Hydrogen Sorption Kinetics in MgH2 and TiH2 Thin Films

<!DOCTYPE html> <html lang="en" dir="ltr"> <head> <meta name="format-detection" content="telephone=no"> <meta name="viewport" content="width=device-width, initial-scale=1.0" /> <meta charset="utf-8"> <meta http-equiv="X-UA-Compatible" content="IE=edge"> <link rel="canonical" href="https://www.scientific.net/DDF.383.127" /> <meta property="og:title" content="Hydrogen Sorption Kinetics in MgH2 and TiH2 Thin Films | Scientific.Net" /> <meta property="og:type" content="website" /> <meta property="og:url" content="https://www.scientific.net/DDF.383.127" /> <meta property="og:image" content="/Content/app/scinet5/images/metadata_logo.png" /> <meta property="og:image:type" content="image/png" /> <meta property="og:image:width" content="261" /> <meta property="og:image:height" content="260" /> <meta property="og:image:alt" content="Scientific.Net Logo" /> <meta name="citation_language" content="en" /> <meta name="citation_publisher" content="Trans Tech Publications Ltd" /> <meta name="citation_title" content="Hydrogen Sorption Kinetics in MgH2 and TiH2 Thin Films" /> <meta name="citation_publication_date" content="2018" /> <meta name="citation_online_date" content="2018/02/28" /> <meta name="citation_journal_title" content="Defect and Diffusion Forum" /> <meta name="citation_issn" content="1662-9507" /> <meta name="citation_volume" content="383" /> <meta name="citation_firstpage" content="127" /> <meta name="citation_lastpage" content="132" /> <meta name="citation_pdf_url" content="https://www.scientific.net/DDF.383.127.pdf" /> <meta name="citation_abstract_html_url" content="https://www.scientific.net/DDF.383.127" /> <meta name="citation_keywords" content="Hydrogenation Kinetics;Linear Regime;MgH<sub>2</sub>;Pressure Dependence;TiH<sub>2</sub>" /> <meta name="citation_doi" content="10.4028/www.scientific.net/DDF.383.127" /> <meta name="citation_author" content="Efi Hadjixenophontos" /> <meta name="citation_author" content="Lukas Michalek" /> <meta name="citation_author" content="Andreas Weigel" /> <meta name="citation_author" content="Guido Schmitz" /> <meta name="citation_reference" content="B. e. a. Sakintuna, International Journal of Hydrogen Energy 32, 1121 (2007)." /> <meta name="citation_reference" content="J. -C. Crivello, R.V. Denys, M. e. a. Dornheim, Appl. Phys. A 122, 122 (2016)." /> <meta name="citation_reference" content="M. Daryani, A. e. a. Simchi, International Journal of Hydrogen Energy 39, 21007 (2014)." /> <meta name="citation_reference" content="E. Hadjixenophontos, M. Roussel, T. e. a. Sato, International Journal of Hydrogen Energy (2017)." /> <meta name="citation_reference" content="Pyun S. -I. & Yoon Y. -G, International Materials Reviews 45, 190 (2013)." /> <meta name="citation_reference" content="H.T. Uchida et al., Acta Materialia 85 (2015)." /> <meta name="citation_reference" content="A. Surrey, L. Schultz, B. Rellinghaus, Adv Struct Chem Imag 2, 526 (2017)." /> <meta name="citation_reference" content="R.R. Georg Job, Physical Chemistry from a Different Angle (2011)." /> <meta name="citation_reference" content="M. Paskevicius, D.A. Sheppard, C.E. Buckley, Journal of the American Chemical Society 132, 5077 (2010)." /> <meta name="citation_reference" content="A. San-Martin, F.D. Manchester, Bulletin of Alloy Phase Diagrams 8, 30 (1987)." /> <meta name="person" content="Efi Hadjixenophontos, Lukas Michalek, Andreas Weigel, Guido Schmitz" /> <meta name="description" content="The diffusion mechanism of H in metals and metal hydrides is studied particularly at high H2 pressures. Thin films of Mg and Ti offer a convenient tool to quantify the atomic transport. We show how different parameters of hydrogenation affect the kinetics. At 200°C, the Pd-Mg interface is predominant and a linear regime of hydrogenation is observed, whereas at 300°C a parabolic regime is detected. In Mg, the hydride forms from the surface to the substrate whereas in Ti growth of TiH2 starts from the substrate. A linear kinetics is seen during hydrogenation of Ti films, which is due to the oxide layer on top, measured to be about 10nm thick. In the studied high pressure regime, the hydrogenation is not pressure dependent any more. Quantitative calculation of the growth rate and the diffusion coefficient of H in the hydrides is presented." /> <meta name="keywords" content="Hydrogenation Kinetics, Linear Regime, MgH<sub>2</sub>, Pressure Dependence, TiH<sub>2</sub>" /> <meta name="copyright" content="2018 Trans Tech Publications Ltd. All Rights Reserved" /> <title>Hydrogen Sorption Kinetics in MgH2 and TiH2 Thin Films | Scientific.Net</title> <link href="/Content/app/scinet5/images/favicon.ico" rel="shortcut icon" /> <link