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Catalytic Mechanisms in Chemical Engineering – Catalysis
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category-chemical-engineering tag-catalysis tag-catalytic-mechanisms tag-chemical-engineering tag-enzymatic-catalysis tag-green-chemistry tag-heterogeneous-catalysis tag-homogeneous-catalysis tag-metal-complexes tag-photocatalysis tag-reaction-kinetics" itemtype="https://schema.org/CreativeWork" itemscope> <div class="inside-article"> <div class="featured-image page-header-image-single "> <img width="1200" height="628" src="https://catalysis.blog/archive/wp-content/uploads/2024/10/banner-min-scaled-e1730101483133.jpg" class="attachment-full size-full" alt="" itemprop="image" decoding="async" fetchpriority="high" /> </div> <header class="entry-header"> <h1 class="entry-title" itemprop="headline">Catalytic Mechanisms in Chemical Engineering</h1> <div class="entry-meta"> <span class="posted-on"><time class="entry-date published" datetime="2024-10-28T13:14:52+05:30" itemprop="datePublished">October 28, 2024</time></span> <span class="byline">by <span class="author vcard" itemprop="author" itemtype="https://schema.org/Person" itemscope><a class="url fn n" href="https://catalysis.blog/archive/author/catalysis/" title="View all posts by catalysis" rel="author" itemprop="url"><span class="author-name" itemprop="name">catalysis</span></a></span></span> </div> </header> <div class="entry-content" itemprop="text"> <p><span style="font-weight: 400;">Catalysis plays a very central role in chemical engineering and underpins many industrial processes, from petroleum refining and the production of pharmaceuticals to the development of renewable energy sources. The suitability of catalysts as accelerators in chemical reactions, without their own changes by the process, makes them irreplaceable in both classical and innovative applications. Over the years, newly exposed mechanistic insight of catalysis has gone ahead to open ways for the development of more effective, selective, and sustainable reactions. </span></p> <h3><b>Heterogeneous Catalysis in Surface Phenomena and Reaction Dynamics</b></h3> <p><span style="font-weight: 400;">This type of catalysis, where the catalyst is in a different phase than the reactants, typically solid catalysts in interaction with gaseous or liquid reactants, is quite common in industrial chemical processes. The catalyst surface holds most of the reaction mechanism. In a heterogeneous catalysis, reactants are adsorbed on the active sites located on the surface of catalysts, where the conversion will take place prior to the desorption of the products. Effectiveness is related to parameters in heterogeneous catalysts, such as surface area, nature of active sites, and strength of the interaction between the catalyst and reactants.</span></p> <p><span style="font-weight: 400;">Understanding and optimizing the surface phenomena that control the dynamics of reactions are critical issues in heterogeneous catalysis. The nature and distribution of active sites on the catalyst surface may significantly affect the reaction rate and selectivity. For example, during the synthesis of ammonia through the Haber-Bosch process, the structure comprising iron atoms on the surface of the catalyst determines the successful cleavage of nitrogen molecules into atoms, a step that proves to be a very critical pathway in the mechanism of reaction.</span></p> <h3><b>Homogeneous Catalysis in Molecular Precision in Solution</b></h3> <p><span style="font-weight: 400;">In contrast to heterogeneous catalysis, a homogeneous catalyst is able to be employed in the same phase as the reactant most often, dissolved in a solution. More specifically, a homogeneous catalyst can be commonly identified by its molecular specificity, in which it is known to interact with reactants through well-defined coordination complexes at the molecular level. The concept of this catalysis is therefore applied to such homogeneous processes as polymerization, hydroformylation, and hydrogenation.</span></p> <p><span style="font-weight: 400;">In most mechanisms of homogeneous catalysis, the intervention of intermediate species that allow easy atom or group transfer between reactants is involved. For example, during hydroformylation of alkenes using a rhodium-based catalyst, such a complex forms with carbon monoxide and hydrogen, which are then added as a formyl group to the alkene. It is humanly possible to control the electronic and steric properties of the catalyst by ligand design for effecting a pathway of reaction with control on its product distribution.