-a-source-of-catalyst-production" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/142523.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">195</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">6</span> Benzoxaboralone: A Boronic Acid with High Oxidative Stability and Utility in Biological Contexts</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Brian%20J.%20Graham">Brian J. Graham</a>, <a href="https://publications.waset.org/abstracts/search?q=Ronald%20T.%20Raines"> Ronald T. Raines</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The presence of a nearly vacant p orbital on boron endows boronic acids with unique abilities as a catalyst and ligand. An organocatalytic process has been developed for the conversion of biomass-derived sugars to 5-hydroxymethylfurfural, which is a platform chemical. Specifically, 2-carboxyphenylboronic acid (2-CPBA) has been shown to be an optimal catalyst for this process, promoting the desired transformation in the absence of metals. The attributes of 2-CPBA as a catalyst led to additional investigations of its structure and reactivity. 2-CPBA was found to exist as a cyclized benzoxaborolone adduct rather than a free carboxylic acid. This cyclization has profound consequences for the oxidative stability of the boronic acid. Stereoelectronic effects within the oxaborolone ring destabilize the oxidation transition state by reducing electron donation from the cyclic oxygen to the developing p orbital on boron. That leads to a 10,000-fold increase in oxidative stability while maintaining the normal reactivity of boronic acids toward diols (e.g., carbohydrates) and nucleophiles in proteins while also presenting numerous hydrogen-bond accepting and donating groups. Thus, benzoxaborolones are useful in catalysis, chemical biology, medicinal chemistry, and allied fields. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bioisosteres" title="bioisosteres">bioisosteres</a>, <a href="https://publications.waset.org/abstracts/search?q=boronic%20acid" title=" boronic acid"> boronic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=catalysis" title=" catalysis"> catalysis</a>, <a href="https://publications.waset.org/abstracts/search?q=oxidative%20stability" title=" oxidative stability"> oxidative stability</a>, <a href="https://publications.waset.org/abstracts/search?q=pharmacophore" title=" pharmacophore"> pharmacophore</a>, <a href="https://publications.waset.org/abstracts/search?q=stereoelectronic%20effects" title=" stereoelectronic effects"> stereoelectronic effects</a> </p> <a href="https://publications.waset.org/abstracts/140795/benzoxaboralone-a-boronic-acid-with-high-oxidative-stability-and-utility-in-biological-contexts" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/140795.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">189</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5</span> Hydrodeoxygenation of Furfural over RU Sub-Nano Particles Supported on Al₂O₃-SIO₂ Mixed Oxides</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Chaima%20Zoulikha%20Tabet%20Zatla">Chaima Zoulikha Tabet Zatla</a>, <a href="https://publications.waset.org/abstracts/search?q=Nihel%20Dib"> Nihel Dib</a>, <a href="https://publications.waset.org/abstracts/search?q=Sumeya%20Bedrane"> Sumeya Bedrane</a>, <a href="https://publications.waset.org/abstracts/search?q=Juan%20Carlos%20Hernandez%20Garrido"> Juan Carlos Hernandez Garrido</a>, <a href="https://publications.waset.org/abstracts/search?q=Redouane%20Bachir"> Redouane Bachir</a>, <a href="https://publications.waset.org/abstracts/search?q=Miguel%20Angel%20Cauqui"> Miguel Angel Cauqui</a>, <a href="https://publications.waset.org/abstracts/search?q=Jose%20Juan%20Calvino%20Gamez"> Jose Juan Calvino Gamez</a> </p> <p class="card-text"><strong>Abstract:</strong></p> These last year's our planet has witnessed global warming, which is a serious threat to our lives; it has many causes, such as the CO₂ excess in the atmosphere that results from our activity, for the purpose of living in a neater and better environment, working and improving an eco-responsible energy system is a must. Valorization of biomass to produce biofuels is among the most compelling routes to decrease air pollution without considerable modification in current vehicle technology. Effective transformation of lignocellulosic biomass-derived compounds into liquid fuels and value-added chemicals is an economically viable solution. Presently, very competitive technics for the conversion of lignocellulosic biomass into platform chemicals, such as furfural and Hydroxymethylfurfural (HMF), are used. Furfural (C₅H₄O₂) is a major hemi cellulosic biomass-derived platform molecule. In our work, we focus on the valorization of lignocellulosic biomass derivative furfural that is transformed into biofuel through a hydrodeoxygenation reaction in general and involving a catalytic process. In order to get to this point, we are synthesizing and characterizing a series of catalysts with different amounts of Ru (0.5%, 1% and 2%) supported on alumina-silica mixed oxides with various molar ratios (Si/Al = 2.5; 5; 7; 10; 15). These catalysts will be characterized by numerous technics such as N₂ adsorption/desorption, Pyridine adsorption (acidity measure), FTIR, X-rays diffraction, AAS, TEM and SEM. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=furfural" title="furfural">furfural</a>, <a href="https://publications.waset.org/abstracts/search?q=ruthenium" title=" ruthenium"> ruthenium</a>, <a href="https://publications.waset.org/abstracts/search?q=silica-alumina" title=" silica-alumina"> silica-alumina</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass" title=" biomass"> biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=biofuel" title=" biofuel"> biofuel</a> </p> <a href="https://publications.waset.org/abstracts/163321/hydrodeoxygenation-of-furfural-over-ru-sub-nano-particles-supported-on-al2o3-sio2-mixed-oxides" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/163321.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">84</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4</span> Chemical Composition and Biological Properties of Algerian Honeys</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ouchemoukh%20Salim">Ouchemoukh Salim</a>, <a href="https://publications.waset.org/abstracts/search?q=Amessis-Ouchemoukh%20Nadia"> Amessis-Ouchemoukh Nadia</a>, <a href="https://publications.waset.org/abstracts/search?q=Guenaoui%20Nawel"> Guenaoui Nawel</a>, <a href="https://publications.waset.org/abstracts/search?q=Moumeni%20Lynda"> Moumeni Lynda</a>, <a href="https://publications.waset.org/abstracts/search?q=Zaidi%20Hicham"> Zaidi Hicham</a>, <a href="https://publications.waset.org/abstracts/search?q=Otmani%20Amar"> Otmani Amar</a>, <a href="https://publications.waset.org/abstracts/search?q=Sadou%20Dyhia">Sadou Dyhia</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Honey is a hive food rich in carbohydrates and water and it also has a lot of nutrients (enzymes, minerals, organic acids, phytochemicals...). It is used in different nutritional and therapeutic fields. Algerian honey was studied for its physicochemical parameters, nutritional values (moisture, brix, pH, electrical conductivity, and amounts of HMF, proteins, proline, total phenolic compounds and flavonoids) and some biological activities (antioxidant, anti-inflammatory and enzymatic anti-browning). The antioxidant activities of the samples were estimated using different methods (ABTS, DPPH free radicals scavenging, reducing power, and chelating ferrous activity). All honeys were acidic (3.45≤pH≤4.65). The color varied from mimosa yellow to dark brown. The specific rotation was levorotatory in most honey samples, and the electrical conductivity, hydroxymethylfurfural, and proline values agreed with the international honey requirements. For anti-inflammatory activity, the results showed that the inhibiting capacity of the denaturation of the BSA of the honey analyzed varied from 15 to 75 % with a maximum of activity at the concentration of 0,5 mg/ml. All honey exhibited enzymatic anti-browning on different slices of fruits. In fact, the results showed that the controls have the greatest browning unit compared to the honeys studied and PPO and POD enzymes had the lowest enzyme activity. High significant correlations were found between the color of honey, its antioxidant content and its biological activities (antioxidant, anti-inflammatory and enzymatic anti-browning). The dark color of honey is a good indicator of the best biological properties, therefore, the best nutritional and therapeutic values. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=honey" title="honey">honey</a>, <a href="https://publications.waset.org/abstracts/search?q=physico-chemical%20parameters" title=" physico-chemical parameters"> physico-chemical parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=bioactive%20compounds" title=" bioactive compounds"> bioactive compounds</a>, <a href="https://publications.waset.org/abstracts/search?q=biological%20properties" title=" biological properties"> biological properties</a> </p> <a href="https://publications.waset.org/abstracts/185000/chemical-composition-and-biological-properties-of-algerian-honeys" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/185000.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">55</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3</span> Humins: From Industrial By-Product to High Value Polymers</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Pierluigi%20Tosi">Pierluigi Tosi</a>, <a href="https://publications.waset.org/abstracts/search?q=Ed%20de%20Jong"> Ed de Jong</a>, <a href="https://publications.waset.org/abstracts/search?q=Gerard%20van%20Klink"> Gerard van Klink</a>, <a href="https://publications.waset.org/abstracts/search?q=Luc%20Vincent"> Luc Vincent</a>, <a href="https://publications.waset.org/abstracts/search?q=Alice%20Mija"> Alice Mija</a> </p> <p class="card-text"><strong>Abstract:</strong></p> During the last decades renewable and low-cost resources have attracted increasingly interest. Carbohydrates can be derived by lignocellulosic biomasses, which is an attractive option since they represent the most abundant carbon source available in nature. Carbohydrates can be converted in a plethora of industrially relevant compounds, such