href="/Content/public.min.css?v=BKBihgCkUm340JBGsNjEPtWz8I22CUsubMPC3V1WYzw" rel="stylesheet" /> <link rel="preconnect" href="https://www.google-analytics.com"> <link rel="preconnect" href="https://www.gstatic.com"> <link rel="preconnect" href="https://www.googletagmanager.com"> <link rel="icon" href="/Content/app/scinet5/images/favicon.ico"> <link rel="apple-touch-icon" href="/Content/app/scinet5/images/apple-touch-icon.png"> <link rel="preconnect" href="https://fonts.googleapis.com"> <link rel="preconnect" href="https://fonts.gstatic.com" crossorigin> <link href="https://fonts.googleapis.com/css?family=Open+Sans+Condensed:300,700%7COpen+Sans:300i,400,400i,600,600i,700&display=swap" rel="stylesheet">    <script> (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start': new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0], j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src= 'https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f); })(window,document,'script','dataLayer','GTM-T3VDKWV');</script>  </head> <body> <noscript>  <iframe src="https://www.googletagmanager.com/ns.html?id=GTM-T3VDKWV" height="0" width="0" style="display:none;visibility:hidden"></iframe> </noscript> <div class="sc-content-container"> <div class="sc-content"> <div class="header-menu-container"> <div class="identity-menu-container header-menu-container-not-logged-in"> <div class="container"> <div class="row"> <ul class="role-menu"> <li class="user-menu between normal-user-menu"> <div class="hdivider-100"></div> <div class="cart-info"> <a href="https://main.scientific.net/Payment/Cart"> <i class="inline-icon cart-icon-white"></i> <span id="cartInfoTotalItemsCount"></span> </a> </div> <div class="user-menu-login-or-register"> <a href="https://main.scientific.net/Account/Registration?ReturnUrl=https%3A%2F%2Fwww.scientific.net%2FDDF.383.127" rel="nofollow"> Registration </a> <a href="https://main.scientific.net/Account/Login?ReturnUrl=https%3A%2F%2Fwww.scientific.net%2FDDF.383.127" rel="nofollow"> Log In </a> </div> </li> </ul> </div> </div> </div> <div class="header-fluid"> <div class="container"> <div class="row"> <div class="block-header"> <div class="logo-block"> <a href="/" class="application-logo inline-icon logo-icon"></a> <div class="burger-menu-button visible-xs"> <div class="hamburger-box"> <div class="hamburger-inner"></div> </div> </div> </div> <div class="menu-and-search-block"> <div class="burger-menu"> <nav class="burger-menu-items"> <div class="public-menu"> <ul> <li><a href="/ForLibraries">For Libraries</a></li> <li><a href="/ForPublication/Paper">For Publication</a></li> <li><a href="/DocuCenter">Downloads</a></li> <li><a href="/news/all">News</a></li> <li><a href="/Home/AboutUs">About Us</a></li> <li><a href="/Home/Contacts">Contact Us</a></li> </ul> </div> </nav> </div> <div class="header-menu-top"> <div class="header-menu-list"> <a href="/ForLibraries">For Libraries</a> <a href="/ForPublication/Paper">For Publication</a> <a href="/DocuCenter">Downloads</a> <a href="/news/all">News</a> <a href="/Home/AboutUs">About Us</a> <a href="/Home/Contacts">Contact Us</a> </div> </div> <div class="search-block"> <input class="search-control" type="search" placeholder="Search" data-url="/Search"> <button class="button button-95 button-grey search-btn button-simple"> <span class="hidden-xs">Search</span> <i class="inline-icon search-icon-grey visible-xs"></i> </button> </div> </div> </div> </div> </div> </div> </div> <div class="container-fluid"> <div class="row"> <div class="banner-new"></div> </div> </div> <div class="content"> <div class="container"> <div class="row content-container"> <div class="left-content col-md-4 col-sm-5"> <div class="left-content-first-line icon-container mobile-collapse-button"> <div class="page-name-block underline-begin sibling-name-block"> <div class="page-name-block-text"> Paper Titles <a class="left-content-expand-button"><i class="inline-icon arrow-right-black no-hover-icon on-focus-arrow-down-black"></i></a> </div> </div> </div> <div class="row mobile-collapse-content"> <a href="/DDF.383.96" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> Effect of Equal Channel and Dynamic Channel Angular Pressing of Ni and Further Heat Treatment on its Structure and Grain Boundary Diffusion <br /> <span class="paper-volume-number">p.96</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.103" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> Effect of Atomic Complexes Formation in Grain Boundaries on Grain Boundary Diffusion <br /> <span class="paper-volume-number">p.103</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.112" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> Mullins' Self-Similar Grooving Solution Revisited <br /> <span