</span></p> <p></div></div> <div style="background: #f7f7f7;border: 1px solid rgba(0, 0, 0, 0.07);"> <div style="padding: 30px;"><div class="Adblock-main"> <div class="Adblock-head"> <h2>Yearwise Publication Trend on <b>“<a href="https://catalysis.blog/publication-trends/index/chemical engineering" target="_blank" title="chemical engineering - yearwise publication trends">chemical engineering</a>”</b></h2> </div> </div><div class="results-container"><div class="chart-block" style="padding:15px;"> <div class="left"> <div id="results" class="results"></div> </div> <div class="right"> <div class="chart-container"><canvas id="publicationChart"></canvas></div> </div> <div class="keywordsdiv"> <div style="text-align:center;"><b>Find publication trends on relevant topics</b> </div> <span class="gp-icon icon-tags"><svg viewBox="0 0 512 512" aria-hidden="true" xmlns="http://www.w3.org/2000/svg" width="1em" height="1em"><path d="M20 39.5c-8.836 0-16 7.163-16 16v176c0 4.243 1.686 8.313 4.687 11.314l224 224c6.248 6.248 16.378 6.248 22.626 0l176-176c6.244-6.244 6.25-16.364.013-22.615l-223.5-224A15.999 15.999 0 00196.5 39.5H20zm56 96c0-13.255 10.745-24 24-24s24 10.745 24 24-10.745 24-24 24-24-10.745-24-24z"></path><path d="M259.515 43.015c4.686-4.687 12.284-4.687 16.97 0l228 228c4.686 4.686 4.686 12.284 0 16.97l-180 180c-4.686 4.687-12.284 4.687-16.97 0-4.686-4.686-4.686-12.284 0-16.97L479.029 279.5 259.515 59.985c-4.686-4.686-4.686-12.284 0-16.97z"></path></svg></span> <span id="keyword-stats"></span> </div> </div></div></div><div class="inside-article"><style> table { margin: 0 0 1.5em; 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if (!statistics || Object.keys(statistics).length === 0) { resultsContainer.innerHTML = '<p>No data found.</p>'; return; } var tableHTML = `<div class='pub-scroll'> <table class='tablediv' border='1' cellspacing='0' cellpadding='0'> <tr> <th>Year</th> <th>Publication Count</th> </tr>`; Object.entries(statistics).sort(([yearA], [yearB]) => yearB - yearA).forEach(([year, count]) => { const displayCount = count === 0 ? 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This specificity and efficiency of enzymatic catalysis generally result in rates many orders of magnitude higher than those of corresponding uncatalyzed reactions. Mechanisms of enzymatic catalysis position substrates precisely within an active site such that they undergo a series of highly orchestrated steps that lead to the formation of products.</span></p> <p><span style="font-weight: 400;">Enzymatic catalysis studies have contributed so much to the design of synthetic catalysts. Many researchers, by replicating a part of the active sites of enzymes, have succeeded in launching catalysts that can give very high selectivity and efficiency of an industrial process. For example, the observation of stereoselectivity for enzymatic reactions has prompted the development of chiral catalysts for asymmetric synthesis, which is of importance to pharmaceutical production.</span></p> <h3><b>Photocatalysis Harnessing Light for Chemical Transformations</b></h3> <p><span style="font-weight: 400;">Photocatalysis, an emerging field in which light energy drives chemical reactions with a catalyst, bears much promise for the development of resultant applications, solar energy conversion, environmental remediation, and green chemistry. It is conceptual that by which way the catalyst absorbs photons to generate electron-hole pairs that can induce redox reactions with selected reactants.</span></p> <p><span style="font-weight: 400;">One challenging problem in photocatalysis is the effective utilization of light energy. In fact, the development of an appropriate photocatalyst with an optimal band gap to compare with the energy of the incident light has been a prime factor for maximum efficiency in the process. In addition, photocatalyst stability under long exposure to light and prevention of electron-hole pair recombination are other important factors exerting influence on the efficiency of the overall performance of the catalytic system.</span></p> <h3><b>Catalysis by Metal Coordination Complexes</b></h3> <p><span style="font-weight: 400;">Homogeneous catalysis is based on metal coordination complexes, although heterogeneous catalysis is also relied upon, whereby a metal catalyst activates substrates in reactions through coordination processes. The nature of the ligands in the coordination sphere may strongly modify catalytic activity, throwing open a way to finely tune the reactivity and selectivity of the catalyst.