as 5-hydroxymethylfurfural (HMF) and levulinic acid (LA), within acid catalyzed dehydration of sugars with mineral acids. Unfortunately, these acid catalyzed conversions suffer of the unavoidable formation of highly viscous heterogeneous poly-disperse carbon based materials known as humins. This black colored low value by-product is made by a complex mixture of macromolecules built by covalent random condensations of the several compounds present during the acid catalyzed conversion. Humins molecular structure is still under investigation but seems based on furanic rings network linked by aliphatic chains and decorated by several reactive moieties (ketones, aldehydes, hydroxyls, …). Despite decades of research, currently there is no way to avoid humins formation. The key parameter for enhance the economic viability of carbohydrate conversion processes is, therefore, increasing the economic value of the humins by-product. Herein are presented new humins based polymeric materials that can be prepared starting from the raw by-product by thermal treatment, without any step of purification or pretreatment. Humins foams can be produced with the control of reaction key parameters, obtaining polymeric porous materials with designed porosity, density, thermal and electrical conductivity, chemical and electrical stability, carbon amount and mechanical properties. Physico chemical properties can be enhanced by modifications on the starting raw material or adding different species during the polymerization. A comparisons on the properties of different compositions will be presented, along with tested applications. The authors gratefully acknowledge the European Community for financial support through Marie-Curie H2020-MSCA-ITN-2015 "HUGS" Project. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=by-product" title="by-product">by-product</a>, <a href="https://publications.waset.org/abstracts/search?q=humins" title=" humins"> humins</a>, <a href="https://publications.waset.org/abstracts/search?q=polymers" title=" polymers"> polymers</a>, <a href="https://publications.waset.org/abstracts/search?q=valorization" title=" valorization "> valorization </a> </p> <a href="https://publications.waset.org/abstracts/78782/humins-from-industrial-by-product-to-high-value-polymers" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/78782.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">143</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">2</span> Antiangiogenic and Pro-Apoptotic Properties of Shemamruthaa: An Herbal Preparation in Experimental Mammary Carcinoma-Bearing Rats and Breast Cancer Cell Line In vitro</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nandhakumar%20Elumalai">Nandhakumar Elumalai</a>, <a href="https://publications.waset.org/abstracts/search?q=Purushothaman%20Ayyakannu"> Purushothaman Ayyakannu</a>, <a href="https://publications.waset.org/abstracts/search?q=Sachidanandam%20T.%20Panchanatham"> Sachidanandam T. Panchanatham</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Background: Understanding the basic mechanisms and factors underlying the tumor growth and invasion has gained attention in recent times. The processes of angiogenesis and apoptosis are known to play a vital role in various stages of cancer. The vascular endothelial growth factor (VEGF) is well established as one of the key regulators of tumor angiogenesis while MMPs are known for their exclusive ability to degrade ECM. Objective: The present study was designed to evaluate the pro apoptotic and anti angiogenic activity of the herbal formulation Shemamruthaa. The anticancer activity of Shemamruthaa was tested in breast cancer cell line (MCF-7). Results of MTT, trypan blue and flow cytometric analysis of apoptotis suggested that Shemamruthaa can induce cytotoxicity in cancer cells, in a concentration- and time dependent manner and induce apoptosis. With these results, we further evaluated the antiangiogenic and pro-apoptotic activities of Shemamruthaa in DMBA induced mammary carcinoma in Sprague Dawley rats. Flavono tumour was induced in 8-week-old Sprague-Dawley rats by gastric intubation of 25 mg DMBA in 1ml olive oil. After 90 days of induction period, the rats were orally administered with Shemamruthaa (400 mg/kg body wt) for 45 days. Treatment with the drug SM significantly modulated the expression of p53, MMP-2, MMP-3, MMP-9 and VEGF by means of its anti angiogenic and protease inhibiting activity. Conclusion: Based on these results, it might be concluded that the formulation, Shemamruthaa, constituted of dried flowers of Hibiscus rosa-sinensis, fruits of Emblica officinalis, and honey has been found to exhibit pronounced antiproliferative and apoptotic effects. This enhanced anticancer effect of Shemamruthaa might be attributed to the synergistic action of polyphenols such as flavonoids, tannins, alkaloids, glycosides, saponins, steroids, terpenoids, vitamin C, niacin, pyrogallol, hydroxymethylfurfural, trilinolein, and other compounds present in the formulation. Collectively, these results demonstrate that Shemamruthaa holds potential to be developed as a potent chemotherapeutic agent against mammary carcinoma. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Shemamruthaa" title="Shemamruthaa">Shemamruthaa</a>, <a href="https://publications.waset.org/abstracts/search?q=flavonoids" title=" flavonoids"> flavonoids</a>, <a href="https://publications.waset.org/abstracts/search?q=MCF-7%20cell%20line" title=" MCF-7 cell line"> MCF-7 cell line</a>, <a href="https://publications.waset.org/abstracts/search?q=mammary%20cancer" title=" mammary cancer"> mammary cancer</a> </p> <a href="https://publications.waset.org/abstracts/64047/antiangiogenic-and-pro-apoptotic-properties-of-shemamruthaa-an-herbal-preparation-in-experimental-mammary-carcinoma-bearing-rats-and-breast-cancer-cell-line-in-vitro" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/64047.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">252</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">1</span> Harvesting Value-added Products Through Anodic Electrocatalytic Upgrading Intermediate Compounds Utilizing Biomass to Accelerating Hydrogen Evolution</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mehran%20Nozari-Asbemarz">Mehran Nozari-Asbemarz</a>, <a href="https://publications.waset.org/abstracts/search?q=Italo%20Pisano"> Italo Pisano</a>, <a href="https://publications.waset.org/abstracts/search?q=Simin%20Arshi"> Simin Arshi</a>, <a href="https://publications.waset.org/abstracts/search?q=Edmond%20Magner"> Edmond Magner</a>, <a href="https://publications.waset.org/abstracts/search?q=James%20J.%20Leahy"> James J. Leahy</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Integrating electrolytic synthesis with renewable energy makes it feasible to address urgent environmental and energy challenges. Conventional water electrolyzers concurrently produce H₂ and O₂, demanding additional procedures in gas separation to prevent contamination of H₂ with O₂. Moreover, the oxygen evolution reaction (OER), which is sluggish and has a low overall energy conversion efficiency, does not deliver a significant value product on the electrode surface. Compared to conventional water electrolysis, integrating electrolytic hydrogen generation from water with thermodynamically more advantageous aqueous organic oxidation processes can increase energy conversion efficiency and create value-added compounds instead of oxygen at the anode. One strategy is to use renewable and sustainable carbon sources from biomass, which has a large annual production capacity and presents a significant opportunity to supplement carbon sourced from fossil fuels. Numerous catalytic techniques have been researched in order to utilize biomass economically. Because of its safe operating conditions, excellent energy efficiency, and reasonable control over production rate and selectivity using electrochemical parameters, electrocatalytic upgrading stands out as an appealing choice among the numerous biomass refinery technologies. Therefore, we propose a broad framework for coupling H2 generation from water splitting with oxidative biomass upgrading processes. Four representative biomass targets were considered for oxidative upgrading that used a hierarchically porous CoFe-MOF/LDH @ Graphite Paper bifunctional electrocatalyst, including glucose, ethanol, benzyl, furfural, and 5-hydroxymethylfurfural (HMF). The potential required to support 50 mA cm-2 is considerably lower than (~ 380 mV) the potential for OER. All four compounds can be oxidized to yield liquid byproducts with economic benefit. The electrocatalytic oxidation of glucose to the value-added products, gluconic acid, glucuronic acid, and glucaric acid, was examined in detail. The cell potential for combined H₂ production and glucose oxidation was substantially lower than for water splitting (1.44 V(RHE) vs. 1.82 V(RHE) for 50 mA cm-2). In contrast, the oxidation byproduct at the anode was significantly more valuable than O₂, taking advantage of the more favorable glucose oxidation in comparison to the OER. Overall, such a combination of HER and oxidative biomass valorization using electrocatalysts prevents the production of potentially explosive H₂/O₂mixtures and produces high-value products at both electrodes with lower voltage input, thereby increasing the efficiency and activity of electrocatalytic conversion. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biomass" title="biomass">biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=electrocatalytic" title=" electrocatalytic"> electrocatalytic</a>, <a href="https://publications.waset.org/abstracts/search?q=glucose%20oxidation" title=" glucose oxidation"> glucose oxidation</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogen%20evolution" title=" hydrogen evolution"> hydrogen evolution</a> </p> <a href="https://publications.waset.org/abstracts/162039/harvesting-value-added-products-through-anodic-electrocatalytic-upgrading-intermediate-compounds-utilizing-biomass-to-accelerating-hydrogen-evolution" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/162039.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">96</span> </span> </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/WASET-16th-foundational-anniversary.pdf">WASET 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