class="paper-volume-number">p.112</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.118" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> The Role of Interfaces in Evolution of Structure and Thermal Stability of Cu-Nb Composite Processed by High-Pressure Torsion <br /> <span class="paper-volume-number">p.118</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.127" class="normal-large-text icon-container active-element active"> <div class="element-list"> <div class="element-list-text"> Hydrogen Sorption Kinetics in MgH<sub>2</sub> and TiH<sub>2</sub> Thin Films <br /> <span class="paper-volume-number">p.127</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.133" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> On the Mechanism of Oxidation Resistance of W-Cr-Pd Alloys <br /> <span class="paper-volume-number">p.133</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.142" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> <i>In Situ</i> XRD Experiments on the Growth of Expanded Austenite Using Different Process Gases <br /> <span class="paper-volume-number">p.142</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.147" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> Oxidation Kinetics of Nitrogen Doped TiO<sub>2-未</sub> Thin Films: Analysis on the Basis of Oxygen Activity Dependence of the Chemical Diffusion Coefficient <br /> <span class="paper-volume-number">p.147</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> <a href="/DDF.383.153" class="normal-large-text icon-container"> <div class="element-list"> <div class="element-list-text"> Properties of Species Profiles during Oxygen Chemical Diffusion in Oxides <br /> <span class="paper-volume-number">p.153</span> </div> <div class="element-list-arrow"> <i class="inline-icon arrow-right-black no-focus-icon on-hover-arrow-left-red"></i> </div> </div> </a> </div> </div> <div class="right-content col-md-8 col-sm-7 col-xs-12 paper-title-main-page"> <div class="bread-crumbs hidden-xs"> <a class="bread-crumbs-first" href="/">Home</a><i class="inline-icon arrow-breadcrumbs"></i><a class="bread-crumbs-first" href="/DDF">Defect and Diffusion Forum</a><i class="inline-icon arrow-breadcrumbs"></i><a class="bread-crumbs-first" href="/DDF.383">Defect and Diffusion Forum Vol. 383</a><i class="inline-icon arrow-breadcrumbs"></i><span class="bread-crumbs-second">Hydrogen Sorption Kinetics in MgH2 and TiH2 Thin...</span></div> <div class="page-name-block underline-begin"> <h1 class="page-name-block-text">Hydrogen Sorption Kinetics in MgH<sub>2</sub> and TiH<sub>2</sub> Thin Films</h1> </div> <div class="paper-statistics"> <div class="loading"> <i class="inline-icon download-and-visitor-statistics-icon"></i> <span class="normal-text" id="paperDownloadsAndVisitorsCount"></span> </div> </div> <div class="clearfix"></div> <div class="page-paper-title"> <div class="preview-block"> <img alt="Article Preview" width="128" height="180" src="/DDF.383.127/thumbnail.gif"> <div id="preview-button" data-url-preview-log="/Paper/PreviewImageLog?paperId=527688"> <i class="inline-icon preview-icon"></i> </div>  <div id="paper-preview-modal" class="modal fade"> <div class="modal-dialog" role="document"> <div class="popup-page-name underline-begin"> <div class="page-name-block-text">Article Preview</div> </div> <img alt="Article Preview" class="preview-image lazyload" data-src="/DDF.383.127/preview.gif"> <a data-dismiss="modal" title="Close" class="inline-icon close-icon"></a> </div> </div>  </div> <div class="abstract-block-description"> <h3 class="page-paper-first-header">Abstract:</h3> <p class="normal-text"> The diffusion mechanism of H in metals and metal hydrides is studied particularly at high H<sub>2</sub> pressures. Thin films of Mg and Ti offer a convenient tool to quantify the atomic transport. We show how different parameters of hydrogenation affect the kinetics. At 200掳C, the Pd-Mg interface is predominant and a linear regime of hydrogenation is observed, whereas at 300掳C a parabolic regime is detected. In Mg, the hydride forms from the surface to the substrate whereas in Ti growth of TiH<sub>2</sub> starts from the substrate. A linear kinetics is seen during hydrogenation of Ti films, which is due to the oxide layer on top, measured to be about 10nm thick. In the studied high pressure regime, the hydrogenation is not pressure dependent any more. Quantitative calculation of the growth rate and the diffusion coefficient of H in the hydrides is presented. </p> </div> <div class="paper-access-buttons col-xs-12"> <div class="row"> <div class="sa-button-wrap"> <a id="sa-button" class="wayfinder-login d-flex sa-button" href="javascript:;"> <div class="sa-button-logo-wrap"> <i class="inline-icon sa-white"></i> </div> <div