</span></p> <p><span style="font-weight: 400;">In most homogeneous catalysis, metal complexes act to stabilize transition states or intermediates, which in turn lead to a decrease in the activation energy of the reaction. For example, in alkene hydrogenation by a transition metal complex, an intermediate of metal hydride can be generated to facilitate the addition of hydrogen to the double bond. In such a manner, perfect control of the catalytic process can be achieved through the possibility of modification of the electronic properties in the metal center due to the appropriate design of the ligand.</span></p> <p><span style="font-weight: 400;">In most cases of heterogeneous catalysis, metal complex catalysts are supported on solid substrates, thereby creating active sites for a wide variety of reactions, including oxidation, hydrogenation, and carbon-carbon coupling. The interaction of a metal center with the support material can, in turn, be a determining factor for the stability and activity of the catalyst, making an informed selection of the support material critical to composition.</span></p> <p></div></div> <div style="background: #f7f7f7;border: 1px solid rgba(0, 0, 0, 0.07);"> <div style="padding: 30px;"><div class="Adblock-main"> <div class="Adblock-head"> <h2>Recent Publications on <b>“<a href="https://catalysis.blog/recent-publications/index/chemical engineering" target="_blank" rel="noopener" title="chemical engineering - yearwise publication list">chemical engineering</a>”</b></h2> </div> </div> <div class="pb-main"><div class="article-scroll"><div id="results_recent" class="results"></div></div><div class="keywordsdiv" style="margin: 0px 15px;margin-top:20px;"> <div style="text-align:center;"><b>Find publications on relevant topics</b> </div> <span class="gp-icon icon-tags"><svg viewBox="0 0 512 512" aria-hidden="true" xmlns="http://www.w3.org/2000/svg" width="1em" height="1em"><path d="M20 39.5c-8.836 0-16 7.163-16 16v176c0 4.243 1.686 8.313 4.687 11.314l224 224c6.248 6.248 16.378 6.248 22.626 0l176-176c6.244-6.244 6.25-16.364.013-22.615l-223.5-224A15.999 15.999 0 00196.5 39.5H20zm56 96c0-13.255 10.745-24 24-24s24 10.745 24 24-10.745 24-24 24-24-10.745-24-24z"></path><path d="M259.515 43.015c4.686-4.687 12.284-4.687 16.97 0l228 228c4.686 4.686 4.686 12.284 0 16.97l-180 180c-4.686 4.687-12.284 4.687-16.97 0-4.686-4.686-4.686-12.284 0-16.97L479.029 279.5 259.515 59.985c-4.686-4.686-4.686-12.284 0-16.97z"></path></svg></span> <span id="keyword-papers"></span> </div></div></div><div class="inside-article"> <style> .pb-main{ border: solid 1px #ccc; 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From the rates of reactions under various conditions, one is able to develop insight into the sequence of steps comprising the catalytic cycle and especially to determine the rate-limiting ones. This information becomes very important in optimizing catalytic processes since it enables the establishment of conditions that maximize reaction rates while at the same time minimizing side reactions.</span></p> <p><span style="font-weight: 400;">Mechanistic studies depend mainly on spectrometric, chromatographic methods and, more recently, on computational modeling to monitor the progression of a reaction and to detect any intermediates. Because the mechanistic information being extracted is so detailed, combining the experimental data with the theoretical approach yields highly detailed mechanistic pathways that describe the entire sequence of events leading to the formation of a product. Such pathways then serve as a roadmap for the development of catalysts that are more efficient and selective.</span></p> <h3><b>Challenges and Future Directions in Catalysis</b></h3> <p><span style="font-weight: 400;">Despite the solid advances reached in the understanding of catalytic mechanisms, several challenges are still lying ahead in the field of catalysis among these are the design and optimization of catalysts that are active in high selectivity and, at the same time, are stable under industrial conditions. Deactivation of the catalyst is due to fouling, poisoning, or sintering, which are the main issues reducing the efficiency of the catalytic process.