class="d-flex justify-content-center align-items-center sa-button-text text-truncate"> <div class="sa-button-text-primary text-truncate">Access through your institution</div> </div> </a> </div> <div class="title-button-pdf"> <button id="readPaperButton" data-url-read-paper-log="/Paper/ReadThePaperLog?paperId=527688" class="button button-160"> <span class="inline-element">Read The Paper</span> </button> </div> </div> <div class="row"> </div> </div> <div class="clearfix"></div> <div class="connected-title-container"> <div class="connected-title-text semibold-middle-text">You might also be interested in these eBooks</div> <div class="connected-title-list-container"> <div class="connected-title-list-item"> <a href="/book/diffusion-in-materials-dimat-2017/978-3-0357-3130-9" title="Diffusion in Materials DIMAT-2017"> <img class="ls-is-cached lazyloaded" src="/Image/TitleCover/4480?width=190" alt="Diffusion in Materials DIMAT-2017" /> </a> <a id="downloadPdfButton" href="/book/diffusion-in-materials-dimat-2017/978-3-0357-3130-9/ebook" class="button"> <span>View Preview</span> <i class="inline-icon book-icon-white small-icon button-icon-right"></i> </a> </div> </div> </div> <div class="papers-block-info-title"> <h2>Info:</h2> </div> <div class="clearfix"></div> <div class="papers-block-info-list"> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Periodical:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <a href="/DDF">Defect and Diffusion Forum</a> <span>(Volume 383)</span> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Pages:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <p>127-132</p> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>DOI:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <p><a href="https://doi.org/10.4028/www.scientific.net/DDF.383.127">https://doi.org/10.4028/www.scientific.net/DDF.383.127</a></p> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Citation:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <p><a id="paperCitationsButton" href="#">Cite this paper</a></p> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Online since:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <p>February 2018</p> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Authors:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <a class="inline-icon mail-icon-red author-send-message" href="#" data-url="/Paper/_Message?paperId=527688&personId=1527132&urlSent=https%3A%2F%2Fwww.scientific.net%2FDDF.383.127" title="Send message to Corresponding Author"> </a> <a href="/author-papers/efi-hadjixenophontos">Efi Hadjixenophontos</a>*, <a href="/author-papers/lukas-michalek">Lukas Michalek</a>, <a href="/author-papers/andreas-weigel">Andreas Weigel</a>, <a href="/author-papers/guido-schmitz-2">Guido Schmitz</a> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Keywords:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <a href="/paper-keyword/hydrogenation-kinetics">Hydrogenation Kinetics</a>, <a href="/paper-keyword/linear-regime">Linear Regime</a>, <a href="/paper-keyword/mgh2">MgH<sub>2</sub></a>, <a href="/paper-keyword/pressure-dependence">Pressure Dependence</a>, <a href="/paper-keyword/tih2">TiH<sub>2</sub></a> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Export:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <a href="/DDF.383.127.ris">RIS</a>, <a href="/DDF.383.127.bib">BibTeX</a> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Price:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <p id="paper-price-info"></p> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Permissions:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <p> <i class="inline-icon icon-permission"></i> <a href="https://marketplace.copyright.com/rs-ui-web/mp/search/article/10.4028%2Fwww.scientific.net%2FDDF.383.127" target="_blank"> Request Permissions </a> </p> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Сopyright:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <p> 漏 2018 Trans Tech Publications Ltd. All Rights Reserved </p> </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Share:</p> </div> </div> <div class="info-row-content share-icons semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row">  <div id="" class="a2a_kit a2a_kit_size_32 a2a_default_style"> <a class="a2a_button_linkedin"></a> <a class="a2a_button_mendeley"></a> <a class="a2a_button_email"></a> <a class="a2a_button_x"></a> <a class="a2a_button_twitter"></a> <a class="a2a_button_whatsapp"></a> <a class="a2a_button_microsoft_teams"></a> <a class="a2a_button_skype"></a> <a class="a2a_button_outlook_com"></a> <a class="a2a_dd" href="https://www.addtoany.com/share"></a> </div> <script async src="https://static.addtoany.com/menu/page.js"></script>  </div> </div> </div> </div> <div class="papers-block-info col-lg-12"> <div class="row"> <div class="info-row-name normal-text-gray col-md-2 col-sm-3 col-xs-4"> <div class="row"> <p>Citation:</p> </div> </div> <div class="info-row-content semibold-middle-text col-md-10 col-sm-9 col-xs-8"> <div class="row"> <div class="scite-badge" data-doi="10.4028/www.scientific.net/DDF.383.127" data-layout="horizontal" data-show-zero="true" data-small="false" data-show-labels="false" data-tally-show="true"> </div> </div> </div> </div> </div> </div> <div class="block-corresponding-buttons col-xs-12"> <div class="row"> <div class="block-corresponding normal-text-gray col-md-4 col-xs-12"> <div class="row"> <p><span>*</span> - Corresponding Author</p> </div> </div> </div> </div> <div class="related-article reference-collapse col-xs-12"> <div class="row"> <div class="view"> <div class="panel-group" id="references-panel"> <div class="panel panel-default"> <div class="panel-heading"> <a class="panel-title bold-large-text icon-container" data-toggle="collapse" data-parent="#references-panel" href="#reference-panel-element"> References <i class="inline-icon arrow-right-black"></i> </a> </div> <div id="reference-panel-element" class="panel-collapse collapse"> <div class="panel-body"> <div class="references-block"> <div class="reference-text volume-info-text"> <p> <span>[1]</span> B. e. a. Sakintuna, International Journal of Hydrogen Energy 32, 1121 (2007). </p> <p><a href="https://scholar.google.com/scholar?q=B.%20e.%20a.%20Sakintuna%2C%20International%20Journal%20of%20Hydrogen%20Energy%2032%2C%201121%20%282007%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[2]</span> J. -C. Crivello, R.V. Denys, M. e. a. Dornheim, Appl. Phys. A 122, 122 (2016). </p> <p><a href="https://scholar.google.com/scholar?q=J.%20-C.%20Crivello%2C%20R.V.%20Denys%2C%20M.%20e.%20a.%20Dornheim%2C%20Appl.%20Phys.%20A%20122%2C%20122%20%282016%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[3]</span> M. Daryani, A. e. a. Simchi, International Journal of Hydrogen Energy 39, 21007 (2014). </p> <p><a href="https://scholar.google.com/scholar?q=M.%20Daryani%2C%20A.%20e.%20a.%20Simchi%2C%20International%20Journal%20of%20Hydrogen%20Energy%2039%2C%2021007%20%282014%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[4]</span> E. Hadjixenophontos, M. Roussel, T. e. a. Sato, International Journal of Hydrogen Energy (2017). </p> <p><a href="https://scholar.google.com/scholar?q=E.%20Hadjixenophontos%2C%20M.%20Roussel%2C%20T.%20e.%20a.%20Sato%2C%20International%20Journal%20of%20Hydrogen%20Energy%20%282017%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[5]</span> Pyun S. -I. & Yoon Y. -G, International Materials Reviews 45, 190 (2013). </p> <p><a href="https://scholar.google.com/scholar?q=Pyun%20S.%20-I.%20%26%20Yoon%20Y.%20-G%2C%20International%20Materials%20Reviews%2045%2C%20190%20%282013%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[6]</span> H.T. Uchida et al., Acta Materialia 85 (2015). </p> <p><a href="https://scholar.google.com/scholar?q=H.T.%20Uchida%20et%20al.%2C%20Acta%20Materialia%2085%20%282015%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[7]</span> A. Surrey, L. Schultz, B. Rellinghaus, Adv Struct Chem Imag 2, 526 (2017). </p> <p><a href="https://scholar.google.com/scholar?q=A.%20Surrey%2C%20L.%20Schultz%2C%20B.%20Rellinghaus%2C%20Adv%20Struct%20Chem%20Imag%202%2C%20526%20%282017%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[8]</span> R.R. Georg Job, Physical Chemistry from a Different Angle (2011). </p> <p><a href="https://scholar.google.com/scholar?q=R.R.%20Georg%20Job%2C%20Physical%20Chemistry%20from%20a%20Different%20Angle%20%282011%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[9]</span> M. Paskevicius, D.A. Sheppard, C.E. Buckley, Journal of the American Chemical Society 132, 5077 (2010). </p> <p><a href="https://scholar.google.com/scholar?q=M.%20Paskevicius%2C%20D.A.%20Sheppard%2C%20C.E.%20Buckley%2C%20Journal%20of%20the%20American%20Chemical%20Society%20132%2C%205077%20%282010%29.">Google Scholar</a></p> </div> <div class="reference-text volume-info-text"> <p> <span>[10]</span> A. San-Martin, F.D. Manchester, Bulletin of Alloy Phase Diagrams 8, 30 (1987). </p> <p><a href="https://scholar.google.com/scholar?q=A.%20San-Martin%2C%20F.D.%20Manchester%2C%20Bulletin%20of%20Alloy%20Phase%20Diagrams%208%2C%2030%20%281987%29.">Google Scholar</a></p> </div> </div> </div> </div> </div> </div> </div> </div> </div> <div class="related-article cited-collapse col-xs-12"> <div class="row"> <div class="view"> <div class="panel-group" id="cited-panel"> <div class="panel panel-default"> <div class="panel-heading"> <a id="citedby-link" class="panel-title bold-large-text icon-container" data-toggle="collapse" data-parent="#cited-panel-" data-paper-id="527688" href="#citedby-root"> Cited by <i class="inline-icon arrow-right-black"></i> </a> </div> <div id="citedby-root" class="panel-collapse collapse"> <span class="busy-icon"></span> </div> </div> </div> </div> </div> </div> <div class="related-article related-collapse col-xs-12"> <div class="row"> <div class="view"> <div class="panel-group" id="related-articles-panel"> <div class="panel panel-default"> <div class="panel-heading"> <a id="related-articles-link" class="panel-title bold-large-text icon-container" data-toggle="collapse" data-parent="#related-articles-panel" href="#related-articles-root"> Related Articles <i class="inline-icon arrow-right-black"></i> </a> </div> <div id="related-articles-root" class="panel-collapse collapse"> <span class="busy-icon"></span> </div> </div> </div> </div> </div> </div> </div> </div> </div> </div> </div> <div id="author-message-modal" class="modal fade" tabindex="-1" role="dialog"></div> <div id="citations-modal" class="modal fade" role="dialog"> <div class="modal-dialog popup"> <div class="popup-page-name underline-begin"> <div class="page-name-block-text">Citation</div> </div> <a class="inline-icon close-icon" data-dismiss="modal" title="Close"></a> <div class="modal-body"> <div id="citations-modal-content"></div> </div> </div> </div> <div id="addToCart" class="modal fade" tabindex="-1" role="dialog"> <div class="modal-dialog" role="document"> <div class="popup-page-name underline-begin"> <div class="page-name-block-text">Add To Cart</div> </div> <div class="shopping-cart-block"> <div class="popup-cart-block-image"> <i class="inline-icon add-paper-icon"></i> </div> <div class="popup-cart-block-text"> <p>Paper price: <span id="popup-paper-price"></span></p> <p>After payment, you will receive an email with instructions and a link to download the purchased paper.</p> <p>You may also check the possible access via personal account by logging in or/and check access through your institution.</p> </div> </div> <div class="popup-block-buttons clearfix"> <div class="three-buttons-block"> <a data-dismiss="modal" class="button button-95 button-grey icon-container"> <i class="inline-icon button-arrow-back-black button-icon-left"></i> <span class="inline-element">Back</span> </a> <button data-url="/Cart/AddPaper" data-paperid="527688" id="addPaperButton" class="button button-160" disabled> <span class="inline-element">Add to Cart</span> <i class="inline-icon cart-icon-white button-icon-right"></i> </button> </div> </div> <a data-dismiss="modal" title="Close" class="inline-icon close-icon"></a> </div> </div> <div id="addedToCart" class="modal fade" tabindex="-1" role="dialog"> <div class="modal-dialog" role="document"> <div class="popup-page-name underline-begin"> <div class="page-name-block-text">Add To Cart</div> </div> <div class="shopping-cart-block"> <div class="popup-cart-block-image"> <i class="inline-icon add-paper-icon"></i> </div> <div class="popup-cart-block-text"> <p>This paper has been added to your cart</p> </div> </div> <div class="popup-block-buttons clearfix"> <div class="three-buttons-block"> <a data-dismiss="modal" class="button button-95 button-grey icon-container"> <i class="inline-icon button-arrow-back-black button-icon-left"></i> <span class="inline-element">Back</span> </a> <a href="https://main.scientific.net/Payment/Cart" class="button button-160"> <span class="inline-element">To Cart</span> <i class="inline-icon cart-icon-white button-icon-right"></i> </a> </div> </div> <a data-dismiss="modal" title="Close" class="inline-icon close-icon"></a> </div> </div> <div class="social-icon-popup"> <a href="https://www.facebook.com/Scientific.Net.Ltd/" target="_blank" rel="noopener" title="Scientific.Net"><i class="inline-icon facebook-popup-icon social-icon"></i></a> <a href="https://twitter.com/Scientific_Net/" target="_blank" rel="noopener" title="Scientific.Net"><i class="inline-icon twitter-popup-icon social-icon"></i></a> <a href="https://www.linkedin.com/company/scientificnet/" target="_blank" rel="noopener" title="Scientific.Net"><i class="inline-icon linkedin-popup-icon social-icon"></i></a> </div> </div> <div class="sc-footer"> <div class="footer-fluid"> <div class="container"> <div class="row"> <div class="footer-menu col-md-12 col-sm-12 col-xs-12"> <ul class="list-inline menu-font"> <li><a href="/ForLibraries">For Libraries</a></li> <li><a href="/ForPublication/Paper">For Publication</a></li> <li><a href="/insights" target="_blank">Insights</a></li> <li><a href="/DocuCenter">Downloads</a></li> <li><a href="/Home/AboutUs">About Us</a></li> <li><a href="/PolicyAndEthics/PublishingPolicies">Policy & Ethics</a></li> <li><a href="/Home/Contacts">Contact Us</a></li> <li><a