</span></p> <p><span style="font-weight: 400;">Catalysis will in the future certainly provide solutions to some of humanity’s most daunting global challenges, such as climate change, energy security, and sustainable development. The new technologies for tomorrow will arise from next-generation catalysis, which can be achieved only with improved catalyst design that requires a fundamental understanding of the underlying mechanisms.</span></p> <p><span style="font-weight: 400;">In the future, catalysis will surely find ways to provide solutions for some of mankind’s most alarming global problems, like climate change, energy security, and sustainable development. Emerging new technologies developed to suit the challenges of an ever-changing world will rely on better catalyst design, which, in turn, relies on fundamental insight into catalytic mechanisms.</span></p> <h3><b>Conclusion</b></h3> <p><b></b><span style="font-weight: 400;">Catalytic mechanisms are building blocks for future developments in chemical engineering that apply to a range of industries and environments. To enhance the productivity and selectivity of a reaction, we are investigating various catalysis mechanisms, such as enzymatic or photocatalytic techniques that include heterogeneous and homogeneous catalysts. In particular, catalysis will progress in the future if we are able to solve current limitations, including catalyst stability and others, as well as develop more green and sustainable processes. More research and technology development needs to continue down the pathway of solving global problems, optimizing chemical production. Ultimately, a new level of insight into catalytic mechanisms will enable the design of more efficient and sustainable solutions.</span></p> <p></p> <h3><b>References</b></h3> <ol> <li>Hirschhorn, J.N., 2009. <a href="https://www.nejm.org/doi/full/10.1056/NEJMp0808934">Genomewide association studies—illuminating biologic pathways.</a> <i>New England journal of medicine</i>, <i>360</i>(17), pp.1699-1701.</li> <li>Hardy, J. and Singleton, A., 2009. <a href="https://www.nejm.org/doi/abs/10.1056/NEJMra0808700">Genomewide association studies and human disease.</a> <i>New England Journal of Medicine</i>, <i>360</i>(17), pp.1759-1768.</li> <li>Kraft, P. and Hunter, D.J., 2009. <a href="https://www.nejm.org/doi/abs/10.1056/NEJMp0810107">Genetic risk prediction—are we there yet?.</a> <i>New England Journal of Medicine</i>, <i>360</i>(17), pp.1701-1703.</li> <li>Schadt, E.E., Molony, C., Chudin, E., Hao, K., Yang, X., Lum, P.Y., Kasarskis, A., Zhang, B., Wang, S., Suver, C. and Zhu, J., 2008. <a href="https://journals.plos.org/plosbiology/article?id=10.1371/journal.pbio.0060107">Mapping the genetic architecture of gene expression in human liver.</a> <i>PLoS biology</i>, <i>6</i>(5), p.e107.</li> <li>Saxena, R., Voight, B.F., Lyssenko, V., Burtt, N.P., de Bakker, P.I., Chen, H., Roix, J.J., Kathiresan, S., Hirschhorn, J.N., Daly, M.J. and Hughes, T.E., 2007. <a href="https://www.science.org/doi/abs/10.1126/science.1142358">Genome-wide association analysis identifies loci for type 2 diabetes and triglyceride levels.</a> <i>Science</i>, <i>316</i>(5829), pp.1331-1336.</li> <li>Zelcer, N., Hong, C., Boyadjian, R. and Tontonoz, P., 2009. <a href="https://www.science.org/doi/abs/10.1126/science.1168974">LXR regulates cholesterol uptake through Idol-dependent ubiquitination of the LDL receptor.</a> <i>Science</i>, <i>325</i>(5936), pp.100-104.</li> <li>Nagle, C.A., An, J., Shiota, M., Torres, T.P., Cline, G.W., Liu, Z.X., Wang, S., Catlin, R.L., Shulman, G.I., Newgard, C.B. and Coleman, R.A., 2007. <a href="https://www.jbc.org/article/S0021-9258(20)63633-X/fulltext">Hepatic overexpression of glycerol-sn-3-phosphate acyltransferase 1 in rats causes insulin resistance.</a> <i>Journal of Biological Chemistry</i>, <i>282</i>(20), pp.14807-14815.</li> </ol> <p></div></div> <div style="background: #f7f7f7;border: 1px solid rgba(0, 0, 0, 0.07);"> <div style="padding: 30px;"><div class="Adblock-main"> <div class="Adblock-head"> <h2>Top Experts on “<b style="color:#000;font-size:22px;">chemical engineering</b>“</h2> </div> </div><div class="author-main"><div id="results_author"></div><div style="text-align: center;"><a class="register-button" href="https://catalysis.blog/expert-search" target="_blank" rel="noopener">Find experts on any field</a></div></div><div class="inside-article" style="background: none;border: none;box-shadow: none;margin-top: -70px;"> <style> .author-block { padding: 15px; 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