href="/Home/Imprint">Imprint</a></li> <li><a href="/Home/PrivacyPolicy">Privacy Policy</a></li> <li><a href="/Home/Sitemap">Sitemap</a></li> <li><a href="/Conferences">All Conferences</a></li> <li><a href="/special-issues">All Special Issues</a></li> <li><a href="/news/all">All News</a></li> <li><a href="/read-and-publish-agreements">Read & Publish Agreements</a></li> </ul> </div> </div> </div> </div> <div class="line-footer"></div> <div class="footer-fluid"> <div class="container"> <div class="row"> <div class="col-xs-12"> <a href="https://www.facebook.com/Scientific.Net.Ltd/" target="_blank" rel="noopener" title="Scientific.Net"><i class="inline-icon facebook-footer-icon social-icon"></i></a> <a href="https://twitter.com/Scientific_Net/" target="_blank" rel="noopener" title="Scientific.Net"><i class="inline-icon twitter-footer-icon social-icon"></i></a> <a href="https://www.linkedin.com/company/scientificnet/" target="_blank" rel="noopener" title="Scientific.Net"><i class="inline-icon linkedin-footer-icon social-icon"></i></a> </div> </div> </div> </div> <div class="line-footer"></div> <div class="footer-fluid"> <div class="container"> <div class="row"> <div class="col-xs-12 footer-copyright"> <p> © 2024 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied. <br />Scientific.Net is a registered trademark of Trans Tech Publications Ltd. </p> </div> </div> </div> </div> </div> <a class="scrollTop inline-icon scroll-top-icon" href="#" style="display: none"></a> </div> <script src="/Scripts/public.min.js?v=BtSq2PJEHRTW2PekpQGgIQKs7-OSPiKhsoI9rMs6kTU"></script> <script src="https://scholar.google.com/scholar_js/casa.js" async></script> <script async type="application/javascript" src="https://cdn.scite.ai/badge/scite-badge-latest.min.js"></script> <script> $(function () { var statisticsDownloadedHandler = function ($element) { return function (count) { $element.text(count); $element.parent().removeClass("loading"); }; }; $.get("/Paper/GetDownloadsAndVisitorsCount?paperId=527688", statisticsDownloadedHandler($("#paperDownloadsAndVisitorsCount"))); $.ajax({method: "GET", url: "/Paper/GetPrice?paperId=527688" }) .retry({times: 3, timeout: 3000 }) .done(function (price) { $("#paper-price-info").html(price); $("#popup-paper-price").html(price); $("#addPaperButton").removeAttr("disabled"); }); $("#paperCitationsButton").on("click", function (e) { e.preventDefault(); Scinet.busy.lock(); var $modal = $("#citations-modal"), $modalContent = $("#citations-modal-content"); $.get("/Paper/Citations?doi=10.4028%2Fwww.scientific.net%2FDDF.383.127") .done(function (content) { Scinet.busy.unlock(); $modalContent.html(content); $modal.modal(); }) .fail(function () { Scinet.busy.unlock(); Scinet.error("The DOI has not been activated yet. Please try again later."); }); }); $("#ask-by-email-button") .on("click", function (e) { e.preventDefault(); var url = $(this).data("url"); $("#ask-by-email-modal") .load(url, function () { $("#ask-by-email-modal").modal(); }); }); $("#downloadPdfButton").on("click", function () { Scinet.busy.lock(); setTimeout(Scinet.busy.unlock, 8000); }); var readThePaperLogged = false; $("#readPaperButton").on( "click", function (e) { e.preventDefault(); $("#addToCart").modal(); if (!readThePaperLogged) { var url = $("#readPaperButton").data("urlReadPaperLog"); $.ajax({ url: url }); readThePaperLogged = true; } }); $("#addPaperButton").on( "click", function (e) { e.preventDefault(); var $button = $(this), url = $button.data("url"), paperId = $button.data("paperid"); $.post(url, { paperId: paperId }) .done( function () { Scinet.public.loadCartInfo(); $('#addToCart').modal('hide'); $("#addedToCart").modal(); }); }); $(".paper-title-main-page a.panel-title").on("click", function () { $(this).toggleClass("active"); }); $(".author-send-message").on("click", function (e) { e.preventDefault(); var url = $(this).data("url"), $modal = $("#author-message-modal"); $modal.load(url, function () { $modal.modal(); }); }); var previewLogged = false; $("#preview-button") .on("click", function () { $("#paper-preview-modal").modal(); if (!previewLogged) { var url = $(this).data("url-preview-log"); $.ajax({ url: url }); previewLogged = true; } }); function getCitedByInfo(page) { var $citedbyroot = $("#citedby-root"); var paperId = $("#citedby-link").data("paper-id"); if (paperId && page) { $.ajax( { method: "GET", url: "/Paper/CitedBy", data: { paperId: paperId, pageNumber: page } }) .done( function (response) { $citedbyroot.html(response); $(".citedby-paginator").on("click", function () { var pageNumber = $(this).attr("page"); getCitedByInfo(pageNumber); }); }) .fail( function (request, status, error) { $citedbyroot .html('<div style="color: red; padding-top: 30px; padding-bottom: 30px;"><p>' + error + "</p></div>"); }); } } $("#citedby-link") .on("click", function () { var $citedbyroot = $("#citedby-root"); if (!$citedbyroot.data("loaded")) { getCitedByInfo(1); $citedbyroot.data("loaded", true); } }); $("#citations-modal-content") .on("click", ".citations-list-item-value a", function (e) { e.preventDefault(); }); var clipboard = new ClipboardJS("#citations-modal-content .citations-list-item .inline-icon"); clipboard.on("success", function (e) { var $icon = $(e.trigger); var originalName = "data-original-title"; var prevTitle = $icon.attr(originalName); $icon.addClass("icon-copied").removeClass("icon-copy"); $icon.attr(originalName, "Copied!").tooltip("show"); setTimeout(function () { $icon.attr(originalName, prevTitle).tooltip("hide"); $icon.addClass("icon-copy").removeClass("icon-copied"); }, 3000); e.clearSelection(); }); function getRelatedArticles() { var $releatedArticlesRoot = $("#related-articles-root"); $.ajax( { method: "GET", url: "/Paper/RelatedArticles?paperId=527688" }) .done( function (response) { $releatedArticlesRoot.html(response); }) .fail( function (request, status, error) { $releatedArticlesRoot .html('<div style="color: red; padding-top: 30px; padding-bottom: 30px;"><p>Server Error. Sorry for the inconvenience. Our team is working to fix this internal error. Please check back shortly.</p></div>'); }); } $("#related-articles-link") .on("click", function () { var $releatedArticlesRoot = $("#related-articles-root"); if (!$releatedArticlesRoot.data("loaded")) { getRelatedArticles(); $releatedArticlesRoot.data("loaded", true); } }) $("body").tooltip({ selector: "[data-toggle=tooltip]" }); }); $(document) .ready( function () { var isHidden = sessionStorage.getItem('isPublicMessagesHidden'); if (isHidden === 'true') { $('.message-container').hide(); } $('#hide-button') .click( function (event) { event.preventDefault(); $('.message-container').hide(); sessionStorage.setItem('isPublicMessagesHidden', 'true'); }); }); </script> <script asp-render-component-scripts> (function (w, a, y, f) { w._wayfinder = w._wayfinder || function () { (w._wayfinder.q = w._wayfinder.q || []).push(arguments) }; p = { oaDomain: 'scientific.net', oaAppId: '9a54dd64-0769-4f59-a7ec-b249515c9de7' }; w._wayfinder.settings = p; w._wayfinder.options = { rememberCrossSite: false }; h = a.getElementsByTagName('head')[0]; s = a.createElement('script'); s.async = 1; q = Object.keys(p).map(function (key) { return key + '=' + p[key] }).join('&'); s.src = y + 'v1' + f + "?" + q; h.appendChild(s); } )(window, document, 'https://wayfinder.openathens.net/embed/', '/loader.js'); $(function () { var wayfinderEnabled = true; $("#sa-button").on("click", function (e) { if (wayfinderEnabled) { setTargetPageCookie(); } else { e.preventDefault(); setTargetPageCookie(); window.location.href = this.href; } }); function setTargetPageCookie() { var in5Minutes = 1 / 3600 * 5; Cookies.set("Scinet.TargetPage", window.location.href, { domain: ".scientific.net", expires: in5Minutes, secure: true }); } }); Scinet.public = (function () { function loadCartInfo(onLoad) { var formatCartItemCount = function (count) { var format = (count > 1 || count === 0) ? "{0} items" : "{0} item"; $("#cartInfoTotalItemsCount").html(Scinet.stringFormat(format, count)); }, cookieCartItemCount = Cookies.get("Scinet5.CartItemsCount"); if (onLoad && cookieCartItemCount != null) { formatCartItemCount(parseInt(cookieCartItemCount, 10)); } else { $.ajax({ url: "/Cart/GetItemsCount", cache: false }) .done( function (count) { Cookies.set("Scinet5.CartItemsCount", count, { domain: ".scientific.net", secure: true }); formatCartItemCount(count); }); } } return { loadCartInfo: loadCartInfo }; })(); $(function () { Scinet.public.loadCartInfo(true); $("[data-add-book-to-cart]").on("click", function (e) { e.preventDefault(); var data = $(this).data("add-book-to-cart"); console.log(data); var url = "/Cart/AddBook"; $.post(url, data) .done( function () { Scinet.public.loadCartInfo(); $("#addToCart").modal(); }) .fail( function (xhr) { Scinet.error(xhr.responseText); }); }) }); </script> <script> var $buoop = { required: { e: 11, f: -6, o: -6, s: -3, c: -6 }, insecure: false, unsupported: false, api: 2019.11, reminder: 0, onshow: function () { window.browserUpdateOutdated = true; } }; function $buo_f() { var e = document.createElement("script"); e.src = "//browser-update.org/update.min.js"; document.body.appendChild(e); }; try { document.addEventListener("DOMContentLoaded", $buo_f, false) } catch (e) { window.attachEvent("onload", $buo_f) } </script>   <script> window.clientErrorLogActionUrl = "/Errors/LogClientError"; </script> </body> </html>

CINXE.COM

Hydrogen Sorption Kinetics in MgH2 and TiH2 Thin Films | Scientific.Net